DE10134720A1 - Synergistic pesticidal mixture containing a sodium ion channel inhibitor, especially indoxacarb, and thiacloprid, clothianidin or imidacloprid, useful especially in plant protection - Google Patents

Abstract

A pesticidal mixture contains one or more sodium ion channel effectors (inhibitors) and thiacloprid, clothianidin or imidacloprid.

Description

Synergistic blends

The invention relates to synergistic mixtures containing one or more Sodium ion channel effectors and the compound (Z) -3- (6-chloro-3-pyridylme thyl) -1,3-thiazolidin-2-ylidencyanamide or the compound (E) -1- (2-chloro-1,3- thiazol-5-ylmethyl) -3-methyl-2-nitroguanidine or the compound 1 - [(6-chloro-3- pyridinyl) methyl] -N-nitro-2-imidazolidinimine and the use of these mixtures to control animal pests.

Mixtures of sodium ion channel antagonists with certain compounds from the group of modulators of acetylcholine receptors are already known (WO 00/54 591, Research Disclosure May 1997, No. 39786). The well-known However, mixtures are not always satisfactory in use, be it that the Effect against certain insects is insufficient or the required up wall quantities are very large.

It has now been found that mixtures containing one or more sodium Ion channel effectors and the compound (Z) -3- (6-chloro-3-pyridylmethyl) -1,3-thi azolidin-2-ylidencyanamide (thiacloprid) or the compound (E) -1- (2-chloro-1,3- thiazol-5-ylmethyl) -3-methyl-2-nitroguanidine (chlothianidine) or the compound 1 - [(6-Chloro-3-pyridinyl) methyl] -N-nitro-2-imidazolidinimine (imidacloprid) synerg are gistically effective and are suitable for controlling animal pests. on Because of this synergism, significantly smaller amounts of active ingredient can be used become, d. H. the effect of the mixture is greater than the effect of the single compo components.

The term sodium ion channel effector refers to a compound that prevents the transport of sodium ions through the cell membrane of a nerve cell. Such compounds and their mode of action are described, for example, in "Pesticide Biochemistry and Physiology, 60: 177-185" and "Archives of Insect Biochemistry and Physiology, 37: 91-103". Sodium ion channel inhibitors are described, for example, in US Pat. Nos. 5,543,573; US 5,708,170; US 5,324,837 and US 5,462,938. Compounds of the following formulas may be mentioned as examples:

wherein
A represents CR ⁴ R ⁵ or NR ⁶ ,
W stands for O or S,
X, Y, Z, X ', Y' and Z 'independently of one another represent H, halogen, OH, CN, NO ₂ ,
optionally mono- or polysubstituted by halogen, C ₁ -C ₃ alkoxy, C ₁ - C ₃ haloalkoxy, C ₃ -C ₆ cycloalkyl, C ₂ -C ₆ alkenyloxy or sulfonyloxy substituted C ₁ -C ₆ alkyl,
optionally mono- or polysubstituted by halogen, C ₁ -C ₃ alkoxy or C ₃ -C ₆ cycloalkyl-substituted C ₁ -C ₆ alkoxy,
for C ₁ -C ₆ alkoxycarbonyl, for C ₃ -C ₆ cycloalkylcarbonyloxy, for phenyl which is optionally mono- or polysubstituted by halogen, C ₁ -C ₄ alkyl or C ₁ -C ₄ alkoxy,
for aminocarbonyloxy which is optionally mono- or disubstituted by C ₁ -C ₃ -alkyl,
for C ₁ -C ₆ alkoxycarbonyloxy, for C ₁ -C ₆ alkylsulfonyloxy, for C ₂ -C ₆ alkenyl or for NR ₁₂ R ₁₃ ,
m, p and q independently of one another represent 1, 2, 3, 4 or 5,
n represents 0, 1 or 2,
r represents 1 or 2,
t represents 1, 2, 3 or 4,
R, R ¹ , R ² , R ³ , R ⁴ and R ⁵ independently of one another are H or C ₁ -C ₄ alkyl,
R ⁶ for H, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ alkoxyalkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ haloalkoxy, C ₂ -C ₆ -Alkenyl, C ₂ -C ₆ -alkynyl, C ₁ -C ₆ -alkylcarbonyl, C ₁ -C ₆ -alkoxycarbonyl, C ₁ -C ₆ -alkylthio or C ₁ -C ₆ -halogenylthio,
R ⁷ and R ⁸ independently of one another are H, halogen, C ₁ -C ₆ alkyl, C ₁ -C ₆ alkylcarbonyloxy or, if appropriate, one or more times by halo, CN, NO ₂ , C ₁ -C ₆ alkyl , C ₁ -C ₆ haloalkyl, C ₁ -C ₆ alkoxy or C ₁ - C ₆ haloalkoxy,
R ⁹ and R ¹⁰ independently of one another represent H or C ₁ -C ₄ alkyl,
R ^{11 represents} H, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -haloalkyl, C ₁ -C ₄ -alkylcarbonyl, C ₁ -C ₆ -alk oxycarbonyl or C ₁ -C ₆ -haogenalkoxycarbonyl,
R ¹² and R ¹³ independently of one another represent H or C ₁ -C ₆ alkyl,
G for H,
optionally mono- or polysubstituted by halogen, C ₁ -C ₄ alkoxy, C ₁ - C ₆ haloalkoxy, CN, NO _2, S (O) _n R ^14, COR ^15, CO ₂ R ^16, phenyl or C ₃ - C ₆ cycloalkyl substituted C ₁ -C ₆ alkyl,
for C ₁ -C ₆ alkoxy, C ₁ -C ₆ haloalkoxy, CN, NO ₂ , S (O) _n R ¹⁷ , COR ¹⁸ , CO ₂ R ¹⁹
for phenyl which is optionally mono- or polysubstituted by halogen, CN, C ₁ -C ₃ -haloalkyl or C ₁ -C ₃ -haloalkoxy,
represents C ₃ -C ₆ cycloalkyl or phenylthio,
Q for optionally single or multiple by halogen, CN, SCH, NO ₂ , S (O) _n R ²⁰ , C ₁ -C ₄ alkyl, C ₁ -C ₄ haloalkyl, C ₁ -C ₄ alkoxyalkyl, C ₁ -C ₆ - alkoxy, C ₁ -C ₆ haloalkoxy or NR ²¹ R ²² substituted phenyl,
n represents 0, 1 or 2,
R ¹⁴ , R ¹⁵ , R ¹⁶ , R ¹⁸ , R ¹⁹ , R ²¹ and R ²² independently of one another represent H or C ₁ -C ₆ alkyl,
R ¹⁷ and R ²⁰ independently of one another represent C ₁ -C ₆ alkyl or C ₁ -C ₆ haloalkyl,
R ^{33 stands} for CO ₂ R ³⁴ ,
R ^{34 represents} H, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, phenyl or halophenyl and the group
CN stands for CN or in particular for C = N.

Sodium ion channel effectors of the formula (I) are preferred, in particular those in which C N stands for C = N.

Sodium ion channel effectors of the formula (II) are also particularly preferred especially those in which C N stands for C = N.

Also preferred are sodium ion channel effects of the formula (III), in particular especially those in which C N stands for C = N.

Preferred compounds of the formula (I) are those in which
X _{m stands} for 4-OCF ₃ or 4-SCF ₃ ,
Y _{p is} 3-Cl, 3-CF ₃ , 3-CN, 4-Cl, 4-CF ₃ or 4-CN and
Zq stands for 3-Cl, 3-CF ₃ , 3-CN, 4-Cl, 4-CF ₃ or 4-CN,
the compound of the formula may be mentioned

Preferred compounds of the formula (II) are those in which
Y ' _{p stands} for 4-OCF ₃ or 4-SCF ₃
X ' _{m represents} 3-Cl, 3-CF ₃ , 3-CN, 4-Cl, 4-CF ₃ or 4-CN
R ⁷ stands for H and
R ^{8 represents} phenyl substituted by 3-Cl, 3-CF ₃ , 3-CN, 4-Cl, 4-CF ₃ or 4-CN.

The compound of the formula may be mentioned

Preferred compounds of the formula (III) are those in which
Cl represents phenyl substituted by 4-OCF ₃ or 4-SCF ₃ ,
G represents H, CO ₂ CH ₃ or CO ₂ C ₂ H ₅ ,
R ^{33 represents} CO ₂ CH ₃ or CO ₂ C ₂ H ₅ and
Z ' _{t represents} 3-Cl, 3-CF ₃ , 3-CN, 4-Cl, 4-CF ₃ or 4-CN.

The compound of the formula may be mentioned

Further sodium ion channel inhibitors are mentioned in US 5,116,850 and US 5,304,573. Compounds of the following formulas are listed as examples.

wherein
W represents oxygen or sulfur,
X "and Y" independently of one another for H, CN, SCN, for optionally one or more times by halogen, NO ₂ , CN, C ₁ -C ₄ alkoxy, C ₁ -C ₄ alkylthio, phenyl, halophenyl, C ₁ - C ₄ alkylsulfonyl or C ₁ -C ₄ alkoxycarbonyl substituted C ₁ -C ₆ alkyl,
for C ₂ -C ₄ alkenyl, C ₂ -C ₄ haloalkenyl, C ₂ -C ₄ alkynyl, C ₂ -C ₄ haloalkynyl, C ₃ -C ₆ cycloalkyl, C ₃ -C ₆ halocycloalkyl,
for optionally one or more times by halogen, CN, NO ₂ , C ₁ -C ₄ alkyl, C ₁ -C ₄ haloalkyl, C ₁ -C ₄ alkoxy, C ₁ -C ₄ haloalkoxy, C ₁ -C ₄ Alkylthio, C ₁ -C ₄ alkylsulfonyl or C ₁ -C ₄ haloalkylsulfonyl substituted phenyl,
for a six-membered aromatic ring which contains one or two heteroatoms, these heteroatoms being selected from the series 0 or 1 oxygen atom, 0 or 1 sulfur atom and 0, 1 or 2 nitrogen atoms and where this heteroaromatic ring is linked via a carbon atom and if appropriate is mono- or polysubstituted by the groups mentioned at X ",
Q 'for H,
optionally mono- or polysubstituted by halogen, CN, C ₁ -C ₃ alkoxy, C ₁ -C ₆ -alkoxycarbonyl or phenyl-substituted C ₁ -C ₆ alkyl, where phenyl in turn mono- or polysubstituted by halogen, CN, NO ₂ C ₁ -C ₄ alkyl, C ₁ - C ₄ haloalkyl, C ₁ -C ₄ alkylsulfonyl and C ₁ -C ₄ alkylsulfinyl which may be substituted,
for C ₂ -C ₆ alkenyl, C ₂ -C ₆ alkynyl or
represents C ₁ -C ₄ alkylcarbonyl, C ₁ -C ₄ haloalkylcarbonyl or NR ²⁸ R ²⁹ ,
or
for a five- or six-membered heteroaromatic ring (e.g. pyridyl) which contains one or two heteroatoms, these heteroatoms being selected from the series 0 or 1 oxygen atom, 0 or 1 sulfur atom and 0, 1 or 2 nitrogen atoms and wherein this heteroaromatic ring is linked via a carbon atom and it is optionally mono- or polysubstituted by the groups mentioned at X ",
m represents 0, 1, 2, 3, 4 or 5,
G 'for phenyl which is optionally mono- or polysubstituted by the groups mentioned at X ",
for a five or six-membered heteroaromatic ring (e.g. pyridyl) which contains one or two heteroatoms, these heteroatoms being selected from the group consisting of 0 or 1 oxygen atom, 0 or 1 sulfur atom and 0, 1 or 2 nitrogen atoms, and this heteroaromatic ring is linked via a carbon atom and it is optionally substituted one or more times by the groups mentioned at X ",
represents phenyl, which is optionally monosubstituted to trisubstituted by the groups mentioned at X ",
R ²³ , R ²⁴ , R ²⁵ , R ²⁶ , R ²⁷ , R ²⁸ and R ²⁹ independently of one another represent H or C ₁ -C ₄ alkyl and the group
CN stands for CN or in particular for C = N.

Preferred compounds of the formula (IV) are those in which
X " _{m stands} for 4-OCF ₃ or 4-SCF ₃ ,
G 'represents phenyl substituted by 3-Cl, 3-CF ₃ , 3-CN, 4-Cl, 4-CF ₃ or 4-CN and
Q 'represents a Herero cycle substituted by Cl or CF ₃ , e.g. B. for 4-Cl-2-pyridyl.

The following connection may be mentioned as an example:

Preferred compounds of the formula (V) are those in which Y " _{m represents} 4-OCF ₃ or 4-SCF ₃ .

The following compounds may be mentioned by way of example:

Further sodium ion channel effectors are benzophenone hydrazones, for example from EP-O-0 742 202, JP-1000 14 69, WO 96/33 168, WP-O-647 622, WO 97/11 050 and WO 97 / 38 973 are known. These include the benzophenone hydrazones of the formula (VI)

wherein
R ^{30 represents} H, C ₁ -C ₆ alkyl or C ₁ -C ₆ alkoxycarbonyl, in particular H or COCH ₃ ,
R ^{31 represents} C ₁ -C ₆ alkyl, in particular methyl or ethyl,
R ^{32 represents} halogen, especially chlorine and
R ^{33 represents} O-SO ₂ -C ₁ -C ₆ alkyl or O-SO ₂ -C ₁ -C ₆ haloalkyl, in particular O-SO ₂ CH ₃ or O-SO ₂ -CF ₃ or
represents CH ₂ -S (O) _y -C ₁ -C ₆ alkyl or CH ₂ -S (O) _y -C ₁ -C ₆ haloalkyl,
wherein
Y represents 0, 1 or 2,
especially for (CH ₂ ) S (O) _y CH ₃ , CH ₂ -S (O) _y C ₂ H ₅ or CH ₂ -S (O) _y CH ₂ CF ₃ , emphasized for CH ₂ -S-CH ₃ .

The following compounds are specifically mentioned:

Another group of sodium ion channel inhibitors are bis-aryl-methyl piperidines, for example from WO 95/23 507, U.S. 5,569,664, WO 96/36 228, WO 07/26 252, WO 98/00 015, WO 99/14 193 and where 00/01 838 are known.

These include the compounds of the formula (VII)

wherein
R ^{34 represents} H or OH,
R ³⁵ and R ³⁶ independently of one another represent halogen, C ₁ -C ₆ haloalkyl, haloalkylthio or C ₁ -C ₆ haloalkoxy, in particular CF ₃ , OCF ₃ and SCF ₃ ,
R ³⁷ for H, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ halo alkoxy, C ₁ -C ₆ alkoxycarbonyl, NH-CO ₂ -C ₁ -C ₆ alkyl or CH = NOC ₁ -C ₆ alkyl,
A stands for CH or N and
B represents N or N ^⊕ -O ^⊖ .

The following compounds are specifically mentioned:

Another group of sodium ion channel effectors are oxadiazines, which are used in e.g. from WO 96/36 618, WO 99/41 245, U.S. 5,536,720 and WO 98/33 794 are known.

These include the compounds of the formula (VIII)

wherein
R ^{38 represents} H, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkylcarbonyl or C ₁ -C ₆ -alkylcarbonyloxy, in particular H,
R ^{39 represents} C ₁ -C ₆ alkyl or C ₁ -C ₆ alkoxy,
R ^{40 represents} halogen, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ haloalkoxy or C ₁ -C ₆ halo alkylthio, in particular chlorine, CF ₃ , OCF ₃ or SCF ₃ and
Ar for phenyl which is optionally mono- or polysubstituted by halogen, CN, C ₁ -C ₆ -alkyl or C ₁ -C ₆ -halogenalkyl, in particular for 4-chlorophenyl, 4-cyanophenyl, 4-trifluoromethylphenyl, 3-chlorophenyl, 3- Cyano phenyl or 3-trifluoromethylphenyl, or
represents 5-membered or 6-membered hetaryl, each substituted by halogen, CN, C ₁ -C ₆ -alkyl or C ₁ -C ₆ -halogenalkyl, each having an O, S or N atom, in particular for thienyl , Furanyl or pyridyl.

The following compounds may be mentioned by way of example:

In addition to one or more compounds from the series of the sodium ion channel effectors disclosed above, the mixtures according to the invention contain at least one of the following compounds of the formulas (IX), (X) and (XI)

Compound (IX) is known from US 4,849,432.
Compound (X) is known from EP-0-375 907-A1.
Compound (XI) is known from EP-0-192 060.

In the mixtures, the ratio (in parts by weight) is between Na ions channel effectors and compound of formula (IX) to (XI) in general between 1: 0.1 and 1: 100, preferably between 1: 1 and 1:50.  

A particularly preferred mixture according to the invention contains the active ingredients indoxacarb of the formula

and clothianidin of formula (X)

Another particularly preferred mixture according to the invention contains the active substances indoxacarb of the formula

and thiacloprid of formula (IX)

Another particularly preferred mixture according to the invention contains the active substances indoxacarb of the formula

and imidacloprid of formula (XI)

The active substance combinations (mixtures) are suitable for combating animal pests, especially insects, arachnids and nematodes, which occur in agriculture, in forests, in the protection of stored products and materials, and in the hygiene sector with good plant tolerance and favorable warm-blood toxicity. They can preferably be used as pesticides. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The pests mentioned above include:
From the order of the Isopoda z. B. Oniscus asellus, Armadillidium vulgare, Porcellio scaber.
From the order of the Diplopoda z. B. Blaniulus guttulatus.
From the order of the Chilopoda z. B. Geophilus carpophagus, Scutigera spp.
From the order of the Symphyla z. B. Scutigerella immaculata.
From the order of the Thysanura z. B. Lepisma saccharina.
From the order of the Collembola z. B. Onychiurus armatus.
From the order of Orthoptera z. B. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
From the order of the Blattaria z. B. Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica.
From the order of the Dermaptera z. B. Auricular Forficula.
From the order of the Isoptera z. B. Reticulitermes spp.
From the order of the Phthiraptera z. B. Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.
From the order of the Thysanoptera z. B. Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
From the order of Heteroptera z. B. Eurygaster; spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.

From the order of Homoptera z. B. Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodellphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.

From the order of the Lepidoptera z. B. Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp.,  Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.

From the order of the Coleoptera z. B. Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus suleatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.

From the order of the Hymenoptera z. B. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.

From the order of the Diptera z. B. Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyia spp., Liriomyza spp.

From the order of the Siphonaptera z. B. Xenopsylla cheopis, Ceratophyllus spp.  

From the class of the Arachnida z. B. Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.

The plant parasitic nematodes include z. B. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.

According to the invention, all plants and parts of plants can be treated. Under Plants are understood to mean all plants and plant oil populations, such as desired and undesirable wild plants or crops (including naturally occurring crops). Cultivated plants can be plants that by conventional breeding and optimization methods or by biotechno logical and genetic engineering methods or combinations of these methods can be obtained, including the transgenic plants and inclusive plant varieties that can or cannot be protected by plant breeders' rights. Plant parts should include all above-ground and underground parts and organs of plants, such as sprout, leaf, flower and root L are understood, where exemplary leaves, needles, stems, stems, flowers, fruiting bodies, fruits and Seeds as well as roots, tubers and rhizomes are listed. To the plants sharing also includes crops, vegetative and generative propagation material, for example cuttings, tubers, rhizomes, cuttings and seeds.

The treatment according to the invention of the plants and parts of plants with the active ingredients substances are mixed directly or by influencing their surroundings, Habitat or storage space according to the usual treatment methods, e.g. B. by Diving, spraying, vaporizing, atomizing, sprinkling, brushing and if there is more  Rung material, especially in seeds, still by one or more layers Envelop.

The active ingredient mixtures can be converted into the customary formulations such as solutions, emulsions, wettable powders, suspensions, powders, dusts, Pastes, soluble powders, granules, suspension emulsion concentrates, active ingredient impregnated natural and synthetic materials as well as very fine encapsulation in polyme other fabrics.

These formulations are prepared in a known manner, e.g. B. by mixing of the active ingredients with extenders, i.e. liquid solvents and / or solid Carriers, optionally using surface-active agents, thus emulsifiers and / or dispersants and / or foam-producing Means.

In the case of the use of water as an extender, e.g. B. also organic Solvents are used as auxiliary solvents. As a liquid solvent essentially come into question: aromatics, such as xylene, toluene, or alkyl naphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as Chlorobenzenes, chlorethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. B. petroleum fractions, mineral and vegetable Oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as Acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar Solvents such as dimethylformamide and dimethyl sulfoxide, and water.

The following are suitable as solid carriers:
z. B. ammonium salts and natural rock powders such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders, such as highly disperse silica, aluminum oxide and silicates, are suitable as solid carriers for granules: z. B. broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours and granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stems; as emulsifying and / or foam-generating agents come into question: z. B. nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. B. alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolyzates; as dispersants come into question: z. B. lignin sulfite and methyl cellulose.

Adhesives such as carboxymethyl cellulose, natural, can be used in the formulations and synthetic powdery, granular or latex-shaped polymers are used, such as Gunimiarabicum, polyvinyl alcohol, polyvinyl acetate, and natural phospho lipids such as cephalins and lecithins and synthetic phospholipids. Further Additives can be mineral and vegetable oils.

Dyes such as inorganic pigments, e.g. B. iron oxide, titanium oxide, ferro cyan and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, Molybdenum and zinc can be used.

The formulations generally contain between 0.1 and 95% by weight Active ingredient, preferably between 0.5 and 90%.

The active ingredient according to the invention can be in its commercially available formulations and in the use forms prepared from these formulations in a mixture with other active ingredients, such as insecticides, attractants, sterilants, bactericides, Acaricides, nematicides, fungicides, growth regulators or herbi ziden available. Insecticides include, for example, phosphoric acid esters, Carbamates, carboxylic acid esters, chlorinated hydrocarbons, phenylureas, substances produced by microorganisms u. a.

Particularly cheap mixing partners are e.g. B. the following:  

fungicides

Aldimorph, ampropylfos, ampropylfos potassium, andoprim, anilazine, azaconazole, azoxystrobin,
Benalaxyl, Benodanil, Benomyl, Benzamacril, Benzamacryl-Isobutyl, Bialaphos, Binapacryl, Biphenyl, Bitertanol, Blasticidin-S. Bromuconazole, bupirimate, buthiobate,
Calcium polysulfide, capsimycin, captafol, captan, carbendazim, carboxin, carvone, quinomethionate (quinomethionate), chlobenthiazone, chlorfenazole, chloroneb, chloropicrin, chlorothalonil, chlozolinate, clozylacon, cufraneb, cymoxanil, cyphodarnocinil, cypodinconazole
Debacarb, dichlorophene, diclobutrazole, diclofluanide, diclomezin, dicloran, diethofencarb, difenoconazole, dimethirimol, dimethomorph; Diniconazol, Diniconazol-M, Dinocap, Diphenylamine, Dipyrithione, Ditalimfos, Dithianon, Dodemorph, Dodine, Drazoxolon,
Ediphenphos, Epoxiconazole, Etaconazole, Ethirimol, Etridiazole,
Famoxadone, Fenapanil, Fenarimol, Fenbuconazol, Fenfiuram, Fenitropan, Fenpiclonil, Fenpropidin, Fenpropimorph, Fentinacetat, Fentinhydroxyd, Ferbam, Ferimzon, Fluazinam, Flumetover, Fluoromid, Fluquinconazol, Flurprimidol, Flusprimol, Flusprimol, Flusprimol, Flusprimol, Flusprimol, Flusprimol, Flusprimol, Flusprimil, Flusprimidol, Flusilosol , Fosetyl sodium, fthalide, fuberidazole, furalaxyl, furametpyr, furcarbonil, furconazole, furconazole-cis, furmecyclox,
guazatine,
Hexachlorobenzene, hexaconazole, hymexazole,
Imazalil, Imibenconazol, Iminoctadin, Iminoctadinealbesilat, Iminoctadinetriacetat, Iodocarb, Ipconazol, Iprobefos (IBP), Iprodione, Irumamycin, Isoprothiolan, Isovaledione,
Kasugamycin, Kresoxim-methyl, copper preparations, such as: copper hydroxide, copper naphthenate, copper oxychloride, copper sulfate, copper oxide, oxine-copper and Bordeaux mixture,
Mancopper, Mancozeb, Maneb, Meferimzone, MepaniLpyrim, Mepronil, Metalaxyl, Metconazol, Methasulfocarb, Metrifuroxam, Metiram, Metomeclam, Metsulfovax, Mildiomycin, Myclobutanil, Myclozolin,
Nickel dimethyldithiocarbamate, nitrothal isopropyl, Nuarimol,
Ofurace, Oxadixyl, Oxamocarb, Oxolinicacid, Oxycarboxim, Oxyfenthiin,
Paclobutrazole, pefurazoate, penconazole, pencycuron, phosdiphen, pimaricin, piperalin, polyoxin, polyoxorim, probenazole, prochloraz, procymidon, propamocarb, propanosine sodium, propiconazole, propineb, pyrazophos, pyrifen, pyifenox, pyrroyilonil
Quinconazole, quintozen (PCNB),
Sulfur and sulfur preparations,
Tebuconazole, tecloftalam, tecnazene, Tetcyclacis, tetraconazole, thiabendazole, Thicyofen, Thifluzamide, thiophanate-methyl, thiram, Tioxymid, tolclofos-methyl, tolylfluanid, triadimefon, triadimenol, Triazbutil, triazoxide, Trichlamid, tricyclazole, tridemorph, triflumizole, triforine, triticonazole,
uniconazole
Validamycin A, vinclozolin, viniconazole,
Zarilamid, Zineb, Ziram as well
Dagger G,
OK 8705,
OK 8801,
α- (1,1-dimethylethyl) -β- (2-phenoxyethyl) -1H-1,2,4-triazole-1-ethanol,
α- (2,4-dichlorophenyl) -β-fluoro-b-propyl-1H-1,2,4-triazole-1-ethanol,
α- (2,4-dichlorophenyl) -β-methoxy-a-methyl-1H-1,2,4-triazole-1-ethanol,
α- (5-methyl-1,3-dioxan-5-yl) -β - [[4- (trifluoromethyl) phenyl] methylene] -1H-1,2,4-triazol-1-ethanol,
(5RS, 6RS) -6-Hydroxy-2,2,7,7-tetramethyl-5- (1H-1,2,4-triazol-1-yl) -3-octanone, (E) -a- (methoxyimino ) -N-methyl-2-phenoxy-phenylacetarnid,
{2-Methyl-1 - [[[1- (4-methylphenyl) ethyl] amino] carbonyl] propyl} carbamic acid 1-isopropyl ester
1- (2,4-dichlorophenyl) -2- (1H-1,2,4-triazol-1-yl) -ethanone-O- (phenylmethyl) oxime,
1- (2-methyl-1-naphthalenyl) -1H-pyrrole-2,5-dione,
1- (3,5-dichlorophenyl) -3- (2-propenyl) -2,5-pyrrolidinedione,
1 - [(diiodomethyl) sulphonyl] -4-methylbenzene,
1 - [[2- (2,4-dichlorophenyl) -1,3-dioxolan-2-yl] methyl] -1H-imidazole,
1 - [[2- (4-chlorophenyl) -3-phenyloxiranyl] methyl] -1H-1,2,4-triazole,
1- [1- [2 - [(2,4-dichlorophenyl) methoxy] phenyl] ethenyl] -1H-imidazole,
1-methyl-5-nonyl-2- (phenylmethyl) -3-pyrrolidinol,
2 ', 6'-dibromo-2-methyl-4'-trifluoromethoxy-4'-trifluoromethyl-1,3-thiazole-5-carboxanilide,
2,2-dichloro-N- [1- (4-chlorophenyl) ethyl] -1-ethyl-3-methyl-cyclopropanecarboxamide,
2,6-dichloro-5- (methylthio) -4-pyrimidinyl thiocyanate,
2,6-dichloro-N- (4-trifluoromethylbenzyl) -benzamide,
2,6-dichloro-N - [[4- (trifluoromethyl) phenyl] methyl] benzamide,
2- (2,3,3-triiodo-2-propenyl) -2H-tetrazole,
2 - [(1-methylethyl) sulphonyl] -5- (trichloromethyl) -1,3,4-thiadiazole,
2 - [[6-Deoxy-4-O- (4-O-methyl-β-D-glycopyranosyl) -aD-glucopyranosyl] amino] -4- methoxy-1H-pyrrolo [2,3-d] pyrimidine- 5-carbonitrile,
2-aminobutane,
2-bromo-2- (bromomethyl) -pentandinitril,
2-chloro-N- (2,3-dihydro-1,1,3-trimethyl-1H-inden-4-yl) -3-pyridine carboxamide,
2-chloro-N- (2,6-dimethylphenyl) -N- (isothiocyanatomethyl) -acetamide,
2-phenylphenol (OPP),
3,4-dichloro-1- [4- (difluoromethoxy) phenyl] -1H-pyrrole-2,5-dione,
3,5-dichloro-N- [cyano [(1-methyl-2-propynyl) oxy] -methylL] -benzamide,
3- (1,1-dimethylpropyl-1-oxo-1H-indene-2-carbonitrile,
3- [2- (4-chlorophenyl) -5-ethoxy-3-isoxazolidinyl] -pyridine,
4-chloro-2-cyano-N, N-dimethyl-5- (4-methylphenyl) -1H-imidazol-1-sulfonamide,
4-methyl-tetrazolo [1,5-a] quinazolin-5 (4H) -one,
8- (1,1-dimethylethyl) -N-ethyl-N-propyl-1,4-dioxaspiro [4.5] decane-2-methanamine,
8-hydroxyquinoline sulfate,
9H-xanthene-9-carboxylic acid 2 - [(phenylamino) carbonyl] hydrazide,
bis (1-methylethyl) -3-methyl-4 - [(3-methylbenzoyl) oxy] -2,5-thiophene dicarboxylate,
cis-1- (4-chlorophenyl) -2- (1H-1,2,4-triazol-1-yl) cycloheptanol,
cis-4- [3- [4- (1,1-dimethylpropyl) phenyl-2-methylpropyl] -2,6-dimethylmorpholine hydrochloride,
Ethyl - [(4-chlorophenyl) azo] cyanoacetate,
potassium bicarbonate,
Methantetrathiol sodium salt,
Methyl-1- (2,3-dihydro-2,2-dimethyl-1H-inden-1-yl) -1H-imidazole-5-carboxylate,
Methyl-N- (2,6-dimethylphenyl) -N- (5-isoxazolylcarbonyl) -DL-alaninate,
Methyl N- (chloroacetyl) -N- (2,6-dimethylphenyl) -DL-alaninate,
N- (2,3-dichloro-4-hydroxyphenyl) -1-methyl-cyclohexanecarboxamide.
N- (2,6-dimethylphenyl) -2-methoxy-N- (tetrahydro-2-oxo-3-furanyl) acetamide,
N- (2,6-dimethylphenyl) -2-methoxy-N- (tetrahydro-2-oxo-3-thienyl) acetamide,
N- (2-chloro-4-nitrophenyl) -4-methyl-3-nitro-benzenesulfonamide,
N- (4-Cyclohexylphenyl) -1,4,5,6-tetrahydro-2-pyrimidinamine,
N- (4-hexylphenyl) -1,4,5,6-tetrahydro-2-pyrimidinamine,
N- (5-chloro-2-methylphenyl) -2-methoxy-N- (2-oxo-3-oxazolidinyl) -acetamide,
N- (6-methoxy) -3-pyridinyl) -cyclopropanecarboxamide,
N- [2,2,2-trichloro-1 - [(chloroacetyl) amino] ethyl-benzamide,
N- [3-chloro-4,5-bis- (2-propynyloxy) -phenyl] -N'-methoxy-methanimidamid,
N-formyl-N-hydroxy-DL-alanine sodium salt,
O, O-diethyl [2- (dipropylamino) -2-oxoethyl] -ethylphosphoramidothioat,
O-methyl-S-phenyl-phenylpropylphosphoramidothioat,
S-Methyl-1,2,3-benzothiadiazole-7-carbothioate,
spiro [2H] -1-benzopyran-2,1 '(3'H) -isobenzofuran] -3'-one,

bactericidal

Bronopol, dichlorophene, nitrapyrin, nickel dimethyldithiocarbamate, kasugamycin, Octhilinone, furan carboxylic acid, oxytetracycline, probenazole, streptomycin, Teclofia lam, copper sulfate and other copper preparations.

Insecticides / acaricides / nematicides

Abamectin, Acephate, Acetamiprid, Acrinathrin, Alanycarb, Aldicarb, Aldoxycarb, Alpha-cypermethrin, Alphamethrin, Amitraz, Avermectin, AZ 60541, Azadirachtin, Azamethiphos, Azinphos A, Azinphos M, Azocyclotin,
Bacillus popilliae, Bacillus sphaericus, Bacillus subtilis, Bacillus thuringiensis, Baculoviruses, Beauveria bassiana, Beauveria tenella, Bendiocarb, Benfuracarb, Bensultap, Benzoximate, Betacyfluthrin, Bifenazate, Bifenthrin, Biethanoprofinoxhrin, Bethenomethrofin, Biobanomethrin Butyl pyridaben
Cadusafos, carbaryl, carbofuran, carbophenothion, carbosulfan, cartap, Chloethocarb, chlorethoxyfos, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormephos, chlorpyrifos, chlorpyrifos M, Chlovaporthrin, cis-resmethrin, Cispermethrin, Clocythrin, cloethocarb, clofentezine, cyanophos, Cycloprene, cycloprothrin, cyfluthrin , Cyhalothrin, cyhexatin, cypermethrin, cyromazine,
Deltamethrin, Demeton M, Demeton S, Demeton-S-methyl, Diafenthiuron, Diazinon, Dichlorvos, Diflubenzuron, Dimethoat, Dimethylvinphos, Diofenolan, Disulfoton, Docusat-sodium, Dofenapyn,
Eflusilanate; Emamectin, Empenthrin, Endosulfan, Entomopfthora spp., Eprinomectin, Esfenvalerate, Ethiofencarb, Ethion, Ethoprophos, Etofenprox, Etoxazole, Etrimfos,
Fenamiphos, Fenazaquin, Fenbutatin oxide, Fenitrothion, Fenothiocarb, Fenoxacrim, Fenoxycarb, Fenpropathrin, Fenpyrad, Fenpyrithrin, Fenpyroximate, Fenvalerate, Fipronil, Fluazinam, Fluazuron, Flubrocythrinate, Flucycloxoxinon, Fluutinoxuron, Fluutinoxuron, Fluutinoxuron, Fluutinoxinone, , Furathiocarb,
granulosis
Halofenozide, HCH, Heptenophos, Hexaflumuron, Hexythiazox, Hydroprene, Imidacloprid, Isazofos, Isofenphos, Isoxathion, Ivermectin, Kernpolyederviruses
Lambda cyhalothrin, lufenuron
Malathion, mecarbam, metaldehyde, methamidophos, metharhilic anisopliae, metharhilic flavoviride, methidathione, methiocarb, methomyl, methoxyfenozide, metolcarb, metoxadiazone; Mevinphos, Milbemectin, Monocrotophos,
Naled, Nitenpyram, Nithiazine, Novaluron
Omethoate, Oxamyl, Oxydemethon M
Paecilomyces fumosoroseus, Parathion A, Parathion M, Permethrin, Phenthoat, Phorat, Phosalone, Phosmet, Phosphamidon, Phoxim, Pirimicarb, Pirimiphos A, Pirimiphos M, Profenofos, Promecarb, Propoxur, Prothiofos, Prothoat, Pyromhrhridos, Pymmethrofzin, Pymmethrofinos , Pyridathione, pyrimidifen, pyriproxyfen,
quinalphos,
ribavirin
Salithion, Sebufos, Selamectin, Silafluofen, Spinosad, Sulfotep, Sulprofos,
Tau-fluvalinate, oxalate hydrogen tebufenozide, tebufenpyrad, Tebupirimiphos, teflubenzuron, tefluthrin, temephos, Temivinphos, terbufos, tetrachlorvinphos, theta cypermethrin, thiamethoxam, Thiapronil, Thiatriphos, thiocyclam, thiodicarb, thiofanox, thuringiensin, Tralocythrin, tralomethrin, triarathene, Triazamate, triazophos , Triazuron, trichlophenidine, trichlorfon, triflumuron, trimethacarb,
Vamidothion, Vaniliprole, Verticillium lecanii
YI 5302
Zeta-cypermethrin, zolaprofos
(1R-cis) - [S- (phenylmethyl) -3-furanyl] methyl-3 - [(dihydro-2-oxo-3 (2H) - furanylidene) methyl] -2,2-dimethylcyclopropane carboxylate
(3-phenoxyphenyl) methyl-2,2,3,3-tetramethylcyclopropanecarboxylat
1 - [(2-Chloro-5-thiazolyl) methyl] tetrahydro-3,5-dimethyl-N-nitro-1,3,5-triazine-2 (1H) - imine
2- (2-chloro-6-fluorophenyl) -4- [4- (1,1-dimethylethyl) phenyl] -4,5-dihydro-oxazol
2- (Acetlyoxy) -3-dodecyl-1,4-naphthalenedione
2-chloro-N - [[[4- (1-phenylethoxy) phenyl] amino] carbonyl] -benzamide
2-chloro-N - [[[4- (2,2-dichloro-1,1-difluoroethoxy) phenyl] amino] carbonyl] -benzamide
3-methylphenyl propylcarbamate
4- [4- (4-ethoxyphenyl) -4-methylpentyl] -1-fluoro-2-phenoxy-benzene
4-chloro-2- (1,1-dimethylethyl) -5 - [[2- (2,6-dimethyl-4-phenoxyphenoxy) ethyl] thio] - 3 (2H) pyridazinone
4-chloro-2- (2-chloro-2-methylpropyl) -5 - [(6-iodo-3-pyridinyl) methoxy] -3 (2H) - pyridazinone
4-chloro-5 - [(6-chloro-3-pyridinyl) methoxy] -2- (3,4-dichlorophenyl) -3 (2H) -pyridazinone
Bacillus thuringiensis strain EG-2348
Benzoic acid [2-benzoyl-1- (1,1-dimethylethyl) hydrazide
Butanoic acid 2,2-dimethyl-3- (2,4-dichlorophenyl) -2-oxo-1-oxaspiro [4.5] dec-3-en-4-yl ester
[3 - [(6-chloro-3-pyridinyl) methyl] -2-thiazolidinylidene] -cyanamide
Dihydro-2- (nitromethylene) -2H-1,3-thiazine-3 (4H) -carboxaldehyde
Ethyl [2 - [[1,6-dihydro-6-oxo-1- (phenylmethyl) -4-pyridazinyl] oxy] ethyl carbamate
N- (3,4,4-trifluoro-1-oxo-3-butenyl) -glycine
N- (4-chlorophenyl) -3- [4- (difluoromethoxy) phenyl] -4,5-dihydro-4-phenyl-1H-pyrazole-1-carboxamide
N - [(2-chloro-5-thiazolyl) methyl] -N'-methyl-N "nitroguanidine
N-methyl-N '- (1-methyl-2-propenyl) -1,2-hydrazindicarbothioamid
N-methyl-N'-2-propenyl-1,2-hydrazindicarbothioamid
O, O-diethyl [2- (dipropylamino) -2-oxoethyl] -ethylphosphoramidothioat

A mixture with other known active ingredients, such as herbicides or with Fertilizers and growth regulators are possible.

The active compound combinations according to the invention can also be used as Insecticides in their commercial formulations and in those from them Formulations prepared application forms in combination with synergists available. Synergists are compounds through which the action of the active ingredients is increased without the added synergist itself having to be active.  

The active ingredient content of the prepared from the commercially available formulations Application forms can vary widely. The drug concentration of the Use forms can be from 0.0000001 to 95% by weight of active ingredient, preferably are between 0.0001 and 1% by weight.

The application takes place in a customary manner adapted to the application forms Wise.

When used against hygiene and storage pests, the effects stand out fabric mixes through an excellent residual effect on wood and clay as well due to good stability to alkali on limed substrates.

The active compound combinations according to the invention act not only against plant, hygiene and stored-product pests, but also in the veterinary sector against animal parasites (ectoparasites) such as tick ticks, leather ticks, space mites, running mites, flies (stinging and licking), parasitic fly larvae, lice and hair lice , Featherlings and fleas. These parasites include:
From the order of the Anoplurida z. B. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.
From the order of the Mallophagida and the subordinates Amblycerina and Ischnocerina z. B. Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp.
From the order Diptera and the subordinates Nematocerina and Brachycerina z. B. Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp ., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.
From the order of the Siphonapterida z. B. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.
From the order of the Heteropterida z. B. Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.
From the order of the Blattarida z. B. Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp.
From the subclass of Acaria (Acarida) and the orders of the Meta and Mesostigmata z. B. Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp. Pneumonyssus spp., Sternostoma spp., Varroa spp.
From the order of the Actinedida (Prostigmata) and Acaridida (Astigmata) z. B. Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp. Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.

The active compound combinations according to the invention are also suitable for combating of arthropods, the farm animals, such as. B. cattle, sheep, goats, Horses, pigs, donkeys, camels, buffaloes, rabbits, chickens, turkeys, ducks, geese, Bees, other pets such as B. dogs, cats, house birds, aquarium fish as well as so-called experimental animals, such as. B. hamsters, guinea pigs, rats and Infest mice. By fighting these arthropods, deaths and  Reductions in performance (for meat, milk, wool, skins, eggs, honey, etc.) can be reduced, so that by using the active compounds according to the invention more economical and easier animal husbandry is possible.

The active ingredient mixtures according to the invention are used in veterinary medicine närsektor in a known manner by enteral administration in the form of for example tablets, capsules, drinkers, drenches, granules, pastes, boluses, des suppository method, from suppositories, by parenteral administration, such as Example by injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), Implants, by nasal application, by dermal application in the form of for example diving or bathing (dipping), spraying (spray), pouring on (Pour-on and spot-on), washing, powdering and with the help of active molded articles, such as collars, ear tags, tail tags, link measuring tapes, holsters, marking devices etc.

When used for cattle, poultry, pets, etc., you can use the active ingredient formulations (e.g. powders, emulsions, flowable Agents), which contain the active ingredients in an amount of 1 to 80 wt .-%, directly or after 100 to 10,000-fold dilution or use it as a chemical bath use.

It has also been found that the mixtures according to the invention have a high Show insecticidal activity against insects that destroy technical materials.

The following insects may be mentioned by way of example and preferably, but without limitation:
Beetle like
Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearesces, Specus Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus.
Skin wings like
Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur.
Termites like
Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus.
Bristle tails such as Lepisma saccharina.

In the present context, technical materials include non-living ones Understand materials, such as preferably plastics, adhesives, glues, papers and cartons, leather, wood, woodworking products and paints.

The one to be protected against insect attack is very particularly preferably Material around wood and wood processing products.

Wood and wood processing products which can be protected by the agent according to the invention or mixtures containing it are to be understood as examples:
Lumber, wooden beams, railway sleepers, bridge parts, jetties, wooden vehicles, boxes, pallets, containers, telephone poles, wooden cladding, wooden windows and doors, plywood, chipboard, carpentry or wooden products that are generally used in house construction or joinery.

The active ingredients can be used as such, in the form of concentrates or in general usual formulations such as powders, granules, solutions, suspensions, emulsions or pastes.

The formulations mentioned can be prepared in a manner known per se become; z. B. by mixing the active ingredients with at least one solution or Diluents, emulsifiers, dispersants and / or binders or fixatives, Water repellants, possibly desiccants and UV stabilizers and added if necessary dyes and pigments and other processing aids.

The insecticidal agents or used to protect wood and wood-based materials Concentrates contain the active ingredient according to the invention in a concentration of 0.0001 to 95% by weight, in particular 0.001 to 60% by weight.

The amount of agents or concentrates used depends on the type and type come from insects and depending on the medium. The optimal amount to use can be determined by test series in the application. In general however, it is sufficient 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of the active ingredient, based on the material to be protected.

An organic chemical solution serves as the solvent and / or diluent medium or solvent mixture and / or an oily or oily heavy volatile organic chemical solvent or solvent mixture and / or a polar organic chemical solvent or solvent mixture and / or water and optionally an emulsifier and / or wetting agent.

The organic chemical solvents used are preferably oily or oily ones Solvents with an evaporation number above 35 and a flash point above 30 ° C, preferably above 45 ° C, used. As such volatile, Water-insoluble, oily and oily solvents become corresponding mineral oils  or their aromatic fractions or mineral oil-containing solvent mixtures preferably white spirit, petroleum and / or alkylbenzene used.

Mineral oils with a boiling range of 170 to 220 ° C are advantageous, test petrol with a boiling range of 170 to 220 ° C, spindle oil with a boiling range from 250 to 350 ° C, petroleum or aromatics with a boiling range from 160 to 280 ° C, Turpentine oil and the like.

In a preferred embodiment, liquid aliphatic hydrocarbons substances with a boiling range of 180 to 210 ° C or high-boiling mixtures of aromatic and aliphatic hydrocarbons with a boiling range of 180 to 220 ° C and / or locker oil and / or monochloronaphthalene, preferably α- Monochloronaphthalene used.

The organic non-volatile oily or oily solvents with a Evaporation rate above 35 and a flash point above 30 ° C, preferably above 45 ° C, can be partially organic or slightly volatile chemical solvents are replaced, provided that the solvent mix also an evaporation number above 35 and a flash point above 30 ° C, preferably above 45 ° C, and that the insecticide fungicide Ge is soluble or emulsifiable in this solvent mixture.

According to a preferred embodiment, part of the organic chemical Solvent or solvent mixture through an aliphatic polar orga niche chemical solvent or solvent mixture replaced. Preferably come aliphatic containing hydroxyl and / or ester and / or ether groups organic chemical solvents such as glycol ether, ester or the like. to use.

Within the scope of the present Er finding the known water-dilutable and / or in the used  organic chemical solvents soluble or dispersible or emulsifiable Synthetic resins and / or binding drying oils, in particular binders from or containing an acrylic resin, a vinyl resin, e.g. B. polyvinyl acetate, Polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin such as indene Coumarone resin, silicone resin, drying vegetable and / or drying oils and / or physically drying binders based on a natural and / or synthetic resin used.

The synthetic resin used as a binder can be in the form of an emulsion, dispersion or solution. Bitumen or bitumi can also be used as binders nous substances up to 10 wt .-% can be used. In addition, in itself known dyes, pigments, water repellants, odor correctors and Inhibitors or anticorrosive agents and the like are used.

According to the invention, preference is given to at least one organic chemical binder an alkyd resin or modified alkyd resin and / or a drying vegetable Contain oil in the medium or in the concentrate. Are preferred according to the invention Alkyd resins with an oil content of more than 45% by weight, preferably 50 to 68% by weight.

The binder mentioned can be wholly or partly by a fixative (ge mix) or a plasticizer (mixture) can be replaced. These additions are said to be one Prevent volatilization of the active ingredients as well as crystallization or precipitation. They preferably replace 0.01 to 30% of the binder (based on 100% of the binder used).

The plasticizers come from the chemical classes of phthalic acid esters such as Dibutyl, dioctyl or benzyl butyl phthalate, phosphoric acid esters such as tributyl phosphate, adipic acid esters such as di- (2-ethylhexyl) adipate, stearates such as butyl stearate  or amyl stearate, oleates such as butyl oleate, glycerol ether or higher molecular weight Gly kolether, glycerol ester and p-toluenesulfonic acid ester.

Fixing agents are chemically based on polyvinyl alkyl ethers such as. B. Polyvinyl methyl ether or ketones such as benzophenone, ethylene benzophenone.

Water is also particularly suitable as a solvent or diluent, optionally mixed with one or more of the above organic chemical solvents or diluents, emulsifiers and dispersants.

A particularly effective wood protection is achieved through industrial impregnation processes, z. B. vacuum, double vacuum or printing process.

The ready-to-use agents can, if appropriate, still further insecticides and optionally contain one or more fungicides.

The additional mixing partners are preferably those in WO 94/29 268 Insecticides and fungicides mentioned in question. The ones mentioned in this document Connections are an integral part of this application.

Particularly preferred mixing partners can be insecticides, such as chlorpyriphos, Phoxim, silafluofin, alphamethrin, cyfluthrin, cypermethrin, deltamethrin, Permethrin, Irnidacloprid, NI-25, Flufenoxuron, Hexaflumuron, Transfluthrin, Thia cloprid, methoxyphenoxide and triflumuron, as well as fungicides such as epoxyconazole, hexaconazole, azaconazole, propiconazole, Tebuconazole, cyproconazole, metconazole, imazalil, dichlorfluanid, tolylfluanid, 3-iodo-2-propynyl butyl carbamate, N-octyl-isothiazolin-3-one and 4,5-dichloro-N- octylisothiazolin-3-one.

At the same time, the mixtures according to the invention can be used to protect against growth of Objects, in particular of hulls, screens, nets, structures, quay  locations and signaling systems that come into contact with sea or brackish water, be used.

Overgrowth by sessile oligochaetes, such as lime tube worms and by mussels and species of the group Ledamorpha (barnacles), such as various Lepas and Scalpellum species, or by species from the group Balanomorpha (barnacles), such as Balanus or pollicipes species, increases the frictional resistance of ships and subsequently performs through increased energy consumption and beyond frequent dry dock stays for a significant increase in operating costs.

In addition to the growth by algae, for example Ectocarpus sp. and Ceramium sp., comes in particular the vegetation by sessile Entomostraken groups, which are summarized under the name Cirripedia (barnacles) their importance.

It has now surprisingly been found that the mixtures according to the invention gene alone or in combination with other active ingredients, an excellent Have antifouling effect.

By using the mixtures according to the invention alone or in combination with other active ingredients, can rely on the use of heavy metals such. B. in bis- (trialkyltin) sulfides, tri-n-butyltin laurate, tri-n-butyltin chloride, copper (I) oxide, Triethyltin chloride, tri-n-butyl (2-phenyl-4-chlorophenoxy) tin, tributyltin oxide, Molybdenum disulfide, antimony oxide, polymeric butyl titanate, phenyl (bispyridine) - bismuth chloride, tri-n-butyltin fluoride, manganese ethylene bisthiocarbamate, zinc di methyldithiocarbamate, zinc ethylene bisthiocarbamate, zinc and copper salts of 2- Pyridinthiol-1-oxide, bisdimethyldithiocarbamoylzinkethylenististhiocarbamate, zinc oxide, copper (I) ethylene bisdithiocarbamate, copper thiocyanate, copper naphthenate and Tributyltin halides are omitted or the concentration of this verbin reduced significantly.  

The ready-to-use antifouling paints can also be used if necessary Active ingredients, preferably algicides, fungicides, herbicides, molluscicides or others Contain antifouling agents.

Suitable combination partners for the antifouling agents according to the invention are preferably:
Algicides like
2-tert-butylamino-4-cyclopropylamino-6-methylthio-1,3,5-triazine, dichlorophene, diuron, endothal, fentin acetate, isoproturon, methabenzthiazuron, oxyfluorfen, quinoclamine and terbutryn;
Fungicides like
Benzo [b] thiophenecarboxylic acid cyclohexylamide-S, S-dioxide, dichlofluanid, fluor folpet, 3-iodo-2-propynyl-butylcarbamate, tolylfluanid and azoles such as azaconazole, cyproconazole, epoxyconazole, hexaconazole, metconazole, propiconazole and propiconazole;
Molluscicides like
Fentin acetate, metaldehyde, methiocarb, niclosamide, thlodicarb and trimethacarb;
or conventional antifouling agents such as 4,5-dichloro-2-octyl-4-isothiazolin-3-one, diiodomethylparatrylsulfone, 2- (N, N -dimethylthiocarbamoylthio) -5-nitrothiazyl, potassium, copper, sodium and Zinc salts of 2-pyridinthiol-1-oxide, pyridine triphenylborane, tetrabutyldistannoxane, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, 2,4,5,6-tetrachloroisophthalonitrile, tetramethylthiuram disulfide and 2,4, 6-Trichlorphenylmaleinimid.

The antifouling agents used contain the active ingredient according to the invention compounds according to the invention in a concentration of 0.001 to 50% by weight, in particular from 0.01 to 20% by weight.  

The antifouling agents according to the invention further contain the usual ones Components such as B. in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.

Antifouling paints contain algicidal, fungicidal, molluscicides and insecticidal active substances according to the invention, in particular binders.

Examples of recognized binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in one Solvent system especially in an aqueous system, vinyl chloride / vinyl acetate copolymer systems in the form of aqueous dispersions or in the form of organic solvent systems, butadiene / styrene / acrylonitrile rubbers, dry oils such as linseed oil, resin esters or modified hard resins in combination with tar or bitumen, asphalt and epoxy compounds, small amounts of chlorine rubber, chlorinated polypropylene and vinyl resins.

Paints may also contain inorganic pigments, organic Pigments or dyes, which are preferably insoluble in sea water. Further Paints can contain materials, such as rosin, to be controlled To enable release of the active ingredients. The paints can also be soft makers, modifiers influencing the rheological properties, and contain other conventional ingredients. Also in self-polishing antifouling Systems can be the compounds of the invention or those mentioned above Mixtures can be incorporated.

The active ingredient mixtures are also suitable for controlling animal pests, in particular insects, arachnids and mites, which are used in closed rooms, such as, for example, apartments, factory halls, offices, vehicle cabins and the like. occur. To control these pests, they can be used alone or in combination with other active ingredients and auxiliaries in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include:
From the order of the Scorpionidea z. B. Buthus occitanus.
From the order of Acarina z. B. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides formae.
From the order of the Araneae z. B. Aviculariidae, Araneidae.
From the order of the Opiliones z. B. Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
From the order of the Isopoda z. B. Oniscus asellus, Porcellio scaber.
From the order of the Diplopoda z. B. Blaniulus guttulatus, Polydesmus spp.
From the order of the Chilopoda z. B. Geophilus spp.
From the order of the Zygentoma z. B. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
From the order of the Blattaria z. B. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Feriplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.
From the order of the Saltatoria z. B. Acheta domesticus.
From the order of the Dermaptera z. B. Auricular Forficula.
From the order of the Isoptera z. B. Kalotermes spp., Reticulitermes spp.
From the order of Psocoptera z. B. Lepinatus spp., Liposcelis spp.
From the order of the Coleptera z. B. Antbrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.
From the order of the Diptera z. B. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musaria domestica. , Stomoxys calcitrans, Tipula paludosa.
From the order of the Lepidoptera z. B. Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
From the order of the Siphonaptera z. B. Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
From the order of the Hymenoptera z. B. Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
From the order of the Anoplura z. B. Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis.
From the order of Heteroptera z. B. Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.

The application in the field of household insecticides is carried out alone or in Kombina tion with other suitable active ingredients such as phosphoric acid esters, carbamates, Pyrethroids, growth regulators or active ingredients from other known Classes of insecticides.

The application takes place in aerosols, unpressurized sprays, e.g. B. Pump and Atomizer sprays, automatic fog machines, foggers, foams, gels, vaporizers products with evaporator platelets made of cellulose or plastic, liquid evaporators, Gel and membrane evaporators, propeller-driven evaporators, energy-free or passive evaporation systems, moth papers, moth bags and Moth angels, as granules or dusts, in lures or bait stations.

As already mentioned above, according to the invention all plants and their parts can be treated. In a preferred embodiment, wild occur or by conventional organic breeding methods, such as crossbreeding or Protoplast fusion obtained plant species and plant varieties and their parts treated. In a further preferred embodiment, transgenes are  Plants and plant varieties, if necessary by genetic engineering methods in combination with conventional methods (Genetic Modified Organisms) and their parts treated. The term "parts" or "parts of Plants "or" parts of plants "was explained above.

Plants of the commercially available in each case are particularly preferred according to the invention or plant varieties in use. Among plant varieties is understood to mean plants with certain properties ("traits") that are characterized by both conventional breeding, by mutagenesis or by recombinant DNA Techniques have been obtained. These can be varieties, bio and genotypes.

Depending on the plant species or plant varieties, their location and growth conditions (soils, climate, growing season, nutrition) can be determined by the Treatment according to the invention also has superadditive ("synergistic") effects For example, reduced application rates and / or extensions of the Spectrum of activity and / or an enhancement of the effect of the invention usable substances and agents, better plant growth, increased tolerance against high or low temperatures, increased tolerance to drought or against water or soil salt content, increased flowering performance, easier harvesting, Acceleration of ripeness, higher crop yields, higher quality and / or higher Nutritional value of the harvested products, higher shelf life and / or workability of the harvested products possible that go beyond the expected effects go.

Among the preferred transgenic (genetic engineering) to be treated according to the invention genetically preserved) plants or plant varieties belong to all plants that are affected by the received genetic engineering modification genetic material, which this Gives plants special beneficial valuable properties ("traits"). Examples for such properties are better plant growth, increased tolerance to over high or low temperatures, increased drought tolerance or against water or soil salt content, increased flowering performance, easier harvesting,  Acceleration of ripeness, higher crop yields, higher quality and / or higher Nutritional value of the harvested products, higher shelf life and / or workability of the harvest products. Further and particularly highlighted examples of such Properties are an increased defense of the plants against animal and micro biological pests, such as insects, mites, phytopathogenic fungi, Bacteria and / or viruses and an increased tolerance of the plants to certain herbicidal active ingredients. The important ones are examples of transgenic plants Cultivated plants, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, Rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and Grapes) mentioned, especially corn, soybeans, potatoes, cotton and rapeseed be highlighted. As properties ("traits") are particularly prominent raised the plants' increased defense against insects through in the plants emerging toxins, especially those characterized by the genetic material Bacillus thuringiensis (e.g. through the genes CryIA (a), CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CryIF and their combinations) are produced in the plants (hereinafter "Bt plants"). As properties ("Traits") are also particularly emphasized the increased defense against plants against fungi, bacteria and viruses through Systemic Acquired Resistance (SAR), Systemin, phytoalexins, elicitors and resistance genes and correspondingly expri protein and toxins. As properties ("traits") continue to be special highlighted the increased tolerance of plants to certain herbicides Active ingredients, for example imidazolinones, sulfonylureas, glyphosates or Phosphinotricin (e.g. "PAT" gene). Each of the desired properties ("Traits") conferring genes can also be combined with each other in the transgenic plants. Examples of "Bt plants" are maize varieties, Sorts of cotton, soybeans and potatoes are mentioned under the trade designations YIELD GARD® (e.g. corn, cotton, soy), Knockout® (e.g. Maize), StarLink® (e.g. maize), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf® (potato) are sold. As examples of herbicide tolerant Plants are maize varieties, cotton varieties and soy varieties that are among the Trade names Roundup Ready® (tolerance against glyphosate e.g. maize,  Cotton, soy), Liberty Link® (tolerance to phosphinotricin, e.g. rapeseed), IMI® (Tolerance to imidazolinones) and STS® (tolerance to sulfonylureas e.g. Maize). As a herbicide resistant (conventional herbicide- Plants grown tolerance are also those under the name Clearfield® distributed varieties (e.g. maize) mentioned. Of course, these statements apply also for those developed in the future or coming onto the market in the future Plant varieties with these or future genetic characteristics ( "Traits").

The plants listed can be particularly advantageous according to the invention with the Active ingredient mixtures according to the invention are treated. The active ingredients Preferred ranges or mixtures given above also apply to the Treatment of these plants. Plant treatment should be particularly emphasized with the compounds or mixtures specifically listed in the present text.  

applications Calculation formula for the degree of killing of a combination of two active substances

The expected effect for a given combination of two active substances can (See Colby, S.R., "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds 15, pages 20-22, 1967) can be calculated as follows:

If
X the degree of destruction, expressed in% of the untreated control, when using the active ingredient A in an application rate of m ppm,
Y the degree of destruction, expressed in% of the untreated control, when the active ingredient B is used in an application rate of n ppm,
E means the degree of destruction, expressed in% of the untreated control, when active ingredients A and B are used in application rates of m and n ppm,
then

If the actual degree of insecticidal killing is greater than calculated, then that is Combination superadditive in killing, i.e. H. there is a synergistic effect in front. In this case, the degree of killing actually observed must be greater than the value for the expected Ab calculated from the above formula Degree of killing (E).  

Example A Phaedon larvae test

Solvent: 7 parts by weight of dimethylformamide
Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 Ge is mixed most of the active ingredient with the specified amounts of solvent and emulsifier and dilute the concentrate with water containing emulsifier to the desired level Concentration.

Cabbage leaves (Brassica oleracea) are dipped into the active ingredient preparation the desired concentration and treated with larvae of the horseradish leaf beetle (Phaedon cochleariae) occupied while the leaves are still moist.

After the desired time, the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae are released were killed. The determined killing values are calculated using the Colby formula (see sheet 1).

In this test, the following combination of active ingredients according to the present An showed report a synergistically enhanced effectiveness compared to the individual Active ingredients used:  

Table A sheet 1

plant-damaging insects

Phaedon larvae test

Table A Sheet 2

plant-damaging insects

Phaedon larvae test

Example B Plutella test (normally sensitive)

Solvent: 7 parts by weight of dimethylformamide
Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 Ge is mixed most of the active ingredient with the specified amounts of solvent and emulsifier and dilute the concentrate with water containing emulsifier to the desired level Concentration.

Cabbage leaves (Brassica oleracea) are dipped into the active ingredient preparation the desired concentration and treated with normal sensitive caterpillars Cabbage cockroach (Plutella xylostella) occupied while the leaves are still moist.

After the desired time, the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars are killed were. The determined killing values are calculated using the Colby formula (see sheet 1).

In this test, the following combination of active substances according to the present An showed report a synergistically enhanced effectiveness compared to the individual Active ingredients used:  

Table B

plant-damaging insects

Example C Plutella test (resistant)

Solvent: 7 parts by weight of dimethylformamide
Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 Ge is mixed most of the active ingredient with the specified amounts of solvent and emulsifier and dilute the concentrate with water containing emulsifier to the desired level Concentration.

Cabbage leaves (Brassica oleracea) are dipped into the active ingredient preparation the desired concentration and treated with resistant caterpillars of the cabbage cockroach (Plutella xylostella) occupied while the leaves are still moist.

After the desired time, the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars are killed were. The determined killing values are calculated using the Colby formula (see sheet 1).

In this test, the following combination of active substances according to the present An showed report a synergistically enhanced effectiveness compared to the individual Active ingredients used:  

Table C.

plant-damaging insects

Plutella test (resistant)

Example D Spodoptera frugiperda test

Solvent: 7 parts by weight of dimethylformamide
Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 Ge is mixed most of the active ingredient with the specified amounts of solvent and emulsifier and dilute the concentrate with water containing emulsifier to the desired level Concentration.

Cabbage leaves (Brassica oleracea) are dipped into the active ingredient preparation of the desired concentration and treated with caterpillars of the army worm (Spodoptera frugiperda) occupied while the leaves are still moist.

After the desired time, the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars are killed were. The determined killing values are calculated using the Colby formula (see sheet 1).

In this test, the following combination of active ingredients according to the present An showed report a synergistically enhanced effectiveness compared to the individual Active ingredients used:  

Table D

plant-damaging insects

Spodoptera frugiperda test

Example E Heliothis virescens test

Solvent: 7 parts by weight of dimethylformamide
Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 Ge is mixed most of the active ingredient with the specified amounts of solvent and emulsifier and dilute the concentrate with water containing emulsifier to the desired level Concentration.

Soybean shoots (Glycine max) are dipped into the active ingredient preparation of the ge desired concentration and treated with Heliothis virescens caterpillars, see above as long as the leaves are still moist.

After the desired time, the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars are killed were. The determined killing values are calculated using the Colby formula (see sheet 1).

In this test, the following combination of active ingredients according to the present An showed report a synergistically enhanced effectiveness compared to the individual Active ingredients used:  

Table E

plant-damaging insects

Heliothis virescens test

Claims (1)

Mixtures containing one or more sodium ion channel effectors and the Compound (Z) -3- (6-chloro-3-pyridylmethyl) -1,3-thiazolidin-2-ylidencyanamide or the compound (E) -1- (2-chloro-1,3-thiazol-5-ylmethyl) -3-methyl-2-nitroguanidine or the compound 1 - [(6-chloro-3-pyridinyl) methyl] -N-nitro-2-imidazolidinimine.