DE102013218616A1 - Use of alkyl / alkenyl oligoglycoside derivatives for textile treatment - Google Patents

Abstract

Described is the use of alkyl and / or alkenyl oligoglycoside carboxylates, sulfates, phosphates and / or isethionates derived from alkyl and / or alkenyl oligoglycosides of general formula (I), RO- (G) p (I) meaning R C6-22 alkyl or C6-22 alkenyl, G glycoside unit derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, for textile treatment, in particular dyed textiles. The textiles treated with the compounds have improved color stability. The compounds can be incorporated in particular stable in liquid detergent.

Description

The invention relates to the technical field of textile treatment. In particular, the use of alkyl / alkenyl oligoglycoside derivatives in textile treatment agents, suitable agents and methods for treating textiles is described.

For cleaning textiles various surfactant-containing agents are known, which can remove soils of all kinds from the textile in an aqueous liquor. Surfactants serve as washing-active substances to increase the solubility in water, among other things of fat and dirt particles that adhere to the laundry. However, the performance of such agents on greasy soils is not always optimal, resulting in consumer dissatisfaction. It is a general effort to further optimize the cleaning performance of detergents, especially on greasy soiling.

Unfortunately, by textile treatments, especially by washes, also desirable parameters of the textile are changed. Targeted coloration is an important and desirable feature of dyed textiles. If dyed textiles are increasingly subjected to a textile treatment, in particular a cleaning with a detergent, the color fades and the textiles lose their fashionable appeal. Thus, there has been no lack of effort to improve the fabric treatment agents so that (in addition to maximizing detergency of a detergent) color fading of the fabric is minimized.

If dyes from a textile fiber z. As a laundry be removed and go into the fleet, it is possible that, for. B. in the presence of differently colored textiles in the laundry during the textile treatment, not only a color fading takes place, but in addition these textiles are discolored by the transferred into the fleet dyes. The color transfer of dyes in the fleet z. B. on the textiles of the laundry must therefore be prevented or at least minimized.

The person skilled in the art is aware of various dye transfer inhibitors, such as, for example, polymers or copolymers of N-vinylimidazole, which in particular lead to flocculation, precipitation or phase separation of the detergent in the formulation of liquid detergents. In particular, liquid detergents lack color transfer inhibiting agents that are sufficiently compatible with anionic surfactants.

The object of the present invention is to provide components for textile treatment agents, in particular for the treatment of dyed textiles, which optimize or restrict the color retention of textiles, in particular the decolorization of the textiles and the discoloration of the textiles as part of a textile treatment. If these components are incorporated in particular liquid preparations, the preparations should be stable on storage. If these components are incorporated in detergent, the detergent should have at least one equal or better cleaning performance, in particular primary washing power.

The objects are achieved according to the invention by using alkyl and / or alkenyl oligoglycoside carboxylates, sulfates, phosphates and / or isethionates which are derived from alkyl and / or alkenyl oligoglycosides of the general formula (I), RO- (G) _p (I) with the meaning
RC _6-22 alkyl or C _6-22 alkenyl,
G glycoside unit, which is derived from a sugar with 5 or 6 carbon atoms,
p number from 1 to 10.

It has been found according to the invention that the use of alkyl and / or alkenyl oligoglycoside carboxylates, sulfates, phosphates and / or isoethionates in textile treatment agents such as, for example, detergents or softeners results in improved color stability of dyed textiles. In particular, the fading of the textile dye and the discoloration of textiles is reduced to prevented. If said alkyl and / or alkenyl oligoglycosides are used in detergents, the cleaning performance of the detergent, in particular the primary washing power, is additionally improved. When used in liquid detergents, in particular liquid detergents, the storage stability of the composition is increased compared with conventional dye transfer inhibitors.

A first subject of the invention is therefore the use of alkyl and / or alkenyl oligoglycoside carboxylates, sulfates, phosphates and / or isethionates, which are derived from alkyl and / or alkenyl oligoglycosides of the general formula (I), RO- (G) _p (I) with the meaning
RC _6-22 alkyl or C _6-22 alkenyl, (preferably C _8-18 alkyl or C _8-18 alkenyl),
G glycoside unit, which is derived from a sugar with 5 or 6 carbon atoms,
p number from 1 to 10, preferably a number between 1 and 5.

in textile treatment, in particular dyed textiles.

Colored textiles are in particular textiles to be understood, which have been dyed by at least one organic and / or at least one inorganic dye, said dye (s) is / are on the material of the textile / and there to remain for a targeted coloring (s).

Under color stability according to the invention, the maintenance of an original coloration of a dyed textile after one or more textile treatments, in particular laundry and / or conditioning understood. The degree of color stability can be seen, especially after several textile treatments, to the naked eye by comparison with the original color or otherwise determined by device analysis by colorimetric measurement.

All amounts of a component of a mixture are, unless otherwise defined, wt .-% based on the total weight of the mixture containing this ingredient.

According to the invention, it is preferred to use alkyl oligoglycoside carboxylates, sulfates, phosphates and / or isethionates, particularly preferably alkyl oligoglycoside carboxylates or phosphates, in particular alkyl glycoside carboxylates.

In the alkyl and / or alkenyl oligoglycosides at least one hydroxyl group is preferably in at least one of the radicals G by -OC _1-12 -alkenyl-COOM, -OSO ₃ M, -OP (O) (OM) ₂ or -O- CH ₂ -CH ₂ -SO ₃ M, O-CH ₂ -CH ₂ -O-SO ₃ M, each with M = H, alkali metal or NH ₄ replaced. It is particularly preferred to use an alkyl oligoglycoside carboxylate in which -OC _1-12 -alkylene-COOM or -O (CH ₂ -) _n COOM with M = H, Na or K and n = 1 to 3, respectively. Particularly preferably, at least one OH group of the radical G according to formula (I) is replaced by a group -O-CH ₂ -COONa.

Particular preference is given to using an alkyl oligoglycoside carboxylate in which the alkyl radical is a lauryl radical. Especially preferred is a Laurylglucosidcarboxylat as a Plantapon ^® LGC and Plantapon ^® LGC Sorb by BASF SE is available.

In the alkyl glycosides of the general formula (I), the glycoside units G are preferably derived from aldoses or ketoses.

Preferably, because of the better reactivity, the reducing saccharides, the aldoses, are used. Among the aldoses, glucose is particularly suitable for their easy accessibility and technical availability. The alkyl glycosides used as starting materials are therefore the alkylglucosides.

The index p in the general formula (I) indicates the degree of oligomerization, i. H. The distribution of mono- and oligoglycosides and stands for a number between 1 and 10. While p in a given compound always has to be an integer and can take here especially the values p = 1 to 6, the value p for a particular alkyl glycoside an analytic calculated arithmetical variable, which usually represents a fractional number. Preferably, alkyl glycosides having an average degree of oligomerization p of from 1.1 to 3.0 are used. Particularly preferred are those alkyl glycosides whose degree of oligomerization is less than 1.5 and in particular between 1.1, and 1.4.

The alkyl radical R is derived from primary alcohols having 6 to 22, preferably 12 to 18 carbon atoms. Typical examples are caproic alcohol, caprylic alcohol, capric alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol and behenyl alcohol, as well as technical fractions which, in addition to those mentioned Saturated alcohols may also contain portions of unsaturated alcohols and are obtained on the basis of natural fats and oils, such as palm oil, palm kernel oil, coconut oil or beef tallow. The use of technical coconut oil is particularly preferred here.

In addition to the fatty alcohols mentioned, the alkyl glycosides can also be derived from synthetic primary alcohols having 6 to 22 carbon atoms, in particular the so-called oxo alcohols, which have a proportion of 5 to 40% by weight of branched isomers.

Particularly preferred alkyl radicals are those having 8/10, 12/14, 8 to 16, 12 to 16 or 16 to 18 carbon atoms. Mixtures of the alkyl radicals result in a production starting from natural fats and oils or mineral oils.

Processes for the preparation of these alkyl glycosides are described, for example, in the American patents US 3,547,828 and US 3,839,318 as well as the German patent application DE-A-37 23 826 described. For alkyl polyglycosides per se, for example, on the DE-A-100 27 975 . DE-A-101 38 094 and DE-A-100 31 014 to get expelled.

For a further discussion of the Alkyloligo / polyglycosides (APG) may be added WO 03/013450 to get expelled.

The alkyl or alkenyl oligoglycoside carboxylates, phosphates, sulfates or isethionates used according to the invention can be prepared by known processes. The carboxylates are prepared, for example, by reacting the alkyloligoglycosides with salts of chlorocarboxylic acids in the presence of bases. For example, it can be reacted with 2-chloroacetic acid sodium salt in the presence of NaOH. In the reaction, both the hydroxyl groups in the ring and the -CH ₂ -OH group can be reacted. The degree of conversion depends inter alia on the stoichiometry of the feedstock. Preferably, the alkyl oligoglycosides are reacted at least on the -CH ₂ -OH group, optionally with an agent capable of reacting one or more of the hydroxyl groups on the ring.

Other hydroxyl groups may also be etherified, for example.

The preparation of the isethionates is for example in the WO 94/26857 described. It also states that the products can be used for hair and body care. In particular, aqueous detergent mixtures are described which contain alkyloligoglycoside isethionates and, for example, further anionic surfactants.

The preparation of the sulfates is for example in the WO 93/10208 and WO 91/15192 described. The latter document also describes mixtures of APG sulfates with, inter alia, alkyl sulfates or alkyl ether sulfates and other ingredients. It is stated that the surfactant mixtures can be used in products that are used for washing, dyeing, rippling or rinsing hair.

The preparation of the sulfates can also as in EP-A-0 186 242 described described. For example, the corresponding alkyl glycoside can be reacted with gaseous sulfur trioxide or with sulfuric acid followed by neutralization.

Furthermore, on the DE-A-195 00 780 in which cosmetic and pharmaceutical preparations containing Alkyloligoglykosidsulfate are described.

In the DE-A-195 01 185 detergent mixtures of Alkyloligoglykosidsulfaten and alkyl ether phosphates are described, which can be used for example in hair rinses, hair dyes or Haarwellmitteln.

The alkyl and / or alkenyl oligoglycoside carboxylates, sulfates, phosphates and / or isoethionates used according to the invention are used in particular in textile treatment agents, in particular in combination with at least one additional surfactant. The textile treatment compositions used according to the invention are preferably solid textile detergents, liquid laundry detergents, liquid laundry detergents in a water-soluble coating, solid textile fabric softeners, liquid textile softeners. Particularly preferred are the aforementioned liquid embodiments of the textile treatment agent used in the invention.

The textile treatment agents contain at least one alkyl and / or alkenyl oligoglycoside carboxylate, sulfate, phosphate and / or isethionate, preferably in a total amount of from 0.1 to 15% by weight, particularly preferably from 0.2 to 10% by weight. %. In textile treatment compositions for conditioning textiles, preferably 0.1 to 2.0% by weight, particularly preferably 0.2 to 1.0% by weight, of the glycoside compounds are present. It is again preferred if said textile treatment agents for conditioning textiles anionic surfactants (ie, all anionic surfactants including said oligoglycoside compounds of the formula (I)) in a total amount of 0.1 to 2.0 wt .-%, particularly preferably 0 , 2 to 1.0 wt .-%, contained.

In detergents for textiles are preferably from 1.0 to 5.0 wt .-%, more preferably 2.0 to 4.0 wt .-%, of said glycoside compounds according to general formula (I) before. In the cleansing textile treatment agents, the glycoside compounds of the formula (I) used can completely or partially replace the customary anionic surfactants. Thus, the glycoside compounds can be used as the sole anionic surfactant in the agents, or it can be used mixtures with conventional other anionic surfactants. These conventional anionic surfactants are explained in more detail later. Preferably, further anionic surfactants and the glycoside compounds in a weight ratio in the range of 16 to 1 to 1 to 1, particularly preferably 4 to 1 to 2 to 1, contained in the inventive cleansing textile treatment agents.

In the textile treatment agents used according to the invention, in particular when replacing part or all of the conventional anionic surfactant with the glycoside compound of the formula (I) used according to the invention, increased color stability is determined after the textile treatment and subsequent examination of the dyeing.

The textile treatment agents described may advantageously additionally contain anionic and / or further nonionic surfactants for optimizing the cleaning performance.

Suitable anionic surfactants include, but are not limited to, alkylbenzenesulfonates, olefin sulfonates, alkanesulfonates, fatty alcohol sulfates, fatty alcohol ether sulfates or a mixture of two or more of these anionic surfactants. Of these anionic surfactants, alkylbenzenesulfonates, fatty alcohol ether sulfates and mixtures thereof are particularly preferred. Other suitable anionic surfactants are soaps, ie salts of fatty acids, especially the Na or K salts of C _12-18 fatty acids. Soaps can have a particularly advantageous effect on the cold washing performance.

Preferred surfactants of the sulfonate type are alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as are obtained, for example, from C _12-18 -monoolefins having terminal or internal double bonds by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acidic Hydrolysis of the sulfonation obtained. Also suitable are C _12-18 alkanesulfonates and the esters of α-sulfo fatty acids (ester sulfonates), for example the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.

in der R' und R'' unabhängig H oder Alkyl sind und zusammen 9 bis 19, vorzugsweise 9 bis 15 und insbesondere 9 bis 13 C-Atome enthalten. Ein ganz besonders bevorzugter Vertreter ist Natriumdodecylbenzylsulfonat.Alkylbenzenesulfonates are preferably selected from linear or branched alkylbenzenesulfonates of the formula

in which R 'and R "are independently H or alkyl and together contain 9 to 19, preferably 9 to 15 and in particular 9 to 13 C atoms. A most preferred representative is sodium dodecylbenzylsulfonate.

As alk (en) ylsulfate are the salts of sulfuric acid half esters of C ₁₂ -C ₁₈ fatty alcohols, for example from coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or C ₁₀ -C ₂₀ -oxo alcohols and those half esters secondary alcohols of these chain lengths are preferred. Of washing technology interest, the C ₁₂ -C ₁₆ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates and C ₁₄ -C ₁₅ alkyl sulfates are preferred. 2,3-alkyl sulfates are also suitable anionic surfactants. Also alkyl ether sulfates having the formula R ^{1 is} -O- (AO) _n -SO ₃ ^- X ⁺ are suitable. In this formula, R ^{1 is} a linear or branched, substituted or unsubstituted alkyl radical, preferably a linear, unsubstituted alkyl radical, more preferably a fatty alcohol radical. Preferred radicals R ¹ are selected from decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl radicals and mixtures thereof, where the representatives with even number of carbon atoms Atoms are preferred. Particularly preferred radicals R ¹ are derived from C ₁₂ -C ₁₈ fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or C ₁₀ -C ₂₀ oxo alcohols.

AO represents an ethylene oxide (EO) or propylene oxide (PO) moiety, preferably an ethylene oxide moiety. The index n stands for an integer from 1 to 50, preferably from 1 to 20 and especially from 2 to 10. Most preferably, n stands for the numbers 2, 3, 4, 5, 6, 7 or 8. X stands for a monovalent cation or the nth part of an n-valent cation, the alkali metal ions are preferred, and Na ⁺ or K ⁺ including Na, with Na ^{+ being} extremely preferred. Other cations X + may be selected from H ₃ N ⁺ CH ₂ CH ₂ OH, NH ₄ ^+, ½Zn ^{2 +,} ½Mg ^2+, ½Ca ^2+, ½Mn ^2+, and mixtures thereof.

mit k = 11 bis 19, n = 2, 3, 4, 5, 6, 7 oder 8. Ganz besonders bevorzugte Vertreter sind Na-C_12-14 Fettalkoholethersulfate mit 2 EO (k = 11–13, n = 2 in Formel A-1). Der angegebenen Ethoxylierungsgrad stellt einen statistischen Mittelwert dar, der für ein spezielles Produkt eine ganze oder eine gebrochene Zahl sein kann. Die angegebenen Alkoxylierungsgrade stellen statistische Mittelwerte dar, die für ein spezielles Produkt eine ganze oder eine gebrochene Zahl sein können. Bevorzugte Alkoxylate/Ethoxylate weisen eine eingeengte Homologenverteilung auf (narrow range ethoxylates, NRE).Particularly suitable textile treatment agents contain an alkyl ether sulfate selected from fatty alcohol ether sulfates of the formula

with k = 11 to 19, n = 2, 3, 4, 5, 6, 7 or 8. Very particularly preferred representatives are Na-C _12-14 fatty alcohol _ether sulfates with 2 EO (k = 11-13, n = 2 in formula A-1). The stated degree of ethoxylation represents a statistical average that may be an integer or a fractional number for a particular product. The indicated degrees of alkoxylation represent statistical averages, which may be an integer or a fractional number for a particular product. Preferred alkoxylates / ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE).

The anionic surfactants including the fatty acid soaps may be in the form of their sodium, potassium or magnesium or ammonium salts. Preferably, the anionic surfactants are in the form of their sodium salts and / or ammonium salts. Amines which can be used for the neutralization are preferably choline, triethylamine, monoethanolamine, diethanolamine, triethanolamine, methylethylamine or a mixture thereof, with monoethanolamine being preferred.

It is preferred according to the invention, when designed as a detergent textile treatment agent additional anionic surfactant in a total amount of 4.0 to 25.0 wt .-%, in particular from 5.0 to 20 wt .-%, included.

In various embodiments, the textile treatment agent used according to the invention further contains, in addition to the glycoside compound (s) used, at least one nonionic surfactant. Suitable nonionic surfactants include alkoxylated fatty alcohols, alkoxylated oxo alcohols, alkoxylated fatty acid alkyl esters, fatty acid amides, alkoxylated fatty acid amides, polyhydroxy fatty acid amides, alkylphenol polyglycol ethers, amine oxides, alkyl (poly) glucosides, and mixtures thereof.

Preferred textile treatment agents contain at least one fatty alcohol alkoxylate of the formula R ^{2 is} -O- (AO) _m -H, in the
R ^{2 is} a linear or branched, substituted or unsubstituted alkyl radical,
AO for an ethylene oxide (EO) or propylene oxide (PO) grouping,
m stands for integers from 1 to 50.

In the abovementioned formula, R ^{2 is} a linear or branched, substituted or unsubstituted alkyl radical, preferably a linear, unsubstituted alkyl radical, particularly preferably a fatty alcohol radical. Preferred radicals R ² are selected from decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, Eicosylresten and mixtures thereof, wherein the agent with an even number of C Atoms are preferred. Particularly preferred radicals R ² are derived from C ₁₂ -C ₁₈ -fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or C ₁₀ -C ₂₀ -oxo alcohols.

AO represents an ethylene oxide (EO) or propylene oxide (PO) moiety, preferably an ethylene oxide moiety. The subscript m is an integer from 1 to 50, preferably from 1 to 20 and especially from 2 to 10. Most preferably, m is the numbers 2, 3, 4, 5, 6, 7 or 8.

mit k = 11 bis 19, m = 2, 3, 4, 5, 6, 7 oder 8. Ganz besonders bevorzugte Vertreter sind C_12-18 Fettalkohole mit 7 EO (k = 11–17, m = 7 in Formel C-1).In summary, particularly preferred fatty alcohol alkoxylates are those of the formula

with k = 11 to 19, m = 2, 3, 4, 5, 6, 7 or 8. Very particularly preferred representatives are C _12-18 fatty alcohols with 7 EO (k = 11-17, m = 7 in formula C- 1).

It is preferred according to the invention if the textile treatment agents according to the invention (in particular detergents and conditioning agents) comprise nonionic surfactant in a total amount of 1.0 to 15.0% by weight, in particular 2.0 to 10.0% by weight.

• (A) Textilbehandlungsmittel, enthaltend – mindestens ein Alkyl- und/oder Alkenyl-Oligoglykosidcarboxylat, -sulfat, -phosphat und/oder -isethionat, das sich von Alkyl- und/oder Alkenyloligoglykosiden der allgemeinen Formel (I) ableitet, R-O-(G)_p (I) mit der Bedeutung R C_6-22-Alkyl oder C_6-22-Alkenyl, G Glykosideinheit, die sich von einem Zucker mit 5 oder 6 Kohlenstoffatomen ableitet, p Zahl von 1 bis 10, – mindestens ein zusätzliches anionisches Tensid, – mindestens ein nichtionisches Tensid.
• (B) Textilbehandlungsmittel, enthaltend – mindestens ein Alkyl- und/oder Alkenyl-Oligoglykosidcarboxylat, das sich von Alkyl- und/oder Alkenyloligoglykosiden der allgemeinen Formel (I) ableitet, R-O-(G)_p (I) mit der Bedeutung R C_6-22-Alkyl oder C_6-22-Alkenyl, G Glykosideinheit, die sich von einem Zucker mit 5 oder 6 Kohlenstoffatomen ableitet, p Zahl von 1 bis 10, – mindestens ein zusätzliches anionisches Tensid, – mindestens ein nichtionisches Tensid.
• (C) Textilbehandlungsmittel, enthaltend – mindestens ein Alkyl- und/oder Alkenyl-Oligoglykosidcarboxylat, -sulfat, -phosphat und/oder -isethionat, das sich von Alkyl- und/oder Alkenyloligoglykosiden der allgemeinen Formel (I) ableitet, R-O-(G)_p (I) mit der Bedeutung R C_6-22-Alkyl oder C_6-22-Alkenyl, G Glykosideinheit, die sich von einem Zucker mit 5 oder 6 Kohlenstoffatomen ableitet, p Zahl von 1 bis 10, – mindestens ein zusätzliches anionisches Tensid der Formel R¹-O-(CH₂CH₂O)_n-SO₃ ^– X⁺ worin R¹ für einen linearen oder verzweigten, substituierten oder unsubstituierten Alkylrest mit 10 bis 20 Kohlenstoffatomen steht, X für ein einwertiges Kation oder den n-ten Teil eines n-wertigen Kations steht und n = 2, 3, 4, 5, 6, 7 oder 8 ist, – mindestens ein nichtionisches Tensid der Formel
  
  mit k = 11 bis 19, m = 2, 3, 4, 5, 6, 7 oder 8.
• (D) Textilbehandlungsmittel, enthaltend – mindestens ein Alkyl- und/oder Alkenyl-Oligoglykosidcarboxylat, das sich von Alkyl- und/oder Alkenyloligoglykosiden der allgemeinen Formel (I) ableitet, R-O-(G)_p (I) mit der Bedeutung R C_6-22-Alkyl oder C_6-22-Alkenyl, G Glykosideinheit, die sich von einem Zucker mit 5 oder 6 Kohlenstoffatomen ableitet, p Zahl von 1 bis 10, – mindestens ein zusätzliches anionisches Tensid der Formel R¹-O-(CH₂CH₂O)_n-SO₃ ^– X⁺ worin R¹ für einen linearen oder verzweigten, substituierten oder unsubstituierten Alkylrest mit 10 bis 20 Kohlenstoffatomen steht, X für ein einwertiges Kation oder den n-ten Teil eines n-wertigen Kations steht und n = 2, 3, 4, 5, 6, 7 oder 8 ist, – mindestens ein nichtionisches Tensid der Formel
  
  mit k = 11 bis 19, m = 2, 3, 4, 5, 6, 7 oder 8.
• (E) Textilbehandlungsmittel, enthaltend – in einer Gesamtmenge von 0,1 bis 15,0 Gew.-% mindestens eines Alkyl- und/oder Alkenyl-Oligoglykosidcarboxylats, -sulfats, -phosphats und/oder -isethionats, das sich von Alkyl- und/oder Alkenyloligoglykosiden der allgemeinen Formel (I) ableitet, R-O-(G)_p (I) mit der Bedeutung R C_6-22-Alkyl oder C_6-22-Alkenyl, G Glykosideinheit, die sich von einem Zucker mit 5 oder 6 Kohlenstoffatomen ableitet, p Zahl von 1 bis 10, – in einer Gesamtmenge von 4,0 bis 20,0 Gew.-% mindestens eines zusätzlichen anionischen Tensids, – in einer Gesamtmenge von 1,0 bis 15,0 Gew.-% mindestens eines nichtionischen Tensids.
• (F) Textilbehandlungsmittel, enthaltend – in einer Gesamtmenge von 0,1 bis 15,0 Gew.-% mindestens eines Alkyl- und/oder Alkenyl-Oligoglykosidcarboxylats, -sulfats, -phosphats und/oder -isethionats, das sich von Alkyl- und/oder Alkenyloligoglykosiden der allgemeinen Formel (I) ableitet, R-O-(G)_p (I) mit der Bedeutung R C_6-22-Alkyl oder C_6-22-Alkenyl, G Glykosideinheit, die sich von einem Zucker mit 5 oder 6 Kohlenstoffatomen ableitet, p Zahl von 1 bis 10, – in einer Gesamtmenge 4,0 bis 20,0 Gew.-% mindestens eines zusätzlichen anionischen Tensids, – in einer Gesamtmenge 1,0 bis 15,0 Gew.-% mindestens eines nichtionischen Tensids.
• (G) Textilbehandlungsmittel, enthaltend – in einer Gesamtmenge von 0,1 bis 15,0 Gew.-% mindestens eines Alkyl- und/oder Alkenyl-Oligoglykosidcarboxylats, -sulfats, -phosphats und/oder -isethionats, das sich von Alkyl- und/oder Alkenyloligoglykosiden der allgemeinen Formel (I) ableitet, R-O-(G)_p (I) mit der Bedeutung R C_6-22-Alkyl oder C_6-22-Alkenyl, G Glykosideinheit, die sich von einem Zucker mit 5 oder 6 Kohlenstoffatomen ableitet, p Zahl von 1 bis 10, – in einer Gesamtmenge von 1,0 bis 10,0 Gew.-% mindestens eines zusätzlichen anionischen Tensids der Formel R¹-O-(CH₂CH₂O)_n-SO₃ ^– X⁺ worin R¹ für einen linearen oder verzweigten, substituierten oder unsubstituierten Alkylrest mit 10 bis 20 Kohlenstoffatomen steht, X für ein einwertiges Kation oder den n-ten Teil eines n-wertigen Kations steht und n = 2, 3, 4, 5, 6, 7 oder 8 ist, – in einer Gesamtmenge von 1,0 bis 15,0 Gew.-% mindestens eines nichtionischen Tensids der Formel
  
  mit k = 11 bis 19, m = 2, 3, 4, 5, 6, 7 oder 8.
• (H) Textilbehandlungsmittel, enthaltend – in einer Gesamtmenge von 0,1 bis 5,0 Gew.-% mindestens eines Alkyl- und/oder Alkenyl-Oligoglykosidcarboxylats, -sulfats, -phosphats und/oder -isethionats, das sich von Alkyl- und/oder Alkenyloligoglykosiden der allgemeinen Formel (I) ableitet, R-O-(G)_p (I) mit der Bedeutung R C_6-22-Alkyl oder C_6-22-Alkenyl, G Glykosideinheit, die sich von einem Zucker mit 5 oder 6 Kohlenstoffatomen ableitet, p Zahl von 1 bis 10, – in einer Gesamtmenge von 1,0 bis 10,0 Gew.-% mindestens eines zusätzlichen anionischen Tensids der Formel R¹-O-(CH₂CH₂O)_n-SO₃ ^– X⁺ worin R¹ für einen linearen oder verzweigten, substituierten oder unsubstituierten Alkylrest mit 10 bis 20 Kohlenstoffatomen steht, X für ein einwertiges Kation oder den n-ten Teil eines n-wertigen Kations steht und n = 2, 3, 4, 5, 6, 7 oder 8 ist, – in einer Gesamtmenge von 1,0 bis 15,0 Gew.-% mindestens eines nichtionischen Tensids der Formel
  
  mit k = 11 bis 19, m = 2, 3, 4, 5, 6, 7 oder 8.

It has proved to be particularly advantageous to use textile treatment agents according to one of embodiments (A) to (H) according to the invention:

• (A) textile treatment agent containing - at least one alkyl and / or alkenyl oligoglycoside carboxylate, sulfate, phosphate and / or isethionate derived from alkyl and / or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, - at least one additional anionic surfactant, - at least one nonionic surfactant.
• (B) textile treatment agent containing - at least one alkyl and / or alkenyl oligoglycoside carboxylate derived from alkyl and / or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, - at least one additional anionic surfactant, - at least one nonionic surfactant.
• (C) textile treatment composition containing - at least one alkyl and / or alkenyl oligoglycoside carboxylate, sulfate, phosphate and / or isethionate derived from alkyl and / or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit, which is derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, - at least one additional anionic surfactant of the formula R ^{1 is} -O- (CH ₂ CH ₂ O) _n -SO ₃ ^- X ⁺ wherein R ^{1 is} a linear or branched, substituted or unsubstituted alkyl radical having 10 to 20 carbon atoms, X is a monovalent cation or the n-th part of an n-valent cation and n = 2, 3, 4, 5, 6, Is 7 or 8, - At least one nonionic surfactant of the formula
  
  with k = 11 to 19, m = 2, 3, 4, 5, 6, 7 or 8.
• (D) textile treatment compositions containing - at least one alkyl and / or alkenyl oligoglycoside carboxylate derived from alkyl and / or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit, which is derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, - at least one additional anionic surfactant of the formula R ^{1 is} -O- (CH ₂ CH ₂ O) _n -SO ₃ ^- X ⁺ wherein R ^{1 is} a linear or branched, substituted or unsubstituted alkyl radical having 10 to 20 carbon atoms, X is a monovalent cation or the n-th part of an n-valent cation and n = 2, 3, 4, 5, 6, 7 or 8, - at least one nonionic surfactant of the formula
  
  with k = 11 to 19, m = 2, 3, 4, 5, 6, 7 or 8.
• (E) Textile treatment agent containing - in a total amount of 0.1 to 15.0 wt .-% of at least one alkyl and / or alkenyl Oligoglykosidcarboxylats, sulfate, phosphate and / or -isethionats, which is derived from alkyl and or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, - in a total amount from 4.0 to 20, 0 wt .-% of at least one additional anionic surfactant, - in a total amount of 1.0 to 15.0 wt .-% of at least one nonionic surfactant.
• (F) Textile treatment agent containing - in a total amount of 0.1 to 15.0 wt .-% of at least one alkyl and / or alkenyl oligoglycoside carboxylate, sulfate, phosphate and / or -isethionats, which is derived from alkyl and or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit, which is derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, - in a total amount 4.0 to 20.0 % By weight of at least one additional anionic surfactant, in a total amount of from 1.0 to 15.0% by weight of at least one nonionic surfactant.
• (G) Textile treatment agent containing - in a total amount of 0.1 to 15.0 wt .-% of at least one alkyl and / or alkenyl oligoglycoside carboxylate, sulfate, phosphate and / or -isethionats, of alkyl and or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, - in a total amount from 1.0 to 10, 0 wt .-% of at least one additional anionic surfactant of the formula R ^{1 is} -O- (CH ₂ CH ₂ O) _n -SO ₃ ^- X ⁺ wherein R ^{1 is} a linear or branched, substituted or unsubstituted alkyl radical having 10 to 20 carbon atoms, X is a monovalent cation or the n-th part of an n-valent cation and n = 2, 3, 4, 5, 6, 7 or 8, in a total amount of from 1.0 to 15.0% by weight of at least one nonionic surfactant of the formula
  
  with k = 11 to 19, m = 2, 3, 4, 5, 6, 7 or 8.
• (H) A fabric treatment composition comprising - in a total amount of from 0.1 to 5.0% by weight of at least one alkyl and / or alkenyl oligoglycoside carboxylate, sulfate, phosphate and / or isethionate derived from alkyl and / or isethionate or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, - in a total amount from 1.0 to 10, 0 wt .-% of at least one additional anionic surfactant of the formula R ^{1 is} -O- (CH ₂ CH ₂ O) _n -SO ₃ ^- X ⁺ wherein R ^{1 is} a linear or branched, substituted or unsubstituted alkyl radical having 10 to 20 carbon atoms, X is a monovalent cation or the n-th part of an n-valent cation and n = 2, 3, 4, 5, 6, 7 or 8, in a total amount of from 1.0 to 15.0% by weight of at least one nonionic surfactant of the formula
  
  with k = 11 to 19, m = 2, 3, 4, 5, 6, 7 or 8.

The aforementioned preferred embodiments of the respective parameters of the embodiments (A) to (H) are of course preferred according to the invention mutatis mutandis. In the embodiments (A) to (H), compounds of the general formula (I) are very particularly preferred, where in the general formula (I) the glycoside unit G is derived from aldoses or ketoses, in particular glucose, p is a number from 1 , 1 to 3.0 and R is a C _12-18 alkyl radical. In addition, it is additionally particularly preferred if at least one hydroxyl group in at least one of the glycoside units G is represented by -OC _1-12 -alkylene-COOM or -O- (CH ₂ -) _n COOM where M = H, Na or K and n = 1, 2 or 3, is replaced.

In addition, the textile treatment agent used according to the invention in general, and preferably its aforementioned preferred embodiments (in particular the embodiments (A) to (H)), contain further ingredients which further improve the performance and / or aesthetic properties of the textile treatment agent. In the context of the present invention, the textile treatment agent preferably additionally contains one or more substances from the group of enzymes, bleaching agents, Chelating agents, builders, electrolytes, nonaqueous solvents, pH adjusters, perfumes, perfume carriers, fluorescers, dyes, hydrotropes, foam inhibitors, silicone oils, antiredeposition agents, grayness inhibitors, anti-shrinkage agents, crease inhibitors, dye transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, Antistatic agents, bittering agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents, softening components and UV absorbers.

The textile treatment agent used according to the invention preferably contains at least one enzyme. In principle, all the enzymes established in the prior art for this purpose can be used in this regard. Preferably, it is one or more enzymes capable of exhibiting catalytic activity in a fabric treatment agent, in particular a protease, amylase, lipase, cellulase, hemicellulase, mannanase, pectin-cleaving enzyme, tannase, xylanase, xanthanase, β-glucosidase, carrageenase , Perhydrolase, oxidase, oxidoreductase and their mixtures. Preferred hydrolytic enzymes include in particular proteases, amylases, in particular α-amylases, cellulases, lipases, hemicellulases, in particular pectinases, mannanases, β-glucanases, and mixtures thereof. Proteases, amylases and / or lipases and mixtures thereof are particularly preferred, and proteases are particularly preferred. These enzymes are basically of natural origin; Starting from the natural molecules, improved variants are available for use in textile treatment agents, in particular detergents, which are preferably used accordingly.

The enzymes to be used may also be formulated together with accompanying substances, for example from the fermentation, or with stabilizers.

As a bleaching agent can serve all substances that destroy or absorb dyes by oxidation, reduction or adsorption and thereby discolor materials. These include, among others, hypohalite-containing bleach, hydrogen peroxide, perborate, percarbonate, peroxoacetic acid, diperoxoazelaic acid, diperoxododecanedioic acid, and oxidative enzyme systems. Suitable builders which may be present in the textile treatment agent used according to the invention are, in particular, silicates, aluminum silicates (in particular zeolites), carbonates, salts of organic di- and polycarboxylic acids and mixtures of these substances.

Organic builders which may be present in the textile treatment agent used according to the invention are, for example, the polycarboxylic acids which can be used in the form of their sodium salts, polycarboxylic acids meaning those carboxylic acids which carry more than one acid function. For example, these are citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, and mixtures of these. Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof.

As builders further polymeric polycarboxylates are suitable. These are, for example, the alkali metal salts of polyacrylic acid or polymethacrylic acid, for example, those having a molecular weight of 600 to 750,000 g / mol.

Suitable polymers are in particular polyacrylates, which preferably have a molecular weight of from 1,000 to 15,000 g / mol. Because of their superior solubility, the short-chain polyacrylates, which have relative weight-average molecular weights of from 1,000 to 10,000 g / mol, and more preferably from 1,000 to 5,000 g / mol, may again be preferred from this group. Also suitable are copolymeric polycarboxylates, in particular those of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid. To improve the water solubility, the polymers may also contain allylsulfonic acids, such as allyloxybenzenesulfonic acid and methallylsulfonic acid, as a monomer.

Soluble builders, such as citric acid, or acrylic polymers having a relative molecular weight (weight average) of from 1,000 to 5,000 g / mol are preferably used in liquid textile treatment compositions.

If the textile treatment agents according to the invention are liquid, they preferably contain water as the main solvent. It is preferred that the textile treatment agent contains more than 5 wt .-%, preferably more than 15 wt .-% and particularly preferably more than 25 wt .-%, each based on the total amount of fabric treatment agent, water. Particularly preferred liquid textile treatment agents contain - based on their weight - 5 to 90 wt .-%, preferably 10 to 85 wt .-%, especially preferably from 25 to 75% by weight and in particular from 35 to 65% by weight of water. Alternatively, the fabric treatment agents may be low to water anhydrous fabric treatment agents, wherein the water content in a preferred embodiment is less than 10 weight percent, and more preferably less than 8 weight percent, based on the total liquid fabric treatment agent ,

In addition, nonaqueous solvents may be added to the fabric treatment agent. Suitable non-aqueous solvents include mono- or polyhydric alcohols, alkanolamines or glycol ethers, provided that they are miscible with water in the specified concentration range. Preferably, the solvents are selected from ethanol, n-propanol, i-propanol, butanols, glycol, propanediol, butanediol, methylpropanediol, glycerol, diglycol, propyldiglycol, butyldiglycol, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether, Diethylene glycol ethyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol propyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, methoxytriglycol, ethoxytriglycol, butoxytriglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol t-butyl ether, di-n-octyl ether and mixtures thereof Solvent. However, it is preferred that the textile treatment agent contains an alcohol, in particular ethanol and / or glycerol, in amounts between 0.5 and 5 wt .-%, based on the total fabric treatment agent.

Softening components (hereinafter textile-softening compound) which can preferably be used in the textile treatment agents according to the invention are selected from at least one compound from the group formed from quaternary ammonium compounds, cationic polymers, polysiloxanes, fabric softening clays.

wobei in (Q1) R für einen acyclischen Alkylrest mit 12 bis 24 Kohlenstoffatomen, R¹ für einen gesättigten C₁-C₄ Alkyl- oder Hydroxyalkylrest steht, R² und R³ entweder gleich R oder R¹ sind oder für einen aromatischen Rest stehen. X^– steht entweder für ein Halogenid-, Methosulfat-, Methophosphat- oder Phosphation sowie Mischungen aus diesen. Beispiele für kationische Verbindungen der Formel (Q1) sind Monotalgtrimethylammoniumchlorid, Monostearyltrimethylammoniumchlorid, Didecyldimethylammoniumchlorid, Ditalgdimethylammoniumchlorid oder Dihexadecylammoniumchlorid.Suitable examples of quaternary ammonium compounds are shown, for example, in the formulas (Q1) and (Q2):

wherein in (Q1) R is an acyclic alkyl radical having 12 to 24 carbon atoms, R ^{1 is} a saturated C ₁ -C ₄ alkyl or hydroxyalkyl radical, R ² and R ^{3 are} either R or R ¹ or are an aromatic radical , X ^- is either a halide, methosulfate, methophosphate or phosphate ion and mixtures thereof. Examples of cationic compounds of the formula (Q1) are monotaltrimethylammonium chloride, monostearyltrimethylammonium chloride, didecyldimethylammonium chloride, ditallowdimethylammonium chloride or dihexadecylammonium chloride.

Compounds of formula (Q2) are so-called ester quats. Esterquats are characterized by excellent biodegradability. In formula (Q2), R ^{4 is} an aliphatic alk (en) yl radical having 11 to 21 carbon atoms with 0, 1, 2 or 3 double bonds and / or optionally with substituents; R ⁵ is H, OH or O (CO) R ⁷ , R ⁶ is, independently of R ^5, H, OH or O (CO) R ⁸ , where R ⁷ and R ⁸ are each independently an aliphatic alk (ene) ylrest having 11 to 21 carbon atoms with 0, 1, 2 or 3 double bonds. m, n and p can each independently be 1, 2 or 3. X ^- may be either a halide, methosulfate, methophosphate or phosphate ion as well as mixtures of these anions. Preference is given to compounds in which R ^{5 represents} the group O (CO) R ⁷ . Particular preference is given to compounds in which R ^{5 is} the group O (CO) R ⁷ and R ⁴ and R ^{7 are} alk (en) yl radicals having 15 to 17 carbon atoms. Particularly preferred are compounds in which R ^{6 is} also OH.

Compounds of the formula (Q2) are preferably used as fabric softening compounds in the textile treatment agents according to the invention. Preferred esterquats of the formula (Q2) as the softening component are methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium methosulfate, methyl N- (2-hydroxyethyl) -N, N-di ( palmacyloxyethyl) ammonium methosulfate, 1,2-bis [tallowacyloxy] -3-trimethylammonium propane chloride, N, N-dimethyl-N, N-di (tallowacyloxyethyl) ammonium methosulfate, N, N-dimethyl-N, N-di (tallowacyloxyethyl) ammonium chloride or methyl N, N-bis (stearoyloxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate.

If quaternized compounds of the formula (Q2) which have unsaturated alkyl chains are used, the acyl groups whose corresponding fatty acids have an iodine number between 1 and 100, preferably between 5 and 80, more preferably between 10 and 60 and in particular between 15 and 45, are preferred and having a cis / trans isomer ratio (in% by weight) of greater than 30:70, preferably greater than 50:50 and in particular equal to or greater than 60:40. Commercial examples are sold by Stepan under the tradename Stepantex ^® methylhydroxyalkyldialkoyloxyalkylammonium or those known under Dehyquart ^® Cognis products, known under Rewoquat ^® products of Evonik or those known under Tetranyl ^® products of Kao.

Instead of the ester group O (CO) R, where R is a long-chain alk (en) yl radical, it is possible to use softening compounds which have the following groups: RO (CO), N (CO) R or RN (CO), where of these groups, N (CO) R groups are preferred.

mit
R¹ = unabhängig von einander C₁-C₃₀-Alkyl, vorzugsweise C₁-C₄-Alkyl, insbesondere Methyl oder Ethyl,
n = 1 bis 5000, vorzugsweise 10 bis 2500, insbesondere 100 bis 1500.It is particularly preferred if at least one polysiloxane is used as a fabric softening compound, as these not only have a softening effect, but also enhance the perfume impression on the laundry. A preferably usable polysiloxane has at least the following structural unit

With
R ¹ = independently of one another C ₁ -C ₃₀ -alkyl, preferably C ₁ -C ₄ -alkyl, in particular methyl or ethyl,
n = 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.

mit
R¹ = C₁-C₃₀-Alkyl, vorzugsweise C₁-C₄-Alkyl, insbesondere Methyl oder Ethyl,
Y = ggf. substituiertes, lineares oder verzweigtes C₁-C₂₀-Alkylen, vorzugsweise -(CH₂)_m- mit m = 1 bis 16, vorzugsweise 1 bis 8, insbesondere 2 bis 4, im speziellen 3,
R², R³ = unabhängig voneinander H oder gegebenenfalls substituiertes, lineares oder verzweigtes C₁-C₃₀-Alkyl, vorzugsweise mit Aminogruppen substituiertes C₁-C₃₀-Alkyl, besonders bevorzugt -(CH₂)_b-NH₂ mit b = 1 bis 10, äußerst bevorzugt b = 2,
x = 1 bis 5000, vorzugsweise 10 bis 2500, insbesondere 100 bis 1500.It may be preferred that the polysiloxane additionally has the following structural unit:

With
R ¹ = C ₁ -C ₃₀ -alkyl, preferably C ₁ -C ₄ -alkyl, in particular methyl or ethyl,
Y = optionally substituted, linear or branched C ₁ -C ₂₀ -alkylene, preferably - (CH ₂ ) _m - where m = 1 to 16, preferably 1 to 8, in particular 2 to 4, in particular 3,
R ² , R ³ = independently of one another are H or optionally substituted, linear or branched C ₁ -C ₃₀ -alkyl, preferably C ₁ -C ₃₀ -alkyl substituted by amino groups, more preferably - (CH ₂ ) _b -NH ₂ where b = 1 to 10, most preferably b = 2,
x = 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.

If the polysiloxane has only the structural unit a) with R ¹ = methyl, it is a polydimethylsiloxane. Polydimethylpolysiloxanes are known as efficient fabric care compounds.

Suitable polydimethylsiloxanes include DC-200 (ex Dow Corning), Baysilone ^® M 50, Baysilone ^® M 100, Baysilone ^® M 350, Baysilone ^® M 500, Baysilone ^® M 1000, Baysilone ^® M 1500, Baysilone ^® M 2000 or Baysilone ^® M 5000 (all ex GE Bayer Silicones).

However, it may also be preferred that the polysiloxane contains the structural units a) and b). A particularly preferred polysiloxane has the following structure: (CH ₃ ) ₃ Si [O-Si (CH ₃ ) ₂ ] _n - [O-Si (CH ₃ ) {(CH ₂ ) ₃ -NH- (CH ₂ ) ₂ -NH ₂ }] _x -OSi ( CH ₃ ) ₃ where the sum n + x is a number between 2 and 10,000.

Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). The commercially available products Dow Corning ^® 7224, Dow Corning ^® 929 Cationic Emulsion or Formasil are also suitable, for example, 410 (GE Silicones). Furthermore, cationic polymers are also suitable fabric softening compounds. Some of these additionally have skin and / or textile-care properties. Suitable cationic polymers include in particular those described in "CTFA International Cosmetic Ingredient Dictionary", Fourth Edition, JM Nikitakis, et al, Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991 are described and summarized under the collective name "Polyquaternium".

• (J) Textilbehandlungsmittel, enthaltend – mindestens ein Alkyl- und/oder Alkenyl-Oligoglykosidcarboxylat, -sulfat, -phosphat und/oder -isethionat, das sich von Alkyl- und/oder Alkenyloligoglykosiden der allgemeinen Formel (I) ableitet, R-O-(G)_p (I) mit der Bedeutung R C_6-22-Alkyl oder C_6-22-Alkenyl, G Glykosideinheit, die sich von einem Zucker mit 5 oder 6 Kohlenstoffatomen ableitet, p Zahl von 1 bis 10, – mindestens eine quaternäre Ammoniumverbindung ausgewählt aus Formel (Q2)
  
  wobei R⁴ steht für einen aliphatischen Alk(en)ylrest mit 11 bis 21 Kohlenstoffatomen mit 0, 1, 2 oder 3 Doppelbindungen und/oder gegebenenfalls mit Substituente; R⁵ steht für H, OH oder O(CO)R⁷, R⁶ steht unabhängig von R⁵ für H, OH oder O(CO)R⁸, wobei R⁷ und R⁸ unabhängig voneinander jeweils für einen aliphatischen Alk(en)ylrest mit 11 bis 21 Kohlenstoffatomen mit 0, 1, 2 oder 3 Doppelbindungen steht, m, n und p haben unabhängig voneinander den Wert 1, 2 oder 3 X^– steht für ein Halogenid-, Methosulfat-, Methophosphat- oder Phosphation sowie Mischungen aus diesen Anionen sein.
• (K) Textilbehandlungsmittel, enthaltend – in einer Gesamtmenge von 0,1 bis 2,0 Gew.-% mindestens eines Alkyl- und/oder Alkenyl-Oligoglykosidcarboxylats, -sulfats, -phosphats und/oder -isethionats, das sich von Alkyl- und/oder Alkenyloligoglykosiden der allgemeinen Formel (I) ableitet, R-O-(G)_p (I) mit der Bedeutung R C_6-22-Alkyl oder C_6-22-Alkenyl, G Glykosideinheit, die sich von einem Zucker mit 5 oder 6 Kohlenstoffatomen ableitet, p Zahl von 1 bis 10, – in einer Gesamtmenge von 0,1 bis 2,0 Gew.-% mindestens einer quaternären Ammoniumverbindung ausgewählt aus Formel (Q2)
  
  wobei R⁴ steht für einen aliphatischen Alk(en)ylrest mit 11 bis 21 Kohlenstoffatomen mit 0, 1, 2 oder 3 Doppelbindungen und/oder gegebenenfalls mit Substituente; R⁵ steht für H, OH oder O(CO)R⁷, R⁶ steht unabhängig von R⁵ für H, OH oder O(CO)R⁸, wobei R⁷ und R⁸ unabhängig voneinander jeweils für einen aliphatischen Alk(en)ylrest mit 11 bis 21 Kohlenstoffatomen mit 0, 1, 2 oder 3 Doppelbindungen steht, m, n und p haben unabhängig voneinander den Wert 1, 2 oder 3 X^– steht für ein Halogenid-, Methosulfat-, Methophosphat- oder Phosphation sowie Mischungen aus diesen Anionen sein.
• (L) Textilbehandlungsmittel, enthaltend – in einer Gesamtmenge von 0,1 bis 1,0 Gew.-% mindestens eines Alkyl- und/oder Alkenyl-Oligoglykosidcarboxylats, -sulfats, -phosphats und/oder -isethionats, das sich von Alkyl- und/oder Alkenyloligoglykosiden der allgemeinen Formel (I) ableitet, R-O-(G)_p (I) mit der Bedeutung R C_6-22-Alkyl oder C_6-22-Alkenyl, G Glykosideinheit, die sich von einem Zucker mit 5 oder 6 Kohlenstoffatomen ableitet, p Zahl von 1 bis 10, – in einer Gesamtmenge von 0,1 bis 2,0 Gew.-% mindestens einer quaternären Ammoniumverbindung ausgewählt aus Formel (Q2)
  
  wobei R⁴ steht für einen aliphatischen Alk(en)ylrest mit 11 bis 21 Kohlenstoffatomen mit 0, 1, 2 oder 3 Doppelbindungen und/oder gegebenenfalls mit Substituente; R⁵ steht für H, OH oder O(CO)R⁷, R⁶ steht unabhängig von R⁵ für H, OH oder O(CO)R⁸, wobei R⁷ und R⁸ unabhängig voneinander jeweils für einen aliphatischen Alk(en)ylrest mit 11 bis 21 Kohlenstoffatomen mit 0, 1, 2 oder 3 Doppelbindungen steht, m, n und p haben unabhängig voneinander den Wert 1, 2 oder 3 X^– steht für ein Halogenid-, Methosulfat-, Methophosphat- oder Phosphation sowie Mischungen aus diesen Anionen sein.

A suitable fabric softening clay is, for example, a smectite clay. Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof. Montmorillonite clays are the preferred softening clays. Bentonites contain mainly montmorillonites and can serve as a preferred source of fabric softening clay.

• (J) textile treatment compositions containing - at least one alkyl and / or alkenyl oligoglycoside carboxylate, sulfate, phosphate and / or isethionate derived from alkyl and / or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, - at least one quaternary ammonium compound selected from formula (Q2)
  
  in which R ⁴ is an aliphatic alk (en) yl radical having 11 to 21 carbon atoms with 0, 1, 2 or 3 double bonds and / or optionally with substituents; R ⁵ is H, OH or O (CO) R ⁷ , R ⁶ is, independently of R ^5, H, OH or O (CO) R ⁸ , where R ⁷ and R ⁸ are each independently an aliphatic alk (ene) ylrest having 11 to 21 carbon atoms with 0, 1, 2 or 3 double bonds, m, n and p independently of one another have the value 1, 2 or 3 X ^- is a halide, methosulfate, methophosphate or phosphate ion and mixtures be these anions.
• (K) Textile treatment agent containing - in a total amount of 0.1 to 2.0 wt .-% of at least one alkyl and / or alkenyl oligoglycoside carboxylate, sulfate, phosphate and / or -isethionats, of alkyl and or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, - in a total amount of 0.1 to 2, 0% by weight of at least one quaternary ammonium compound selected from formula (Q2)
  
  wherein R ⁴ is an aliphatic alk (en) yl radical having 11 to 21 carbon atoms having 0, 1, 2 or 3 double bonds and / or optionally having substituents; R ⁵ is H, OH or O (CO) R ⁷ , R ⁶ is, independently of R ^5, H, OH or O (CO) R ⁸ , where R ⁷ and R ⁸ are each independently an aliphatic alk (ene) ylrest having 11 to 21 carbon atoms with 0, 1, 2 or 3 double bonds, m, n and p independently of one another have the value 1, 2 or 3 X ^- is a halide, methosulfate, methophosphate or phosphate ion and mixtures be these anions.
• (L) A fabric treatment composition comprising - in a total amount of from 0.1 to 1.0% by weight of at least one alkyl and / or alkenyl oligoglycoside carboxylate, sulfate, phosphate and / or isethionate derived from alkyl and or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, - in a total amount of 0.1 to 2, 0% by weight of at least one quaternary ammonium compound selected from formula (Q2)
  
  wherein R ⁴ is an aliphatic alk (en) yl radical having 11 to 21 carbon atoms having 0, 1, 2 or 3 double bonds and / or optionally having substituents; R ⁵ is H, OH or O (CO) R ⁷ , R ⁶ is, independently of R ^5, H, OH or O (CO) R ⁸ , where R ⁷ and R ⁸ are each independently an aliphatic alk (ene) ylrest having 11 to 21 carbon atoms with 0, 1, 2 or 3 double bonds, m, n and p independently of one another have the value 1, 2 or 3 X ^- is a halide, methosulfate, methophosphate or phosphate ion and mixtures be these anions.

The aforementioned preferred embodiments of the respective parameters of embodiments (J) to (L) are of course preferred according to the invention mutatis mutandis. In the embodiments (J) to (L), compounds of the general formula (I) are very particularly preferred, where in the general formula (I) the glycoside unit G is derived from aldoses or ketoses, in particular glucose, p is a number from 1 , 1 to 3.0, R is a C _12-18 alkyl radical. In addition, it is additionally particularly preferred if at least one hydroxyl group in at least one of the glycoside units G is represented by -OC _1-12 -alkylene-COOM or -O- (CH ₂ -) _n COOM where M = H, Na or K and n = 1, 2 or 3, is replaced.

A further subject of the invention is a process for textile treatment in which textiles, in particular dyed textiles, with at least one alkyl and / or alkenyl oligoglycoside compound as described in the first subject of the invention (in particular as a component of previously described textile treatment agent) is brought into contact with a textile.

Examples

The following liquid detergent formulation was prepared by mixing the components: E [% by weight] V [% by weight] C12-18 fatty alcohol with 7 units of ethylene oxide 4.0 4.0 C12-14 fatty alcohol ether sulfate sodium salt with 2 units of ethylene oxide 3.0 3.0 C12-18 fatty acid, Na salt 0.5 0.5 Sodium hydroxide, 50% 1.2 1.2 boric acid 0.5 0.5 Enzymes (amylase, cellulase) 1.5 1.5 Perfume 1.5 1.5 sodium chloride 1.5 1.5 ethanol 2.0 2.0 Sokalan HP 56 K * 0.1 0.1 Phosphonic acid, Na salt 0.5 0.5 citric acid 0.2 0.2 C _10-16 alkyl glycoside carboxymethyl ether, sodium salt 1.0 - water Ad 100 Ad 100 * Vinylimidazole vinylpyrrolidone copolymer (30% active in water, BASF SE)

Two identical loads of coloreds were produced with a wide variety of colors and each washload was washed with one of the liquid detergents 20 times at 40.degree. The color of the respective same laundry items from the laundry loads was compared. The color retention of the washing load washed with liquid detergent E was better than the color retention of the washing load washed with the liquid detergent V.

QUOTES INCLUDE IN THE DESCRIPTION

This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Cited patent literature

• US 3547828 [0023]
• US 3839318 [0023]
• DE 3723826 A [0023]
• DE 10027975 A [0023]
• DE 10138094 A [0023]
• DE 10031014 A [0023]
• WO 03/013450 [0024]
• WO 94/26857 [0027]
• WO 93/10208 [0028]
• WO 91/15192 [0028]
• EP 0186242 A [0029]
• DE 19500780 A [0030]
• DE 19501185 A [0031]

Cited non-patent literature

• "CTFA International Cosmetic Ingredient Dictionary", Fourth Edition, JM Nikitakis, et al, Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991 [0074]

Claims (11)

Use of alkyl and / or alkenyl oligoglycoside carboxylates, sulfates, phosphates and / or isethionates derived from alkyl and / or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit, which is derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, for textile treatment, in particular dyed textiles. Use according to claim 1, wherein said alkyl and / or alkenyl oligoglycoside compounds are used for the color stability of dyed textiles, in particular against discoloration and / or discoloration. Use according to claim 1 or 2, characterized in that in the alkyl and / or alkenyl oligoglycosides in at least one of the radicals G at least one hydroxyl group by -OC _1-12 alkenyl-COOM, -OSO ₃ M, -OP (O ) (OM) ₂ , -O-CH ₂ -CH ₂ -O-SO ₃ M, or -O-CH ₂ -CH ₂ -SO ₃ M is replaced with MH, alkali metal, NH ₄ . Use according to one of the preceding claims, characterized in that in the general formula (I) the glycoside unit G is derived from aldoses or ketoses, in particular glucose, p is a number from 1.1 to 3.0 and R is a C _{12- 18} alkyl. Use according to one of the preceding claims; characterized in that an alkyloligoglycoside carboxylate is used in which in at least one of the radicals G at least one hydroxyl group by -OC _1-12 -alkylene-COOM or -O- (CH ₂ -) COOM with M = H, Na or K and n = 1, 2 or 3, is replaced. Use according to any one of the preceding claims, characterized in that said alkyl and / or alkenyl oligoglycoside compounds are used together with at least one additional anionic surfactant. Use according to any one of the preceding claims, characterized in that said alkyl and / or alkenyl oligoglycoside compounds are used together with at least one nonionic surfactant. Use according to any one of the preceding claims, characterized in that said alkyl and / or alkenyl oligoglycoside compounds are additionally co-containing with one or more of enzymes, bleaches, chelants, builders, electrolytes, nonaqueous solvents, pH adjusters, perfumes, Perfume carriers, fluorescers, dyes, hydrotropes, foam inhibitors, silicone oils, antiredeposition agents, grayness inhibitors, anti-shrinkage agents, crease inhibitors, dye transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatics, bittering agents, ironing aids, repellents and impregnants, swelling and anti-slip agents , plasticizing components and UV absorbers. Textile treatment agent containing - at least one alkyl and / or alkenyl oligoglycoside carboxylate, sulfate, phosphate and / or isethionate derived from alkyl and / or alkenyl oligoglycosides of general formula (I), RO- (G) _p (I) with the meaning RC _6-22 -alkyl or C _6-22 -alkenyl, G glycoside unit derived from a sugar having 5 or 6 carbon atoms, p number from 1 to 10, - at least one additional anionic surfactant, - at least one nonionic surfactant. Textile treatment composition according to claim 8, characterized in that it contains said alkyl and / or alkenyl oligoglycoside compounds in a total amount of 0.1 to 15 wt .-%, 0.2 to 10 wt .-%. Process for textile treatment, characterized in that textiles, in particular dyed textiles, with at least one alkyl and / or alkenyl oligoglycoside compound as described in claims 1 to 5, in particular as a component in textile treatment agent according to one of claims 8 or 9, with a textile is brought into contact.