DE69702569D1 - Verfahren zur Herstellung von elastomerischen EP(D)M Copolymeren - Google Patents

Verfahren zur Herstellung von elastomerischen EP(D)M Copolymeren

Info

Publication number: DE69702569D1
Authority: DE; Germany
Prior art keywords: elastomeric; copolymers; production
Prior art date: 1996-05-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

DE69702569T

Other languages

English (en)

Other versions

DE69702569T2 (de

Inventor

Viviano Banzi

Liliana Gila

Roberto Santi

Paolo Biagini

Giampietro Borsotti

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Enichem SpA

Original Assignee

Enichem SpA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-05-09

Filing date

1997-05-03

Publication date

2000-08-24

1997-05-03 Application filed by Enichem SpA filed Critical Enichem SpA

2000-08-24 Publication of DE69702569D1 publication Critical patent/DE69702569D1/de

2001-03-15 Application granted granted Critical

2001-03-15 Publication of DE69702569T2 publication Critical patent/DE69702569T2/de

2017-05-04 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/04—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene copolymers
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/06—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene-diene terpolymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/09—Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

DE69702569T 1996-05-09 1997-05-03 Verfahren zur Herstellung von elastomerischen EP(D)M Copolymeren Expired - Lifetime DE69702569T2 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT96MI000926A IT1283630B1 (it)	1996-05-09	1996-05-09	Procedimento per la preparazione di copolimeri elastomerici ep(d)m

Publications (2)

Publication Number	Publication Date
DE69702569D1 true DE69702569D1 (de)	2000-08-24
DE69702569T2 DE69702569T2 (de)	2001-03-15

Family

ID=11374226

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE69702569T Expired - Lifetime DE69702569T2 (de)	1996-05-09	1997-05-03	Verfahren zur Herstellung von elastomerischen EP(D)M Copolymeren

Country Status (12)

Country	Link
US (1)	US6124413A (de)
EP (1)	EP0806436B1 (de)
JP (1)	JP3986613B2 (de)
KR (1)	KR100257458B1 (de)
CN (1)	CN1098869C (de)
BR (1)	BR9703091A (de)
CA (1)	CA2204177C (de)
DE (1)	DE69702569T2 (de)
ES (1)	ES2148895T3 (de)
IT (1)	IT1283630B1 (de)
MX (1)	MX9703331A (de)
RU (1)	RU2179561C2 (de)

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IT1298616B1 (it)	1998-03-10	2000-01-12	Enichem Spa	Complesso metallocenico pontato per la (co) polimerizzazione delle olefine
KR100342541B1 (ko) *	1998-04-16	2002-06-28	나까니시 히로유끼	올레핀 중합촉매 및 중합방법
KR20010034199A (ko) *	1998-11-20	2001-04-25	간디 지오프레이 에이치.	다리화 메탈로센, 제조, 촉매계 내에서의 용도
ITMI20011017A1 (it) *	2001-05-17	2002-11-17	Enichem Spa	Procedimento per la preparazione di copolimeri e terpolimeri elastomerici ep (d) m
EP1412394A2 (de) *	2001-07-19	2004-04-28	Univation Technologies LLC	Metallocenkatalysator, der niedrige mengen von comonomeren inkorporiert
US8008412B2 (en)	2002-09-20	2011-08-30	Exxonmobil Chemical Patents Inc.	Polymer production at supersolution conditions
US7439312B2 (en)	2002-10-24	2008-10-21	Exxonmobil Chemical Patents Inc.	Branched crystalline polypropylene
WO2004052950A1 (en)	2002-12-05	2004-06-24	Exxonmobil Chemical Patents Inc.	High temperature bulk polymerization of branched crystalline polypropylene
WO2004052952A1 (en) *	2002-12-05	2004-06-24	Exxonmobil Chemical Patents Inc.	Branched diene-modified crystalline polypropylene terpolymers
EP1464657A1 (de) *	2003-03-06	2004-10-06	ATOFINA Research	Hydrogenierter Metallocenkatalysator
DE602005010255D1 (de)	2004-07-08	2008-11-20	Exxonmobil Chem Patents Inc	Katalysator system für die olefinpolymerisation und verfahren zu seiner verwendung
KR100586922B1 (ko)	2004-11-18	2006-06-08	금호폴리켐 주식회사	고수율의 이피(디)엠의 제조방법 및 수율의 제어방법,이피(디)엠의 회수방법
US8143352B2 (en)	2006-12-20	2012-03-27	Exxonmobil Research And Engineering Company	Process for fluid phase in-line blending of polymers
US8242237B2 (en)	2006-12-20	2012-08-14	Exxonmobil Chemical Patents Inc.	Phase separator and monomer recycle for supercritical polymerization process
US8080610B2 (en)	2007-03-06	2011-12-20	Exxonmobil Research And Engineering Company	Monomer recycle process for fluid phase in-line blending of polymers
JP2010529253A (ja)	2007-06-04	2010-08-26	エクソンモービル・ケミカル・パテンツ・インク	非常に均一なプロピレンの溶液重合法
CN101855249B (zh)	2007-09-13	2013-02-13	埃克森美孚研究工程公司	在线生产增塑聚合物和增塑聚合物共混物的方法
US7910637B2 (en)	2007-09-13	2011-03-22	Exxonmobil Research And Engineering Company	In-line blending of plasticizers with a base polymer
US7910679B2 (en)	2007-12-20	2011-03-22	Exxonmobil Research And Engineering Company	Bulk homogeneous polymerization process for ethylene propylene copolymers
EP2231779B1 (de)	2007-12-20	2012-06-06	ExxonMobil Research and Engineering Company	In-line-verfahren zur herstellung von pelletstabilen polyolefinen
EP2231772B1 (de)	2007-12-20	2014-04-16	ExxonMobil Research and Engineering Company	Polypropylen-ethylen-propylen-copolymer-mischungen und in-line-verfahren zu deren herstellung
US8318875B2 (en)	2008-01-18	2012-11-27	Exxonmobil Chemical Patents Inc.	Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
KR101367402B1 (ko) *	2009-11-27	2014-02-25	주식회사 엘지화학	높은 디엔계 단량체 함량과 고분자량을 가지는 탄성 중합체의 제조방법
US8629292B2 (en)	2010-10-07	2014-01-14	Chevron Phillips Chemical Company Lp	Stereoselective synthesis of bridged metallocene complexes
US8637616B2 (en)	2010-10-07	2014-01-28	Chevron Philips Chemical Company Lp	Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects
US8609793B2 (en)	2010-10-07	2013-12-17	Chevron Phillips Chemical Company Lp	Catalyst systems containing a bridged metallocene
US10800865B2 (en)	2015-09-14	2020-10-13	Exxonmobil Chemical Patents Inc.	Process for making branched EPDM and the EPDM therefrom
US11041034B2 (en)	2018-02-09	2021-06-22	Exxonmobil Chemical Patents Inc.	Ethylene-a-olefin-diene elastomers and methods of making them
CN112334499B (zh)	2018-06-04	2023-03-24	埃克森美孚化学专利公司	具有si-si桥的茂金属
US11198747B2 (en)	2018-06-04	2021-12-14	Exxonmobil Chemical Patents Inc.	Catalyst systems including two hafnocene catalyst compounds
KR102603860B1 (ko) *	2022-08-09	2023-11-22	윤정식	패각분말을 고함량 포함하는 조성물 및 이를 이용한 마스터 배치

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CA1327673C (en) *	1988-06-16	1994-03-08	Sigmund Floyd	Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system
EP0552946B1 (de) *	1992-01-23	1997-04-16	Mitsui Petrochemical Industries, Ltd.	Ethylen/Alpha-Olefin/7-Methyl-1,6-Octadien Copolymerisat-Kautschuk und Zusammensetzungen desselben
CA2137777A1 (en) *	1992-06-18	1993-12-23	Maurizio Galimberti	Process for preparing an ethylenic copolymer
CA2125247C (en) *	1993-06-07	2001-02-20	Daisuke Fukuoka	Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
EP1209165B1 (de) *	1993-06-07	2006-04-19	Mitsui Chemicals, Inc.	Propylenelastomere
IT1271406B (it) *	1993-09-13	1997-05-28	Spherilene Srl	Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti
TW383313B (en) *	1994-12-20	2000-03-01	Mitsui Petrochemical Ind	Preparation of ethylene-alpha-olefin-nonconjugate polyene random copolymers, the copolymers obtaining which, and the use of the copolymers
TW383314B (en) *	1994-12-20	2000-03-01	Mitsui Petrochemical Ind	Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer
US5696213A (en) *	1995-04-21	1997-12-09	Exxon Chemical Patents Inc.	Ethylene-α-olefin-diolefin elastomers solution polymerization process
TW326450B (en) *	1995-06-28	1998-02-11	Mitsui Petroleum Chemicals Ind	Ethylene copolymer rubber, vulcanizable rubber composition containing the copolymer rubber, and process for preparing the same
IT1275777B1 (it) *	1995-07-06	1997-10-17	Enichem Spa	Catalizzatore metallocenico per la (co)polimerizzazione delle olefine

1996
- 1996-05-09 IT IT96MI000926A patent/IT1283630B1/it active IP Right Grant
1997
- 1997-04-30 CA CA002204177A patent/CA2204177C/en not_active Expired - Lifetime
- 1997-04-30 US US08/841,396 patent/US6124413A/en not_active Expired - Lifetime
- 1997-05-03 EP EP97201335A patent/EP0806436B1/de not_active Expired - Lifetime
- 1997-05-03 ES ES97201335T patent/ES2148895T3/es not_active Expired - Lifetime
- 1997-05-03 DE DE69702569T patent/DE69702569T2/de not_active Expired - Lifetime
- 1997-05-07 MX MX9703331A patent/MX9703331A/es not_active IP Right Cessation
- 1997-05-08 CN CN97111129A patent/CN1098869C/zh not_active Expired - Lifetime
- 1997-05-08 RU RU97107128/04A patent/RU2179561C2/ru active
- 1997-05-08 BR BR9703091A patent/BR9703091A/pt not_active IP Right Cessation
- 1997-05-08 KR KR1019970017639A patent/KR100257458B1/ko not_active IP Right Cessation
- 1997-05-09 JP JP11979797A patent/JP3986613B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
JP3986613B2 (ja)	2007-10-03
CN1098869C (zh)	2003-01-15
EP0806436B1 (de)	2000-07-19
MX9703331A (es)	1998-04-30
CA2204177C (en)	2006-06-20
IT1283630B1 (it)	1998-04-23
CA2204177A1 (en)	1997-11-09
JPH1067817A (ja)	1998-03-10
US6124413A (en)	2000-09-26
ITMI960926A1 (it)	1997-11-09
KR100257458B1 (ko)	2000-06-01
CN1172816A (zh)	1998-02-11
RU2179561C2 (ru)	2002-02-20
DE69702569T2 (de)	2001-03-15
EP0806436A1 (de)	1997-11-12
KR970074808A (ko)	1997-12-10
ES2148895T3 (es)	2000-10-16
BR9703091A (pt)	1998-09-08
ITMI960926A0 (de)	1996-05-09

Publication	Publication Date	Title
DE69702569D1 (de)	2000-08-24	Verfahren zur Herstellung von elastomerischen EP(D)M Copolymeren
DE69632293D1 (de)	2004-06-03	Verfahren zur Herstellung von Polysiloxan-Polycarbonat-Blockcopolymeren
DE69704964D1 (de)	2001-07-05	Verfahren zur Herstellung von Acryloxypropylsilane
DE69626710D1 (de)	2003-04-24	Verfahren zur Herstellung von Polysiloxanpolycarbonatblockcopolymeren
DE69521009D1 (de)	2001-06-28	Verbesserte Verfahren zur Herstellung von Polymere
DE69715578D1 (de)	2002-10-24	Verfahren zur Herstellung von Molekularsieben
DE69404257D1 (de)	1997-08-21	Verfahren zur Herstellung von alpha-Olefinpolymeren
DE69706234D1 (de)	2001-09-27	Verfahren zur Herstellung von vernetztem Polymer
DE69613770D1 (de)	2001-08-16	Verfahren zur Herstellung von Ethylen-Propylen-Copolymeren
DE69732199D1 (de)	2005-02-17	Verfahren zur Herstellung von Polyelektrolyten
DE69710130D1 (de)	2002-03-14	Verfahren zur Herstellung von Vinylpolymeren
DE69713022D1 (de)	2002-07-11	Verfahren zur Herstellung von Unterkleidung
DE59707913D1 (de)	2002-09-12	Kontinuierliches Verfahren zur Herstellung von gamma- Aminopropyltrialkoxysilanen
DE69736631D1 (de)	2006-10-19	Verfahren zur herstellung von olefinpolymeren
DE69622493D1 (de)	2002-08-29	Verfahren zur Herstellung von Polyarylenether-Siloxan-Copolymeren
DE69501524D1 (de)	1998-03-05	Verfahren zur Herstellung von Propylenblockcopolymeren
DE69709236D1 (de)	2002-01-31	Verfahren zur Herstellung von Ethylenpolymeren
DE69305323D1 (de)	1996-11-14	Verfahren zur Herstellung von Äthylen-Propylen-Blockcopolymeren
DE69510596D1 (de)	1999-08-12	Verfahren zur Herstellung von Organooxysilane
DE69712146D1 (de)	2002-05-29	Verfahren zur kontinuierlichem Herstellung von Silikongummizusammensetzung
DE69834718D1 (de)	2006-07-06	Verfahren zur herstellung von olefinpolymeren
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