DE3837125A1 - Process for the production of mouldings from metal and a thermoplastic - Google Patents
Process for the production of mouldings from metal and a thermoplasticInfo
- Publication number
- DE3837125A1 DE3837125A1 DE19883837125 DE3837125A DE3837125A1 DE 3837125 A1 DE3837125 A1 DE 3837125A1 DE 19883837125 DE19883837125 DE 19883837125 DE 3837125 A DE3837125 A DE 3837125A DE 3837125 A1 DE3837125 A1 DE 3837125A1
- Authority
- DE
- Germany
- Prior art keywords
- chips
- metal foil
- thermoplastic
- metal
- indicates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/0026—Recovery of plastics or other constituents of waste material containing plastics by agglomeration or compacting
- B29B17/0042—Recovery of plastics or other constituents of waste material containing plastics by agglomeration or compacting for shaping parts, e.g. multilayered parts with at least one layer containing regenerated plastic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/06—Recovery or working-up of waste materials of polymers without chemical reactions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/10—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products
- E04C2/16—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of fibres, chips, vegetable stems, or the like
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/10—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products
- E04C2/20—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of plastics
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/10—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products
- E04C2/20—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of plastics
- E04C2/22—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of plastics reinforced
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2705/00—Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2009/00—Layered products
- B29L2009/003—Layered products comprising a metal layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Sustainable Development (AREA)
- Mechanical Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
Description
Die Erfindung bezieht sich auf ein Verfahren zur Herstellung von Formkörpern aus Metall und einem thermoplastischen Kunst stoff.The invention relates to a method of manufacture of moldings made of metal and a thermoplastic art material.
Zahlreiche Artikel des täglichen Lebens bestehen aus Metall, andere bestehen aus thermoplastischem Kunststoff. Weitere Artikel bestehen aus thermoplastischem Kunststoff, der zu mindest einseitig und bereichsweise mit einer Metallfolie beschichtet oder in Verbund gebracht ist. Das gilt insbes. für Artikel der Verpackungsindustrie, die z. B. aus einem Kunststoffbehälterteil und einer Abdeckung aus Metallfolie bestehen. Bei der Herstellung dieser Artikel und nach deren Gebrauch entstehen Abfälle, die bisher, insbes. in bezug auf die Kunststoffkomponente, die Umwelt und Deponien belasten. Zwar ist es bekannt, bei der Herstellung von Kunststoffolien entstehende Besäumabfälle in eine Kunststoffschneckenpresse, einen sog. Extruder, zurückzuführen, um daraus erneut Kunst stoffolien herzustellen. Eine solche Rückführung ist jedoch bisher nicht durchgeführt worden, wo es sich um Kombinationen von thermoplastischem Kunststoff und Metallfolie handelt. Im übrigen fehlt ein einfaches Verfahren, welches es erlaubt, aus Metall und thermoplastischem Kunststoff, vorzugsweise aus entsprechenden Abfällen, Gegenstände eigener Art herzu stellen, die hohen Anforderungen in bezug auf Festigkeit, Stabilität und Korrosionsverhalten genügen.Many everyday items are made of metal, others are made of thermoplastic. Further Articles are made of thermoplastic plastic, which too at least on one side and in some areas with a metal foil is coated or combined. This applies in particular. for articles in the packaging industry, e.g. B. from one Plastic container part and a cover made of metal foil consist. In the manufacture of these articles and after Use waste that has so far, especially in relation to the plastic component, the environment and landfills. It is well known in the manufacture of plastic films trimmings generated in a plastic screw press, a so-called extruder, to make art out of it again to produce fabric films. However, such a return is So far it has not been carried out where there are combinations is about thermoplastic and metal foil. There is also no simple procedure that allows made of metal and thermoplastic, preferably from corresponding waste, objects of their own kind make high demands in terms of strength, Stability and corrosion behavior are sufficient.
Der Erfindung liegt die Aufgabe zugrunde, aus Metall und ther moplastischem Kunststoff Gegenstände eigener Art herzustellen, die z. B. in der Bauindustrie, in der Verpackungsindustrie, aber für andere Zwecke eingesetzt werden können. The invention has for its object from metal and ther to produce plastic materials of their own kind, the z. B. in the construction industry, in the packaging industry, but can be used for other purposes.
Zur Lösung dieser Aufgabe ist Gegenstand der Erfindung ein Verfahren zur Herstellung von Formkörpern aus Metall und ei nem thermoplastischen Kunststoff, welches dadurch gekennzeich net ist, daß Abfälle von Metallfolie und von thermoplasti schem Kunststoff zu Schnitzeln zerkleinert werden, daß die Schnitzel in eine Schneckenstrangpresse für das Aufschmelzen von thermoplastischem Kunststoff eingeführt und darin extru dierfähig aufbereitet werden und daß die Mischung aus dem aufgeschmolzenen Kunststoff und den Schnitzeln aus Metallfo lie mit Hilfe eines an die Schneckenstrangpresse angeschlos senen Strangpreßwerkzeuges kontinuierlich zu dem Formkörper geformt wird, der danach in Abschnitte abgelängt werden kann.The object of the invention is to achieve this object Process for the production of moldings from metal and egg nem thermoplastic, which is characterized by net is that waste of metal foil and thermoplastic chemical plastic shredded into chips that the Schnitzel in a screw extruder for melting of thermoplastic introduced and extru therein be prepared and that the mixture of the melted plastic and the chips from metal fo lie connected to the screw extruder with the help of a his extrusion tool continuously to the shaped body is formed, which can then be cut into sections.
In dieser Lehre zum technischen Handeln liegt eine Abstim mungsregel, und zwar dahingehend, das Mischungsverhältnis Metallfolie/Kunststoff so einzurichten, daß eine extrudier fähige Aufbereitung in einem Extruder möglich ist. Der Anteil an thermoplastischem Kunststoff darf nicht zu niedrig sein, kann aber andererseits praktisch beliebig hoch sein. Die Schnitzel sollen eine Kantenlänge von einigen mm, z. B. von 2 mm, aufweisen.There is a vote in this teaching on technical action rule, namely the mixing ratio Set up metal foil / plastic so that an extruded capable preparation in an extruder is possible. The amount thermoplastic must not be too low, on the other hand, it can be practically arbitrarily high. The Schnitzel should have an edge length of a few mm, e.g. B. from 2 mm.
Eine bevorzugte Ausführungsform der Erfindung ist dadurch gekennzeichnet, daß Abfälle, insbes. Besäumabfälle, von zu mindest einseitig und bereichsweise mit Metallfolie beschich teten Verpackungsbehältern und/oder Verpackungsmaterialien als Ausgangsmaterial eingesetzt werden. Insoweit nutzt die Erfindung die Tatsache, daß bei den Abfällen dieser Art die Verhältnisse so liegen, daß ohne weiteres eine extrudierfä hige Aufbereitung in einem Extruder möglich ist. Das ist über raschend. Hinzukommt, daß die Metallfoliebestandteile und die Kunststoffbestandteile bereits innig miteinander verei nigt sind. Das alles gilt insbes. dann, wenn mit Abfällen gearbeitet wird, die zu 80 bis 90 Gew.% aus Kunststoff, zu 10 bis 20 Gew.% aus Metallfolieschnitzel bestehen. Zu in qua litativer Hinsicht besonders guten Formkörpern gelangt man, wenn der Kunststoff aus Polyvinylchlorid besteht und die Me tallfolie aus einer Aluminiumlegierung. Im Rahmen der Erfin dung liegt es, den Schnitzeln zusätzlich Metallfolieschnitzel beizumischen. Im Rahmen der Erfindung liegt es fernerhin, den Schnitzeln zusätzlich feinteilige thermoplastische Kunst stoffe, beispielsweise Kunststoffolienschnitzel, beizumischen. Es versteht sich, daß man den Schnitzeln auch andere Füller beimischen kann. - Im Rahmen der Erfindung kann mit allen üblichen Schneckenstrangpressen gearbeitet werden. Vorzugs weise arbeitet man mit Doppelschneckenextrudern.A preferred embodiment of the invention is thereby characterized that waste, in particular trimming waste, from to Coat metal foil on at least one side and in some areas teten packaging containers and / or packaging materials be used as starting material. To that extent uses the Invention the fact that the waste of this type Ratios are such that an extrudable processing in an extruder is possible. That is about surprising. In addition, the metal foil components and the plastic components are already intimately united are nigt. All of this applies in particular when it comes to waste is worked, which is 80 to 90 wt.% Plastic, too 10 to 20% by weight consist of metal foil chips. Too in literally, particularly good moldings are obtained, if the plastic is made of polyvinyl chloride and the Me tall foil made of an aluminum alloy. As part of the Erfin It is appropriate to add a scrap of metal foil to the chips to mix. It is also within the scope of the invention the chips also fine-particle thermoplastic art Add substances such as shredded plastic wrap. It goes without saying that the fillets are also other fillers can mix. - Within the scope of the invention can with all usual screw extruders to be worked. Preferential wise one works with twin screw extruders.
Arbeitet man nach der Lehre der Erfindung, so kommt man zu Formkörpern, die sich in mechanischer Hinsicht besonders aus zeichnen. Der Metallbestandteil bildet in den Formkörpern eine Bewehrung und ein Skelett in einer Kunststoffmatrix, was den Formkörpern besondere Biegefestigkeit und Druckfestig keit, aber auch besondere Dauerfestigkeit, verleiht. Der Kunststoffbestandteil macht die Formteile darüber hinaus witterungsbeständig und in den meisten Umgebungen auch außer ordentlich korrosionsfest. Die hergestellten Formkörper kön nen daher für viele Verwendungszwecke in der Bauindustrie und in der Verpackungsindustrie, z. B. in Form von Wandplat ten oder Deckplatten für Wandplatten, Fußbodenplatten und Deckenplatten oder Deckplatten für Fußboden- und Deckenplat ten, Profilen, auch für die Herstellung von Transportpaletten, eingesetzt werden. Insbes. lassen sich beliebige Profile durch Strangpressen formen, z. B. auch Kantenschutzprofile, wie sie in der Verpackungsindustrie gebräuchlich sind.If one works according to the teaching of the invention, one comes to Shaped bodies that are particularly mechanical to draw. The metal component forms in the moldings a reinforcement and a skeleton in a plastic matrix, which gives the moldings particular flexural strength and compressive strength ability, but also special fatigue strength. The Plastic component also makes the molded parts weather-resistant and in most environments also outside neatly corrosion-resistant. The moldings produced can Therefore, for many uses in the construction industry and in the packaging industry, e.g. B. in the form of wall plate or cover plates for wall plates, floor plates and Ceiling plates or cover plates for floor and ceiling plate profiles, also for the production of transport pallets, be used. Esp. can be any profiles Form extrusion, e.g. B. also edge protection profiles, such as they are used in the packaging industry.
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19883837125 DE3837125A1 (en) | 1988-11-02 | 1988-11-02 | Process for the production of mouldings from metal and a thermoplastic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19883837125 DE3837125A1 (en) | 1988-11-02 | 1988-11-02 | Process for the production of mouldings from metal and a thermoplastic |
Publications (2)
Publication Number | Publication Date |
---|---|
DE3837125A1 true DE3837125A1 (en) | 1990-05-03 |
DE3837125C2 DE3837125C2 (en) | 1990-11-15 |
Family
ID=6366291
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19883837125 Granted DE3837125A1 (en) | 1988-11-02 | 1988-11-02 | Process for the production of mouldings from metal and a thermoplastic |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE3837125A1 (en) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3916938A1 (en) * | 1989-05-24 | 1990-11-29 | Gerhard Dingler | COMPONENT |
EP0487952A1 (en) * | 1990-11-14 | 1992-06-03 | Gerhard Dingler | Building element |
DE4102115A1 (en) * | 1991-01-25 | 1992-08-06 | Rolf Dipl Ing Schnause | Sheets which utilise domestic scrap - have two e.g. wood FRP or metal skins bonded to core made of two mutually incompatible thermoplastics mixed with non-thermoplastic particles |
DE4228409A1 (en) * | 1992-08-26 | 1994-03-03 | Messing Oliver | Plate for panelling, sepn. or support purposes - has with its core of waste material a cpd. comprising thin layered metal and plastic material. |
DE4231097A1 (en) * | 1992-09-17 | 1994-03-24 | Evd Gmbh | Process for producing a composite particle body and the body produced according to this |
EP0634258A1 (en) * | 1993-07-13 | 1995-01-18 | B.M.P. Holding B.V. | Method of producing material based on recycled plastic and the obtained material |
BE1007288A3 (en) * | 1993-07-13 | 1995-05-09 | Bmp Holding Bv | Method for manufacturing material from recycled synthetic matter and thematerial obtained |
WO1995020878A1 (en) * | 1994-02-01 | 1995-08-10 | Theodor Krall | Process for producing bactericidal/fungicidal plastic bodies |
DE4440760A1 (en) * | 1994-11-15 | 1996-05-23 | Rolf Koehnlein | Recycling used laminated fruit juice and milk containers |
ES2356543A1 (en) * | 2009-09-30 | 2011-04-11 | Sp Kloner Ecotec S.L. | Method for processing tetrabrik packaging waste to manufacture plastic pieces. (Machine-translation by Google Translate, not legally binding) |
ES2358694A1 (en) * | 2009-10-29 | 2011-05-13 | Sp Kloner Ecotec S.L. | Composite for the manufacture of structural elements based on thermoplastic polymers from recycled materials. (Machine-translation by Google Translate, not legally binding) |
US8075823B2 (en) | 1999-07-30 | 2011-12-13 | Guggenbichler J Peter | Process for preparing antimicrobial plastic bodies having improved long-time performance |
ES2738828A1 (en) * | 2018-07-24 | 2020-01-27 | Moratilla Jose Angel Luis | TRAFFIC SIGNS ELABORATED WITH ECOLOGICAL AND RENEWABLE MATERIALS (Machine-translation by Google Translate, not legally binding) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4217439C2 (en) * | 1992-05-26 | 1995-08-17 | Tesch G H | Sheet-like material containing sheet material and method for its production |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2402976A1 (en) * | 1974-01-22 | 1975-07-24 | Paturle Sa Ets | Structural compsn. based on recycled waste materials - containing low density polyethylene, and high proportion of inorganic-organic filler |
-
1988
- 1988-11-02 DE DE19883837125 patent/DE3837125A1/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2402976A1 (en) * | 1974-01-22 | 1975-07-24 | Paturle Sa Ets | Structural compsn. based on recycled waste materials - containing low density polyethylene, and high proportion of inorganic-organic filler |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4020124C2 (en) * | 1989-05-24 | 2000-03-02 | Gerhard Dingler | Use of a component as a formwork panel for concreting work |
DE4020124A1 (en) * | 1989-05-24 | 1992-01-02 | Gerhard Dingler | Construction elements esp. facing sheets for cast concrete - comprises plastic and metal strip bodies used such that heat conductivity value of element does not exceed predetermined value |
DE3916938A1 (en) * | 1989-05-24 | 1990-11-29 | Gerhard Dingler | COMPONENT |
EP0487952A1 (en) * | 1990-11-14 | 1992-06-03 | Gerhard Dingler | Building element |
DE4102115A1 (en) * | 1991-01-25 | 1992-08-06 | Rolf Dipl Ing Schnause | Sheets which utilise domestic scrap - have two e.g. wood FRP or metal skins bonded to core made of two mutually incompatible thermoplastics mixed with non-thermoplastic particles |
DE4228409A1 (en) * | 1992-08-26 | 1994-03-03 | Messing Oliver | Plate for panelling, sepn. or support purposes - has with its core of waste material a cpd. comprising thin layered metal and plastic material. |
DE4231097A1 (en) * | 1992-09-17 | 1994-03-24 | Evd Gmbh | Process for producing a composite particle body and the body produced according to this |
EP0634258A1 (en) * | 1993-07-13 | 1995-01-18 | B.M.P. Holding B.V. | Method of producing material based on recycled plastic and the obtained material |
BE1007288A3 (en) * | 1993-07-13 | 1995-05-09 | Bmp Holding Bv | Method for manufacturing material from recycled synthetic matter and thematerial obtained |
WO1995020878A1 (en) * | 1994-02-01 | 1995-08-10 | Theodor Krall | Process for producing bactericidal/fungicidal plastic bodies |
DE4440760A1 (en) * | 1994-11-15 | 1996-05-23 | Rolf Koehnlein | Recycling used laminated fruit juice and milk containers |
US8075823B2 (en) | 1999-07-30 | 2011-12-13 | Guggenbichler J Peter | Process for preparing antimicrobial plastic bodies having improved long-time performance |
ES2356543A1 (en) * | 2009-09-30 | 2011-04-11 | Sp Kloner Ecotec S.L. | Method for processing tetrabrik packaging waste to manufacture plastic pieces. (Machine-translation by Google Translate, not legally binding) |
ES2358694A1 (en) * | 2009-10-29 | 2011-05-13 | Sp Kloner Ecotec S.L. | Composite for the manufacture of structural elements based on thermoplastic polymers from recycled materials. (Machine-translation by Google Translate, not legally binding) |
ES2738828A1 (en) * | 2018-07-24 | 2020-01-27 | Moratilla Jose Angel Luis | TRAFFIC SIGNS ELABORATED WITH ECOLOGICAL AND RENEWABLE MATERIALS (Machine-translation by Google Translate, not legally binding) |
Also Published As
Publication number | Publication date |
---|---|
DE3837125C2 (en) | 1990-11-15 |
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Legal Events
Date | Code | Title | Description |
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OP8 | Request for examination as to paragraph 44 patent law | ||
D2 | Grant after examination | ||
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |