CN1948219A - High conductive high strength graphite brick for ultralarge blast furnace, its production technology and application - Google Patents
High conductive high strength graphite brick for ultralarge blast furnace, its production technology and application Download PDFInfo
- Publication number
- CN1948219A CN1948219A CN 200610131620 CN200610131620A CN1948219A CN 1948219 A CN1948219 A CN 1948219A CN 200610131620 CN200610131620 CN 200610131620 CN 200610131620 A CN200610131620 A CN 200610131620A CN 1948219 A CN1948219 A CN 1948219A
- Authority
- CN
- China
- Prior art keywords
- temperature
- blast furnace
- graphite brick
- high strength
- particle diameter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Ceramic Products (AREA)
Abstract
The present invention relates to a high heat conductivity and high strength graphite brick for super-large blast furnace. It is made up by using (by wt%) 92%-94% of mixed coke formed from petroleum coke and pitch coke and 6%-8% of powdered graphite through the processes of pulverizing, grinding, screening, wet kneading, moulding, roasting and graphitization.
Description
Technical field
The invention belongs to the graphite product field, relate to a kind of graphite brick, relate in particular to the application of a kind of high conductive high strength graphite brick for ultralarge blast furnace and preparation method and this graphite brick.
Background technology
Blast furnace is meant a kind of refractory materials that is used for blast furnace lining with " brick ", according to its basic physical and chemical, can be divided into unlike material, and be defined as different appellations.Based on the high alumina brick of alumina raw material, with the silicon carbide brick of sic raw material; Based on carbon raw material and the graphite brick that behind high temperature graphitization, forms.At present, be that furnace bottom is built the bulk graphite brick by laying bricks or stones in the domestic iron-smelting blast furnace.This graphite brick is that to be broken to certain particle size with petroleum coke powder be raw material, adds medium temperature coal pitch then, and, compression moulding mixed through pinching, roasting, greying and processing obtain.Thermal conductivity and intensity with the graphite brick of above-mentioned prescription and explained hereafter thereof are all lower.The furnace bosh of domestic existing blast furnace, bosh position and shaft position (above zone, air port) liner is built refractory brick aluminium silicon series or carborundum series by laying bricks or stones more, and does not have the report of building graphite brick by laying bricks or stones.Blast furnace is in operational process, and aforementioned region is subjected to the impact of thermal load in the stove, the influences such as fluctuation of temperature for a long time, and material and airflow scouring and wearing and tearing, be subjected to the erosion of molten iron and slag, blast furnace lining is damaged, has a strong impact on the normal operation of blast furnace, make blast furnace shortening in work-ing life.
Along with blast furnace maximizes, longevityization, the existing situation of blast furnace has not adapted to the requirement of development, the manufacturing enterprise's expectation life-span in 20 years of blast furnace simultaneously.Therefore, high heat conduction, high strength fritter graphite brick and production that research and development iron and steel enterprise ultra-large type blast furnace is used, and study it and use, become enterprise and institution that is engaged in the iron and steel research and development and the important topic of being engaged in plain research and development of charcoal and production unit.
Here said ultra-large type blast furnace, general custom are called that blast furnace is the ultra-large type blast furnace more than 4000 cubic metres.It is reported that domestic 4300 cubic metres blast furnace has built up in Baoshan Iron ﹠ Steel Co., Ltd, Taiyuan Iron ﹠ Steel (Group) Co. puts into operation; Here said high heat conduction, high strength graphite brick are meant: thermal conductivity is that 170W/mK is above, ultimate compression strength is the fritter graphite brick of the above different size of 30Mpa under the room temperature.
Summary of the invention
The objective of the invention is to adapt to the needs of blast furnace maximization and new product development, the high conductive high strength fritter graphite brick and production technique and the application that provide a kind of ultra-large type blast furnace to use in order to solve the problem that prior art exists.
The objective of the invention is to be achieved by following technical scheme:
A kind of ultra-large type blast furnace is with high conductive high strength fritter graphite brick, and in 100 mass parts raw materials, wherein, mixing Jiao that refinery coke and pitch coke are formed accounts for 92～94%, and graphite is broken to account for 6～8%, and the weight ratio of described refinery coke and pitch coke is 5: 1; The medium temperature coal pitch consumption is 26～30% of a described raw materials quality sum; Above-mentioned raw material is through fragmentation, part abrasive dust, sieve according to the certain particle level then, its granulometric composition and being distributed as: 2≤particle diameter＜3 less than 2%; 1≤particle diameter＜2 are 11 ± 2%; 0.5≤particle diameter＜1 is 10 ± 2%; 0.075 following particle is 57 ± 3%; All the other are the particle of 0.075≤particle diameter＜0.5; Make the fritter graphite brick of 240～380mm * 115～145mm * 76.5～102mm.
Above-mentioned ultra-large type blast furnace high conductive high strength fritter graphite brick, its volume density 1.78～1.82g/cm
3, apparent porosity is 12.00～15.00%, and ultimate compression strength is 38.00～43.00Mpa, and thermal conductivity is 170～185W/m.K under the room temperature.
As the production method of above-mentioned ultra-large type blast furnace with high conductive high strength fritter graphite brick, it is made up of following steps:
(1) raw material composition, fragmentation, abrasive dust, screening and batching: in 100 mass parts raw materials, mixing Jiao burnt and that pitch coke is formed of raw material PetroChina Company Limited. accounts for 92～94%, and graphite is broken to account for 6～8%, and wherein the mass ratio of refinery coke and pitch coke is 5: 1; The medium temperature coal pitch consumption is 26～30% of a raw materials quality; Above-mentioned raw material is through fragmentation, part abrasive dust, sieve according to the certain particle level then, its granulometric composition and being distributed as: be unit in mm, 2≤particle diameter＜3 less than 2%; 1≤particle diameter＜2 are 11 ± 2%; 0.5≤particle diameter＜1 is 10 ± 2%; 0.075 following particle is 57 ± 3%; All the other are the particle of 0.075≤particle diameter＜0.5;
(2) mixed pinching: the raw material that step (1) is obtained mixes 30～35min in mixing to pinch to do in the pot, and it does 100～110 ℃ of mixed temperature; 26～30% the medium temperature coal pitch that adds the above-mentioned raw materials quality then, 153～165 ℃ of the temperature that wet mixing 40～45min, thickener take the dish out of the pot;
(3) die mould: the raw material that mixes after pinching through step (2) carries out moulding in forming press, its preload pressure is 15～18Mpa, and squeeze time is 5～8min simultaneously; The small product size density that suppresses is 1.68～1.71g/cm
3Its length 500～800mm after the moulding, width 120～180, thickness 85～115mm;
(4) roasting: the product of step (3) compression moulding is carried out roasting in the internal combustion type stoving oven, roasting 320h, top temperature is 1250 ℃; Its segmental averaging heat-up rate such as following table:
Segmentation average heating speed during table 1. roasting
| Temperature rise period | Temperature range (℃) | Temperature rise speed (℃/h) | Time length (h) | Remarks |
| 1 2 3 4 5 6 7 8 9 | 130～350 351～400 401～500 501～600 601～700 701～800 801～1000 1001～1250 1250 | 4.4 1.6 1.4 2.0 4.0 5.0 8.0 8.3 | 50 30 70 50 25 20 25 30 20 | 130 ℃ of constant temperature of initial temperature in the stove |
Here need to prove: temperature (starting temperature) is 130 ℃ in the intensification forehearth; Calculate the average heating speed value and be behind the radix point one, take four houses five to advance for second; As seen from the table, initial heat-up rate is 4.4 ℃/h, rises to 350 ℃ with 50h; From 351～400 ℃, 401～500 ℃, 501～600 ℃, 1.4～2.0 ℃/h of average heating speed, shared 150h (slowly heat up, very fast to prevent the pitch volatilization, influence quality product); From 601～700 ℃, 701～800 ℃, 4.0～5.0 ℃/h of average heating speed, shared 45h; From 801～1000 ℃, 1001～1250 ℃, 8.0～8.3 ℃/h of average heating speed, shared 55h; Continue to keep 20h when being warming up to 1250 ℃.
(5) dipping: the product behind step (4) roasting naturally cooling, take out and put into the high-pressure impregnation jar dipping that medium temperature coal pitch is housed, its pressure 10～15bar, be 2～2.5h clamping time, 140～190 ℃ of impregnating autoclave temperature;
(6) re-baking: the product that above-mentioned steps (5) dipping is good is put into and is carried out re-baking in the external combustion type re-baking tunnel furnace, and its roasting time is 77h, and maturing temperature is 800 ℃;
(7) double-steeping: the product through step (6) re-baking carries out double-steeping again, its pressure 10～15bar, clamping time 2～2.5h, 140～190 ℃ of impregnating autoclave temperature;
(8) three roastings: the product through step (7) double-steeping carries out three roastings in external combustion type re-baking tunnel furnace, its roasting time is 77h, and maturing temperature is 800 ℃;
(9) greying, product processing
To put into greying in the graphitizing furnace through the intermediates after (8) three roastings of step, its temperature is 2900 ℃, send electric weight 5000kwh; Treat that greying finishes to naturally cool to after the normal temperature, the greying blank is processed into high heat conduction, the high strength fritter graphite brick of 240～380mm * 115～145mm * needed different size of 76.5～102mm.
Above-mentioned ultra-large type blast furnace high conductive high strength fritter graphite brick, its volume density 1.78～1.82g/cm
3, apparent porosity is 12.00～15.00%, and ultimate compression strength is 38.00～43.00Mpa, and thermal conductivity is 170～185W/m.K under the room temperature.
Aforesaid high conductive high strength fritter graphite brick is used for the method for ultra-large type blast furnace lining, add the high heat conduction of described different size, high strength fritter graphite brick with the concentrated type copper cooling plate, peace traditional method masonry heater lining structure, the high thermal conductivity layer in zone more than blast-furnace tuyere.
High conductive high strength graphite brick of the present invention is compared with existing graphite brick, and one of them characteristic is brick body little (fritter graphite bricks), as the blast furnace stack liner, concentrates on the above zone of blast-furnace tuyere.In order to reach under the condition of strengthening smelting, furnace life adopts high conductive high strength fritter graphite brick of the present invention to combine with the reinforcement cooling apparatus in design and constitutes furnace lining structure in the life-span target more than 20 years.Its basic dominant ideas are: based on the theory of refractory materials " high heat conduction, anti-thermal shock ", can form the whole angle of good high thermal conductivity layer from inner lining refractory and high strength cooling equipment (as: copper cooling plate) simultaneously, adopt " concentrated type copper cooling plate+fritter graphite brick " to constitute furnace lining structure.Wherein, the copper cooling plate of high cooling intensity+described fritter graphite brick of the present invention; the common heat-conducting layer that constitutes; to help to solidify the residue skin, and then reduce temperature again, also stop the erosion of harmful element in the stove simultaneously in the hot side formation of furnace lining; furnace lining and cooling system are protected; have preferably that the oneself makes lining, self-protection ability is finally realized long-life purpose of blast furnace.Adopt the graphite brick of different specification size according to different sites.With traditional building method, link together with its brick body, form graphite brick bricking structure with integrity.
The above-mentioned ultra-large type blast furnace that makes detects through relevant department with high heat conduction, high strength fritter graphite brick, its result's example following table:
Table 2. ultra-large type blast furnace is used high conductive high strength fritter graphite brick detected result (specification 240～380mm * 115～145mm * 76.5～102mm) of fritter graphite brick
| Analysis project | Unit | Analytical results | Test method standard |
| Volume density | g/cm 3 | 1.78～1.82 | YB/T119-1997 |
| Ultimate compression strength | Mpa | 38.00～43.00 | GB/T1431-1985 |
| Apparent porosity | ％ | 12.00～15.00 | YB/T908-1997 |
| Folding strength (20 ℃) | Mpa | 22.00～28.00 | GB/T3074.1-1982 |
| Fixed carbon | ％ | 99.50～99.70 | GB/T3521-1995 |
| Fe | ％ | 0.01～0.03 | GB/T3521-1995 |
| Ash content | ％ | 0.15～0.02 | GB/T1429-1985 |
| Alkali-resistivity | U | YB/T5213-1993 |
| The coefficient of expansion | 10 -6/K | 2.00～3.00 | GB/T3074.4-1982 |
| Oxidation-resistance | mg/g.h | 1.50～5.00 | GB/T3074.3-1982 |
| Thermal conductivity under the room temperature | W/m.K | 170～185 | GB/T8722-1988 |
| 200 ℃ of thermal conductivitys | W/m.K | 140～160 | GB/T8722-1988 |
| Folding strength (1300 ℃ * 0.5h) | Mpa | 25.00～30.00 | GB/T13243-1991 |
| Heavily burn line and change (1400 ℃ * 4h, under shielding gas) | ％ | ±0.2 | GB/T5988-1986 |
High conductive high strength graphite brick for ultralarge blast furnace of the present invention shows compared with prior art, have significant technical progress and obvious effects through the practical application of relevant department's detection, Baoshan Iron ﹠ Steel Co., Ltd and Taiyuan Iron ﹠ Steel (Group) Co.:
(1) ultra-large type blast furnace of the present invention high conductive high strength fritter graphite brick (240～380mm * 115～145mm * 76.5～102mm), its volume density 1.78～1.82g/cm
3, apparent porosity is 12.00～15.00%, and ultimate compression strength is 38.00～43.00Mpa, and thermal conductivity is 170～185W/m.K under the room temperature.
(2) after being used in the above field liner of blast-furnace tuyere, the erosional competency that can resist the washing away of the gentle stream of material, wearing and tearing and molten iron, slag is strong; And the copper cooling plate (the copper coin cooling layer cools off with water coolant) with high cooling intensity adds that graphite brick has constituted high thermal conductivity layer jointly; help like this to solidify residue in the hot side formation of furnace lining; and then reduced the temperature of furnace lining; also stoped simultaneously the erosion of harmful element in the stove; furnace lining and cooling system are protected, and having had preferably, the oneself makes lining, self-protection ability.
(3) the heat-shock resistance ability is better than existing graphite brick greatly.
(4) on the ultra-large type blast furnace, use, can prolong the work-ing life of blast furnace, make to reach 20 years the work-ing life of blast furnace.
It is raw material that the present invention adopts broken with refinery coke, pitch coke and graphite, adds the intensity that a certain amount of pitch coke increases graphite brick, adds the broken thermal conductivity that improves graphite brick of certain graphite.Simultaneously, the present invention has adopted the fine particle prescription, and adopts two dipping and three sinter process processes in the middle of technological process, and the intensity of graphite brick is improved.In the middle of graphitizing process, improve graphited temperature and reached 2900 ℃, improved and sent electric weight to reach 5000kwh/t, the thermal conductivity of graphite brick is significantly improved.
Description of drawings
Figure is a process flow diagram of the present invention, wherein
1
b-single-steeping 2
b-double-steeping 1
a-bakes to burn the article
2
a-re-baking 3
a-three roastings
Embodiment
Embodiment 1
Add the 100kg pitch coke in the 500kg refinery coke, it is broken to add 52.2kg graphite again, through fragmentation, part abrasive dust, sieve according to the certain particle level, and its granulometric composition and distribute as follows:
In mm is unit, the 6.52kg of 2≤granularity＜3 (1%); 1≤granularity＜2 are 71.74kg (11%); 0.5≤granularity＜1 is 65.22kg (10%); 0.075≤granularity＜0.5 is 136.95kg (21%); 0.075 following particle is 371.74kg (57%);
From accompanying drawing as seen, put above-mentioned powder into mixed dried the mixing in the pot of pinching, the time is 30min, 105 ℃ of temperature.Add medium temperature coal pitch 182.61kg then, carry out wet mixing under same temperature, mixing time is 40min, 160 ℃ of the temperature that thickener takes the dish out of the pot.Through being cooled to about 100 ℃, put into moulding on the shaper then, preload pressure 16Mpa, squeeze time 6min, the small product size density 1.69g/cm that suppresses
3, its specification 500mm * 120mm * 85mm.The above-mentioned product that suppresses is put into stoving oven carry out bakes to burn the article 1
a, roasting time is 320h, and top temperature is 1250 ℃, and its concrete segmental averaging heat-up rate is: be warming up to 350 ℃ on the basis that the 1st section intensification is 130 ℃ of temperature in the roasting forehearth (starting temperature), need 50h, average heating speed is 4.4 ℃/h; The 2nd section intensification is to be warming up to 400 ℃ from 351, needs 30h, and average heating speed is 1.6 ℃/h; The 3rd section intensification is to be warming up to 500 ℃ from 401 ℃, needs 70h, and average heating speed is 1.4 ℃/h; The 4th section intensification is to rise to 600 ℃ from 501, needs 50h, and average heating speed is 2.0 ℃/h; The 5th section intensification is to rise to 700 ℃ from 601 ℃, needs 25h, and average heating speed is 4.0 ℃/h; The 6th section intensification is to rise to 800 ℃ from 701 ℃, needs 20h, and average heating speed is 5.0 ℃/h; The 7th section intensification is to rise to 1000 ℃ from 801, needs 25h, and average heating speed is 8.0 ℃/h; The 8th section intensification is to rise to 1250 ℃ from 1001 ℃, needs 30h, and average heating speed is 8.3 ℃/h; The 9th section is to keep 20h in 1250 ℃ of constant temperature; So shared 320h.Behind above-mentioned roasting, naturally cooling, taking-up is put into the high-pressure impregnation jar and is carried out single-steeping 1
b, impregnation pressure 12bar, clamping time 2.3h, 150 ℃ of impregnating autoclave temperature.Take out then and put into external combustion type re-baking tunnel furnace and carry out re-baking 2
a, roasting time is 77h, maturing temperature is 800 ℃.Carry out double-steeping 2 after the cooling again
bWith three roastings 3
aThe processing condition of double-steeping and three roastings, the same respectively once processing condition of dipping, re-baking; Put into graphitizing furnace at last and carry out greying, 2900 ℃ of graphitization temperatures send electric weight 5000kwh/t.After treating that greying finishes to naturally cool to normal temperature, the greying blank is become 240mm * 115mm * 76.5mm graphite brick through machine tooling.
Embodiment 2
Add the 50kg pitch coke in the 250kg refinery coke, it is broken to add 22.58kg graphite again, through fragmentation, part abrasive dust, sieve according to the certain particle level, and its granulometric composition and distribute as follows:
Is 1.61kg (0.5%) more than or equal to 2mm less than 3mm, is 38.71kg (12%) more than or equal to 1mm less than 2mm, is 35.48kg (11%) more than or equal to 0.5mm less than 1mm, is 59.68kg (18.5%) more than or equal to 0.075mm less than 0.5mm, the following 187.10kg of 0.075mm (58%).
From accompanying drawing as seen, above-mentioned powder is done mixed pinching, the time is 35min, 108 ℃ of temperature.Add medium temperature coal pitch 93.55kg then, carry out wet mixing under same temperature, mixing time is 45min, 158 ℃ of the temperature that thickener takes the dish out of the pot.Then through being cooled to about 100 ℃, put it on the shaper in the moulding preload pressure 17Mpa, squeeze time 5min, the small product size density 1.70g/cm that suppresses
3, its specification 800mm * 180mm * 115mm.The product that suppresses is put into stoving oven carry out bakes to burn the article 1
aRoasting time is 320h, top temperature is 1250 ℃, its concrete segmental averaging heat-up rate is: be warming up to 350 ℃ on the basis that the 1st section intensification is 130 ℃ of temperature in the roasting forehearth (starting temperature), need 50h, average heating speed is that the 2nd section intensification of 4.4 ℃/h is to be warming up to 400 ℃ from 351 ℃, needs 30h, and average heating speed is 1.6 ℃/h; The 3rd section intensification is to be warming up to 500 ℃ from 401 ℃, needs 70h, and average heating speed is 1.4 ℃/h; The 4th section intensification is to rise to 600 ℃ from 501 ℃, needs 50h, and average heating speed is 2.0 ℃/h; The 5th section intensification is to rise to 700 ℃ from 601 ℃, needs 25h, and average heating speed is 4.0 ℃/h; The 6th section intensification is to rise to 800 ℃ from 701 ℃, needs 20h, and average heating speed is 5.0 ℃/h; The 7th section intensification is to rise to 1000 ℃ from 801 ℃, needs 25h, and average heating speed is 8.0 ℃/h; The 8th section intensification is to rise to 1250 ℃ from 1001, needs 30h, and average heating speed is 8.3 ℃/h; The 9th section is to keep 20h in 1250 ℃ of constant temperature; So shared 320h.Behind above-mentioned roasting naturally cooling, taking-up is put into the high-pressure impregnation jar again and is carried out single-steeping 1
b, impregnation pressure 13bar, clamping time 2.5h, 160 ℃ of impregnating autoclave temperature; Put into external combustion type re-baking tunnel furnace then and carry out re-baking 2
a, roasting time is 77h, maturing temperature is 800 ℃.And then carry out double-steeping 2
bWith three roastings 3
a(its double-steeping is with above-mentioned single-steeping processing condition, three roastings processing condition with above-mentioned re-baking); Put into graphitizing furnace at last and carry out greying, 2900 ℃ of graphitization temperatures send electric weight 5000kwh/t.After treating that greying finishes to naturally cool to normal temperature, the greying blank is become 380mm * 145mm * 102mm graphite brick with machine tooling.
Embodiment 3 (high heat conduction, high strength fritter graphite brick are in the application of ultra-large type blast furnace)
High conductive high strength graphite brick of the present invention is used for the application of ultra-large type blast furnace lining, with concentrated type copper cooling plate+high heat conduction of described different size fritter, high strength graphite brick, in the above zone of blast-furnace tuyere,, and form high thermal conductivity layer according to traditional method masonry heater lining structure.
Blast furnace lining is made up of concentrated type copper cooling plate and high heat conduction of the present invention, high strength fritter graphite brick.So; the copper cooling plate of high cooling intensity (the copper coin cooling layer cools off with water coolant) adds that described fritter graphite brick has constituted high thermal conductivity layer jointly; help like this to solidify residue in the hot side formation of furnace lining; and then reduced the temperature of furnace lining; also stoped simultaneously the erosion of harmful element in the stove; furnace lining and cooling system are protected, and the oneself makes lining, self-protection ability to make it have preferably.The final long lifetime of realizing blast furnace.
The building method of above-mentioned graphite brick, links together with other brick body after clay is smeared in the brick surface with traditional method again, forms the graphite brick bricking structure with integrity.
Claims (5)
1, a kind of ultra-large type blast furnace is with high conductive high strength fritter graphite brick, and in 100 mass parts raw materials, mixing Jiao burnt and that pitch coke is formed of raw material PetroChina Company Limited. accounts for 92～94%, and graphite is broken to account for 6～8%, and wherein the mass ratio of refinery coke and pitch coke is 5: 1; The medium temperature coal pitch consumption is 26～30% of a raw materials quality; Above-mentioned raw material is through pulverizing, part abrasive dust, sieve according to the certain particle level, its granulometric composition and being distributed as: be unit in mm, 2≤particle diameter＜3 less than 2%; 1≤particle diameter＜2 are 11 ± 2%; 0.5≤particle diameter＜1 is 10 ± 2%; 0.075 following particle is 57 ± 3%; All the other are the particle of 0.075≤particle diameter＜0.5; Make the fritter graphite brick of 240～380mm * 115～145mm * 76.5～102mm.
2, ultra-large type blast furnace according to claim 1 high conductive high strength fritter graphite brick, its volume density 1.78～1.82g/cm
3, apparent porosity is 12.00～15.00%, and ultimate compression strength is 38.00～43.00Mpa, and thermal conductivity is 170～185W/m.K under the room temperature.
3, the ultra-large type blast furnace as claimed in claim 1 production method of high conductive high strength fritter graphite brick, it is that following steps are formed:
(1) batching: in 100 mass parts raw materials, mixing Jiao burnt and that pitch coke is formed of raw material PetroChina Company Limited. accounts for 92～94%, and graphite is broken to account for 6～8%, and wherein the mass ratio of refinery coke and pitch coke is 5: 1; The medium temperature coal pitch consumption is 26～30% of a raw materials quality; Above-mentioned raw materials is through pulverizing, part abrasive dust, sieve according to the certain particle level, its granulometric composition and distribute as follows: be unit in mm, 2≤particle diameter＜3 less than 2%; 1≤particle diameter＜2 are 11 ± 2%; 0.5≤particle diameter＜1 is 10 ± 2%; 0.075 following particle is 57 ± 3%; All the other are the particle of 0.075≤particle diameter＜0.5;
(2) mixed pinching:, mix 30～35min in mixing to pinch to do in the pot, its dried 105 ± 5 ℃ of temperature of mixing with the raw material of above-mentioned steps (1) preparation; 26～30% the medium temperature coal pitch that adds the above-mentioned raw materials total mass then, wet mixing 40～45min under uniform temp, the temperature 153-165 that thickener takes the dish out of the pot ℃;
(3) die mould: the raw material that mixes after pinching through step (2) carries out moulding in forming press, its preload pressure is 15～18Mpa, and squeeze time is 5～8min simultaneously; The small product size density that suppresses is 1.68g～1.71/cm
3Its length 500～800mm after the moulding, width 120～180mm, thickness 85～115mm;
(4) roasting: will carry out bakes to burn the article (1a) in the internal combustion type stoving oven through the product of step (3) compression moulding, roasting time is 320 hours, and top temperature is 1250 ℃;
(5) dipping: the product behind step (4) roasting naturally cooling, taking-up is put into the high-pressure impregnation jar that medium temperature coal pitch is housed and is carried out single-steeping (1
b), its pressure 10-15bar, be 2～2.5h clamping time, 140-190 ℃ of impregnating autoclave temperature;
(6) re-baking: the product that above-mentioned (5) dipping is good is put into and is carried out re-baking (2a) in the external combustion type re-baking tunnel furnace, and its roasting time is 77h, and maturing temperature is 800 ℃;
(7) double-steeping: the product through above-mentioned steps (6) re-baking carries out double-steeping (2 again
b), its process and processing condition are flooded identical with the first time;
(8) three roastings: the product through above-mentioned steps (7) double-steeping carries out three roastings (3a), the same re-baking of its process and processing condition in external combustion type re-baking tunnel furnace;
(9) greying, product processing
To put into greying in the graphitizing furnace through the intermediates after three roastings of above-mentioned steps (8), its temperature is 2900 ℃, send electric weight 5000kwh/t.After treating that greying finishes to naturally cool to normal temperature, the greying blank is processed into the fritter graphite brick of needed 240～380mm * 115～145mm * 76.5～102mm specification.
4, ultra-large type blast furnace according to claim 2 high conductive high strength fritter graphite brick, its volume density 1.78～1.82g/cm
3, apparent porosity is 12.00～15.00%, and ultimate compression strength is 38.00～43.00Mpa, and thermal conductivity is 170～185W/m.K under the room temperature.
5, high conductive high strength fritter graphite brick as claimed in claim 1 is used for the method for ultra-large type blast furnace lining, with concentrated type copper cooling plate+high heat conduction of described different size, high strength fritter graphite brick, masonry heater lining structure in the zone forms high thermal conductivity layer more than blast-furnace tuyere.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101316204A CN100457681C (en) | 2006-11-07 | 2006-11-07 | High conductive high strength graphite brick for ultralarge blast furnace, its production technology and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101316204A CN100457681C (en) | 2006-11-07 | 2006-11-07 | High conductive high strength graphite brick for ultralarge blast furnace, its production technology and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1948219A true CN1948219A (en) | 2007-04-18 |
| CN100457681C CN100457681C (en) | 2009-02-04 |
Family
ID=38017861
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101316204A Expired - Fee Related CN100457681C (en) | 2006-11-07 | 2006-11-07 | High conductive high strength graphite brick for ultralarge blast furnace, its production technology and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100457681C (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101708994A (en) * | 2009-12-01 | 2010-05-19 | 陕西盛华冶化有限公司 | Masonry material for ladle of ferro-silicon-calcium electric furnace |
| CN101798080A (en) * | 2010-03-01 | 2010-08-11 | 中钢集团吉林炭素股份有限公司 | Method for manufacturing graphite electrode joint material |
| CN102060293A (en) * | 2010-11-16 | 2011-05-18 | 中钢集团吉林炭素股份有限公司 | Method for preparing binder-free graphite product |
| CN101381232B (en) * | 2007-06-07 | 2012-06-27 | 揖斐电株式会社 | Graphite material and a method of producing graphite material |
| CN102674853A (en) * | 2012-05-15 | 2012-09-19 | 河南方圆炭素集团有限公司 | Graphite core for nickel iron electric furnace door |
| CN101993246B (en) * | 2009-08-27 | 2013-02-20 | 河南方圆炭素集团有限公司 | Thermal conductive graphite blocks for blast-furnace bottom and hearth |
| CN106278265A (en) * | 2016-07-28 | 2017-01-04 | 芜湖迈特电子科技有限公司 | High heat-conductivity conducting graphite heat-conducting fin fine-processing technique |
| CN106744919A (en) * | 2017-01-17 | 2017-05-31 | 韩俊培 | A kind of production technology of polycrystalline silicon base plate special graphite |
| CN107365154A (en) * | 2017-08-28 | 2017-11-21 | 程安娜 | Life carbon material process is manufactured with the machining chips of graphitization carbon |
| CN109702156A (en) * | 2019-01-31 | 2019-05-03 | 青岛卓越碳素制品有限公司 | A kind of high-speed rail conducting wire alloyed copper bar continuous cast crystallizer and its production technology |
| CN109879668A (en) * | 2019-04-19 | 2019-06-14 | 平顶山东方碳素股份有限公司 | A kind of composition of raw materials and its preparation flow for silicon carbide blast furnace carbon brick |
| CN109970458A (en) * | 2017-12-28 | 2019-07-05 | 蓝星硅材料有限公司 | A kind of modified carbonaceous chute and preparation method thereof |
| CN113372119A (en) * | 2020-04-28 | 2021-09-10 | 吉林炭素有限公司 | Design method for dry material particle size composition in graphite electrode body formula |
| CN115505665A (en) * | 2022-10-08 | 2022-12-23 | 中冶华天南京工程技术有限公司 | High-efficiency long-life furnace hearth tuyere combined brick |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5860672A (en) * | 1981-10-05 | 1983-04-11 | 三菱化学株式会社 | Carbonaceous refractory formed body |
| JPS59121107A (en) * | 1982-12-27 | 1984-07-13 | Ibiden Co Ltd | Manufacture of carbon electrode rod |
| JPS62182107A (en) * | 1986-02-05 | 1987-08-10 | Nippon Light Metal Co Ltd | Production of high-density carbon material |
| CN1048834A (en) * | 1990-05-18 | 1991-01-30 | 东新电碳厂 | Method for producing carbon material |
| CN100350077C (en) * | 2004-04-15 | 2007-11-21 | 方大炭素新材料科技股份有限公司 | Graphitic cathode carbon block for aluminium electrolytic bath and its producing method |
| CN1247451C (en) * | 2004-05-27 | 2006-03-29 | 兴和兴永碳素有限公司 | High density and intensity abrasive resistant graphite materials and producing process thereof |
| CN100480431C (en) * | 2004-07-02 | 2009-04-22 | 贵阳铝镁设计研究院 | Production process for graphitized cathode |
| CN1311476C (en) * | 2005-04-21 | 2007-04-18 | 王占武 | Sliding plate for pantograph of power locomotive and its mfg. method |
-
2006
- 2006-11-07 CN CNB2006101316204A patent/CN100457681C/en not_active Expired - Fee Related
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101381232B (en) * | 2007-06-07 | 2012-06-27 | 揖斐电株式会社 | Graphite material and a method of producing graphite material |
| CN101993246B (en) * | 2009-08-27 | 2013-02-20 | 河南方圆炭素集团有限公司 | Thermal conductive graphite blocks for blast-furnace bottom and hearth |
| CN101708994A (en) * | 2009-12-01 | 2010-05-19 | 陕西盛华冶化有限公司 | Masonry material for ladle of ferro-silicon-calcium electric furnace |
| CN101798080A (en) * | 2010-03-01 | 2010-08-11 | 中钢集团吉林炭素股份有限公司 | Method for manufacturing graphite electrode joint material |
| CN101798080B (en) * | 2010-03-01 | 2012-10-03 | 中钢集团吉林炭素股份有限公司 | Method for manufacturing graphite electrode joint material |
| CN102060293A (en) * | 2010-11-16 | 2011-05-18 | 中钢集团吉林炭素股份有限公司 | Method for preparing binder-free graphite product |
| CN102060293B (en) * | 2010-11-16 | 2012-07-25 | 中钢集团吉林炭素股份有限公司 | Method for preparing binder-free graphite product |
| CN102674853A (en) * | 2012-05-15 | 2012-09-19 | 河南方圆炭素集团有限公司 | Graphite core for nickel iron electric furnace door |
| CN102674853B (en) * | 2012-05-15 | 2013-09-04 | 河南方圆炭素集团有限公司 | Graphite core for nickel iron electric furnace door |
| CN106278265B (en) * | 2016-07-28 | 2019-03-05 | 芜湖迈特电子科技有限公司 | High heat-conductivity conducting graphite heat-conducting fin fine-processing technique |
| CN106278265A (en) * | 2016-07-28 | 2017-01-04 | 芜湖迈特电子科技有限公司 | High heat-conductivity conducting graphite heat-conducting fin fine-processing technique |
| CN106744919A (en) * | 2017-01-17 | 2017-05-31 | 韩俊培 | A kind of production technology of polycrystalline silicon base plate special graphite |
| CN107365154A (en) * | 2017-08-28 | 2017-11-21 | 程安娜 | Life carbon material process is manufactured with the machining chips of graphitization carbon |
| CN109970458A (en) * | 2017-12-28 | 2019-07-05 | 蓝星硅材料有限公司 | A kind of modified carbonaceous chute and preparation method thereof |
| CN109702156A (en) * | 2019-01-31 | 2019-05-03 | 青岛卓越碳素制品有限公司 | A kind of high-speed rail conducting wire alloyed copper bar continuous cast crystallizer and its production technology |
| CN109702156B (en) * | 2019-01-31 | 2020-08-11 | 青岛卓越碳素制品有限公司 | High-speed rail conductor alloy copper rod continuous casting crystallizer and production process thereof |
| CN109879668A (en) * | 2019-04-19 | 2019-06-14 | 平顶山东方碳素股份有限公司 | A kind of composition of raw materials and its preparation flow for silicon carbide blast furnace carbon brick |
| CN113372119A (en) * | 2020-04-28 | 2021-09-10 | 吉林炭素有限公司 | Design method for dry material particle size composition in graphite electrode body formula |
| CN113372119B (en) * | 2020-04-28 | 2022-12-30 | 吉林炭素有限公司 | Design method for particle size composition of dry materials in graphite electrode body formula |
| CN115505665A (en) * | 2022-10-08 | 2022-12-23 | 中冶华天南京工程技术有限公司 | High-efficiency long-life furnace hearth tuyere combined brick |
| CN115505665B (en) * | 2022-10-08 | 2024-07-16 | 中冶华天南京工程技术有限公司 | High-efficiency long-life hearth tuyere combined brick |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100457681C (en) | 2009-02-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100457681C (en) | High conductive high strength graphite brick for ultralarge blast furnace, its production technology and application | |
| CN107973610B (en) | Silicon carbide ramming mass taking waste silicon carbide saggar as main raw material | |
| CN108484138A (en) | A kind of sliding plate brick and preparation method thereof adding composite alumina micro mist and carbon source | |
| CN103880448B (en) | A kind of casting is large-scale from combined silicon carbide product | |
| CN106986649B (en) | A kind of high-performance SiC/W cermet combining nozzle and preparation method thereof | |
| CN109836136A (en) | A kind of low-carbon aluminium-magnesia carbon brick and preparation method thereof | |
| CN101503302B (en) | Carboneous fire-resistant material for furnace brick lining and preparation thereof | |
| CN109081697A (en) | It is a kind of to prepare B4The method of C/SiC composite ceramic | |
| CN107602099B (en) | Low-carbon sliding plate brick containing modified graphite for pushing off slag of converter and preparation method thereof | |
| CN108083765B (en) | Low-heat-conduction anti-stripping brick and preparation method thereof | |
| CN111362674B (en) | Acid-resistant corundum ramming mass and method for manufacturing acid regenerator nozzle by using same | |
| CN112358302B (en) | Self-repairing anhydrous stemming | |
| CN107500748B (en) | Magnesia-alumina spinel-graphene refractory material product and preparation process thereof | |
| CN101591190B (en) | Novel Si3N4-SiC-C refractory brick for sidewall of aluminum electrolysis bath and preparation method thereof | |
| CN100335446C (en) | Compound Sialon-corundum fire brick series and its production process | |
| CN100396648C (en) | Novel semi-graphitization silicon nitride carbide brick and its production method | |
| CN100497244C (en) | Composite carbon brick and its production | |
| CN103979981A (en) | A large-size semi-graphite silicon carbide carbon brick and a production process thereof | |
| CN107244930A (en) | A kind of resistance to molten iron corrodes blast furnace carbon brick and preparation method thereof | |
| CN1107662C (en) | Blast furnace taphole stemming with low water content and its preparing method | |
| CN1296318C (en) | Soper microporous carbon brick for furnace lining and its producing method | |
| CN1304329C (en) | High heat conductivity carbon brick for blast furnace and its producing method | |
| CN1944328A (en) | Novel moulded light carbon brick and its producing method | |
| CN111908931A (en) | Low-carbon aluminum silicon carbide carbon brick containing nano carbon and preparation method thereof | |
| JP2018127376A (en) | Refractory brick |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090204 Termination date: 20121107 |