DK2793579T6 - Anvendelse af strobilurintype forbindelser til bekæmpelse af fytopatogene svampe, der er resistente over for qo-hæmmere - Google Patents
Anvendelse af strobilurintype forbindelser til bekæmpelse af fytopatogene svampe, der er resistente over for qo-hæmmere Download PDFInfo
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- DK2793579T6 DK2793579T6 DK12795452.7T DK12795452T DK2793579T6 DK 2793579 T6 DK2793579 T6 DK 2793579T6 DK 12795452 T DK12795452 T DK 12795452T DK 2793579 T6 DK2793579 T6 DK 2793579T6
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Claims (16)
1. Anvendelse af forbindelser med formel I R2 R—> R4 hvor: R1 og R2 uafhængigt af hinanden er hydrogen, halogen, Ci-C4-alkyl, Ci-C4_alkoxy, C2-C6~alkenyl, C2-C6-alkenyloxy, C2-C6~alkynyl, C3- C6-cycloalkyl eller C3-C6-cycloalkyl-Ci-C4-alkyl, hvor grupperne R1 og R2 are cis-orienterede, eller R1 og R2 sammen med de to carbonatomer, der kobler dem, danner en phenylring, forudsat at R4 er 4-methyl-l,4-dihydrotetrazol-5-on-l-yl (formel R4-7), og hvor de alifatiske dele af R1 og/eller R2 eller ovennævnte phenylring kan bære 1, 2, 3 eller op til det maksimale antal af identiske eller forskellige grupper Ra, som uafhængigt af hinanden er udvalgt blandt: Ra, halogen, CN, nitro, Ci-C4-alkyl, Ci-C4~alkoxy, Ci-C4-haloalkyl og C1-C4- haloalkoxy; Y er en direkte binding eller en divalent gruppe, der er udvalgt blandt -OCH2-, -CH2-, -CH2CH2-, -C (Z) =N-0-CH2-, -CHZ-C (Z) =N-0- CH2-, -0-N=C(Z)-C(Z)=N-0-CH2-, -C(=0)-C(Z)=N-0-CH2- og -C(=N-0- Z)-C(Z)=n-o-ch2-, hvor bindingen på venstre side af den divalente gruppe Y er bundet til R3, og bindingen på højre side er bundet til carbonatomet, der substitueres med R2, og Z, der kan være ens eller forskellig i forhold til eventuelle andre Z, er hydrogen, Ci-C4_alkyl eller Ci-C4~haloalkyl; R3 er phenyl eller en 3- til 10-leddet, mættet, delvist umættet eller aromatisk mono- eller bicyklisk heterocyclyl, hvor ringelementatomerne i heterocyclyl'en ud over carbonatomer indbefatter 1, 2, 3 eller 4 heteroatomer, der er udvalgt fra gruppen, der består af N, 0 og S; hvor de cykliske grupper R3 kan bære 1, 2, 3, 4 eller op til det maksimale mulige antal af identiske eller forskellige grupper Rb, som uafhængigt af hinanden er udvalgt blandt: Rb, der kan være ens eller forskellig i forhold til eventuelle andre Rb og er amino, halogen, hydroxyl, oxo, nitro, CN, carboxyl, Ci-C4-alkyl, C2-C4-alkenyl, C2-C4~alkynyl, C1-C4- haloalkyl, Ci-C4-alkoxy, Ci-C4-haloalkoxy, C3-C6-cycloalkyl, C3- C6-cycloalkenyl, C2-C6~alkenyloxy, C3~C6-alkynyloxy, C1-C6-alkoxyimino-Ci-C4-alkyl, C2-C6-alkenyloxyimino-Ci-C4-alkyl, C2- C6-alkynyloxyimino-Ci-C4-alkyl, Ci-C4-alkylamino, C1-C4- alkoxycarbonyl, Ci-C4-alkylcarbonyloxy, phenyl, naphthyl eller en 3- til 10-leddet, mættet, delvist umættet eller aromatisk mono- eller bicyklisk heterocyclyl, som foruden carbonatomer indeholder et til fire heteroatomer fra gruppen, der består af N, 0 og S, som ringelementer; og hvor ovennævnte phenyl- og heterocyclylgrupper Rb er bundet via en direkte binding, et oxygen- eller svovlatom, og to radikaler Rb, der er bundet til tilgrænsende ringelementatomer i den cykliske gruppe R3, sammen med ringelementatomerne kan danne en fusioneret 5-, 6- eller 7-leddet, mættet, delvist umættet eller aromatisk cyklus, som kan være en carbocyklus eller heterocyklus, hvor ringelementatomerne i heterocyklussen ud over carbonatomer indbefatter 1, 2, 3 eller 4 heteroatomer, der er udvalgt fra gruppen, der består af N, 0 og S, og hvor de alifatiske eller cykliske grupper Rb for deres del kan bære 1, 2, 3 eller op til det maksimale mulige antal af identiske eller forskellige grupper Rc, der kan være ens eller forskellig i forhold til eventuelle andre Rc og er halogen, hydroxyl, nitro, CN, carboxyl, C1-C4-alkyl, C2~C4-alkenyl, C2-Cs-alkynyl, Ci-C4-haloalkyl, C1-C4- alkoxy, Ci-C4-haloalkoxy, Ci-C6-alkoxyimino-Ci-C4-alkyl, C2-C6- alkenyloxyimino-Ci-C4-alkyl, C2-C6-alkynyloxyimino-Ci-C4-alkyl, Ci-C6-alkoxyimino-, C2-C6-alkenyloxyimino-, C2-C6- alkynyloxyimino-, C2-C6-haloalkenyloxyimino-, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, phenyl eller en 5-leddet, mættet, delvist umættet eller aromatisk heterocyclyl, som foruden carbonatomer indeholder et til tre heteroatomer fra gruppen, der består af N, 0 og S, som ringelementer; hvor ovennævnte cykliske grupper Rc er bundet via en direkte binding, et oxygen- eller svovlatom, og hvor de alifatiske eller cykliske grupper Rc for deres del kan bære 1, 2, 3 eller op til det maksimale mulige antal af identiske eller forskellige grupper Rd: Rd, der kan være ens eller forskellig i forhold til eventuelle andre Rd og er halogen, Ci-C4-alkyl eller Ci-C4-haloalkyl; eller R3 er -CRA=N-0-RB, hvor RA er amino, hydroxyl, Ci-C4~alkyl, C2-C4~alkenyl, C2-C4_alkynyl, Ci-C4-haloalkyl, Ci-C4-alkoxy, Ci-C4-haloalkoxy, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, C2-C6-alkenyloxy, C3-C6-alkynyloxy, C1-C4-alkoxyimino-Ci-C4-alkyl, Ci-C4~al kyl amino, Ci-C4_alkoxycarbonyl, Ci-C4-alkylcarbonyloxy, phenyl, phenyl-Ci-C4-alkyl, naphthyl eller en 3- til 10-leddet, mættet, delvist umættet eller aromatisk mono- eller bicyklisk heterocyclyl, som foruden carbonatomer indeholder et til fire heteroatomer fra gruppen, der består af 0, N og S, som ringelementer; og hvor ovennævnte cykliske RA er bundet via en direkte binding, et oxygen- eller svovlatom; RB er Ci-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, Ci-C4-haloalkyl, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, Ci-C4-alkoxyimino-Ci-C4-alkyl, Ci-C4-alkoxycarbonyl, phenyl, phenyl-Ci-C4-alkyl, naphthyl eller en 3- til 10-leddet, mættet, delvist umættet eller aromatisk mono- eller bicyklisk heterocyclyl, som foruden carbonatomer indeholder et til fire heteroatomer fra gruppen, der består af 0, N og S, som ringelementer; hvor de alifatiske eller cykliske grupper RA og/eller RB for deres del kan bære 1, 2, 3 eller op til det maksimale mulige antal af identiske eller forskellige grupper Re: Re, der kan være ens eller forskellig i forhold til eventuelle andre Re, er halogen, hydroxyl, nitro, CN, carboxyl, Ci-C4-alkyl, C2-C4-alkenyl, C2-Cs-alkynyl, Ci-C4-haloalkyl, Ci-C4-alkoxy eller C1-C4-haloalkoxy; R4 er en monovalent gruppe, der er udvalgt blandt formlerne R4-1 til R4-7 °Y^n'0'ch3; °γ^°^Η3 . °y^0'CH= ; °γ%5 . 'CH3 x'ch3 X'CH3 X'CH3 R4-1 R4-2 R4-3 R4-4 oJ^OH, . o T O n T f λ 11 i X'CH3 h/1 n-n 6 R4-5 R4-6 R R4-7 hvor den takkede linje definerer påhæftningspunktet, og X er en direkte binding eller en divalent gruppe CH2, 0 eller NH, R5 er Ci-C4-alkyl, Ci-C4-alkoxy, Ci-C4-haloalkyl, Ci-C4-haloalkoxy eller C3-C6-cycloalkyl, R6 er Ci-C4~alkyl eller Ci-C4-haloalkyl; og N-oxiderne og de landbrugsmæssigt acceptable salte deraf til bekæmpelse af fytopatogene svampe, der indeholder en mutation i det mitokondriske cytochrom b-gen, der bibringer resistens over for Qo-hæmmere, hvor mutationen er G143A.
2. Anvendelse ifølge krav 1, hvor de fytopatogene svampe er udvalgt fra gruppen, der består af Alternaria alternata, Blumeria graminis, Pyricularia oryzae (også kaldet Magnaporthe grisea), Septoria tritici (også kaldet Mycosphaerella graminicola), Mycosphaerella fijiensis, Venturia inaequalis, Pyrenophora teres, Pyrenophora triticirepentis og Plasmopara viticola.
3. Anvendelse ifølge et hvilket som helst af kravene 1 til 2, hvor den fytopatogene svamp er Septoria tritici.
4. Fremgangsmåde til bekæmpelse af fytopatogene svampe ifølge et hvilket som helst af kravene 1 til 3, der omfatter: behandling af de fytopatogene svampe ifølge et hvilket som helst af kravene 1 til 3 eller materialer, planter, jord eller frø, der er i risiko for at være inficeret med fotopatogene svampe ifølge et hvilket som helst af kravene 1 til 3, med en effektiv mængde af mindst én forbindelse med formel I ifølge krav 1 eller en sammensætning, der omfatter denne.
5. Fremgangsmåde ifølge krav 4, der omfatter: a) identificering af de fytopatogene svampe ifølge et hvilket som helst af kravene 1 til 3 eller materialer, planter, jord eller frø, der er i risiko for at være inficeret med fotopatogene svampe ifølge et hvilket som helst af kravene 1 til 3, og b) behandling af svampene eller materialerne, planterne, jorden eller frøene med en effektiv mængde af mindst én forbindelse med formel I ifølge krav 1 eller en sammensætning, der omfatter denne.
6. Forbindelser med formel I R2 R—Y^5V'R R4 hvor: R1 og R2 uafhængigt af hinanden er hydrogen, Ci-C4-alkyl, C1-C4-alkoxy, C2-C6-alkenyl, C2-C6-alkenyloxy, C2-C6-alkynyl, C3-C6-cycloalkyl eller C3-C6-cycloalkyl-Ci-CU-alkyl, hvor grupperne R1 og R2 er cis-orienterede, hvor de alifatiske dele af R1 og/eller R2 kan bære 1, 2, 3 eller op til det maksimale antal af identiske eller forskellige grupper Ra, som uafhængigt af hinanden er udvalgt blandt: Ra, CN, nitro, Ci-CU-alkyl, Ci-C4-alkoxy, Ci-C4-haloalkyl og Ci-C4_haloalkoxy; Y er en direkte binding eller en divalent gruppe, der er udvalgt blandt -OCH2-, -CH2-, -CH2CH2-, -C (Z) =N-0-CH2-, -CHZ-C (Z) =N-0- CH2-, -0-N=C(Z)-C(Z)=N-0-CH2-, -C(=0)-C(Z)=N-0-CH2- og -C(=N-0- Z)-C(Z)=N-0-CH2-, hvor bindingen på venstre side af den divalente gruppe Y er bundet til R3, og bindingen på højre side er bundet til carbonatomet, der substitueres med R2, og Z, der kan være ens eller forskellig i forhold til eventuelle andre Z, er Ci-C4_alkyl eller Ci-C4_haloalkyl; R3 er phenyl eller en 3- til 10-leddet, mættet, delvist umættet eller aromatisk mono- eller bicyklisk heterocyclyl, hvor ringelementatomerne i heterocyclyl'en ud over carbonatomer indbefatter 1, 2, 3 eller 4 heteroatomer, der er udvalgt fra gruppen, der består af N, 0 og S; hvor de cykliske grupper R3 kan bære 1, 2, 3, 4 eller op til det maksimale mulige antal af identiske eller forskellige grupper Rb, som uafhængigt af hinanden er udvalgt blandt: Rb, der kan være ens eller forskellig i forhold til eventuelle andre Rb og er amino, halogen, hydroxyl, oxo, nitro, CN, carboxyl, Ci-C4-alkyl, C2-C4~alkenyl, C2~C4-alkynyl, C1-C4- haloalkyl, Ci-C4~alkoxy, Ci-C4-haloalkoxy, C3-C6-cycloalkyl, C3- C6-cycloalkenyl, C2-C6-alkenyloxy, C3-C6-alkynyloxy, C1-C6-alkoxyimino-Ci-C4-alkyl, C2-C6-alkenyloxyimino-Ci-C4-alkyl, C2- C6-alkynyloxyimino-Ci-C4-alkyl, Ci-C4-alkylamino, C1-C4- alkoxycarbonyl, Ci-C4-alkylcarbonyloxy, phenyl, naphthyl eller en 3- til 10-leddet, mættet, delvist umættet eller aromatisk mono- eller bicyklisk heterocyclyl, som foruden carbonatomer indeholder et til fire heteroatomer fra gruppen, der består af N, 0 og S, som ringelementer; og hvor ovennævnte phenyl- og heterocyclylgrupper Rb er bundet via en direkte binding, et oxygen- eller svovlatom; og to radikaler Rb, der er bundet til tilgrænsende ringelementatomer i den cykliske gruppe R3, sammen med ringelementatomerne kan danne en fusioneret 5-, 6- eller 7-leddet, mættet, delvist umættet eller aromatisk cyklus, som kan være en carbocyklus eller heterocyklus, hvor ringelementatomerne i den fusionerede heterocyklus ud over carbonatomer indbefatter 1, 2, 3 eller 4 heteroatomer, der er udvalgt fra gruppen, der består af N, 0 og S, og hvor de alifatiske eller cykliske grupper Rb for deres del kan bære 1, 2, 3 eller op til det maksimale mulige antal af identiske eller forskellige grupper R°: hvor R°, der kan være ens eller forskellig i forhold til eventuelle andre Rc, er halogen, hydroxyl, nitro, CN, carboxyl, Ci-C4-alkyl, C2-C4-alkenyl, C2-Cs-alkynyl, Ci-C4-haloalkyl, C1-C4-alkoxy, Ci-C4-haloalkoxy, Ci-C6-alkoxyimino-Ci-C4-alkyl, C2-C6-alkenyloxyimino-Ci-C4-alkyl, C2-C6-alkynyloxyimino-Ci-C4-alkyl, Ci-C4-alkoxyimino-Ci-C4-alkyl, Ci-C6-alkoxyimino-, C2-C6- alkenyloxyimino-, C2-C6-alkynyloxyimino-, C2-C6- haloalkenyloxyimino-, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, phenyl eller en 5-leddet, mættet, delvist umættet eller aromatisk heterocyclyl, som foruden carbonatomer indeholder et til tre heteroatomer fra gruppen, der består af N, 0 og S, som ringelementer; hvor ovennævnte cykliske grupper Rc er bundet via en direkte binding, et oxygen- eller svovlatom, og hvor de alifatiske eller cykliske grupper Rc for deres del kan bære 1, 2, 3 eller op til det maksimale mulige antal af identiske eller forskellige grupper Rd: hvor Rd, der kan være ens eller forskellig i forhold til eventuelle andre Rd, er halogen, Ci-C4-alkyl eller C1-C4-haloalkyl; eller R3 er -CRA=N-0-RB, hvor RA er amino, hydroxyl, Ci-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, Ci-C4-haloalkyl, Ci-C4~alkoxy, Ci-C4~haloalkoxy, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, C2-C6~alkenyloxy, C3-C6~alkynyloxy, C1-C4-alkoxyimino-Ci-C4-alkyl, C1-C4-al kyl amino, Ci-C4-alkoxycarbonyl, Ci-C4-alkylcarbonyloxy, phenyl, phenyl-Ci-C4~alkyl, naphthyl eller en 3- til 10-leddet, mættet, delvist umættet eller aromatisk mono- eller bicyklisk heterocyclyl, som foruden carbonatomer indeholder et til fire heteroatomer fra gruppen, der består af 0, N og S, som ringelementer; og hvor ovennævnte cykliske RA er bundet via en direkte binding, et oxygen- eller svovlatom; RB er Ci-C4-alkyl, C2-C4-alkenyl, C2-C4~alkynyl, Ci-C4-haloalkyl, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, CCi-C4-alkoxyimino-Ci-C4-alkyl, Ci-C4_alkoxycarbonyl, phenyl, phenyl-Ci-C4-alkyl, naphthyl eller en 3- til 10-leddet, mættet, delvist umættet eller aromatisk mono- eller bicyklisk heterocyclyl, som foruden carbonatomer indeholder et til fire heteroatomer fra gruppen, der består af 0, N og S, som ringelementer; hvor de alifatiske eller cykliske grupper RA og/eller RB for deres del kan bære 1, 2, 3 eller op til det maksimale mulige antal af identiske eller forskellige grupper Re: hvor Re, der kan være ens eller forskellig i forhold til eventuelle andre Re, er halogen, hydroxyl, nitro, CN, carboxyl, Ci-C4-alkyl, C2-C4-alkenyl, C2-Cs-alkynyl, Ci-C4-haloalkyl, C1-C4-alkoxy eller Ci-C4-haloalkoxy; R4 er en monovalent gruppe, der er udvalgt blandt formlerne R4- 1 til R4-7 'νΤΛ νΜΛΛ Μ|Μ °Y^N'°'CH3 ; °Y^0'CH3 ; °γ^0'ΕΗ3 = °γ%5 ; X"ch3 x'ch3 x"ch3 X'GH3 R4-1 R4-2 R4-3 R4-4 V^"' ; ογ£Ν.0 . ΐΝ X-CHS L0.ft Η · 6 R4-5 R4-6 R R4-7 hvor den takkede linje definerer påhæftningspunktet, og hvor X er en divalent gruppe 0 eller NH, R5 er Ci-C4-alkyl, Ci-C4-alkoxy, Ci-C4-haloalkyl, Ci-C4-haloalkoxy eller C3-C6-cycloalkyl, R6 er Ci-C4-alkyl eller Ci-C4~haloalkyl; og N-oxiderne og de landbrugsmæssigt acceptable salte deraf, bortset fra (2E, 3Z) -2-(ethyliden)-5-phenyl-3- pentensyremethylester (CAS-nr. 681026-20-0).
7. Forbindelser ifølge krav 6, hvor R1 og R2 uafhængigt af hinanden er hydrogen, Ci-C4-alkyl, Ci-C4-alkoxy, C2-C6-alkenyl, C2-C6-alkenyloxy, C2-C6~alkynyl, C3-C6-cycloalkyl eller C3-C6-cycloalkyl-Ci-C4-alkyl.
8. Forbindelser ifølge et hvilket som helst af kravene 6 til 7, hvor R1 er hydrogen, Ci-C4-alkyl, Ci-C4-alkoxy, Ci-C4-alkoxy-Ci-C4-alkyl eller Ci-C4-haloalkoxy-Ci-C4-alkyl.
9. Forbindelser ifølge krav 8, hvor R1 er methyl eller ethyl.
10. Forbindelser ifølge et hvilket som helst af kravene 6 til 9, hvor R2 er hydrogen.
11. Forbindelser ifølge et hvilket som helst af kravene 6 til 10, hvor Y er -OCH2-, -CH2CH2-, -C (CH3) =N-0-CH2-, -0-N=C (CH3) - C (CHS) =N-0-CH2- eller -C (=N-0-CH3) -C (CH3) =N-0-CH2- .
12. Forbindelser ifølge et hvilket som helst af kravene 6 til 11, hvor R3 er pyrazolyl, imidazolyl, oxazolyl, isoxazolyl, thiazolyl, 1,2,4-triazolyl, 1,2,4-oxadiazolyl, 1,3,4- oxadiazolyl eller 1,2,4-thiadiazolyl, der er substitueret med phenyl, hvor phenyl'en kan bære 1, 2, 3 eller op til det maksimale mulige antal af identiske eller forskellige grupper RG: hvor Rc, der kan være ens eller forskellige i forhold til eventuelle andre Rc, er halogen, Ci-C4-alkyl, C2-C4-alkenyl, Ci-C4-haloalkyl, Ci-C4-alkoxy, Ci-C4-haloalkoxy, Ci-C4-alkoxyimino-Ci-C4-alkyl, phenyl eller en 5-leddet, mættet, delvist umættet eller aromatisk heterocyclyl, som foruden carbonatomer indeholder et til tre heteroatomer fra gruppen, der består af N, 0 og S, som ringelementer; og hvor ovennævnte heterocyclylgrupper Rc er bundet via en direkte binding, et oxygen- eller svovlatom og for deres del kan bære 1, 2, 3 eller op til det maksimale mulige antal af identiske eller forskellige grupper Rd.
13. Forbindelser ifølge et hvilket som helst af kravene 6 til 12, hvor R4 er -C (=NOCH3) -CONHCH3, -C (=NOCH3) -COOCH3, -C (=CHOCH3) -COOCH3, -C (=CHOCH3) -CONHCH3, -N (OCHs) -COOCHs, -N (CHS) -COOCHs eller -N (CH2CH3) -COOCHs.
14. Agrokemiske sammensætninger, hvilke sammensætninger omfatter et hjælpstof og mindst én forbindelse med formel I ifølge et hvilket som helst af kravene 6 til 13, et N-oxid eller et landbrugsmæssigt acceptabelt salt deraf.
15. Sammensætninger ifølge krav 14, der omfatter mindst ét yderligere aktivt stof.
16. Sammensætninger ifølge krav 15, hvor det yderligere aktive stof er udvalgt blandt klasserne A) til 0): A) Respirationshæmmere Hæmmere af kompleks III i Q0-bindingsstedet (f.eks. strobiluriner): azoxystrobin, coumethoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, fenaminstrobin, fenoxystrobin/flufenoxystrobin, fluoxastrobin, kresoximmethyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyrametostrobin, pyraoxystrobin, trifloxystrobin, 2-[2-(2,5- dimethylphenoxymethyl)-phenyl]-3-methoxyacrylsyremethylester og 2-(2-(3-(2,6-dichlorphenyl)-1-methyl- allylidenaminooxymethyl)-phenyl)-2-methoxyimino-N-methylacetamid, pyribencarb, triclopyricarb/chlordin-carb, famoxadon, fenamidon; - hæinmere of kompleks III i Qi-bindingsstedet: cyazofamid, amisulbrom, [(3S, 6S, 7R, 8R)-8-benzyl-3-[(3-acetoxy-4- methoxypyridin-2-carbonyl)amino]-6-methyl-4,9-dioxo-l,5-dioxonan-7-yl]-2-methylpropanoat, [(3S, 6S, 7R, 8R)-8-benzyl-3-[[3-(acetoxymethoxy)-4-methoxypyridin-2-carbonyl]amino]-6-methyl-4,9-dioxo-l,5-dioxonan-7-yl]-2-methylpropanoat, [(3S,6S,7R,8R)-8-benzyl-3-[(3-isobutoxycarbonyloxy-4-methoxypyridin-2-carbonyl)amino]-6-methyl-4,9-dioxo-l, 5-dioxonan-7-yl]-2-methylpropanoat, [(3S, 6S,7R,8R)-8-benzyl-3-[[3-(1,3-benzodioxol-5-ylmethoxy)-4-methoxypyridin-2-carbonyl]amino]-6-methyl-4,9-dioxo-l, 5-dioxonan-7-yl]-2-methylpropanoat; (3S, 6S, 7R, 8R) -3-[[(3-hydroxy-4-methoxy-2- pyridinyl)carbonyl]amino]-6-methyl-4,9-dioxo-8-(phenylmethyl)- 1.5- dioxonan-7-yl-2-methylpropanoat; - hæmmere of kompleks II (f.eks. carboxamider): benodanil, benzovindiflupyr, bixafen, boscalid, carboxin, fenfuram, fluopyram, flutolanil, fluxapyroxad, furametpyr, isopyrazam, mepronil, oxycarboxin, penflufen, penthiopyrad, sedaxan, tecloftalam, thifluzamid, N-(4'-trifluormethylthiobiphenyl-2-yl)-3-difluormethyl-l-methyl-lH-pyrazol-4-carboxamid, N- (2- (1,3,3-trimethylbutyl)-phenyl)-1,3-dimethyl-5-fluor-lH-pyrazol-4-carboxamid, 3-(difluormethyl)-1-methyl-N-(1,1,3- trimethylindan-4-yl)pyrazol-4-carboxamid, 3-(trifluormethyl)-1-methyl-N-(1,1,3-trimethylindan-4-yl)pyrazol-4-carboxamid, 1,3-dimethyl-N-(1,1,3-trimethylindan-4-yl)pyrazol-4-carboxamid, 3-(trifluormethyl)-1,5-dimethyl-N-(1,1,3- trimethylindan-4-yl)-pyrazol-4-carboxamid, 3-(difluormethyl)- 1.5- dimethyl-N-(1,1,3-trimethylindan-4-yl)pyrazol-4- carboxamid, 1,3, 5-trimethyl-N-(1,1,3-trimethylindan-4- yl)pyrazol-4-carboxamid; andre respirationshæmmere (f.eks. kompleks I, afkoblere): diflumetorim, (5, 8-difluorquinazolin-4-yl)-{2-[2-fluor-4-(4- trifluormethylpyridin-2-yloxy)-phenyl]-ethyl}-amin; nitrophenylderivater: binapacryl, dinobuton, dinocap, fluazinam; ferimzon; organometalforbindelser: fentinsalte, såsom fentinacetat, fentinchlorid eller fentinhydroxid; ametoctradin; og silthiofam; B) Sterolbiosyntesehæmmere (SBI-fungicider) Hæmmere af C14-demethylase (DMI-fungicider): triazoler: azaconazol, bitertanol, bromuconazol, cyproconazol, difenoconazol, diniconazol, diniconazol-M, epoxiconazol, fenbuconazol, fluquinconazol, flusilazol, flutriafol, hexaconazol, imibenconazol, ipconazol, metconazol, myclobutanil, oxpoconazol, paclobutrazol, penconazol, propiconazol, prothioconazol, simeconazol, tebuconazol, tetraconazol, triadimefon, triadimenol, triticonazol, uniconazol, 1-[rel-(2 S;3R)-3-(2-chlorphenyl)-2-(2,4- difluorphenyl)-oxiranylmethyl]-5-thiocyanat-lH-[1,2,4]triazol, 2-[rel-(2 S;3R)-3-(2-chlorphenyl)-2-(2,4-difluorphenyl)-oxiranylmethyl]-2H-[1,2,4]triazol-3-thiol; imidazoler: imazalil, pefurazoat, prochloraz, triflumizol; pyrimidiner, pyridiner og piperaziner: fenarimol, nuarimol, pyrifenox, triforin; Hæmmere af deltal4-reduktase: aldimorph, dodemorph, dodemorphacetat, fenpropimorph, tridemorph, fenpropidin, piperalin, spiroxamin; - Hæmmere of 3-ketoreduktase: fenhexamid; C) Nukleinsyresyntesehæmmere phenylamider eller acylaminosyrefungicider: benalaxyl, benalaxyl-M, kiralaxyl, metalaxyl, metalaxyl-M (mefenoxam), ofurac, oxadixyl; andre: hymexazol, octhilinon, oxolinsyre, bupirimat, 5- fluorcytosin, 5-fluor-2-(p-tolylmethoxy)pyrimidin-4-amin, 5-fluor-2-(4—fluorphenylmethoxy)pyrimidin-4-amin; D) Hæmmere of celledeling og cytoskelet - tubulinhæmmere, såsom benzimidazoler, thiophanater: benomyl, carbendazim, fuberidazol, thiabendazol, thiophanatmethyl; triazolopyrimidiner: 5-chlor-7-(4-methylpiperidin-l-yl)-6- (2,4,6-trifluorphenyl)-[1,2,4]triazol[1,5-a]pyrimidin; andre celledelingshæmmere: diethofencarb, ethaboxam, pencycuron, fluopicolid, zoxamid, metrafenon, pyriofenon; E) Hæinmere af aminosyre- og proteinsyntese methioninsyntesehæmmere (anilinpyrimidiner): cyprodinil, mepanipyrim, pyrimethanil; proteinsyntesehæmmere: blasticidin-S, kasugamycin, kasugamycin-hydrochloridhydrat, mildiomycin, streptomycin, oxytetracyclin, polyoxin, validamycin A; F) Signaltransduktionshæmmere - MAP/histidinkinasehæmmere: fluoroimid, iprodion, procymidon, vinclozolin, fenpiclonil, fludioxonil; - G-proteinhæmmere: quinoxyfen; G) Lipid- og membransyntesehæmmere Phospholipidbiosyntesehæmmere: edifenphos, iprobenfos, pyrazophos, isoprothiolan; lipidperoxidation: dicloran, quintozen, tecnazen, tolclofosmethyl, biphenyl, chlorneb, etridiazol; - phospholipidbiosyntese og cellevægsdeponering: dimethomorph, flumorph, mandipropamid, pyrimorph, benthiavalicarb, iprovalicarb, valifenalat og N-(1-(1-(4- cyanophenyl)ethansulfonyl)-but-2-yl)-carbaminsyre-(4-fluorphenyl)-ester; forbindelser, der påvirker cellemembranpermeabilitet og fedtsyrer: propamocarb, propamocarbhydrochlorid; - fedtsyreamidhydrolasehæmmere: 1-[4-[4-[5-(2,6-difluorphenyl)- 4,5-dihydro-3-isoxazolyl]-2-thiazolyl]-1-piperidinyl]-2-[5-methyl-3-(trifluormethyl)-lH-pyrazol-l-yl]ethanon; H) Hæmmere med flere aktivitetssteder - uorganiske aktive stoffer: Bordeaux-blanding, kobberacetat, kobberhydroxid, kobberoxychlorid, basisk kobbersulfat, svovl; - thio- og dithiocarbamater: ferbam, mancozeb, maneb, metam, metiram, propineb, thiram, zineb, ziram; organochlorforbindelser (f.eks. phthalimider, sulfamider, chlornitriler): anilazin, chlorthalonil, captafol, captan, folpet, dichlofluanid, dichlorphen, flusulfamid, hexachlorbenzen, pentachlorphenol og dens salte, phthalid, tolylfluanid, N-(4-chlor-2-nitrophenyl)-N-ethyl-4- methyIbenzensu1fonamid; guanidiner og andre: guanidin, dodin, dodin fri base, guazatin, guazatincetat, iminoctadin, iminoctadintriacetat, iminoctadintris(albesilat) , dithianon, 2,6-dimethyl-lH,SH-[1,4] dithiino [2,3-c:5,6-c']dipyrrol-1,3,5,7(2H, 6H)-tetraon; I) Cellevægssyntesehæmmere hæmmere af glucansyntese: validamycin, polyoxin B; melaninsyntesehæmmere: pyroquilon, tricyclazol, carpropamid, dicyclomet, fenoxanil; J) Planteforsvarsinduktorer acibenzolar-S-methyl, probenazol, isotianil, tiadinil, prohexadioncalcium; phosphonater: fosetyl, fosetylaluminum, phosphorsyre og dens salte; K) Ukendt virkningsmekanisme - bronopol, chinomethionat, cyflufenamid, cymoxanil, dazomet, debacarb, diclomezin, difenzoquat, difenzoquatmethylsulfat, diphenylamin, fenpyrazamin, flumetover, flusulfamid, flutianil, methasulfocarb, nitrapyrin, nitrothalisopropyl, oxathiapiprolin, oxinkobber, proquinazid, tebufloquin, tecloftalam, triazoxid, 2-butoxy-6-iod-3-propylchromen-4-on, N-(cyclopropylmethoxyimino-(6-difluormethoxy-2,3-difluorphenyl)-methyl)-2-phenylacetamid, Ν' -(4-(4-chlor-3- trifluormethylphenoxy)-2,5-dimethylphenyl)-N-ethyl-N-methylformamidin, Ν' -(4-(4-fluor-3-trifluormethylphenoxy)-2,5-dimethylphenyl)-N-ethyl-N-methylformamidin, N'-(2-methyl-5- trifluormethyl-4-(3-trimethylsilanylpropoxy)-phenyl)-N-ethyl-N-methylformamidin, N'-(5-difluormethyl-2-methyl-4-(3- trimethylsilanylpropoxy)-phenyl)-N-ethyl-N-methylformamidin, methoxyeddikesyre-6-tert-butyl-8-fluor-2,3-dimethylquinolin-4-ylester, 3-[5-(4-methylphenyl)-2,3-dimethylisoxazolidin-3-yl]-pyridin, 3-[5-(4-chlorphenyl)-2,3-dimethylisoxazolidin-3-yl]-pyridin-(pyrisoxazol), N-(6-methoxypyridin-3-yl)- cyclopropancarboxylsyreamid, 5-chlor-l-(4,6- dimethoxypyrimidin-2-yl)-2-methyl-lH-benzoimidazol, 2- (4- chlorphenyl)-N-[4-(3,4-dimethoxyphenyl)-isoxazol-5-yl]-2-prop-2-ynyloxyacetamid; L) Antifungale biologiske bekæmpelsesmidler, piantebioaktivatorer Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus pumilus, Bacillus subtilis, Bacillus subtilis var. amyloliquefaciens FZB24, Candida oleophila 1-82, Candida saitoana, Chitosan, Clonostachys rosea f. catenulata også kaldet Gliocladium catenulatum, Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Fusarium oxysporum, Metschnikowia fructicola, Microdochium dimerum, Phlebiopsis gigantea, Pseudozyma flocculosa, Pythium oligandrum DV74, Reynoutria sachlinensis, Talaromyces flavus V117b, Trichoderma asperellum SKT-1, T. atroviride LC52, T. harzianum T-22, T. harzianum TH 35, T. harzianum T-39, T. harzianum og T. viride, T. harzianum ICC012 og T. viride ICC080, T. polysporum og T. harzianum, T. stromaticum, T. virens GL-21, T. viride, T. viride TV1, Ulocladium oudemansii HRU3; M) Vækstregulerende midler abscisinsyre, amidochlor, ancymidol, 6-benzylaminopurin, brassinolid, butralin, chlormequat (chlormequatchlorid) , cholinchlorid, cyclanilid, daminozid, dikegulac, dimethipin, 2,6-dimethylpuridin, ethephon, flumetralin, flurprimidol, fluthiacet, forchlorfenuron, gibberellinsyre, inabenfid, indol- 3-eddikesyre, maleinhydrazid, mefluidid, mepiquat (mepiquatchlorid), naphthaleneddikesyre, N-6-benzyladenin, paclobutrazol, prohexadion (prohexadioncalcium), prohydrojasmon, thidiazuron, triapenthenol, tributylphosphortrithioat, 2,3,5-triiodbenzoesyre, trinexapacethyl og uniconazol; N) Herbicider - acetamider: acetochlor, alachlor, butachlor, dimethachlor, dimethenamid, flufenacet, mefenacet, metolachlor, metazachlor, napropamid, naproanilid, pethoxamid, pretilachlor, propachlor, thenylchlor; aminosyrederivater: bilanafos, glyphosat, glufosinat, sulfosat; aryloxyphenoxypropionater: clodinafop, cyhalofopbutyl, fenoxaprop, fluazifop, haloxyfop, metamifop, propaquizafop, quizalofop, quizalofop-P-tefuryl; - Bipyridyler: diquat, paraquat; (thio)carbamater: asulam, butylat, carbetamid, desmedipham, dimepiperat, eptam (EPTC), esprocarb, molinat, orbencarb, phenmedipham, prosulfocarb, pyributicarb, thiobencarb, triallat; cyclohexandioner: butroxydim, clethodim, cycloxydim, profoxydim, sethoxydim, tepraloxydim, tralkoxydim; dinitroaniliner: benfluralin, ethalfluralin, oryzalin, pendimethalin, prodiamin, trifluralin; - diphenylethere: acifluorfen, aclonifen, bifenox, diclofop, ethoxyfen, fomesafen, lactofen, oxyfluorfen; - hydroxybenzonitriler: bomoxynil, dichlobenil, ioxynil; - imidazolinoner: imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr; - phenoxyeddikesyrer: clomeprop, 2,4-dichlorphenoxyeddikesyre (2,4-D), 2,4-DB, dichlorprop, MCPA, MCPA-thioethyl, MCPB, Mecoprop; pyraziner: chloridazon, flufenpyrethyl, fluthiacet, norflurazon, pyridat; - pyridiner: aminopyralid, clopyralid, diflufenican, dithiopyr, fluridon, fluroxypyr, picloram, picolinafen, thiazopyr; sulfonylurinstoffer: amidosulfuron, azimsulfuron, bensulfuron, chlorimuronethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, foramsulfuron, halosulfuron, imazosulfuron, iodosulfuron, mesosulfuron, metazosulfuron, metsulfuronmethyl, nicosulfuron, oxasulfuron, primisulfuron, prosulfuron, pyrazosulfuron, rimsulfuron, sulfometuron, sulfosulfuron, thifensulfuron, triasulfuron, tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron, 1-((2-chlor-6-propylimidazo[l,2-b]pyridazin-3-yl)sulfonyl) - 3-(4, 6-dimethoxypyrimidin-2-yl)urinstof; triaziner: ametryn, atrazin, cyanazin, dimethametryn, ethiozin, hexazinon, metamitron, metribuzin, prometryn, simazin, terbuthylazin, terbutryn, triaziflam; urinstoffer: chlortoluron, daimuron, diuron, fluometuron, isoproturon, linuron, methabenzthiazuron, tebuthiuron; andre acetolactatsyntasehæmmere: bispyribacnatrium, cloransulammethyl, diclosulam, florasulam, flucarbazon, flumetsulam, metosulam, ortho-sulfamuron, penoxsulam, propoxycarbazon, pyribambenzpropyl, pyribenzoxim, pyriftalid, pyriminobacmethyl, pyrimisulfan, pyrithiobac, pyroxasulfon, pyroxsulam; andre: amicarbazon, aminotriazol, anilofos, beflubutamid, benazolin, bencarbazon, benfluresat, benzofenap, bentazon, benzobicyclon, bicyclopyron, bromacil, bromobutid, butafenacil, butamifos, cafenstrol, carfentrazon, cinidonethyl, chlorthal, cinmethylin, clomazon, cumyluron, cyprosulfamid, dicamba, difenzoquat, diflufenzopyr, Drechslera monoceras, endothal, ethofumesat, etobenzanid, fenoxasulfon, fentrazamid, flumicloracpentyl, flumioxazin, flupoxam, flurochloridon, flurtamon, indanofan, isoxaben, isoxaflutol, lenacil, propanil, propyzamid, quinclorac, quinmerac, mesotrion, methylarsonsyre, naptalam, oxadiargyl, oxadiazon, oxaziclomefon, pentoxazon, pinoxaden, pyraclonil, pyraflufenethyl, pyrasulfotol, pyrazoxyfen, pyrazolynat, quinoclamin, saflufenacil, sulcotrion, sulfentrazon, terbacil, tefuryltrion, tembotrion, thiencarbazon, topramezon, (3-[2-chlor-4-fluor-5-(3-methyl-2,6-dioxo-4-trifluormethyl-3,6-dihydro-2H-pyrimidin-l-yl)-phenoxy]-pyridin-2-yloxy)-eddikesyreethylester, 6-amino-5- chlor-2-cyclopropylpyrimidin-4-carboxylsyrernethylester, 6- chlor-3-(2-cyclopropyl-6-methylphenoxy)-pyridazin-4-ol, 4- amino-3-chlor-6-(4-chlorphenyl)-5-fluorpyridin-2-carboxylsyre, 4-amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)-pyridin-2-carboxylsyremethylester og 4-amino-3-chlor-6-(4-chlor-3-dimethylamino-2-fluorphenyl)-pyridin-2-carboxy1syremethylester; 0) Insecticider organo(thio)phosphater: acephat, azamethiphos, azinphosmethyl, chlorpyrifos, chlorpyrifosmethyl, chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoat, disulfoton, ethion, fenitrothion, fenthion, isoxathion, malathion, methamidophos, methidathion, methylparathion, mevinphos, monocrotophos, oxydemetonmethyl, paraoxon, parathion, phenthoat, phosalon, phosmet, phosphamidon, phorat, phoxim, pirimiphosmethyl, profenofos, prothiofos, sulprophos, tetrachlorvinphos, terbufos, triazophos, trichlorfon; - carbamater: alanycarb, aldicarb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, fenoxycarb, furathiocarb, methiocarb, methomyl, oxamyl, pirimicarb, propoxur, thiodicarb, triazamat; - pyrethroider: allethrin, bifenthrin, cyfluthrin, cyhalothrin, cyphenothrin, cypermethrin, alfa-cypermethrin, beta- cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerat, etofenprox, fenpropathrin, fenvalerat, imiprothrin, lambda-cyhalothrin, permethrin, prallethrin, pyrethrin I og II, resmethrin, silafluofen, tau-fluvalinat, tefluthrin, tetramethrin, tralomethrin, transfluthrin, profluthrin, dimefluthrin; insektvækstregulerende midler: a) chitinsyntesehæmmere: benzoylurinstoffer: chlorfluazuron, cyramazin, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron; buprofezin, diofenolan, hexythiazox, etoxazol, clofentazine; b) ecdysonantagonister: halofenozid, methoxyfenozid, tebufenozid, azadirachtin; c) juvenoider: pyriproxyfen, methopren, fenoxycarb; d) lipidbiosyntesehæmmere: spirodiclofen, spiromesifen, spirotetramat; - nicotinreceptor-agonist/antagonistforbindelser: clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, acetamiprid, thiacloprid, 1-(2-chlorthiazol-5-ylmethyl)-2-nitrimino-3,5-dimethyl-[1,3,5]triazinan; - GABA-antagonistforbindelser: endosulfan, ethiprole, fipronil, vaniliprol, pyrafluprol, pyriprol, 5-amino-l-(2,6-dichlor-4-methylphenyl)-4-sulfinamoyl-lH-pyrazol-3-carbothiosyreamid; makrocykliske lactoninsekticider: abamectin, emamectin, milbemectin, lepimectin, spinosad, spinetoram; mitokondrisk elektrontransporthæmmer (METI) I-acaricider: fenazaquin, pyridaben, tebufenpyrad, tolfenpyrad, flufenerim; METI II- og Ill-forbindelser: acequinocyl, fluacyprim, hydramethylnon; - Afkoblende midler: chlorfenapyr; - hæmmere af oxidativ phosphorylering: cyhexatin, diafenthiuron, fenbutatinoxid, propargit; - fældningsforstyrrende forbindelser: cryomazin; - oxidasehæmmere med blandet funktion: piperonylbutoxid; - natriumkanalblokerende midler: indoxacarb, metaflumizon; - andre: benclothiaz, bifenazat, cartap, flonicamid, pyridalyl, pymetrozin, svovl, thiocyclam, flubendiamid, chlorantraniliprol, cyazypyr (HGW86), cyenopyrafen, flupyrazofos, cyflumetofen, amidoflumet, imicyafos, bistrifluron og pyrifluquinazon.
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- 2012-12-06 PL PL12795452T patent/PL2793579T6/pl unknown
- 2012-12-06 PE PE2014000987A patent/PE20141431A1/es not_active Application Discontinuation
- 2012-12-06 KR KR1020147020070A patent/KR102066829B1/ko active IP Right Grant
- 2012-12-06 BR BR112014015535A patent/BR112014015535A8/pt not_active Application Discontinuation
- 2012-12-06 PT PT127954527T patent/PT2793579T/pt unknown
- 2012-12-06 WO PCT/EP2012/074586 patent/WO2013092224A1/en active Application Filing
- 2012-12-06 DK DK12795452.7T patent/DK2793579T6/da active
- 2012-12-06 ES ES12795452.7T patent/ES2590466T7/es active Active
- 2012-12-06 CA CA2856954A patent/CA2856954C/en active Active
- 2012-12-06 CN CN201280063932.XA patent/CN104010502B/zh active Active
- 2012-12-06 IN IN4984CHN2014 patent/IN2014CN04984A/en unknown
- 2012-12-06 HU HUE12795452A patent/HUE030004T2/en unknown
- 2012-12-06 JP JP2014547826A patent/JP6189324B2/ja active Active
- 2012-12-06 US US14/364,532 patent/US9271501B2/en active Active
- 2012-12-06 EA EA201400686A patent/EA024331B1/ru not_active IP Right Cessation
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2014
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- 2014-05-29 CL CL2014001421A patent/CL2014001421A1/es unknown
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2016
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2017
- 2017-05-10 JP JP2017093458A patent/JP6430580B2/ja active Active
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2018
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