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DE3440534A1 - Process for coating plastics - Google Patents

Process for coating plastics

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Publication number
DE3440534A1
DE3440534A1 DE3440534A DE3440534A DE3440534A1 DE 3440534 A1 DE3440534 A1 DE 3440534A1 DE 3440534 A DE3440534 A DE 3440534A DE 3440534 A DE3440534 A DE 3440534A DE 3440534 A1 DE3440534 A1 DE 3440534A1
Authority
DE
Germany
Prior art keywords
polyacrylate
polyurethane
inq
aqueous dispersion
pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE3440534A
Other languages
German (de)
Inventor
Frank Clasen
Karl-Heinz Weinert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHEMULACK CHEMISCHE LACKFABRIK
Original Assignee
CHEMULACK CHEMISCHE LACKFABRIK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE3316550A priority Critical patent/DE3316550C2/en
Application filed by CHEMULACK CHEMISCHE LACKFABRIK filed Critical CHEMULACK CHEMISCHE LACKFABRIK
Priority to DE19843440537 priority patent/DE3440537A1/en
Priority to DE19843440535 priority patent/DE3440535A1/en
Priority to DE3440534A priority patent/DE3440534A1/en
Priority to AU50129/85A priority patent/AU5012985A/en
Priority to EP85905506A priority patent/EP0199785A1/en
Priority to PCT/DE1985/000431 priority patent/WO1986002655A1/en
Publication of DE3440534A1 publication Critical patent/DE3440534A1/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2433/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention relates to a process for coating plastics, in which, as primer, an aqueous dispersion is used which contains an aliphatic polyurethane containing reactive carboxyl groups, a polyacrylate, a pigment and optionally a curing agent. The invention comprises using, as coating to be applied to the primer coat, on the one hand an aqueous dispersion which likewise comprises an aliphatic polyurethane containing reactive carboxyl groups, a polyacrylate, optionally a pigment and optionally a curing agent, or which on the other hand, is a mixture of a hydroxyl-containing polymer as binder, an organic solvent, a pigment and a curing agent. Coatings of this type adhere well and do not attack the plastic under the primer coat by penetrating the latter.

Description

DIPL.-INQ. DIETER JANDER DR.- INQ. MAJN-FREP BONING _. /nr~ DIPL.-INQ. DIETER JANDER DR.- INQ. MAJN - FREP BONING _. / no ~

PATENTANWÄLTE J 4 H U 0 O HPATENT LAWYERS J 4 H U 0 O H

Beschreibung : "Verfahren zum Beschichten von Kunststoffen" Description : " Process for coating plastics "

Das Hauptpatent ... (Anmeldung P 33 16 550.5-43) bezieht sich auf ein Verfahren zum Beschichten von Kunststoffen, bei dem man als Grundierungsmittel' eine wässrige Dispersion verwendet, welche ein aliphatisches, reaktionsfähige Carboxylgruppen aufweisendes Polyurethan, ein Polyacrylat, ein Pigment und ggf. einen Härter enthält, wobei das Verhältnis von Polyurethan zu Polyacrylat zwischen 90 : 10 und 10 : 90, insbesondere zwischen 80 : 20 und 20 : 80, insbesondere zwischen 70 : 30 und 30 : 70, insbesondere zwischen 60 : 40 und 40 : 60, liegt.The main patent ... (Application P 33 16 550.5-43) relates to a method for coating plastics in which an aqueous dispersion containing an aliphatic, reactive carboxyl group is used as the primer Polyurethane, a polyacrylate, a pigment and optionally a hardener, the ratio of polyurethane to Polyacrylate between 90:10 and 10:90, in particular between 80:20 and 20:80, in particular between 70:30 and 30:70, in particular between 60:40 and 40:60.

Polyacrylat kann reaktionsfähige Carboxylgruppen aufweisen, aber auch frei von solchen reaktionsfähigen Carboxylgruppen sein (was nicht ausschließt, daß es geringe Mengen herstellungsbedingter Carboxylgruppen aufweist).Polyacrylate can have reactive carboxyl groups, but it can also be free from such reactive carboxyl groups (which does not exclude the fact that it has small amounts of production-related carboxyl groups).

Der vorliegenden Erfindung liegt die Aufgabe zugrunde, einen dazu geeigneten Überzug zu schaffen.The present invention is based on the object of providing a coating that is suitable for this purpose.

Diese Aufgabe wird erfindungsgemäß einerseits dadurch gelöst, daß als auf die Grundierung aufzutragender Überzug eine wässrige Dispersion verwendet wird, welche ein aliphatisches, reaktionsfähige Carboxylgruppen aufweisendes Polyurethan, ein reaktionsfähige Carboxylgruppen aufweisendes oder von solchen Carboxylgruppen freies Polyacrylat, ggf. ein Pigment und ggf. einen Härter enthält, wobei das Verhältnis von Polyurethan zu Polyacrylat zwischen 90 : 10 und 10 : 90, insbesondere zwischen 80 : 20 und 20 : 80, insbesondere zwischen 70 : 30 und 30 : 70, insbesondere zwischen 60 : 40 und 40 : 60, liegt.According to the invention, this object is achieved on the one hand in that an aqueous coating is used as the coating to be applied to the primer Dispersion is used, which is an aliphatic, reactive carboxyl-containing polyurethane, a reactive Polyacrylate containing carboxyl groups or free of such carboxyl groups, optionally a pigment and optionally contains a hardener, the ratio of polyurethane to polyacrylate between 90:10 and 10:90, in particular between 80:20 and 20:80, in particular between 70:30 and 30:70, in particular between 60:40 and 40:60.

Ein solcher Überzug haftet nicht nur gut, er greift ferner den Kunststoff (durch die Grundierung hindurch) nicht an und ist außerdem umweltfreundlich.Such a coating not only adheres well, it also does not attack the plastic (through the primer) and is also environmentally friendly.

. -- DIPL.-INQ. DIETER JANDER DR.-INQ. MANFRED BONINQ - . /OCO/. - DIPL.-INQ. DIETER JANDER DR.-INQ. MANFRED BONINQ -. / OCO /

PATtNTANWALFE WTHuOOH PATtNTANWALFE WTHuOOH

-Z--Z-

"Obige Aufgabe wird erfindungsgemäß andererseits dadurch gelöst, daß als auf die Grundierung aufzutragender Überzug eine Mischung verwendet wird, die ein hydroxylgruppenhaltiges Polymer als Bindemittel, insbesondere Polyacrylat und/oder Polyester, ein organisches Lösungsmittel, ggf. ein Pigment und einen Härter, insbesondere ein Isozyanat, enthält."On the other hand, the above object is achieved according to the invention by that a mixture is used as the coating to be applied to the primer, which contains a hydroxyl group-containing polymer as a binder, in particular polyacrylate and / or polyester, an organic solvent, possibly a pigment and a hardener, in particular an isocyanate.

Auch dieser Überzug haftet gut und greift durch die Grundierung hindurch den unter der Grundierung befindlichen Kunststoff nicht oder kaum an. " ■ ■This coating also adheres well and does not grip the plastic underneath the primer through the primer or hardly on. "■ ■

Beide Beschichtungen sind primär für die Auto-Industrie gedacht. Den sehr strengen Normen derselben genügen sie.Both coatings are primarily intended for the automotive industry. They meet the very strict standards of the same.

Weiterhin wird erfindungsgeraäß vorgeschlagen, daß als zu beschichtendes Kunststoffsubstrat Acrylnitril-Butadien-Styrol-Copolymere (ABS), Polyamid (PA), lackierfähiges Polyoxymethylen (POM), insbesondere Hostaform X 313, Polyurethan (PUR), Polyvinylchlorid (PVC), Kautschuk (EPDM), Polypropylen Kautschuk modifiziert (PP-EPDM), Vinylchlorid-Vinylacetat-Copolymere (PVCA), ungesättigte Polyester (UP), Epoxid (EP), vorbehandeltes, z.B. geflammtes Polyäthylen (PE) und Polypropylen (PP), Polyphenylenoxid (PPO), insbesondere Noryl 731-802, Polybutylenterephthalat (PBTP), GFK verwendet werden.Furthermore, it is proposed according to the invention that as the one to be coated Plastic substrate Acrylonitrile-butadiene-styrene copolymers (ABS), polyamide (PA), paintable polyoxymethylene (POM), in particular Hostaform X 313, polyurethane (PUR), polyvinyl chloride (PVC), rubber (EPDM), modified polypropylene rubber (PP-EPDM), vinyl chloride-vinyl acetate copolymers (PVCA), unsaturated polyester (UP), epoxy (EP), pretreated, e.g. flamed Polyethylene (PE) and polypropylene (PP), polyphenylene oxide (PPO), especially Noryl 731-802, polybutylene terephthalate (PBTP), GRP be used.

Als Polyurethane und Polyacrylate kommen all jene Stoffe in Frage, die in Wasser dispergiert (als Dispersion oder Hydrosol) sind, oberhalb von O C filmbildende Eigenschaften aufweisen und pigmentverträglich und lagerstabil sind.Polyurethanes and polyacrylates are all those substances that can be used which are dispersed in water (as a dispersion or hydrosol) have film-forming properties above O C and are compatible with pigments and have a long shelf life.

Zur Herstellung der zu verwendenden Grundierungsmittel und des Überzuges gemäß Anspruch 1 werden Polyurethan-Dispersionen eingesetzt, die bei einem Festkörpergehalt (Gew.-%) von 25 - 50 %, To produce the primer to be used and the coating according to claim 1, polyurethane dispersions are used which, with a solids content (% by weight) of 25-50 %,

DIPL.-INQ. DIETER JANDER DR.-INQ. MAMFREP BDNINQ PATENTANWÄLTEDIPL.-INQ. DIETER JANDER DR.-INQ. MAMFREP BDNINQ PATENT LAWYERS

vorzugsweise 35 - 40 #, eine Konsistenz von -<3000 mPas, vorzugsweise 100 - 500 mPas, aufweisen. Das Poryacrylai-Hydrosol hat bei einem Festkörperanteil in Gewichtsprozent von 30 - 60 %, vorzugsweise 45 - 50 %, eine Konsistenz von <1000 mPas, vorzugsweise <400 mPas.preferably 35-40 #, have a consistency of - <3000 mPas, preferably 100-500 mPas. The Poryacrylai hydrosol has a solid content in percent by weight of 30-60 %, preferably 45-50 %, a consistency of <1000 mPas, preferably <400 mPas.

Der Flüssigkeitsanteil in der Grundierung wie auch in dem Überzug gemäß Anspruch 1 braucht nicht nur aus Wasser zu bestehen, sondern er kann auch aus 75 - 99 Gew.-%, insbesondere 81 - 92 Ge\f.-%, Wasser und 25-1 Gev.-%, insbesondere 19-8 Gew.-^, organischen Lösungsmitteln und zugesetztem Neutralisationsmittel bestehen.The liquid content in the primer as well as in the coating according to claim 1 need not only consist of water, but it can also consist of 75-99% by weight , in particular 81-92% by weight, water and 25-1 Gev .-%, in particular 19-8 wt .- ^, consist of organic solvents and added neutralizing agent.

Die wässrige Dispersion kann mit und ohne Härtungsbeschleuniger verwendet werden.The aqueous dispersion can be used with or without a hardening accelerator.

Als Pigment können die sonst üblichen Pigmente eingesetzt werden. The otherwise customary pigments can be used as the pigment.

Natürlich können die Grundierung wie auch die überzüge zusätzlich Additive, wie Netzmittel, Verlaufmittel, usw., aufweisen.Of course, the primer as well as the coatings can additionally contain additives such as wetting agents, leveling agents, etc.

Die Erfindung bezieht sich auch auf die Stoffe gemäß den Ansprüchen .The invention also relates to the substances according to the claims .

Claims (9)

DIPL-INQ. DIETER JANDER DR.-INQ. MANFRED ßÖNINQDIPL-INQ. DIETER JANDER DR.-INQ. MANFRED ßÖNINQ PATENTANWÄLTEPATENT LAWYERS European Patent AttorneysEuropean patent attorneys KURFÜRSTENDAMM 66KURFÜRSTENDAMM 66 1 BERLIN 151 BERLIN 15 Telefon · 030/8 83 bO 71 /72Telephone 030/8 83 BO 71/72 Telegramme: Consideration BerlinTelegrams: Consideration Berlin 2. November 1984 887/19 531 DENovember 2, 1984 887/19 531 DE AnmeldungSign up der Firmaof the company CHEMULACK Chemische- und Lackfabrik GmbH. & Co.KG Goerzallee 303CHEMULACK Chemische- und Lackfabrik GmbH. & Co.KG Goerzallee 303 1000 Berlin 371000 Berlin 37 Ansprüche : Claims : 1. Verfahren zum Beschichten von Kunststoffen, bei dem man als Grundierungsmittel eine wässrige Dispersion verwendet, welche1. Process for coating plastics, in which one an aqueous dispersion is used as a primer, which a) ein aliphatisches, reaktionsfähige Carboxylgruppen aufweisendes Polyurethan
--. b) ein Polyacrylata) an aliphatic, reactive carboxyl group-containing polyurethane
-. b) a polyacrylate c) ein Pigment und ggf.c) a pigment and possibly d) einen Härterd) a hardener enthält, wobei das Verhältnis von Polyurethan zu Polyacrylat zwischen 90 : 10 und 10 : 90, insbesondere zwischen 80 : 20 und 20 : 80, insbesondere zwischen 70 : 30 und 30 : 70, insbesondere zwischen 60 : 40 und 40 : 60, liegt, nach Patent ... (Anmeldung P 33 16 550.5-43), dadurch gekennzeichnet, daß als auf die Grundierung aufzutragender Überzug ei-contains, the ratio of polyurethane to polyacrylate between 90:10 and 10:90, in particular between 80:20 and 20:80, in particular between 70:30 and 30:70, in particular between 60:40 and 40:60, according to patent ... (application P 33 16 550.5-43), characterized in that that a coating to be applied to the primer j^g wönryiviroTMcTioTieinTi ironuondp+· .ΐ«ί·ϊτ"Ή_ vreO /-Οίο I j ^ g wönryiviroTMcTioTieinTi ironuondp + · .ΐ «ί · ϊτ" Ή_ vreO / -Οίο I 01 10921 90001 10921 900 2 - r»2 - r » _ DIPL.-INQ. DIETER JANDER DR.-INQ. MANFRED BONINQ_ DIPL.-INQ. DIETER JANDER DR.-INQ. MANFRED BONINQ PATtNTANWAlTt 0 A 4 0 5 3PATtNTANWAlTt 0 A 4 0 5 3 e) ein aliphatisches, reaktionsfähige Carboxylgruppen aufweisendes Polyurethan e) an aliphatic, reactive polyurethane containing carboxyl groups f) ein reaktionsfähigejSarboxylgruppen aufweisendes oder von solchen Carboxylgruppen freies Polyacrylatf) a reactive sarboxyl group polyacrylate having or free of such carboxyl groups g) ggf· ein Pigment und h) ggf. einen Härterg) optionally · e i n pigment, and h) optionally a curing agent enthält, wobei das Verhältnis von Polyurethan zu Polyacrylat zwischen 90 ; 10 und 10 : 90, insbesondere zwischen 80 : und 20 : 80, insbesondere zwischen 70 : 30 und 30 : 70, insbesondere zwischen 60 : 40 und 40 : 60, liegt.contains, the ratio of polyurethane to polyacrylate between 90; 10 and 10:90, especially between 80: and 20:80, in particular between 70:30 and 30:70, in particular between 60:40 and 40:60. 2. Verfahren zum Beschichten von Kunststoffen, bei dem· man als Grundierungsmittel eine wässrige Dispersion verwendet, welche2. Process for coating plastics, in which · one an aqueous dispersion is used as a primer, which a) ein aliphatisches, reaktionsfähige Carboxylgruppen aufweisendes Polyurethan a) an aliphatic, reactive carboxyl group-containing polyurethane b) ein Polyacrylatb) a polyacrylate c) ein Pigment und ggf.c) a pigment and possibly d) einen Härterd) a hardener enthält, wobei das Verhältnis von Polyurethan zu Polyacrylat zwischen 90 : 10 und 10 : 90, insbesondere zwischen 80 : und 20 : 80, insbesondere zwischen 70 : 30 und 30 : 70, insbesondere zwischen 60 : 40 und 40 : 60, liegt, nach Patent (Anmeldung P 33 16 550.5-43), dadurch gekennzeichnet, daß als auf die Grundierung aufzutragender Überzug eine Mischung verwendet wird, diecontains, the ratio of polyurethane to polyacrylate between 90:10 and 10:90, in particular between 80: and 20:80, in particular between 70:30 and 30:70, in particular between 60:40 and 40:60, according to patent (application P 33 16 550.5-43), characterized in that that a mixture is used as the coating to be applied to the primer, which i) ein hydroxylgruppenhaltiges Polymer als Bindemittel, insbesondere Polyacrylat und/oder Polyester,i) a hydroxyl-containing polymer as a binder, in particular polyacrylate and / or polyester, DIPL.-INQ. DIETER JANDER DR.-INQ. MANFRED BDNINQDIPL.-INQ. DIETER JANDER DR.-INQ. MANFRED BDNINQ PATENTANWÄLTE J 4 4 U O O 4PATENT LAWYERS J 4 4 U O O 4 — 3 —- 3 - j) ein organisches Lösungsmittel k) ggf. ein Pigment und
1) einen Härter, insbesondere ein Isozyanat,j) an organic solvent k) optionally a pigment and
1) a hardener, especially an isocyanate, enthält.contains. 3. Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß als zu beschichtendes Kunststoffsubstrat Acrylnitril-Butadien-Styrol-Copolymere (ABS), Polyamid (PA), lackierfähiges Polyoxymethylen (POM), insbesondere Hostaform X 313, Polyurethan (PUR), Polyvinylchlorid (PVC), Kautschuk (EPEM), Polypropylen Kautschuk modifiziert (PP-EPDM), Vinylchlorid-Vinylacetat-Copolymere (PVCA), ungesättigte Polyester (UP), Epoxid (EP), vorbehandeltes, z.B. geflammtes Polyäthylen (PE) und Polypropylen (PP), Polyphenylenoxid (PPO), insbesondere Noryl 731-802, Polybutylenterephthalat (PBTP), GFK verwendet werden.3. The method according to claim 1 or 2, characterized in that the plastic substrate to be coated Acrylonitrile-butadiene-styrene copolymers (ABS), polyamide (PA), paintable polyoxymethylene (POM), especially Hostaform X 313, polyurethane (PUR), polyvinyl chloride (PVC), rubber (EPEM), modified polypropylene rubber (PP-EPDM), vinyl chloride-vinyl acetate copolymers (PVCA), unsaturated polyester (UP), epoxy (EP), pretreated, e.g. flamed polyethylene (PE) and polypropylene (PP), polyphenylene oxide (PPO), especially Noryl 731-802, polybutylene terephthalate (PBTP), GRP are used will. 4. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß man eine wässrige Dispersion verwendet, in der das Verhältnis von Polyurethan zu Polyacrylat 50 : 50 ist.4. The method according to claim 1, characterized in that that an aqueous dispersion is used in which the ratio of polyurethane to polyacrylate is 50:50. 5. Verfahren nach Anspruch 1 oder 4, dadurch gekennzeichnet, daß man eine wässrige Dispersion verwendet, die als Härter ein Alkylazeridin enthält.5. The method according to claim 1 or 4, characterized in that an aqueous dispersion is used, which contains an alkylaceridine as hardener. 6. Verfahren nach einem der Ansprüche 1, 4 oder 5, dadurch g e kennzeichnet, daß man eine wässrige Dispersion verwendet, in der der Festkörperanteil, bezogen auf die Mischung aus Festkörper und Wasser, 20 - 80 Gew.-%, insbesondere 35 70 Gew.-%, insbesondere 52 - 58 Gew.-<&, beträgt.6. The method according to any one of claims 1, 4 or 5, characterized in that an aqueous dispersion is used in which the solids content, based on the mixture of solids and water, 20-80 wt .-%, in particular 35 70 wt . -%, in particular 52-58% by weight <&. r r rr COWfCOWf DIPL.-INQ. DIETER JANDER DR.- INQ. MANkR-ED BONINQ _ , , ___ ,DIPL.-INQ. DIETER JANDER DR.- INQ. MANkR-ED BONINQ _,, ___, PATENT-ANWÄLTEPATENT LAWYERS 7. Verfahren nach einem der Ansprüche 1, 4 bis 6, dadurch gekennzeichnet, daß man eine wässrige Dispersion verwendet, in der der Anteil des Härters, bezogen auf den Festkörperanteil und Wasser, 0,5^:3—Gew.-%, insbesondere 2 Gew.-%, beträgt.7. The method according to any one of claims 1, 4 to 6, characterized in that an aqueous dispersion is used, in which the proportion of hardener, based on the solids content and water, 0.5 ^: 3 -% by weight, in particular 2% by weight, amounts to. 8. Verfahren nach einem der Ansprüche 1, 4 bis 7, dadurch gekennzeichnet, daß man eine wässrige Dispersion verwendet, die geringe Mengen eines organischen Lösungsmittels enthält.8. The method according to any one of claims 1, 4 to 7, characterized in that an aqueous dispersion is used, which contains small amounts of an organic solvent. 9. Verfahren nach einem der Ansprüche 1, 4 bis 8, dadurch g e kennze i chne t, daß man eine wässrige Dispersion verwendet, die zusätzlich einen Extender enthält, wobei dann der Festkörper aus 5-80 Gew.-%, insbesondere 50 Gew.-%, Pigment und Extender und 95 - 20 Gew.-?6, insbesondere 50 Gew.-#, Polyurethan und Polyacrylat besteht.9. The method according to any one of claims 1, 4 to 8, characterized g e identifier I do not think that an aqueous dispersion is used which also contains an extender, in which case the Solids from 5-80% by weight, in particular 50% by weight, pigment and extenders and 95-20 wt .-? 6, especially 50 wt .- #, polyurethane and polyacrylate. νιο-.1 νιο-. 1
DE3440534A 1983-05-03 1984-11-02 Process for coating plastics Ceased DE3440534A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE3316550A DE3316550C2 (en) 1983-05-03 1983-05-03 Process for priming plastics
DE19843440537 DE3440537A1 (en) 1983-05-03 1984-11-02 Process for coating plastic parts
DE19843440535 DE3440535A1 (en) 1983-05-03 1984-11-02 Process for priming plastics
DE3440534A DE3440534A1 (en) 1983-05-03 1984-11-02 Process for coating plastics
AU50129/85A AU5012985A (en) 1984-11-02 1985-10-25 Verfahren zum grundieren von kunststoffen
EP85905506A EP0199785A1 (en) 1984-11-02 1985-10-25 Process for providing plastics with a primer
PCT/DE1985/000431 WO1986002655A1 (en) 1984-11-02 1985-10-25 Process for providing plastics with a primer

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE3316550A DE3316550C2 (en) 1983-05-03 1983-05-03 Process for priming plastics
DE19843440537 DE3440537A1 (en) 1983-05-03 1984-11-02 Process for coating plastic parts
DE19843440535 DE3440535A1 (en) 1983-05-03 1984-11-02 Process for priming plastics
DE3440534A DE3440534A1 (en) 1983-05-03 1984-11-02 Process for coating plastics

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DE3440534A1 true DE3440534A1 (en) 1986-05-07

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DE3316550A Expired DE3316550C2 (en) 1983-05-03 1983-05-03 Process for priming plastics
DE3440534A Ceased DE3440534A1 (en) 1983-05-03 1984-11-02 Process for coating plastics
DE19843440535 Ceased DE3440535A1 (en) 1983-05-03 1984-11-02 Process for priming plastics
DE19843440537 Ceased DE3440537A1 (en) 1983-05-03 1984-11-02 Process for coating plastic parts

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DE19843440537 Ceased DE3440537A1 (en) 1983-05-03 1984-11-02 Process for coating plastic parts

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DE3744066A1 (en) * 1986-12-26 1988-07-07 Mitsui Petrochemical Ind MOLDED ITEMS FROM A THERMOPLASTIC ELASTOMER
US4880867A (en) * 1986-08-19 1989-11-14 501 Herberts Gesellschaft Mit Beschrankter Aqueous coating compositions, a process for their preparation and method of using the same
US6180181B1 (en) 1998-12-14 2001-01-30 Ppg Industries Ohio, Inc. Methods for forming composite coatings on substrates
CN104212321A (en) * 2014-07-31 2014-12-17 昆山市大地化工新技术开发有限公司 PU double-component multifunctional undercoat and preparation method thereof
WO2015057397A3 (en) * 2013-10-14 2015-07-16 Ticona Llc Coatings for polyoxymethylene polymer molded articles

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DE3316550C2 (en) * 1983-05-03 1985-07-25 Chemulack Chemische- Und Lackfabrik Gmbh & Co Kg, 1000 Berlin Process for priming plastics
EP0199785A1 (en) * 1984-11-02 1986-11-05 CHEMULACK CHEMISCHE-UND LACKFABRIK GMBH &amp; CO. KG Process for providing plastics with a primer
EP0350157B2 (en) * 1988-05-30 1997-12-17 Dainippon Ink And Chemicals, Inc. Aqueous coating composition
DE3844435C1 (en) * 1988-12-31 1990-08-23 Kurz, Geb. Sendtko, Waldtraud, 8011 Vaterstetten, De
ZA913801B (en) * 1990-05-21 1993-01-27 Dow Chemical Co Latent catalysts,cure-inhibited epoxy resin compositions and laminates prepared therefrom
US5916960A (en) * 1993-12-21 1999-06-29 The Sherwin-Williams Company Water-based, storage stable, self-curing coating composition
US6613830B2 (en) * 1999-01-29 2003-09-02 Michael J. Stevenson Aqueous base coating composition for polyolefin surfaces

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DE2551094A1 (en) * 1975-11-14 1977-05-26 Bayer Ag PROCESS FOR THE MANUFACTURING OF WATER DISPERSIBLE POLYURETHANES
US4278578A (en) * 1979-11-05 1981-07-14 Hillyard Enterprises, Inc. Coating composition for synthetic plastic substrates and methods for preparing and using same
US4301053A (en) * 1980-01-29 1981-11-17 General Electric Company Polyurethane resin coating composition
DE3316550C2 (en) * 1983-05-03 1985-07-25 Chemulack Chemische- Und Lackfabrik Gmbh & Co Kg, 1000 Berlin Process for priming plastics

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4880867A (en) * 1986-08-19 1989-11-14 501 Herberts Gesellschaft Mit Beschrankter Aqueous coating compositions, a process for their preparation and method of using the same
DE3744066A1 (en) * 1986-12-26 1988-07-07 Mitsui Petrochemical Ind MOLDED ITEMS FROM A THERMOPLASTIC ELASTOMER
US6180181B1 (en) 1998-12-14 2001-01-30 Ppg Industries Ohio, Inc. Methods for forming composite coatings on substrates
WO2015057397A3 (en) * 2013-10-14 2015-07-16 Ticona Llc Coatings for polyoxymethylene polymer molded articles
CN104212321A (en) * 2014-07-31 2014-12-17 昆山市大地化工新技术开发有限公司 PU double-component multifunctional undercoat and preparation method thereof

Also Published As

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DE3440537A1 (en) 1986-05-07
DE3440535A1 (en) 1986-05-07
DE3316550C2 (en) 1985-07-25
DE3316550A1 (en) 1984-11-08

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