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CN1872920A - Super weather-proof elastic waterproof paint and production method thereof - Google Patents

Super weather-proof elastic waterproof paint and production method thereof Download PDF

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Publication number
CN1872920A
CN1872920A CN 200510042770 CN200510042770A CN1872920A CN 1872920 A CN1872920 A CN 1872920A CN 200510042770 CN200510042770 CN 200510042770 CN 200510042770 A CN200510042770 A CN 200510042770A CN 1872920 A CN1872920 A CN 1872920A
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China
Prior art keywords
agent
thickening material
emulsion
water
defoamer
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Pending
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CN 200510042770
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Chinese (zh)
Inventor
张宾
张祖槿
李军
魏晋良
窦爱云
李文强
吕志明
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YUMEN PETROLEUM ADMINISTRATION BUREAU
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YUMEN PETROLEUM ADMINISTRATION BUREAU
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Priority to CN 200510042770 priority Critical patent/CN1872920A/en
Publication of CN1872920A publication Critical patent/CN1872920A/en
Pending legal-status Critical Current

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Abstract

The invention discloses an ultra-weather-resistant elastic waterproof coating and a production method thereof. It is composed of water, auxiliary agent, pigment, filler and emulsion; wherein the auxiliary agent consists of propylene glycol, a film forming auxiliary agent, a bactericide, a flatting agent, a dispersing agent, a thickening agent, a defoaming agent, an ultraviolet absorbent and a pH regulator; the pigment is rutile type titanium dioxide; the filler consists of talcum powder, ceramic powder and light calcium carbonate; the emulsion is elastic waterproof emulsion. The production steps are two stages of slurry preparation and paint mixing, and the raw materials are prepared by the working procedures of dispersion, grinding, redispersion and the like according to the proportion. The product is coated on a concrete prefabricated member with 6-12 high pH value or a wall surface built by integrally cast concrete and concrete bricks or a cement mortar wall surface, can protect the wall surface from being eroded by wind and rain, and is particularly suitable for areas with strong ultraviolet rays.

Description

Super weather resisting elastic water proofing paint and production method thereof
Technical field
The present invention relates to a kind of super weather resisting elastic water proofing paint and production method thereof.
Background technology
The exterior coating long-term exposure is subjected to the influence of daylight, rainwater, dust storm, cold and hot variation etc. in the open air, after after a while, the outward appearance of facing ftractures, peels off, efflorescence, variable color, fade, phenomenon such as loss of gloss.Particularly in the Northwest, dry, ultraviolet ray is strong, day and night temperature is big, causes wall crazing, and building cracks is a modal problem in the current building operation quality, perplexing current construction industry for a long time always, fissured appearance not only influences the attractive in appearance of architectural coating, and can have a negative impact to buildings itself, even harm.
Summary of the invention
The purpose of this invention is to provide a kind of super weather resisting elastic water proofing paint.
Another object of the present invention provides a kind of production method of super weather resisting elastic water proofing paint.
Super weather resisting elastic water proofing paint of the present invention is made up of water, auxiliary agent, pigment, filler, emulsion; Wherein auxiliary agent is made up of propylene glycol, film coalescence aid, sterilant, flow agent, dispersion agent, thickening material, defoamer, UV light absorber, PH conditioning agent; Pigment is Rutile type Titanium Dioxide; Filler is made up of talcum powder, ceramics powder, light calcium carbonate; Emulsion is the elastic water-proof emulsion;
The weight percentage scope of each raw material is:
Water 5%-15%, propylene glycol 2%-4%, film coalescence aid 0.5%-2%,
Sterilant 0.1%-0.4%, flow agent 0.4%-0.7%, dispersion agent 0.2%-0.7%,
Thickening material 0.5%-1%, defoamer 0.1%-0.2%, UV light absorber 0.1-0.5%,
PH conditioning agent 0.1-0.2%, Rutile type Titanium Dioxide 15%-25%,
Talcum powder 5%-10%, ceramics powder 5%-15%, light calcium carbonate 5%-10% and elastic water-proof emulsion 30%-50%; Wherein defoamer is a Shanghai Hai Chuan chemical industry silicone compounds type defoamer; Dispersion agent is Luomen Hars China Co.'s anionic sodium polyacrylate salt brine solution; Flow agent is the rheology modified auxiliary agent of the solvent-free nonionic polyurethane of Luomen Hars China Co.; Film coalescence aid is U.S. Yi Shiman 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate; Sterilant is the industrial sanitas of the nitrogenous organic ring compound of Japanese Ruo Puke auxiliary agent; UV light absorber is the bright science, industry and trade 2-of company limited of Nanjing Holley hydroxyl-4-methoxy benzophenone; The PH conditioning agent is Beijing 2-of Xing Meiya chemical industry company limited amino-2 methyl isophthalic acid-1 propyl alcohol; Super weather resisting elastic water proofing paint elastic water-proof emulsion is that Luomen Hars China Co.'s self-cross linking type pure acrylic acid is an emulsion.
Thickening material is made up of thickening material 1 and thickening material 2; Thickening material 1 is formed and the type thickening material for Luomen Hars China Co.'s hydrophobically-modified alkali swelling; Thickening material 2 is Shanghai long wind auxiliary agent polyacrylic acid emulsion-type thickening material.
Each raw material preferred weight percentage composition scope of preparation super weather resisting elastic water proofing paint of the present invention is:
Water 5%-15%, propylene glycol 2%-3%, film coalescence aid 0.5%-1.5%,
Sterilant 0.1%-0.2%, flow agent 0.4%-0.7%, dispersion agent 0.2%-0.4%,
Thickening material 10.3%-0.6%, thickening material 2 0.2%-0.4%,
Defoamer 0.1%-0.2%, UV light absorber 0.2%-0.5%,
PH conditioning agent 0.1-0.2%, Rutile type Titanium Dioxide 15%-25%,
Talcum powder 800 order 5%-10%, ceramics powder 400 order 10%-12%,
Light calcium carbonate 5%-10% and elastic water-proof emulsion 40%-50%.
The optimum weight percentage composition scope of each raw material of super weather resisting elastic water proofing paint of the present invention is:
Water 10.0%, propylene glycol 2.2%, film coalescence aid 1.2%, sterilant 0.1%,
Flow agent 0.5%, dispersion agent 0.4%, thickening material 10.5%, thickening material 20.3%,
Defoamer 0.15%, UV light absorber 0.5%, PH conditioning agent 0.15%,
Rutile type Titanium Dioxide 18.0%, talcum powder 800 orders 8%,
Ceramics powder 400 orders 12.0%, light calcium carbonate 6% and elastic water-proof emulsion 40.0%.
The production method that above-mentioned each raw material is made super weather resisting elastic water proofing paint of the present invention is:
1) preparation of slurry
A, the accurate required water of weighing, auxiliary agent, pigment, filler and emulsion;
B, at first with water and sterilant mixing and stirring, rotating speed is controlled at 300 rev/mins, stirs after 10 minutes, closes dispersion machine; The amount of taking-up 20% is standby, adds dispersion agent, propylene glycol, UV light absorber, film coalescence aid then successively, and 300 rev/mins of rotating speeds disperse to get final product in 30 minutes;
2) paint
C, in above scattered base fluid, add Rutile type Titanium Dioxide, ceramics powder, talcum powder 800 orders, light calcium carbonate successively, dispersing speed transfers to 1200 rev/mins, and high speed dispersion was ground after 30 minutes, grinds 3-4 time, detect fineness requirement<35um, viscosity controller is about 70ku;
300 rev/mins of d, dispersing speed, add the good defoamer of pure-acrylic emulsion and dilution, add an amount of PH conditioning agent, pH value is controlled between the 8-9, adds the good flow agent of dilution, drips the good thickening material of dilution then, after stirring, viscosity controller is brushed on sheet glass with the wool brush about 95ku, observes bubble, particle, the levelling property of coating surface;
E, filtration connect surge pump, tighten filter screen, put into reciprocating sieve, open air compressor and filter; F, packing.
The preparation of invention, detection equipment used and preparation technology are as follows:
Plant and instrument: reactor, high speed dispersor, sand mill, scrubbing resistance instrument, stirred pot, viscometer, fineness instrument, unit elongation determinator, weather-proof instrument experimental box etc.
The mechanism of action of the present invention: paint film stretches elasticity, the reaction of utilization bridge formation technology obtains the nucleocapsid structure congeries, and is soft outer hard in the particle core shell structure, has stronger stretching, extension elasticity, the body of wall fine fisssure of effectively contending with.Weathering resistance, used UV light absorber, ultraviolet radiation is to cause the coating principal element apparent and that physicals cancerates of filming, and adds a spot of UV light absorber, can suppress or delay the generation of this process, improve the weathering resistance of filming, increase the service life.Strong antipollution, application chemical combination bridge formation technology form Abherent and film, and are difficult for being stained with dust.High antipollution, anti-aging employing sclerous reaction type emulsion form crosslinked shape and film, and the gloss fidelity is lasting, and anti-aging function is remarkable, can protect buildings for a long time.Waterproof and breathable, form have highly air-permeable can film, effectively intercept moisture but allow a small amount of turnover of water vapour, play the effect of waterproof and breathable.The one-way ventilating function: the water droplet of outside then can not enter body of wall.
Key of the present invention is to adopt self-crosslinking, silicon modification technology, has strengthened water-repellancy, emulsion particle is designed to soft nuclear monocoque can improves elasticity greatly.Another key is to have added UV light absorber, and UV light absorber is a kind of efficient anti-aging auxiliary agent of performance brilliance, can absorb the 240-340nm UV-light, stops powdering of paint; Have, the nontoxic characteristic of look shallow, tasteless, there is not combustibility, do not impair one's health.Be particularly suitable for the strong area of ultraviolet ray.The present invention not only has snappiness and good splitting resistance, the body of wall fine fisssure of can effectively contending with; but also have excellent persistence and weather resisteant; this product brushing is on the metope that the concrete precast element of the high potential of hydrogen of 6-12 or one-piece casting concrete and concrete brick are built into or on the sand-cement slurry metope; can protect metope not to be subjected to erosion by wind and rain; it has maximum provide protection to polymkeric substance, continues the rational loss of energy of yellowing and blocker simultaneously.The production technique of product of the present invention is simple, and cost is lower.And construction is simple, all can with roller coat, spraying.If metope has stain, available clear water or neutral cleaning agent are scrubbed metope gently still as new.
Embodiment
The following examples can make those skilled in the art understand the present invention better, but do not limit the present invention in any way.
Embodiment 1:
1) preparation of slurry:
A, the accurate required water of weighing, auxiliary agent, pigment, filler and emulsion,
B, at first with 100Kg water and 1kg sterilant mixing and stirring, rotating speed is controlled at 300 rev/mins, stirs after 10 minutes, closes dispersion machine.The amount of taking-up 20% is standby, adds dispersion agent 4Kg then successively, propylene glycol 22Kg, and UV light absorber 5Kg, film coalescence aid 12Kg, 300 rev/mins of rotating speeds disperse to get final product in 30 minutes.
2) paint:
C, in above scattered base fluid, add Rutile type Titanium Dioxide 180Kg successively, ceramics powder 120Kg, talcum powder 800 order 80Kg, light calcium carbonate 60Kg, dispersing speed transfers to 1200 rev/mins, high speed dispersion was ground after 30 minutes, grind 3-4 time, detect fineness requirement<35um, viscosity controller is about 70ku.300 rev/mins of dispersing speed, add the good defoamer 1.5kg of dilution, add pure-acrylic emulsion 400Kg, stirring at low speed, add the PH conditioning agent (pH value is controlled between the 8-9) of 1.5Kg again after, add flow agent 5Kg, drip the good 5kg thickening material 1 of dilution then, add the thickening material 2 of 3kg again, after stirring, viscosity controller is about 95Ku.
Preparation, to detect used plant and instrument as follows:
Plant and instrument: reactor, high speed dispersor, sand mill, scrubbing resistance instrument, stirred pot, viscometer, fineness instrument, unit elongation determinator, weather-proof instrument experimental box etc.
Interventions Requested Assay
Surface drying time, h 2 pass through
Do solid work the time, h 24 pass through
Water tolerance (240h) Flawless, bubble, peel off
Abrasion resistance (2000 times) Flawless, show-through
Alkali resistance (15 circulations) Flawless, foaming
Freeze-thaw resistance (15 circulations) Flawless, bubble, peel off, have light discolouration
Cohesive strength, Mpa 1.4
Water-permeable (0.3Mpa, 30min) Waterproof
Elongation at break, % 345
Tensile strength, Mpa 2.0
Low temperature flexibility (20 ℃) Flawless, bubble, peel off, have flexible
The artificial weathering ageing resistance 1000h is non-foaming, do not peel off, flawless.
Embodiment 2:
The preparation of slurry:
A, accurate weighing required water, auxiliary agent, pigment, filler and emulsion
At first with 100Kg water and 1kg sterilant mixing and stirring, rotating speed is controlled at 300 rev/mins to b, stirs after 10 minutes, closes dispersion machine.The amount of taking-up 20% is standby, adds dispersion agent 4Kg then successively, propylene glycol 20Kg, and UV light absorber 5Kg, film coalescence aid 14Kg, 300 rev/mins of rotating speeds disperse to get final product in 30 minutes.
2) paint
C, in above scattered base fluid, add Rutile type Titanium Dioxide 180Kg successively, ceramics powder 100Kg, talcum powder 800 order 60Kg, light calcium carbonate 50Kg; Dispersing speed transfers to 1200 rev/mins, and high speed dispersion was ground after 30 minutes, grinds 3-4 time, detects fineness requirement<35um, and viscosity controller is about 70ku.300 rev/mins of dispersing speed, add the good defoamer 1.5kg of dilution, add elastic water-proof emulsion 450Kg, stirring at low speed, add the PH conditioning agent (pH value is controlled between the 8-9) of 1.5Kg again after, add flow agent 5Kg, drip the good 5kg thickening material 1 of dilution then, add the thickening material 2 of 3kg again, after stirring, viscosity controller is about 95ku.
Preparation, to detect used plant and instrument as follows:
Plant and instrument: reactor, high speed dispersor, sand mill, scrubbing resistance instrument, stirred pot, viscometer, fineness instrument, unit elongation determinator, weather-proof instrument etc.
The technical indicator of this product is as follows:
Interventions Requested Assay
Surface drying time, h 2 pass through
Do solid work the time, h 24 pass through
Water tolerance (240h) Flawless, bubble, peel off
Abrasion resistance (2000 times) Flawless, show-through
Alkali resistance (15 circulations) Flawless, foaming
Freeze-thaw resistance (15 circulations) Flawless, bubble, peel off, nondiscoloration
Cohesive strength, Mpa 1.2
Water-permeable (0.3Mpa, 30min) Waterproof
Elongation at break, % 250
Tensile strength, Mpa 1.5
Low temperature flexibility (20 ℃) Flawless, bubble, peel off, have flexible
The artificial weathering ageing resistance 1000h is non-foaming, do not peel off, flawless.

Claims (4)

1, a kind of super weather resisting elastic water proofing paint is made up of water, auxiliary agent, pigment, filler, emulsion; It is characterized in that: wherein auxiliary agent is made up of propylene glycol, film coalescence aid, sterilant, flow agent, dispersion agent, thickening material, defoamer, UV light absorber, PH conditioning agent; Pigment is Rutile type Titanium Dioxide; Filler is made up of talcum powder, ceramics powder, light calcium carbonate; Emulsion is the elastic water-proof emulsion;
The weight percentage scope of each raw material is:
Water 5%-15%,
Propylene glycol 2%-4%,
Film coalescence aid 0.5%-2%,
Sterilant 0.1%-0.4%,
Flow agent 0.4%-0.7%,
Dispersion agent 0.2%-0.7%,
Thickening material 0.5%-1%,
Defoamer 0.1%-0.2%,
UV light absorber 0.1-0.5%,
PH conditioning agent 0.1-0.2%,
Rutile type Titanium Dioxide 15%-25%,
Talcum powder 5%-10%,
Ceramics powder 5%-15%,
Light calcium carbonate 5%-10% and
Elastic water-proof emulsion 30%-50%;
Wherein defoamer is a silicone compounds type defoamer; Dispersion agent is an anionic sodium polyacrylate salt brine solution;
Flow agent is the rheology modified auxiliary agent of solvent-free nonionic polyurethane;
Film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate;
Sterilant is the industrial sanitas of nitrogenous organic ring compound;
UV light absorber is 2-hydroxyl-4-methoxy benzophenone;
The PH conditioning agent is 2-amino-2 methyl isophthalic acid-1 propyl alcohol;
The elastic water-proof emulsion is an emulsion for the self-cross linking type pure acrylic acid.
2, super weather resisting elastic water proofing paint according to claim 1 is characterized in that: described thickening material is made up of thickening material 1 and thickening material 2; Thickening material 1 is formed and the type thickening material for the hydrophobically-modified alkali swelling; Thickening material 2 is a polyacrylic acid emulsion-type thickening material;
The weight percentage scope of each raw material is:
Water 5%-15%,
Propylene glycol 2%-3%,
Film coalescence aid 0.5%-1.5%,
Sterilant 0.1%-0.2%,
Flow agent 0.4%-0.7%,
Dispersion agent 0.2%-0.4%,
Thickening material 1 0.3%-0.6%,
Thickening material 2 0.2%-0.4%,
Defoamer 0.1%-0.2%,
UV light absorber 0.2%-0.5%,
PH conditioning agent 0.1-0.2%,
Rutile type Titanium Dioxide 15%-25%,
Talcum powder 800 order 5%-10%,
Ceramics powder 400 order 10%-12%,
Light calcium carbonate 5%-10% and
Elastic water-proof emulsion 40%-50%.
3, super weather resisting elastic water proofing paint according to claim 2 is characterized in that:
The weight percentage scope of each raw material is:
Water 10.0%,
Propylene glycol 2.2%,
Film coalescence aid 1.2%,
Sterilant 0.1%,
Flow agent 0.5%,
Dispersion agent 0.4%,
Thickening material 1 0.5%,
Thickening material 2 0.3%,
Defoamer 0.15%,
UV light absorber 0.5%,
PH conditioning agent 0.15%,
Rutile type Titanium Dioxide 18.0%,
Talcum powder 800 orders 8%,
Ceramics powder 400 orders 12.0%,
Light calcium carbonate 6% He
Elastic water-proof emulsion 40.0%.
4, a kind of production method of super weather resisting elastic water proofing paint of claim 1, it is characterized in that: it may further comprise the steps,
1) preparation of slurry
A, the accurate required water of weighing, auxiliary agent, pigment, filler and emulsion;
B, at first with water and sterilant mixing and stirring, rotating speed is controlled at 300 rev/mins, stirs after 10 minutes, closes dispersion machine; The amount of taking-up 20% is standby, adds dispersion agent, propylene glycol, UV light absorber, film coalescence aid then successively, and 300 rev/mins of rotating speeds disperse to get final product in 30 minutes;
2) paint
C, in above scattered base fluid, add Rutile type Titanium Dioxide, ceramics powder, talcum powder 800 orders, light calcium carbonate successively, dispersing speed transfers to 1200 rev/mins, and high speed dispersion was ground after 30 minutes, grinds 3-4 time, detect fineness requirement<35um, viscosity controller is about 70ku;
300 rev/mins of d, dispersing speed, add the good defoamer of pure-acrylic emulsion and dilution, add an amount of PH conditioning agent, pH value is controlled between the 8-9, adds the good flow agent of dilution, drips the good thickening material of dilution then, after stirring, viscosity controller is brushed on sheet glass with the wool brush about 95ku, observes bubble, particle, the levelling property of coating surface;
E, filtration connect surge pump, tighten filter screen, put into reciprocating sieve, open air compressor and filter;
F, packing.
CN 200510042770 2005-05-31 2005-05-31 Super weather-proof elastic waterproof paint and production method thereof Pending CN1872920A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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