CN1635202A - Nano thermal storage warming all band infrared fibrous composition - Google Patents
Nano thermal storage warming all band infrared fibrous composition Download PDFInfo
- Publication number
- CN1635202A CN1635202A CN 200310122001 CN200310122001A CN1635202A CN 1635202 A CN1635202 A CN 1635202A CN 200310122001 CN200310122001 CN 200310122001 CN 200310122001 A CN200310122001 A CN 200310122001A CN 1635202 A CN1635202 A CN 1635202A
- Authority
- CN
- China
- Prior art keywords
- band infrared
- nanometer
- particle diameter
- fibre composition
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 238000010792 warming Methods 0.000 title 1
- 239000000835 fiber Substances 0.000 claims abstract description 36
- 239000002245 particle Substances 0.000 claims abstract description 22
- 238000009825 accumulation Methods 0.000 claims abstract description 21
- 229910026551 ZrC Inorganic materials 0.000 claims abstract description 15
- OTCHGXYCWNXDOA-UHFFFAOYSA-N [C].[Zr] Chemical compound [C].[Zr] OTCHGXYCWNXDOA-UHFFFAOYSA-N 0.000 claims abstract description 15
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- -1 aluminic acid ester Chemical class 0.000 claims description 24
- 239000005995 Aluminium silicate Substances 0.000 claims description 12
- 235000012211 aluminium silicate Nutrition 0.000 claims description 12
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000004952 Polyamide Substances 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 229910000077 silane Inorganic materials 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 229920000297 Rayon Polymers 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 2
- 229910010272 inorganic material Inorganic materials 0.000 abstract description 5
- 239000011147 inorganic material Substances 0.000 abstract description 5
- 239000004753 textile Substances 0.000 abstract description 5
- 238000010521 absorption reaction Methods 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 238000009987 spinning Methods 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 3
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 238000009940 knitting Methods 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 description 8
- 230000000694 effects Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- 230000017531 blood circulation Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 241000127225 Enceliopsis nudicaulis Species 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000006806 disease prevention Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000007500 overflow downdraw method Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Abstract
The invention discloses a nanometer heat accumulation temperature elevated all wave section bend infra-red fiber composition, comprising 0.5~2% zirconium carbide with particle diameter of 10~100nm, 1~4% porcelain clay with particle diameter of 10~100nm, 0.02~0.6% spinning auxiliary agent, and the residual resin all by weight. By adding inorganic material capable of absorbing visible light and near infrared ray in high efficiency to the resin, the fiber of the invention can absorb the energy of visible light and near infrared ray to full advantage, and increase the temperature of fiber or textiles; by adding material capable of absorbing far-infrared ray in high efficiency to the fiber, the invention can increase the temperature of the textile at the same time with sending near-infrared ray, and improve the energy of far-infrared ray sent by the textile; because the added inorganic material is of nanometer grade, it is of great advantages to spinning and knitting, at same time, the nanometer powder increases the surface area and increases the infrared absorption and sending function.
Description
Technical field
The present invention relates to a kind of photo-thermal conversion fiber.
Background technology
The photo-thermal conversion fiber is a kind of novel warmth retention property functional fibre, and it can optionally absorb sunray and be converted into heat energy, to improve heat insulation effect, it is applied to aspects such as insulation garment, and very big development prospect is arranged.
About far IR fibre, appear in the newspapers both at home and abroad, as in resin raw material, adding the little energy of far infrared powder, make synthetic fiber etc., they can absorb far infrared effectively, and are converted into heat, and have certain limitation for the transform light energy of visible light.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of nanometer accumulation of heat intensification all band infrared fibre composition is provided.
Technical scheme of the present invention is summarized as follows:
A kind of nanometer accumulation of heat intensification all band infrared fibre composition comprises zirconium carbide 0.5～2%, kaolin 1～4% by weight percentage, spinning-aid agent 0.02～0.6%, surplus is a resin, and the particle diameter of described zirconium carbide is 10～100nm, and described kaolinic particle diameter is 10～100nm.
Described spinning-aid agent is titanate esters or aluminic acid ester or silane.
Described resin is polyester or polypropylene or polyamide or polyacrylonitrile or viscose glue.
Described titanate esters is three oleoyl isopropyl titanates or isopropyl stearyl-methylpropenyl titanate esters.
Described aluminic acid ester is DL-411A or DL-411AF.
Described silane is two-(γ-tri-ethoxy silylpropyl) four sulphur or γ-sulfydryl trimethoxy silane or γ-(methacryloxy) propyl trimethoxy silicane or gamma-aminopropyl-triethoxy-silane.
A kind of nanometer accumulation of heat intensification all band infrared fibre composition of the present invention after making fiber and being woven to textiles, can play accumulation of heat and increase warm and function of health care by heating the blood circulation effect that promotes the user.
Because the present invention has added energy efficient absorption visible light and near infrared inorganic material zirconium carbide in the resin that routine is used, make fiber can fully absorb visible light and near infrared energy, improve the temperature of fiber or textiles, and the material kaolin that in this fiber, also adds energy efficient absorption far infrared, obviously this fiber and far infrared fiber fabric are inequality, in the near infrared while of emission, the temperature of fabric is raise, the far-infrared ray power of fabric emission is improved greatly, the fabric that people use this fiber to be made into, can stimulate circulation, increase volume of blood flow, play the effect of disease-prevention health better.Because the inorganic material of adding is nano level material, therefore, help spinning and braiding again, simultaneously, nano level powder, its surface area significantly increases, and has further increased the INFRARED ABSORPTION and the emitting performance of material.
The specific embodiment
Nanometer accumulation of heat intensification all band infrared fibre preparation of compositions of the present invention becomes fiber, be the preparation method who adopts the functional fiber that discloses, for example: take a morsel earlier and serve as the resin of carrier, add a certain proportion of nano level zirconium carbide and nano level kaolin and fully be mixed and made into concentrated master batch, then, again under the effect of spinning-aid agent, will concentrate master batch and mixed with resin is even, carry out spinning production through fusion method or wet method.
The adding of spinning-aid agent improves the spinnability of fibre-forming polymer under the situation that adds inorganic material.
The basic principle of selecting for use of spinning-aid agent is nontoxic, non-stimulated to people's skin.
Spinning-aid agent can select titanate esters or aluminic acid ester or silane.Wherein DL-411A in the aluminic acid ester or DL-411AF are that Fujian Normal University's macromolecule pilot plant and Foochow Cang Shan chemical industry kerosene factory produce, and they have function admirable, characteristics with low cost.
Below by embodiment the present invention is further described.
Embodiment 1
A kind of nanometer accumulation of heat intensification all band infrared fibre composition comprises 5 kilograms of zirconium carbides, 1 kilogram of kaolin by weight percentage; 0.2 kilogram of three oleoyl isopropyl titanate; 984.8 kilograms of resins, the particle diameter of described zirconium carbide are 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 2
A kind of nanometer accumulation of heat intensification all band infrared fibre composition; comprise 15 kilograms of zirconium carbides by weight percentage; 15 kilograms of kaolin; 0.5 kilogram of isopropyl stearyl monomethyl propenyl titanate esters; 969.5 kilograms of polyester; the particle diameter of described zirconium carbide is 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 3
A kind of nanometer accumulation of heat intensification all band infrared fibre composition comprises 20 kilograms of zirconium carbides, 10 kilograms of kaolin by weight percentage, the DL-411A1 kilogram, 969 kilograms of polypropylene, the particle diameter of described zirconium carbide are 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 4
A kind of nanometer accumulation of heat intensification all band infrared fibre composition, comprise 10 kilograms of zirconium carbides by weight percentage, 40 kilograms of kaolin, two-5 kilograms of (γ-tri-ethoxy silylpropyl) four sulphur, 945 kilograms of viscose glues, the particle diameter of described zirconium carbide is 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 5
A kind of nanometer accumulation of heat intensification all band infrared fibre composition comprises 20 kilograms of zirconium carbides, 35 kilograms of kaolin by weight percentage, 2 kilograms of γ-sulfydryl trimethoxy silane, 943 kilograms of polyacrylonitrile, the particle diameter of described zirconium carbide are 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 6
A kind of nanometer accumulation of heat intensification all band infrared fibre composition, comprise 10 kilograms of zirconium carbides by weight percentage, 30 kilograms of kaolin, 3 kilograms of γ-(methacryloxy) propyl trimethoxy silicane, 957 kilograms of polyamide, the particle diameter of described zirconium carbide is 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 7
A kind of nanometer accumulation of heat intensification all band infrared fibre composition comprises 10 kilograms of zirconium carbides, 20 kilograms of kaolin by weight percentage, 4 kilograms of gamma-aminopropyl-triethoxy-silanes, 966 kilograms of polyamide, the particle diameter of described zirconium carbide are 10～100nm, and described kaolinic particle diameter is 10～100nm.
Embodiment 8
A kind of nanometer accumulation of heat intensification all band infrared fibre composition comprises 20 kilograms of zirconium carbides, 20 kilograms of kaolin by weight percentage, the DL-411AF4 kilogram, 956 kilograms of polyamide, the particle diameter of described zirconium carbide are 10～100nm, and described kaolinic particle diameter is 10～100nm.
Claims (6)
1. a nanometer accumulation of heat intensification all band infrared fibre composition is characterized in that comprising by weight percentage zirconium carbide 0.5～2%, kaolin 1～4%, spinning-aid agent 0.02～0.6%, surplus is a resin, and the particle diameter of described zirconium carbide is 10～100nm, and described kaolinic particle diameter is 10～100nm.
2. a kind of nanometer accumulation of heat intensification all band infrared fibre composition according to claim 1, the described spinning-aid agent of its feature is titanate esters or aluminic acid ester or silane.
3. a kind of nanometer accumulation of heat intensification all band infrared fibre composition according to claim 1, the described resin of its feature is polyester or polypropylene or polyamide or polyacrylonitrile or viscose glue.
4. a kind of nanometer accumulation of heat intensification all band infrared fibre composition according to claim 2, the described titanate esters of its feature is three oleoyl isopropyl titanates or isopropyl stearyl monomethyl propenyl titanate esters.
5. a kind of nanometer accumulation of heat intensification all band infrared fibre composition according to claim 2, the described aluminic acid ester of its feature is DL-411A or DL-411AF.
6. a kind of nanometer accumulation of heat intensification all band infrared fibre composition according to claim 2, the described silane of its feature are two-(γ-tri-ethoxy silylpropyl) four sulphur or γ-sulfydryl trimethoxy silane or γ-(methacryloxy) propyl trimethoxy silicane or gamma-aminopropyl-triethoxy-silane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310122001 CN1635202A (en) | 2003-12-30 | 2003-12-30 | Nano thermal storage warming all band infrared fibrous composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310122001 CN1635202A (en) | 2003-12-30 | 2003-12-30 | Nano thermal storage warming all band infrared fibrous composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1635202A true CN1635202A (en) | 2005-07-06 |
Family
ID=34844331
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200310122001 Pending CN1635202A (en) | 2003-12-30 | 2003-12-30 | Nano thermal storage warming all band infrared fibrous composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1635202A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101640953B (en) * | 2009-08-18 | 2012-02-01 | 中山市康益保健用品有限公司 | Far infrared heating shell fabric |
| CN103132177A (en) * | 2013-03-13 | 2013-06-05 | 苏州大学 | Nano zirconium carbide induction type heat-storage heat-preservation polyester fiber and preparation method thereof |
| CN105200546A (en) * | 2015-11-03 | 2015-12-30 | 安踏（中国）有限公司 | Light-absorption and heat-storage far-infrared fiber as well as preparation method and application thereof |
| CN109385688A (en) * | 2017-08-10 | 2019-02-26 | 中国石化仪征化纤有限责任公司 | A kind of abnormity thermal polyester fibers and preparation method thereof |
| CN113155776A (en) * | 2021-04-29 | 2021-07-23 | 华东交通大学 | Prediction method for optimal harvest time of oranges |
-
2003
- 2003-12-30 CN CN 200310122001 patent/CN1635202A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101640953B (en) * | 2009-08-18 | 2012-02-01 | 中山市康益保健用品有限公司 | Far infrared heating shell fabric |
| CN103132177A (en) * | 2013-03-13 | 2013-06-05 | 苏州大学 | Nano zirconium carbide induction type heat-storage heat-preservation polyester fiber and preparation method thereof |
| CN103132177B (en) * | 2013-03-13 | 2015-01-21 | 苏州大学 | Nano zirconium carbide induction type heat-storage heat-preservation polyester fiber and preparation method thereof |
| CN105200546A (en) * | 2015-11-03 | 2015-12-30 | 安踏（中国）有限公司 | Light-absorption and heat-storage far-infrared fiber as well as preparation method and application thereof |
| CN105200546B (en) * | 2015-11-03 | 2018-01-26 | 安踏（中国）有限公司 | A kind of extinction accumulation of heat far IR fibre, its preparation method and application |
| CN109385688A (en) * | 2017-08-10 | 2019-02-26 | 中国石化仪征化纤有限责任公司 | A kind of abnormity thermal polyester fibers and preparation method thereof |
| CN113155776A (en) * | 2021-04-29 | 2021-07-23 | 华东交通大学 | Prediction method for optimal harvest time of oranges |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103541039B (en) | A kind of multi-functional modified dacron staple fibre and preparation method thereof | |
| CN106367836B (en) | A kind of manufacturing method of hollow biomass graphene polyester fiber | |
| CN101545153B (en) | Anion terylene colored fiber and preparation and application thereof | |
| CN103285920A (en) | Three-dimensional fiber-based aerogel catalyst carrier and preparation method thereof | |
| CN104878468A (en) | Nano-titanium dioxide-feeding silkworm rearing method for preparing high-performance silk and product prepared by nano-titanium dioxide-feeding silkworm rearing method | |
| CN104886008A (en) | Graphene oxide-feeding silkworm rearing method for preparing high-strength silk and product of silk | |
| CN106567192A (en) | Method for preparing multifunctional health-care nanofiber membrane | |
| CN111910285A (en) | Graphene biological composite fiber and preparation method and application thereof | |
| CN106350932A (en) | Flocking lace fabric | |
| CN100427537C (en) | Carbon sensitive material, its preparation method and application | |
| CN109609100A (en) | A kind of photothermal composite material and preparation method thereof being provided simultaneously with extinction fever heat storage function | |
| CN105113127A (en) | Large-area flexible piezoelectric spontaneous-heating non-woven fabric and manufacturing method thereof | |
| CN104878467A (en) | Nano-aluminum oxide-feeding silkworm rearing method for preparing high-performance silk and product prepared by nano-aluminum oxide-feeding silkworm rearing method | |
| CN1635202A (en) | Nano thermal storage warming all band infrared fibrous composition | |
| CN1644779A (en) | Production of silk cotton wadding material | |
| CN105442298A (en) | Preparation method for ultrasound-assisted fiber surface expanding of nonwoven cloth and loading with nano zinc oxide | |
| CN102953147A (en) | Coffee carbon-containing anti-flaming polyester staple fiber and preparation method thereof | |
| CN109082728B (en) | Graphene-containing plant protein nanofiber and preparation method thereof | |
| CN106222787B (en) | A kind of method that regenerative piece of polyester bottle prepares photothermal response staple fiber | |
| CN109440223A (en) | A kind of wet fiber material preparation method of spiral porous structure | |
| CN103469364B (en) | Preparation method of indium-tin-oxide-coated titanium dioxide nano fiber | |
| CN1944731A (en) | Functiaonl bamboo carbon fibre and chitin fibre blended yarn and its producing method | |
| CN106319680B (en) | A kind of manufacturing method of multifunction polyester staple fiber | |
| CN1277005C (en) | Active carbon far infrared functional fibre and its manufacturing method | |
| CN103469363B (en) | Indium-tin-oxide-coated titanium dioxide nano fiber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: TIANJIN CITY GUOKE ELECTRONICS TECHNOLOGY CO., LT Free format text: FORMER OWNER: YUAN BING; APPLICANT Effective date: 20070209 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20070209 Address after: 300384 Tianjin Huayuan Industrial Zone Orchid Road No. 1 Huayuan technology annotation workshop 303 Applicant after: Tianjin Ke Ke Electronic Technology Co., Ltd. Address before: 300072 12-4-602, three village, Tianjin University, Tianjin, Nankai District Applicant before: Yuan Bing Co-applicant before: Wang Qia |
|
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |