EP0226946A1 - Method for continuously making webs for the building industry - Google Patents
Method for continuously making webs for the building industry Download PDFInfo
- Publication number
- EP0226946A1 EP0226946A1 EP86117176A EP86117176A EP0226946A1 EP 0226946 A1 EP0226946 A1 EP 0226946A1 EP 86117176 A EP86117176 A EP 86117176A EP 86117176 A EP86117176 A EP 86117176A EP 0226946 A1 EP0226946 A1 EP 0226946A1
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- European Patent Office
- Prior art keywords
- web
- layer
- pressure
- molding layer
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000000034 method Methods 0.000 title claims abstract description 32
- 238000001816 cooling Methods 0.000 claims abstract description 20
- 238000010924 continuous production Methods 0.000 claims abstract description 4
- 238000007906 compression Methods 0.000 claims abstract description 3
- 238000000465 moulding Methods 0.000 claims description 17
- 239000002184 metal Substances 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 14
- 239000012815 thermoplastic material Substances 0.000 claims description 7
- 238000005245 sintering Methods 0.000 claims description 3
- 230000001427 coherent effect Effects 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims description 2
- 239000004760 aramid Substances 0.000 claims 1
- 229920003235 aromatic polyamide Polymers 0.000 claims 1
- 230000005672 electromagnetic field Effects 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 7
- 229920001169 thermoplastic Polymers 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 description 14
- 238000003825 pressing Methods 0.000 description 9
- 238000000227 grinding Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229920000271 Kevlar® Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- -1 for example Chemical compound 0.000 description 1
- 239000004761 kevlar Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
- B29C43/30—Making multilayered or multicoloured articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/006—Pressing and sintering powders, granules or fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/44—Compression means for making articles of indefinite length
- B29C43/48—Endless belts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/02—Moulding by agglomerating
- B29C67/04—Sintering
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/06—PVC, i.e. polyvinylchloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
- B29K2105/251—Particles, powder or granules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/002—Coloured
- B29K2995/0021—Multi-coloured
Definitions
- the invention relates to a method for the continuous production of sheet goods for the building industry according to the preamble of claim 1.
- Flooring and wall coverings and in particular those made of thermoplastic materials are understood to be web products for the construction industry in the sense of this invention.
- the preferred area of application is the production of directionally patterned floor and wall coverings based on PVC.
- Shaped pieces in the sense of this invention are in particular chips, crumbs, sections, pieces or chips made of suitable starting materials.
- a process for the production of patterned webs made of thermoplastic material in which particles, e.g. chips, crumbs, sections, pieces or chips are continuously poured onto a carrier tape to form a raw layer, the raw layer is preheated and then pressed and welded qua g -continuously using pressure and heat and then cooled under the action of pressure.
- a pressure of approx. 10 to 60 bar is applied periodically by a (double) vibratory press, alternately the material is transported step by step and quasi continuously.
- the periodic mode of operation should avoid the occurrence of voids in the web material thus produced.
- the disadvantage of this method is that only a low working speed of at most 2 m / min can be achieved.
- a double belt press is known in which two endless, driven metal belts are guided over deflecting rollers in such a way that between the metal belts a band-shaped layer of a material to be treated is first passed over a heated and then a cooled roller. An approximately constant pressure is constantly exerted on the material web. There is no indication in this document of the suitability of this double belt press for the method according to the invention.
- the object of the present invention is to improve a continuous process for the production of sheet goods for the construction industry in accordance with the preamble of claim 1 such that no voids occur even at higher production speeds, that even under unfavorable conditions (large denomination of the chips, high working speeds, etc .) sharply defined boundary lines of the fittings used can be reached.
- the process should be able to be implemented with simple constructive measures.
- thermoplastics are, in particular, vinyl polymers and / or copolymers of vinyl chloride, such as, for example, polyvinyl chloride, containing plasticizers and, if appropriate, other auxiliaries, such as stabilizers, pigments, fillers. Mixtures of particles of different thermoplastic materials or else plastic mixtures can also be used, thermoplastic materials such as acrylates, polyesters, ethylene-vinyl acetate being used.
- the shaped pieces can each have different colors and / or can preferably be patterned in themselves.
- Moldings which are produced by extrusion and moldings which are produced by punching or chipping from raw rolled skins are particularly suitable.
- Balls (0 from 2 to 30 mm), cubes (2 to 30 mm edge length), disks with a thickness of 1 to 5 mm with a rectangular or round shape with lengths of 2 to 60 mm are considered as preferred shapes.
- the various fittings can be used individually, but preferably mixed from two to four types.
- the shaped pieces are poured in a cold or preheated / still warm state with the aid of a pouring device onto a conveyor belt to form a layer with a largely constant layer height.
- the layer height should preferably correspond to 1.5 to 3 times the average dimensions of the fittings. Good results are obtained with bed heights of 8 mm to 50 mm, in particular 10 to 20 mm.
- the molding layer can then advantageously, e.g. using a doctor blade, a shaker, or a spiked roller, be mechanically equalized and pre-compressed.
- the molding layer is then preheated. 80 ° C are sufficient as the preheating temperature with a low bed height and appropriate design of the pre-device, but the molding layer is advantageously pre-sintered at a higher temperature. This takes place at an average temperature of approx. 130 ° C, preferably an average temperature of the continuous web of 150 ° C to 170 ° C should be reached at the end of the sintering section. Uniform heating up to the middle of the molding layer is advantageous. Temperatures above 180 ° C generally do not lead to better work results. * subsequent
- the preheated or pre-sintered web in the pressing device is heated to temperatures in the range from 170 ° C. to 220 ° C., preferably to temperatures from 175 ° C. to 185 ° C.
- the setting of the temperature depends on the dwell time of the web in the pressing device, on the thickness of the web, on the material of the shaped pieces and on the pressing pressure exerted. It has surprisingly been found that a pre-pressure of approximately 3 bar to 9 bar leads to excellent results.
- the pressure is preferably 5 bar to 7 bar.
- Favorable residence times have been found to be 0.3 minutes to 1.5 minutes, preferably 0.5 minutes to 1 minute. Production speeds of more than 8 m / min could be achieved.
- a largely uniform pressure is exerted on the web during pressing and during cooling. It is crucial that the pressure never falls below a minimum value of approx. 1.5 bar to 2 bar (absolute).
- the cooling under the action of pressure should take place at least to such an extent that the temperature of the web is below the softening temperature of the plastic material used.
- it cools down to temperatures from 70 ° C to 90 ° C.
- Temperatures of 65 ° C to 75 ° C have been found to be favorable for optimal web withdrawal from the steel belts of the pressing device, for example.
- the cooled web is homogeneous and void-free, but shows a slightly smeared structure of the surface design. It has surprisingly been found that this mixed color formation and fuzzy limitation of the contours of the moldings used is limited to a layer close to the surface. After removing a layer of approximately 0.1 to 0.5 mm, preferably 0.15 mm to 0.25 mm, the design appears extremely sharply defined and clear. It is advantageous that the structure appears uniform in all directions, so that the direction of production is no longer recognizable on the surface image.
- the layer near the surface can preferably be removed by grinding.
- patterned chips from a rolled raw hide of approx. 2 mm thickness in a circular shape with 5 mm and 10 mm 0 and in a rectangular shape of 5 mm ⁇ 10 mm were used. These shaped pieces 1 are mixed and fed onto a first conveyor 3 by means of a feed device 2.
- This conveyor consists of an approximately 10 cm to 20 cm wide conveyor belt which is rotatably mounted and carries out pivoting movements across the width of the following conveyor 4.
- This second conveyor 4 reserves over a distance of, for example, 0.5 m to 1.5 m in order to achieve a uniform bed on the continuous transport device 7.
- the bed is leveled and pre-compressed by means of a pin roller 5.
- the average bed height in the first test example is approx. 2.5 mm.
- the metal conveyor belt 74 of the continuous transport device 7 was heated by a heater 72 and by the roller 73 to a temperature of about 180 ° C.
- the molded piece layer 6 was heated from above with a heating device 8 by means of radiant heat.
- the molding layer was heated to an average temperature of 160 ° C, the individual moldings being pre-sintered into a coherent porous web.
- a double belt press 9 with a heating drum 94, a cooling drum 95, a metal belt 92, which was driven by a deflection roller 93, and a metal belt 91 indirectly driven by the plastic web 10 by frictional engagement was used as the compression and cooling device.
- the tensile stresses of the approximately 1.5 mm thick metal strips 91, 92 and thus the pressures on the web in the heating zone or in the cooling zone can advantageously be regulated or controlled separately by hydraulic adjustment of the rollers 98.
- the pressure in the area of the heating drum 94 was set to approximately 6 bar (corresponds to 7 bar absolute) via the metal strip 91, the pressure in the area of the cooling drum 95 was 3 bar (corresponds to 4 bar absolute). It is crucial that the pressure in the area of the cooling drum does not fall below a value of approx. 1.5 bar to 2 bar (absolute), otherwise blowholes can be expected. Higher pressures require a correspondingly high level of design effort.
- the transition between the heating drum 94 and the cooling drum 95 takes place under relatively low pressure, but this is not critical insofar as the tension of the belts 91, 92 is still sufficiently high.
- the diameter of the cooling drum 95 and the heating drum 94 was 630 mm in the exemplary embodiment with a width of 600 mm in each case.
- the production speed was 2 m / min.
- an idler belt 12 was introduced onto the continuous transport device 7 via the roller 73.
- This idler belt 12 consists of dense Kevlar fabric and is removed from the supply roll 121 and, after the pressing, is pulled off the web 11 and wound up with the take-up roll 122 in order to be used again later. It is also possible to return the idler belt directly to the deflection roller 73.
- a second idler belt can optionally also be inserted from above between the preheated or presintered web 10 and the metal belt 92 of the double belt press 9.
- the belt 91 is heated to a temperature of 185 ° C. via the heated roller 99.
- the maximum temperature of the web was approximately 180 ° C. in the transition area between the heating drum 94 and the cooling drum 95.
- the cooling drum 95 is water-cooled from the inside. In addition, this area is externally cooled by the cooling device 97 e.g. cooled by cold air.
- the average temperature of the web at the end of the cooling section at point A was approximately 75 ° C. and at the withdrawal of the web from steel belt 91 (point B) approximately 70 ° C.
- the thickness of the web was determined to be approximately 2.4 mm before entry into the double belt press 9, and when the web 11 was pulled off (point B) it was approximately 2.2 mm.
- the surface structure was slightly washed out and out of focus.
- the cooled web 11 is ground on one side to a final dimension of 2 mm by means of a grinding device (not shown). This resulted in a sharply defined, direction-free pattern.
- shaped pieces with an average characteristic dimension of 2 to 5 mm are poured into a shaped piece layer 6 with an average dumping height of 8 mm and treated as in the first test example.
- the thickness of the web after presintering was approx. 7 mm, the production speed was 1 m / min.
- the compressed web 11 had a thickness of 5.5 mm. This was ground down on both sides by 0.25 mm each.
- the finished sheet with a thickness of 5 mm showed a clear structure and a direction-free pattern.
- a third exemplary embodiment is carried out with the same test conditions as in the first example.
- the production speed is 6 m / min, the finished web of 2.2 mm before grinding or 2 mm after grinding results in the same pattern as in the first version example.
- a double belt press with a drum diameter of 2000 mm is used, the same fittings as in the second embodiment and the same dumping height as in this example being used.
- the production speed which in this example is 3 m / min, all other process conditions and results remained identical to those of test 2.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Tyre Moulding (AREA)
- Package Frames And Binding Bands (AREA)
- Conveying And Assembling Of Building Elements In Situ (AREA)
- Percussive Tools And Related Accessories (AREA)
Abstract
Description
Die Erfindung betrifft ein Verfahren zur kontinuierlichen Herstellung von Bahnenware für das Bauwesen gemäß dem Oberbegriff des Anspruchs 1.The invention relates to a method for the continuous production of sheet goods for the building industry according to the preamble of claim 1.
Als Bahnenwaren für das Bauwesen im Sinne dieser Erfindung werden insbesondere Fußboden- und Wandbeläge und insbesondere solche aus thermoplastischen Kunststoffen verstanden. Bevorzugtes Einsatzgebiet ist die Herstellung richtungsfrei gemusterter Fußboden- und Wandbeläge auf der Basis von PVC.Flooring and wall coverings and in particular those made of thermoplastic materials are understood to be web products for the construction industry in the sense of this invention. The preferred area of application is the production of directionally patterned floor and wall coverings based on PVC.
Formstücke im Sinne dieser Erfindung sind insbesondere Schnitzel, Krümel, Abschnitte, Stücke oder Chips aus geeigneten Ausgangsmaterialien.Shaped pieces in the sense of this invention are in particular chips, crumbs, sections, pieces or chips made of suitable starting materials.
Aus der DE-B2-19 28 405 ist ein Verfahren zur Herstellung in sich gemusterter Fußbodenbeläge bekannt, bei dem ein Gemisch von unter sich verschiedenfarbigen Schnitzeln thermoplastischer Kunststoffe zu einer Bahn ausgewalzt und anschließend mit weiteren Bahnen vereinigt und kalandriert wird. Bei diesen Verfahren können nur Bahnen geringer Dicke hergestellt werden, da bei größeren Dicken durch Lufteinschlüsse Lunker suftreten. Weiterhin führen Walz- und Kalandrierverfahrensschritte grundsätzlich zu einer gerichteten Struktur der entstehenden Muster.From DE-B2-19 28 405 a process for the production of patterned floor coverings is known, in which a mixture of differently colored chips of thermoplastic materials is rolled out into a web and then combined with other webs and calendered. With this method, only sheets of small thickness can be produced, since voids occur in the case of larger thicknesses due to air pockets. Furthermore, rolling and calendering process steps generally lead to a directional structure of the resulting patterns.
Aus der DE-PS 637 144 ist ein Verfahren zur Herstellung von Fußbodenbelägen bekannt, bei dem eine Kautschukmischung o.dgl. zwischen zwei umlaufenden Bändern um eine Vulkanisationstrommel und Kühltrommeln geführt wird , wobei drei Trommeln in S-Form angeordnet sind, so daß der Druck, der von den Bändern auf den Belag ausgeübt wird, von Beginn der Heizperiode bis zum Ende der Kühlphase annähernd konstant bleibt. Diese Schrift gibt jedoch keine Anregung für ein Verfahren oder eine Vorrichtung zur Herstellung von Bahnenware aus thermoplastischen Kunststoffen und hat dementsprechend keinen Einfluß auf die technische Entwicklung auf diesem Gebiet ausgeübt.From DE-PS 637 144 a method for the production of floor coverings is known in which a rubber mixture or the like. is guided between two circulating belts around a vulcanization drum and cooling drums, three drums being arranged in an S-shape, so that the pressure exerted by the belts on the covering remains approximately constant from the beginning of the heating period to the end of the cooling phase. However, this document gives no suggestion for a method or a device for the production of sheet goods from thermoplastic materials and accordingly has no influence on the technical development in this area.
Aus der DE-C2-3D 31 839 ist ein Verfahren zur Herstellung von gemusterten Bahnen aus thermoplastischem Kunststoff bekannt, bei dem Teilchen, z.B. Schnitzel, Krümel, Abschnitte, Stücke oder Chips kontinuierlich auf ein Trägerband zu einer Rohschicht aufgeschüttet werden, die Rohschicht vorgewärmt und anschließend unter Anwendung von Druck und Wärme quagi-kontinuierlich verpreßt und verschweißt und anschließend unter Druckeinwirkung abgekühlt wird. Dabei wird ein Druck von ca. 10 bis 60 bar periodisch von einer (Doppel-) Schwingpresse aufgebracht, alternierend dazu findet der Materialtransport schrittweise und quasi kontinuierlich statt. Die periodische Arbeitsweise sollte das Auftreten von Lunkern in der so hergestellten Bahnenware vermeiden. Nachteil dieses Verfahrens ist es, daß nur eine geringe Arbeitsgeschwindigkeit von maximal 2 m/min erreicht werden kann. Bei großen Belagsdicken und bei Verwendung größerer Formstücke traten trotz Verwendung des periodischen Pressens Lunker im Inneren der Bahnen auf. Bedingt durch den notwendigen hohen Druck und durch die periodische Druckeinwirkung waren teure und aufwendige Konstruktionen notwendig. Weiterhin bedingte dieses Arbeitsverfahren hohe Temperaturen, um lunkerfreie Arbeitsergebnisse zu erzielen. Insbesondere bei dicken Schichten war ein Verwaschen der Konturen der eingesetzten Teilchen in der fertigen Bahn zu beobachten.From DE-C2-3D 31 839 a process for the production of patterned webs made of thermoplastic material is known, in which particles, e.g. chips, crumbs, sections, pieces or chips are continuously poured onto a carrier tape to form a raw layer, the raw layer is preheated and then pressed and welded qua g -continuously using pressure and heat and then cooled under the action of pressure. A pressure of approx. 10 to 60 bar is applied periodically by a (double) vibratory press, alternately the material is transported step by step and quasi continuously. The periodic mode of operation should avoid the occurrence of voids in the web material thus produced. The disadvantage of this method is that only a low working speed of at most 2 m / min can be achieved. With large covering thicknesses and when using larger fittings, voids occurred in the interior of the webs despite the use of periodic pressing. Due to the necessary high pressure and the periodic pressure, expensive and complex constructions were necessary. Furthermore, this working process required high temperatures in order to achieve void-free work results. In the case of thick layers in particular, the contours of the particles used were washed out in the finished web.
Aus der DE-A1-26 36 170 ist eine Doppelbandpresse bekannt, bei der zwei endlose, angetriebene Metallbänder so über Umlenkwalze geführt werden, daß zwischen den Metallbändern eine bandförmige Schicht eines zu behandelnden Materials zunächst über eine geheizte und anschließend eine gekühlte Walze geführt wird. Dabei wird auf die Materialbahn ständig ein annähernd konstanter Druc ausgeübt. Ein Hinweis für die Eignung dieser Doppelbandpresse für das erfindungsgemäße Verfahren findet sich in dieser Schrif nicht.From DE-A1-26 36 170 a double belt press is known in which two endless, driven metal belts are guided over deflecting rollers in such a way that between the metal belts a band-shaped layer of a material to be treated is first passed over a heated and then a cooled roller. An approximately constant pressure is constantly exerted on the material web. There is no indication in this document of the suitability of this double belt press for the method according to the invention.
Aufgabe der vorliegenden Erfindung ist es, ein kontinuierliches Verfahren zur Herstellung von Bahnenware für das Bauwesen gemäß dem Oberbegriff des Anspruchs 1 so zu verbessern, daß auch bei höheren Fertigungsgeschwindigkeiten keine Lunker auftreten, daß auch unter ungünstigen Voraussetzungen (große Stückelung der Chips, hohe Arbeitsgeschwindigkeiten etc.) scharf abgegrenzte Begrenzungslinien der eingesetzten Formstücke erreichbar sind. Das Verfahren soll dabei mit einfachen konstruktiven Maßnahmen zu verwirklichen sein.The object of the present invention is to improve a continuous process for the production of sheet goods for the construction industry in accordance with the preamble of claim 1 such that no voids occur even at higher production speeds, that even under unfavorable conditions (large denomination of the chips, high working speeds, etc .) sharply defined boundary lines of the fittings used can be reached. The process should be able to be implemented with simple constructive measures.
Gemäß der Erfindung wird diese Aufgabe durch die kennzeichnende Merkmale des Anspruchs 1 gelöst.According to the invention, this object is achieved by the characterizing features of claim 1.
Als Formstücke können dabei Schnitzel, Krümel, Abschnitte, Stücke oder Chips, insbesondere aus thermoplastischem Kunststoff eingesetzt werden. Geeignete thermoplastische Kunststoffe sind insbesondere Vinylpolymerisate und/oder Copolymere des Vinylchlorids, wie beispielsweise Polyvinylchlorid, enthaltend Weichmacher sowie ggf. weitere Hilfsstoffe, wie Stabilisatoren, Pigmente, Füllstoffe. Es können auch Mischungen von Teilchen aus unterschiedlichen thermoplastischen Kunststoffen oder aber auch Kunststoffmischungen eingesetzt werden, wobei thermoplastische Kunststoffe wie Acrylate, Polyester, Ethylen-Vinylacetat zur Anwendung kommen.Chips, crumbs, sections, pieces or chips, in particular made of thermoplastic, can be used as shaped pieces. Suitable thermoplastics are, in particular, vinyl polymers and / or copolymers of vinyl chloride, such as, for example, polyvinyl chloride, containing plasticizers and, if appropriate, other auxiliaries, such as stabilizers, pigments, fillers. Mixtures of particles of different thermoplastic materials or else plastic mixtures can also be used, thermoplastic materials such as acrylates, polyesters, ethylene-vinyl acetate being used.
Die Formstücke können jeweils unterschiedliche Farben aufweisen und/oder vorzugsweise in sich gemustert sein.The shaped pieces can each have different colors and / or can preferably be patterned in themselves.
Besonders eignen sich Formstücke, die durch Strangpressen hergestellt werden sowie Formstücke, die durch Ausstanzen oder Abschlagen aus Roh-Walzfellen hergestellt werden. Als bevorzugte Formen kommen dabei Kugeln (0 von 2 bis 30 mm), Würfel (2 bis 30 mm Kantenlänge), Scheiben einer Dicke von 1 bis 5 mm mit rechteckiger oder runder Form mit Längen von 2 bis 60 mm in Betracht.Moldings which are produced by extrusion and moldings which are produced by punching or chipping from raw rolled skins are particularly suitable. Balls (0 from 2 to 30 mm), cubes (2 to 30 mm edge length), disks with a thickness of 1 to 5 mm with a rectangular or round shape with lengths of 2 to 60 mm are considered as preferred shapes.
Die diversen Formstücke können dabei einzeln, bevorzugt aber gemischt aus zwei bis vier Sorten eingesetzt werden.The various fittings can be used individually, but preferably mixed from two to four types.
Die Formstücke werden im kalten oder vorgewärmten/noch warmen Zustand mit Hilfe einer Schüttvorrichtung auf ein Transportband zu einer Schicht mit weitgehend konstanter Schichthöhe geschüttet. Die Schichthöhe sollte dabei vorzugsweise dem 1,5 bis 3-fachen der durchschnittlichen Abmessungen der Formstücke entsprechen. Gute Ergebnisse werden mit Schütthöhen von 8 mm bis 50 mm, insbesondere mit 10 bis 20 mm erhalten.The shaped pieces are poured in a cold or preheated / still warm state with the aid of a pouring device onto a conveyor belt to form a layer with a largely constant layer height. The layer height should preferably correspond to 1.5 to 3 times the average dimensions of the fittings. Good results are obtained with bed heights of 8 mm to 50 mm, in particular 10 to 20 mm.
Die Formstückschicht kann anschließend vorteilhaft,z.B. mittels eines Rakels, einer Schüttelvorrichtung, oder einer Stachelwalze, mechanisch egalisiert und vorverdichtet werden.The molding layer can then advantageously, e.g. using a doctor blade, a shaker, or a spiked roller, be mechanically equalized and pre-compressed.
Die Formstückschicht wird anschließend vorgewärmt. Als Vorwärmtemperatur reichen bei geringer Schütthöhe und entsprechender Auslegung der PreBeinrichtung 80°C aus, vorteilhaft wird die Formstückschicht jedoch bei höherer Temperatur vorgesintert. Dieses erfolgt bei einer mittleren Temperatur ab ca. 130°C, vorzugsweise sollte am Ende der Sinterstrecke eine mittlere Temperatur der zusammenhängenden Bahn von 150°C bis 170°C erreicht werden. Eine gleichmäßige Erwärmung bis in die Mitte der Formstückschicht ist vorteilhaft. Temperaturen oberhalb 180°C führen im allgemeinen nicht zu besseren Arbeitsergebnissen.
* sich anschließendenThe molding layer is then preheated. 80 ° C are sufficient as the preheating temperature with a low bed height and appropriate design of the pre-device, but the molding layer is advantageously pre-sintered at a higher temperature. This takes place at an average temperature of approx. 130 ° C, preferably an average temperature of the continuous web of 150 ° C to 170 ° C should be reached at the end of the sintering section. Uniform heating up to the middle of the molding layer is advantageous. Temperatures above 180 ° C generally do not lead to better work results.
* subsequent
Im Anschluß an das Vorwärmen bzw. Vorsintern der Formstückschicht wird diese kontinuierlich unter weitgehend konstanter und gleichmäßiger Druckeinwirkung im thermoplastischen Zustand zu einer homogenen Bahn verdichtet und anschließend unter Beibehaltung der Druckeinwirkung abgekühlt. Es hat sich überraschen herausgestellt, daß ein gleichmäßiger Preßvorgang dem langsam pulsierenden Druckeinfluß, z.B. gemäß dem Verfahren nach der DE-C2-30 31 839, überlegen ist. Unerwartet zeigen sich bei dem erfindungsgemäßen Verfahren auch beim Einsatz großer Formstücke und bei hohen Arbeitsgeschwindigkeiten von mehr als 8 m/min keine Lunker.Following the preheating or pre-sintering of the molding layer, it is continuously compacted to a homogeneous web under largely constant and uniform pressure in the thermoplastic state and then cooled while maintaining the pressure. It has surprisingly been found that a uniform pressing process can withstand the slowly pulsating pressure influence, e.g. according to the method according to DE-C2-30 31 839, is superior. Unexpectedly, there are no voids in the method according to the invention, even when using large shaped pieces and at high working speeds of more than 8 m / min.
Während des Verpressens wird die vorgewärmte bzw. vorgesinterte Bahn in der Preßeinrichtung, vorzugsweise beidseitig, erwärmt auf Temperaturen im Bereich von 170°C bis 220°C, vorzugsweise auf Temperaturen von 175°C bis 185°C. Die Einstellung der Temperatur ist dabei abhängig von der Verweilzeit der Bahn in der Preßeinrichtung, von der Dicke der Bahn, vom Material der Formstücke und vom ausgeübten Preßdruck. Überraschend hat sich herausgestellt, daß ein PreBdruck von ca. 3 bar bis 9 bar zu hervorragenden Ergebnissen führt. Vorzugsweise liegt der Druck bei 5 bar bis 7 bar. Als günstige Verweilzeiten haben sich 0,3 min bis 1,5 min, bevorzugt 0,5 min bis 1 min herausgestellt. Dabei konnten Produktionsgeschwindigkeiten von mehr als 8 m/min erzielt werden.During the pressing, the preheated or pre-sintered web in the pressing device, preferably on both sides, is heated to temperatures in the range from 170 ° C. to 220 ° C., preferably to temperatures from 175 ° C. to 185 ° C. The setting of the temperature depends on the dwell time of the web in the pressing device, on the thickness of the web, on the material of the shaped pieces and on the pressing pressure exerted. It has surprisingly been found that a pre-pressure of approximately 3 bar to 9 bar leads to excellent results. The pressure is preferably 5 bar to 7 bar. Favorable residence times have been found to be 0.3 minutes to 1.5 minutes, preferably 0.5 minutes to 1 minute. Production speeds of more than 8 m / min could be achieved.
Erfindungsgemäß wird auf die Bahn während des Pressens und während der Abkühlung ein jeweils weitgehend gleichmäßiger Druck ausgeübt. Entscheidend ist dabei, daß der Druck zu keinem Zeitpunkt unter einen Mindestwert von ca. 1,5 bar bis 2 bar (absolut) fällt.According to the invention, a largely uniform pressure is exerted on the web during pressing and during cooling. It is crucial that the pressure never falls below a minimum value of approx. 1.5 bar to 2 bar (absolute).
Die Abkühlung unter Druckeinwirkung sollte zumindest soweit erfolgen, daß die Temperatur der Bahn unter die Erweichungstemperatur des eingesetzten Kunststoffmaterials liegt. Vorteilhaft erfolgt die Abkühlung bis auf Temperaturen von 70°C bis 90°C. Für einen optimalen Abzug der Bahn von den z.B. Stahlbändern der Preßeinrichtung haben sich Temperaturen von 65°C bis 75°C als günstig herausgestellt.The cooling under the action of pressure should take place at least to such an extent that the temperature of the web is below the softening temperature of the plastic material used. Advantageous it cools down to temperatures from 70 ° C to 90 ° C. Temperatures of 65 ° C to 75 ° C have been found to be favorable for optimal web withdrawal from the steel belts of the pressing device, for example.
Die abgekühlte Bahn ist homogen und lunkerfrei, zeigt jedoch eine leicht verschmierte Struktur des Oberflächen-Designs. Es hat sich überraschend herausgestellt, daß diese Mischfarbenbildung und unscharfe Begrenzung der Konturen der eingesetzten Formstücke auf eine oberflächennahe Schicht begrenzt ist. Nach Entfernen einer Schicht von ca. 0,1 bis 0,5 mm, vorzugsweise 0,15mm bis 0,25 mm, erscheint das Design äußerst scharf abgegrenzt und klar. Vorteilhaft ist dabei, daß die Struktur in allen Richtungen gleichmäßig erscheint, so daß die Produktionsrichtung auf dem Oberflächenbild nicht mehr erkennbar ist. Die Entfernung der oberflächennahen Schicht kann vorzugsweise mittels Schleifen erfolgen.The cooled web is homogeneous and void-free, but shows a slightly smeared structure of the surface design. It has surprisingly been found that this mixed color formation and fuzzy limitation of the contours of the moldings used is limited to a layer close to the surface. After removing a layer of approximately 0.1 to 0.5 mm, preferably 0.15 mm to 0.25 mm, the design appears extremely sharply defined and clear. It is advantageous that the structure appears uniform in all directions, so that the direction of production is no longer recognizable on the surface image. The layer near the surface can preferably be removed by grinding.
Nach dem Entfernen der oberflächennahen Schicht können noch weitere Arbeitsschritte eingesetzt werden wie Spalten, Tempern, Polieren etc. Als Vorteilhaft hat sich herausgestellt, daß nach dem erfindungsgemäßen Verfahren hergestellte Bahnenwaren nur eine äußerst geringe Schrumpfneigung zeigen, so daß ein Tempern ggf. entfallen kann.After the layer close to the surface has been removed, further work steps can be used, such as splitting, tempering, polishing, etc. It has been found to be advantageous that web products produced by the process according to the invention show only an extremely low tendency to shrink, so that tempering can possibly be omitted.
Eine vorteilhafte Vorrichtung zur Durchführung des erfindungsgemäßen Verfahrens ist in den Ansprüchen 12 bis 14 angegeben.An advantageous device for performing the method according to the invention is specified in claims 12 to 14.
Ein Ausführungsbeispiel der Erfindung ist in der Zeichnung dargestellt und wird im folgenden näher beschrieben.An embodiment of the invention is shown in the drawing and will be described in more detail below.
Es zeigt dabei die
- Figur eine Einrichtung zur Durchführung des erfindungsgemäßen Verfahrens.
- Figure a device for performing the method according to the invention.
Für ein erstes Versuchsbeispiel wurden in sich gemusterte Chips aus einem gewalzten Rohfell von ca. 2 mm Dicke in Kreisform mit 5 mm und 10 mm 0 sowie in Rechteckform von 5 mm x 10 mm verwendet . Diese Formstücke 1 werden gemischt und mittels einer Aufgabevorrichtung 2 auf eine erste Fördereinrichtung 3 aufgegeben. Diese Fördereinrichtung besteht aus einem ca. 10 cm bis 20 cm breiten Förderband, das drehbar gelagert ist und Schwenkbewegungen über die Breite der folgenden Fördereinrichtung 4 ausführt. Diese zweite Fördereinrichtung 4 reserviert über eine Strecke von beispielsweise 0,5 m bis 1,5 m, um eine gleichmäßige Schüttung auf der kontinuierlichen Transportvorrichtung 7 zu erreichen. Mittels einer Stiftwalze 5 wird die Schüttung egalisiert und vorverdichtet. Die mittlere Schütthöhe beträgt im ersten Versuchsbeispiel ca. 2,5 mm. Das Metall-Förder band 74 der kontinuierlichen Transportvorrichtung 7 wurde durch eine Heizeinrichtung 72 und durch die Walze 73 beheizt auf eine Temperatur von ca. 180°C. Gleichzeitig wurde die Formstückschich 6 mit einer Heizeinrichtung 8 mittels Strahlungswärme von oben erwärmt. Die Formstückschicht wurde dabei auf eine mittlere Temperatur von 160°C aufgeheizt, wobei die einzelnen Formstücke zu einer zusammenhängenden porösen Bahn vorgesintert wurden. Als Verdichtungs- und Kühlvorrichtung wurde eine Doppelbandpresse 9 verwendet mit einer Heiztrommel 94, einer Kühltrommel 95, einem Metallband 92, das von einer Umlenkwalze 93 angetrieben wurde, und einem durch die Kunststoffbahn 10 durch Reibschluß indirekt angetriebenen Metallband 91.For a first test example, patterned chips from a rolled raw hide of approx. 2 mm thickness in a circular shape with 5 mm and 10 mm 0 and in a rectangular shape of 5 mm × 10 mm were used. These shaped pieces 1 are mixed and fed onto a first conveyor 3 by means of a feed device 2. This conveyor consists of an approximately 10 cm to 20 cm wide conveyor belt which is rotatably mounted and carries out pivoting movements across the width of the following conveyor 4. This second conveyor 4 reserves over a distance of, for example, 0.5 m to 1.5 m in order to achieve a uniform bed on the
Die Zugspannungen der ca. 1,5 mm starken Metallbänder 91, 92 und damit die Drücke auf die Bahn in der Heizzone bzw. in der Kühlzone können in vorteilhafter Weise getrennt durch hydraulisches Verstellen der Walzen 98 geregelt oder gesteuert werden.The tensile stresses of the approximately 1.5 mm thick metal strips 91, 92 and thus the pressures on the web in the heating zone or in the cooling zone can advantageously be regulated or controlled separately by hydraulic adjustment of the
Im Ausführungsbeispiel wurde der Druck im Bereich der Heiztrommel 94 über das Metallband 91 auf ca. 6 bar (entspricht 7 bar absolut) eingestellt, der Druck im Bereich der Kühltromme 95 betrug 3 bar (entspricht 4 bar absolut). Entscheidend ist, daß der Druck im Bereich der Kühltrommel nicht unter einen Wert von ca. 1,5 bar bis 2 bar (absolut) fällt, da sonst mit Lunkern zu rechnen ist. Höhere Drücke erfordern einen entsprechend hohen konstruktiven Aufwand.In the exemplary embodiment, the pressure in the area of the heating drum 94 was set to approximately 6 bar (corresponds to 7 bar absolute) via the
Der Übergang zwischen der Heiztrommel 94 und der Kühltrommel 95 erfolgt zwar unter relativ geringem Druck, dieses ist jedoch, soweit die Zugspannung der Bänder 91, 92 noch genügend hoch ist, unkritisch. Die Durchmesser der Kühltrommel 95 und der Heiztrommel 94 betrug im Ausführungsbeispiel 630 mm bei einer Breite von jeweils 600 mm. Im ersten Versuchsbeispiel ergab sich eine Produktionsgeschwindigkeit von 2 m/min.The transition between the heating drum 94 and the cooling drum 95 takes place under relatively low pressure, but this is not critical insofar as the tension of the
Beim ersten Versuchsbeispiel wurde ein Mitläuferband 12 über die Rolle 73 auf die kontinuierliche Transportvorrichtung 7 eingeführt. Dieses Mitläuferband 12 besteht aus dichtem Kevlar-Gewebe und wird von der Vorratsrolle 121 entnommen und nach dem Pressen von der Bahn 11 abgezogen und mit der Aufwickelroll 122 aufgewickelt, um später erneut eingesetzt zu werden. Es ist auch möglich, das Mitläuferband direkt zur Umlenkrolle 73 zurückzuführen. Weiterhin kann ggf. auch ein zweites Mitläuferband von oben zwischen die vorgewärmte bzw. vorgesinterte Bahn 10 und das Metallband 92 der Doppelbandpresse 9 eingeführt werden.In the first test example, an idler belt 12 was introduced onto the
Die Heizung im Bereich der Heiztrommel 94 erfolgt über die ölbeheizte Heiztrommel 94 mit einer Ö1- Vorlauftemperatur von 1950C, über das vorgeheizte Band 91 sowie über die Heizeinrichtung 96 über Wärmestrahlung. Das Band 91 wird dabei über die beheizte Walze 99 auf eine Temperatur von 185°C temperiert. Die maximale Temperatur der Bahn ergab sich mit ca. 180°C im Übergangsbereich zwischen der Heiztrommel 94 und der Kühltrommel 95.The heating in the heating drum 94 via the oil-fired heating drum 94 having a Ö1- flow temperature of 195 0 C, over the
Die Kühltrommel 95 ist von innen wassergekühlt. Zusätzlich wird dieser Bereich von außen durch die Kühleinrichtung 97 z.B. mittels Kaltluft gekühlt. Die mittlere Temperatur der Bahn betrug am Ende der Kühlstrecke an der Stelle A ca. 75°C, am Abzug der Bahn vom Stahlband 91 (Stelle B) ca. 70°C.The cooling drum 95 is water-cooled from the inside. In addition, this area is externally cooled by the cooling device 97 e.g. cooled by cold air. The average temperature of the web at the end of the cooling section at point A was approximately 75 ° C. and at the withdrawal of the web from steel belt 91 (point B) approximately 70 ° C.
Die Dicke der Bahn wurde vor dem Eintritt in die Doppelbandpresse 9 mit ca. 2,4 mm bestimmt, beim Abziehen der Bahn 11 (Stelle B) betrug diese ca. 2,2 mm. Die Oberflächenstruktur war leicht verwaschen und unscharf.The thickness of the web was determined to be approximately 2.4 mm before entry into the double belt press 9, and when the web 11 was pulled off (point B) it was approximately 2.2 mm. The surface structure was slightly washed out and out of focus.
Mittels einer (nicht dargestellten) Schleifeinrichtung wird die abgekühlte Bahn 11 einseitig auf ein Endmaß von 2 mm abgeschliffen. Dabei ergab sich ein scharf abgegrenztes, richtungsfreies Muster.The cooled web 11 is ground on one side to a final dimension of 2 mm by means of a grinding device (not shown). This resulted in a sharply defined, direction-free pattern.
In einem zweiten Ausführungsbeispiel werden Formstücke mit einer mittleren charakteristischen Abmessung von 2 bis 5 mm zu einer Formstückschicht 6 mit einer mittleren Schütthöhe von 8 mm aufgeschüttet und wie im ersten Versuchsbeispiel behandelt. Die Dicke der Bahn betrug nach dem Vorsintern ca. 7 mm, die Produktionsgeschwindigkeit 1 m/min.In a second exemplary embodiment, shaped pieces with an average characteristic dimension of 2 to 5 mm are poured into a shaped piece layer 6 with an average dumping height of 8 mm and treated as in the first test example. The thickness of the web after presintering was approx. 7 mm, the production speed was 1 m / min.
Die verdichtete Bahn 11 wies eine Dicke von 5,5 mm auf. Diese wurde beidseitig um je 0,25 mm abgeschliffen. Die fertige Bahn mit 5 mm Dicke zeigte eine klare Strukturierung und ein richtungs freies Muster. Mit einer weiteren Vorrichtung mit Trommeldurchmessern von 2000 mm wird ein drittes Ausführungsbeispiel mit sonst gleichen Versuchsbedingungen wie im ersten Beispiel durchgeführt. Die Produktionsgeschwindigkeit beträgt dabei 6 m/min, die fertige Bahn von 2,2 mm vor dem Schleifen bzw. 2 mm nach dem Schleifen ergibt das gleiche Muster wie im ersten Ausführungsbeispiel.The compressed web 11 had a thickness of 5.5 mm. This was ground down on both sides by 0.25 mm each. The finished sheet with a thickness of 5 mm showed a clear structure and a direction-free pattern. With a further device with drum diameters of 2000 mm, a third exemplary embodiment is carried out with the same test conditions as in the first example. The production speed is 6 m / min, the finished web of 2.2 mm before grinding or 2 mm after grinding results in the same pattern as in the first version example.
In einem vierten Ausführungsbeispiel wird eine Doppelbandpresse mit Trommeldurchmessern von 2000 mm verwendet, wobei die gleiche Formstücke wie im zweiten Ausführungsbeispiel und die gleiche Schütthöhe wie in diesem Beispiel eingesetzt werden. Mit Ausnahm der Produktionsgeschwindigkeit, die in diesem Beispiel 3 m/min beträgt,blieben alle weiteren Verfahrensbedingungen und Ergebnisse identisch mit denen des Versuchs 2.In a fourth embodiment, a double belt press with a drum diameter of 2000 mm is used, the same fittings as in the second embodiment and the same dumping height as in this example being used. With the exception of the production speed, which in this example is 3 m / min, all other process conditions and results remained identical to those of test 2.
Eine Verwendung entsprechend größerer Trommeldurchmesser führt zu entsprechend erhöhten Produktionsgeschwindigkeiten.Using correspondingly larger drum diameters leads to correspondingly increased production speeds.
Claims (14)
dadurch gekennzeichnet , daß
characterized in that
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT86117176T ATE51578T1 (en) | 1985-12-27 | 1986-12-10 | PROCESS FOR THE CONTINUOUS PRODUCTION OF ROLL GOODS FOR THE BUILDING INDUSTRY. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3546184 | 1985-12-27 | ||
DE19853546184 DE3546184A1 (en) | 1985-12-27 | 1985-12-27 | METHOD FOR THE CONTINUOUS PRODUCTION OF RAILWAYS FOR THE CONSTRUCTION |
Publications (2)
Publication Number | Publication Date |
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EP0226946A1 true EP0226946A1 (en) | 1987-07-01 |
EP0226946B1 EP0226946B1 (en) | 1990-04-04 |
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EP86117176A Expired - Lifetime EP0226946B1 (en) | 1985-12-27 | 1986-12-10 | Method for continuously making webs for the building industry |
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EP (1) | EP0226946B1 (en) |
JP (1) | JPH0788021B2 (en) |
AT (1) | ATE51578T1 (en) |
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DE (2) | DE3546184A1 (en) |
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EP0512197A1 (en) * | 1991-05-04 | 1992-11-11 | Firma Carl Freudenberg | Process for the continuous manufacture of a randomly patterned, elastomeric floor covering |
WO1993024296A1 (en) * | 1992-05-26 | 1993-12-09 | Tesch Guenter | Floor covering based on thermoplastic material |
WO1994001265A1 (en) * | 1992-07-07 | 1994-01-20 | James Halstead Limited | Apparatus and method for compressing a continuous web |
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WO1998017455A1 (en) * | 1996-10-17 | 1998-04-30 | Forbo International Sa | Method and device for manufacturing plastic-based materials in web form, such as floor and wall covering materials, and also such material manufactured by the method |
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EP0917944A2 (en) * | 1997-11-21 | 1999-05-26 | Schilling-Knobel GmbH | Method for manufacturing of thermally fixed sheets from thermoplastic polymer particles |
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US5244942A (en) * | 1987-12-19 | 1993-09-14 | Huels Troisdorf Ag | Homogenous, particularly multicolor-structured synthetic resin sheet or panel, as well as process for its production |
EP0321760B2 (en) * | 1987-12-19 | 1999-04-14 | Ht Troplast Ag | Homogeneous, multicoloured structured plastic film or panel, and process for its production |
DE3743297A1 (en) * | 1987-12-19 | 1989-06-29 | Huels Troisdorf | Process for the production of homogeneous plastic webs or sheets which have been provided with a multicolour structure |
DE4222241C2 (en) * | 1992-07-07 | 1994-08-25 | Troester Maschf Paul | Sealing plate calender |
DE4240025C2 (en) * | 1992-11-28 | 1994-09-08 | Berstorff Gmbh Masch Hermann | Method and device for producing a molding from thermoplastic material |
DE19527877C2 (en) * | 1995-07-29 | 1998-06-04 | Guenter Tesch | Process for the production of a flat structure, in particular a covering |
EP1679171A1 (en) * | 2005-01-10 | 2006-07-12 | Tarkett SAS | Homogenous surface covering |
DE102007063261B4 (en) * | 2007-12-17 | 2023-03-02 | Ipco Germany Gmbh | Plant for the production of sheet or plate-shaped coverings |
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- 1986-12-10 AT AT86117176T patent/ATE51578T1/en not_active IP Right Cessation
- 1986-12-10 DE DE8686117176T patent/DE3670042D1/en not_active Expired - Lifetime
- 1986-12-10 EP EP86117176A patent/EP0226946B1/en not_active Expired - Lifetime
- 1986-12-23 JP JP61305620A patent/JPH0788021B2/en not_active Expired - Fee Related
- 1986-12-24 CA CA526293A patent/CA1303318C/en not_active Expired - Lifetime
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DE1279321B (en) * | 1963-02-11 | 1968-10-03 | Continental Gummi Werke Ag | Process for the production of multi-colored patterned coverings |
DE2423661A1 (en) * | 1974-05-15 | 1975-11-27 | Siegfried Herbert Moeckel | Plastic patterned flooring finish - produced by applying contrasting top coat on to undercoat before curing |
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EP0479053B1 (en) * | 1990-10-03 | 1995-12-27 | Forbo-Giubiasco Sa | Method of manufacturing high density surface material |
EP0512197A1 (en) * | 1991-05-04 | 1992-11-11 | Firma Carl Freudenberg | Process for the continuous manufacture of a randomly patterned, elastomeric floor covering |
US5604025A (en) * | 1992-05-26 | 1997-02-18 | Tesch; Gunter | Floor covering based upon thermoplastic synthetic material |
WO1993024296A1 (en) * | 1992-05-26 | 1993-12-09 | Tesch Guenter | Floor covering based on thermoplastic material |
WO1994001265A1 (en) * | 1992-07-07 | 1994-01-20 | James Halstead Limited | Apparatus and method for compressing a continuous web |
GB2283199A (en) * | 1992-07-07 | 1995-05-03 | Halstead James Ltd | Apparatus and method for compressing a continuous web |
GB2283199B (en) * | 1992-07-07 | 1995-10-25 | Halstead James Ltd | Apparatus and method for compressing a continuous web |
FR2727048A1 (en) * | 1994-11-17 | 1996-05-24 | Taraflex | SHEET MATERIAL OBTAINED FROM PELLETS OF THERMOPLASTIC MATERIALS |
EP0713354A3 (en) * | 1994-11-17 | 1997-01-22 | Taraflex | Electrically conductive sheet obtained from thermoplastic pellets |
DE19527553C1 (en) * | 1995-07-27 | 1997-02-06 | Dlw Ag | Process for the production of homogeneous plastic flooring or sheets with non-directional color pattern |
WO1998017455A1 (en) * | 1996-10-17 | 1998-04-30 | Forbo International Sa | Method and device for manufacturing plastic-based materials in web form, such as floor and wall covering materials, and also such material manufactured by the method |
US6251330B1 (en) | 1996-10-17 | 2001-06-26 | Forbo International Sa | Method and device for manufacturing plastic-based materials in web form, such as floor and wall covering materials, and also such material manufactured by the method |
EP0899372A2 (en) * | 1997-08-27 | 1999-03-03 | Tarkett Ireland Limited | A method for manufacturing a floor covering |
EP0899372A3 (en) * | 1997-08-27 | 2001-10-31 | Tarkett Ireland Limited | A method for manufacturing a floor covering |
EP0917944A2 (en) * | 1997-11-21 | 1999-05-26 | Schilling-Knobel GmbH | Method for manufacturing of thermally fixed sheets from thermoplastic polymer particles |
WO1999026773A1 (en) * | 1997-11-21 | 1999-06-03 | Schilling-Knobel Gmbh | Method for producing thermoset webs from particles of thermoplastic polymer materials |
EP0917944A3 (en) * | 1997-11-21 | 2000-08-16 | Schilling-Knobel GmbH | Method for manufacturing of thermally fixed sheets from thermoplastic polymer particles |
Also Published As
Publication number | Publication date |
---|---|
EP0226946B1 (en) | 1990-04-04 |
ATE51578T1 (en) | 1990-04-15 |
JPS62160215A (en) | 1987-07-16 |
DE3546184A1 (en) | 1987-07-02 |
ES2013992B3 (en) | 1990-06-16 |
CA1303318C (en) | 1992-06-16 |
DE3670042D1 (en) | 1990-05-10 |
DE3546184C2 (en) | 1989-10-19 |
JPH0788021B2 (en) | 1995-09-27 |
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