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CN207845196U - A kind of desulfurization wastewater low-temperature evaporation concentration systems - Google Patents

A kind of desulfurization wastewater low-temperature evaporation concentration systems Download PDF

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CN207845196U
CN207845196U CN201721168987.3U CN201721168987U CN207845196U CN 207845196 U CN207845196 U CN 207845196U CN 201721168987 U CN201721168987 U CN 201721168987U CN 207845196 U CN207845196 U CN 207845196U
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steam
waste water
flash
desulfurization wastewater
compressor
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曲恒
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Union Rui Sheng (beijing) Technology Co Ltd
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Union Rui Sheng (beijing) Technology Co Ltd
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Abstract

A kind of desulfurization wastewater low-temperature evaporation concentration systems, including waste water heating system, waste water flash distillation process system, flash-off steam aspirate compressibility;After desulfurization wastewater waste water flowing heating system is heated, the spray flash distillation mechanism into waste water flash distillation process system is flashed;The flash-off steam piping connection flash-off steam of waste water flash distillation process system aspirates compressibility;For the steam flashed off after flash-off steam suction compressibility compression heating, the heat source as waste water heating system is connected to waste water heating system;The desulfurization wastewater circulation line of waste water flash distillation process system connects flue penetrating vapo(u)rization system by concentrating water delivery pipe;Heating and low-flash decrement are carried out to desulfurization wastewater, it concentrates waste water and sprays into flue evaporation, steam in waste water is discharged into air with flue gas, salts substances are captured by deduster in waste water, realize the zero-emission of desulfurization wastewater, the safety of electric precipitator operation is improved, while having recycled the salt-free water flashed off.

Description

A kind of desulfurization wastewater low-temperature evaporation concentration systems
Technical field
The utility model belongs to water treatment field, is related to a kind of low-flash evaporation and concentration system of desulfurization (or saliferous) waste water System.
Background technology
In order to reach requirement of the country to SO2 minimum discharges, domestic power plant or other coal combustion equipments mostly use greatly lime stone- Gypsum wet flue gas desulfurizing technology, the technology produce serious discharge of wastewater while high-efficiency desulfurization.In April, 2015, state The publication of business institute《Water pollution action plan》The prevention dynamics to all kinds of water pollutions is enhanced, desulfurization wastewater (is contained due to complicated component Suspended matter, fluoride, heavy metal and salinity etc.), emission hazard receive highest attention in the industry greatly.
Currently, technique (traditional three header methods) removal desulfurization wastewater that desulfurization wastewater processing mostly uses greatly chemical precipitation is dirty Object is contaminated, but this method operating cost is high, limited to the removal of heavy metal ions rate such as the soluble organic fractions such as villaumite and selenium, water outlet is outstanding Floating particles object and COD etc. also tend to be unable to stably reaching standard discharge, be easy to cause secondary pollution.
In order to realize that the zero-emission of desulfurization wastewater, flue evaporation technique are suggested and are gradually paid attention to.The technology will take off The atomization of sulphur waste water is given up saliferous using boiler tail thermal flue gas to spray into the flue between air preheater and electric precipitator after drop Water is evaporated, and the fine solid particle object of generation is captured by electric precipitator, and key is to efficiently use boiler exhaust gas waste heat by waste water Drop evaporating completely in a short time.
For the higher unit of exhaust gas temperature, boiler exhaust gas waste heat is generally all enough in the short time under rated load Inside it is evaporated desulfurization wastewater drop.
However, recent year fired power generating unit or other coal combustion equipments, are generally chronically at underrun state, load Reduction often lead to the decline of exhaust gas temperature, the shortage of heat contained by the flue gas to be evaporated desulfurization wastewater in a short time When, drop will be attached to stack inner surface or enter electric precipitator, and corrosion and equipment fault, desulfurization wastewater flue is easily caused to be steamed Hair technology will be unable to come into operation.
At present to realize Wastewater Pretreatment decrement, using the MED multiple-effect evaporations of high parameter steam, need additionally to consume unit High parameter steam.Also falling film evaporator is easy fouling and blocking.The country also has using membrane technology, first by desulfurization wastewater mistake Filter decrement is then sprayed into flue evaporation.Since wastewater flow rate reduces, required evaporation heat is reduced, and evaporation effect greatly improves.But It is that the operating cost that membrane technology filters decrement method is relatively high, operational safety stability is insufficient.
Utility model content
To solve the above problems, the technical solution adopted in the utility model is as described below.
A kind of desulfurization wastewater low-temperature evaporation concentration systems, including waste water heating system, waste water flash distillation process system, flash distillation steaming Vapour aspirates compressibility;It is characterized in that:The desulfurization wastewater efferent duct of desulfurizer connects waste water flash distillation process system;Waste water dodges It steams processing system and connects waste water heating system;After desulfurization wastewater waste water flowing heating system is heated, into waste water flash distillation process The spray flash distillation mechanism of system is flashed;The flash-off steam piping connection flash-off steam suction compression of waste water flash distillation process system System;The steam flashed off is after flash-off steam suction compressibility compression heating, the heat source as waste water heating system It is connected to waste water heating system;Flash-off steam condenses into water after waste water heating system and realizes condensate-water polishing;Waste water flashes The desulfurization wastewater circulation line of processing system connects flue penetrating vapo(u)rization system by concentrating water delivery pipe, arrives certain density dense Contracting waste water sprays into flue evaporation.
Further, waste water heating system includes heated type condenser, heated type condenser water system, heated type condensing Device pumped vacuum systems, heated type Steam Side of Condenser and condensate draining system;At heated type condenser water system access waste water flash distillation The desulfurization wastewater circulation line of reason system, heated type Steam Side of Condenser are connected with waste water heat source system steam drain;Heating Formula condenser shell-side is the steam from waste water heat source system, and pipe side is desulfurization wastewater, and heating steam is condensed into water and returns It receives.
Further, waste water flash distillation process system includes flash tank, flashed steam cycle system;Flash tank top is that spray flashes Mechanism, bottom are equipped with sink, are connected by desulfurization wastewater circulation line;Flash tank side is steam (vapor) outlet, and outlet is equipped with drop Separator;Waste water sprays into flash tank with misty or drop state, is evaporated, cools down during stagnant sky, is not flashed part and falls Enter bottom sink;The desulfurization wastewater concentrated in the sink of bottom is entered waste water heating system and is heated up after filtration treatment, using useless Water-circulating pump is re-delivered to flash tank top spray flash distillation mechanism.
Further, flash-off steam aspirates compressibility, including wind turbine or compressor, steam absorbing tube road and exhaust line;Wind Machine or compressor connect flash tank steam (vapor) outlet, wind turbine or compressor through exhaust line connection waste water heating system through steam absorbing tube road System.
Further, the wind turbine or compressor of flash tank steam (vapor) outlet connection flash-off steam suction compressibility, flash tank Vacuum established by wind turbine or compressor.
Further, the inside of flash tank is designed to a pressure chamber or multiple and different pressure chambers;Water intake mode is designed as Single layer sprays or Multi-layer sprinkling.
Further, the mode of spray selects to use high pressure nozzle, low-pressure nozzle, gas-liquid two-phase flow nozzle or water drenching dish type Formula.
Further, arrangement of nozzles is in the top of tank body, waist and/or middle and lower part;The direction of ejection using upwards, to Under, centripetal spray and/or radial spray mode.
Further, flash-off steam aspirates compressibility, including a Fans or compressor or more serial or parallel connection wind Machine or compressor;Wind turbine or compressor suction port connect flash distillation plant, and wind turbine or compressor are by electric drive or other machinery side Formula drives;The flash-off steam of wind turbine or compressor suction from flash tank is sent to heated type condenser shell after compression heating step by step Side, the heat source as heated waste water.
Further, flue sprays into vapo(u)rization system atomizer and is installed on the top flue between air preheater and electric precipitator Nei Portion is disposed adjacent to a side flue of air preheater.
Compared with existing hot swapping, the utility model non-scaling does not block, will not cause secondary pollution.
Compared with existing membrane technology filters decrement method, the utility model does not block, with the work(for preheating concentration waste water Can, underload adapts to new stronger.And this method operating cost is also very low.
Description of the drawings
Fig. 1 is the structural schematic diagram of desulfurization wastewater low-temperature evaporation concentration systems;
Wherein 1 flash tank, 2 wind turbines or compressor, 3 filter devices, 4 waste water circulating pumps, 5 heated type condensers;
Specific implementation mode
Below in conjunction with the accompanying drawings 1, the technical solution of the utility model is described in detail.
Desulfurization wastewater low-temperature evaporation concentration systems are taken out including waste water heating system, waste water flash distillation process system, steam Suction pressure compression system.Its basic principle is:50~70 DEG C first are heated in the waste water heating system by desulfurization wastewater outside flash tank, (low-temperature evaporation) decrement is flashed again, is reached certain density concentration waste water and is sprayed into flue evaporation, vapor is discharged with flue gas, The fine solid particle object of generation is captured by electric precipitator.
By heating desulfurization wastewater, waste water flash distillation is not only improved, meanwhile, heat is transmitted into waste water, its temperature is made to be promoted; By flash distillation, the part water in desulfurization wastewater becomes steam, and wastewater flow rate reduces.Discharge reduction and heating, this two measures Effect can all make desulfurization wastewater spray into flue evaporation institute calorific requirement and reduce, and evaporation effect greatly improves after spraying into flue, especially It is in the case of performing low-load running of machine set.
In addition, desulfurization wastewater low-temperature evaporation concentration systems additionally provide the recycling to flash-off steam and water simultaneously.It is de- Sulphur waste water efferent duct connects flash tank lower part sink, and the waste water come from desulfurizer sequentially enters sink, waste water heating system;It is de- Sulphur waste water enters waste water flash distillation process system top spray flash distillation mechanism after being heated outside flash tank is flashed (low temperature steaming Hair);Flash-off steam enters steam suction compressibility;The outlet of steam suction compressibility is connected to waste water heating system, passes through Waste water heating and steam cooling condensation are realized in heat exchange;Can also have been recycled in waste water heating system flash off it is salt-free Water.
Waste water heating system includes that desulfurization wastewater access system, heated type condenser water system, adds heated type condenser Hot type evacuation system for steam condenser, heated type Steam Side of Condenser and condensate draining system, pipeline valve etc..Steam is heated from useless Water heat source system.Heated type condenser is connected with the increasing steam turbine steam drain of waste water heat source system.Heated type condensing Device shell-side is the steam from waste water heat source system, and pipe side is desulfurization wastewater.Waste water heating system of the waste water outside flash tank In system 50~70 DEG C are heated to by low-temperature heat source.The controlled temperature of tank external heat, slows down Ca, Mg ion releasing, and tank body is not easy Fouling;It heats steam simultaneously and is condensed into water in heated type condenser and recycle.
Waste water flash distillation process system includes flash tank, flashed steam cycle system;Flash tank top is spray flash distillation mechanism, bottom Equipped with sink.Side is equipped with steam (vapor) outlet, and steam outlet is equipped with entrainment trap.Waste water is sprayed into misty or drop state Flash tank, and be evaporated, cool down within the hang time, it is not flashed part and falls into bottom sink.Then it through filter device, goes forward side by side Enter the heating of waste water heating system, it is spray flash distillation mechanism to get to flash tank top again using waste water circulating pump.Thus it recycles Back and forth (different and different according to required concentration ratio).The pressure of flash tank is located at 10~20kpa.Whole system is designed to low temperature Flash distillation, not dosing are not consumed energy, and non-scaling does not block, and do not generate secondary pollution, and constantly cycle flashes desulfurization wastewater, meanwhile, Low concentration wastewater, which is constantly supplemented in, to be come, and is concentrated to a degree of waste water and is transported to flue penetrating system.The steaming of flash tank Vapor outlet is equipped with entrainment trap.
The inside of flash tank can be designed to a pressure chamber, can also be designed to 2~5 different pressures chambers.Water inlet side Formula can be designed as single layer spray, 2~5 layers of Multi-layer sprinkling be may be set to be, to increase the hang time of water droplet.
The mode of spray can also select, and carry out different designs according to the property of waste water, high pressure nozzle, low pressure may be used Nozzle, gas-liquid two-phase flow nozzle, the structure types such as no nozzle (water spraying tray).The size of drop can also be different.When using nozzle, The top of tank body, waist, middle and lower part can be arranged in.The direction of ejection can also up, down, centripetal spray, radial to spray Deng.
The shape of flash tank can be cylindrical, trapezoidal, taper or combination thereof form.Flash tank length-width ratio can be Thick fat type can also be thin and tall type.
Flash tank in waste water flash distillation process system, either single tank, can also be multiple tanks.The size of flash tank Either it is identical, can also be different.
The steam (vapor) outlet connection steam of flash tank aspirates compressibility, including one or more serial or parallel connection wind turbine or pressure Contracting machine, pipeline valve etc.;The steam (vapor) outlet of wind turbine or compressor suction port connection flash distillation plant, wind turbine or compressor outlet connection Heated type condenser shell-side, wind turbine or compressor are driven by electric drive or other machinery mode.Wind turbine or compressor suction are come From the flash-off steam of flash tank, heated type condenser shell-side, the steam source as heated waste water are sent to after compression heating step by step.
When certain density concentration waste water sprays into flue, the selection of nozzle mounting position point in air preheater and electric precipitator it Between flue inner top, be disposed adjacent to a side flue of air preheater.
This system is equally applicable to that except desulfurization wastewater, needing to carry out wastewater zero discharge processing other, " saliferous is useless Water ".
Embodiment 1:
As shown in Figure 1, being directed to thermal power plant.Desulfurization wastewater low-temperature evaporation concentration systems include waste water heating system, give up Water flash distillation process system, flash-off steam aspirate compressibility.
Its kernel processing device waste water flash distillation process system includes flash tank, flashed steam cycle system;Flash tank top is spray Leaching flash distillation mechanism, bottom are equipped with sink, and side is steam (vapor) outlet, is equipped with entrainment trap.Waste water is with misty or drop state Flash tank is sprayed into, and is evaporated, cools down within the hang time, part is not flashed and falls into bottom sink.Then it is filtered, is gone forward side by side Enter the heating of waste water heating system, it is spray flash distillation mechanism to get to flash tank top again using waste water circulating pump.Thus it recycles Back and forth (different and different according to required concentration ratio).The vacuum of flash tank is established by wind turbine or compressor.The pressure of flash tank It is located at 10~20kpa.Whole system is designed to low-flash, not dosing, and non-scaling does not block, and does not generate secondary pollution, is System is simple, and constantly cycle flashes desulfurization wastewater, meanwhile, low concentration wastewater, which is constantly supplemented in, to be come, and is concentrated to a degree of Waste water is transported to flue and sprays into system.The steam (vapor) outlet of flash tank is equipped with filter device.
In work, the desulfurization wastewater from thermal power plant desulfurizer, flow is about 30t/h, by pipeline valve and Pump is delivered to flash tank bottom sink, and subsequently into waste water heating system, 0.2Mpa, temperature are forced into heated type condenser It is heated to 66 DEG C or so;The spray flash distillation mechanism for entering back into flash tank inner upper forms spray water mist into tank.Flashing pressure 15kpa, about 54 DEG C of temperature;Desulfurization wastewater is repeatedly recycled, and circulating water flow is about 1030t/h.
Flash tank connects flash-off steam and aspirates compressibility, and the flash-off steam that flow is about 20t/h is inhaled into wind turbine or pressure The steam pressure of contracting machine, wind turbine or compressor outlet is about 26kpa, and temperature is about 66 DEG C.
The steam that flow from wind turbine or compressor outlet is about 20t/h, pressure is about 26kpa, temperature is about 66 DEG C, Into heated type condenser shell-side, it is cooled to condensed water for the desulfurization wastewater of heating tube side flowing, and by steam, and formed about 20t/h's is hydrophobic, recycles.
Concentration desulfurization wastewater after flash process can enter penetrating system, into the system of penetrating concentration desulfurization wastewater about For 10t/h.
Desulfurization wastewater from thermal power plant desulfurizer, flow are about 30t/h, pass through this low-temperature evaporation concentration systems Afterwards, about 20t/h industrial waters have been recycled, the brine waste of about 10t/h higher concentrations has been condensed into, have sprayed into flue evaporation.
It is both needed to make of resistant material with the position of waste water in above equipment.Desulfurization wastewater is through waste water flash concentration Become increasing after system the high-concentration waste water of certain temperature with it is hydrophobic, wherein hydrophobic recoverable, high-concentration waste water (account for about The 1/3 of original input waste water total amount) total amount reduction, it nebulizes (average grain diameter≤70 μm) using atomizer atomization, sprays into cigarette In heat smoke in road.
In flue, waste water after atomization is mixed formula heat exchange with flue gas, using boiler tail thermal flue gas by waste water It is evaporated, the fine solid particle object of generation is captured by electric precipitator, realizes the zero-emission of desulfurization wastewater.In this evaporation process, cigarette Temperature degree reduces about 3-8 DEG C.Since smoke temperature is higher than acid dew point, so low-temperature corrosion, which will not occur, influences unit safety operation.
Finally it should be noted that:The foregoing is merely the explanations of the utility model, are not intended to limit the utility model, to the greatest extent The utility model is described in detail in pipe, for those skilled in the art, can still be remembered to aforementioned The technical solution of load is modified or equivalent replacement of some of the technical features.All spirit in the utility model Within principle, any modification, equivalent replacement, improvement and so on should be included within the scope of protection of this utility model.

Claims (7)

1. a kind of desulfurization wastewater low-temperature evaporation concentration systems, including waste water heating system, waste water flash distillation process system, flash-off steam Aspirate compressibility;It is characterized in that:The desulfurization wastewater efferent duct of desulfurizer connects waste water flash distillation process system;Waste water flashes Processing system connects waste water heating system;The flash-off steam piping connection flash-off steam suction compression system of waste water flash distillation process system System;The desulfurization wastewater circulation line of waste water flash distillation process system connects flue penetrating vapo(u)rization system by concentrating water delivery pipe;It is useless Water heating system includes heated type condenser, heated type condenser water system, heated type evacuation system for steam condenser, heated type Steam Side of Condenser and condensate draining system;The desulfurization wastewater of heated type condenser water system access waste water flash distillation process system recycles Pipeline, heated type Steam Side of Condenser are connected with waste water heat source system steam drain;Heated type condenser shell-side is from useless The steam of water heat source system, pipe side are desulfurization wastewater, and heating steam is condensed into water and recycles;Waste water flash distillation process system packet Include flash tank, flashed steam cycle system;Flash tank top is spray flash distillation mechanism, and bottom is equipped with sink, is recycled by desulfurization wastewater Piping connection;Flash tank side is steam (vapor) outlet, and outlet is equipped with entrainment trap;Flash-off steam aspirates compressibility, including Wind turbine or compressor, steam absorbing tube road and exhaust line;Wind turbine or compressor connect flash tank steam (vapor) outlet, wind turbine through steam absorbing tube road Or compressor connects waste water heating system through exhaust line.
2. desulfurization wastewater low-temperature evaporation concentration systems according to claim 1, which is characterized in that flash tank steam (vapor) outlet connects The wind turbine or compressor of flash-off steam suction compressibility are connect, the vacuum of flash tank is established by wind turbine or compressor.
3. desulfurization wastewater low-temperature evaporation concentration systems according to claim 1, which is characterized in that the interior design of flash tank At a pressure chamber or multiple and different pressure chambers;Water intake mode is designed as single layer spray or Multi-layer sprinkling.
4. desulfurization wastewater low-temperature evaporation concentration systems according to claim 3, which is characterized in that the mode of spray selects to adopt With high pressure nozzle, low-pressure nozzle, gas-liquid two-phase flow nozzle or water drenching disk-form.
5. desulfurization wastewater low-temperature evaporation concentration systems according to claim 4, which is characterized in that arrangement of nozzles is in tank body Top, waist and/or middle and lower part;The direction of ejection is using upward, downward, centripetal spray and/or radial spray mode.
6. desulfurization wastewater low-temperature evaporation concentration systems according to claim 1, which is characterized in that flash-off steam suction compression System, including a Fans or compressor or more serial or parallel connection wind turbines or compressor;Wind turbine or compressor suction port connection Flash distillation plant, wind turbine or compressor are driven by electric drive or mechanical system;The sudden strain of a muscle of wind turbine or compressor suction from flash tank Steam is steamed, is sent to heated type condenser shell-side, the heat source as heated waste water after compression heating step by step.
7. desulfurization wastewater low-temperature evaporation concentration systems according to claim 1, which is characterized in that flue sprays into vapo(u)rization system Atomizer is installed on the flue inner top between air preheater and electric precipitator, is disposed adjacent to a side flue of air preheater.
CN201721168987.3U 2017-08-30 2017-08-30 A kind of desulfurization wastewater low-temperature evaporation concentration systems Active CN207845196U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111634969A (en) * 2020-05-30 2020-09-08 联合瑞升(北京)科技有限公司 High vacuum maintenance system for salt-containing wastewater treatment and operation method
CN111807591A (en) * 2020-06-02 2020-10-23 北京朗新明环保科技有限公司 Mixed salt curing method and system for high-salinity wastewater of power plant

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111634969A (en) * 2020-05-30 2020-09-08 联合瑞升(北京)科技有限公司 High vacuum maintenance system for salt-containing wastewater treatment and operation method
CN111807591A (en) * 2020-06-02 2020-10-23 北京朗新明环保科技有限公司 Mixed salt curing method and system for high-salinity wastewater of power plant
CN111807591B (en) * 2020-06-02 2024-01-23 国能朗新明环保科技有限公司 Method and system for curing mixed salt of high-salt wastewater of power plant

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