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DE102004057702A1 - Cap for an aerosol or spray container incorporates an angled spray channel made as a single item out of an elastic synthetic material - Google Patents

Cap for an aerosol or spray container incorporates an angled spray channel made as a single item out of an elastic synthetic material Download PDF

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Publication number
DE102004057702A1
DE102004057702A1 DE102004057702A DE102004057702A DE102004057702A1 DE 102004057702 A1 DE102004057702 A1 DE 102004057702A1 DE 102004057702 A DE102004057702 A DE 102004057702A DE 102004057702 A DE102004057702 A DE 102004057702A DE 102004057702 A1 DE102004057702 A1 DE 102004057702A1
Authority
DE
Germany
Prior art keywords
spray
cap
spray channel
container
angled
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE102004057702A
Other languages
German (de)
Inventor
Heiko Eberhardt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Deutschland GmbH
Original Assignee
Wella GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wella GmbH filed Critical Wella GmbH
Priority to DE102004057702A priority Critical patent/DE102004057702A1/en
Priority to JP2007541810A priority patent/JP2008520507A/en
Priority to EP05824165A priority patent/EP1828020B1/en
Priority to PCT/EP2005/012435 priority patent/WO2006058627A1/en
Priority to CNA2005800408880A priority patent/CN101128370A/en
Priority to AT05824165T priority patent/ATE418505T1/en
Priority to ES05824165T priority patent/ES2319221T3/en
Priority to CA2587652A priority patent/CA2587652C/en
Priority to MX2007006339A priority patent/MX2007006339A/en
Priority to DE602005011993T priority patent/DE602005011993D1/en
Priority to BRPI0518707-9A priority patent/BRPI0518707A2/en
Priority to AU2005311510A priority patent/AU2005311510A1/en
Publication of DE102004057702A1 publication Critical patent/DE102004057702A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/44—Valves specially adapted therefor; Regulating devices
    • B65D83/46—Tilt valves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/28—Nozzles, nozzle fittings or accessories specially adapted therefor
    • B65D83/30—Nozzles, nozzle fittings or accessories specially adapted therefor for guiding the flow of spray, e.g. funnels, hoods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/75—Aerosol containers not provided for in groups B65D83/16 - B65D83/74
    • B65D83/753—Aerosol containers not provided for in groups B65D83/16 - B65D83/74 characterised by details or accessories associated with outlets

Landscapes

  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Nozzles (AREA)
  • Medicinal Preparation (AREA)

Abstract

The cap (7) for an aerosol or spray container (1) incorporates an angled spray channel (10) made as a single item out of an elastic synthetic material.

Description

Die Erfindung betrifft eine Kappe mit einem in der Kappe integrierten Sprühwinkel, welcher einen abgewinkelten Sprühkanal (10) umgibt, und mit einer Taste zum Betätigen eines Ventils eines Behälters, insbesondere eines Aerosolbehälters oder Sprühbehälters. Dabei ist die Taste dazu vorgesehen, über den abgewinkelten Sprühkanal gegen einen Stem des Behälters zu wirken, um den Stem bei manuellem Betätigen der Taste auszulenken, und um damit das Ventil zu öffnen, wodurch im Behälter enthaltenes Produkt, z. B. ein Haarspray, durch den Stem und eine an der Kappe vorgesehene Produktabgabeöffnung unter Passieren des Sprühkanals austreten kann. Der Sprühkanal weist eine akustische Abdichtung auf, um ein angenehmes Geräusch beim Aussprühen zu erreichen.The invention relates to a cap with a spray angle integrated in the cap, which has an angled spray channel (US Pat. 10 ), and with a button for actuating a valve of a container, in particular an aerosol container or spray container. The key is intended to act on the angled spray channel against a stem of the container to deflect the stem upon manual actuation of the key and thereby open the valve, thereby containing product in the container, for. As a hair spray, can escape through the Stem and provided on the cap product discharge opening while passing through the spray channel. The spray channel has an acoustic seal to achieve a pleasant sound when spraying.

Eine derartige Kappe ist aus der WO 01/96210 A2 bekannt. Der Sprühkanal dieser Kappe ist von einem schalldämmenden Material umgeben, um derart den Schallpegel an sich zu reduzieren, aber auch um einzelne Frequenzbereiche besonders stark zu dämpfen. Dabei sind Schichten aus TPE (Thermoplastisches Elastomer) oder TPU (Thermoplastisches Polyurethan) um den Sprühkanal vorgesehen.A Such cap is known from WO 01/96210 A2. The spray channel of this Cap is of a sound-absorbing Material surrounded, so as to reduce the sound level, but also to attenuate individual frequency ranges particularly strong. there are layers of TPE (Thermoplastic Elastomer) or TPU (Thermoplastic Elastomer) Polyurethane) around the spray channel intended.

Die bekannte Kappe hat den Nachteil, dass die schichtenweise Herstellung des Sprühwinkels relativ teuer ist.The known cap has the disadvantage that the layer-wise production the spray angle is relatively expensive.

Es liegt die Aufgabe zugrunde, diesen Nachteil zu beseitigen. Gelöst ist die Aufgabe dadurch, dass der Sprühkanal in einstückiger Weise aus einem elastischen Kunststoff hergestellt ist.It the object is to eliminate this disadvantage. Solved is the Task in that the spray channel in one piece Way is made of an elastic plastic.

Die vorgeschlagene Kappe hat den Vorteil, dass sie relativ kostengünstig ist, da der Sprühkanal in einstückiger Weise hergestellt wird. Durch die hohe Elastizität des verwendeten Materials werden im Material auftretende Schwingungen, welche Geräusche nach außen abgeben könnten, gedämpft.The proposed cap has the advantage that it is relatively inexpensive, since the spray channel in one-piece Way is made. Due to the high elasticity of the material used Are occurring in the material vibrations, which noises after Outside could give up attenuated.

Aufgrund der Konstruktion der bekannten Sprühwinkel findet eine relativ hohe Schallemission bei diesen statt, da relativ harte Materialien, z. B. PP für den Sprühwinkel, verwendet werden. Diese auch Sprühhebel genannten by virtue of the construction of the known spray angle finds a relative high acoustic emission takes place in these because relatively hard materials, z. B. PP for the spray angle, be used. These also spray levers mentioned

Ausführungen sind mechanisch sehr stabil ausgelegt. Sie könnten hohe Kräfte übertragen, die in der Praxis jedoch nicht vorkommen.versions are designed mechanically very stable. They could transmit high forces, which do not occur in practice.

Der vorgeschlagene Sprühkanal kann die geforderten Kräfte ebenso auf den Stem übertragen. Zudem ist er in der Lage, die Wegunterschiede einer um ein Gelenk schwenkbarer Taste, welche am Tastenende bis zu 7 mm betragen, auf das Ventil zu übertragen, welches in der Regel einen Auslöseweg von 3,5 bis 4 mm aufweist. Dabei wird die Bedienkraft nicht unbedingt erhöht.Of the proposed spray channel can the required forces also transferred to the stem. moreover he is able to change the path differences of a pivotable about a joint Key, which is up to 7 mm at the end of the key, on the valve transferred to, which usually a tripping of 3.5 to 4 mm. The operating force is not necessarily elevated.

Der Sprühkanal kann aus einem sehr flexiblen, elastischen und weichen Material, insbesondere einem Kunststoff der Familien TPE (Thermoplastisches Elastomer) oder TPU (Thermoplastisches Polyurethan) hergestellt werden (Anspruch 2). Eine einzige Kunststoffsorte für den Sprühkanal ist dabei ausreichend. Der Sprühkanal kann jedoch auch aus einem Gemisch mindestens zweier Kunststoffe der Familien TPE und TPU hergestellt werden (Anspruch 3), insbesondere aus PP oder PE (Anspruch 4). Ebenso sind Mischungen aus TPE mit PP oder PE oder einem anderen Kunststoff denkbar. Versuche haben gezeigt, dass ein Sprühhebel aus PP mindestens 40 % TPE enthalten muss (Anspruch 5), um eine gute Schalldämmung zu haben.Of the spray channel can be made of a very flexible, elastic and soft material, in particular a plastic of families TPE (Thermoplastic Elastomer) or TPU (thermoplastic polyurethane) be (claim 2). A single type of plastic for the spray channel is enough. The spray channel However, it can also consist of a mixture of at least two plastics the families TPE and TPU are produced (claim 3), in particular made of PP or PE (claim 4). Likewise, mixtures of TPE with PP or PE or another plastic conceivable. Have attempts shown a spray lever from PP must contain at least 40% TPE (claim 5) to a good soundproofing to have.

Im folgenden wird die Erfindung an Hand von zwei Figuren, die ein Ausführungsbeispiel zeigen, näher beschrieben. Es zeigt:in the The following is the invention with reference to two figures, which is an embodiment show, closer described. It shows:

1 in einer Seitenansicht mit teilweisem Vertikalschnitt eine Kappe mit einer Taste, die gegen einen Sprühhebel, welcher einen abgewinkelten Sprühkanal enthält, wirkt, wobei die Kappe auf einen Behälter, der ein Haarspray enthält, aufgesteckt ist, und wobei die Taste nicht betätigt ist, sowie 1 in a side view with partial vertical section, a cap with a button which acts against a spray lever, which contains an angled spray channel, the cap is fitted on a container containing a hair spray, and wherein the button is not actuated, as well

2 in einer Seitenansicht mit teilweisem Vertikalschnitt den Gegenstand der 1, jedoch mit betätigter Taste. 2 in a side view with partial vertical section the subject of 1 , but with pressed button.

Bei einer Kappe 7 mit einem in der Kappe 7 integrierten Sprühwinkel 2, welcher einen abgewinkelten Sprühkanal 10 umgibt, dient einer Taste 6 zum Betätigen eines Ventils eines Behälters 1, der ein Aerosolbehälter ist. Die Taste 6 ist dazu vorgesehen, um ein Gelenk 5 zu schwenken und über den abgewinkelten Sprühkanal 10 gegen einen Stem 11 des Behälters 1 zu wirken, um den Stem 11 bei manuellem Betätigen der Taste 6 auszulenken, und um damit das (nicht dargestellte) Ventil zu öffnen, wodurch im Behälter 1 enthaltenes Produkt durch den Stem 11 und eine an der Kappe 7 vorgesehene Produktabgabeöffnung 3 unter Passieren des Sprühkanals 10 austreten kann. Der Sprühkanal 10 weist eine akustische Abdichtung auf. Dazu ist der Sprühkanal in einstückiger Weise aus einem elastischen Kunststoff hergestellt. Er besteht zu 50 % aus PP und zu 50 % aus einem TPE. Das TPE ist Santoprene®. Es könnte jedoch auch Vayram® oder Evoprene® sein. Beim Betätigen der Taste 6 wird der Sprühkanal 10 deformiert, da er im Bereich der Produktabgabeöffnung 3 mit der Kappe 7 verbunden ist. Das Sprühgeräusch ist relativ angenehm.For a cap 7 with one in the cap 7 integrated spray angle 2 , which has an angled spray channel 10 surrounds, serves a key 6 for actuating a valve of a container 1 which is an aerosol container. The key 6 is meant to be a joint 5 to swing and over the angled spray channel 10 against a stem 11 of the container 1 to act to the stem 11 when manually pressing the button 6 to deflect, and thus to open the valve (not shown), whereby in the container 1 included product by the stem 11 and one on the cap 7 intended product delivery opening 3 passing the spray channel 10 can escape. The spray channel 10 has an acoustic seal. For this purpose, the spray is made in one piece from an elastic plastic. It consists of 50% PP and 50% TPE. The TPE is Santoprene ® . However, it could also be Vayram ® or EvopreneTM ®. When loading make the key 6 becomes the spray channel 10 deformed as it is in the area of the product discharge opening 3 with the cap 7 connected is. The spray noise is relatively pleasant.

11
Behältercontainer
22
Sprühwinkelspray angle
33
ProduktabgabeöffnungProduct discharge opening
44
Tastenendekey end
55
Gelenkjoint
66
Tastebutton
77
Kappecap
88th
Randedge
1010
Sprühkanalspray channel
1111
StemStem
1212
Düsejet

Claims (5)

Kappe (7) mit einem in der Kappe (7) integrierten Sprühwinkel (2), welcher einen abgewinkelten Sprühkanal (10) umgibt, und mit einer Taste (6) zum Betätigen eines Ventils eines Behälters (1), insbesondere eines Aerosolbehälters oder Sprühbehälters, wobei die Taste (6) dazu vorgesehen ist, über den abgewinkelten Sprühkanal (10) gegen einen Stem (11) des Behälters (1) zu wirken, um den Stem (11) bei manuellem Betätigen der Taste (6) auszulenken, und um damit das Ventil zu öffnen, wodurch im Behälter (1) enthaltenes Produkt durch den Stem (11) und eine an der Kappe (7) vorgesehene Produktabgabeöffnung (3) unter Passieren des Sprühkanals (10) austreten kann, und wobei der Sprühkanal (10) eine akustische Abdichtung aufweist, dadurch gekennzeichnet, dass der Sprühkanal in einstückiger Weise aus einem elastischen Kunststoff hergestellt ist.Cap ( 7 ) with one in the cap ( 7 ) integrated spray angle ( 2 ), which has an angled spray channel ( 10 ) and with a key ( 6 ) for actuating a valve of a container ( 1 ), in particular an aerosol container or spray container, wherein the button ( 6 ) is intended, via the angled spray channel ( 10 ) against a stem ( 11 ) of the container ( 1 ) to affect the stem ( 11 ) by manually pressing the button ( 6 ) and thereby open the valve, whereby in the container ( 1 ) contained by the stem ( 11 ) and one on the cap ( 7 ) provided product delivery opening ( 3 ) passing the spray channel ( 10 ), and wherein the spray channel ( 10 ) has an acoustic seal, characterized in that the spray channel is made in one piece of an elastic plastic. Kappe nach Anspruch 1, dadurch gekennzeichnet, dass der Sprühkanal (10) aus einem sehr flexiblen, elastischen und weichen Material, insbesondere einem Kunststoff der Familien TPE (Thermoplastisches Elastomer) oder TPU (Thermoplastisches Polyurethan) hergestellt ist.Cap according to claim 1, characterized in that the spray channel ( 10 ) is made of a very flexible, elastic and soft material, in particular a plastic of the families TPE (thermoplastic elastomer) or TPU (thermoplastic polyurethane). Kappe nach Anspruch 1, dadurch gekennzeichnet, dass der Sprühkanal (10) aus einem Gemisch mindestens zweier Kunststoffe der Familien TPE und TPU hergestellt ist.Cap according to claim 1, characterized in that the spray channel ( 10 ) is made of a mixture of at least two plastics of the families TPE and TPU. Kappe nach Anspruch 3, dadurch gekennzeichnet, dass das Gemisch ein TPE, insbesondere Polypropylen (PP) oder Polyethylen (PE) enthält.Cap according to claim 3, characterized in that the mixture is a TPE, in particular polypropylene (PP) or polyethylene (PE) contains. Kappe nach Anspruch 4, dadurch gekennzeichnet, dass der Sprühkanal (10) aus Polypropylen (PP) besteht und einen Anteil von mindestens 40 % TPE aufweist.Cap according to claim 4, characterized in that the spray channel ( 10 ) consists of polypropylene (PP) and has a content of at least 40% TPE.
DE102004057702A 2004-11-30 2004-11-30 Cap for an aerosol or spray container incorporates an angled spray channel made as a single item out of an elastic synthetic material Withdrawn DE102004057702A1 (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
DE102004057702A DE102004057702A1 (en) 2004-11-30 2004-11-30 Cap for an aerosol or spray container incorporates an angled spray channel made as a single item out of an elastic synthetic material
JP2007541810A JP2008520507A (en) 2004-11-30 2005-11-21 Cap with an angled spray channel for aerosol or spray containers
EP05824165A EP1828020B1 (en) 2004-11-30 2005-11-21 Cap with an angled spray channel for an aerosol container or a spray container
PCT/EP2005/012435 WO2006058627A1 (en) 2004-11-30 2005-11-21 Cap with an angled spray channel for an aerosol container or a spray container
CNA2005800408880A CN101128370A (en) 2004-11-30 2005-11-21 Cap with an angled spray channel for an aerosol container or a spray container
AT05824165T ATE418505T1 (en) 2004-11-30 2005-11-21 CAP WITH AN ANGLED SPRAY CHANNEL FOR AN AEROSOL CONTAINER OR SPRAY CONTAINER
ES05824165T ES2319221T3 (en) 2004-11-30 2005-11-21 PLUG WITH AN ANGULATED SPRAY CHANNEL FOR AN AEROSOL CONTAINER OR A SPRAY CONTAINER.
CA2587652A CA2587652C (en) 2004-11-30 2005-11-21 Cap with an angled spray channel for an aerosol container or a spray container
MX2007006339A MX2007006339A (en) 2004-11-30 2005-11-21 Cap with an angled spray channel for an aerosol container or a spray container.
DE602005011993T DE602005011993D1 (en) 2004-11-30 2005-11-21 CAP WITH AN ANGULATED SPRAY CHANNEL FOR AN AEROSOL CONTAINER OR A SPRAY CONTAINER
BRPI0518707-9A BRPI0518707A2 (en) 2004-11-30 2005-11-21 lid with an angled spray channel for an aerosol container or a spray container
AU2005311510A AU2005311510A1 (en) 2004-11-30 2005-11-21 Cap with an angled spray channel for an aerosol container or a spray container

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102004057702A DE102004057702A1 (en) 2004-11-30 2004-11-30 Cap for an aerosol or spray container incorporates an angled spray channel made as a single item out of an elastic synthetic material

Publications (1)

Publication Number Publication Date
DE102004057702A1 true DE102004057702A1 (en) 2006-06-01

Family

ID=36072146

Family Applications (2)

Application Number Title Priority Date Filing Date
DE102004057702A Withdrawn DE102004057702A1 (en) 2004-11-30 2004-11-30 Cap for an aerosol or spray container incorporates an angled spray channel made as a single item out of an elastic synthetic material
DE602005011993T Active DE602005011993D1 (en) 2004-11-30 2005-11-21 CAP WITH AN ANGULATED SPRAY CHANNEL FOR AN AEROSOL CONTAINER OR A SPRAY CONTAINER

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE602005011993T Active DE602005011993D1 (en) 2004-11-30 2005-11-21 CAP WITH AN ANGULATED SPRAY CHANNEL FOR AN AEROSOL CONTAINER OR A SPRAY CONTAINER

Country Status (11)

Country Link
EP (1) EP1828020B1 (en)
JP (1) JP2008520507A (en)
CN (1) CN101128370A (en)
AT (1) ATE418505T1 (en)
AU (1) AU2005311510A1 (en)
BR (1) BRPI0518707A2 (en)
CA (1) CA2587652C (en)
DE (2) DE102004057702A1 (en)
ES (1) ES2319221T3 (en)
MX (1) MX2007006339A (en)
WO (1) WO2006058627A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2924097A1 (en) * 2007-03-26 2009-05-29 Lindal France Soc Par Actions CAP FOR SPRAYER.
US8881944B2 (en) 2008-06-30 2014-11-11 S.C. Johnson & Son, Inc. Overcap for and a method of actuating a volatile material dispenser
US8276832B2 (en) * 2009-07-22 2012-10-02 S.C. Johnson & Son, Inc. Multiple spray actuator overcap
USD627224S1 (en) 2009-10-08 2010-11-16 S.C. Johnson & Son, Inc. Overcap
USD657242S1 (en) 2010-01-14 2012-04-10 S.C. Johnson & Son, Inc. Container with nozzle
USD648216S1 (en) 2010-01-14 2011-11-08 S.C. Johnson & Son, Inc. Actuator nozzle for a diffusion device

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0669268A1 (en) * 1994-02-24 1995-08-30 L'oreal Dispensing device for a product and press-button for such a device
EP0863089A1 (en) * 1997-03-03 1998-09-09 L'oreal Dispensing head and dispenser with such head
WO2001096210A2 (en) * 2000-06-10 2001-12-20 Wella Aktiengesellschaft Discharging container

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0003343D0 (en) * 2000-02-14 2000-04-05 Unilever Plc Actuator mechanism
US6595393B1 (en) * 2002-01-07 2003-07-22 Zarc International, Inc. Spray delivery system and method for aerosol products

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0669268A1 (en) * 1994-02-24 1995-08-30 L'oreal Dispensing device for a product and press-button for such a device
EP0863089A1 (en) * 1997-03-03 1998-09-09 L'oreal Dispensing head and dispenser with such head
WO2001096210A2 (en) * 2000-06-10 2001-12-20 Wella Aktiengesellschaft Discharging container

Also Published As

Publication number Publication date
ATE418505T1 (en) 2009-01-15
AU2005311510A1 (en) 2006-06-08
CA2587652C (en) 2010-08-17
MX2007006339A (en) 2007-06-19
CN101128370A (en) 2008-02-20
EP1828020B1 (en) 2008-12-24
EP1828020A1 (en) 2007-09-05
CA2587652A1 (en) 2006-06-08
ES2319221T3 (en) 2009-05-05
BRPI0518707A2 (en) 2008-12-02
WO2006058627A1 (en) 2006-06-08
DE602005011993D1 (en) 2009-02-19
JP2008520507A (en) 2008-06-19

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