CN205720167U - Optimization urea concentration assay device for diesel engine after treatment - Google Patents
Optimization urea concentration assay device for diesel engine after treatment Download PDFInfo
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- CN205720167U CN205720167U CN201620618190.8U CN201620618190U CN205720167U CN 205720167 U CN205720167 U CN 205720167U CN 201620618190 U CN201620618190 U CN 201620618190U CN 205720167 U CN205720167 U CN 205720167U
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title claims abstract description 110
- 239000004202 carbamide Substances 0.000 title claims abstract description 110
- 238000003556 assay Methods 0.000 title 1
- 238000005457 optimization Methods 0.000 title 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 123
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 53
- 238000005070 sampling Methods 0.000 claims abstract description 45
- 230000003197 catalytic effect Effects 0.000 claims abstract description 24
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 22
- 239000007789 gas Substances 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000003054 catalyst Substances 0.000 claims description 10
- 239000002912 waste gas Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 18
- 238000010531 catalytic reduction reaction Methods 0.000 abstract description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 36
- 238000002347 injection Methods 0.000 description 18
- 239000007924 injection Substances 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 10
- 239000007787 solid Substances 0.000 description 9
- 238000000197 pyrolysis Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 238000005507 spraying Methods 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
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- Exhaust Gas After Treatment (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
本实用新型公开了一种用于柴油机后处理的优化尿素浓度试验装置,其结构为:尿素分解管一端通过尿素分解管快接头连接到发动机排气管,所述尿素分解管的另一端通过前催化器快接头连接到催化器,所述催化器再通过后催化器快接头连接到废气连接管,所述废气连接管置入到废气处理池中,所述废气处理池设置有废气尾管;在所述尿素分解管前端设置有尿素喷嘴,后端设置有尿素喷嘴后氨采样口;在尿素喷嘴后氨采样口与催化器之间设置有前氨采样口,在废气连接管上设有后氨采样口。本实用新型装置能够找出不同温度下选择性催化还原后处理系统反应的最优尿素浓度。
The utility model discloses an optimized urea concentration test device for aftertreatment of diesel engines. The catalytic converter quick connector is connected to the catalytic converter, and the catalytic converter is connected to the exhaust gas connecting pipe through the rear catalytic converter quick connector, and the exhaust gas connecting pipe is placed into the exhaust gas treatment pool, and the exhaust gas treatment pool is provided with an exhaust gas tail pipe; A urea nozzle is provided at the front end of the urea decomposition pipe, and a rear ammonia sampling port is provided at the rear end of the urea nozzle; a front ammonia sampling port is provided between the ammonia sampling port behind the urea nozzle and the catalytic converter, and a rear ammonia sampling port is provided on the exhaust gas connecting pipe. Ammonia sampling port. The device of the utility model can find out the optimum urea concentration for the selective catalytic reduction post-treatment system reaction at different temperatures.
Description
技术领域technical field
本实用新型涉及内燃机氮氧化物后处理领域,具体涉及一种用于柴油机后处理的优化尿素浓度试验装置。The utility model relates to the field of aftertreatment of nitrogen oxides of internal combustion engines, in particular to an optimized urea concentration test device for aftertreatment of diesel engines.
背景技术Background technique
为减少机动车氮氧化物和颗粒物的排放,国家制定了一系列的排放法规。目前,要使柴油机动车适应国IV、国V标准的主要技术手段是以尿素溶液为还原剂的选择性催化还原后处理技术。选择性催化还原后处理系统的还原剂主要是浓度为32.5%的尿素溶液,该浓度的尿素溶液具有最低的冰点。但对于一些环境温度较高的地区或季节,可以不需要这么低的冰点,应以最优的尿素浓度向后处理系统中供应尿素。In order to reduce the emission of nitrogen oxides and particulate matter from motor vehicles, the state has formulated a series of emission regulations. At present, the main technical means to make diesel vehicles adapt to the National IV and National V standards is the selective catalytic reduction post-treatment technology with urea solution as the reducing agent. The reducing agent of the selective catalytic reduction aftertreatment system is mainly 32.5% urea solution, which has the lowest freezing point. However, for some areas or seasons with high ambient temperature, such a low freezing point may not be required, and urea should be supplied to the post-treatment system with the optimal urea concentration.
实用新型内容Utility model content
本实用新型所要解决的技术问题是提供一种用于柴油机后处理的优化尿素浓度试验装置,能够找出不同温度下选择性催化还原后处理系统反应的最优尿素浓度。The technical problem to be solved by the utility model is to provide an optimized urea concentration test device for aftertreatment of diesel engines, which can find out the optimal urea concentration for the reaction of the selective catalytic reduction aftertreatment system at different temperatures.
为解决上述技术问题,本实用新型采用的技术方案是:In order to solve the problems of the technologies described above, the technical solution adopted in the utility model is:
一种用于柴油机后处理的优化尿素浓度试验装置,尿素分解管一端通过尿素分解管快接头连接到发动机排气管,所述尿素分解管的另一端通过前催化器快接头连接到催化器,所述催化器再通过后催化器快接头连接到废气连接管,所述废气连接管置入到废气处理池中,所述废气处理池设置有废气尾管;An optimized urea concentration test device for aftertreatment of diesel engines, one end of the urea decomposition tube is connected to the engine exhaust pipe through a quick connector of the urea decomposition tube, and the other end of the urea decomposition tube is connected to the catalytic converter through a quick connector of the front catalyst, The catalytic converter is connected to the exhaust gas connecting pipe through the rear catalytic converter quick connector, and the exhaust gas connecting pipe is placed in the exhaust gas treatment pool, and the exhaust gas treatment pool is provided with an exhaust gas tail pipe;
在所述尿素分解管前端设置有尿素喷嘴,后端设置有尿素喷嘴后氨采样口;在尿素喷嘴后氨采样口与催化器之间设置有前氨采样口,在废气连接管上设有后氨采样口。A urea nozzle is provided at the front end of the urea decomposition pipe, and a rear ammonia sampling port is provided at the rear end of the urea nozzle; a front ammonia sampling port is provided between the ammonia sampling port behind the urea nozzle and the catalytic converter, and a rear ammonia sampling port is provided on the exhaust gas connecting pipe. Ammonia sampling port.
根据上述方案,在所述尿素喷嘴后氨采样口与前氨采样口之间设有水喷嘴。According to the above solution, a water nozzle is provided between the rear ammonia sampling port and the front ammonia sampling port of the urea nozzle.
根据上述方案,在尿素分解管快接头与尿素喷嘴之间还设有前压力传感器、尿素喷嘴前温度传感器,在尿素喷嘴与尿素喷嘴后氨采样口之间设有尿素喷嘴后温度传感器,在前催化器快接头与尿素喷嘴后氨采样口之间设有催化器前温度传感器,在废气连接管上设有催化器后温度传感器、后压力传感器。According to the above scheme, a front pressure sensor and a temperature sensor in front of the urea nozzle are also provided between the quick connector of the urea decomposition pipe and the urea nozzle, and a temperature sensor behind the urea nozzle is provided between the urea nozzle and the ammonia sampling port behind the urea nozzle. A temperature sensor before the catalyst is installed between the quick connector of the catalyst and the ammonia sampling port behind the urea nozzle, and a temperature sensor and a pressure sensor after the catalyst are installed on the exhaust gas connecting pipe.
根据上述方案,所述废气处理池为密封箱体,其内部装有废气处理液。According to the above scheme, the exhaust gas treatment pool is a sealed box, and the exhaust gas treatment liquid is installed inside it.
与现有技术相比,本实用新型的有益效果是:1)可以分别测出尿素热解、水解和总的产氨量,分析每一步反应的效率;2)可以测出不同尿素浓度下催化器的转换效率,并找出最优的尿素喷射浓度;3)可以监测在径向不同位置处的温度分布和氨分布,为后续分析提供数据;4)可以监测水对排气温度的影响;5)可以实时显示固体尿素热解效率、水解效率、氮氧化物转化效率。Compared with the prior art, the beneficial effects of the utility model are: 1) can measure the urea pyrolysis, hydrolysis and total ammonia production respectively, analyze the efficiency of each step reaction; 3) The temperature distribution and ammonia distribution at different positions in the radial direction can be monitored to provide data for subsequent analysis; 4) The influence of water on the exhaust temperature can be monitored; 5) It can display solid urea pyrolysis efficiency, hydrolysis efficiency and nitrogen oxide conversion efficiency in real time.
各氨采样口沿着圆周在径向不同深度插入管中以测取管中径向不同位置的温度分布情况。各温度传感器沿着圆周在径向不同深度插入管中以测取管中径向不同位置的氨气量的分布情况。Each ammonia sampling port is inserted into the tube at different radial depths along the circumference to measure the temperature distribution at different radial positions in the tube. Each temperature sensor is inserted into the tube at different radial depths along the circumference to measure the distribution of ammonia gas at different radial positions in the tube.
附图说明Description of drawings
图1为本实用新型用于柴油机后处理的优化尿素浓度试验装置结构示意图。Fig. 1 is a structural schematic diagram of an optimized urea concentration test device for diesel engine post-treatment according to the present invention.
图2为本实用新型中各温度传感器的径向布置方式。Fig. 2 is the radial arrangement of each temperature sensor in the utility model.
图3为本实用新型中各氨采样口的径向布置方式。Fig. 3 is the radial arrangement of each ammonia sampling port in the utility model.
图中:尿素分解管快接头1、前压力传感器2、尿素喷嘴前温度传感器3、尿素喷嘴4、尿素分解管5、尿素喷嘴后温度传感器6、尿素喷嘴后氨采样口7、水喷嘴8、催化器前温度传感器9、前氨采样口10、前催化器快接头11、催化器12、后催化器快接头13、催化器后温度传感器14、后压力传感器15、后氨采样口16、废气连接管17、废气处理池18、废气尾管19。In the figure: urea decomposition pipe quick connector 1, front pressure sensor 2, temperature sensor in front of urea nozzle 3, urea nozzle 4, urea decomposition pipe 5, temperature sensor behind urea nozzle 6, ammonia sampling port 7 behind urea nozzle, water nozzle 8, Catalyst front temperature sensor 9, front ammonia sampling port 10, front catalytic converter quick connector 11, catalytic converter 12, rear catalytic converter quick connector 13, catalytic converter rear temperature sensor 14, rear pressure sensor 15, rear ammonia sampling port 16, exhaust gas Connecting pipe 17, waste gas treatment tank 18, waste gas tailpipe 19.
具体实施方式detailed description
下面结合附图和具体实施方式对本实用新型作进一步详细的说明。本实用新型提供的一种用于柴油机后处理的优化尿素浓度试验装置,其结构为:尿素分解管5一端通过尿素分解管快接头1连接到发动机排气管,所述尿素分解管5的另一端通过前催化器快接头11连接到催化器12,所述催化器12再通过后催化器快接头13连接到废气连接管17,所述废气连接管17置入到废气处理池18中,所述废气处理池18设置有废气尾管19;Below in conjunction with accompanying drawing and specific embodiment, the utility model is described in further detail. The utility model provides an optimized urea concentration test device for post-treatment of diesel engines. Its structure is: one end of the urea decomposition pipe 5 is connected to the engine exhaust pipe through the urea decomposition pipe quick joint 1, and the other end of the urea decomposition pipe 5 One end is connected to the catalytic converter 12 through the front catalytic converter quick joint 11, and the catalytic converter 12 is connected to the exhaust gas connecting pipe 17 through the rear catalytic converter quick joint 13, and the exhaust gas connecting pipe 17 is inserted into the exhaust gas treatment pool 18, so The exhaust gas treatment pool 18 is provided with an exhaust tailpipe 19;
在所述尿素分解管5前端设置有尿素喷嘴4,后端设置有尿素喷嘴后氨采样口7;在尿素喷嘴后氨采样口7与催化器12之间设置有前氨采样口10,在废气连接管17上设有后氨采样口16。The front end of the urea decomposition pipe 5 is provided with a urea nozzle 4, and the rear end is provided with an ammonia sampling port 7 after the urea nozzle; a front ammonia sampling port 10 is arranged between the ammonia sampling port 7 and the catalytic converter 12 after the urea nozzle, and the exhaust gas A rear ammonia sampling port 16 is provided on the connecting pipe 17 .
在所述尿素喷嘴后氨采样口7与前氨采样口10之间设有水喷嘴8。A water nozzle 8 is provided between the rear ammonia sampling port 7 and the front ammonia sampling port 10 of the urea nozzle.
在尿素分解管快接头1与尿素喷嘴4之间还设有前压力传感器2、尿素喷嘴前温度传感器3,在尿素喷嘴4与尿素喷嘴后氨采样口7之间设有尿素喷嘴后温度传感器6,在前催化器快接头11与尿素喷嘴后氨采样口7之间设有催化器前温度传感器9,在废气连接管17上设有催化器后温度传感器14、后压力传感器15。A front pressure sensor 2 and a temperature sensor 3 in front of the urea nozzle are also provided between the urea decomposition pipe quick joint 1 and the urea nozzle 4, and a temperature sensor 6 after the urea nozzle is provided between the urea nozzle 4 and the ammonia sampling port 7 behind the urea nozzle A temperature sensor 9 before the catalyst is provided between the quick connector 11 of the front catalyst and the ammonia sampling port 7 after the urea nozzle, and a temperature sensor 14 and a pressure sensor 15 after the catalyst are provided on the exhaust gas connecting pipe 17 .
所述废气处理池18为密封箱体,其内部装有废气处理液。The exhaust gas treatment pool 18 is a sealed box, and the exhaust gas treatment liquid is installed inside it.
如图2所示,各氨采样口沿着圆周在径向不同深度插入管中以测取管中径向不同位置的温度分布情况。如图3所示,各温度传感器沿着圆周在径向不同深度插入管中以测取管中径向不同位置的氨气量的分布情况。As shown in Figure 2, each ammonia sampling port is inserted into the tube at different radial depths along the circumference to measure the temperature distribution at different radial positions in the tube. As shown in Figure 3, each temperature sensor is inserted into the tube at different radial depths along the circumference to measure the distribution of ammonia gas at different radial positions in the tube.
另外,本实用新型的试验方法详述如下:In addition, the test method of the utility model is described in detail as follows:
一、观察氨气的产生效率,用以确定不同工况下的最优尿素喷射浓度1. Observe the production efficiency of ammonia gas to determine the optimal urea injection concentration under different working conditions
实施例1:喷射“固体尿素+水”Example 1: Spraying "solid urea + water"
1)某一工况下的尿素浓度:1) Urea concentration under a certain working condition:
式中:为尿素浓度;为尿素喷射质量,g;为水的喷射量,g。In the formula: is the urea concentration; is the injection mass of urea, g; is the injection volume of water, g.
2)某一工况的氨气产生效率计算公式2) Calculation formula of ammonia production efficiency in a certain working condition
式中:为氨气的产生效率;为尿素分解产生的氨气质量,即前氨采样口测得的氨气质量,g;为尿素喷射质量,g。In the formula: is the production efficiency of ammonia gas; is the mass of ammonia gas produced by urea decomposition, i.e. the mass of ammonia gas measured at the front ammonia sampling port, g; is the injection mass of urea, g.
3)实施步骤为:(1)选定发动机的工况;(2)定量喷射尿素固体;(3)逐渐增加喷水量;(4)观察氨气的产生效率,当产生效率到达最大时,此时的尿素浓度为当前工况最优喷射浓度。3) The implementation steps are: (1) select the working condition of the engine; (2) quantitatively inject urea solids; (3) gradually increase the amount of water injection; (4) observe the production efficiency of ammonia, when the production efficiency reaches the maximum, The urea concentration at this time is the optimal injection concentration for the current working condition.
实施例2:喷射不同浓度的尿素溶液Embodiment 2: spraying urea solutions of different concentrations
1)某一工况的氨气产生效率计算公式1) Calculation formula of ammonia production efficiency in a certain working condition
式中:为氨气的产生效率;为尿素分解产生的氨气质量,即前氨采样口测得的氨气质量,g;为当前浓度下尿素水溶液喷射质量,g;为当前尿素浓度。In the formula: is the production efficiency of ammonia gas; is the mass of ammonia gas produced by urea decomposition, i.e. the mass of ammonia gas measured at the front ammonia sampling port, g; is the injection mass of urea aqueous solution at the current concentration, g; is the current urea concentration.
2)实施步骤为:(1)选定发动机的工况;(2)定量喷射尿素水溶液;(3)逐渐增加喷射量;(4)观察氨气的产生效率,当产生效率到达最大时,此时的尿素浓度为当前工况最优喷射浓度。2) The implementation steps are: (1) select the working condition of the engine; (2) quantitatively inject urea aqueous solution; (3) gradually increase the injection amount; (4) observe the production efficiency of ammonia, when the production efficiency reaches the maximum, then The urea concentration at the time is the optimal injection concentration for the current working condition.
二、通过氮氧化物最优转换效率,用以确定不同工况下的氮氧化物最优转换效率的尿素喷射浓度2. Through the optimal conversion efficiency of nitrogen oxides, the urea injection concentration is used to determine the optimal conversion efficiency of nitrogen oxides under different working conditions
实施例3:喷射“固体尿素+水”Example 3: Spraying "solid urea+water"
1)某一工况下的尿素浓度:1) Urea concentration under a certain working condition:
式中:为尿素浓度;为尿素喷射质量,g;为水的喷射量,g。In the formula: is the urea concentration; is the injection mass of urea, g; is the injection volume of water, g.
2)某一工况的氮氧化物转化效率计算公式2) The formula for calculating the conversion efficiency of nitrogen oxides in a certain working condition
式中:为氮氧化物的转换效率;为尿素分解产生的氨气质量,即前氨采样口测得的氨气质量,g;为转化后未参与反应的氨气质量,即后氨采样口测得的氨气质量,g。In the formula: is the conversion efficiency of nitrogen oxides; is the mass of ammonia gas produced by urea decomposition, i.e. the mass of ammonia gas measured at the front ammonia sampling port, g; is the mass of ammonia gas that did not participate in the reaction after conversion, that is, the mass of ammonia gas measured at the rear ammonia sampling port, g.
3)实施步骤为:(1)选定发动机的工况;(2)定量喷射尿素固体;(3)逐渐增加喷水量;(4)观察氮氧化物的转化效率,当转化效率到达最大时,此时的尿素浓度为当前工况最优喷射浓度。3) The implementation steps are: (1) select the working condition of the engine; (2) quantitatively inject urea solid; (3) gradually increase the amount of water injection; (4) observe the conversion efficiency of nitrogen oxides, when the conversion efficiency reaches the maximum , the urea concentration at this time is the optimal injection concentration for the current working condition.
实施例4:喷射不同浓度的尿素溶液Embodiment 4: spraying urea solutions of different concentrations
1)某一工况的氮氧化物转化效率计算公式1) The formula for calculating the conversion efficiency of nitrogen oxides in a certain working condition
式中:为氮氧化物的转换效率;为尿素分解产生的氨气质量,即前氨采样口测得的氨气质量,g;为转化后未参与反应的氨气质量,即后氨采样口测得的氨气质量,g。In the formula: is the conversion efficiency of nitrogen oxides; is the mass of ammonia gas produced by urea decomposition, i.e. the mass of ammonia gas measured at the front ammonia sampling port, g; is the mass of ammonia gas that did not participate in the reaction after conversion, that is, the mass of ammonia gas measured at the rear ammonia sampling port, g.
2)实施步骤为:(1)选定发动机的工况;(2)定量喷射尿素水溶液;(3)逐渐增加喷射量;(4)观察氮氧化物的转化效率,当氮氧化物转化效率到达最大时,此时的尿素浓度为当前工况最优喷射浓度。2) The implementation steps are: (1) select the working condition of the engine; (2) quantitatively inject urea aqueous solution; (3) gradually increase the injection amount; (4) observe the conversion efficiency of nitrogen oxides, when the conversion efficiency of nitrogen oxides reaches At the maximum, the urea concentration at this time is the optimal injection concentration for the current working condition.
其中η热解为尿素固体热解产生NH3的效率;为尿素固体热解产生的NH3量,即尿素喷嘴后氨采样口7所测得的量,单位g;为尿素喷射质量,单位g; Wherein η pyrolysis is urea solid pyrolysis produces NH Efficiency ; is the amount of NH produced by urea solid pyrolysis, that is, the amount measured at the ammonia sampling port 7 behind the urea nozzle, in g; is the injection mass of urea, in g;
其中η水解为尿素固体水解产生NH3的效率;为尿素热解和水解产生的总氨气质量,即前氨采样口10测得的氨气质量,单位g;为尿素固体热解产生的NH3量,即尿素喷嘴后氨采样口7所测得的量,单位g;为尿素喷射质量,单位g。 Wherein η hydrolysis is urea solid hydrolysis and produces NH Efficiency ; is the total ammonia mass produced by urea pyrolysis and hydrolysis, i.e. the ammonia mass measured at the front ammonia sampling port 10, in g; is the amount of NH produced by urea solid pyrolysis, that is, the amount measured at the ammonia sampling port 7 behind the urea nozzle, in g; is the injection mass of urea, in g.
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