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CN1804075A - Method for manufacturing anti-corrosion alloy brass H65 and copper belt thereof - Google Patents

Method for manufacturing anti-corrosion alloy brass H65 and copper belt thereof Download PDF

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Publication number
CN1804075A
CN1804075A CN 200610042012 CN200610042012A CN1804075A CN 1804075 A CN1804075 A CN 1804075A CN 200610042012 CN200610042012 CN 200610042012 CN 200610042012 A CN200610042012 A CN 200610042012A CN 1804075 A CN1804075 A CN 1804075A
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China
Prior art keywords
brass
annealing
corrosion
corrosion alloy
alloy
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CN 200610042012
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Chinese (zh)
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CN100389218C (en
Inventor
刘洪勤
彭作华
常保平
孟祥东
赵新建
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HEZE GUANGYUAN COPPER STRIP CO Ltd
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HEZE GUANGYUAN COPPER STRIP CO Ltd
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Priority to CNB2006100420126A priority Critical patent/CN100389218C/en
Publication of CN1804075A publication Critical patent/CN1804075A/en
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Abstract

The corrosion-resistant alloy H65 comprises 63.5-68% Cu, 0.01-0.2% Sn or 0.01-0.07% P as microelement, and Zn. The copper strap is manufactured by: designing alloy, preparing, level continuous casting, milling surface, coarse rolling, intermediate annealing, precise rolling, shearing, and packing. This product has can be used to vehicle radiator and cooling pipe to avoid pollution fresh water and prolong service time.

Description

The making method of corrosion alloy brass H65 and copper strips thereof
(1) technical field under
The present invention relates to a kind of alloy, the making method of particularly a kind of corrosion alloy brass H65 and copper strips thereof.
(2) background technology
At present, brass H65 is made up of the zinc of 63.5~68%Cu and surplus, belongs to common Mock platina.Dezincification corrosion very easily takes place in common Mock platina, along with constantly riseing of copper valency, is to reduce manufacturing cost, and the used thickness of copper strips is also at continuous attenuate, and this has had a strong impact on the work-ing life of subsequent product.
(3) content of the present invention
The present invention is in order to remedy the deficiencies in the prior art, provides a kind of and have better erosion resistance, improved the corrosion alloy brass H65 in work-ing life of product and the making method of copper strips thereof.
The present invention is achieved through the following technical solutions:
A kind of corrosion alloy brass H65, its special character is: be made up of following components in weight percentage: copper: 63.5~68%; Trace element: tin 0.01~0.2% and/or phosphorus 0.01~0.07%; Surplus is a zinc.
Corrosion alloy brass H65 of the present invention, described trace element are tin, and weight percent is 0.01~0.2%.
Corrosion alloy brass H65 of the present invention, described trace element are phosphorus, and weight percent is 0.01~0.07%.
Corrosion alloy brass H65 of the present invention, described trace element are tin 0.01~0.2% and phosphorus 0.01~0.07%.
The making method of corrosion alloy brass H65 copper strips of the present invention can adopt following concrete steps: alloy designs → batching → horizontal casting → mill face → roughing → process annealing → finish rolling → shearing, pack.
The making method of corrosion alloy brass H65 copper strips of the present invention also can adopt following concrete steps: alloy designs → batching → D.C.casting → hot rolling → mill face → roughing → process annealing → finish rolling → shearing, pack.
The present invention is on the basis of market brass H65, reaches the corrosion resistance nature that improves alloy by adding micro-tin, phosphorus.Tin element and phosphoric can exist simultaneously, but also Individual existence.
The present invention is mainly used in and makes the automobile radiators cooling tube, and the market brass H65 of the common usefulness of this alloy ratio has better erosion resistance, can avoid polluting fresh water environment, has improved the work-ing life of product greatly.
(4) embodiment
Embodiment 1:
This embodiment is made up of following components in weight percentage: copper: 63.5%; Trace element: tin 0.01%; Surplus is a zinc.As follows with its process of making copper strips: as to pass through alloy designs earlier, prepare burden by above component ratio, behind horizontal casting, produce the thick strand of 16mm, through milling the face operation, about 13.7mm is thick then, roughing again (1.3mm is thick), then adopt repeatedly process annealing softening and cold rolling, annealing process is 450~500 ℃ of annealing temperatures, annealing time 4~5 hours, and finished product is rolling then, finished product thickness is 0.09mm, shears at last, packs and form finished product.
Embodiment 2:
This embodiment is made up of following components in weight percentage: copper: 68%; Trace element: tin 0.2%; Surplus is a zinc.As follows with its process of making copper strips: as to pass through alloy designs earlier, prepare burden by above component ratio, behind horizontal casting, produce the thick strand of 16mm, through milling the face operation, about 13.7mm is thick then, roughing again (1.3mm is thick), then adopt repeatedly process annealing softening and cold rolling, annealing process is 450~500 ℃ of annealing temperatures, annealing time 4~5 hours, and finished product is rolling then, finished product thickness is 0.18mm, shears at last, packs and form finished product.
Embodiment 3:
This embodiment is made up of following components in weight percentage: copper: 63.5%; Trace element: phosphorus 0.01%; Surplus is a zinc.As follows with its process of making copper strips: as to pass through alloy designs earlier, prepare burden by above component ratio, behind horizontal casting, produce the thick strand of 16mm, through milling the face operation, about 13.7mm is thick then, roughing again (1.3mm is thick), then adopt repeatedly process annealing softening and cold rolling, annealing process is 450~500 ℃ of annealing temperatures, annealing time 4~5 hours, and finished product is rolling then, finished product thickness is 0.14mm, shears at last, packs and form finished product.
Embodiment 4:
This embodiment is made up of following components in weight percentage: copper: 65%; Trace element: phosphorus 0.07%; Surplus is a zinc.As follows with its process of making copper strips: as to pass through alloy designs earlier, prepare burden by above component ratio, behind D.C.casting, produce 180 thick ingot castings, through hot rolling (14.5mm is thick), then through milling the face operation, about 13.7mm is thick, roughing again (1.3mm is thick) then adopts repeatedly process annealing softening and cold rolling, and annealing process is 450~500 ℃ of annealing temperatures, annealing time 4~5 hours, finished product is rolling then, and finished product thickness is 0.16mm, shears at last, packs and form finished product.
Embodiment 5:
This embodiment is made up of following components in weight percentage: copper: 67%; Trace element: tin 0.1 and phosphorus 0.03%; Surplus is a zinc.As follows with its process of making copper strips: as to pass through alloy designs earlier, prepare burden by above component ratio, behind D.C.casting, produce the thick ingot casting of 180mm, through hot rolling (14.5mm is thick), then through milling the face operation, about 13.7mm is thick, roughing again (1.3mm is thick) then adopts repeatedly process annealing softening and cold rolling, and annealing process is 450~500 ℃ of annealing temperatures, annealing time 4~5 hours, finished product is rolling then, and finished product thickness is 0.12mm, shears at last, packs and form finished product.
Embodiment 6:
This embodiment is made up of following components in weight percentage: copper: 68%; Trace element: tin 0.05 and phosphorus 0.07%; Surplus is a zinc.As follows with its process of making copper strips: as to pass through alloy designs earlier, prepare burden by above component ratio, behind D.C.casting, produce the thick ingot casting of 180mm, through hot rolling (14.5mm is thick), then through milling the face operation, about 13.7mm is thick, roughing again (1.3mm is thick) then adopts repeatedly process annealing softening and cold rolling, and annealing process is 450~500 ℃ of annealing temperatures, annealing time 4~5 hours, finished product is rolling then, and finished product thickness is 0.09mm, shears at last, packs and form finished product.

Claims (7)

1. a corrosion alloy brass H65 is characterized in that: be made up of following components in weight percentage: copper: 63.5~68%; Trace element: tin 0.01~0.2% and/or phosphorus 0.01~0.07%; Surplus is a zinc.
2. corrosion alloy brass H65 according to claim 1 is characterized in that: described trace element is a tin, and weight percent is 0.01~0.2%.
3. corrosion alloy brass H65 according to claim 1 is characterized in that: described trace element is a phosphorus, and weight percent is 0.01~0.07%.
4. corrosion alloy brass H65 according to claim 1 is characterized in that: described trace element is tin 0.01~0.2% and phosphorus 0.01~0.07%.
5. the making method of corrosion alloy brass H65 copper strips according to claim 1 is characterized in that: comprise following concrete steps: alloy designs → batching → horizontal casting → mill face → roughing → process annealing → finish rolling → shearing, pack.
6. the making method of corrosion alloy brass H65 copper strips according to claim 1 is characterized in that: comprise following concrete steps: alloy designs → batching → D.C.casting → hot rolling → mill face → roughing → process annealing → finish rolling → shearing, pack.
7. according to the making method of claim 5 or 6 described corrosion alloy brass H65 copper strips, it is characterized in that: in the step process annealing wherein, adopt repeatedly process annealing softening, annealing process is 450~500 ℃ * 4~5 hours.
CNB2006100420126A 2006-01-13 2006-01-13 Method for manufacturing anti-corrosion alloy brass H65 and copper belt thereof Active CN100389218C (en)

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Application Number Priority Date Filing Date Title
CNB2006100420126A CN100389218C (en) 2006-01-13 2006-01-13 Method for manufacturing anti-corrosion alloy brass H65 and copper belt thereof

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CN1804075A true CN1804075A (en) 2006-07-19
CN100389218C CN100389218C (en) 2008-05-21

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100566885C (en) * 2007-10-22 2009-12-09 倪智勇 Production method of high-conductivity oxygen-free copper strip
CN101775522A (en) * 2010-03-02 2010-07-14 十堰益民铜材有限公司 Anticorrosive copper belt for automobile water tank and horizontal continuous casting method thereof
CN102230103A (en) * 2011-04-08 2011-11-02 菏泽广源铜带股份有限公司 Alloy brass
CN102230106A (en) * 2011-04-08 2011-11-02 菏泽广源铜带股份有限公司 Corrosion resistant alloy brass
CN102230104A (en) * 2011-04-08 2011-11-02 菏泽广源铜带股份有限公司 Elastic alloy brass with high strength
CN103484718A (en) * 2013-10-10 2014-01-01 铜陵金威铜业有限公司 Lock making copper strip and preparation method thereof
CN111378869A (en) * 2020-03-25 2020-07-07 宁波金田铜业(集团)股份有限公司 Fine-grain reinforced brass strip for connector and processing method thereof

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Publication number Priority date Publication date Assignee Title
JP6803457B2 (en) 2017-03-24 2020-12-23 株式会社Ihi Abrasion resistant copper-zinc alloy and machinery using it

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2062427A (en) * 1936-08-26 1936-12-01 American Brass Co Copper-tin-phosphorus-zinc alloy
CN100457938C (en) * 2004-04-20 2009-02-04 中铝上海铜业有限公司 Nickel silver band for piezoelectric crystal oscillator housing and method for producing same

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100566885C (en) * 2007-10-22 2009-12-09 倪智勇 Production method of high-conductivity oxygen-free copper strip
CN101775522A (en) * 2010-03-02 2010-07-14 十堰益民铜材有限公司 Anticorrosive copper belt for automobile water tank and horizontal continuous casting method thereof
CN101775522B (en) * 2010-03-02 2011-09-21 十堰益民铜材有限公司 Anticorrosive copper belt for automobile water tank and horizontal continuous casting method thereof
CN102230103A (en) * 2011-04-08 2011-11-02 菏泽广源铜带股份有限公司 Alloy brass
CN102230106A (en) * 2011-04-08 2011-11-02 菏泽广源铜带股份有限公司 Corrosion resistant alloy brass
CN102230104A (en) * 2011-04-08 2011-11-02 菏泽广源铜带股份有限公司 Elastic alloy brass with high strength
CN103484718A (en) * 2013-10-10 2014-01-01 铜陵金威铜业有限公司 Lock making copper strip and preparation method thereof
CN103484718B (en) * 2013-10-10 2016-06-29 铜陵金威铜业有限公司 Lockmaking copper strips and its preparation method
CN111378869A (en) * 2020-03-25 2020-07-07 宁波金田铜业(集团)股份有限公司 Fine-grain reinforced brass strip for connector and processing method thereof

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