Nothing Special   »   [go: up one dir, main page]

CS228525B2 - Herbicide and a method for the production its effective agents - Google Patents

Herbicide and a method for the production its effective agents Download PDF

Info

Publication number
CS228525B2
CS228525B2 CS818553A CS855381A CS228525B2 CS 228525 B2 CS228525 B2 CS 228525B2 CS 818553 A CS818553 A CS 818553A CS 855381 A CS855381 A CS 855381A CS 228525 B2 CS228525 B2 CS 228525B2
Authority
CS
Czechoslovakia
Prior art keywords
fluorine
hydrogen
atom
nicotinamide
chlorine
Prior art date
Application number
CS818553A
Other languages
Czech (cs)
English (en)
Inventor
Michael C Cramp
James Gilmour
Edgar W Parnell
Original Assignee
May & Baker Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by May & Baker Ltd filed Critical May & Baker Ltd
Priority to CS811294A priority Critical patent/CS228549B2/cs
Publication of CS228525B2 publication Critical patent/CS228525B2/cs

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79Acids; Esters
    • C07D213/80Acids; Esters in position 3
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/81Amides; Imides
    • C07D213/82Amides; Imides in position 3
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00Sulfones; Sulfoxides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/83Thioacids; Thioesters; Thioamides; Thioimides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pyridine Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CS818553A 1980-11-21 1981-11-20 Herbicide and a method for the production its effective agents CS228525B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CS811294A CS228549B2 (cs) 1980-11-21 1983-02-28 Způsob výroby derivátů nikotinamidu

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB8037372 1980-11-21

Publications (1)

Publication Number Publication Date
CS228525B2 true CS228525B2 (en) 1984-05-14

Family

ID=10517468

Family Applications (1)

Application Number Title Priority Date Filing Date
CS818553A CS228525B2 (en) 1980-11-21 1981-11-20 Herbicide and a method for the production its effective agents

Country Status (34)

Country Link
US (1) US4618366A (es)
EP (1) EP0053011B1 (es)
JP (1) JPS57118568A (es)
KR (1) KR880001314B1 (es)
AR (1) AR229801A1 (es)
AT (1) ATE12491T1 (es)
AU (1) AU557053B2 (es)
BG (1) BG47942A3 (es)
BR (1) BR8107585A (es)
CA (1) CA1229612A (es)
CS (1) CS228525B2 (es)
DD (1) DD200969A5 (es)
DE (1) DE3169738D1 (es)
DK (1) DK171022B1 (es)
EG (1) EG15683A (es)
ES (3) ES8401468A1 (es)
GB (1) GB2087887B (es)
GR (1) GR77297B (es)
HU (1) HU188711B (es)
IE (1) IE52802B1 (es)
IL (1) IL64220A (es)
KE (1) KE3798A (es)
MA (1) MA19337A1 (es)
MY (1) MY8700515A (es)
NZ (1) NZ199006A (es)
OA (1) OA06956A (es)
PH (1) PH18472A (es)
PL (1) PL132171B1 (es)
PT (1) PT74020B (es)
RO (3) RO87038B (es)
SG (1) SG8688G (es)
SU (1) SU1356950A3 (es)
TR (1) TR22684A (es)
ZA (1) ZA818032B (es)

Families Citing this family (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4744819A (en) * 1984-10-23 1988-05-17 Daicel Chemical Industries Ltd. 4-oxo pyridinecarboxamide derivatives as plant growth regulators
US4725306A (en) * 1984-11-09 1988-02-16 Daicel Chemical Industries Ltd. Pyridinecarboxamide plant growth inhibitors
GR861640B (en) * 1985-07-02 1986-10-24 May & Baker Ltd Insecticide method by using diflufenican
BR8603423A (pt) * 1985-07-23 1987-03-04 May & Baker Ltd Processo para controlar o crescimento de ervas daninhas em um local de cultura de cereais;bem como produto e composicao herbicidas
US5264411A (en) * 1985-07-23 1993-11-23 May & Baker Limited Herbicidal method comprising the use of diflufenican
GB8526735D0 (en) * 1985-10-30 1985-12-04 May & Baker Ltd Compositions of matter
US4692185A (en) * 1986-01-13 1987-09-08 Stauffer Chemical Company N-(ortho-substituted) benzyl, 3-trifluoromethylphenoxy nicotinamides as herbicides
GB8617740D0 (en) * 1986-07-21 1986-08-28 May & Baker Ltd Compositions of matter
GB8617741D0 (en) * 1986-07-21 1986-08-28 May & Baker Ltd Compositions of matter
GB8630697D0 (en) * 1986-12-23 1987-02-04 May & Baker Ltd Compositions of matter
GB8630698D0 (en) * 1986-12-23 1987-02-04 May & Baker Ltd Compositions of matter
GB8630806D0 (en) * 1986-12-23 1987-02-04 May & Baker Ltd Compositions of matter
GB8710362D0 (en) * 1987-05-01 1987-06-03 Shell Int Research Anilide herbicides
GB8710585D0 (en) * 1987-05-05 1987-06-10 May & Baker Ltd Compositions of matter
GB8710584D0 (en) * 1987-05-05 1987-06-10 May & Baker Ltd Compositions of matter
US4861891A (en) * 1988-08-31 1989-08-29 Pfizer Inc. Antidepressant N-substituted nicotinamide compounds
FR2639185B1 (fr) * 1988-11-22 1991-01-25 Rhone Poulenc Agrochimie Produit herbicide, son utilisation et procede pour la lutte selective contre les mauvaises herbes dans les cultures de riz et de cereales
DE4021439A1 (de) * 1989-12-14 1991-06-20 Bayer Ag 2-iminopyridin-derivate
GB9005965D0 (en) * 1990-03-16 1990-05-09 Shell Int Research Herbicidal carboxamide derivatives
GB9025828D0 (en) * 1990-11-28 1991-01-09 Shell Int Research Herbicidal carboxamide derivatives
TR25135A (tr) * 1991-03-13 1992-11-01 Shell Int Research HERBISID ÖZELLIKTE KARBOKSAMID TüREVLERI
DE69627709T2 (de) * 1995-12-28 2004-02-26 Kureha Kagaku Kogyo K.K. N-(unsubstituierte oder substituierte)-4-substituierte-6-(unsubstituierte oder substituierte)phenoxy-2-pyridincarboxamide oder -thiocarboxamide, verfahren zu deren herstellung sowie herbizide
ATE256113T1 (de) 1996-03-21 2003-12-15 Lonza Ag Verfahren zur herstellung von arylamiden heteroaromatischer carbonsäuren
SK283920B6 (sk) 1996-03-28 2004-05-04 Lonza Ag Spôsob výroby arylamidov heteroaromatických karboxylových kyselín
US5900484A (en) 1996-09-18 1999-05-04 Lonza Ag Process for the preparation of arylamides of heteroaromatic carboxylic acids
SI0806415T1 (en) * 1996-05-09 2000-04-30 Lonza Ag Process for the preparation of arylamides of heteroaromatic carboxylic acids
CA2209392C (en) * 1996-07-23 2007-02-20 Yves Bessard Process for preparing pyridinecarboxylic esters
EP0971894A1 (en) * 1997-04-04 2000-01-19 Pfizer Products Inc. Nicotinamide derivatives
DE19854081A1 (de) * 1998-11-24 2000-05-25 Bayer Ag Substituierte N-Pyrazolyl-phenoxynicotinsäure-(thio)amide
DE19946852A1 (de) * 1999-09-30 2001-04-05 Bayer Ag Substituierte N-Phenyl-phenoxynicotinsäure-(thio)amide
KR100661081B1 (ko) * 2000-06-10 2006-12-26 동화약품공업주식회사 항바이러스제로 유용한 6-메틸니코틴아미드 유도체
CN1294121C (zh) * 2001-05-31 2007-01-10 日本农药株式会社 取代的酰基苯胺衍生物、其中间体、农业与园艺化学品及其用途
DE102004047927A1 (de) * 2004-10-01 2006-04-06 Bayer Cropscience Gmbh Wässrige Dispersionen enthaltend Diflufenican
AU2006200731B2 (en) 2005-03-31 2011-05-19 Sumitomo Chemical Company, Limited Emulsifiable concentrate
JP4862989B2 (ja) * 2006-03-09 2012-01-25 日産化学工業株式会社 除草剤組成物
EP2052606A1 (de) 2007-10-24 2009-04-29 Bayer CropScience AG Herbizid-Kombination
DE102008037620A1 (de) * 2008-08-14 2010-02-18 Bayer Crop Science Ag Herbizid-Kombination mit Dimethoxytriazinyl-substituierten Difluormethansulfonylaniliden
CN102203065B (zh) * 2008-10-29 2014-07-09 霍夫曼-拉罗奇有限公司 新的苯基酰胺或吡啶基酰胺衍生物和它们作为gpbar1激动剂的应用
MA34606B1 (fr) 2010-10-15 2013-10-02 Bayer Ip Gmbh Utilisation d'herbicides inhibiteurs d'als pour la lutte contre une vegetation non souhaitee chez des plantes beta vulgaris tolerentes aux herbicides inhibiteurs d'als
UA117447C2 (uk) 2011-05-04 2018-08-10 Байєр Інтеллектуал Проперті Гмбх Застосування гербіцидів інгібіторів als для боротьби з небажаною рослинністю на площі вирощування brassica
CN102318608A (zh) * 2011-07-06 2012-01-18 陕西美邦农药有限公司 一种含吡氟酰草胺与吡草醚的除草组合物
HUE039517T2 (hu) 2012-12-13 2019-01-28 Bayer Cropscience Ag ALS inhibitor herbicidek alkalmazása nemkívánatos növényzet irtására ALS inhibitor herbicidet toleráló beta vulgaris növényekben
WO2014117292A1 (zh) * 2013-01-31 2014-08-07 中国科学院上海药物研究所 酰胺类化合物及其制备方法、药物组合物和用途
CN103947666A (zh) * 2014-03-21 2014-07-30 江苏省农业科学院 一种含绿麦隆、丙草胺和吡氟酰草胺的农药组合物及其应用
CN104402814A (zh) * 2014-12-01 2015-03-11 南通嘉禾化工有限公司 一锅法合成2-氯-n-(2,4-二氟苯基)烟酰胺的方法
BR112017020100B1 (pt) * 2015-03-20 2022-05-03 Bayer Cropscience Aktiengesellschaft Composições herbicidas compreendendo isoxaflutol e diflufenican, e método para controlar uma ou mais ervas daninhas em uma ou mais plantações de plantas úteis
WO2016173964A1 (en) 2015-04-27 2016-11-03 Bayer Cropscience Aktiengesellschaft Use of certain herbicide combinations in tuberous root crop plants
WO2016173972A1 (en) 2015-04-27 2016-11-03 Bayer Cropscience Aktiengesellschaft Use of certain herbicide combinations in tuberous root crop plants
PT108561B (pt) 2015-06-16 2017-07-20 Sapec Agro S A Mistura herbicida
EP3364760B1 (en) 2015-10-22 2021-12-01 Adama Agan Ltd. Use of a mixture of herbicides on potatoes
JP2021530478A (ja) * 2018-07-09 2021-11-11 リーバー インスティチュート インコーポレイテッドLieber Institute, Inc. NaV1.8を阻害するためのピリジンカルボキシアミド化合物
IL303203A (en) 2020-12-01 2023-07-01 Bayer Ag The compositions containing mesosulfuron-methyl and TEHP
WO2022117515A1 (en) 2020-12-01 2022-06-09 Bayer Aktiengesellschaft Compositions comprising iodosulfuron-methyl and tehp
CN113666868A (zh) * 2021-08-11 2021-11-19 池州飞昊达化工有限公司 一种氟吡啶酰胺衍生物及其合成方法
GB2611348A (en) * 2021-10-01 2023-04-05 Rotam Agrochem Int Co Ltd A crystalline form of diflufenican, a process for its preparation and use of the same
CN118201483A (zh) 2021-10-15 2024-06-14 科沃施种子欧洲股份两合公司 ALS抑制剂除草剂耐受的甜菜(Beta Vulgaris)突变体
WO2024023035A1 (en) 2022-07-25 2024-02-01 Syngenta Crop Protection Ag Herbicidal compositions
WO2024083834A1 (en) * 2022-10-18 2024-04-25 Upl Mauritius Limited A method of controlling weeds

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2197872A1 (en) * 1972-09-04 1974-03-29 Dynachim Sarl 2-Phenoxy nicotinic esters and amides - prepd. by reaction of nicotinic acid anhydride or halide with an alcohol or amine
GB1550574A (en) * 1977-12-12 1979-08-15 Ciba Geigy Ag Pyridyloxy-phenoxy-propionic acid derivatives which are effective as herbicides and as agents regulating plant growth
US4327218A (en) * 1979-10-01 1982-04-27 Stauffer Chemical Company N-Aryl, 2-phenoxy nicotinamide compounds and the herbicidal use thereof
US4270946A (en) * 1979-10-01 1981-06-02 Stauffer Chemical Company N-Aryl,2-phenoxy nicotinamide compounds and the herbicidal use thereof

Also Published As

Publication number Publication date
GB2087887A (en) 1982-06-03
OA06956A (fr) 1983-07-31
SG8688G (en) 1988-07-01
US4618366A (en) 1986-10-21
AR229801A1 (es) 1983-11-30
PT74020B (fr) 1986-06-02
DK513481A (da) 1982-05-22
TR22684A (tr) 1988-03-03
HU188711B (en) 1986-05-28
DE3169738D1 (en) 1985-05-09
PT74020A (fr) 1981-12-01
EP0053011B1 (en) 1985-04-03
RO87038A (ro) 1985-05-20
MY8700515A (en) 1987-12-31
RO83101A (ro) 1984-02-21
RO87037B (ro) 1985-05-31
ES515995A0 (es) 1983-11-01
JPS57118568A (en) 1982-07-23
IE52802B1 (en) 1988-03-16
DD200969A5 (de) 1983-06-29
IL64220A (en) 1985-06-30
ES8407025A1 (es) 1984-09-01
JPS6126994B2 (es) 1986-06-23
ZA818032B (en) 1982-10-27
RO87038B (ro) 1985-05-31
ES507332A0 (es) 1983-07-16
SU1356950A3 (ru) 1987-11-30
KR830006907A (ko) 1983-10-12
IE812713L (en) 1982-05-21
DK171022B1 (da) 1996-04-22
PL132171B1 (en) 1985-02-28
RO83101B (ro) 1984-02-28
PH18472A (en) 1985-07-18
GB2087887B (en) 1984-11-14
AU557053B2 (en) 1986-12-04
ATE12491T1 (de) 1985-04-15
GR77297B (es) 1984-09-11
AU7763281A (en) 1982-05-27
NZ199006A (en) 1985-07-31
PL233901A1 (en) 1983-02-14
KR880001314B1 (ko) 1988-07-23
ES520104A0 (es) 1984-09-01
KE3798A (en) 1988-04-29
BG47942A3 (en) 1990-10-15
CA1229612A (en) 1987-11-24
EP0053011A1 (en) 1982-06-02
RO87037A (ro) 1985-05-20
EG15683A (en) 1993-07-30
ES8400737A1 (es) 1983-11-01
IL64220A0 (en) 1982-02-28
ES8401468A1 (es) 1983-07-16
MA19337A1 (fr) 1982-07-01
BR8107585A (pt) 1982-08-17

Similar Documents

Publication Publication Date Title
CS228525B2 (en) Herbicide and a method for the production its effective agents
EP0083613B1 (en) N-phenylpyrazole derivatives useful as herbicides
RU2037486C1 (ru) Производные карбоксамида, гербицидная композиция и способ борьбы с нежелательными растениями
US5104443A (en) Heterocyclic 2-alkoxyphenoxysulfonylureas and the use thereof as herbicides or plant growth regulators
US4816064A (en) Triazine derivatives, herbicidal composition containing them, and method of controlling growth of undesired vegetation by using same
KR850000993B1 (ko) N-페닐피라졸 유도체의 제조방법
DK156573B (da) 2-(2-fluor-4-halogen-5-substitueret-phenyl)-hydantoinderivater, et herbicidt praeparat indeholdende disse, en fremgangsmaade til bekaempelse af ukrudt under anvendelse af disse samt anvendelse af disse som herbicid
GB2136427A (en) Herbicidal N-pyridylpyrazole Derivatives
KR20040019099A (ko) 피리딘 화합물의 제조 방법
US4496390A (en) N-Phenylpyrazole derivatives
EP0493925B1 (en) Pyrazole derivatives having herbicidal activity, their preparation and their use
US4505740A (en) Herbicidal 5-amino-4-cyano-1-phenyl-pyrazoles
US5102443A (en) Heterocyclically substituted phenoxysulfonylureas, and the use thereof as herbicides or plant growth regulators
JPH0818931B2 (ja) ジフルフエニカンを用いる雑草防除方法
JPH06228135A (ja) イミダゾリニル−ピリダジン類
US4391629A (en) 2-Pyridyloxyacetanilides and their use as herbicides
US4722749A (en) Pyridinesulfonamides and their use as herbicidal agents
EP3475273B1 (de) 3-amino-1,2,4-triazinderivate und deren verwendung zur bekämpfung unerwünschten pflanzenwachstums
GB2205101A (en) Oxadiazole derivatives useful as herbicides
US4846881A (en) 3,4,6-trisubstituted 1,2,4-triazin-5(4H)-one herbicides
US4552586A (en) Certain 2-pyridyloxyacetanilides and their use as herbicides
CS237333B2 (en) Herbicide agent
EP0397295A2 (de) 2-Phenyl-perhydro-isoindol-1-one und -1-thione, Verfahren zu ihrer Herstellung und ihre Verwendung als Mittel mit herbizider Wirkung