CN201609628U - Gas dewatering device - Google Patents
Gas dewatering device Download PDFInfo
- Publication number
- CN201609628U CN201609628U CN2009201172550U CN200920117255U CN201609628U CN 201609628 U CN201609628 U CN 201609628U CN 2009201172550 U CN2009201172550 U CN 2009201172550U CN 200920117255 U CN200920117255 U CN 200920117255U CN 201609628 U CN201609628 U CN 201609628U
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- Prior art keywords
- pipe
- nafion
- gas
- air pump
- instrument
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- 229920000557 Nafion® Polymers 0.000 claims abstract description 41
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 238000005070 sampling Methods 0.000 abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
- 238000012544 monitoring process Methods 0.000 abstract description 4
- 238000004868 gas analysis Methods 0.000 abstract description 3
- 230000003204 osmotic effect Effects 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 58
- 238000000034 method Methods 0.000 description 9
- 238000001914 filtration Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 5
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000010926 purge Methods 0.000 description 4
- 108090000862 Ion Channels Proteins 0.000 description 3
- 102000004310 Ion Channels Human genes 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 125000000542 sulfonic acid group Chemical group 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000002352 surface water Substances 0.000 description 2
- 238000012952 Resampling Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000000738 capillary electrophoresis-mass spectrometry Methods 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000004807 localization Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920002338 polyhydroxyethylmethacrylate Polymers 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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Abstract
The utility model discloses a water removing device and particularly relates to a device for removing water through osmotic pressure on both sides of a Nafion pipe. The water removing device is characterized in that the device comprises a gas sampling pipe, an air pump, a Nafion pipe, an instrument air generator and the like, wherein a heater is installed on the pipe wall of the gas sampling pipe, the gas sampling pipe is connected with the air pump, the air pump is connected with an inner pipe of the Nafion pipe, the instrument air generator is connected with an outer pipe of the Nafion pipe, and a two-stage millipore filter is additionally arranged in the front of the air pump. The device has the advantages of low cost, high dewatering performance, small volume and the like, can be widely applied to various industries such as atmospheric environment monitoring, online pollution source monitoring, various gas analysis, quick emergency command vehicles and the like.
Description
Technical field
The utility model relates to a kind of de-watering apparatus, specifically is meant a kind of device that dewaters by the osmotic pressure of Nafion pipe both sides.
Technical background
The gas sampling system is the parts of most critical in stationary source smoke on-line monitoring system, atmosphere environment supervision system, the gas analyzer.Sample gas contains moisture content and can cause analyzing the inaccurate of data even cause analytical instrument mortality to damage.As: in the infrared analysis field, it is inaccurate that the moisture content in the sample gas can disturb the infrared analysis result to cause analyzing data.In analyzing water-soluble, corrosive gas, moisture content can make analytical instrument be corroded to cause analytical instrument mortality to damage.
Gas sampling both domestic and external system is to the main methods such as electronic cooling, compressor cooling, drier that adopt in the processing procedure of sample gas.Electronic cooling and compression mechanism cold process all are to use reduction sample gas dew-point temperature to make it reach the purpose of sample air dry.The in use common problem of electronic cooling and compression mechanism cold process is: 1, pipeline and instrument are silted up by water or particulate; 2, the loss of water-soluble analytes; 3, analyzer is corroded by acid mist; 4, can cause pipeline blockage because freeze in order to reach the desirable too low dew-point temperature of water removal effect.Drier dewaters and can't be used for corrosive gas analysis and often maintenance of needs.
Along with the pay attention to day by day of country to environmental protection work, the precision of all gases analysis improves constantly, and the requirement of gas sampling system is also being improved constantly.The dewater problem brought of electronic cooling or compression mechanism cold process will influence the development that China's gas detects industry.
The utility model content
The utility model is at deficiency of the prior art, proposed a kind of handled easily, respond well de-watering apparatus.
The utility model is achieved by following technical proposals:
A kind of gas de-watering apparatus, it comprises: gas sampler, air pump, Nafion pipe, instrument air generator, the tube wall that it is characterized in that gas sampler is equipped with heater, the Nafion pipe is polytetrafluoroethylene (PTFE) and fluoro-3, the polymeric membrane pipe that the copolymer of 6-diepoxy-4-methyl-7-decene-sulfuric acid is composited, gas sampler is connected with air pump, and air pump is connected with the interior pipe of Nafion pipe, and the instrument air generator is connected with the outer tube of Nafion pipe.
As preferably, above-mentioned a kind of gas de-watering apparatus after described sample gas comes out from gas sampler, filters through 1～5um millipore filter with through the millipore filter of 0.1～0.2um, enters into air pump again.
As preferably, above-mentioned a kind of gas de-watering apparatus, described Nafion pipe is made up by many pipes, is fixed into cellularly with fluorubber, and it is encapsulated in the stainless steel 316L pipe, forms a Nafion pipe group.
In the utility model, after sample gas entered the Nafion pipe from import, because the Nafion pipe contains sulfonic acid group, Nafion had extremely strong seepage of water.By sulfonic acid group, on the Nafion tube wall, formed a crosslinked ion channel, water promptly is transferred to the another side of tube wall, evaporation then by ion channel after tube wall surface absorbs through sulfonic group.Dry instrument wind is taken away steam endlessly by the instrument wind inlet, reaches the sample gas dry purpose that dewaters.This pipe only plays suction-operated to hydroxyl, and a sulfonic acid group can be accepted 13 hydrones.Therefore under the purging of the instrument wind of certain aridity, the gas dew point temperature can be reached-27 ℃--40 ℃.
The gas sampling technical scheme has two parts.The one, sampling section, main gas sampler; The sample gas that air pump is collected filters the bigger particle of volume in the sample gas by thicker filter, filters volume smaller particles thing in the sample gas by thinner filter again, in order to avoid influence the moisture removal property of Nafion pipe.Sample gas after filtering is heated to 100 ℃, enters the Nafion pipe with the flow velocity of 4L/min.The Nafion tube-surface is swept in the instrument wind of the drying that produces with the instrument air generator, takes away steam.The Nafion pipe is divided into sample gas inlet part and sample gas exit portion, and sample gas inlet part is heated to 50 ℃, and the Nafion pipe is taken away steam fast, but can't fully remove the moisture content in the sample gas.Sample gas exit portion is cooled to 20 ℃, moisture content residual in the sample gas can be removed.The 2nd, instrument air generator, instrument air generator provide and purge the dry instrument wind of Nafion pipe, make in the Nafion pipe, outer to form the aqueous vapor partial pressure gradient poor for pipe, reach the Nafion pipe endlessly to the purpose of the outer conveying of pipe moisture content.The instrument air generator adopts the mole sieve drier of heatless regeneration formula, and the mole sieve drier technology of heatless regeneration formula can reach-70 ℃ of dew points interior very ripe, cheap at present, but needs often to safeguard.In order to reduce maintenance, with air filtration, oil removing dewaters before instrument air generator inlet.Filter in the outlet of instrument air generator.Substantially can reach the 3-4 Maintenance free.
Beneficial effect: the utility model can be used for atmosphere environment supervision, in line source monitoring, all gases analysis, industry such as Emergency Command Vehicle fast.The gas sampling system of alternative external costliness is used for CEMS, satisfies the standard of GB/T76 fully.Because its cost is low, the moisture removal property height, characteristics such as volume is little are for technical development, the localization process of industries such as gas analysis in future, environmental protection have been accelerated speed.
Figure of description
Fig. 1 de-watering apparatus assembly structure schematic diagram
1, gas sampler 2,1～5um millipore filter 3,0.1～0.2um millipore filter 4, air pump 5, Nafion pipe 6, instrument air generator 7, heater
The specific embodiment
Below in conjunction with accompanying drawing, enforcement of the present utility model is specified:
Embodiment one
According to structure shown in Figure 1, sample gas is heated to 120 ℃ by gas sampler 1 by the heater 7 of tube wall, makes moisture content in the gas phenomenon of dewfall not occur on the one hand, and protective gas sampling pipe 1 is not corroded on the other hand.Sample gas enters resampling filter heater 7 with the flow velocity of per minute 1L after by gas sampler 1 and is heated to 120 ℃, and the moisture content in the gas is further evaporated, and filters bulky grain thing in the sample gas.
The sample gas that has 120 ℃ is respectively 5um millipore filter 2 and 0.1um millipore filter 3 by filtering accuracy.Filter adopts polytetrafluoroethylmaterial material to make, and filter core adopts macromolecule PE material to make, and has high temperature resistant, corrosion resistant characteristics.Drop in 80 ℃ by the sample temperature degree behind the double-filtration, satisfy the operating temperature of air pump 4.
It is cellular that Nafion pipe 5 adopts 50 Nafion to divide the effective fluorubber of proton exchange to be fixed into, and purpose is the dry amount that adds full-page proof gas.Shell and inlet, outlet adopt stainless steel 316L fine finishining moulding, sealing and fixing.Nafion manages 5 intake sections and is operated in heated condition, is heated to 90 ℃, and exit portion is operated in the normal temperature state.Air pump 4 is managed 5 sample gas inlet with the pretreated sample gas of sampler from Nafion and is entered in the pipe.Moisture content in the sample gas transmits hydrone because Nafion pipe 5 interior Nafion divide the inside pipe wall of proton exchange pipe to deposit the moist gradient difference and begin with the pipe outer wall to the pipe outer wall.Because intake section is operated in heated condition, the transmission speed of hydrone is than very fast, but dew-point temperature is low inadequately.When the sample gas of removing part moisture content enters the latter half of Nafion pipe 5,, the moisture content of not removing in the sample gas is further got rid of because work at normal temperatures.
In Nation pipe 5, ion channel extends to outer surface by the inner surface of pipe.Hydrone at first combines with sulfonic group on the inner surface, the hydrone of the sulfonic group combination of tube wall depths less (supposing that the pressure of outer surface water vapour is lower than the pressure of inner surface water vapour), therefore hydrone there is stronger attraction, the hydrone of pipe internal surface will pass through sulfonic group very soon, arrive the outer surface of tube wall, be dispersed in the environment, realize to wet sample aerocolloidal go molten.The sweep gas (normally air) that the moisture of being discharged by Nafion pipe 5 is dried is taken system out of, and then the inside and outside barometric gradient that exists of tube wall can guarantee that molten process continues to carry out.
In the formula: V
PBe the dry gas flow velocity;
V
SBe the sample gas velocity;
P
SBe the sample atmospheric pressure;
P
VBe dry gas pressure.
The dew point of instrument air generator 6 generation per minute 4L makes the inside and outside barometric gradient that exists of tube wall for-70 ℃ dry gas purging Nafion manages 5 outer tube walls, and the aqueous vapor that evaporates is taken away.Instrument wind enters from the instrument wind inlet of Nafion pipe 5, purges Nafion with stable flow velocity and manages 5 outer tube walls, enters the atmosphere from the outlet of instrument wind again, sees accompanying drawing 2.
According to test, when sample temperature degree is 25 ℃, can reach-45 ℃ dew point, so water removal effect is very desirable.
Claims (2)
1. gas de-watering apparatus, it comprises: gas sampler (1), air pump (4), Nafion manage (5), instrument air generator (6), the tube wall that it is characterized in that gas sampler (1) is equipped with heater (7), gas sampler (1) is connected with air pump (4), air pump (4) is connected with the interior pipe of Nafion pipe (5), and instrument air generator (6) is connected with the outer tube of Nafion pipe (5).
2. a kind of gas de-watering apparatus according to claim 1 is characterized in that described Nafion pipe (5) is made up by many pipes, is fixed into cellularly with fluorubber, and it is encapsulated in the stainless steel 316L pipe, forms a Nafion pipe group.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009201172550U CN201609628U (en) | 2009-04-09 | 2009-04-09 | Gas dewatering device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009201172550U CN201609628U (en) | 2009-04-09 | 2009-04-09 | Gas dewatering device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN201609628U true CN201609628U (en) | 2010-10-20 |
Family
ID=42960259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009201172550U Expired - Fee Related CN201609628U (en) | 2009-04-09 | 2009-04-09 | Gas dewatering device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN201609628U (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102553404A (en) * | 2012-02-10 | 2012-07-11 | 深圳市赛宝伦计算机技术有限公司 | Drying device and on-line monitoring instrument |
| CN104634900A (en) * | 2015-01-08 | 2015-05-20 | 聚光科技(杭州)股份有限公司 | Fixed pollution source emission monitoring system and fixed pollution source emission monitoring method |
| CN106596868A (en) * | 2017-01-21 | 2017-04-26 | 江苏旭龙环境科技有限公司 | Deoiling and anti-clogging VOCs online monitoring apparatus |
| CN106770979A (en) * | 2017-01-21 | 2017-05-31 | 江苏旭龙环境科技有限公司 | The anti-blocking VOCs on-Line Monitor Devices of one kind water removal |
| CN106770977A (en) * | 2017-01-21 | 2017-05-31 | 江苏旭龙环境科技有限公司 | A kind of oil removing removes water anti-blocking VOCs on-Line Monitor Devices |
| CN109060466A (en) * | 2018-10-30 | 2018-12-21 | 中国气象局气象探测中心 | Sample gas processing method and device for greenhouse gases background online observation |
| CN110595859A (en) * | 2019-10-29 | 2019-12-20 | 长沙开元弘盛科技有限公司 | Water removal method, analyzer and water removal device thereof |
| CN110631970A (en) * | 2019-09-16 | 2019-12-31 | 合肥福瞳光电科技有限公司 | Dynamic heating system and atmosphere ultrafine particle detector |
-
2009
- 2009-04-09 CN CN2009201172550U patent/CN201609628U/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102553404A (en) * | 2012-02-10 | 2012-07-11 | 深圳市赛宝伦计算机技术有限公司 | Drying device and on-line monitoring instrument |
| CN102553404B (en) * | 2012-02-10 | 2014-06-25 | 深圳市赛宝伦计算机技术有限公司 | Drying device and on-line monitoring instrument |
| CN104634900A (en) * | 2015-01-08 | 2015-05-20 | 聚光科技(杭州)股份有限公司 | Fixed pollution source emission monitoring system and fixed pollution source emission monitoring method |
| CN106596868A (en) * | 2017-01-21 | 2017-04-26 | 江苏旭龙环境科技有限公司 | Deoiling and anti-clogging VOCs online monitoring apparatus |
| CN106770979A (en) * | 2017-01-21 | 2017-05-31 | 江苏旭龙环境科技有限公司 | The anti-blocking VOCs on-Line Monitor Devices of one kind water removal |
| CN106770977A (en) * | 2017-01-21 | 2017-05-31 | 江苏旭龙环境科技有限公司 | A kind of oil removing removes water anti-blocking VOCs on-Line Monitor Devices |
| CN109060466A (en) * | 2018-10-30 | 2018-12-21 | 中国气象局气象探测中心 | Sample gas processing method and device for greenhouse gases background online observation |
| CN110631970A (en) * | 2019-09-16 | 2019-12-31 | 合肥福瞳光电科技有限公司 | Dynamic heating system and atmosphere ultrafine particle detector |
| CN110595859A (en) * | 2019-10-29 | 2019-12-20 | 长沙开元弘盛科技有限公司 | Water removal method, analyzer and water removal device thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: HANGZHOU FUMING ENVIRONMENTAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: CHEN MING Effective date: 20110513 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 310053 BUILDING 6 (HIGH-TECH. SOFTWARE PARK), NO. 1, WEIYE ROAD, BINJIANG DISTRICT, HANGZHOU CITY, ZHEJIANG PROVINCE TO: 310053 BUILDING 6 (HANGZHOU HIGH-TECH. SOFTWARE PARK), NO. 1, WEIYE ROAD, BINJIANG DISTRICT, HANGZHOU CITY, ZHEJIANG PROVINCE |
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| TR01 | Transfer of patent right |
Effective date of registration: 20110513 Address after: 310053 building, No. 1, Albert Road, Hangzhou, Zhejiang, Binjiang District (Hangzhou hi tech software park), 6 Patentee after: Hangzhou Fuming Environment Technology Co., Ltd. Address before: 310053, building 1, 6, Albert Road, Hangzhou, Zhejiang, Binjiang District (high tech software park) Patentee before: Chen Ming |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of utility model: Gas water removal device Effective date of registration: 20140321 Granted publication date: 20101020 Pledgee: CITIC Bank, Limited by Share Ltd, Hangzhou, Xiaoshan branch Pledgor: Hangzhou Fuming Environment Technology Co., Ltd. Registration number: 2014330000008 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20101020 Termination date: 20180409 |
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| CF01 | Termination of patent right due to non-payment of annual fee |