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EP0219801B1 - Fire-screening glazing unit - Google Patents

Fire-screening glazing unit Download PDF

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Publication number
EP0219801B1
EP0219801B1 EP86114193A EP86114193A EP0219801B1 EP 0219801 B1 EP0219801 B1 EP 0219801B1 EP 86114193 A EP86114193 A EP 86114193A EP 86114193 A EP86114193 A EP 86114193A EP 0219801 B1 EP0219801 B1 EP 0219801B1
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EP
European Patent Office
Prior art keywords
glass
glass pane
pane
fire
glazing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP86114193A
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German (de)
French (fr)
Other versions
EP0219801A2 (en
EP0219801A3 (en
Inventor
Günter Dr. Ortmanns
Jakob Nieven
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vegla Vereinigte Glaswerke GmbH
Original Assignee
Vegla Vereinigte Glaswerke GmbH
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Application filed by Vegla Vereinigte Glaswerke GmbH filed Critical Vegla Vereinigte Glaswerke GmbH
Priority to AT86114193T priority Critical patent/ATE56664T1/en
Publication of EP0219801A2 publication Critical patent/EP0219801A2/en
Publication of EP0219801A3 publication Critical patent/EP0219801A3/en
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Classifications

    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B5/00—Doors, windows, or like closures for special purposes; Border constructions therefor
    • E06B5/10—Doors, windows, or like closures for special purposes; Border constructions therefor for protection against air-raid or other war-like action; for other protective purposes
    • E06B5/16—Fireproof doors or similar closures; Adaptations of fixed constructions therefor
    • E06B5/165—Fireproof windows
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B32B17/10045—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets with at least one intermediate layer consisting of a glass sheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal

Definitions

  • the invention relates to the use of a laminated glass pane as fire-resistant glazing.
  • At least one of the glass panes consists of a heat-resistant special glass, namely a borosilicate or aluminosilicate glass with a low coefficient of thermal expansion or with a low product of coefficient of thermal expansion a and modulus of elasticity E. , and this special glass pane has a compressive stress in the edge area.
  • a heat-resistant special glass namely a borosilicate or aluminosilicate glass with a low coefficient of thermal expansion or with a low product of coefficient of thermal expansion a and modulus of elasticity E.
  • this special glass pane has a compressive stress in the edge area.
  • Such special glasses are expensive, and the production of optically perfect, that is, distortion-free, glass panes from these special glasses is associated with considerable difficulties because of the high viscosity of such glass melts.
  • the individual glass panes of this known glazing are arranged with an air gap of 10 to 100 mm from each other.
  • two or more silicate glass panes of conventional composition are also spaced apart from one another, the glass pane arranged on the side facing the heat being an armored glass pane and the glass pane arranged on the side facing away from the heat being a non-reinforced but toughened glass pane ( DE-PS 26 45 259).
  • the reinforced glass pane can be a two-layer laminated glass pane.
  • Laminated glass panes are known from US Pat. No. 4,341,576, which consist of three or more thermally toughened float glass panes and intermediate layers made of a plastic such as polyvinyl butyral.
  • Laminated glasses are also known from DE-C-657.447, which consist of several thermally toughened glass panes with elastic intermediate layers arranged between them.
  • the invention has for its object to provide a fire resistance class G 30 corresponding glazing unit with a symmetrical structure that is simple to manufacture, has no armouring obstructions such as wire inlays, and consists exclusively of single glass panes of the usual float glass compositions.
  • this object is achieved in that existing glazing consisting of at least three at least 3 mm thick parallel to each other, through transparent adhesive layers of a thermoplastic material such as polyvinyl butyral interconnected to a laminated glass pane, in which at least the two outer float glass panes are thermally toughened , is used as fire-resistant glazing of fire resistance class G 30 according to DIN 4102.
  • the fire-retardant properties of the laminated glasses mentioned are based on the interaction of the heat-absorbing properties of the individual glass panes on the one hand and the increased service life of a toughened glass pane until it bursts or splits compared to that of a non-toughened glass pane on the other hand, these properties mutually influencing and interacting lead the desired goal.
  • the second glass pane in the middle field only has due to the heat-absorbing effect of this first glass pane reached a temperature which is substantially below the temperature of the first pane of glass in the middle of the field. After the first glass pane has burst, it therefore takes a few minutes again for a temperature difference to arise in the second glass pane between the center and the edge of the pane, which leads to tensile stresses in the edge region of the second glass pane that this second glass pane also breaks.
  • the third pane of glass which in turn is a toughened pane of glass, released for the immediate application of heat. Since on the one hand the middle field of the third pane of glass had been protected against the direct exposure to heat and therefore its temperature had risen only relatively slowly, but on the other hand the edge area of this third pane of glass had already been heated up considerably by heat conduction via the metallic frame, this is the time The temperature difference between the pane surface and the edge region seated in the mounting frame is comparatively small and remains so low even during the further heat that it does not lead to the tensile stresses required for this third glass pane to rupture in the edge region of this third glass pane. As a result, at least this third pane of glass remains in the frame uninterrupted until it begins to soften and thereby collapse. However, this only occurs at a point in time that is certainly only after the required time interval of 30 minutes.
  • glazing units in which two outer tempered glass panes are connected to a central non-tempered glass pane already meet the requirements of fire resistance class G 30. Greater safety is achieved, however, and this is an advantageous further development of the invention, even if this medium one Silicate glass pane made of toughened glass exists because in this way the point in time at which the third glass pane is exposed to the direct action of heat is postponed further because of the increased service life of the second glass pane.
  • the fire resistance period can be increased by four or more prestressed ones. Glass panes are processed into a laminated glass unit.
  • the thickness of the individual glass panes is not critical if the individual glass panes each have a minimum thickness of at least 3 mm. On the other hand, it has been shown that above a certain thickness of the individual glass panes it is no longer possible to achieve any significant increase in the fire resistance duration.
  • the individual silicate glass panes preferably have a thickness 6 of about 4 to 6 mm each, so that the finished glazing unit has a total thickness of only about 12 to 18 mm.
  • the thickness and the material of the adhesive layers between the individual glass panes are not critical for the functionality of the glazing unit.
  • the films made of polyvinyl butyral which are customary for the production of laminated glass panes, for example with a thickness of 0.38 mm.
  • a preferred embodiment of the glazing unit used according to the invention consists of a laminated glass of three 4 mm thick thermally toughened glass panes made of float glass, the level of the prestressing being within the values customary for single-pane safety glass. These three thermally toughened glass panes are connected to one another via two 0.38 mm thick adhesive layers made of thermoplastic polyvinyl butyral, the connection being carried out in a manner known per se and customarily by heat overpressure treatment in an autoclave.
  • the glazing unit is a laminated glass pane 1 composed of three 4 mm thick glass panes 2, 3 and 4, each made of thermally toughened float glass, which are bonded together using thermoplastic adhesive layers 5, 6 made of polyvinyl butyral using heat and pressure.
  • the areal dimensions of the laminated glass pane for the fire test are 160 x 120 cm.
  • the laminated glass pane 1 is installed within the opening 7 in the wall 8 of a fire test furnace, with the aid of a suitable steel frame construction.
  • the steel frame construction comprises square tube sections 10, the width dimensions of the square tube corresponding approximately to the thickness of the laminated glass pane 1.
  • the square tube sections 10 are screwed by means of screws 11 to the surfaces of the wall 8 delimiting the opening 7.
  • the laminated glass pane 1 With the help of the glass retaining strips 12, which are screwed to the square tube sections 10 with screws 13, the laminated glass pane 1 is clamped at the edge. Between the glass holding strips 12 and the glass pane, intermediate layers 14 made of non-combustible, resilient material are arranged, for example strips made of a material consisting essentially of mineral fibers. Likewise, between the square tube sections 10 and Circumferential surfaces of the laminated glass pane 1 are arranged at least along the lower edge of the laminated glass pane 1 as a support for the laminated glass pane profile strips 15 made of a non-combustible material.
  • the glass pane 2 of the laminated glass pane 1 faces the fire chamber of the test furnace and is thus exposed to the direct action of flame, while the glass pane 4 is arranged on the side facing away from the fire.
  • the fire test is carried out in accordance with DIN 4102, Part 2, September 1977 edition, Sections 6.1 to 6.2.5.
  • the temperatures are measured at various points on the laminated glass pane using thermocouples that are in contact with the individual glass panes.
  • the three thermocouples 18, 19 and 20 are arranged approximately in the middle of the pane surface and thus reflect the temperature in the middle of the glazing.
  • the thermocouples 21, 22 and 23 are arranged in the edge region covered by the glass retaining strips 12 and reflect the temperature in the immediate edge region of the glass panes.
  • thermocouples 18 and 21 are arranged on the surface of the glass pane 2 facing the fire and are glued to the glass pane with a suitable refractory adhesive
  • the thermocouples 19 and 22 are in contact with the surface of the glass pane 3, are arranged within the intermediate layer 6 and give the temperature of the glass pane 3 again.
  • the temperature of the glass pane 4 facing away from the fire is measured with the thermocouples 20 and 23, which are in contact with the surface of this glass pane and are arranged within the intermediate layer 5.
  • the thermocouples 18, 19 and 20 on the one hand and 21, 22 and 23 on the other hand are each arranged one behind the other at the same height.
  • thermocouple 18 corresponds to the temperature measured by the thermocouple 18 in the central field of the glass pane 2 exposed to fire
  • curve 19' corresponds to the temperature measured by the thermocouple 19 in the central field of the central glass pane 3
  • curve 20 corresponds to that of the thermocouple 20 measured temperature in the middle of the glass pane 4 facing away from the fire side.
  • the measured temperatures each represent the temperature on the surface of the glass panes.
  • the curve 21 ' represents the temperature profile of the glass pane 2 facing the fire, measured by the thermocouple 21, in the edge region covered by the glass retaining strip 12, while the curves 22' and 23 'each show the temperature profile in the edge region of the middle glass plate 3 or that of the fire represent glass plate 4 facing away.
  • the glass pane 3 has a temperature which is approximately 200 ° below the temperature of the glass pane 2.
  • the temperature curve 19 ' continues to rise approximately parallel to the temperature curve 18' until, at time t 3 , that is to say approximately 8 minutes after the start of the experiment, the temperature difference between the temperature in the middle field (curve 19 ') and the temperature in the peripheral region (curve 22 ') has become so large that the resulting tensile stresses in the edge area lead to the glass pane 3 bursting.
  • the temperature curve 19 ′ drops steeply immediately after the glass pane 3 breaks, which in this case is due to the fact that the thermocouple 19 has lost its direct contact with the glass surface of the glass pane 3.
  • the glass pane 4 only has a temperature which is approximately 350 ° below the temperature of the glass pane 3.
  • the relatively slow rise in the temperature curve 20 ′ in the middle of the glass pane 4 becomes significantly steeper at time t 3 .
  • This combustion process is completed at time 4 and the further rise in temperature of the glass pane 4 slows down, as curve 20 ′ shows.
  • the fact that the combustion products of the Intermediate layer 5 adhere to the surface of the glass pane 4 and thereby form an insulating layer against the heat radiation and the convective heat transfer to this glass pane.
  • the edge region of the glass plate 4 heats up only insignificantly more slowly than the center field of the glass pane until time t 3 , and also in the period between t 3 and t s , in which an acceleration of the temperature increase in the middle field is observed, the temperature difference between the middle field and the edge region never reaches values that can lead to dangerous tensile stresses in the edge region of the glass pane 4. Surprisingly, the situation even reverses at time t 5 .
  • the middle field and the edge area of the glass pane 4 have the same temperature, and because of the steeper rise in the temperature in the edge area due to the intensive heat conduction 11 due to the frame construction on the one hand and the lower heat transfer in the middle field of the glass pane 4 on the other hand, the temperature difference increases with time, with the opposite Sign.
  • the edge area of this glass pane 4 is not only free of dangerous tensile stresses, but is even placed under compressive stresses.

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  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Special Wing (AREA)
  • Securing Of Glass Panes Or The Like (AREA)

Abstract

1. Use of a glazing, which consists of at least three individual float glass panes which are each at least 3 millimetres thick, are arranged one parallely to the other and connected one with the other into a compound glass pane by transparent adhesive layers of a thermoplastic synthetic material such as polyvinyl butyral and in which at least both the outer float glass panes are prestressed thermally, as glazing capable of fire resistance and of the fire resistance class G 30 according to German Industrial Norm 4102.

Description

Die Erfindung betrifft die Verwendung einer Verbundglasscheibe als feuerwiderstandsfähige Verglasung.The invention relates to the use of a laminated glass pane as fire-resistant glazing.

Die Anforderungen, die gegen Feuer widerstandsfähige Verglasungen erfüllen müssen, ergeben sich aus DIN 4102, Teil 5, Ausgabe September 1977. Um der Feuerwiderstandsklasse G 30 zu entsprechen, müssen die Verglasungen für einen Zeitraum von wenigstens 30 Minuten bei nach DIN 4102, Teil 2, vorgeschriebenen Brandversuchen als Raumabschluß wirksam bleiben. Auf der vom Feuer abgekehrten Seite der Verglasungen dürfen weder Flammen noch Brandgase auftreten.The requirements that fire-resistant glazing must meet are set out in DIN 4102, Part 5, September 1977 edition. To comply with fire resistance class G 30, the glazing must be used for at least 30 minutes in accordance with DIN 4102, Part 2, prescribed fire tests remain effective as room closures. No flames or combustion gases may occur on the side of the glazing facing away from the fire.

Bei einer ersten bekannten feuerwiderstandsfähigen Verglasung der eingangs genannten Art (DE-OS 24 56 991) besteht wenigstens eine der Glasscheiben aus einem hitzebeständigen Spezialglas, nämlich aus einem Borosilikat- oder Alumosilikatglas mit niedrigem Wärmeausdehnungskoeffizienten bzw. mit einem niedrigen Produkt aus Wärmeausdehnungskoeffizient a und Elastizitätsmodul E, und diese Spezialglasscheibe weist im Randbereich eine Druckspannung auf. Solche Spezialgläser sind teuer, und die Herstellung optisch einwandfreier, das heißt-verzerrungsfreier Glasscheiben aus diesen Spezialgläsern ist wegen der hohen Viskosität solcher Glasschmelzen mit erheblichen Schwierigkeiten verbunden. Die einzelnen Glasscheiben dieser bekannten Verglasung sind mit Luftabstand von 10 bis 100 mm voneinander angeordnet. Dabei ist es auch bekannt, die eine der beiden mit Luftabstand voneinander angeordneten Glasscheiben durch eine Verbundglasscheibe aus zwei vorgespannten üblichen Silikatglasscheiben zu ersetzen, während die andere der beiden mit Luftabstand voneinander angeordneten Glasscheiben aus dem hitzebeständigen Spezialglas besteht.In the case of a first known fire-resistant glazing of the type mentioned at the beginning (DE-OS 24 56 991), at least one of the glass panes consists of a heat-resistant special glass, namely a borosilicate or aluminosilicate glass with a low coefficient of thermal expansion or with a low product of coefficient of thermal expansion a and modulus of elasticity E. , and this special glass pane has a compressive stress in the edge area. Such special glasses are expensive, and the production of optically perfect, that is, distortion-free, glass panes from these special glasses is associated with considerable difficulties because of the high viscosity of such glass melts. The individual glass panes of this known glazing are arranged with an air gap of 10 to 100 mm from each other. It is also known to replace one of the two glass panes which are spaced apart from one another by a laminated glass pane made from two tempered conventional silicate glass panes, while the other of the two glass panes which are spaced apart from one another consists of the heat-resistant special glass.

Bei einer anderen bekannten feuerwiderstandsfähigen Verglasung sind zwei oder mehr Silikatglasscheiben üblicher Zusammensetzung ebenfalls mit Luftabstand voneinander angeordnet, wobei die auf der der Hitzeeinwirkung zugewandten Seite angeordnete Glasscheibe eine armierte Glasscheibe, und die auf der der Hitzeeinwirkung abgewandten Seite angeordnete Glasscheibe eine nichtarmierte jedoch vorgespannte Glasscheibe ist (DE-PS 26 45 259). Die armierte Glasscheibe kann in diesem Fall eine zweischichtige Verbundglasscheibe sein. Diese Verglasungseinheit mit einem solchen unsymmetrischen Aufbau erfüllt die Anforderungen der Feuerwiderstandsklasse G 30 nur dann, wenn das Feuer auf die armierte Glasscheibe einwirkt. Da jedoch nach DIN 4102, Teil 5, bei unsymmetrischen Verglasungen das Feuer bei einem probekörper auf die eine Seite und bei einem weiteren probekörper auf die andere Seite einwirken soll, haben diese bekannten Verglasungen nur dann mit Sicherheit die gewünschten Eigenschaften, wenn auf beiden Seiten der nichtarmierten vorgespannten Glasscheibe jeweils mit Luftabstand eine armierte Glasscheibe angeordnet ist. Eine Verglasung mit einem derartigen Aufbau ist jedoch sehr aufwendig.In another known fire-resistant glazing, two or more silicate glass panes of conventional composition are also spaced apart from one another, the glass pane arranged on the side facing the heat being an armored glass pane and the glass pane arranged on the side facing away from the heat being a non-reinforced but toughened glass pane ( DE-PS 26 45 259). In this case, the reinforced glass pane can be a two-layer laminated glass pane. This glazing unit with such an asymmetrical structure only fulfills the requirements of fire resistance class G 30 if the fire acts on the reinforced glass pane. However, since according to DIN 4102, Part 5, with asymmetrical glazing, the fire should act on one side on one test specimen and on the other side on another test specimen, these known glazings only have the desired properties with certainty if on both sides the non-reinforced toughened glass pane is arranged with a reinforced glass pane each with air clearance. Glazing with such a structure is very expensive.

Aus der US-A-4.341.576 sind Verbundglasscheiben bekannt, die aus drei oder mehr thermisch vorgespannten Floatglasscheiben und Zwischenschichten aus einem Kunststoff wie Polyvinylbutyral bestehen.Laminated glass panes are known from US Pat. No. 4,341,576, which consist of three or more thermally toughened float glass panes and intermediate layers made of a plastic such as polyvinyl butyral.

Auch aus der DE-C-657.447 sind Verbundgläser bekannt, die aus mehreren thermisch vorgespannten Glasscheiben mit dazwischen angeordneten elastischen Zwischenschichten bestehen.Laminated glasses are also known from DE-C-657.447, which consist of several thermally toughened glass panes with elastic intermediate layers arranged between them.

Der Erfindung liegt die Aufgabe zugrunde, eine der Feuerwiderstandsklasse G 30 entsprechende Verglasungseinheit mit symmetrischem Aufbau zu schaffen, die einfach in ihrer Herstellung ist, keine die Sicht behindernde Armierungen wie Drahteinlagen aufweist, und ausschließlich aus Einzelglasscheiben der üblichen Floatglaszusammensetzungen besteht.The invention has for its object to provide a fire resistance class G 30 corresponding glazing unit with a symmetrical structure that is simple to manufacture, has no armouring obstructions such as wire inlays, and consists exclusively of single glass panes of the usual float glass compositions.

Erfindungsgemäß wird diese Aufgabe dadurch gelöst, daß eine aus wenigstens drei jeweils mindestens 3 mm dicken parallel zueinander angeordneten, durch durchsichtige Kleberschichten aus einem thermoplastischen Kunststoff wie Polyvinylbutyral zu einer Verbundglasscheibe miteinander verbundenen einzelnen Floatglasscheiben bestehenden Verglasung, bei der wenigstens die beiden äußeren Floatglasscheiben thermisch vorgespannt sind, als feuerwiderstandsfähige Verglasung der Feuerwiderstandsklasse G 30 nach DIN 4102 verwendet wird.According to the invention this object is achieved in that existing glazing consisting of at least three at least 3 mm thick parallel to each other, through transparent adhesive layers of a thermoplastic material such as polyvinyl butyral interconnected to a laminated glass pane, in which at least the two outer float glass panes are thermally toughened , is used as fire-resistant glazing of fire resistance class G 30 according to DIN 4102.

Es hat sich überraschenderweise gezeigt, daß an sich bekannte Verbundglasscheiben aus üblichem Floatglas die strengen Anforderungen der Feuerwiderstandsklasse G 30 erfüllen. Derartige Verbundglasscheiben erfüllen auch alle oben genannten Anforderungen. Insbesondere sind sie klar durchsichtig, symmetrisch aufgebaut und haben insgesamt eine verhältnismäßig geringe Dicke. Ferner sind sie einfach herzustellen, nämlich nach den bekannten und üblichen Verfahren für die Herstellung von vorgespanntem Einscheibensicherheitsglas und von Verbundsicherheitsglas.Surprisingly, it has been shown that known laminated glass panes made of conventional float glass meet the strict requirements of fire resistance class G 30. Such laminated glass panes also meet all of the above requirements. In particular, they are clearly transparent, symmetrically constructed and overall have a relatively small thickness. Furthermore, they are easy to manufacture, namely by the known and customary methods for the production of toughened toughened safety glass and laminated safety glass.

Die feuerhemmenden Eigenschaften der genannten Verbundgläser beruhen auf dem Zusammenwirken der wärmeabsorbierenden Eigenschaften der einzelnen Glasscheiben einerseits und der erhöhten Standzeit einer vorgespannten Glasscheibe bis zum Bersten bzw. Zersplittern im Vergleich zu derjenigen einer nicht vorgespannten Glasscheibe andererseits, wobei diese Eigenschaften sich gegenseitig beeinflussen und im Zusammenwirken zu dem angestrebten Ziel führen.The fire-retardant properties of the laminated glasses mentioned are based on the interaction of the heat-absorbing properties of the individual glass panes on the one hand and the increased service life of a toughened glass pane until it bursts or splits compared to that of a non-toughened glass pane on the other hand, these properties mutually influencing and interacting lead the desired goal.

Wenn die dem Feuer zugewandte vorgespannte Einzelglasscheibe nach einigen Minuten aufgrund der Zugspannungen zerbricht, die wegen der steigenden Temperaturdifferenz zwischen dem Randbereich und dem Mittelfeld der Glasscheibe im Randbereich entstehen, hat wegen derwärmeabsorbierenden Wirkung dieser ersten Glasscheibe die zweite Glasscheibe im Mittelfeld erst eine Temperatur erreicht, die wesentlich unterhalb der Temperatur der ersten Glasscheibe im Mittelfeld liegt. Nach dem Zerbersten der ersten Glasscheibe dauert es deshalb wiederum einige Minuten, bis in der zweiten Glasscheibe zwischen Scheibenmitte und Scheibenrand eine Temperaturdifferenz entstanden ist, die zu solchen Zugspannungen im Randbereich der zweiten Glasscheibe führt, daß auch diese zweite Glasscheibe zerbricht. Erst beim Zerbersten der zweiten Glasscheibe wird die dritte Glasscheibe, bei der es sich wiederum um eine vorgespannte Glasscheibe handelt, für die unmittelbare Hitzebeaufschlagung freigegeben. Da einerseits bis zu diesem Augenblick das Mittelfeld der dritten Glasscheibe gegen die unmittelbare Hitzebeaufschlagung geschützt und daher ihre Temperatur nur verhältnismäßig langsam angestiegen war, andererseits aber der Randbereich dieser dritten Glasscheibe durch die Wärmeleitung über den metallischen Rahmen bereits stark erwärmt wurde, ist zu diesem Zeitpunkt die Temperaturdifferenz zwischen der Scheibenfläche und dem im Einbaurahmen sitzenden Randbereich verhältnismäßig gering und bleibt auch während der weiteren Hitzeeinwirkung so niedrig, daß sie nicht zu den für ein Zerbersten dieser dritten Glasscheibe erforderlichen Zugspannungen im Randbereich dieser dritten Glasscheibe führt. Infolgedessen bleibt zumindest diese dritte Glasscheibe so lange unzerbrochen im Rahmen, bis sie zu erweichen beginnt und dadurch in sich zusammensackt. Das aber erfolgt erst zu einem Zeitpunkt, der mit Sicherheit erst nach dem geforderten Zeitintervall von 30 Minuten liegt.If the tempered single glass pane facing the fire breaks after a few minutes due to the tensile stresses that arise due to the increasing temperature difference between the edge area and the middle field of the glass pane in the edge area, the second glass pane in the middle field only has due to the heat-absorbing effect of this first glass pane reached a temperature which is substantially below the temperature of the first pane of glass in the middle of the field. After the first glass pane has burst, it therefore takes a few minutes again for a temperature difference to arise in the second glass pane between the center and the edge of the pane, which leads to tensile stresses in the edge region of the second glass pane that this second glass pane also breaks. Only when the second pane of glass breaks, is the third pane of glass, which in turn is a toughened pane of glass, released for the immediate application of heat. Since on the one hand the middle field of the third pane of glass had been protected against the direct exposure to heat and therefore its temperature had risen only relatively slowly, but on the other hand the edge area of this third pane of glass had already been heated up considerably by heat conduction via the metallic frame, this is the time The temperature difference between the pane surface and the edge region seated in the mounting frame is comparatively small and remains so low even during the further heat that it does not lead to the tensile stresses required for this third glass pane to rupture in the edge region of this third glass pane. As a result, at least this third pane of glass remains in the frame uninterrupted until it begins to soften and thereby collapse. However, this only occurs at a point in time that is certainly only after the required time interval of 30 minutes.

In vielen Fällen erfüllen bereits Verglasungseinheiten, bei denen zwei äußere vorgespannte Glasscheiben mit einer mittleren nicht vorgespannten Glasscheibe verbunden sind, die Bedingungen entsprechend der Feuerwiderstandsklasse G 30. Eine größere Sicherheit erreicht man jedoch, und darin besteht eine vorteilhafte Weiterentwicklung der Erfindung, wenn auch diese mittlere Silikatglasscheibe aus vorgespanntem Glas besteht, weil auf diese Weise der Zeitpunkt, zu dem die dritte Glasscheibe der unmittelbaren Hitzeeinwirkung ausgesetzt wird, wegen der erhöhten Standzeit der zweiten Glasscheibe weiter hinausgeschoben wird.In many cases, glazing units in which two outer tempered glass panes are connected to a central non-tempered glass pane already meet the requirements of fire resistance class G 30. Greater safety is achieved, however, and this is an advantageous further development of the invention, even if this medium one Silicate glass pane made of toughened glass exists because in this way the point in time at which the third glass pane is exposed to the direct action of heat is postponed further because of the increased service life of the second glass pane.

Die Feuerwiderstandsdauer läßt sich gewünschtenfalls dadurch erhöhen, daß vier oder mehr jeweils vorgespannte. Glasscheiben zu einer Verbundglaseinheit verarbeitet werden.If desired, the fire resistance period can be increased by four or more prestressed ones. Glass panes are processed into a laminated glass unit.

Die Dicke der einzelnen Glasscheiben, und damit die Dicke der gesamten Verglasungseinheit, ist nicht kritisch, sofern die einzelnen Glasscheiben jeweils eine Mindestdicke von wenigstens 3 mm aufweisen. Es hat sich andererseits gezeigt, daß sich oberhalb einer bestimmten Dicke der einzelnen Glasscheiben auch keine wesentliche Erhöhung der Feuerwiderstandsdauer mehr erreichen läßt. Vorzugsweise haben die einzelnen Silikatglasscheiben eine Dicke 6 von jeweils etwa 4 bis 6 mm, so daß die fertige Verglasungseinheit eine Gesamtdicke von lediglich etwa 12 bis 18 mm aufweist.The thickness of the individual glass panes, and thus the thickness of the entire glazing unit, is not critical if the individual glass panes each have a minimum thickness of at least 3 mm. On the other hand, it has been shown that above a certain thickness of the individual glass panes it is no longer possible to achieve any significant increase in the fire resistance duration. The individual silicate glass panes preferably have a thickness 6 of about 4 to 6 mm each, so that the finished glazing unit has a total thickness of only about 12 to 18 mm.

Ebenso wenig wie die Dicke der Silikatglasscheiben ist die Dicke und das Material der Klebeschichten zwischen den Einzelglasscheiben für die Funktionstüchtigkeit der Verglasungseinheit kritisch. Für den erfindungsgemäßen Zweck eignen sich z.B. die für die Herstellung von Verbundglasscheiben üblichen Folien aus Polyvinylbutyral, beispielsweise mit einer Dicke von 0,38 mm.Just like the thickness of the silicate glass panes, the thickness and the material of the adhesive layers between the individual glass panes are not critical for the functionality of the glazing unit. For the purpose according to the invention, e.g. the films made of polyvinyl butyral which are customary for the production of laminated glass panes, for example with a thickness of 0.38 mm.

Eine bevorzugte Ausführungform der erfindungsgemäß verwendeten Verglasungseinheit besteht aus einem Verbundglas aus drei jeweils 4 mm dicken thermisch vorgespannten Glasscheiben aus Floatglas, wobei die Höhe der Vorspannung sich innerhalb der für Einscheibensicherheitsglas üblichen Werte bewegt. Diese drei thermisch vorgespannten Glasscheiben sind über zwei jeweils 0,38 mm dicke Kleberschichten aus thermoplastischem Polyvinylbutyral miteinander verbunden, wobei die Verbindung in an sich bekannter und üblicher Weise durch eine Wärme-Überdruck-Behandlung in einem Autoklav erfolgt.A preferred embodiment of the glazing unit used according to the invention consists of a laminated glass of three 4 mm thick thermally toughened glass panes made of float glass, the level of the prestressing being within the values customary for single-pane safety glass. These three thermally toughened glass panes are connected to one another via two 0.38 mm thick adhesive layers made of thermoplastic polyvinyl butyral, the connection being carried out in a manner known per se and customarily by heat overpressure treatment in an autoclave.

Ein Ausführungsbeispiel der Erfindung wird anhand der Zeichnungen näher erläutert. Von den Zeichnungen zeigt

  • Fig. 1 einen senkrechten Schnitt durch eine erfindungsgemäße Verglasung, die zum Zwecke eines Brandversuchs in der Wandöffnung eines Brandofens eingesetzt ist, und
  • Fig. 2 das Versuchsprotokoll während eines Brandversuchs in Form eines Diagramms.
An embodiment of the invention is explained in more detail with reference to the drawings. From the drawings shows
  • Fig. 1 is a vertical section through a glazing according to the invention, which is used for the purpose of a fire test in the wall opening of a fire stove, and
  • Fig. 2 shows the test protocol during a fire test in the form of a diagram.

Die Verglasungseinheit ist eine Verbundglasscheibe 1 aus drei jeweils 4 mm dicken Glasscheiben 2, 3 und 4, jeweils aus thermisch vorgespanntem Floatglas, die mit Hilfe der thermoplastischen Kleberschichten 5, 6 aus Polyvinylbutyral unter Anwendung von Wärme und Druck miteinander verbunden sind. Die flächenmäßigen Abmessungen der Verbundglasscheibe betragen für den Brandversuch 160 x 120 cm. Die Verbundglasscheibe 1 ist innerhalb der Öffnung 7 in der Wand 8 eines Brandversuchsofens eingebaut, und zwar mit Hilfe einer geeigneten Stahlrahmenkonstruktion. Die Stahlrahmenkonstruktion umfaßt Vierkantrohrabschnitte 10, wobei die Breitenabmessungen des Vierkantrohres etwa der Dicke der Verbundglasscheibe 1 entsprechen. Die Vierkantrohrabschnitte 10 sind mit Hilfe von Schrauben 11 mit den die Öffnung 7 begrenzenden Flächen der Wand 8 verschraubt. Mit Hilfe der Glashalteleisten 12, die mit Schrauben 13 mit den Vierkantrohrabschnitten 10 verschraubt werden, wird die Verbundglasscheibe 1 am Rand eingespannt. Zwischen den Glashalteleisten 12 und der Glasscheibe sind Zwischenlagen 14 aus nicht brennbarem nachgiebigem Material angeordnet, beispielsweise Streifen aus einem im wesentlichen aus Mineralfasern bestehenden Material. Ebenso sind zwischen den Vierkantrohrabschnitten 10 und den Umfangsflächen der Verbundglasscheibe 1 wenigstens entlang der Unterkante der Verbundglasscheibe 1 als Auflager für die Verbundglasscheibe Profilstreifen 15 aus einem nicht brennbaren Material angeordnet.The glazing unit is a laminated glass pane 1 composed of three 4 mm thick glass panes 2, 3 and 4, each made of thermally toughened float glass, which are bonded together using thermoplastic adhesive layers 5, 6 made of polyvinyl butyral using heat and pressure. The areal dimensions of the laminated glass pane for the fire test are 160 x 120 cm. The laminated glass pane 1 is installed within the opening 7 in the wall 8 of a fire test furnace, with the aid of a suitable steel frame construction. The steel frame construction comprises square tube sections 10, the width dimensions of the square tube corresponding approximately to the thickness of the laminated glass pane 1. The square tube sections 10 are screwed by means of screws 11 to the surfaces of the wall 8 delimiting the opening 7. With the help of the glass retaining strips 12, which are screwed to the square tube sections 10 with screws 13, the laminated glass pane 1 is clamped at the edge. Between the glass holding strips 12 and the glass pane, intermediate layers 14 made of non-combustible, resilient material are arranged, for example strips made of a material consisting essentially of mineral fibers. Likewise, between the square tube sections 10 and Circumferential surfaces of the laminated glass pane 1 are arranged at least along the lower edge of the laminated glass pane 1 as a support for the laminated glass pane profile strips 15 made of a non-combustible material.

Die Glasscheibe 2 der Verbundglasscheibe 1 ist dem Brandraum des Versuchsofens zugewandt und damit der direkten Flammeneinwirkung ausgesetzt, während die Glasscheibe 4 auf der dem Feuer abgewandten Seite angeordnet ist.The glass pane 2 of the laminated glass pane 1 faces the fire chamber of the test furnace and is thus exposed to the direct action of flame, while the glass pane 4 is arranged on the side facing away from the fire.

Der Brandversuch wird entsprechend DIN 4102, Teil 2, Ausgabe September 1977, Abschnitt 6.1 bis 6.2.5 durchgeführt. Während des Brandversuchs werden die Temperaturen an verschiedenen Stellen der Verbundglasscheibe gemessen, und zwar mit Hilfe von Thermoelementen, die mit den einzelnen Glasscheiben in Kontakt stehen. Die drei Thermoelemente 18, 19 und 20 sind etwa in der Mitte der Scheibenfläche angeordnet und geben so die Temperatur im Mittelfeld der Verglasung wieder. Die Thermoelemente 21, 22 und 23 sind in dem von den Glashalteleisten 12 abgedeckten Randbereich angeordnet und geben die Temperatur im unmittelbaren Randbereich der Glasscheiben wieder. Während die Thermoelemente 18 und 21 auf der dem Feuer zugewandten Oberfläche der Glasscheibe 2 angeordnet und mit einem geeigneten feuerfesten Kleber mit der Glasscheibe verklebt sind, stehen die Thermoelemente 19 und 22 mit der Oberfläche der Glasscheibe 3 in Kontakt, sind innerhalb der Zwischenschicht 6 angeordnet und geben die Temperatur der Glasscheibe 3 wieder. Die Temperatur der dem Feuer abgewandten Glasscheibe 4 wird mit den Thermoelementen 20 und 23 gemessen, die mit der Oberfläche dieser Glasscheibe in Kontakt stehen und innerhalb der Zwischenschicht 5 angeordnet sind. Die Thermoelemente 18, 19 und 20 einerseits und 21, 22 und 23 andererseits sind jeweils auf gleicher Höhe hintereinander angeordnet.The fire test is carried out in accordance with DIN 4102, Part 2, September 1977 edition, Sections 6.1 to 6.2.5. During the fire test, the temperatures are measured at various points on the laminated glass pane using thermocouples that are in contact with the individual glass panes. The three thermocouples 18, 19 and 20 are arranged approximately in the middle of the pane surface and thus reflect the temperature in the middle of the glazing. The thermocouples 21, 22 and 23 are arranged in the edge region covered by the glass retaining strips 12 and reflect the temperature in the immediate edge region of the glass panes. While the thermocouples 18 and 21 are arranged on the surface of the glass pane 2 facing the fire and are glued to the glass pane with a suitable refractory adhesive, the thermocouples 19 and 22 are in contact with the surface of the glass pane 3, are arranged within the intermediate layer 6 and give the temperature of the glass pane 3 again. The temperature of the glass pane 4 facing away from the fire is measured with the thermocouples 20 and 23, which are in contact with the surface of this glass pane and are arranged within the intermediate layer 5. The thermocouples 18, 19 and 20 on the one hand and 21, 22 and 23 on the other hand are each arranged one behind the other at the same height.

Das mit Hilfe dieser sechs Thermoelemente aufgenommene Temperaturdiagramm, aus dem sich der Versuchsverlauf ablesen läßt, ist in Fig. 2 dargestellt. In diesem Diagramm entspricht Kurve 18' der von dem Thermoelement 18 gemessenen Temperatur im Mittelfeld der dem Feuer ausgesetzten Glasscheibe 2, die Kurve 19' der von dem Thermoelement 19 gemessenen Temperatur im Mittelfeld der mittleren Glasscheibe 3, und die Kurve 20' der von dem Thermoelement 20 gemessenen Temperatur im Mittelfeld der der Feuerseite abgewandten Glasscheibe 4. Die gemessenen Temperaturen stellen jeweils die Temperatur an der Oberfläche der Glasscheiben dar.The temperature diagram recorded with the aid of these six thermocouples, from which the course of the experiment can be read, is shown in FIG. 2. In this diagram, curve 18 'corresponds to the temperature measured by the thermocouple 18 in the central field of the glass pane 2 exposed to fire, curve 19' corresponds to the temperature measured by the thermocouple 19 in the central field of the central glass pane 3, and curve 20 'corresponds to that of the thermocouple 20 measured temperature in the middle of the glass pane 4 facing away from the fire side. The measured temperatures each represent the temperature on the surface of the glass panes.

Die Kurve 21' stellt den von dem Thermoelement 21 gemessenen Temperaturverlauf der dem Feuer zugewandten Glasscheibe 2 in dem von der Glashalteleiste 12 überdeckten Randbereich dar, während die Kurven 22' und 23' jeweils den Temperaturverlauf im Randbereich der mittleren Glasscheibe 3 bzw. der dem Feuer abgewandten Glasscheibe 4 darstellen.The curve 21 'represents the temperature profile of the glass pane 2 facing the fire, measured by the thermocouple 21, in the edge region covered by the glass retaining strip 12, while the curves 22' and 23 'each show the temperature profile in the edge region of the middle glass plate 3 or that of the fire represent glass plate 4 facing away.

Unmittelbar nach Beginn des Brandversuchs steigt entsprechend der Kurve 18' die Temperatur im Mittelfeld der dem Feuer ausgesetzten Glasscheibe 2 steil an, während die Temperatur in dem gegen die unmittelbare Hitzebeaufschlagung geschützten Randbereich entsprechend der Kurve 21' nur verhältnismäßig langsam ansteigt. Nach etwa 5 Minuten (Zeitpunkt t,) ist die dadurch bedingte Temperaturdifferenz zwischen dem Mittelfeld und dem Randbereich so groß geworden, daß die dadurch im Randbereich hervorgerufenen Zugspannungen zum Zerbersten dieser Glasscheibe 2 führen. In der Temperaturkurve 18' macht sich diese Tatsache jedoch nicht bemerkbar, weil die beim Bruch der Glasscheibe entstandenen Glaskrümel über die Zwischenschicht 6 noch durch die Glasscheibe 3 eine Zeitlang festgehalten werden. Erst im Zeitpunkt t2, das heißt nach etwa 7,5 Minuten, hat die Zwischenschicht 6 ihre Klebewirkung völlig verloren, und die Krümel der Glasscheibe 2 fallen herunter, so daß nunmehr die Glasscheibe 3 unmittelbar dem Feuer ausgesetzt ist.Immediately after the start of the fire test, the temperature in the middle of the glass pane 2 exposed to the fire rises steeply in accordance with curve 18 ', while the temperature in the edge region protected against direct heat exposure rises only relatively slowly in accordance with curve 21'. After about 5 minutes (time t 1) the resulting temperature difference between the central field and the edge area has become so great that the tensile stresses thereby caused in the edge area lead to the breaking of this glass pane 2. However, this fact is not noticeable in the temperature curve 18 ', because the glass crumbs that formed when the glass pane broke are still retained for a while by the glass pane 3 via the intermediate layer 6. Only at the time t 2 , that is to say after about 7.5 minutes, has the intermediate layer 6 completely lost its adhesive effect, and the crumbs of the glass pane 2 fall down, so that the glass pane 3 is now directly exposed to the fire.

Zum Zeitpunkt ti, in dem die Glasscheibe 2 zerbricht, weist die Glasscheibe 3 eine Temperatur auf, die etwa 200° unter der Temperatur der Glasscheibe 2 liegt. Die Temperaturkurve 19' steigt etwa parallel zur Temperaturkurve 18' weiter an, bis im Zeitpunkt t3, das heißt etwa 8 Minuten nach Beginn des Versuchs, die Temperaturdifferenz zwischen der Temperatur im Mittelfeld (Kurve 19') und der Temperatur im Randbereich (Kurve 22') so groß geworden ist, daß die dadurch entstehenden Zugspannungen im Randbereich zum Zerbersten der Glasscheibe 3 führen. Die Temperaturkurve 19' fällt unmittelbar nach dem Bruch der Glasscheibe 3 steil ab, was in diesem Fall darauf zurückzuführen ist, daß das Thermoelement 19 seinen direkten Kontakt mit der Glasoberfläche der Glasscheibe 3 verloren hat. Im Zeitpunkt t4, das heißt nach etwa 10,5 Minuten, fallen die Glaskrümel, die bis zu diesem Zeitpunkt noch durch die Zwischenschicht 5 festgehalten wurden, herunter, so daß nunmehr die Glasscheibe 4 allein für den Abschluß der Öffnung 7 sorgt. Diese Glasscheibe 4 ist im Rahmen noch fest eingespannt, weil die 10 Randbereiche der zerborstenen Glasscheiben 2 und 3 jeweils im Rahmen verbleiben.At the time t i at which the glass pane 2 breaks, the glass pane 3 has a temperature which is approximately 200 ° below the temperature of the glass pane 2. The temperature curve 19 'continues to rise approximately parallel to the temperature curve 18' until, at time t 3 , that is to say approximately 8 minutes after the start of the experiment, the temperature difference between the temperature in the middle field (curve 19 ') and the temperature in the peripheral region (curve 22 ') has become so large that the resulting tensile stresses in the edge area lead to the glass pane 3 bursting. The temperature curve 19 ′ drops steeply immediately after the glass pane 3 breaks, which in this case is due to the fact that the thermocouple 19 has lost its direct contact with the glass surface of the glass pane 3. At time t 4 , that is to say after about 10.5 minutes, the glass crumbs, which were still held by the intermediate layer 5 until then, fall down, so that now the glass pane 4 alone ensures the closure of the opening 7. This glass pane 4 is still firmly clamped in the frame because the 10 edge regions of the broken glass panes 2 and 3 each remain in the frame.

Im Zeitpunkt t3, in dem die Glasscheibe 3 zerbricht, weist die Glasscheibe 4 erst eine Temperatur auf, die etwa 350° unterhalb der Temperatur der Glasscheibe 3 liegt. Der bis dahin verhältnismäßig langsame Anstieg der Temperaturkurve 20' im Mittelfeld der Glasscheibe 4 wird im Zeitpunkt t3 deutlich steiler. Dieser bis zum Zeitpunkt ts andauernde steilere Anstieg der Tempe- raturkurve 20' kann auf die durch das Verbrennen der organischen Zwischenschicht 5 hervorgerufene zusätzliche Wärmeentwicklung zurückgeführt werden. Dieser Verbrennungsvorgang ist im Zeitpunkt 4 abgeschlossen, und der weitere Temperaturanstieg der Glasscheibe 4 verlangsamt sich, wie die Kurve 20' zeigt. Zu der Verlangsamung des Temperaturanstiegs trägt auch die Tatsache bei, daß die Verbrennungsprodukte der Zwischenschicht 5 auf der Oberfläche der Glasscheibe 4 haften bleiben und dadurch eine Isolierschicht gegen die Wärmestrahlung und die konvektive Wärmeübertragung auf diese Glasscheibe bilden.At the time t 3 , in which the glass pane 3 breaks, the glass pane 4 only has a temperature which is approximately 350 ° below the temperature of the glass pane 3. The relatively slow rise in the temperature curve 20 ′ in the middle of the glass pane 4 becomes significantly steeper at time t 3 . This continued until the time t s steeper rise in Tempe - raturkurve 20 'can be attributed to the by burning the organic interlayer caused additional heat development. 5 This combustion process is completed at time 4 and the further rise in temperature of the glass pane 4 slows down, as curve 20 ′ shows. The fact that the combustion products of the Intermediate layer 5 adhere to the surface of the glass pane 4 and thereby form an insulating layer against the heat radiation and the convective heat transfer to this glass pane.

Wie die Temperaturkurven 20' und 23' zeigen, die den Temperaturverlauf im Mittelfeld und im Randbereich der Glasscheibe 4 darstellen, erwärmt sich der Randbereich der Glasscheibe 4 bis zum Zeitpunkt t3 nur unwesentlich langsamer als das Mittelfeld der Glasscheibe, und auch in dem Zeitraum zwischen t3 und ts, in dem eine Beschleunigung der Temperaturerhöhung im Mittelfeld beobachtet wird, erreicht die Temperaturdifferenz zwischen Mittelfeld und Randbereich zu keinem Zeitpunkt Werte, die zu gefährlichen Zugspannungen im Randbereich der Glasscheibe 4 führen können. Überraschenderweise kehren sich im Zeitpunkt t5 die Verhältnisse sogar um. Im Zeitpunkt t6 haben Mittelfeld und Randbereich der Glasscheibe 4 dieselbe Temperatur, und wegen des steileren Anstiegs der Temperatur im Randbereich aufgrund der intensiven Wärmeleitung 11 durch die Rahmenkonstruktion einerseits und des niedrigeren Wärmeübergangs im Mittelfeld der Glasscheibe 4 andererseits vergrößert sich sogar mitzunehmenderZeit die Temperaturdifferenz mit umgekehrtem Vorzeichen. Infolge dieses Effektes ist der Randbereich dieser Glasscheibe 4 nicht nur frei von gefährlichen Zugspannungen, sondern wird sogar unter Druckspannungen gesetzt. Auf diese Weise ist sichergestellt, daß die Glasscheibe 4 nicht wie die Glasscheiben 2 und 3 durch das Entstehen von Zugspannungen im Randbereich zerbricht, sondern daß sie unzerbrochen im Rahmen bleibt, bis sie aus anderen Gründen, nämlich beispielsweise infolge des Erweichens des Glases, sich oben auf dem Rahmen löst und in sich zusammensackt. In dem beschriebenen Versuch ist das im Zeitpunkt t7 der Fall, das heißt nach 36 Minuten. Bis zu diesem Zeitpunkt t7 schließt die Glasscheibe 4 die Öffnung 7 vollständig ab, so daß die Bedingungen für die Feuerwiderstandsklasse G 30 voll erfüllt sind.As the temperature curves 20 'and 23' show, which represent the temperature profile in the middle field and in the edge region of the glass pane 4, the edge region of the glass plate 4 heats up only insignificantly more slowly than the center field of the glass pane until time t 3 , and also in the period between t 3 and t s , in which an acceleration of the temperature increase in the middle field is observed, the temperature difference between the middle field and the edge region never reaches values that can lead to dangerous tensile stresses in the edge region of the glass pane 4. Surprisingly, the situation even reverses at time t 5 . At time t 6 , the middle field and the edge area of the glass pane 4 have the same temperature, and because of the steeper rise in the temperature in the edge area due to the intensive heat conduction 11 due to the frame construction on the one hand and the lower heat transfer in the middle field of the glass pane 4 on the other hand, the temperature difference increases with time, with the opposite Sign. As a result of this effect, the edge area of this glass pane 4 is not only free of dangerous tensile stresses, but is even placed under compressive stresses. In this way it is ensured that the glass pane 4 does not break like the glass panes 2 and 3 due to the creation of tensile stresses in the edge region, but that it remains unbroken in the frame until it rises for other reasons, for example due to the softening of the glass loosens on the frame and slumps down. In the experiment described, this is the case at time t 7 , that is after 36 minutes. Up to this point in time t 7 , the glass pane 4 closes the opening 7 completely, so that the conditions for the fire resistance class G 30 are fully met.

Claims (5)

1. Use of a glazing, which consists of at least three individual float glass panes which are each at least 3 millimetres thick, are arranged one parallelly to the other and connected one with the other into a compound glass pane by transparent adhesive layers of a thermoplastic synthetic material such as polyvinyl butyral and in which at least both the outer float glass panes are prestressed thermally, as glazing capable of fire resistance and of the fire resistance class G 30 according to German Industrial Norm 4102.
2. Use of a glazing according to claim 1, characterised thereby, that the thickness of the individual glass panes each amounts to 4 to 6 millimetres.
3. Use of a glazing according to claim 1 or 2, characterised thereby, that the or each glass pane arranged between the outer prestressed glass panes is likewise prestressed thermally.
4. Use of a glazing according to claim 3, characterised thereby, that three glass panes, which are each of float glass 4 millimetres thick and prestressed thermally, are connected one with the other by two intermediate layers each about 0.4 millimetres thick and of polyvinyl butyral.
5. Use of a glazing according to claim 3, characterised thereby, that four glass panes, which are each prestressed thermally, are connected one with the other by three intermediate layers each about 0.4 millimetres thick and of polyvinyl butyral.
EP86114193A 1985-10-19 1986-10-14 Fire-screening glazing unit Expired - Lifetime EP0219801B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT86114193T ATE56664T1 (en) 1985-10-19 1986-10-14 FIRE RESISTANT GLAZING UNIT.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19853537255 DE3537255A1 (en) 1985-10-19 1985-10-19 FIRE RESISTANT GLAZING UNIT
DE3537255 1985-10-19

Publications (3)

Publication Number Publication Date
EP0219801A2 EP0219801A2 (en) 1987-04-29
EP0219801A3 EP0219801A3 (en) 1988-07-20
EP0219801B1 true EP0219801B1 (en) 1990-09-19

Family

ID=6283966

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86114193A Expired - Lifetime EP0219801B1 (en) 1985-10-19 1986-10-14 Fire-screening glazing unit

Country Status (3)

Country Link
EP (1) EP0219801B1 (en)
AT (1) ATE56664T1 (en)
DE (2) DE3537255A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0635617A2 (en) 1993-07-22 1995-01-25 Saint-Gobain Vitrage Transparent flame shielding panel

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3807426A1 (en) * 1987-12-16 1989-06-29 Gartner & Co J FIRE-SAFE GLAZING SYSTEM
FR2710932B1 (en) * 1993-10-07 1995-12-08 Saint Gobain Vitrage Int Gas separation element intended to equip the upper part of premises.
DE19729336A1 (en) * 1997-07-09 1999-01-14 Vetrotech Saint Gobain Int Ag Fire-resistant laminated glass
DE10118614A1 (en) * 2001-04-12 2002-10-24 Flabeg Gmbh & Co Kg Glazing unit for buildings comprises a coating consisting of a material not letting through UV light, and is applied either to the second pane or the fourth pane
DE10118617B4 (en) * 2001-04-12 2007-11-08 Econtrol-Glas Gmbh & Co.Kg Glazing unit for buildings
EP1577276A1 (en) * 2004-03-05 2005-09-21 Glaverbel Glazing panel
CN109083575B (en) * 2018-09-25 2019-12-24 河南中楷幕墙门窗科技有限公司 Bridge-cut-off aluminum alloy heat-insulation fireproof window and assembling method

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE657447C (en) * 1932-02-13 1938-03-04 Fritz Eckert Dr Laminated safety glass
US4341576A (en) * 1981-06-01 1982-07-27 Ppg Industries, Inc. Fabricating laminated safety glass without an autoclave
DE3128530A1 (en) * 1981-07-18 1983-02-03 Dynamit Nobel Ag, 5210 Troisdorf SOFTENING FILMS FROM PARTLY ACETALIZED POLYVINYL ALCOHOLS

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0635617A2 (en) 1993-07-22 1995-01-25 Saint-Gobain Vitrage Transparent flame shielding panel

Also Published As

Publication number Publication date
DE3674325D1 (en) 1990-10-25
DE3537255A1 (en) 1987-04-23
EP0219801A2 (en) 1987-04-29
ATE56664T1 (en) 1990-10-15
EP0219801A3 (en) 1988-07-20

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