DE102005042053A1 - Zeolite and perfume containing particles with improved fragrance properties - Google Patents

Abstract

The z. The sometimes low stability of odoriferous substances in carrier particles generally limits the perfumer in his freedom to perfume carrier particles. In particular in connection with carrier particles containing zeolite, decomposition products often form from previously pleasantly scented fragrances, which can ruin the entire fragrance impression. The present invention now provides certain zeolite-containing carriers which can ensure improved perfume stability.

Description

The The present invention relates to zeolite and perfume containing particles which are phyllosilicate included, the ratio of zeolite which is present in a total amount of more than 20% by weight, but less than 70 wt .-%, based on the total particle contained is to, phyllosilicate is less than 7: 1. It also concerns the use of these particles, process for their preparation, and agents containing these particles.

at textile washing, Treatment and aftertreatment, it is common today, the detergents and post-treatment agents certain amounts of perfume zuzumischen, which serve the washing or rinsing eye itself, but also the with the washing or rinsing eye treated textile material to give a pleasant fragrance. The fragrance of washing or cleaning and post-treatment agents is next Color and appearance are an important aspect of the aesthetic product impression and an important point in the consumer decision for or against a particular product. For perfuming the perfume can either be incorporated directly into the funds or in an additional Step of washing or rinsing eye be supplied. The first way determines a specific product characteristic, in the case of second way, the consumer can be offered through different Fragrance variants about "his" fragrance individually decide, comparable to the choice of an Eau de Toilette or one Aftershave.

Perfume particles and methods for scenting washing and rinsing eyes are as such known in the art, usually carrier materials organic or inorganic nature, such. As starches, silicas, phosphates, Zeolites, alkali metal salts of polycarboxylic acids, cyclodextrins, etc. with Fragrances and other aids are brought together.

Corresponding need known perfume particles either additional Barrier layers, to the perfume on the carrier to fix, or are not alike for the scenting of detergents or cleaning products and for direct use as a sole fragrance, for example for the rinse cycle suitable in a washing machine.

One additional Problem have such fragrance particles, which as a carrier material Contain zeolite. It could be observed that with zeolite-containing Fragrance particles often stability problems in terms of perceivable fragrance impression arise, so that z. B. the odor characteristic a fragrance particle, especially after several weeks of storage changed significantly adversely, so that z. B. a first fragrant particles then smells rather evil. So it's about it to assume that at least individual components of a perfume composition, with which a ent speaking zeolite-containing particles is impregnated, during storage the particle of at least partial decomposition to the victim fall, why the original harmonic odor is lost.

There However, on the other hand, it is desirable in many applications, that perfume-containing particles also contain zeolite (the zeolites play a special role for example, in reducing the hardness of the water together with Polycarboxylates as substitutes for Phosphates in detergents), there is a need for improved zeolite and perfume containing particles.

The It is an object of the present invention to provide particles for disposal to make, which are characterized by the fact that they are indeed a larger amount contain zeolite, but still good fragrance stability even after several weeks Offer storage.

It has now surprisingly been found that this object is achieved by the subject matter of the present invention, namely a particle which comprises zeolite in a total amount of more than 20% by weight, but less than 70% by weight, based on the total particle, and perfume which is preferably absorbed in the particle and / or adsorbed on the particle, said particle also containing sheet silicates, provided that the ratio of zeolite to layered silicate relative to the total particle is less than 7: 1 , The Applicant could unexpectedly find that corresponding particles which combine zeolite and phyllosilicate in the appropriate proportions, lead to significantly improved fragrance stability even with storage for several weeks, whereas otherwise completely comparable particles, which, however, z. B. no ratio zeolite to layered silicate of less than 7: 1 or even no phyllosilicate contained, but z. B. the appropriate amount of additional Zeolite, led to greater problems in fragrance stability. Advantageously, the particles according to the invention also have very good powder properties, even at high perfume loading, ie they are readily flowable and do not agglomerate.

The particles according to the invention to lead advantageously to a more intensive fragrance experience with the consumer, For example, if you do laundry washed with a detergent formulation containing the particles of the invention includes. It is thus achieved a fragrance-enhancing effect, the The particles directly affects, as well as objects, in which these particles incorporated, for example, detergent formulations, as well as Things, such as B. Textiles, which with the objects (here: detergent formulation) be treated.

One Another advantage of the particles according to the invention is advantageously in that the resulting from the particles fragrance impression directly and indirectly longer holds up. "Immediate" in this context means that the particles according to the invention as such over a longer one Period smell. "Indirect" means in this Related to objects (eg, detergent formulation) containing the particles of the invention involve, longer smell, and that even when using these objects (eg, detergent formulation for Washing of textile) the things treated with it (here: washed Textile) longer smell.

It So is advantageously a fragrance-retarding effect (ie the temporal extent of the fragrance impression) both with reference to the Particles, such as on the particles containing objects, such as on the particles achieved with these objects.

• (a) Zweischichtsilikate, wie vorzugsweise Silikate der Kaolin- und/oder Serpentingruppe, wie insbesondere Kaolinit, Dickit, Halloysit, Antigorit, Lizardit und/oder Chryosotil
• (b) Dreischichtsilikate, wie vorzugsweise Pyrophyllit, Talk, Silikate der Glimmer-Gruppe wie z. B. Muskovit, der Smectit-Gruppe wie insbesondere Montmorillonit, Beidellit, Hectorit, Nontronit und/oder Saponit, der Hydroglimmer-Gruppe wie z. B. Illit, Seladonit und Glaukonit sowie Vermiculite und Chlorite, wie vorzugsweise Clinochlor, Chamosit und/oder Donbassit
• (c) Schichtsilikate mit Wechsellagerungsstrukturen, wie vorzugsweise die Muskovit-Montmorillonit-Mixed-Layer (auch Illit-Smectit-Mixed-Layer)
• (d) Tonminerale mit Faserstruktur wie vorzugsweise Sepiolith und/oder Palygorskit und/oder
• (e) nichtkristalline Silikate, wie z. B. Allophan und Imogolit.

The phyllosilicate to be used is, in a preferred embodiment, um

• (a) two-layer silicates, such as, preferably, silicates of the kaolin and / or serpentine group, in particular kaolinite, dickite, halloysite, antigorite, lizardite and / or chryosotile
• (B) three-layer silicates, such as preferably pyrophyllite, talc, silicas of the mica group such. As muscovite, the smectite group such as in particular montmorillonite, beidellite, hectorite, nontronite and / or saponite, the hydrogels group such. Illite, celadonite and glauconite as well as vermiculites and chlorites, such as preferably clinochlor, chamosite and / or donbassite
• (c) sheet silicates with alternating support structures, such as preferably the muscovite-montmorillonite mixed-layer (also illite-smectite-mixed-layer)
• (D) clay minerals with fiber structure such as preferably sepiolite and / or Palygorskit and / or
• (e) non-crystalline silicates, such as. Allophane and imogolite.

phyllosilicates one finds for example in clay, in which generally silicatic Particles prevail. Such clay minerals, such as. Kaolinite, Illite, montmorillonite, etc. are mainly due to weathering z. B. feldspars, emerged. Bentonites are certain clays, which are smectites, above all montmorillonite, containing as main minerals, being next to it For example, mica, illite and cristobalite are present as impurities could be. Bentonites are for the invention can be used with advantage, so that the particles according to a preferred embodiment Phyllosilicate in the form of clay, preferably of smectite-rich Clay, especially bentonite included.

It is known that the the properties of the clays, in particular the bentonites modified can be. It is Z. Possible, the swellability of crude bentonite by exchanging the Ca for Na ions (eg activated Calcium bentonite) increase. It is also z. Possible, the specific surface by treatment with inorganic acids (eg acid activated Bentonite). Likewise, it is possible the organophilia z. B. by reaction of sodium bentonite with quaternary Ammonium compounds (eg organophilic bentonites or bentones) to increase. For the purposes of this invention, the term "phyllosilicates", clay, bentonite, montmorillonite, hectorite, etc. also includes the corresponding derivatives or modified substances.

To a preferred embodiment contains the particle layered silicate in amounts of more than 5 wt .-%, preferably more than 10 wt .-%, advantageously more than 15 wt .-%, in further before geous way, more than 20 wt .-%, in a more advantageous manner more than 25% by weight, in particular in amounts of at least 30% by weight, based on the total particle. Phyllosilicate can also in still larger quantities be contained, for example in amounts of at least 40 wt .-% or at least 50 wt .-%.

However, it may also be desirable in the context of another embodiment to limit the content of phyllosilicate rather. According to such an embodiment, the particle contains less than 50% by weight, preferably less than 40% by weight, advantageously less than 35% by weight, more preferably less than 30% by weight, more preferably less than 25% by weight, even more preferably not more than 20% by weight % Phyllosilicate based on the total particle.

Very can be advantageous Phyllosilicate amounts of 5-20 Wt .-%, preferably from 5-10 Wt .-%, based on the total particle. This corresponds to one preferred embodiment.

With the term perfume are perfume oils, perfumes and fragrances meant. As perfume oils or fragrances can individual Fragrance compounds, eg. B. the synthetic products of the type the esters, ethers, aldehydes, ketones, alcohols and hydrocarbons be used. Fragrance compounds of the ester type are z. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, Linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethyl acetate, Benzyl acetate, ethyl methyl phenyl glycinate, allyl cyclohexyl propionate, Styrallyl propionate, benzyl salicylate, cyclohexyl salicylate, floramate, Melusat and Jasmecyclat. Ethers include, for example, benzyl ethyl ether and ambroxan, to the aldehydes e.g. B. the linear alkanals with 8-18 C atoms, Citral, citronellal, citronellyloxy-acetaldehyde, cyclamenaldehyde, Lilial and Bourgeonal, to the ketones z. As the Jonone, α-Isomethylionon and Methylcedrylketone, to the alcohols Anethol, Citronellol, Eugenol, Geraniol, linalool, phenylethyl alcohol and terpineol, to the hydrocarbons belong mainly the terpenes like limonene and pinene. However, mixtures are preferred different fragrances used, which together create an appealing Create a fragrance.

Such Perfume oils can also natural Contain fragrance mixtures, as they are accessible from plant sources, z. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable are Muscat sage oil, Chamomile oil, Clove oil, Balm oil, mint oil, Cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil, as well as Orange blossom oil, neroliol, Orange peel oil and sandalwood oil.

Around To be perceptible, one must Perfume volatile being, besides the nature of the functional groups and the structure the molecular weight of the chemical compound also plays an important role plays. So most perfumes have molecular weights up to about 200 Dalton, while Molar masses of 300 daltons and above constitute an exception. Due to the different volatility changed by fragrances the smell of a compound of several fragrances Par füms or perfume during Evaporation, whereby the odor impressions in "top note", "middle note" (middle note or body) and "base note" (end note or dry divided out). Because the smell perception to a large extent too on the smell intensity is based, the top note of a perfume or fragrance is not alone from volatile Connections while the base note for the most part from less volatile, i.e. adherent fragrances.

Tenacious Fragrances, in the context of the present invention advantageously can be used, for example, the essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, bergamot oil, Champacablütenöl, Edeltannöl, Edeltannenzapfenapfen, Elemiöl, eucalyptus oil, fennel oil, spruce alder oil, galbanum, geranium oil, ginger grass, guaiac wood, Gurjunbalsamöl, Helichrysumöl, Ho oil , Ginger oil, iris oil, cajeput oil, calamus oil, chamomile oil, camphor oil, kanaga oil, cardamom oil, cassia oil, pine oil, copaiba balsam, coriander oil, spearmint oil, caraway oil, cumin oil, lavender oil, lemongrass oil, lime oil, tangerine oil, lemon balm oil, musk kernel oil, myrrh oil, clove oil, neroli oil, niaouli oil , Olibanum Oil, Orange Oil, Origanum Oil, Palmarosa Oil, Patchouli Oil, Peru Balsam Oil, Petitgrain Oil, Pepper Oil, Peppermint Oil, Pimento Oil, Pine Oil, Rose Oil, Rosemary Oil, Sandalwood Oil, Celery Oil, Spik Oil, Star Aniseed Oil, Turpentine Oil, Thuja Oil, Thyme Oil, Verbena Oil, Vetiver Oil, Juniper Berry Oil, Vermouth Oil , Wintergreen oil , Ylang-ylang oil, hyssop oil, cinnamon oil, cinnamon leaf oil, citronella oil, lemon oil as well Cypress oil.

But the higher-boiling or solid fragrances of natural or synthetic origin can be used in the context of the present invention advantageously as adherent fragrances or fragrance mixtures, ie fragrances. These compounds include the following compounds and mixtures thereof: ambrettolide, α-amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, benzyl acetate, benzyl benzoate, benzyl formate, benzyl valerate, borneol , Bornyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, hydroquinone di-methyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, Iron , Isoeugenol, isoeugenol methyl ether, isosafrole, jasmone, camphor, karvakrol, karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, methyl n-amyl ketone, methyl anthranilate, p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-β-naphthyl ketone, methyl-n-nonylacetaldehyde, methyl n-nonyl ketone, muskon, β-naphthol ethyl ether, β-naphthol methyl ether, nerol, nitrobenzene, n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p- Oxy-acetophenone, pentadecanolide, β-phenylethyl alcohol, phenylacetaldehyde-di-methylacetal, phenylacetic acid, pulegone, safrole, isoamyl salicylate, methyl salicylate, hexyl salicylate, cyclohexyl salicylate, santalol, skatole, terpineol, thymine, thymol, γ-undelactone, vaniline, veratrumaldehyde, cinnamaldehyde, Cinnamyl alcohol, cinnamic acid, cinnamic acid ethyl ester, cinnamic acid benzyl ester.

To the more volatile Fragrances that are advantageous in the context of the present invention can be used count especially the lower-boiling fragrances natural or synthetic origin, used alone or in mixtures can be. examples for more volatile Fragrances are alkyl isothiocyanates (alkyl mustard oils), butanedione, limonene, linalool, Linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, Phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

All The above-mentioned fragrances are alone or in a mixture according to the present invention Invention can be used with the advantages already mentioned.

Of the Perfume stabilizing effect according to the invention relates essentially to the entire fragrance or fragrance collective.

Of the Perfume-stabilizing effect also relates in particular those fragrances or fragrances which are general in connection with stability problems of perfume on carrier materials, in particular zeolite, stand or be brought. Such rather problematic Fragrances are known to those skilled in the daily intuition.

Usually is it so that such Fragrances because of their instability not only in zeolite-containing Particles are incorporated. Here, the invention opens the expert an increased freedom in the use of its fragrances.

Such rather problematic scents concern in particular allyl alcohol esters, Esters of secondary alcohols, Ester tertiary Alcohols, allylic ketones, acetals, ketals, condensation products of amines and aldehydes and / or mixtures thereof. Especially these fragrances can, as far as they are part of a perfume composition containing a zeolite carrier be incorporated, lead to significant stability problems and so that whole Deface odor image or even completely ruin it.

allyl alcohol are the esters of allyl alcohol, which has the following structural feature has, C (OH) -C = C. examples for Allylalkohlester are in particular Allylamylglycolat, allylanthranilate, Allyl benzoate, allyl butyrate, allyl caprate, allyl caproate, allyl cinnamate, Allylcyclohexane acetate, allylcyclohexanebutyrate, allylcyclohexanepropionate, Allylheptoate, allylnonanoate, allylsalicylate, amylcinnamylacetate, Amyl cinnamyl formate, cinnamyl formates, cinnamyl acetates, cyclogalbanate, Geranyl acetate, geranyl acetoacetate, geranyl benzoate, geranyl cinnamate, Methallyl butyrate, methallyl caproate, neryl acetate, neryl butyrate, amyl cinnamyl formate, Alpha methyl cinnamyl acetate, methyl geranyl tiglate, mertenyl acetate, Farnesyl acetate, fenchyl acetate, geranyl anthranilate, geranyl butyrate, Gerany isobutyrate, geranyl caproate, geranyl caprylate, geranyl ethyl carbonate, Geranyl formate, geranyl furoate, geranyl heptoate, geranyl methoxyacetate, Geranyl pelargonate, geranyl phenylacetate, geranyl phthalate, geranyl propionate, Geranyl iso-propoxyacetate, geranyl valerate, geranyl iso-valerate, trans-2-hexenyl acetate, trans-2-hexenyl butyrate, trans-2-hexenyl caproate, trans-2-hexenylphenylacetate, trans-2-hexenylpropionate, trans-2-hexenyltiglate, trans-2-hexenyl valerate, beta-pentenyl acetate, alpha-phenylallyl acetate, Prenyl acetate, Trichloromethylphenylcarbinylacetat and / or their Mixtures. Allyl alcohol esters can to stability problems in zeolite-containing carriers to lead, which negatively affects the odor image of the entire perfume composition impact. With the agents according to the invention manages to create perfume compositions, which allyl alcohol esters include to stabilize better. The aforementioned Fragrances can preferably be contained in the particles according to the invention.

Examples of Esters of Secondary Alcohols (Secondary alcohols are present when two H atoms are substituted by organic radicals (R ¹ and R ² ) on the carbon atom bearing the OH group [general formulas: R ¹ -CH ( OH) -R ² ]) are in particular ortho-tert-amylcyclohexyl acetate, isoamylbenzylacetate, secondary n-amylbutyrate, amylvinylcarbinylacetate, amylvinylcarbinylpropionate, cyclohexylsalicylate, dihydro-nor-cyclopentadienylacetate, dihydro-nor-cyclopentadienylpropionate, isobornylacetate, isobornylsalicylate, isobornylvalerate, Frutene, 2 Methylbutene-2-ol-4-acetate, methylphenylcarbinylacetate, 2-methyl-3-phenylpropan-2-yl acetate, prenylacetate, 4-tert-butylcyclohexylacetate, verdox (2-tert-butylcyclohexylacetate), I vertenex (4- tert-butylcyclohexyl acetate), Violiff (carboxylic acid 4-cycloocten-1-yl methyl ester), ethenyl-iso-amyl carbinyl acetate, fenchyl acetate, fenchyl benzoate, fenchyl n-butyrate, fenchyl isobutyrate, levo-menthyl acetate, dl-menthyl acetate, menthyl anthranilate, menthyl benzoate, menthyl isobutyrate, menthyl formate, levo-menthyl phenylacetate, menthyl propionate, menthyl salicylate, menthyl iso-valerate, cyclohexyl acetates, cyclohexyl anthranilate , Cyclohexyl benzoate, cyclohexyl butyrate, cyclohexyl isobutyrate, cyclohexyl caproate, cyclohexyl cinnamate, cyclohexyl formate, cyclohexylheptoate, cyclohexyl oxalate, cyclohexyl pelargonate, cyclohexylphenylacetate, cyclohexylpropionate, cyclohexyl thioglycolate, cyclohexyl valerate, cyclohexyl iso-valerate, methylmylacetate, methylbenzylcarbinylacetate, methylbutylcyclohexanylacetate, 5-methyl-3 -butyl-tetrahydropyran-4-yl acetate, methyl citrate, methyl isophosphate, 2-methylcyclohexyl acetate, 4-methylcyclohexyl acetate, 4-methylcyclohexylmethylcarbinylacetate, methylethylbenzylcarbinylacetate, 2-methylheptanol-6-acetate, methylheptenylacetate, alpha-methyl-n-hexylcarbinylformate, methyl 2-methylbutyrate, methylnonylca rbinylacetate, methylphenylcarbinylacetate, methylphenylcarbinylanthranilate, methylphenylcarbinylbenzoate, methylphenylcarbinyl-n-butyrate, methylphenylcarbinylisobutyrate, methylphenylcarbinylcaproate, methylphenylcarbinylcaprylate, methylphenylcarbinyl cinnamate, methylphenylcarbinylformate, methylphenylcarbinylphenylacetate, methylphenylcarbinylpropionate, methylphenylcarbinylsalicylate, methylphenylcarbinyliso-valerate, 3-nonanylacetate, 3-nonenylacetate, Nonanediol 2,3-acetate, nonynol acetate, 2-octanyl acetate, 3-octanyl acetate, n-octyl acetate, sec-octyl-isobutyrate, beta-pentenyl acetate, alpha-phenylallyl acetate, phenylethylmethylcarbinyl iso-valerate, phenylethylene glycol diphenylacetate, Phenyl ethylethyl carbinyl acetate, phenyl glycol diacetate, sec-phenyl glycol monoacetate, phenyl glycol monobenzoate, isopropyl caprate, isopropyl caproate, isoporpyl caprylate, isopropyl cinnamate, para-isopropylcyclohexanyl acetate, propyl glycol diacetate, propylene glycol di-isobutyrate, propylene glycol dipropionate, isopropyl-n-hepto isopropyl n-hept-1-yne carbonate, isopropyl pelargonate, isopropyl propionate, isopropyl undecylenate, isopropyl n-valerate, isopropyl n-valerate, isopropyl iso-valerate, isopropyl sebacate, isopulegyl acetate, isopuleglyceoacetatoacetate, isopuleglyisobutyrate, isopulegylformate, thymylpropionate, alpha-2,4-trimethylcyclohexane methyl acetates, trimethylcyclohexyl acetate, vanillin triacetate, vanillylidene diacetate, vanillyl vanillate, and / or mixtures thereof. These esters can lead to stability problems in zeolite-containing carriers, which negatively affect the odor profile of the entire perfume composition. The compositions according to the invention make it possible to better stabilize perfume compositions comprising esters of secondary alcohols. The aforementioned fragrances may preferably be present in the particles according to the invention.

Preferred examples of esters of tertiary alcohols (tertiary alcohols are those in which three H atoms are substituted by organic radicals R ¹ , R ² , R ³ at the α-C atom which carries the OH group (general formula: R ¹ R ² R ³ C-OH)) are tertiary amyl acetate, Caryophylleneacetat, Cedrenylacetat, Cedrylacetat, Dihydromyrcenylacetat, Dihydroterpinylacetat, dimethylbenzyl carbinyl acetate, Dimethylbenzylcarbinylisobutyrat, Dimethylheptenylacetat, Dimethylheptenyl formate, Dimethylheptenylpropionat, Dimethylheptenyl iso-butyrate, Dimethylphenylethylcarbinylacetat, Dimethylphenylethylcarbinyl iso-butyrate Dimethylphenylethylcarbinyl iso-valerate, dihydro-nor-dicyclopentadienylacetate, dimethylbenzylcarbinylbutyrate, dimethylbenzylcarbinylformate, dimethylbenzylcarbinylpropionate, dimethylphenylethylcarbinyl-n-butyrate, dimethylphenyletylcarbinylformate, dimethylphenylethylcarbinylpropionate, elemylacetate, ethynylcyclohexylacetate, eudesylacetate, eugenylcinnamate, eugenylformate, iso-eu genyl formate, Eugenylphenylacetat, Isoeudehylphenylacetat, Guaiylacetat, Hydroxycitronellyl ethyl carbonate, Linallylacetat, Linallylanthranilat, Linallylbenzoat, Linallylbutyrat, Linallyl iosbutyrat, Linallylcarproat, Linallylcaprylat, Linallylcinnamat, Linallylcitronellat, Linallyl formate, Linallylheptoat, Linallyl-N-methyl anthranilate, Linallylmethyltiglat, Linallyl pelargonate, Linallylphenylacetat, Linallylpropionat , Linallyl pyruvate, linallyl salicylate, linallyl n-valerate, linallyl iso-valerate, methylcyclopentenolone butyrate, methylcyclopentenolone propionate, methylethylphenylcarbinylacetate, methylheptincarbonate, methylnicotinate, myrcenylacetates, myrcenylformate, myrcenylpropionate, cis-ocimenylacetate, phenylsalicylate, terpinylacetate, terpinylanthranilate, terpinylbenzoate, terpinyl-n- butyrate, terpinyl isobutyrate, terpinyl cinnamate, terpinyl formate, terpinyl phenylacetate, terpinyl propionate, terpinyl n-valerate, terpinyl iso-valerate, tributyl acetyl citrate, and / or mixtures thereof. These esters can lead to stability problems in zeolite-containing carriers, which negatively affect the odor profile of the entire perfume composition. The compositions according to the invention make it possible to better stabilize perfume compositions which comprise esters of tertiary alcohols. The aforementioned fragrances may preferably be present in the particles according to the invention.

Some esters with just such stability problems can be both esters of allylic and secondary or allylic and tertiary alcohols, in particular amylvinylcarbinyl acetate, amyl vinylcarbinylpropionate, hexylvinylcarbinylacetate, 3-nonenylacetate, 4-hydroxy-2-hexenylacetate, linallylanthranilate, linallylbenzoate, linallylbutyrate, linallyliosbutyrate, linallyl carproat, Linallylcaprylat, Linallylcinnamat, Linallylcitronellat, Linallylformat, Linallylheptoat, Linallyl N-methylanthranilate, Linallylmethyltiglat, Linallylpelargonat, Llinallylphenylacetat, Linallylpropionat, Linallylpyruvat, Linallylsalicylat, Linallyl-n-valerate, Linallyl-iso-valerate, myrtenol acetate, Nerolidylacetate, Nerolidylbutyrat, beta pentenyl acetate, alpha-phenylallyl acetate, and / or mixtures thereof. These esters can also lead to stability problems in zeolite-containing carriers, which have a negative effect on the odor profile of the entire perfume composition. With the means according to the invention succeed to better stabilize perfume compositions comprising these esters. The aforementioned fragrances may preferably be present in the particles according to the invention.

allylic Ketones are over following structural feature, C-C (= O) -C = C. Preferred examples are acetylfuran, allethrolone, allylionone, allylpulegone, amylcyclopentenone, Benzylideneacetone, benzylideneacetophenone, alpha-isomethyl-ionone, 4- (2,6,6-trimethyl-1-cyclohexene-1-yl) 3-buten-2-one, Beta damascone (1- (2,6,6-trimethylcyclohexen-1-yl) -2-buten-1-one), Damascenone (1- (2,6,6-trimethyl-1,3-cyclohexadien-1-yl) -2-buten-1-one), Delta Damascone (1- (2,6,6-trimethyl-3-cyclohexen-1-yl) -2-buten-1-one), alpha ionone (4- (2,6,6-trimethyl-1-cyclohexenyl-1-yl) -3-butene-2-one), beta ionone (4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -3-buten-2-one), Gamma methyl ionone, (4- (2,6,6-trimethyl-2-cyclohexyl-1-yl) -3-methyl-3-buten-2-one), Pulegone and / or mixtures thereof. Allylic ketones can too stability problems in zeolite-containing carriers to lead, which refers to the smell of the entire perfume composition affect negatively. With the compositions according to the invention, perfume compositions, which allylic ketones include better stabilizing. The aforementioned Fragrances can preferably be contained in the particles according to the invention.

Acetals are geminal diethers of the general formula R ¹ CH (OR ² ) (OR ³ ). Preferred examples are acetaldehyde-benzyl-beta-methoxyethyl acetal, acetaldehyde-di-iso-amyl acetal, acetaldehyde-di-pentanediol acetal, acetaldehyde-di-n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal , Acetaldehyde phenylethyl-n-propyl acetal, cinnamicaldehyde dimethyl acetal, acetaldehydebenzyl-beta-methoxyethyl acetal, acetaldehyde-di-iso amylacetal, acetaldehyde diethyl acetal, acetaldehyde-di-cis-3-hexenyl acetal, acetaldehyde di pentanediol acetal, acetaldehyde di-n -propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal, acetaldehyde, phenylethyl-n-propyl acetal, acetylindhyl dimethyl acetal, alpha-amyl cinnamic aldehyde-di-iso-propyl acetal, p-tert-amyl phenoxy acetaldehyde diethyl acetal, anisaldehyde diethyl acetal , Anisaldehyde dimethyl acetal, isoapiole., Benzaldehyde diethyl acetal, benzaldehyde di (ethylene glycol monobutyl ether) acetal, benzaldehyde dimethyl acetal, benzaldehyde ethylene glycol acetal, Be nzaldehydglyceryl acetal, Benzaldehydepropylenglycolacetal, Cinnamicaldehyddiethylacetal, Citraldiethyl acetal, citral dimethyl acetal, Citralpropyleneglycolacetal, alpha-Methylcinnamicaldehyd diethylacetal, alpha-Cinnamicaldehyddimethylacetal, phenylacetaldehyde 2,3-butyleneglycol acetal, Phenylacetaldehydcitronellylmethylacetal, Phenylacetaldehyddiallylacetal, Phenylacetaldehyddiamylacetal, Phenylacetaldehyddibenzylacetal, Phenylacetaldehyddibutylacetal, phenylacetaldehyde, Phenylacetaldehyddigeranylacetal, phenylacetaldehyde dimethylacetal, Phenylacetaldehydethyleneglycolacetal, Phenylacetaldglycerylacetal, citronellalcyclomonoglycol acetal, citronellaldiethylace tal, citronellaldimethylacetal, citronellaldiphenylethylacetal, geranoxyacetaldehyde diethyl acetal and / or mixtures thereof.

acetals can to stability problems in zeolite-containing carriers to lead, which refers to the smell of the entire perfume composition affect negatively. With the compositions according to the invention, perfume compositions, which acetals include, to stabilize better. The aforementioned fragrances can preferably in the particles of the invention be included.

Ketals are geminal diethers of the general formula R ¹ R ² C (OR ³ ) (OR ⁴ ). Preferred examples are acetone diethyl ketal, acetone dimethyl ketal, acetophenone diethyl ketal, methyl amyl catechol ketal, methyl butyl catechol ketal and / or mixtures thereof. Ketals can lead to stability problems in zeolite-containing carriers, which have a negative effect on the odor profile of the entire perfume composition. The compositions according to the invention make it possible to better stabilize perfume compositions comprising ketals. The aforementioned fragrances may preferably be present in the particles according to the invention.

preferred examples for Condensation products of amines and aldehydes are anisaldehyde methyl anthranilate, Aurantiol (hydroxycitronellalmethyl anthranilate), verdantiol (4-tert-butyl-alpha-methyldihydrocinnamaldehyde-methyl anthranilate), Vertosin (2,4-dimethyl-3-cyclohexene carbaldehyde), hydroxycitronellalane anthranilate, Hydroxycitronellallinallylanthranilate, methyl N- (4- (4-hydroxy-4-methylpentyl) -3-cyclohexenylmethylidenes) anthranilate, Methyl naphthyl ketone methyl anthranilate, methyl nonyl acetaldehyde methyl anthranilate, methyl N- (3,5,5-trimethylhexylidene) anthranilate, vanillin methyl anthranilate and / or mixtures thereof. Condensation products of amines and aldehydes can cause stability problems in zeolite-containing carriers to lead, which refers to the smell of the entire perfume composition affect negatively. With the compositions according to the invention, perfume compositions, which comprise condensation products of amines and aldehydes, better to stabilize. The aforementioned fragrances may preferably in the particles of the invention be included.

But advantageously, the perfume stability can not only in connection with such fragrance fen, which in zeolite-containing carriers have a clear predisposition to instability or are considered rather unstable (risk group), such. B. Allylamylglycolat and Cyclogalbanat, can be improved, but the perfume stability can also be further improved in connection with other fragrances. Such other fragrances are, without wishing to be limited by the following list, for. B. Adoxal (2,6,10-trimethyl-9-undecene-1-al), amyl acetate, anisaldehyde (4-methoxy-benzaldehydes), bacdanol (2-ethyl-4- (2,2,3-trimethyl-3 -cyclopenten-1-yl) -2-buten-1-ol), benzaldehyde, benzophenone, benzyl acetate, benzyl salicylate, 3-hexen-1-ol, cetalox (dodecahydro-3A, 6,6,9A-tetramethyl-naphtho [2,1B ] -furan), cis-3-hexenylacetate, cis-3-hexenylsalicylate, citronellol, coumarin, cyclohexyl salicylate, cymal (2-methyl-3- (para-isopropylphenyl) propionaldehyde), decyl aldehyde, ethyl vanillin, ethyl 2-methyl butyrate, ethylene brasylate , Eucalyptol, eugenol, exaltolide (cyclopentadecano lid), florhydral (3- (3-isopropylphenyl) butanal), galaxolide (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8 -hexamethylcyclopenta-gamma-2-benzopyran), gamma decalactone, gamma dodecalactone, geraniol, geranylnitrile, helional (alpha-methyl-3,4, (methylenedioxy) hydrocinnamaldehyde), heliotropin, hexylacetate, hexylcinnamaldehyde, hexylsalicylate, hydroxyambrane (2-cyclododecyl) propanol), hydroxycitronellal, iso E super (7-acetyl-1,2,3,4,5,6,7,8-octahyd ro-1,1,6,7, tetramethylnaphthalene), isoeugenol, isojasmon, koavon (acetyl di-isoamylene), lauryl aldehyde, Irg 201 (2,4-dihydroxy-3,6-dimethyl benzoic acid, methyl ester), Lyral (4 - (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde), Majantol (2,2-dimethyl-3- (3-methylphenyl) -propanol), mayorol (4- (1-methylethyl) cyclohexanemethanol ), Methyl anthranilate, methyl beta naphthyl ketoe, methyl cedryl (methyl cedryl ketone), methyl chavicol (1-methyloxy-4,2-propene-1-yl benzene), methyl dihydrojasmonate, methyl nonyl acetaldehyde, musk indanone (4-acetyl-6-tert. butyl-1,1-dimethylindane), nerol, nonalactone (4-hydroxynonanoic acid, lactone), norlimbanol (1- (2,2,6-trimethylcyclohexyl) -3-hexanol), PT Bucinal (2-methyl-3 (para tert-butylphenyl) propionaldehyde), para-hydroxyphenylbutanone, patchouli, phenylacetaldehyde, phenylethylacetate, phenylethylalcohol, phenylethylphenylacetate, phenylhexanol / phenoxanol (3-methyl-5-phenylpentanol), polysantol (3,3-dimethyl-5- (2,2,3 -timethyl-3-cyclopenten-1-yl) -4-penten-2-ol), rosaphene (2-methyl-5-phenylpentanol), sandalwood, alpha-terpinene, tartalide / musk plus (7-acetyl-1, 1,3,4,4,6-hexamethyltetralin), undecalactone, undecabertol (4-methyl-3-decen-5-ol), undecylaldehyde, undecenealdehydes, vanillin and / or mixtures thereof. The aforementioned fragrances may preferably be present in the particles according to the invention.

If the perfume, which is preferably ad / absorbed in / on the particle, at least 4, advantageously at least 5, in a further advantageous manner at least 6, more preferably at least 7, in even more preferably at least 8, preferably at least 9, contains in particular at least 10 different fragrances, so is a preferred embodiment of the invention.

in the For the purposes of this invention, particularly preferred fragrances are soft can be used with advantage are in particular dihydromyrcenol, 4-tert-butylcyclohexyl acetate, Tetrahydrolinalool, methyl palmitate, methyl myristate, methyl oleate, 6-methyl-gamma-ionone, isobornyl acetate, tartalide and / or dihydromethyl-jasmonate, but especially dihydromyrcenol and / or 4-tert-butylcyclohexyl acetate. Preferred particles can after a preferred embodiment consequently comprise at least one of the aforementioned fragrances.

If he wishes, can the perfume also with a perfume fixative be combined. It is assumed that perfume fixative the exhalation of the higher volatile Proportions of perfumes can slow down.

According to one another preferred embodiment includes the perfume, which in / on the carrier material from / adsorbed, a perfume fixative, preferably in the form of diethyl phthalates, musk (derivatives) and mixtures thereof, wherein the fixative preferably 1 to 55 wt .-%, advantageously 2 to 50 wt .-%, even more advantageous 10 to 45 wt .-%, in particular 20 to 40 wt .-% of the total amount of perfume.

According to one another preferred embodiment the particles contain the viscosity of liquids, in particular of Perfume enhancing Agent, preferably PEG (polyethylene glycol), advantageously having a molecular weight of 400 to 2000, wherein the viscosity-increasing agent preferably in amounts of 0.1 to 20 wt .-%, advantageously from 0.15 to 10% by weight, more preferably from 0.2 to 5 wt .-%, in particular from 0.25 to 3 wt .-% is included on the entire particle.

It it turned out that the viscosity of liquids, especially of perfume raising funds another contribution to the stabilization of the perfume in the Provide particles, especially when simultaneously nonionic Surfactant is present.

The viscosity increasing agents are preferably polyethylene glycols (PEG for short), which are described by the fol general formula can be described: H- (O-CH ₂ -CH ₂ ) _n OH in the degree of polymerization n of about 5 to> 100,000, corresponding to molar masses of 200 to 5,000,000 gmol ^-1 , can vary. The products with molecular weights below 25,000 gmol ^-1 are referred to as actual polyethylene glycols, while higher molecular weight products are often referred to in the literature as polyethylene oxides (PEOX for short). The polyethylene glycols preferably used may have a linear or branched structure, with particular preference being given to linear polyethylene glycols and end-capped.

To the particularly preferred polyethylene glycols include those with relative molecular masses between 400 and 2000. It can In particular, polyethylene glycols are used which an at room temperature and a pressure of 1 bar in the liquid state available; Here is mainly of polyethylene glycol with a relative molecular mass from 200, 400 and 600 the speech.

As mentioned earlier when creating a perfume composition "top note", "heart note" or middle note "(middle note or body) and "base note" (end note or dry out). Includes the top note (tête, Tip, smell) substantially volatile perfumes preferably mostly fresh character. The middle note (Bouqet, Corps, Coeur, Heart note, body) comprises Substantially moderately volatile fragrances, preferably of a mostly flowery character and the base note (Fond, Afterglow) in the essentially little volatile Fragrances, essentially the basic character (Leitgeruch) of the Determine perfumes.

The is called so that the Topnote essentially the first phase of the scent process of a Perfumes or one with the perfume perfumed agent, such as B. a detergent determined. You all come the decisive role in the first impression of the smell experience to, i. z. B. when opening the detergent package and when filling the detergent in the Washing machine. The top note should be essentially attention and interest in the perfume and thus for the aroused means, which is why they essentially a mixture of light, volatile Substances represents, although partly already notes of heart and base already play a role in the first fragrance phase. typical Components of the top note are, for example, the citrus oils, fruit notes, Lavender, dihydomyrcenol or rose oxide. The expert knows one Variety of other ingredients from the daily intuition or can these of the relevant specialist literature remove.

The second, middle phase of the scent process of a perfume or one with the perfume perfumed agent, such as As a detergent is from the heart note certainly. This is preferably formed by a mixture of rounder, more complex notes that give a perfume fullness, character and a certain direction give. You can z. B. predominantly of flowery components such as lily of the valley, Jasmine or Rose shaped be. In addition, you can Here are many of the spicy ones Ingredients of a perfume such as B. Eugenol (essential carnation odor) find. The expert knows a variety of other components from the daily view or can this be the relevant one Refer to technical literature.

The Base note of the perfume (with which, for example, a detergent is scented) determines the character of the Fragrance. It is very long on the scented objects and is essentially composed of heavier, warmer notes. Z. For example, you can have a precious wood base with isolated odorants of others woods and Z. B. also with musk fragrances and / or an animal Complex as well as predestined Base notes such as patchouli and vanilla combine.

On the basis of this common perfume note concept become the perfume compositions In general, it can even make a perfume complex construction consist of several hundred individual components. Experience only leads a well-balanced blend of many ingredients (for example at least 15 or 10, in many cases at least 30 or 50 or even more) to the perfumist Success, i. to a fragrance.

In front This is the background of the significance of the present invention even stronger out.

First, it is clear that essentially the degeneration (ie the degeneration, degradation, decomposition) of one or at least a few fragrances is sufficient to ruin the harmonious overall structure of a whole perfume composition. Already the odor reduction of only one note, so The top note, middle note or base note considerably reduces the odor value of the whole perfume composition or even completely destroys it. Against this background, the successful perfuming of inexpensive mass-produced goods, such. As washing or successful perfuming inexpensive mass-produced goods such. As washing or cleaning agents, a venture that requires a lot of experience and highly trained professionals. Here, the perfume compositions have to be adapted to the most diverse, sometimes aggressive media and fundamentals. In the field of detergents z. B. their alkalinity for many perfume compositions highly problematic and also the use of zeolite-containing support materials. The present invention now allows the perfumer a whole new spectrum of perfumery possibilities in the scenting of detergents or cleaners via zeolite-containing particles as fragrance carriers. The skilled person can now also use such fragrances, which would have previously not been considered due to their instability in zeolite-containing carriers. He can now make the top note, middle note and / or base note of a perfume composition even freer and even more individual. He can now also weight relatively unstable fragrances in the perfume compositions quantitatively higher.

• (a) die Kopfnote quantitativ höher gewichtet ist als Herznote und Basisnote, wobei die beiden niedriger gewichteten Noten zueinander im wesentlichen gleich gewichtet sein können oder wobei eine der niedriger gewichteten Noten höher gewichtet ist als die andere, oder
• (b) die Mittelnote quantitativ höher gewichtet ist als die Kopfnote und Basisnote, wobei die beiden niedriger gewichteten Noten zueinander im wesentlichen gleich gewichtet sein können oder wobei eine der niedriger gewichteten Noten höher gewichtet ist als die andere, oder
• (c) die Basisnote quantitativ höher gewichtet ist als Kopfnote und Mittelnote, wobei die beiden niedriger gewichteten Noten zueinander im wesentlichen gleich gewichtet sein können oder wobei eine der niedriger gewichteten Noten höher gewichtet ist als die andere.

According to a preferred embodiment, the notes of the perfume composition contained in the particle of the invention differ in their quantitative weighting, preferably

• (a) the headnote is quantitatively weighted higher than the middle note and the base note, wherein the two lower-weighted notes may be substantially equally weighted to each other, or one of the lower-weighted notes is weighted higher than the other, or
• (b) the middle note is quantitatively weighted higher than the top note and base note, wherein the two lower weighted notes may be substantially equally weighted to each other, or one of the lower weighted notes is weighted higher than the other, or
• (c) the base note is quantitatively weighted higher than the top note and middle note, wherein the two lower weighted notes may be substantially equally weighted to one another or one of the lower weighted notes is weighted higher than the other.

The a grade higher weighted as another means that the total mass of the higher weighted Note forming fragrances is greater as the total mass of fragrances forming the less weighted note, and advantageously by at least 10% by weight, preferably at least 20 wt .-%, in particular at least 30 wt .-%, based on the total mass of the entire perfume composition.

To another preferred embodiment are all notes of the perfume composition essentially equally weighted.

• (a) mandelartigem Geruch, wie vorzugsweise Benzaldehyd, Pentanal, Heptenal, 5-Methylfurfural, Methylbutanal, Furfural und/oder Acetophenon oder
• (b) apfelartigem Geruch, wie vorzugsweise (S)-(+)-Ethyl-2-methylbutanoat, Diethylmalonat, Ethylbutyrat, Geranylbutyrat, Geranylisopentanoat, Isobutylacetat, Linalylisopentanoat, (E)-β-Damascone, Heptyl-2-methylbutyrat, Methyl-3-methylbutanoat, 2-Hexenal-pentyl-methylbutyrat, Ethylmethylbutyrate und/oder Methyl-2-Methylbutanoat oder
• (c) apfelschalenartigem Geruch, wie vorzugsweise Ethylhexanoat, Hexylbutanoat und/oder Hexylhexanoat oder
• (d) aprikosenartigem Geruch wie vorzugsweise γ-Undecalacton oder
• (e) bananenartigem Geruch, wie vorzugsweise Isobutylacetat, Isoamylacetat, Hexenylacetat und/oder Pentylbutanoat oder
• (f) bittermandelartigem Geruch wie vorzugsweise 4-Acetyltoluol oder
• (g) schwarze Johannisbeere-artigem Geruch wie vorzugsweise Mercaptomethylpentanon und/oder Methoxymethylbutanethiol oder
• (h) zitrusartigem Geruch wie vorzugsweise Linalylpentanoat, Heptanal, Linalylisopentanoat dodecanal, Linalylformiat, α-p-Dimethylstyrol, p-Cymenol, Nonanal, β-Cubebene, (Z)-Limonenoxid, cis-6-Ethenyltetrahydro-2,2,6-trimethylpyran-3-ol, cis-pyranoidlinalooloxid, Dihydrolinalool, 6(10)-Dihydromyrcenol, Dihydromyrcenol, β-Farnesen, (Z)-β-Farnesen, (Z)-Ocimen, (E)-Limonenoxid, Dihydroterpinylacetat, (+)-Limonen, (Epoxymethylbutyl)-methylfuran und/oder p-Cymen oder
• (i) kakaoartigem Geruch wie vorzugsweise Dimethylpyrazin, Butylmethylbutyrat und/oder Methylbutanal oder
• (j) kokusnußartigem Geruch, wie vorzugsweise γ-Octalacton, γ-Nonalacton, Methyllaurat, Tetradecanol, Methylnonanoat, (3S,3aS,7aR)-3a,4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2(3H)-on, 5-Butyldihydro-4-methyl-2(3H)-Furanon, Ethylundecanoat und/oder δ-Decalacton oder
• (k) sahneartigem Geruch wie vorzugsweise Diethylacetal, 3-Hydroxy-2-butanon, 2,3-Pentadion und/oder 4-Heptenal oder
• (l) blumenartigem Geruch wie vorzugsweise Benzylalcohol, Phenylessigsäure, Tridecanal, p-Anisylalcohol, Hexanol, (E,E)-Farnesylaceton, Methylgeranat, trans-Crotonaldehyd, Tetradecylaldehyd, Methylanthranilat, Linalooloxid, Epoxylinalool, Phytol, 10-epi-γ-Eudesmol, Neroloxid, Ethyldihydrocinnamat, γ-Dodecalacton, Hexadecanol, 4-Mercapto-4-methyl-2-pentanol, (Z)-Ocimene, Cetylalcohol, Nerolidol, Ethyl-(E)-cinnamat, Elemicin, Pinocarveol, α-Bisabolol, (2R,4R)-Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2H-pyran, (E)-Isoelemicin, Methyl-2-methylpropanoat, Trimethylphenylbutenon, 2-Methylanisol, β-Farnesol, (E)-Isoeugenol, Nitro-phenylethan, Ethylvanillat, 6-Methoxyeugenol, Linalool, β-Ionon, Trimethylphenylbutenon, Ethylbenzoat, Phenylethylbenzoat, Isoeugenol und/oder Acetophenone oder
• (m) Frische-Geruch wie vorzugsweise Methylhexanoat, Undecanon, (Z)-limonenoxid, Benzylacetat, Ethylhydroxyhexanoat, Isopropylhexanoat, Pentadecanal, β-Elemene, α-Zingiberene, (E)-Limonenoxid, (E)-p-Mentha-2,8-dien-1-ol, Menthon, Piperiton, (E)-3-Hexenol und/oder Carveol oder
• (n) Frucht-Geruch wie verzugsweise Ethylphenylacetat, Geranylvalerat, γ-Heptalacton, Ethylpropionat, Diethylacetal, Geranylbutyrat, Ethylheptylat, Ethyloctanoat, Methylhexanoat, Dimethylheptenal, Pentanon, Ethyl-3-methylbutanoat, Geranylisovalerat, Iobutylacetat, Ehoxypropanol, Mthyl-2-butenal, Mthylnonanedion, Linalylacetat, Mthylgeranat, Lmonenoxid, Hdrocinnamicalcohol, Dethylsuccinat, Ehylhexanoat, Ehylmethylpyrazin, β-Cbebene, Nryletat, Ctronellylbutyrat, Heylacetat, Nonylacetat, Butylmethylbutyrat, Pentenal, Isopentyldimethylpyrazin, p-menth-1-en-9-ol, Hexadecanon, Octylacetat, γ-Dodecalacton, Epoxy-β-ionon, Ethyloctenoat, Ethylisohexanoat, Isobornylpropionat, Cedrenol, p-menth-1-en-9-yl acetat, Cadinadien, (Z)-3-Hexenylhexanoat, Ethylcyclohexanoat, 4-Methylthio-2-butanon, 3,5-Octadienon, Methylcyclohexancarboxylat, 2-pentylthiophen, α-Ocimene, Butandiol, Ethylvalerat, Pentanol, Isopiperiton, Butyloctanoat, Ethylvanillat, Methylbutanoat, 2-Mmethylbutylacetat, Propylhexanoat, Butylhexanoat, Isopropylbutanoat, Spathulenol, Butanol, δ-Dodecalacton, Methylquinoxalin, Sesquiphellandren, 2-Hexenol, Ethylbenzoate, Isopropylbenzoat, Ethyllactat und/oder Citronellylisobutyrat oder
• (o) Geranium-artigen Geruch, wie vorzugsweise Geraniol, (E,Z)-2,4-Nonadienal, Octadienon und/oder o-Xylen oder
• (p) weintraubenartigem Geruch wie vorzugsweise Ethyldecanoat und/oder Hexanon oder
• (q) grapefruitartigem Geruch wie vorzugsweise (+)-5,6-Dimethyl-8-isopropenylbicyclo[4.4.0]dec-1-en-3-on und/oder p-Menthenethiol oder
• (r) grasartigem Geruch wie vorzugsweise 2-Ethylpyridin, 2,6-Dimethylnaphthalen, Hexanal und/oder (Z)-3-Hexenol oder
• (s) grüner Note, vorzugsweise 2-Ethylhexanol, 6-Decenal, Dimethylheptenal, Hexanol, Heptanol, Methyl-2-butenal, Hexyloctanoate, Nonansäure, Undecanon, Methylgeranat, Isobornylformiate, Butanal, Octanal, Nonanal, Epoxy-2-decenal, cis-Linalool, Pyranoxid, Nonanol, alpha,γ-dimethylallylalcohol, (Z)-2-penten-1-ol, (Z)-3-hexenylbutanoat, Isobutylthiazol, (E)-2-nonenal, 2-dodecenal, (Z)-4-decenal, 2-octenal, 2-hepten-1-al, Bicyclogermacrene, 2-Octenal, α-Thujene, (Z)-β-Farnesene, (–)-γ-Elemene, 2,4-Octadienal, Fucoserraten, Hexenylacetat, Geranylaceton, Valencene, β-Eudesmol, 1-Hexenol, (E)-2-Undecenal, Artemisia keton, Viridiflorol, 2,6-Nonadienal, Trimethylphenylbutenon, 2,4-Nonadienal, Butylisothiocyanat, 2-Pentanol, Elemol, 2-Hexenal, 3-Hexenal, (+)-(E)-Limonenoxid, cis-Isocitral, Dimethyloctadienal, Bornylformiat, Bornylisovalerat, Isobutyraldehyd, 2,4-Hexadienal, Trimethylphenylbutenon, Nonanon, (E)-2-Hexenal, (+)-cis-Rosenoxide, Menthone, Coumarin, (Epoxymethylbutyl)-methylfuran, 2-Hexenol, (E)-2-hexenol und/oder Carvylacetat oder
• (t) Grüner Tee-artigem Geruch, vorzugsweise (–)-Cubenol oder
• (u) kräuterartigem Geruch, vorzugsweise Octanon, Hexyloctanoat, Caryophyllenoxide,. Methylbutenol, Safranal, Benzylbenzoat, Bornylbutyrat, Hexylacetat, β-Bisabolol, Piperitol, β-Selinene, α-Cubebene, p-Menth-1-en-9-ol, 1,5,9,9-Tetramethyl-12-oxabicyclododeca-4,7-dien, T-muurolol, (–)-Cubenol, Levomenol, Ocimene, α-Thujene, p-Menth-1-en-9-yl acetat, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, Hydroxypentanon, (Z)-Ocimene, β-Elemene, δ-Cadinol, (E)-β-Ocimene, (Z)-Dihydrocarvone, α-Cadinol, Calamenen, (Z)-Piperitol. Lavandulol, β-Bourbonene, (Z)-3-Hexenyl-2-methylbutanoat, 4-(1-Methylethyl)-benzenemethanol, Artemisia keton, Methyl-2-butenol, Heptanol, (E)-Dihydrocarvon, p-2-Menthen-1-ol, α-Curcumene, Spathulenol, Sesquiphellandren, Citronellylvalerat, Bornylisovalerat, 1,5-Octadien-3-ol, Methylbenzoat, 2,3,4,5-Tetrahydroanisol und/oder Hydroxycalamenen oder
• (v) honigartigem Geruch, vorzugsweise Ethylcinnamate, β-Phenethylacetat, Phenylessigsäure, Phenylethanal, Methylanthranilat, Zimtsäure, β-Damascenone, Ethyl-(E)-cinnamat, 2-Phenylethylalcohol, Citronellylvalerate, Phenylethylbenzoate und/oder Eugenol oder
• (w) Hyazinthen-artigem Geruch, vorzugsweise Hotrienol oder
• (x) jasminartigem Geruch, vorzugsweise Methyljasmonate, Methyldihydroepijasmonat und/oder Methylepijasmonat oder
• (y) lavendelartigem Geruch, vorzugsweise Linalylvalerate und/oder Linalool oder
• (z) zitronenartigem Geruch, vorzugsweise Neral, Octanal, δ-3-Carene, Limonen, Geranial, 4-mercapto-4-methyl-2-pentanol, Citral, 2,3-Dehydro-1,8-cineol und/oder α-Terpinen oder
• (aa) lilienartigem Geruch, vorzugsweise Dodecanal oder
• (bb) magnolienartigem Geruch, vorzugsweise Geranylaceton oder
• (cc) mandarinenartigem Geruch, vorzugsweise Undecanol oder
• (dd) melonenartigem Geruch, vorzugsweise Dimethylheptenal oder
• (ee) Minze-artigem Geruch, vorzugsweise Menthone, Ethylsalicylat, p-Anisaldehyd, 2,4,5,7a-tetrahydro-3,6-dimethyl-benzofuran, Epoxy-p-menthene, Geranial, (Methylbutenyl)-methylfuran, Dihydrocarvylacetat, β-Cyclocitral, 1,8-Cineol, β-Phellandrene, Methylpentanon, (+)-Limonen, Dihydrocarveol (–)-Carvon, (E)-p-Mentha-2,8-dien-1-ol, Isopulegylacetat, Piperiton, 2,3-Dehydro-1,8-cineol, α-Terpineol, DL-carvon und/oder α-Phellandrene oder
• (ff) nußartigem Geruch, vorzugsweise 5-methyl-(E)-2-hepten-4-on, γ-Heptalacton, 2-Acetylpyrrol, 3-Octen-2-on, Dihydromethylcyclopentapyrazin, Acetylthiazol, 2-Octenal, 2,4-Heptadienal, 3-Octenon, Hydroxypentanon, Octanol, Dimethylpyrazin, Methylquinoxalin und/oder Acetylpyrrolin oder
• (gg) orangenartigem Geruch, vorzugsweise Methyloctanoat, Undecanon, Decylalcohol, Limonen und/oder 2-Decenal oder
• (hh) Orangenschalen-artigem Geruch, vorzugsweise Decanal und/oder β-Carene oder
• (ii) pfirsichartigem Geruch, vorzugsweise γ-Nonalacton, (Z)-6-Dodecene-γ-lacton, δ-Decalacton, R-δ-Decenolacton, Hexylhexanoat, 5-Octanolid, γ-Decalacton und/oder δ-Undecalacton oder
• (jj) Pfefferminze-artigem Geruch, vorzugsweise Methylsalicylat und/oder I-Menthol oder
• (kk) Kiefer-artigem Geruch, vorzugsweise α-p-Dimethylstyrol, β-Pinene, Bornylbenzoat, δ-Terpinen, Dihydroterpinylacetat und/oder α-Pinen oder
• (ll) ananasartigem Geruch, vorzugsweise Propylbutyrat, Propylpropanoat und/oder Ethylacetat oder
• (mm) pflaumenartigem Geruch, vorzugsweise Benzylbutanoat, oder
• (nn) himbeerartigem Geruch, vorzugsweise β-Ionone oder
• (oo) Rose-artigem Geruch, vorzugsweise β-Phenethylacetat, 2-Ethylhexanol, Geranylvalerat, Geranylacetat, Citronellol, Geraniol, Geranylbutyrat, Geranylisovalerat, Citronellylbutyrat, Citronellylacetat, Isogeraniol, Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2,5-cis-2H-pyran, Isogeraniol, 2-Phenylethylalcohol, Citronellylvalerat und/oder Citronellylisobutyrat, oder
• (pp) Grüne Minze-artigem Geruch, vorzugsweise Carvylacetate und/oder Carveol, oder
• (qq) erdbeerenartigem Geruch, vorzugsweise Hexylmethylbutyrat, Methylcinnamat, Pentenal, Methylcinnamate oder
• (rr) süßlichem Geruch, vorzugsweise Benzylalcohol, Ethylphenylacetat, Tridecanal, Nerol, Methylhexanoat, Linalylisovalerat, Undecanaldehyd, Caryophyllenoxid, Linalylacetat, Safranal, Uncineol, Phenylethanal, p-Anisaldehyd, Eudesmol, Ethylmethylpyrazin, Citronellylbutyrat, 4-Methyl-3-penten-2-on, Nonylacetat, 10-Epi-γ-eudesmol, β-Bisabolol, (Z)-6-Dodecen-γ-lacton, β-Farnesene, 2-Dodecenal, γ-Dodecalacton, Epoxy-β-ionon, 2-Undecenal, Styrenglycol, Methylfuraneol, (–)-cis-Rosenoxid, (E)-β-Ocimene, Dimethylmethoxyfuranon, 1,8-Cineole, Ethylbenzaldehyd, 2-Pentylthiophen, α-Farnesene, Methionol, 7-Methoxycoumarin, (Z)-3-Hexenyl-2-methylbutanoat, o-Aminoacetophenon, Viridiflorol, Isopiperitone, β-Sinensal, Ethylvanillat, Methylbutanoat, p-Methoxystyrol, 6-Methoxyeugenol, 4-Hexanolid, δ-Dodecalacton, Sesquiphellandren, Diethylmalat, Linalylbutyrat, Guaiacol, Coumarin, Methylbenzoat, Isopropylbenzoat, Safrole, Durene, γ-Butyrolacton, Ethylisobutyrat und/oder Furfural oder
• (ss) Vanille-artigem Geruch, vorzugsweise Vanillin, Methylvanillat, Acetovanillon und/oder Ethylvanillat oder
• (tt) wassermelonenartigem Geruch, vorzugsweise 2,4-Nonadienal oder
• (uu) holzartigem Geruch, vorzugsweise α-Muurolene, Cadina-1,4-dien-3-ol, Isocaryophyllene, Eudesmol, α-Ionon, Bornylbutyrat, (E)-α-Bergamoten, Linalooloxid, Ethylpyrazin, 10-epi-γ-Eudesmol, Germacrene B, trans-Sabinenhydrat, Dihydrolinalool, Isodihydrocarveol, β-Farnesene, β-Sesquiphellandren, δ-Elemene, α-Calacorene, Epoxy-β-ionon, Germacrene D, Bicyclogermacrene, Alloaromadendrene, α-Thujene, oxo-β-Ionon, (–)-γ-Elemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6-(2-propenyl)-1,3-benzodioxol, [1ar-(1aalpha,4aalpha,7alpha,7abeta,7balpha)]-decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop[e]azulen, α-Gurjunen, Guaiol, α-Farnesene, γ-Selinene, 4-(1-Methylethyl)-benzenemethanol, Perillen, Elemol, α-Humulene, β-Caryophyllene und/oder β-Guaiene oder
• (vv) Mischungen aus vorgenannten

enthalten. Vorgenannte Riechstoffe können vorzugsweise in den erfindungsgemäßen Teilchen enthalten sein. Die Parfümstabilität kann auch im Zusammenhang mit den vorgenannten Riechstoffen erfindungsgemäß noch weiter verbessert werden.As has already been emphasized, the present invention allows the person skilled in the art a greater freedom of action in the scenting of zeolite-containing particles, thus making it possible to produce zeolite-containing particles with further refined scent notes. For this purpose, the particle according to the invention according to a preferred embodiment, in particular fragrances with

• (a) almond-like odor, such as preferably benzaldehyde, pentanal, heptenal, 5-methylfurfural, methylbutanal, furfural and / or acetophenone or
• (b) apple-like odor, preferably (S) - (+) - ethyl-2-methylbutanoate, diethyl malonate, ethyl butyrate, geranyl butyrate, geranyl isopentanoate, isobutyl acetate, linalyl isopentanoate, (E) -β-damascone, heptyl-2-methyl butyrate, methyl 3-methylbutanoate, 2-hexenalpentyl-methyl butyrate, ethylmethyl butyrate and / or methyl 2-methylbutanoate or
• (c) apple peel-like odor, such as preferably ethylhexanoate, hexylbutanoate and / or hexylhexanoate or
• (d) apricot-like odor, preferably γ-undecalactone, or
• (e) banana-like odor, such as preferably isobutyl acetate, isoamyl acetate, hexenyl acetate and / or pentyl butanoate or
• (f) bitter almond-like odor such as preferably 4-acetyltoluene or
• (g) blackcurrant-like odor, such as preferably mercaptomethylpentanone and / or methoxymethylbutanethiol or
• (c) citrus-like odor such as preferably linalyl pentanoate, heptanal, linalyl isopentanoate dodecanal, linalyl formate, α-p-dimethylstyrene, p-cymenol, nonanal, β-cubebene, (Z) -liminene oxide, cis-6-ethenyl-tetrahydro-2,2,6- trimethylpyran-3-ol, cis-pyranoidlinalooloxide, dihydrolinalool, 6 (10) -dihydromyrcenol, dihydromyrcenol, β-farnesene, (Z) -β-farnesene, (Z) -cime, (E) -liminene oxide, dihydrotypinyl acetate, (+) -Limonen, (Epoxymethylbutyl) -methylfuran and / or p-cymene or
• (i) cocoa like odor, preferably dimethylpyrazine, butylmethyl butyrate and / or methylbutanal or
• (j) coconut-like odor, such as preferably γ-octalactone, γ-nonalactone, methyl laurate, tetradecanol, methyl nonanoate, (3S, 3aS, 7aR) -3a, 4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2 (3H) -on, 5-butyldihydro-4-methyl-2 (3H) -furanone, ethyl undecanoate and / or δ-decalactone or
• (k) creamy odor such as preferably diethyl acetal, 3-hydroxy-2-butanone, 2,3-pentadione and / or 4-heptenal, or
• (l) flower-like odor such as preferably benzyl alcohol, phenylacetic acid, tridecanal, p-anisyl alcohol, hexanol, (E, E) -farnesylacetone, methyl geranate, trans-crotonaldehyde, tetradecylaldehyde, methyl anthranilate, linalooloxide, epoxylinalool, phytol, 10-epi-γ-eudesmol , Nerol oxide, ethyldihydrocinnamate, γ-dodecalactone, hexadecanol, 4-mercapto-4-methyl-2-pentanol, (Z) -oximes, cetyl alcohol, nerolidol, ethyl (E) -cinnamate, elemicin, pinocarveol, α-bisabolol, ( 2R, 4R) -Tetrahydro-4-methyl-2- (2-methyl-1-propenyl) -2H-pyran, (E) -Isoelemicin, methyl 2-methylpropanoate, trimethylphenylbutenone, 2-methylanisole, β-farnesol, ( E) isoeugenol, nitro-phenylethane, ethyl vanillate, 6-methoxyeugenol, linalool, β-ionone, trimethylphenylbutenone, ethyl benzoate, phenylethyl benzoate, isoeugenol and / or acetophenones or
• (m) freshness odor, preferably methylhexanoate, undecanone, (Z) -limonoxide, benzylacetate, ethylhydroxyhexanoate, isopropylhexanoate, pentadecanal, β-elemene, α-zingiberene, (E) -liminic oxide, (E) -p-mentha-2, 8-dien-1-ol, menthone, piperone, (E) -3-hexenol and / or carveol or
• (n) fruit odor such as, preferably, ethyl phenylacetate, geranyl valerate, γ-heptalactone, ethyl propionate, diethyl acetal, geranyl butyrate, ethylheptylate, ethyloctanoate, methylhexanoate, dimethylheptenal, pentanone, ethyl-3-methylbutanoate, geranylisovalerate, iobutylacetate, ethoxypropanol, methyl-2-butenal, Methylnonanedione, linalyl acetate, methyl geranate, lmone oxide, hdrocinnamiccohol, ethylsuccinate, ethylhexanoate, ethylmethylpyrazine, β-cbene, nylate, ctronellylbutyrate, heylacetate, nonylacetate, butylmethylbutyrate, pentenal, isopentyldimethylpyrazine, p-menth-1-en-9-ol, hexadecanone, octylacetate, γ-dodecalactone, epoxy β-ionone, ethyloctenoate, ethylisohexanoate, isobornyl propionate, cedrenol, p-menth-1-en-9-yl acetate, cadinadiene, (Z) -3-hexenylhexanoate, ethylcyclohexanoate, 4-methylthio-2-butanone , 3,5-octadienone, methylcyclohexanecarboxylate, 2-pentylthiophene, α-ocimene, butanediol, ethylvalerate, pentanol, isopiperiton, butyl octanoate, ethyl vanillate, methyl butanoate, 2-methylbutyl acetate, propyl hexanoate, Butyl hexanoate, isopropyl butanoate, spathulenol, butanol, δ-dodecalactone, methylquinoxaline, sesquiphenilene, 2-hexenol, ethyl benzoate, isopropyl benzoate, ethyl lactate and / or citronellyl isobutyrate or
• (o) Geranium-like odor, such as preferably geraniol, (E, Z) -2,4-nonadienal, octadienone and / or o-xylene or
• (p) grape-like odor such as preferably ethyl decanoate and / or hexanone or
• (q) grapefruit-like odor such as preferably (+) - 5,6-dimethyl-8-isopropenylbicyclo [4.4.0] dec-1-en-3-one and / or p-menthenethiol or
• (R) grassy odor such as preferably 2-ethylpyridine, 2,6-dimethylnaphthalene, hexanal and / or (Z) -3-hexenol or
• (s) green note, preferably 2-ethylhexanol, 6-decenal, dimethylheptenal, hexanol, heptanol, methyl-2-butenal, hexyloctanoates, nonanoic acid, undecanone, methyl geranate, isobornylformiate, butanal, octanal, nonanal, epoxy-2-decenal, cis -Linalool, pyranoxide, nonanol, alpha, γ-dimethylallylalcohol, (Z) -2-penten-1-ol, (Z) -3-hexenylbutanoate, isobutylthiazole, (E) -2-nonenal, 2-dodecenal, (Z) 4-decenal, 2-octenal, 2-hepten-1-al, bicyclo mermose, 2-octenal, α-thujene, (Z) -β-farnesene, (-) - γ-elemene, 2,4-octadienal, fucoserrate , Hexenylacetate, geranylacetone, valencene, β-eudesmol, 1-hexenol, (E) -2-undecenal, artemisia ketone, viridiflorol, 2,6-nonadienal, trimethylphenylbutenone, 2,4-nonadienal, butylisothiocyanate, 2-pentanol, elemole, 2-hexenal, 3-hexenal, (+) - (E) -liminene oxide, cis -isocitral, dimethyloctadienal, bornylformate, bornylisovalerate, isobutyraldehyde, 2,4-hexadienal, trimethylphenylbutenone, nonanone, (E) -2-hexenal, (+ ) -cis-Rose Oxides, Menthone, Coumarin, (Epoxymethylbutyl) -methylfu ran, 2-hexenol, (E) -2-hexenol and / or carvyl acetate or
• (t) Green Tea-like odor, preferably (-) - Cubenol or
• (u) herbaceous odor, preferably octanone, hexyloctanoate, caryophyllene oxides ,. Methylbutenol, safranal, benzyl benzoate, bornyl butyrate, hexyl acetate, β-bisabolol, piperitol, β-selenene, α-cubebene, p-menth-1-en-9-ol, 1,5,9,9-tetramethyl-12-oxabicyclododeca- 4,7-diene, T-muurolol, (-) - cubenol, levomenol, ocimene, α-thujene, p-menth-1-en-9-yl acetate, dehydrocarveol, Artemisia alcohol, γ-muurolene, hydroxypentanone, (Z ) -Oximes, β-elemens, δ-cadinol, (E) -β-ocimene, (Z) -dihydrocarvone, α-cadinol, calamine, (Z) -piperitol. Lavandulol, β-bourbonene, (Z) -3-hexenyl-2-methylbutanoate, 4- (1-methylethyl) benzene-ethanol, artemisia ketone, methyl-2-butenol, heptanol, (E) -dihydrocarvone, p-2-menthene 1-ol, α-curcumene, spathulenol, sesquipellandrene, citronellyl valerate, bornyl isovalerate, 1,5-octadien-3-ol, methyl benzoate, 2,3,4,5-tetrahydroanisole and / or hydroxycalmenes or
• (v) honey-like odor, preferably ethyl cinnamate, β-phenethyl acetate, phenylacetic acid, phenylethanal, methyl anthranilate, cinnamic acid, β-damascenone, ethyl (E) -cinnamate, 2-phenylethylalcohol, citronellyl valerate, phenylethyl benzoate and / or eugenol or
• (w) Hyacinth-like odor, preferably Hotrienol or
• (x) jasmine-like odor, preferably methyl jasmonate, methyldihydroepijasmonate and / or methylepijasmonate or
• (y) lavender-like odor, preferably linalyl valerate and / or linalool or
• (z) lemon-like odor, preferably, neral, octanal, δ-3-carene, limonene, geranial, 4-mercapto-4-methyl-2-pentanol, citral, 2,3-dehydro-1,8-cineol and / or α -Terpines or
• (aa) lily-like odor, preferably dodecanal or
• (bb) magnolia-like odor, preferably geranylacetone or
• (cc) mandarin-like odor, preferably undecanol or
• (dd) melon-like odor, preferably dimethylheptenal or
• (ee) minty odor, preferably menthone, ethyl salicylate, p-anisaldehyde, 2,4,5,7a-tetrahydro-3,6-dimethylbenzofuran, epoxy-p-menthene, geranial, (methylbutenyl) -methylfuran, dihydrocarvylacetate , β-cyclocitral, 1,8-cineole, β-phellandrene, methylpentanone, (+) - limonene, dihydrocarveol (-) - carvone, (E) -p-mentha-2,8-dien-1-ol, isopulegyl acetate, Piperitone, 2,3-dehydro-1,8-cineol, α-terpineol, DL-carvone and / or α-phellandrene or
• (ff) Nutty odor, preferably 5-methyl- (E) -2-hepten-4-one, γ-heptalactone, 2-acetylpyrrole, 3-octen-2-one, dihydromethylcyclopentapyrazine, acetylthiazole, 2-octenal, 2,4 Heptadienal, 3-octenone, hydroxypentanone, octanol, dimethylpyrazine, methylquinoxaline and / or acetylpyrroline or
• (gg) orange-like odor, preferably methyloctanoate, undecanone, decyl alcohol, limonene and / or 2-decenal or
• (hh) orange peel-like odor, preferably decanal and / or beta-carene or
• (ii) peach-like odor, preferably γ-nonalactone, (Z) -6-dodecene-γ-lactone, δ-decalactone, R-δ-decenolactone, hexylhexanoate, 5-octanolide, γ-decalactone and / or δ-undecalactone or
• (jj) peppermint-like odor, preferably methyl salicylate and / or I-menthol or
• (kk) pine-like odor, preferably α-p-dimethylstyrene, β-pinene, bornyl benzoate, δ-terpinene, dihydroterpinyl acetate and / or α-pinene or
• (II) pineapple-like odor, preferably propyl butyrate, propyl propanoate and / or ethyl acetate or
• (mm) plum-like odor, preferably benzyl butanoate, or
• (nn) raspberry-like odor, preferably β-ionone or
• (oo) Rose-like odor, preferably β-phenethyl acetate, 2-ethylhexanol, geranyl valerate, geranyl acetate, citronellol, geraniol, geranyl butyrate, geranyl isovalerate, citronellyl butyrate, citronellyl acetate, isogeraniol, tetrahydro-4-methyl-2- (2-methyl-1) propenyl) -2,5-cis-2H-pyran, isogeraniol, 2-phenylethyl alcohol, citronellyl valerate and / or citronellyl isobutyrate, or
• (pp) spearmint-like odor, preferably carvylacetate and / or carveol, or
• (qq) strawberry-like odor, preferably hexylmethyl butyrate, methyl cinnamate, pentenal, methyl cinnamate or
• (rr) sweet odor, preferably benzyl alcohol, ethyl phenylacetate, tridecanal, nerol, methylhexanoate, linalyl isovalerate, undecanedehyde, caryophyllene oxide, linalyl acetate, safranal, uncinol, phenylethanal, p-anisaldehyde, eudesmol, ethylmethylpyrazine, citronellylbutyrate, 4-methyl-3-pentene-2 -on, nonyl acetate, 10-epi-γ-eudesmol, β-bisabolol, (Z) -6-dodecene-γ-lactone, β-farnesene, 2-dodecenal, γ-dodecalactone, epoxy-β-ionone, 2-undecenal , Styrene glycol, methyl furanol, (-) - cis-rose oxide, (E) -β-octenes, dimethylmethoxyfuranone, 1,8-cineols, ethylbenzaldehyde, 2-pentylthiophene, α-farnesene, methionol, 7-methoxycoumarin, (Z) -3 -Hexenyl 2-methylbutanoate, o-aminoacetophenone, viridiflorol, isopiperitones, β-sinensal, ethyl vanillate, methyl butanoate, p-methoxystyrene, 6-methoxyeugenol, 4-hexanolide, δ-dodecalactone, sesquiphenoids, diethyl malate, linalyl butyrate, guaiacol, coumarin, methyl benzoate , Isopropyl benzoate, safroles, durene, γ-butyrolactone, ethyl isobutyrate and / or furfural or
• (ss) vanilla-like odor, preferably vanillin, methyl vanillate, acetovanillon and / or ethyl vanillate or
• (tt) watermelon-like odor, preferably 2,4-nonadienal or
• (uu) woody odor, preferably α-muurolene, cadina-1,4-dien-3-ol, isocaryophyllene, eudesmol, α-ionone, bornyl butyrate, (E) -α-bergamotene, linalooloxide, ethylpyrazine, 10-epi-γ Eudesmol, germacrene B, trans-sabin hydrate, dihydrolinalool, isodihydrocarveol, β-farnesenes, β-sesquiphellandrene, δ-elemene, α-calacorene, epoxy-β-ionone, germacrene D, bicyclo mermose, alloaromadendrene, α-thujene, oxo-β Ionone, (-) - γ-elemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6- (2-propenyl) -1,3- benzodioxole, [1ar- (1aalpha, 4aalpha, 7alpha, 7abeta, 7balpha)] - decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop [e] azulen, α-gurjunen, guaiol, α-farnesene, γ-seleneins, 4- (1-methylethyl) -benzenemethanol, Perillen, Elemol, α-Humulenes, β-Caryophyllene and / or β-Guaiene or
• (vv) mixtures of the above

contain. The aforementioned fragrances may preferably be present in the particles according to the invention. The perfume stability can also according to the invention in connection with the aforementioned fragrances be further improved.

One an essential constituent of the particles according to the invention is the zeolite, which in an amount of more than 20 wt .-%, but less than 70 wt .-%, based on the total particle, is included. Within this bandwidth can be mentioned certain upper and / or lower limits are used advantageously.

In a preferred embodiment contains the particle has certain minimum values of zeolite, viz. B. at least 22 wt .-%, advantageously at least 25 wt .-%, in considerable advantageously at least 28 wt .-%, in a more advantageous manner at least 31 wt .-%, in a further advantageous manner at least 34th Wt .-%, more preferably at least 36 wt .-%, in a very advantageous manner at least 38 wt .-%, in particularly advantageous Way at least 40 wt .-%, in a particularly advantageous manner at least 42 wt .-%, in a significantly advantageous manner at least 44 wt .-%, in a very advantageous manner, at least 46 wt .-%, in extremely advantageous Way at least 48 wt .-%, in the highest advantageously at least 50% by weight, most advantageously at least 52% by weight, in an exceptionally advantageous manner at least 54% by weight, in exceptionally advantageous Way at least 56 wt .-%, in extremely advantageous Way at least 58 wt .-%, in particular at least 60 wt .-% of zeolite based on the total particle.

Also the maximum amount of zeolite can be set advantageously. Thus, according to another preferred embodiment, it may be advantageous be that that Particle does not exceed certain maximum amounts of zeolite, i.e. z. B. less than 68 wt .-%, advantageously less than 66 wt .-%, in considerably more advantageous Way less than 64 wt .-%, more preferably less than 62% by weight, more preferably less than 60% by weight, even more advantageously, less than 58% by weight, in very good advantageously less than 56 wt .-%, in particularly advantageous Way less than 54 wt .-%, in a particularly advantageous manner less than 52% by weight, much less advantageously than 50 wt .-%, in a significantly advantageous manner less than 48 wt .-%, in extremely advantageous Way less than 46 wt .-%, most advantageously less as 44% by weight, in excess advantageously less than 42 wt .-%, in exceptionally advantageous Way less than 40 wt .-%, in an exceptionally advantageous manner less as 38% by weight, in extraordinary advantageously less than 36 wt .-%, in particular less than 34 wt .-% of zeolite based on the total particle.

All in all It is advantageous if the amount of zeolite is within the previously Minimum and maximum amounts mentioned above, so for example in a range of at least 25% by weight but less than 68% by weight Zeolite or in one area after another possible Combination of the above values.

In a preferred embodiment contains the particle has certain minimum levels of perfume, viz. At least 1% by weight, advantageously at least 2% by weight, in a considerably advantageous manner at least 3% by weight, more preferably at least 4% by weight, in a further advantageous manner at least 5 wt .-%, in still further advantageously at least 6 wt .-%, in a very advantageous manner at least 7% by weight, in a particularly advantageous manner at least 8 Wt .-%, most preferably at least 10 wt .-%, in a considerably advantageous manner at least 11 wt .-%, in quite considerable advantageously at least 12 wt .-%, in an extremely advantageous manner at least 13 wt .-%, in the highest advantageously at least 14% by weight, most advantageously at least 16% by weight, in an exceptionally advantageous manner at least 18% by weight, in exceptionally advantageous Way at least 20 wt .-%, in extremely advantageous Way at least 22 wt .-%, in particular at least 24 wt .-% of perfume, based on the entire particle.

advantageously, capital the particles of the invention very big Quantities of perfume without the good powder properties such. B. flowability can be affected. Clumping advantageously does not occur. Surprisingly is the perfume stability in that zeolite-containing particles even at high perfume loading, ie z. B. in perfume quantities of at least 5% by weight, at least 10% by weight, at least 15% by weight, at least 20% by weight, etc., based on the total particle, very much well guaranteed.

In a preferred embodiment, the particle contains nonionic surfactant, preferably selected from the group of the alkoxylated alcohols, the alkylphenol polyglycol ethers, the alkoxylated fatty acid alkyl esters, the polyhydroxy fatty acid amides, the alkyl glycosides, the alkyl polyglucosides, the amine oxides and / or the long-chain alkyl sulfoxides, in particular in an amount of at least 0.1 wt .-% based on the ge whole particles.

there if the particle is preferably impregnated with the nonionic surfactant, i.e. the nonionic surfactant is advantageously substantially in the carrier material distributed.

If the particles contain nonionic surfactant, then that leads advantageously to an even more intense fragrance experience when Consumers, for example, when doing laundry with a detergent formulation washes, which particles of the invention includes. The consumer can therefore advantageously a more intensive Scent of the washed linen perceive in comparison to laundry, with a conventional perfumed Detergent formulation was washed, even if contained absolute amount of the perfume was the same. It is thus achieved a fragrance-enhancing effect, the The particles directly affects, as well as objects, in which these particles incorporated, for example, detergent formulations, as well as Things, such as B. Textiles, which with the objects (here: detergent formulation) be treated.

One Another advantage of the particles according to the invention, which also Containing nonionic surfactant is surprisingly in that the perfume component incorporated in the particle is stabilized even further. Perfume decomposition tendencies so further suppressed. This is the perfume stabilizing invention Effect further reinforced. This is especially true when the particle is incorporated into an object is, such. B. in a detergent formulation, which by their Object property, for example, their alkalinity, the stability of perfume is rather detrimental. Again, the additional effect Perfume stabilizing effect still improving.

One Another advantage of the particles according to the invention, which also Containing nonionic surfactant is surprisingly in that the resulting from the particles fragrance impression directly and indirectly even longer holds up. "Immediately" means in this Context that the particles according to the invention as such over a longer one Period smell. "Indirect" means in this Related to objects (eg, detergent formulation) containing the particles of the invention involve, longer smell, and that even when using these objects (eg, detergent formulation for Washing of textile) the things treated with it (here: washed Textile) longer smell.

It So is the fragrance according to the invention even more intensified, with this fragrance-retarding effect (ie the temporal extent of the fragrance impression) both on the Particles, such as on the particles containing objects, such as on the particles relates to things treated with these objects.

One Another advantage of the particles according to the invention, which also Containing nonionic surfactant is surprisingly also in that it by adding or by the presence of nonionic surfactant, the carrier material the particles with even larger amounts of perfume to load. This is especially surprising because you accept should, that of the carrier material Ingestible perfume quantity would have to sink, if the carrier material additionally must absorb a certain amount of another substance. It will but a further improvement, especially even a maximization the perfume receptivity of the carrier material achieved, so that a perfume loading of the carrier material to an even greater extent becomes possible.

The Usable amount of nonionic surfactant can be set in an advantageous manner.

In a preferred embodiment contains the particle of the invention advantageously at least 0.2 wt .-%, in a more advantageous manner at least 0.3% by weight, more preferably at least 0.4 Wt .-%, in a further advantageous manner at least 0.5 wt .-%, in still more advantageously at least 0.6 wt .-%, in very advantageous Way at least 0.7 wt .-%, in a particularly advantageous manner at least 0.8 wt .-%, in a particularly advantageous manner, at least 0.9 Wt .-%, in a significantly advantageous manner, at least 1.0 wt .-%, in very substantially advantageously at least 1.1 wt .-%, in extremely advantageous Way at least 1.2 wt .-%, in the highest advantageously at least 1.3% by weight, most advantageously at least 1.4% by weight, in an exceptionally advantageous manner at least 1.5% by weight, in exceptionally advantageous Way at least 1.6 wt .-%, in extremely advantageous Way at least 1.7 wt .-%, in particular at least 1.8 wt .-% of nonionic surfactant, based on the total particle.

However, according to another preferred embodiment, it may also be advantageous that the particle does not exceed certain maximum amounts of nonionic surfactant, ie, for example less than 30% by weight, advantageously less than 26% by weight, most advantageously less than 24% wt .-%, more preferably less than 22% by weight, more preferably less than 20% by weight, even more advantageously less than 18% by weight, most preferably less than 16% by weight, in particular advantageously less than 14% by weight, most preferably less than 12% by weight, significantly less than 11% by weight, most advantageously less than 10% by weight, in particular advantageously less than 9% by weight, most advantageously less than 8% by weight, most advantageously less than 7% by weight, most advantageously less than 6% by weight, most preferably less than 5 wt .-%, in an extremely advantageous manner less than 4 wt .-%, in particular less than 3 wt .-% of zeolite based on the total particle.

To a further preferred embodiment is at least partially alkoxylated as a nonionic surfactant Alcohol, preferably in amounts of at least 40% by weight, advantageously of at least 50 wt .-%, in more advantageous Way of at least 60 wt .-%, in a very advantageous manner of at least 70% by weight, more preferably at least 80 wt .-%, in particular of at least 90% by weight, most advantageously in amounts of 100% by weight, each based on the total amount of nonionic surfactant present in the particle which is advantageously ethoxylated, especially primary Alcohols are preferably 8 to 20, especially 12 to 18 carbon atoms and preferably on average 1 to 12 moles of alkylene oxide, preferably ethylene oxide, per mole of alcohol.

According to one another preferred embodiment the nonionic surfactants are a mixture of at least two different nonionic surfactants, preferably of at least two different alkoxylated, advantageously ethoxylated, especially primary Alcohol, being the distinguishing feature in relation to the alkoxylated Alcohols preferably in the degree of alkoxylation.

Lies in this mixture of at least two different nonionic surfactants at least one alkoxylated, preferably ethoxylated alcohol with a degree of alkoxylation less than 7, advantageously not greater than 6, further advantageously not greater than 5, in particular not greater than 4,5 and at least one further alkoxylated, advantageously ethoxylated alcohol having a degree of alkoxylation of at least 7 before, then it is a further preferred embodiment the invention.

According to one another preferred embodiment The invention is the ratio of lower alkoxylated Alcohol too high alkoxylated alcohol in the range of 5: 1 to 1: 5, preferably 4: 1 to 1: 4, advantageously 3: 1 to 1: 3, in particular 2: 1 to 1: 2.

To a further preferred embodiment if the zeolite is preferably zeolite X, Y, A, P, MAP and / or mixtures of these. The zeolite should preferably less than 25% by weight, advantageously less than 20% by weight, in a further advantageous manner less than 15 wt .-%, in even more advantageous Way less than 8 wt .-%, in particular less than 5 wt .-% desorbable Contain water. Such zeolite can be obtained, for example become that one the zeolite at temperatures of 150 ° C to 350 ° C, optionally at reduced pressure (advantageously from about 0.001 to about 20 torr) activated or dehydrated. Then one speaks of activated / dehydrated zeolite.

This is according to the invention relationship from zeolite to phyllosilicate in the particle according to the invention becomes smaller than 7: 1. In a preferred embodiment, the ratio of Zeolite to phyllosilicate less than 6: 1, preferably smaller than 5: 1, advantageously less than 4: 1, in particular smaller as 3: 1.

To a further preferred embodiment contains the particle of the invention a polymeric clay flocculating agent, wherein the clay flocculating agent is a polymer or a copolymer which preferably is Derived from ethylene oxide, acrylamide, acrylic acid, dimethylaminoethyl methacrylate, Vinyl alcohol, vinylpyrrolidone, ethyleneimine and mixtures thereof selected in particular being a weight average molecular weight from 100,000 to 10 million, preferably in the range from 0.005 wt .-% to 20 wt .-% based on the layered silicate, the is contained in the particle.

advantageously, The fabric softening phyllosilicates will be so during the Washing process more efficiently deposited on the tissue. The Deposition is increased and runs even more even.

To a preferred embodiment For example, the polymeric clay flocculating agent is obtained from monomers which are selected from ethylene oxide, acrylamide and acrylic acid.

In a preferred embodiment, the polymeric clay flocculant has a weight tel molecular weight of 150,000 to 5 million, preferably from 150,000 to 800,000.

To a preferred embodiment For example, the polymeric clay flocculant has a molecular weight of 150,000 up to 800,000. According to another preferred embodiment the clay flocculating agent has a molecular weight of 800,000 to 5 million.

To a preferred embodiment is the polymeric clay flocculant in an amount of 0.005 wt .-% to 10 wt .-%, preferably from 0.005 wt .-% to 5 wt .-%, in particular from 0.005 wt .-% to 2 wt .-% based on the sheet silicate before.

Preferably may be the particle of the invention also contain other ingredients and according to a preferred embodiment contains the particle cationic surfactant, zwitterionic compounds, Ampholytes, amphoteric surfactants, betaines, cationic polymers and / or amphoteric polymers. In the presence of such substances, a further improved Objektbeduftung achieved when using the particles especially a further improved fragrance retardation. This means, that if one z. B. textile objects with a detergent, which particles of this invention contains washes, then it can be achieved that still more fragrance sticks to the textile objects and there too longer lingers.

To a preferred embodiment contains the particle at least one quaternary ammonium compound, preferably an alkylated quaternary Ammonium compound, in particular in amounts of 0.1 wt .-% to 30 Wt .-% based on the total particle.

According to a preferred embodiment, the particle contains a quaternary ammonium compound of the formula (I), R ¹ (R ² ) (R ³ ) (R ⁴ ) N ⁺ X ^- (I) wherein R ¹ , R ² and R ^{3 are} independently selected from C ₁ -C ₄ -alkyl, C ₁ -C ₄ -hydroxyalkyl, benzyl and - (C ₂ H ₄ O) _x H, where x is 2 to 5, and wherein R ^{4 is} C ₈ -C ₂₂ alkyl, and wherein X ^{- is} an anion, preferably a halide, methosulfate, methophosphate or phosphate ion, and mixtures thereof.

In a preferred embodiment, the particle contains a quaternary ammonium compound of formula (II), R ⁵ R ⁶ _n R ⁷ _3-n N ⁺ X ^- (II) wherein R ^{5 is} a C ₆ -C ₂₄ alkyl or alkenyl wherein each R ^{6 is} independently a - (C _n H _2n O) _x R ⁸ group, where n is 1 to 4 and x is 1 to 14 and wherein R ^{8 is} a methyl, ethyl or preferably a hydrogen, and wherein each R ^{7 is} independently a C ₁ -C ₁₂ alkyl or alkenyl group, with m being 1 to 3, and wherein X- is an anion, preferably a halide, methosulfate, methophosphate or phosphate ion as well as mixtures of these. In this case, according to a preferred embodiment, R ^{6 is} a -CH ₂ CH ₂ OH, R ⁷ is independently of one another a C ₁ -C ₄ -alkyl, with m being 1 or 2, and where R ^{5 is} a linear C ₆ -C ₁₄ - Alkyl group is.

According to a preferred embodiment, the particle contains a C ₈ -C ₁₆ -alkyl-di (hydroxyethyl) -methyl ammonium compound, preferably a C ₁₂ -C ₁₄ -alkyl-di (hydroxyethyl) -methyl ammonium compound, and / or a C ₈ -C ₁₆ -alkyl (hydroxyethyl) -dimethyl ammonium compound, preferably a C ₁₂ -C ₁₄ -alkyl (hydroxyethyl) -dimethyl ammonium compound, in particular the respective halides, methosulfate, methophosphates or phosphates and mixtures from these.

wobei das R⁹ für eine C_6-28-Alkyl- oder Alkenylgruppe steht, und wobei R¹⁰ und R¹¹ jeweils, unabhängig voneinander, C_1-4 Alkyl-Gruppen sind, und wobei a für die Zahl 0 oder 1 steht, b und c jeweils, unabhängig voneinander, aus ganzen Zahlen von 1 bis 4 ausgewählt sind, und wobei Y Sauerstoff oder Stickstoff ist, und wobei X ein Atom oder eine Atomgruppe mit einer negativen Ladung ist. Die negative Ladung ist meist an Sauerstoff-Atomen lokalisiert durch Abgabe eines Protons von Carboxy- od. Sulfo-Gruppen, Phosphorsäure-Resten, sauren phenolischen oder enolischen Hydroxy-Gruppen. Nach einer bevorzugten Ausführungsform enthält das Teilchen zumindest ein Alkylamidoalkylendimethylcarbonsäure-Betain nach Formel (IV):

wobei d und e, unabhängig voneinander, ganze Zahlen von 1–4 sind, vorzugsweise ist d gleich 2 oder 3 und e gleich 2 oder 3 und wobei R¹² für eine C_10-18-Alkylkette oder Mischungen davon steht.Also zwitterionic compounds can be used with advantage. In a preferred embodiment, the particle contains a zwitterionic compound of formula (III)

wherein R ^{9 is} a C _6-28 alkyl or alkenyl group, and wherein R ¹⁰ and R ^{11 are} each independently and C _{1-4 are} alkyl groups, and wherein a is the number 0 or 1, b and c are each independently selected from integers of 1 to 4, and wherein Y is oxygen or nitrogen, and wherein X is an atom or an atomic group with a negative charge. The negative charge is usually localized to oxygen atoms by release of a proton of carboxy or sulfo groups, phosphoric acid residues, acidic phenolic or enolic hydroxy groups. According to a preferred embodiment, the particle contains at least one alkylamidoalkylenedimethylcarboxylic acid betaine of the formula (IV):

wherein d and e, independently of one another, are integers of 1-4, preferably d is 2 or 3 and e is 2 or 3 and wherein R ^{12 is} a C _10-18 alkyl chain or mixtures thereof.

in der R¹³ für -H, -CH₃, einen C_2-24-Alkyl- oder -Alkenylrest, einen substituierten C_2-24-Alkyl- oder -Alkenylrest mit mindestens einem Substituenten aus der Gruppe -Cl, -Br, -OH, -NH₂, -CN, einen Alkyl- oder Alkenylarylrest mit einer C_1-24-Alkylgruppe, oder für einen substituierten Alkyl- oder Alkenylarylrest mit einer C_1-24-Alkylgruppe und mindestens einem weiteren Substituenten am aromatischen Ring steht, R¹⁴ und R¹⁵ unabhängig voneinander ausgewählt sind aus -CH₂-CN, -CH₃, -CH₂-CH₃, -CH₂-CH₂-CH₃, -CH(CH₃)-CH₃, -CH₂-OH, -CH₂-CH₂-OH, -CH(OH)-CH₃, -CH₂-CH₂-CH₂-OH, -CH₂- CH(OH)-CH₃, -CH(OH)-CH₂-CH₃, -(CH₂CH₂-O)_nH mit n gleich 1, 2, 3, 4, 5 oder 6 und X^– ein Anion ist. Dabei steht X^– nach einer bevorzugten Ausführungsform für ein Anion, das aus der Gruppe Chlorid, Bromid, Iodid, Hydrogensulfat, Methosulfat, Laurylsulfat, Dodecylbenzolsulfonat, p-Toluolsulfonat (Tosylat), Cumolsulfonat oder Xylolsulfonat oder deren Mischungen ausgewählt ist.Also cationic nitrile can be used with advantage. According to a preferred embodiment, the particle contains at least one cationic nitrile of the formula (V)

in the R ^{13 is} -H, -CH ₃ , a C _2-24 -alkyl or -alkenyl radical, a substituted C _2-24 -alkyl or -alkenyl radical having at least one substituent from the group -Cl, -Br, - OH, -NH ₂ , -CN, an alkyl or alkenylaryl radical having a C _1-24 -alkyl group, or represents a substituted alkyl or alkenylaryl radical having a C _1-24 -alkyl group and at least one further substituent on the aromatic ring, R ¹⁴ and R ^{15 are} independently selected from -CH ₂ -CN, -CH ₃ , -CH ₂ -CH ₃ , -CH ₂ -CH ₂ -CH ₃ , -CH (CH ₃ ) -CH ₃ , -CH ₂ - OH, -CH ₂ -CH ₂ -OH, -CH (OH) -CH ₃ , -CH ₂ -CH ₂ -CH ₂ -OH, -CH ₂ - CH (OH) -CH ₃ , -CH (OH) - CH ₂ -CH ₃ , - (CH ₂ CH ₂ -O) _n H where n is 1, 2, 3, 4, 5 or 6 and X ^{- is} an anion. In this case, X ^- in a preferred embodiment is an anion which is selected from the group consisting of chloride, bromide, iodide, hydrogensulfate, methosulfate, lauryl sulfate, dodecylbenzenesulfonate, p-toluenesulfonate (tosylate), cumene sulfonate or xylenesulfonate or mixtures thereof.

in der R¹⁶, R¹⁷ und R¹⁸ unabhängig voneinander ausgewählt sind aus -CH₃, -CH₂-CH₃, -CH₂-CH₂-CH₃, -CH(CH₃)-CH₃, wobei R¹⁶ zusätzlich auch -H sein kann und X ein Anion ist, wobei vorzugsweise R¹⁷ = R¹⁸ = -CH₃ und insbesondere R¹⁶ = R¹⁷ = R¹⁸ = -CH₃ gilt und Verbindungen der Formeln (CH₃)₃N⁽⁺⁾CH₂-CN X^–, (CH₃CH₂)₃N⁽⁺⁾CH₂-CN X^–, (CH₃CH₂CH₂)₃N⁽⁺⁾CH₂-CN X^–, (CH₃CH(CH₃))₃N⁽⁺⁾CH₂-CN X^–, oder (HO-CH₂-CH₂)₃N⁽⁺⁾CH₂-CN X^– besonders bevorzugt sind. Dabei steht X^– nach einer bevorzugten Ausführungsform für ein Anion, das aus der Gruppe Chlorid, Bromid, Iodid, Hydrogensulfat, Methosulfat, Laurylsulfat, Dodecylbenzolsulfonat, p-Toluolsulfonat (Tosylat), Cumolsulfonat oder Xylolsulfonat oder deren Mischungen ausgewählt ist.According to a preferred embodiment, the particle contains at least one cationic nitrile of the formula (VI)

in which R ¹⁶ , R ¹⁷ and R ^{18 are} independently selected from -CH ₃ , -CH ₂ -CH ₃ , -CH ₂ -CH ₂ -CH ₃ , -CH (CH ₃ ) -CH ₃ , wherein R ¹⁶ additionally also can be -H and X is an anion, preferably R ¹⁷ = R ¹⁸ = -CH ₃ and in particular R ¹⁶ = R ¹⁷ = R ¹⁸ = -CH ₃ and compounds of the formulas (CH ₃ ) ₃ N ⁽⁺⁾ CH ₂ -CN X ^- , (CH ₃ CH ₂ ) ₃ N ⁽⁺⁾ CH ₂ -CN X ^- , (CH ₃ CH ₂ CH ₂ ) ₃ N ⁽⁺⁾ CH ₂ -CN X ^- , (CH ₃ CH ( CH _{3)) 3} N ⁽⁺⁾ CH ₂ -CN X ^-, or (HO-CH ₂ -CH _{2) 3} N ⁽⁺⁾ CH ₂ -CN X ^- are particularly preferred. In this case, X ^- in a preferred embodiment is an anion which is selected from the group consisting of chloride, bromide, iodide, hydrogensulfate, methosulfate, lauryl sulfate, dodecylbenzenesulfonate, p-toluenesulfonate (tosylate), cumene sulfonate or xylenesulfonate or mixtures thereof.

Also amides can be used with advantage. In a preferred embodiment, the particle contains an amide, preferably an amide of the formula R ₁₉ R ₂₀ NCOR ₂₁ , wherein R ₁₉ and R _{20 are} independently C ₁ -C ₂₂ alkyl, C ₁ -C ₂₂ alkenyl, C C ₁ -C ₂₂ hydroxyalkyl, aryl and alkyl aryl groups are selected; R _{21 is} hydrogen or a C ₁ -C ₂₂ alkyl, C ₁ -C ₂₂ alkenyl, aryl or alkyl aryl group, or OR ₂₂ wherein R _{22 is} a C ₁ -C ₂₂ alkyl, C ₁ -C ₂₂ alkenyl, an aryl or alkyl aryl group, wherein the amide is contained in particular in amounts of 1% to 10%, based on the entire particle.

Also imidazoline (derivatives) can be used with advantage. According to a preferred embodiment, the particle contains imidazoline (derivatives), preferably imidazolines of the formula 1- (R ₂₃ ) amido (R ₂₄ ) -2- (R ₂₅ ) imidazoline, wherein R ₂₃ , R _{25 are} independently C ₁₂ -C ₂₂ Alkyl are selected and R _{24 is selected} from C ₁ -C ₄ alkyl, in particular in amounts of 1 wt .-% to 10 wt .-%, based on the total particle.

Also organic humectants can be used with advantage, as they lead to a more efficient deposition fabric softening phyllosilicates on textiles. To a preferred embodiment contains the particle organic humectant, which in particular from glycerol, ethylene glycol, propylene glycol, dimers and trimers of glycerol and / or mixtures thereof, preferably in amounts from 0.1% to 30% by weight based on the total particle.

Also Complexing agents can be used with advantage. In a preferred embodiment, the particle contains a complexing agent, preferably phosphonate and / or a citrate, in particular in amounts of 0.1 wt .-% to 10 wt .-% based on the entire particle.

Also, pentaerythritol (derivatives) can be used with advantage because they the Wäscheweichmacheffekt, z. As the phyllosilicates, continue to improve. According to a preferred embodiment, the particle contains pentaerythritol (derivatives), such as preferably a C ₂ -C ₂₄ aliphatic acid ester of pentaerythritol, in particular in amounts of 0.1 to 30 wt .-%, based on the total particle.

Alkali silicate can also be used with advantage. According to a preferred embodiment, the particle contains alkali silicate, preferably with a modulus M ₂ O: SiO ₂ in the range from 1: 1.9 to 1: 3.3, where M is an alkali metal ion. According to a preferred embodiment, the particle contains amorphous sodium silicate, preferably with a modulus of Na ₂ O: SiO ₂ in the range from 1: 2 to 1: 2.8.

• (a) Alkalimetallcarbonat und/oder Alkalimetallbicarbonat, und/oder
• (b) Sulfate, vorzugsweise Alkalimetall- und Erdalkalimetallsulfate, wobei Natrium- und Magnesiumsulfat und insbesondere Natriumsulfat deutlich bevorzugt sind, und/oder
• (c) Kieselsäuren, vorzugsweise Fällungskieselsäuren, insbesondere die Kieselgele, welche vorteilhafterweise hydrophob oder hydrophil sind, und/oder
• (d) Trägerstoffe aus der Gruppe der Tenside, Tensidcompounds, Citrate, Alkalimetallphosphate, Chitinmikrokügelchen, Pektin, Gumme, Gelatine, Harze, Stärken, insbesondere poröse Stärke, modifizierte Stärken und/oder Carboxyalkylstärken, Di- und/oder Polysaccharide, Cyclodextrine, Maltodextrine, (Co-)Polymere, vorzugsweise synthetische (Co-)Polymere, insbesondere wasserlösliche (Co-)Polymere und/oder Terpolymere und/oder Mischungen davon.

The particles may also contain further carrier material, preferably selected from

• (a) alkali metal carbonate and / or alkali metal bicarbonate, and / or
• (b) sulfates, preferably alkali metal and alkaline earth metal sulfates, with sodium and magnesium sulfate, and especially sodium sulfate being clearly preferred, and / or
• (c) silicic acids, preferably precipitated silicas, in particular the silica gels, which are advantageously hydrophobic or hydrophilic, and / or
• (d) excipients from the group of surfactants, surfactant compounds, citrates, alkali metal phosphates, chitin microspheres, pectin, gums, gelatin, resins, starches, in particular porous starch, modified starches and / or carboxyalkyl starches, di- and / or polysaccharides, cyclodextrins, maltodextrins, (Co) polymers, preferably synthetic (co) polymers, in particular water-soluble (co) polymers and / or terpolymers and / or mixtures thereof.

• a) Homopolymere, gewählt aus Polyvinylcompounds wie vorzugsweise Polyvinylacetate, Polyvinylalkohol und/oder Polyvinylpyrrolidon, Polycarboxysäuren wie vorzugsweise Polyacrylsäure und/oder Polymethacrylsäure; Polysulfonsäuren, wie vorzugsweise Polystyrolsulfonsäuren, Polyester, wie vorzugsweise Glycolpolyacrylate; Polyamide, Polyacrylamide, Polyurethane, vorzugsweise Polyurethane, die ionische Gruppen tragen, beispielweise Carboxygruppen, Sulfonsäuregruppen oder tertiäre Amine oder Polyurethane, welche vorzugsweise nichtionische hydro-phile Gruppen enthalten, wie Ethylenoxid, Polyethylenoxid, Polypropylenoxid und Polyalkylenglycolderivative
• b) Polykondensate, wie vorzugsweise ethoxyliertes Phenol, Formaldehydharze, vor-zugsweise sulfonierte aromatische Formaldehydharze, Harnstoff oder Melamine, Formaldehydcompounds, Polyamide, Polyamine, und Epichlorohydrinharze
• c) AB-Copolymere worin A eine mehr wasserlösliche oder in Wasser quellbare Gruppe und B eine weniger wasserlösliche oder in Wasser weniger quellbare Gruppe darstellt, vorzugsweise ausgewählt aus Styrolcopolymeren, wie insbesondere Styrol-Acrylsäure-Polymere oderr Styrol-Ethylenoxid-Polymere, Copolymer von Polyvinyl und Maleinsäurecompounds, wie vorzugsweise Styrol-Malein-säureanhydrid-Polymere oder Vinylacetate, Maleinsäureester-Polymere, Polyvinyl-Polyalkylen-Copolymere, wie vorzugsweise Vinylacetat-Ethylen-Ppolymere, Ethylen-Acrylsäure-Acrylsäureester-Polymere oder Ethylen-Acrylsäure-Acrylonitril-Polymere, Vinylcopolymere, wie vorzugsweise Vinylacetate-Polymere, Acrylsäure-Acrylonitril-Polymere, Acrylsäure-Acrylamidpolymere;
• d) ABA Blockcopolymere wobei "A" für wasserlösliche oder in Wasser quellfähige Gruppen steht wie vorzugsweise Polyethylenoxid, Polyvinylalkohol, Polyacrylamid, Polyacrylicsäure, Polyvinylpyrrolidon, oder Polycaprolacton und "B" für weniger wasserlösliche oder kaum wasserlösliche Gruppen steht, wie vorzugsweise Polypropylenoxid, Polyvinylacetat, Polyvinylbutyral, Polylaurylmethacrylat, Polystyrol, Polyhydroxystearinsäure, Polysiloxane,
• e) AB-Pfropf-(Co)-Polymere, wobei "A" wasserlösliche oder in Wasser quellfähige Gruppen wie vorzugsweise Vinylalkohol, Vinylacetat, Ethylenoxid, Propylenoxide, Vinylsulphonate, Acrylsäuren und Vinylamine sind, "B" ist vorzugsweise ausgewählt aus Vinylpolymer oder Siloxan.
• f) Natürliche Polymere wie vorzugsweise Cellulosederivative, wie insbesondere Carboxymethylcellulose, Hydroxypropylmethylcellulose, Methylcellulose und/oder deren Derivate.

Accordingly, the support material may at least partially also comprise one or more (co) polymers as a carrier, which are preferably at least partially selected from the following groups

• a) homopolymers selected from polyvinyl compounds such as preferably polyvinyl acetates, polyvinyl alcohol and / or polyvinylpyrrolidone, polycarboxylic acids such as preferably polyacrylic acid and / or polymethacrylic acid; Polysulfonic acids, such as, preferably, polystyrenesulfonic acids, polyesters, such as, preferably, glycol polyacrylates; Polyamides, polyacrylamides, polyurethanes, preferably polyurethanes which carry ionic groups, for example carboxy groups, sulfonic acid groups or tertiary amines or polyurethanes which preferably contain nonionic hydrophilic groups, such as ethylene oxide, polyethylene oxide, polypropylene oxide and polyalkylene glycol derivatives
• b) polycondensates, such as preferably ethoxylated phenol, formaldehyde resins, preferably sulfonated aromatic formaldehyde resins, urea or melamines, formaldehyde compounds, polyamides, polyamines, and epichlorohydrin resins
• c) AB copolymers wherein A is a more water-soluble or water-swellable group and B is a less water-soluble or less water-swellable group, preferably selected from styrene copolymers, in particular styrene-acrylic acid polymers or styrene-ethylene oxide polymers, copolymer of polyvinyl and maleic acid compounds, such as preferably styrene-maleic anhydride polymers or vinyl acetates, maleic ester polymers, polyvinyl-polyalkylene copolymers, such as preferably vinyl acetate-ethylene copolymers, ethylene-acrylic acid-acrylic acid ester polymers or ethylene-acrylic acid-acrylonitrile polymers, vinyl copolymers , such as preferably vinyl acetate polymers, acrylic acid-acrylonitrile polymers, Acrylic acid-acrylamide polymers;
• d) ABA block copolymers wherein "A" stands for water-soluble or water-swellable groups such as preferably polyethylene oxide, polyvinyl alcohol, polyacrylamide, polyacrylic acid, polyvinylpyrrolidone, or polycaprolactone and "B" stands for less water-soluble or sparingly water-soluble groups, such as preferably polypropylene oxide, polyvinyl acetate, polyvinyl butyral , Polylauryl methacrylate, polystyrene, polyhydroxystearic acid, polysiloxanes,
• e) AB graft (co) polymers, wherein "A" are water-soluble or water-swellable groups such as preferably vinyl alcohol, vinyl acetate, ethylene oxide, propylene oxides, vinylsulphonates, acrylic acids and vinylamines, "B" is preferably selected from vinyl polymer or siloxane.
• f) Natural polymers such as preferably cellulose derivatives, in particular carboxymethylcellulose, hydroxypropylmethylcellulose, methylcellulose and / or derivatives thereof.

Especially these are polymers, which are preferably at least partially Contain monomers selected are from isobutyl methacrylate, n-butyl acrylate, n-butyl methacrylate, Isobutyl acrylate, n-propyl acrylate, isopropyl methacrylate, methyl methacrylate, Styrene, decyl (meth) acrylate, dodecyl (meth) acrylate, tetradecyl (meth) acrylate and / or hexa-decyl (meth) acrylate and mixtures of these.

To a preferred embodiment contains the particle is an acidic component, preferably carboxylic acid, advantageously polycarboxylic especially citric acid, Adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA), if such an application for ecological reasons not objectionable, and / or mixtures of these, preferably each in the form of their sodium salts.

To a preferred embodiment contains the particle comprises at least one bleaching agent, preferably selected from the group comprising perborates, especially sodium perborate tetrahydrate and sodium perborate monohydrate, percarbonates, peroxypyrophosphates, Citrated perhydrates, persalts and peracids, in particular perbenzoates, Peroxophthalates, diperazelaic acid, Phthaloiminopersäure and diperdodecanedioic acid.

To a preferred embodiment contains the particle at least one more usually in washing or Detergents contained substance, preferably a substance from the group of surfactants, builders (inorganic and organic builders), bleaches, bleach activators, bleach stabilizers, Bleach catalysts, enzymes, special polymers (e.g. those with cobuilder properties), grayness inhibitors, optical Brighteners, UV protection substances, Soil repellents, electrolytes, colorants, fragrances, fragrances, Perfume carrier, pH adjuster, complexing agent, Fluorescers, foam inhibitors, anti-crease agents, antioxidants, quaternary Ammonium compounds, antistatic agents, ironing aids, UV absorbers, Anti redeposition agents, germicides, antimicrobial agents, Fungicides, viscosity regulators, Pearlescers, color transfer inhibitors, Inlet preventer, corrosion inhibitors, preservatives, Plasticizer, softener, Protein hydrolysates, repellents and impregnating agents, hydrotropes, silicone oils and Swelling and Slip Resistance.

• a) Wachse wie Carnauba-, Walrat-, Bienenwachs, Lanolin und/oder entsprechende Derivate;
• b) hydrophobe Pflanzenextrakte
• c) Kohlenwasserstoffe wie Squalen und/oder Squalan;
• d) höhere Fettsäuren, vorzugsweise mit mindestens 12 Kohlenstoffatomen insbesondere Laurin-, Myristin-, Palmitin-, Stearin-, Behen-, Öl-, Linol-, Linolen-, Lanolin-, Isostearin- und polyungesättigte Fettsäuren;
• e)) höhere Fettalkohole, vorzugsweise mit mindestens 12 Kohlenstoffatomen insbesondere Lauryl-, Cetyl-, Stearyl-, Oleyl-, Behenyl-, Cholesterin- and 2-Hexadecanol-Alkohol;
• f) Ester wie Cetyloctanoat, Lauryllactat, Myristyllactat, Cetyllactat, Isopropylmyristat, Myristylmyristat, Isopropylpalmitat, Isopropyladipat, Butylstearat, Decyloleat, Cholesterolisostearat, Glycerolmonostearat, Glyceroldistearat, Glyceroltristearat, Alkyllactat, Alkylcitrat und/oder Alkyltartrat;
• g) Lipide wie z. B. Cholesterin, Ceramide, Saccharoseester und/oder Pseudo-Ceramides
• h) Vitamine wie z. B. Die Vitamine A und E, Vitamin-Alkylester wie z. B. Vitamin C-Alkylester;
• i) Sonnenschutzmittel wie z. B. oder Butylmethoxybenzoylmethan
• j) Phospholipide;
• k) alpha-Hydroxysäuren und/oder deren Derivative
• l) Germicide, wie z. B. synthetische antimikrobielle Mittel wie z. B. 2-Phenoxyethanol und/oder natürliche antimikrobielle Mittel wie z. B. Grapefruitextract oder Weidenrindenextrakt;
• m) Mischungen aus vorgennaten Stoffen.

According to a preferred embodiment, the particle contains at least one substance selected from the following groups:

• a) waxes such as carnauba, spermaceti, beeswax, lanolin and / or corresponding derivatives;
• b) hydrophobic plant extracts
• c) hydrocarbons such as squalene and / or squalane;
• d) higher fatty acids, preferably having at least 12 carbon atoms, in particular lauric, myristic, palmitic, stearic, behenic, oleic, linoleic, linolenic, lanolin, isostearic and polyunsaturated fatty acids;
• e)) higher fatty alcohols, preferably having at least 12 carbon atoms, in particular lauryl, cetyl, stearyl, oleyl, behenyl, cholesterol and 2-hexadecanol alcohol;
• f) esters such as cetyloctanoate, lauryl lactate, myristyl lactate, cetyl lactate, isopropyl myristate, myristyl myristate, isopropyl palmitate, isopropyl adipate, butyl stearate, decyl oleate, cholesterol isostearate, glycerol monostearate, glycerol distearate, glycerol tristearate, alkyl lactate, alkyl citrate and / or alkyl tartrate;
• g) lipids such. As cholesterol, ceramides, sucrose esters and / or pseudo-ceramides
• h) vitamins such. B. Vitamins A and E, vitamin alkyl esters such. For example, vitamin C alkyl esters;
• i) sunscreens such. B. or butylmethoxybenzoylmethane
• j) phospholipids;
• k) alpha-hydroxy acids and / or their derivatives
• l) germicides such. B. synthetic antimicrobial agents such. For example, 2-phenoxyethanol and / or natural antimicrobial agents such. Grapefruit extract or willow bark extract;
• m) mixtures of selected substances.

advantageously, can the aforementioned substances of the skin are beneficial. Your Incorporation into the particles according to the invention is therefore particularly then advantageous if the particles of the invention subject of Textile care component to be. So it's not just the textile cared for, but also the skin, because the aforementioned substances can both textile treatment (eg textile washing) on the textile fibers raise and be delivered from there to the skin and this then to the advantage.

To a preferred embodiment the particle is at least partly surrounded by a coating.

To a further preferred embodiment The invention is the carrier material or the particle at least partially from a coating is surrounded, which preferably at least one at least partially water-soluble or at least partially water-dispersible component contains which in particular chosen is made of polyols, carbohydrates, starches, modified starches, starch hydrolysates, Cellulose and cellulose derivatives, natural and synthetic gums, Silicates, borates, phosphates, chitin and chitosan, water-soluble Polymers, fat components and mixtures of these. For example Waxes and / or resins are also suitable, for. B. beeswax, Benzo resin, carnauba wax, candelilla wax, coumarone-inden resin, Copal, shellac, mastic, polyethylene wax oxidates or sandarak resin. Likewise, paraffins or gelatin, in particular cellulose ethers suitable.

To a further preferred embodiment has the optional coating polycarboxylates.

The optional coating of the particles can be made in the state of the art Technique described ways are performed. The coating material surrounds the particular particle preferably completely, but also a disconnected one Coating desired can be. As coating materials, especially those in Question, which commonly used in the context of detergents or cleaning agents become.

Materials, used as coating materials in the context of the invention can be are any inorganic and / or organic substances and / or Mixtures of substances, preferably those, the pH, temperature and / or Ionic strength-sensitive are so they dependent on a pH, temperature and / or ionic strength change lose their integrity, i.e. for example, dissolve completely or partially.

Especially preferred as potential coating materials are polymers and / or copolymers which have film-forming properties and are preferably from aqueous dispersion can be inserted. The decisive size for the film-forming properties is the glass transition temperature the film-forming polymer and / or copolymer. Above the glass temperature the polymer or copolymer is elastic, meltable and flowable while it is below the glass transition temperature brittle becomes. Only above the glass transition temperature For example, the polymer can be easily processed as it is for forming a film overlay is required. The glass transition temperature can be made softening by the addition of low molecular weight substances Properties, the so-called plasticizers are influenced. In addition to the polymer so can in the aqueous dispersion also plasticizers can be used. As plasticizers, all substances are suitable the glass transition temperature the used, preferably pH-sensitive, polymers and / or copolymers decrease. The polymer can thus at lower temperatures, if necessary even applied at room temperature. Especially preferred Plasticizers are citric acid esters (preferably tributyl citrate and / or triethyl citrate), phthalic acid ester (preferably dimethyl phthalate, diethyl phthalate and / or dibutyl phthalate), Esters of organic polyhydric alcohols (preferably glycerol triacetate), Polyalcohols (preferably glycerol, propylene glycol) and / or polyoxyethylene glycols (preferably polyethylene glycol). The plasticizer is intercalated the polymer chains, increased thereby the mobility, lowers the interactions and avoids by reducing the brittleness Abrasion and cracks in the film.

Especially it is advantageous if the optional coating material Polyacrylate and / or a derivative thereof and / or a corresponding Copolymer based on acrylic acid esters or acrylic acids and contains other monomers. In particular, copolymers of acrylamide and acrylic acid and / or derivatives thereof are for the optional coating material of advantage.

If the carrier material or the particle at least partially has a coating, wel at least partially water-soluble or at least partially water-dispersible component comprising from 0% to 80% by weight of at least one solid polyol having preferably more than 3 hydroxyl radicals and from 20% to 100% by weight of a liquid diol or polyol in which the perfume is substantially insoluble and in which the solid polyol is substantially soluble, said liquid polyol or diol preferably being selected from glycerol, ethylene glycol and diglycerol or mixtures thereof, and wherein the solid Polyol is preferably selected from glucose, sorbitol, maltose, glucamine, sucrose, polyvinyl alcohol, starch, alkylpolyglycoside, sorbitan fatty acid esters, polyhydroxy fatty acid amides whose fatty acid radicals contain 1 to 18 carbon atoms, and mixtures thereof, there is a further preferred embodiment of the invention.

To a preferred embodiment the particle is colored. The particle can be colored through or its surface can be colored or it can be coated or coated with a colored substance be.

Preferably, the particle can be dyed over a coating. In a preferred embodiment, the coating comprises pigments, advantageously in the nanoscale range or in the micrometer range, preferably white pigments, in particular selected from titanium dioxide pigments, in particular anatase pigments and / or rutile pigments, zinc sulfide pigments, zinc oxide (zinc white), Antimony trioxide (antimony white), basic lead carbonate (lead white) 2PbCO ₃ · Pb (OH) ₂ , lithopone ZnS + BaSO ₄ . Preferably, white auxiliaries, such as preferably calcium carbonate, talc 3MgO · 4SiO ₂ · H ₂ O and / or barium sulfate may be included.

• (a) Buntpigmente (vorzugsweise anorganische Buntpigmente, insbesondere Eisenoxid-Pigmente, Chromat-Pigmente, Eisenblau-Pigmente, Chromoxid-Pigmente, Ultramarin-Pigmente, oxidische Mischphasenpigmente und/oder Bismutvanadat-Pigmente),
• (b) Schwarzpigmente (z. B. Anilinschwarz, Perylenschwarz, Eisenoxid-Pigmente, Manganschwarz und/oder Spinellschwarz),
• (c) Glanzpigmente (vorzugsweise plättchenförmige Effektpigmente, Metalleffektpigmente wie z. B. Aluminium-Pigmente (Silberbronze), Kupfer-Pigmente und Kupfer/Zink-Pigmente (Goldbronzen) und Zink-Pigmente, Perlglanzpigmente, wie z. B. Magnesiumstearat, Zinkstearat, Lithiumstearat oder Ethylenglykoldistearat bzw. Polyethylenterephthalat, Interferenzpigmente wie z. B. Metalloxid-Glimmer-Pigmente) und/oder
• (d) Lumineszenzpigmente wie z. B. Azomethinfluoreszenzgelb, Silber-dotierte und/oder Kupfer-dotierte Zinksulfid-Pigmente handeln.

In another preferred embodiment, the pigments may be um

• (a) colored pigments (preferably inorganic colored pigments, in particular iron oxide pigments, chromate pigments, iron blue pigments, chromium oxide pigments, ultramarine pigments, mixed oxide phase pigments and / or bismuth vanadate pigments),
• (b) black pigments (eg aniline black, perylene black, iron oxide pigments, manganese black and / or spinel black),
• (c) luster pigments (preferably flaky effect pigments, metallic effect pigments such as, for example, aluminum pigments (silver bronze), copper pigments and copper / zinc pigments (gold bronze) and zinc pigments, pearlescent pigments, such as, for example, magnesium stearate, zinc stearate, Lithium stearate or ethylene glycol distearate or polyethylene terephthalate, interference pigments such as, for example, metal oxide mica pigments) and / or
• (d) luminescent pigments such as e.g. B. Azomethinfluoreszenzgelb, silver-doped and / or copper-doped zinc sulfide pigments act.

Lies the particle size of the individual Particles substantially between 0.005 and 2.0 mm, so it is It is a further preferred embodiment of the invention. Of the Expression "im essential "means here that at least 40 wt .-%, advantageously at least 50 wt .-%, in a further advantageous manner at least 60% by weight, more preferably at least 70% Wt .-%, preferably at least 80 wt .-%, in particular 90 wt .-% the particles of this particle size requirement fulfill.

If the particles of the invention agglomerated, wherein the agglomerate size is preferably substantially 100-2000 μm, in particular is substantially 100-800 microns, so is again a preferred embodiment of the invention. The term "substantially" here means that at least 40 wt .-%, advantageously at least 50 wt .-%, in a further advantageous manner at least 60% by weight, more preferably at least 70% Wt .-%, preferably at least 80 wt .-%, in particular 90 wt .-% Agglomerates have said agglomerate size. These agglomerated Particles preferably disintegrate again on contact with water into the smaller primary particles from which the agglomerates are / were composed. In some make the agglomerate size can even in the range of 0.1 to 30 mm, if the application technology he wishes is.

The particles according to the invention can have any shape. In a most preferred embodiment but the particle is spherical (Spherical) or at least approximate spherical or approximate ellipsoid shaped. The ellipsoid is similar to the sphere, but the longitudinal axis and transverse axis are different.

• (a) kubisch geformt (würfelförmig) oder zumindest annähernd kubisch geformt, oder
• (b) parallelepiped geformt (z. B. quaderförmig) oder zumindest annähernd parallelepiped geformt, oder
• (c) lamellar geformt (plättchenförmig und ähnliches) oder zumindest annähernd lamellar geformt, oder
• (d) nadelartig oder faserartig geformt oder zumindest annähernd nadelartig oder faserartig geformt.

In other embodiments, the particle is more likely

• (a) cubic (cube-shaped) or at least approximately cubic, or
• (b) shaped parallelepiped (eg cuboid) or at least approximately parallelepiped shaped, or
• (c) lamellar (platy and the like) or at least approximately lamellar, or
• (d) needle-like or fibrous-shaped or at least approximately needle-like or fibrous-shaped.

One Another object of the present invention is the use of the particles of the invention as a washing or cleaning agent or as an additive to washing or Detergents.

• a) die Bereitstellung Zeolith und Schichtsilikat umfassenden Trägermaterials, vorzugsweise auf Basis von wässrigen Suspensionen, welche vorteilhafterweise auch Niotensid und ggf. weitere anorganische und organische Bestandteile, umfassen, wobei die wässrigen Suspensionen anschließend getrocknet werden, danach
• b) gegebenenfalls das Imprägnieren des Trägermaterials mit zumindest einem Niotensid, sowie
• c) das Beladen des Trägermaterials mit Parfüm durch Vermischen von Parfüm und (imprägniertem) Trägermaterial und/oder durch Versprühen von Parfüm auf das (imprägnierte) Trägermaterial, sowie

optional die Beschichtung des parfümierten Trägermaterials.Another object of the present invention is a process for the preparation of particles according to the invention, comprising

• a) the provision of zeolite and phyllosilicate comprehensive carrier material, preferably based on aqueous suspensions, which advantageously also nonionic surfactant and optionally further inorganic and organic constituents, wherein the aqueous suspensions are then dried, thereafter
• b) optionally impregnating the support material with at least one nonionic surfactant, and
• c) the loading of the carrier material with perfume by mixing perfume and (impregnated) carrier material and / or by spraying perfume on the (impregnated) carrier material, and

optionally the coating of the perfumed carrier material.

According to the method step a) the provision of the carrier material according to the invention, preferably based on aqueous Suspensions of inorganic and organic components, advantageously Nonionic surfactant include, wherein the aqueous Suspensions then be dried. Preferably, a carrier material is used, that contains nonionic surfactant.

Especially in this case it is preferred if, during the drying, the aqueous Suspension in the drying material carbon dioxide is generated.

With Drying is in the broadest sense every technical drying possibility meant with which to add water and / or other solvents from the watery Suspensions can be removed so extensively that at the end of drying particles, i.e. particulate Solids are produced which are the desired Form carrier material. These particles must Naturally not entirely solvent-free and / or anhydrous, for example, they can still significant amounts solvent and / or water, but preferably they have water content below 30 wt .-%, advantageously below 25 wt .-%, in particular below 20 wt .-%, in each case based on the end of the drying accumulating solid. The water content can also be lower, though the desired is, for example, below 15 wt .-% or below 10 wt .-% or below 5 wt .-%, each based on the costs incurred at the end of the drying Solid.

to Drying is advantageously supplied to the material to be dried heat. The Drying can preferably be carried out in cocurrent, countercurrent or crossflow. According to the type of heat supply be z. B. contact dryer, convection dryer and radiation dryer distinguished. Depending on the pressure prevailing in the dryer pressure z. In overpressure, Normal pressure and vacuum dryers are divided. In convection drying gets the heat to the material to be dried predominantly by hot Transmit gases (air or inert gas), which is preferred. Therefore be z. B. duct, chamber, belt, shaft, fluidized bed and / or spray dryer applied, which is preferred. In contact drying, which is also preferred, the heat transfer takes place via heat exchanger surfaces. To counting the contact dryers z. B. the roller, tube and cupboard dryer. Floor, plate, drum and paddle dryer work on both principles of heat.

One very preferred according to the invention Drying process is spray drying. Also preferred for drying are fluidized bed processes.

According to one preferred embodiment of the invention the aqueous suspension to be dried according to the invention Substance (s) which increased at Temperatures release carbon dioxide, preferably selected from Hydrogen carbonate compounds, citric acid and / or aconitic acid. at the bicarbonate compounds is the sodium bicarbonate prefers.

According to one another preferred embodiment of the invention the invention to be dried aqueous Suspension 0 to 40 wt .-%, preferably 0.1 to 4 wt .-%, in particular 1 to 3% by weight of citric acid, or 0 to 50 wt .-%, preferably 0.1 to 5 wt .-%, in particular 1 to 4% by weight of bicarbonate compound, or 0 to 40% by weight, preferably 0.1 to 10% by weight, in particular 1 to 5% by weight of aconitic acid.

It may also be advantageous mixtures of bicarbonate compounds, Citric acid and / or aconitic use, the total amount of such a 50 wt .-%, preferably 40 wt .-%, advantageously 20 wt .-%, but especially 10 wt .-% do not exceed should, and wherein a minimum total amount of 0.1 wt .-%, preferably 1 wt .-% should not fall below, in each case based on the entire suspension.

Surprised could be found that in such cases, during which the drying carbon dioxide is released, particles result, which is characterized by an even better absorption capacity for fragrances distinguished.

Contains the provided support material after production no nonionic surfactant, it follows according to a preferred embodiment the impregnation the carrier material according to the invention with at least one nonionic surfactant. Subsequently, the loading of the preferably nonionic surfactant carrier material with perfume Mixing or spraying, as just shown.

• – (A) erfindungsgemäße Teilchen
• – (B) 0, 01 Gew.-% bis 95 Gew.-%, vorzugsweise 5 Gew.-% bis 85 Gew.-%, vorteilhafterweise 3 Gew.-% bis 30 Gew.-%, insbesondere 5 Gew.-% bis 22 Gew.-% zusätzlicher Tensid(e).
• – (C) optional weitere Inhaltsstoffe von Wasch- oder Reinigungsmitteln.

Another object of the present invention is a detergent composition comprising:

• - (A) particles according to the invention
• - (B) 0, 01 wt .-% to 95 wt .-%, preferably 5 wt .-% to 85 wt .-%, advantageously 3 wt .-% to 30 wt .-%, in particular 5 wt .-% to 22% by weight of additional surfactant (s).
• - (C) optional other ingredients of detergents or cleaners.

in the The scope of this invention is within the concept of the detergent composition preferably detergents and / or cleaning agents and / or (textile) care agents and / or softening agents and / or softener compositions.

In a preferred embodiment is the detergent composition according to the invention a multipotent washing or cleaning agent. These are means with effects in several directions, so. z. B. 2-in-1 detergent. These detergents have components with washing or cleaning action and components having a further effect, in particular textile care or conditioning effect and / or skin care effect. This means skin care effect, that this Contains middle components, which indirectly serve the skin care, in that they the laundry go over to the textile and, if necessary, when wearing the textiles are then delivered to the skin. Corresponding substances have already been mentioned above.

One 3-in-1 detergent combines components with washing accordingly or cleaning action and components with two further effects, especially Textilpflege- or Avivagewirkung and skin care effect.

If the extra Surfactant anionic surfactant comprises, preferably in one portion of at least 50% by weight based on the total amount of additional Surfactants, this is a preferred embodiment, it being further preferred that the additional surfactant is a mixture from anionic and nonionic surfactants.

A detergent composition according to the invention, which at least one surfactant, preferably at least two from the Group of alkylbenzenesulfonates, alkyl ester sulfonates, alkyl ethoxylates, Alkyl phenol alkoxylates, alkyl polyglucosides, alkyl sulfates, alkyl ethoxy sulfate, secondary Alkyl sulfates and / or mixtures thereof, these additional Surfactants advantageously in amounts of 1% by weight to 75% by weight contained in the total composition preferred embodiment.

following Advantageous surfactants are described which contain in the detergent composition could be.

As anionic surfactants, for example, those of the sulfonate type and sulfates are used. As surfactants of the sulfonate type preferably come C _9-13 alkylbenzene sulfonates, olefin sulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as they are, for example, from C _12-18 monoolefins with terminal or internal double bond by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation obtained. Also suitable are alkanesulfonates selected from C _12-18 alkanes, for example by sulfochlorination or sulfo xidation be obtained with subsequent hydrolysis or neutralization. Likewise, the esters of α-sulfo fatty acids (ester sulfonates), z. As the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids suitable.

Further Suitable anionic surfactants are sulfated fatty acid glycerol esters. Among fatty acid glycerol esters are to understand the mono-, di- and triesters and their mixtures, such as they are produced by esterification of a monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol to be obtained. Preferred sulfated fatty acid glycerol esters are included the sulphonated products of saturated fatty acids with 6 to 22 carbon atoms, for example the caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or Behenic acid.

Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C ₁₂ -C ₁₈ fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C ₁₀ -C ₂₀ oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials. Of washing technology interest, the C ₁₂ -C ₁₆ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates and C ₁₄ -C ₁₅ alkyl sulfates are preferred. In addition, 2,3-alkyl sulfates, which are produced for example in accordance with US Patent No. 3,234,258 or 5,075,041 and can be obtained as commercial products from Shell Oil Company under the name DAN ^®, are suitable anionic surfactants.

Also, the Schwefelsäuremonoester the oxide with 1 to 6 moles of ethylene oxide ethoxylated straight-chain or branched C _7-21 alcohols, such as C 2-methyl-branched _9-11 alcohols containing on average 3.5 moles of ethylene (EO), or C _12-18 Fatty alcohols containing 1 to 4 EO are suitable. Due to their high foaming behavior, they are only used in detergents in relatively small amounts, for example in amounts of from 1 to 5% by weight.

Further suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols. Preferred sulfosuccinates contain C _8-18 fatty alcohol residues or mixtures of these. Particularly preferred sulfosuccinates contain a fatty alcohol residue derived from ethoxylated fatty alcohols, which by themselves are nonionic surfactants. Sulfosuccinates, whose fatty alcohol residues are derived from ethoxylated fatty alcohols with a narrow homolog distribution, are again particularly preferred. Likewise, it is also possible to use alk (en) ylsuccinic acid having preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.

When other anionic surfactants are especially soaps into consideration. Suitable are saturated fatty acid soaps, like the salts of lauric acid, myristic, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid and in particular of natural fatty acids, z. As coconut, palm kernel or tallow derived soap mixtures.

The including anionic surfactants the soaps can in the form of their sodium, potassium or ammonium salts and as soluble salts organic bases, such as mono-, di- or triethanolamine. The anionic surfactants are preferably in the form of their sodium or potassium salts, especially in the form of the sodium salts.

As nonionic surfactants (additional surfactants) are preferably alkoxylated, preferably ethoxylated, especially primary alcohols having preferably 8 to 18 carbon atoms and an average of 1 to 12 moles of ethylene oxide (EO) per mole of alcohol used in which the alcohol radical linear or preferably in 2- Position may be methyl branched or contain linear and methyl-branched radicals in the mixture, as they are usually present in Oxoalkoholresten. In particular, however, alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for. From coconut, palm, tallow or oleyl alcohol, and on average from 2 to 8 EO per mole of alcohol. The preferred ethoxylated alcohols include, for example, C _12-14 alcohols with 3 EO or 4 EO, C _9-11 alcohols with 7 EO, C _13-15 alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C _12-18 alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C _12-14 -alcohol with 3 EO and C _12-18 -alcohol with 5 EO. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number. Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE). Zusätz It is also possible to use fatty alcohols with more than 12 EO with these nonionic surfactants. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.

In addition, also alkyl glycosides of the formula RO (G) as further nonionic surfactants (additional surfactants) are _x employed in which R is a primary linear or methyl-branched, more particularly 2-methyl-branched, aliphatic radical containing 8 to 22, preferably 12 to 18 C Atom and G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4.

A another class of preferred nonionic surfactants used (additional Surfactants), either as the sole nonionic surfactant or used in combination with other nonionic surfactants, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having 1 to 4 carbon atoms in the alkyl chain, in particular fatty acid methyl ester, as described, for example, in Japanese Patent Application JP 58/217598 are described or preferably after that in the international Patent Application WO-A-90/13533 be prepared described methods.

Also nonionic surfactants of the amine oxide type, for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallow alkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamide can as additional Surfactants are suitable. The amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, in particular not more than half from that.

in der RCO für einen aliphatischen Acylrest mit 6 bis 22 Kohlenstoffatomen, R² für Wasserstoff, einen Alkyl- oder Hydroxyalkylrest mit 1 bis 4 Kohlenstoffatomen und [Z] für einen linearen oder verzweigten Polyhydroxyalkylrest mit 3 bis 10 Kohlenstoffatomen und 3 bis 10 Hydroxylgruppen steht. Bei den Polyhydroxyfettsäureamiden handelt es sich um bekannte Stoffe, die üblicherweise durch reduktive Aminierung eines reduzierenden Zuckers mit Ammoniak, einem Alkylamin oder einem Alkanolamin und nachfolgende Acylierung mit einer Fettsäure, einem Fettsäurealkylester oder einem Fettsäurechlorid erhalten werden können.Further suitable additional surfactants are polyhydroxy fatty acid amides of the formula

in which RCO is an aliphatic acyl radical having 6 to 22 carbon atoms, R ^{2 is} hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and [Z] is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups. The polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.

in der R für einen linearen oder verzweigten Alkyl- oder Alkenylrest mit 7 bis 12 Kohlenstoffatomen, R³ für einen linearen, verzweigten oder cyclischen Alkylrest oder einen Arylrest mit 2 bis 8 Kohlenstoffatomen und R⁴ für einen linearen, verzweigten oder cyclischen Alkylrest oder einen Arylrest oder einen Oxy-Alkylrest mit 1 bis 8 Kohlenstoffatomen steht, wobei C_1-4-Alkyl- oder Phenylreste bevorzugt sind und [Z] für einen linearen Polyhydroxyalkylrest steht, dessen Alkylkette mit mindestens zwei Hydroxylgruppen substituiert ist, oder alkoxylierte, vorzugsweise ethoxylierte oder propoxylierte Derivate dieses Restes.The group of polyhydroxy fatty acid amides also includes compounds of the formula

R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R ^{3 is} a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms and R ^{4 is} a linear, branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms, with C _1-4 alkyl or phenyl radicals being preferred and [Z] being a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated Derivatives of this residue.

[Z] is preferably by reductive amination of a reduced sugar obtained, for example, glucose, fructose, maltose, lactose, galactose, Mannose or xylose. The N-alkoxy or N-aryloxy-substituted compounds can then, for example, according to the teaching of international application WO-A-95/07331 by reaction with fatty acid methyl esters in the presence of an alkoxide as a catalyst in the desired Polyhydroxyfatty acid amides are transferred.

The detergent compositions according to the invention, such as. As cleaning, care and detergent may optionally contain cationic surfactants. Suitable cationic surfactants are, for example, surface-active quaternary compounds, in particular with an ammonium, sulfonium, phosphonium, iodonium or arsonium group, as described, for. B. in the art are also described as antimicrobial agents. Through the use of quaternary surface-active compounds with antimi the agent can be designed with an antimicrobial effect, or its antimicrobial effect, which may already be present due to other ingredients, can be improved.

Particularly preferred cationic surfactants are the quaternary, partially antimicrobial ammonium compounds (QAV, INCI quaternary ammonium compounds) according to the general formula (R ^I ) (R ^II ) (R ^III ) (R ^IV ) N ⁺ X ^- , in which R ^I to R ^IV identical or different C _1-22 alkyl radicals, C _7-28 -Aralkylreste or heterocyclic radicals, wherein two or in the case of an aromatic inclusion as in the pyridine even three radicals together with the nitrogen atom, the heterocycle, z. A pyridinium or imidazolinium compound, and X ^{- are} halide ions, sulfate ions, hydroxide ions or like anions. For optimum antimicrobial activity, preferably at least one of the radicals has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.

QAC are tertiary by implementation Amines with alkylating agents, such as. Methyl chloride, benzyl chloride, Dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary Amines with a long alkyl radical and two methyl groups succeed especially easy, also the quaternization of tertiary amines with two long residues and one methyl group can help with Methyl chloride be carried out under mild conditions. Amines, over three long alkyl radicals or hydroxy-substituted alkyl radicals are less reactive and are preferably quaternized with dimethyl sulfate.

Suitable QAVs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride, CAS No. 8001-54-5), benzalkone B (m, p-dichlorobenzyl-dimethyl-C ₁₂ -al-kylammonium chloride, CAS No. 58390 -78-6), benzoxonium chloride (benzyldodecyl-bis (2-hydroxyethyl) ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-timethyl-ammonium bromide, CAS No. 57-09-0), benzetonium chloride (N , N-dimethyl-N- [2- [2- [p- (1,1,3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzylammonium chloride, CAS No. 121-54-0), dialkyldimethylammonium chlorides such as N-decyl-dimethyl-ammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyldimethylammoniumchloric, 1-cetylpyridiniumchloride (CAS No. 123-03-5) and Thiazoline iodide (CAS No. 15764-48-1) and mixtures thereof. Preferred QACs are the benzalkonium chlorides having C ₈ -C ₁₈ -alkyl radicals, in particular C ₁₂ -C ₁₄ -alkyl-benzyl-dimethylammonium chloride. A particularly preferred QAC is Kokospentaethoxymethylammoniummetho sulfate (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

to Avoidance of possible incompatibilities of the antimicrobial cationic surfactants with in the detergent composition according to the invention contained anionic surfactants are possible aniontensidverträgliches and / or as possible little cationic surfactant used or in a particular embodiment the invention entirely dispensed with antimicrobial cationic surfactants.

When For example, antimicrobials can be used instead Parabens, benzoic acid and / or Benzoate, lactic acid, salicylic acid and / or lactates are used. Particularly preferred are benzoic acid and / or Lactic acid.

The detergent compositions according to the invention, such as cleaning, care and detergent, can be one or more cationic Surfactants in amounts, based on the total composition, from 0 to 5 wt .-%, greater 0 to 5 wt .-%, preferably 0.01 to 3 wt .-%, in particular 0.1 to 1 Wt .-% included.

Likewise, the detergent compositions according to the invention, such as cleaning, care and washing agents, may also contain amphoteric surfactants. Suitable amphoteric surfactants are, for example, betaines of the formula (R ¹⁾ (R ²⁾ (R ³⁾ N ⁺ CH ₂ CO ^- in which R ^{1 is} an optionally interrupted by hetero atoms or hetero atom groups alkyl radical having 8 to 25, preferably 10 to 21 carbon atoms, and R ² and R ^{3 are} identical or different alkyl radicals having 1 to 3 carbon atoms, in particular C ₁₀ -C ₂₂ -alkyldimethylcarboxymethylbetain and C ₁₁ -C ₁₇ -alkylamidopropyldimethylcarboxymethyl betaine. Furthermore, the use of Alkylamidoalkylaminen, alkyl-substituted amino acids, acylated amino acids or biosurfactants as amphoteric surfactants in the inventive compositions, such as cleaning, care and detergent, conceivable.

The detergent compositions according to the invention, such as cleaning, care and laundry detergents, one or more amphoteric Surfactants in amounts, based on the total composition, from 0 to 5 wt .-%, greater 0 to 5 wt .-%, preferably 0.01 to 3 wt .-%, in particular 0.1 to 1 Wt .-% included.

Next Builders are the most important ingredients in the wash-active substances of washing or cleaning agents, especially zeolites, silicates, Carbonates, organic cobuilders and - where no ecological prejudices against insist on their use - too the phosphates. The detergent compositions may accordingly be preferred in the particles of the invention existing builders also additional builders contain. Thus, the detergent composition still comprises at least 1 Wt .-% of an additional Detergent builder substance, such is another preferred embodiment of the invention, it being also preferred, if further customary for washing or cleaning agents additional ingredients are included.

As additional builders, for example and in particular those already mentioned are advantageous. Crystalline, layered sodium silicates or amorphous sodium silicates are preferably suitable. Zeolite, preferably zeolite A and / or P is also advantageous. As zeolite P zeolite MAP ^® (commercial product from Crosfield) is particularly preferred. Also suitable, however, are zeolite X and mixtures of A, X and / or P. Commercially available and preferably usable in the context of the present invention is, for example, a cocrystal of zeolite X and zeolite A (about 80% by weight of zeolite X) ), which is sold by the company CONDEA Augusta SpA under the brand name VEGOBOND AX ^® and by the formula nNa ₂ O · (1 - n) K ₂ O · Al ₂ O ₃ · (2 - 2.5) SiO ₂ · (3.5-5.5) H ₂ O can be described. The zeolite can be used both as a further builder, as well as used for a powdering of the particles. Suitable zeolites preferably have an average particle size of less than 10 microns (volume distribution, measuring method: Coulter Counter) and preferably contain 18 to 22 wt .-%, in particular 20 to 22 wt .-% of bound water.

Of course it is also a use of other common additional builders advantageous, for. B. the well-known phosphates as builders possible in the detergent composition, if such Use not ecological establish should be avoided. Particularly suitable are the sodium salts the orthophosphates, the pyrophosphates and in particular the tripolyphosphates.

useful organic builders For example, they can be used in the form of their sodium salts polycarboxylic like citric acid, adipic acid, Succinic acid, glutaric, Tartaric acid, Sugar acids, amino carboxylic acids, nitrilotriacetic (NTA), if such an operation is not for environmental reasons is objectionable, as well as mixtures of these. Preferred salts are the salts of polycarboxylic acids like citric acid, adipic acid, Succinic acid, glutaric, Tartaric acid, sugar acids and mixtures of these.

Next the components already mentioned can be further in washing or Cleaning agents usual ingredients, in particular from the group of bleaching agents, bleach activators, Enzymes, enzyme stabilizers, fluorescers, dyes, foam inhibitors, Silicone oils, Anti redeposition agents, optical brighteners, grayness inhibitors, Dye transfer inhibitors and corrosion inhibitors incorporated in the detergent composition be or be included. Further optional ones Ingredients preferably come from the group of oligo- and polymeric polycarboxylates, pH adjusters, fluorescers, anti-shrinkage agents, Wetting improvers, antimicrobial agents, germicides, fungicides, Antioxidants, antistatic agents, ironing aids, Phobic and impregnating agents, Swelling and slipping agents, chelating agents, fabric softeners and UV absorbers.

Among the compounds serving as bleaches in water H ₂ O ₂ , sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance. Further usable bleaching agents are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H ₂ O ₂ -producing peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, phthaloiminoperacid or diperdodecanedioic acid.

In order to achieve an improved bleaching effect when washing at temperatures of 60 ° C and below, bleach activators can be incorporated. As bleach activators, it is possible to use compounds which, under perhydrolysis conditions, give aliphatic peroxycarboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid. Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups. Preference is given to polyacylated alkylenediamines, in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglycoluril (TAGU), N- Acylimides, ins particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate and 2,5-diacetoxy-2, 5-dihydrofuran.

In addition to The conventional bleach activators or in their place may also so-called bleach catalysts are incorporated. In these Substances are bleach-enhancing transition metal salts or transition metal complexes such as Mn, Fe, Co, Ru or Mo saline complexes or carbonyl complexes. Also Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with N-containing tripod ligands and Co, Fe, Cu and Ru amine complexes are useful as bleach catalysts.

When Enzymes come from the class of proteases, lipases, amylases, Cellulases or mixtures thereof in question. Especially suitable are from bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis and Streptomyces griseus derived enzymatic agents. Before preferably proteases of the subtilisin type and in particular proteases derived from Bacillus lentus are used. These are enzyme mixtures, for example from protease and amylase or protease and lipase or protease and cellulase or from cellulase and lipase or from Protease, amylase and lipase or protease, lipase and cellulase, but especially cellulase containing mixtures of particular interest. Peroxidases or oxidases have in some cases as proved suitable. The enzymes can on carriers adsorbed and / or in coating substances be embedded to protect them against premature decomposition. Of the Proportion of the enzymes, enzyme mixtures or enzyme granules in the compositions according to the invention may, for example, about 0.1 to 5 wt .-%, preferably 0.1 to about 2 wt .-% amount.

In addition, the Compositions also contain components which reduce oil and grease washout from textiles positively influence (so-called soil repellents). This effect is particularly evident when a textile is dirty is, which previously several times with a detergent according to the invention, that this oil and fat-dissolving Component contains was washed. Among the preferred oil and fat dissolving components counting for example, nonionic cellulose ethers such as methyl cellulose and methylhydroxypropylcellulose with a proportion of methoxyl groups from 15 to 30% by weight and of hydroxypropoxyl groups from 1 to 15 Wt .-%, each based on the nonionic cellulose ether, and the known from the prior art polymers of phthalic acid and / or of terephthalic acid or of their derivatives, in particular polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionic and / or nonionically modified derivatives of these. Especially preferred of these are the sulfonated derivatives of phthalic acid and the terephthalic acid polymers.

The Compositions can as optical brightener derivatives of Diaminostilbendisulfonsäure or containing their alkali metal salts. Suitable z. B. salts of 4,4'-bis (2-anilino-4-morpholino-1,3,5-triazinyl-6-amino) stilbene-2,2'-disulphonic acid or similarly constructed compounds that replace the morpholino group a diethanolamino group, a methylamino group, an anilino group or carry a 2-methoxyethylamino group. Furthermore, brighteners the type of substituted Diphenylstyryle be present, for. B. the alkali salts of 4,4'-bis (2-sulfostyryl) -diphenyl, 4,4'-bis (4-chloro-3-sulfostyryl) or 4- (4-chlorostyryl) -4 '- (2-sulfostyryl) -diphenyls. Mixtures of the aforementioned brightener can be used.

Around the aesthetic Impression of the agents according to the invention to improve they are colored, preferably in part, with suitable dyes. Preferred dyes whose selection the expert no difficulty prepares, have a high storage stability and insensitivity to the other ingredients the agent and against light and no pronounced substantivity to textile fibers, so as not to stain them.

If the detergent composition of the invention is present in the form of agglomerates, so it is a preferred embodiment the invention.

If the detergent composition of the invention a density of advantageously at least 300 g / l, vorfeilhafterweise 400 g / l, more preferably 500 g / l, preferably at least 600 g / l and in particular at least 650 g / l is, so it is also a preferred embodiment of the Invention.

If the detergent composition according to the invention further comprises a second perfume which is sprayed onto the surface of the detergent granules contained, then again a preferred outlet embodiment of the invention.

A further preferred embodiment is a detergent composition of the invention in the form of a laundry detergent bar, preferably in tablet form.

For example can the particles according to the invention, which in the detergent piece are included, nor contain decay accelerators, for example Substances that are a big one Adsorption capacity for water own (such as starch, Cellulose derivatives, alginates, dextrans, cross-linked polyvinylpyrrolidone, Casein derivatives, etc.) and / or in particular gas-evolving substances (such as sodium bicarbonate and citric or tartaric acid, etc.), so that one Shower effect or sparkling effect occurs.

A further preferred embodiment is a detergent composition according to the invention which in pouches, bags or sachets bottled is.

The Pouches, bags or sachets are preferably designed to provide penetration of the Allow detergent composition during the washing process. So they are either water permeable or they dissolve in water, if necessary under adjustable conditions (temperature, pH, ionic strength)

One Another object of the present invention is a method for washing textiles, comprising the step of contacting the textiles with an aqueous Medium containing an effective amount of a detergent composition which particles according to the invention includes.

One Another object of the present invention is a washing or detergent additive, which particles of the invention comprises this additive being in the form of a pouch, the amount measured in the bag or pouch being such that that she for one normal washing load of an automatic washing machine is sufficient.

One Another object of the invention is a plasticizer composition, which during the flushing process an automatic washing machine comprising particles according to the invention.

• *Ölabsorption: Die Teilchen konnten jeweils größere Mengen an Parfümöl aufnehmen (jeweils > 15 Gew.-%, was bedeutet, daß 100 g der Teilchen nach der Parfümbeaufschlagung eine Gewicht von > 115 g aufwiesen). Dabei behielten die erfindungsgemäßen Teilchen ihre guten Pulvereigenschaften, d.h. blieben gut rieselfähig und zeigten keine Verklumpungen.
• **Duftstabilität: Die Duftstabilität wurde von einem sechsköpfigen Panel parfümistischer Laien bewertet. Diese beurteilten den Duft der Teilchen gemäß V1 soiwe E1–E4 ca. 24 Stunden nach der Beladung der Teilchen mit jeweils 18 Gew.-% einer Riechstoffzusammensetzung*** (Parfümöl). Außerdem beurteilten sie den Duft dieser Teilchen nach einer vierwöchigen Lagerung. Übereinstimmend wurde festgestellt, daß sich der Duft der Teilchen gemäß V1 nach vierwöchiger Lagerung deut lich nachteilig geändert hat. Der Duft enthielt unangenehhme Noten, die vor der Lagerung noch nicht vorhanden waren. Der ursprüngliche Wohlgeruch war nach dieser Lagerungszeit sehr deutlich beeinträchtigt. Im Gegensatz dazu war der Duft der Teilchen gemäß E1–E4 auch nach vierwöchiger Lagerung weiterhin gut, der Wohlgeruch blieb jeweils erhalten oder hat sich allenfalls nur graduell geändert. Deshalb bewertete das sechsköpfige Panel die Duftstabilität nach 4 Wochen Lagerung für die Teilchen gemäß V1 mit „schlecht", die entsprechende Duftstabilität der Teilchen gemäß E1–E4 konnte hingegen als „gut" beurteilt werden.
• *** Riechstoffzusammensetzung: Die eingesetzte Riechstoffzusammensetzung enthielt neben anderen Komponenten 15 Gew.-% Allylamylglycolat sowie sowie 15 Gew.-% Cyclogalbanat, jeweils bezogen auf die gesamte Riechstoffzusammensetzung.

The particles according to V1 and E1-E4 were each prepared in a standard spray-drying process.

• * Oil Absorption: The particles were each able to take up larger amounts of perfume oil (> 15% by weight each, which means that 100 g of the particles after perfuming had a weight of> 115 g). In this case, the particles according to the invention retained their good powder properties, ie they remained readily free-flowing and showed no clumping.
• ** Fragrance Stability: Fragrance stability was evaluated by a panel of six perfumed laymen. These judged the scent of the particles according to V1 so E1-E4 about 24 hours after the loading of the particles with 18 wt .-% of a fragrance composition *** (perfume oil). They also assessed the scent of these particles after four weeks of storage. Consistently, it was found that the fragrance of the particles has changed significantly according to V1 V1 after four weeks of storage adversely. The fragrance contained unpleasant notes that were not present before storage. The original fragrance was severely impaired after this storage period. In contrast, the fragrance of the particles according to E1-E4 was still good after four weeks of storage, the fragrance was either preserved or has changed only gradually. Therefore, the six-headed panel rated the fragrance stability after 4 weeks of storage for the particles according to V1 as "poor", whereas the corresponding fragrance stability of the particles according to E1-E4 could be assessed as "good".
• *** Fragrance composition: The fragrance composition used contained, among other components, 15% by weight of allylamyl glycolate and also 15% by weight of cyclogalbanate, based in each case on the total fragrance composition.

Claims (21)

Particles containing - zeolite, in a total amount of more than 20% by weight but less than 70% by weight, relative to the total particle, and - perfume, characterized in that the particle also contains phyllosilicates, the ratio from zeolite to phyllosilicate is less than 7: 1. Particles according to claim 1, characterized that it itself at the sheet silicate around (a) two-layer silicates, such as preferably silicates of the kaolin and / or serpentine group, such as in particular kaolinite, dickite, halloysite, antigorite, lizardite and / or Chryosotil (b) three-layer silicates, such as preferably pyrophyllite, Talc, silicates of the mica group such. Muscovite, the smectite group in particular montmorillonite, beidellite, hectorite, nontronite and / or saponite, the hydrogels group such. B. illite, celadonite and glauconite and vermiculites and chlorites, such as preferably clinochlor, Chamosit and / or Donbassit (c) sheet silicates with alternating support structures, preferably the muscovite montmorillonite mixed layer (also Illit-Smectit-Mixed-Layer) (d) clay minerals with fiber structure such as preferably sepiolite and / or Palygorskit and / or (E) non-crystalline silicates, such as. Allophane and imogolite. Particles according to one of claims 1 or 2, characterized that phyllosilicate in the form of clay, preferably of smectite clay, in particular Bentonite is included. Particles according to one of claims 1 to 3, characterized that it contains nonionic surfactant, preferably chosen from the group of the alkoxylated alcohols, the alkylphenol polyglycol ethers, the alkoxylated fatty acid alkyl ester, the polyhydroxy fatty acid amides, the alkyl glycosides, the alkyl polyglucosides, the amine oxides and / or the long-chain alkyl sulfoxides, in particular in an amount of at least 0.1 wt .-% based on the total particle. Particles according to one of Claims 1 to 4, characterized that it a polymeric clay flocculating agent containing the clay flocculating agent is a polymer or a copolymer which preferably is Derived from ethylene oxide, acrylamide, acrylic acid, dimethylaminoethyl methacrylate, Vinyl alcohol, vinylpyrrolidone, ethyleneimine and mixtures thereof selected in particular being a weight average molecular weight from 100,000 to 10 million, preferably in the range from 0.005% to 20% by weight of the clay in the particle is included. Particles according to one of claims 1 to 5, characterized that it cationic surfactants, zwitterionic compounds, ampholytes, amphoteric surfactants, Betaine, cationic polymers and / or amphoteric polymers contains. Particles according to one of Claims 1 to 6, characterized that it at least one quaternary ammonium compound contains preferably an alkylated quaternary ammonium compound, in particular in amounts of 0.1 wt .-% to 30 wt .-% based on the total particle. Particles according to one of Claims 1 to 7, characterized that it 0.1 wt .-% to 30 wt .-% of an organic humectant containing in particular from glycerol, ethylene glycol, propylene glycol, dimers and trimers of glycerine and / or mixtures thereof. Particles according to one of claims 1 to 8, characterized that it a complexing agent, preferably phosphonate and / or a citrate, contains in particular in amounts of 0.1 wt .-% to 10 wt .-% based on the entire particle. Particles according to any one of claims 1 to 9, characterized in that it contains pentaerythritol (derivatives), such as preferably a C ₂ -C ₂₄ aliphatic Säureester of pentaerythritol, in particular in amounts of from 0.1 to 30 wt .-%. Particles according to one of Claims 1 to 10, characterized in that it contains an alkali metal silicate, preferably with a modulus M ₂ O: SiO _2, in the range from 1: 1.9 to 1: 3.3, where M is an alkali metal ion , Particles according to one of Claims 1 to 11, characterized that it contains an acidic component, preferably carboxylic acid, advantageously polycarboxylic especially citric acid. Particles according to one of Claims 1 to 12, characterized that it at least one more usually in laundry detergents or cleaners, preferably a substance from the group of surfactants, builders (inorganic and organic builders), bleaches, bleach activators, Bleach stabilizers, bleach catalysts, enzymes, special polymers (for example those with cobuilder properties), grayness inhibitors, optical brighteners, UV protectants, soil repellents, electrolytes, Colorants, fragrances, fragrances, perfume carriers, pH adjusters, complexing agents, Fluorescers, foam inhibitors, anti-crease agents, antioxidants, quaternary Ammonium compounds, antistatic agents, ironing aids, UV absorbers, Anti redeposition agents, germicides, antimicrobial agents, Fungicides, viscosity regulators, Pearlescers, color transfer inhibitors, Inlet preventer, corrosion inhibitors, preservatives, Plasticizer, softener, Protein hydrolysates, repellents and impregnating agents, hydrotropes, silicone oils and Contains swelling and slipping agent. Particles according to one of Claims 1 to 13, characterized that it at least partially surrounded by a coating. Particles according to one of Claims 1 to 14, characterized that it colored is. Use of a particle after one of the previous ones claims 1-15 as Washing or cleaning agent or detergent or cleaning agent additive. Process for the preparation of a particle after a the claims 1 to 15, comprising a) providing zeolite and phyllosilicate comprehensive carrier material, preferably based on aqueous Suspensions which advantageously also include nonionic surfactant and, if appropriate, further inorganic and organic constituents include, wherein the watery Suspensions then be dried, then b) optionally impregnating of the carrier material with at least one nonionic surfactant, as well c) loading the carrier material with perfume by mixing perfume and (impregnated) support material and / or by spraying of perfume on the (impregnated) Support material such as optionally the coating of the perfumed carrier material. A detergent composition containing: - (A) particles according to one of the claims 1 to 15 - (B) 0.01% by weight to 95% by weight, preferably 5% by weight to 85% by weight, advantageously from 3% by weight to 30% by weight, in particular 5% by weight up to 22% by weight additional Surfactant (s). Process for washing textiles, comprising Step of contacting the textiles with an aqueous Medium containing an effective amount of a detergent composition Claim 18 contains. Detergent or cleaning agent additive comprising particles according to one of the claims 1 to 15, which is in the form of a bag. Plasticizer composition added during rinsing comprising particles according to any one of claims 1 to 15.