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CN204485642U - Organic exhaust gas adsorption desorption-catalytic combustion coprocessing circulatory system - Google Patents

Organic exhaust gas adsorption desorption-catalytic combustion coprocessing circulatory system Download PDF

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Publication number
CN204485642U
CN204485642U CN201520067454.0U CN201520067454U CN204485642U CN 204485642 U CN204485642 U CN 204485642U CN 201520067454 U CN201520067454 U CN 201520067454U CN 204485642 U CN204485642 U CN 204485642U
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China
Prior art keywords
adsorption
exhaust gas
organic exhaust
desorption
catalytic combustor
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Expired - Fee Related
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CN201520067454.0U
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Chinese (zh)
Inventor
闫茜
刘芳
赵朝成
刘仁涛
高雅
张利
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China University of Petroleum East China
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China University of Petroleum East China
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Abstract

The utility model relates to a kind of organic exhaust gas adsorption desorption-catalytic combustion coprocessing circulatory system.Its technical scheme is: the top of pretreatment unit is connected to the bottom of adsorption reaction room, and adsorption reaction indoor are provided with adsorption column, and adsorption column inside is provided with reaction tube, and reaction tube inside division is three independent stratums; The top of described adsorption reaction room is connected to the left side of catalytic combustor, and the right side of catalytic combustor is connected to the side inlet of pretreatment unit; The bottom of separator is connected to desorption and regeneration case, and top is connected to catalytic combustor.Beneficial effect is: can realize adsorption reaction room and catalytic combustor complements each other, coefficient effect; Pretreatment unit can effectively remove moisture in organic exhaust gas, avoids each adsorbent in adsorption reaction post to reduce its organic exhaust gas adsorption because of water suction, thus guarantees adsorbent high efficiency of additive capability; Can effectively remove impurity in organic exhaust gas, dust and catalyst poison, prevent bed from blocking and catalyst poisoning.

Description

Organic exhaust gas adsorption desorption-catalytic combustion coprocessing circulatory system
Technical field
The utility model relates to a kind of industrial organic waste-gas purification treatment system, particularly a kind of organic exhaust gas adsorption desorption-catalytic combustion coprocessing circulatory system.
Background technology
Organic Waste Gas Pollution derives from many industrial circles such as oil, chemical industry, paint, electronics, rubber, printing.Along with various industry is growing, enter organic exhaust gas in atmospheric environment in process of production also in continuous increase, these pollutants comprise benzene homologues, aldoketones, halogenated hydrocarbons, alcohols etc.Organic exhaust gas becomes one of more difficult waste gas because of strong, the water-soluble characteristic such as low of its strong toxicity, diffusivity.
Absorption method, is current comparatively maturation, applies wider VOCs treatment technology, but it has certain limitation for VOCs treatment.First, the method is only applicable to little air quantity VOCs treatment.Secondly, absorption method is commonly used adsorbent (active carbon, NACF, activated alumina, molecular sieve etc.) and is had high-hydroscopicity energy, and under the higher environmental condition of humidity, adsorption capacity significantly reduces.In addition, if saturated adsorption agent is placed in air ambient for a long time, desorption goes out organic substance can cause secondary pollution to atmospheric environment.
Summary of the invention
The purpose of this utility model is exactly in view of the foregoing defects the prior art has, a kind of organic exhaust gas adsorption desorption-catalytic combustion coprocessing circulatory system is provided, the combination of absorption method and Production by Catalytic Combustion Process can be realized, both multiple sorbing material co-treatment industrial waste gas can have been realized, the organic substance of recyclable process saturated adsorption materials adsorption again, and carry out regneration of adsorbent material simultaneously.
Its technical scheme is: comprise pretreatment unit, adsorption reaction room, separator, desorption and regeneration case, catalytic combustor, the top of described pretreatment unit is connected to the bottom of adsorption reaction room, adsorption reaction indoor are provided with adsorption column, adsorption column inside is provided with reaction tube, and reaction tube inside division is three independent stratums; The top of described adsorption reaction room is connected to the left side of catalytic combustor, and the right side of catalytic combustor is connected to the side inlet of pretreatment unit; The bottom of separator is connected to desorption and regeneration case, and top is connected to catalytic combustor.
The adsorption tube of filling discolour silica gel ball is provided with in above-mentioned pretreatment unit.
The sorbent material layer of catalyst filling modification in above-mentioned catalytic combustor.
The side of above-mentioned separator is provided with blower fan, and the bottom of desorption and regeneration case connects vavuum pump.
The beneficial effects of the utility model are: can realize adsorption reaction room and catalytic combustor complements each other, coefficient effect.Organic exhaust gas concentration through adsorption reaction room reduces, and can improve catalytic combustion treatment effeciency; And catalytic combustion can improve the clean-up effect of organic exhaust gas after adsorption treatment; Pretreatment unit can effectively remove moisture in organic exhaust gas, avoids each adsorbent in adsorption reaction post to reduce its organic exhaust gas adsorption because of water suction, thus guarantees adsorbent high efficiency of additive capability; Can effectively remove impurity in organic exhaust gas, dust and catalyst poison, prevent bed from blocking and catalyst poisoning.
Accompanying drawing explanation
Accompanying drawing 1 is structural representation of the present utility model;
In upper figure: pretreatment unit 1, adsorption reaction room 2, blower fan 3, separator 4, desorption and regeneration case 5, catalytic combustor 6, vavuum pump 7.
Detailed description of the invention
By reference to the accompanying drawings 1, the utility model will be further described:
The utility model comprises pretreatment unit 1, adsorption reaction room 2, separator 4, desorption and regeneration case 5, catalytic combustor 6, the top of described pretreatment unit 1 is connected to the bottom of adsorption reaction room 2, adsorption column is provided with in adsorption reaction room 2, adsorption column inside is provided with reaction tube, reaction tube inside division is three independent stratums, can add different sorbing material as adsorbent.When each layer inserts sorbing material of the same race, contrast the treatment effect of different sorbing material by parallel test.When inserting different sorbing material, different sorbing material associated treatment organic exhaust gas effect can be investigated; The top of described adsorption reaction room 2 is connected to the left side of catalytic combustor 6, and the right side of catalytic combustor 6 is connected to the side inlet of pretreatment unit 1; The bottom of separator 4 is connected to desorption and regeneration case 5, and top is connected to catalytic combustor 6.
Wherein, be provided with the adsorption tube of filling discolour silica gel ball in pretreatment unit 1, first pretreatment carried out to organic exhaust gas, while realizing organic exhaust gas drying and dehydrating, Impurity removal in gas can be realized; The sorbent material layer of catalyst filling modification in above-mentioned catalytic combustor 6, thus reach catalytic treatment, adsorption reaction and carry out simultaneously, realize organic exhaust gas and efficiently process.Example: if select NACF as organic waste-gas adsorbant, then the modification of catalyst soakage method is carried out to activated carbon fiber material, thus the adsorbent obtaining that load has catalyst; The side of above-mentioned separator 4 is provided with blower fan 3, and the bottom of desorption and regeneration case 5 connects vavuum pump 7.
The course of work of the present utility model is:
First industrial organic exhaust gas enters pretreatment unit from bottom, carries out drying, impurity elimination process.After enter by bottom the adsorption reaction post that many adsorption tubes connect.After adsorption treatment, organic exhaust gas sends into catalytic combustion indoor.Meanwhile, blower fan blasts air and enters separator, and separator carries out the process of imurity-removal, dust to air, and after purification, air is as combustion adjuvant, converges, jointly sends into catalytic combustor, for catalytic combustion provides oxygen with organic exhaust gas after adsorption treatment.Organic exhaust gas after purified treatment, if do not reach discharge standard process capable of circulation; If reach discharge standard, directly air can be entered.
After the utility model runs a period of time, adsorbent in indoor for adsorption reaction adsorption tube when will reach capacity, takes out, sends into separator, and in adsorption tube, insert fresh sorbing material or regenerative adsorption material by upon adsorption dose.Now, blower fan is sent into air and is purged saturated adsorption agent, and adsorbent carries out downward spiral rotating motion with air in outside, and carries out desorption in the process.After desorption, sorbing material is thrown on wall under the action of the centrifugal, and falls into bottom dust hopper.Collect the rear adsorbent of process in dust hopper, feeding removes regeneration case and carries out vacuum high-temperature desorption and regeneration, and regeneration processed sorbing material can send into the indoor direct use of adsorption reaction.The organic gas removed then carries out oppositely upwards screw with fresh air in inside, and converges from the rear gas circuit of upper outlet and absorption, enters catalytic combustor and carries out after-treatment.Similarly, organic exhaust gas after purified treatment, if do not reach discharge standard process capable of circulation; If reach discharge standard, directly air can be entered.

Claims (4)

1. organic exhaust gas adsorption desorption-catalytic combustion coprocessing circulatory system, it is characterized in that: comprise pretreatment unit (1), adsorption reaction room (2), separator (4), desorption and regeneration case (5), catalytic combustor (6), the top of described pretreatment unit (1) is connected to the bottom of adsorption reaction room (2), adsorption reaction room is provided with adsorption column in (2), adsorption column inside is provided with reaction tube, and reaction tube inside division is three independent stratums; The top of described adsorption reaction room (2) is connected to the left side of catalytic combustor (6), and the right side of catalytic combustor (6) is connected to the side inlet of pretreatment unit (1); The bottom of separator (4) is connected to desorption and regeneration case (5), and top is connected to catalytic combustor (6).
2. organic exhaust gas adsorption desorption according to claim 1-catalytic combustion coprocessing circulatory system, is characterized in that: be provided with the adsorption tube of filling discolour silica gel ball in described pretreatment unit (1).
3. organic exhaust gas adsorption desorption according to claim 1-catalytic combustion coprocessing circulatory system, is characterized in that: the sorbent material layer of catalyst filling modification in described catalytic combustor (6).
4. organic exhaust gas adsorption desorption according to claim 1-catalytic combustion coprocessing circulatory system, is characterized in that: the side of described separator (4) is provided with blower fan (3), and the bottom of desorption and regeneration case (5) connects vavuum pump (7).
CN201520067454.0U 2015-01-31 2015-01-31 Organic exhaust gas adsorption desorption-catalytic combustion coprocessing circulatory system Expired - Fee Related CN204485642U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201520067454.0U CN204485642U (en) 2015-01-31 2015-01-31 Organic exhaust gas adsorption desorption-catalytic combustion coprocessing circulatory system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201520067454.0U CN204485642U (en) 2015-01-31 2015-01-31 Organic exhaust gas adsorption desorption-catalytic combustion coprocessing circulatory system

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106178814A (en) * 2016-07-08 2016-12-07 上海出版印刷高等专科学校 Low power consuming printing VOCs gas recovery system
CN106362545A (en) * 2016-11-25 2017-02-01 嘉兴亿豪新材料有限公司 Efficient waste gas treatment device
CN106955570A (en) * 2017-03-16 2017-07-18 盐城复华环保产业开发有限公司 A kind of catalytic oxidation process for treating for being used to handle gaseous contaminant
CN108072039A (en) * 2017-12-29 2018-05-25 河南永煤碳纤维有限公司 A kind of carbon fiber production emission-control equipment and method
CN111151126A (en) * 2020-01-13 2020-05-15 吴培源 Graphene adsorption-heat accumulation type catalytic combustion VOCs purification device and technology
US20210245399A1 (en) * 2020-02-12 2021-08-12 Polymetrix Ag Method and device for processing a mixture of recycled polyester material and a polyester prepolymer from a polyester manufacturing process

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106178814A (en) * 2016-07-08 2016-12-07 上海出版印刷高等专科学校 Low power consuming printing VOCs gas recovery system
CN106362545A (en) * 2016-11-25 2017-02-01 嘉兴亿豪新材料有限公司 Efficient waste gas treatment device
CN106955570A (en) * 2017-03-16 2017-07-18 盐城复华环保产业开发有限公司 A kind of catalytic oxidation process for treating for being used to handle gaseous contaminant
CN108072039A (en) * 2017-12-29 2018-05-25 河南永煤碳纤维有限公司 A kind of carbon fiber production emission-control equipment and method
CN111151126A (en) * 2020-01-13 2020-05-15 吴培源 Graphene adsorption-heat accumulation type catalytic combustion VOCs purification device and technology
CN111151126B (en) * 2020-01-13 2022-05-03 吴培源 Device and process for purifying VOCs (volatile organic compounds) through graphene adsorption-heat accumulation type catalytic combustion
US20210245399A1 (en) * 2020-02-12 2021-08-12 Polymetrix Ag Method and device for processing a mixture of recycled polyester material and a polyester prepolymer from a polyester manufacturing process
US11839996B2 (en) * 2020-02-12 2023-12-12 Polymetrix Ag Method and device for processing a mixture of recycled polyester material and a polyester prepolymer from a polyester manufacturing process

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150722

Termination date: 20160131

EXPY Termination of patent right or utility model