CN1611552A - Oil-proof asphalt composition and its preparing method - Google Patents
Oil-proof asphalt composition and its preparing method Download PDFInfo
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- CN1611552A CN1611552A CN 200310104980 CN200310104980A CN1611552A CN 1611552 A CN1611552 A CN 1611552A CN 200310104980 CN200310104980 CN 200310104980 CN 200310104980 A CN200310104980 A CN 200310104980A CN 1611552 A CN1611552 A CN 1611552A
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- oil
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- bituminous composition
- eva
- sbs
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- 239000000203 mixture Substances 0.000 title claims abstract description 59
- 239000010426 asphalt Substances 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims description 7
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 15
- 230000035515 penetration Effects 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 10
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 7
- 239000011280 coal tar Substances 0.000 claims abstract description 7
- 229920001971 elastomer Polymers 0.000 claims abstract description 7
- 239000005060 rubber Substances 0.000 claims abstract description 7
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 7
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 7
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 15
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 14
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 239000005864 Sulphur Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000000605 extraction Methods 0.000 claims description 5
- 230000008961 swelling Effects 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 229920005992 thermoplastic resin Polymers 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- 238000004090 dissolution Methods 0.000 abstract 2
- 230000003628 erosive effect Effects 0.000 abstract 2
- 238000003860 storage Methods 0.000 abstract 2
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 25
- 229920002725 thermoplastic elastomer Polymers 0.000 description 7
- 239000003350 kerosene Substances 0.000 description 6
- 238000005204 segregation Methods 0.000 description 6
- 238000007654 immersion Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000005338 heat storage Methods 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 244000286663 Ficus elastica Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 150000002924 oxiranes Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a kind of stable bitumen combination with flame material, oil dissolution and erosion resistance function for road storage, and its manufacturing method. Concoct base bitumen with suitable penetration and distillate oil or coal tar rich in arene to get base bitumen mixture; By using cross-linking agent, add thermoplastic elaxtic rubber in base bitumen mixture to react for a spell in 150-200deg.C; After reacting, add in ethylene-vinyl acetate copolymer and a kind of oil resistant resin for continuing reaction, in order to generate stable bitumen combination. The stable bitumen combination of the invention has excellent storage stability, fine flame material, oil dissolution and erosion resistance function, and fine high-low temperature serviceability. It can be used in road paving, especially in pavement paving of airport, waste disposal plant, service station, tank battery, and so on.
Description
Technical field
The present invention relates to a kind of oil resistant bituminous composition and preparation method thereof, particularly a kind of road oil resistant bituminous composition of shelf-stable and preparation method thereof.
Background technology
Bituminous material uses as binding agent in the mixture of making road, in order to satisfy the demand that Road construction improves day by day, bituminous material is except having good visco-elasticity, plasticity-, adhesivity, also usually need to satisfy dissolving of anti-fuel (gasoline, diesel oil, kerosene) and oil product (lubricating oil, machine oil etc.) and etch ability.Particularly on the airport, the road surface on ground such as waste disposal field, service station, tank station often is exposed in the fuel and oil product of spill and leakage, pitch can come out from compound in dissolved leaching, make the bituminous pavement deliquescing, cohesive force between aggregate descends, pavement structure fluffs diffusing, finally the pitch that is come out by leaching loses from road surface, causes the road surface to damage.
For addressing the above problem, CN1259157 provides a kind of ground surface material that acid is blown asphalt component and contained the polymkeric substance of epoxide group that contains.This ground surface material be can with the acid of pitch reaction in the presence of, allow pitch and oxygen reaction obtain acid at temperature 240-340 ℃ and blow pitch, this acid blows that pitch and solubility promoter are mixed to obtain basic asphalt, and the trimer of basic asphalt and ethene, butyl acrylate, glycidyl acrylate mixes.
CN1219187 also provides a kind of bituminous composition that contains asphalt component, thermoplastic rubber and vinyl-vinyl acetate copolymer.Said composition is under heating up pitch and thermoplastic elastomer and vinyl-vinyl acetate copolymer to be mixed.
Because thermoplastic elastomer and pitch are formed, structural difference is big, the thermoplastic rubber can only swelling in pitch, is difficult to disperse, and fragrance branch content height then can promote thermoplastic rubber's swelling, polymkeric substance/composition stable in the favourable heat-storage process in the pitch.But pitch is behind catalyzed oxidation, and fragrance wherein divides content to reduce, the consistency meeting variation of pitch and polymkeric substance, and then influence composition stable.
Summary of the invention
The object of the invention is to provide a kind of use properties good, bituminous composition of the anti-fuel of shelf-stable and oil product dissolving and etch ability and preparation method thereof.
Oil resistant bituminous composition of the present invention comprises following component by weight:
Basic asphalt: 100 parts;
Styrene-butadiene-styrene triblock copolymer (SBS): 1～10 part, be preferably 2～7 parts;
Vinyl-vinyl acetate copolymer (EVA): 0.5～8 part, preferred 1～4 part;
Acrylonitrile, divinyl and styrene copolymer (ABS): 1～4 part;
Linking agent: 0.1～0.3 part.
In the bituminous composition of the present invention, the penetration degree of basic asphalt is 60-2001/10mm (testing according to ASTMD5 under 25 ℃).Preferred extraction oil or the coal tar that is rich in aromatic hydrocarbons that adds is extracted oil or coal tar add-on＜20wt% out in the basic asphalt, is generally 5～10wt%.
SBS is modifying asphalt SBS commonly used in the bituminous composition of the present invention, and molecular weight is generally 50000-300000, preferred linear or star shaped SBS, most preferably linear SBS.SBS also can replace or mix use with the close thermoplastic elastic rubber of other performance.
The EVA that uses in the bituminous composition of the present invention is EVA commonly used in the modifying asphalt, vinyl-acetic ester among the EVA (VA) content 25-40wt%, and preferred 25-35wt%, melt index is 5～400.
In the bituminous composition of the present invention ABS resin be that propylene is fine, divinyl, styrene copolymer, melt flow rate (MFR) 1.0-2.0g/10min, Vicat softening point 90-100 ℃, relative density 1.03-1.07.
Linking agent in the bituminous composition of the present invention is selected from the sulphur distillation, and active sulphur and sulphur give in the composition a kind of, or other has the additive of crosslinked function.
Oil resistant bituminous composition preparation method of the present invention is as follows: the pitch of selecting suitable penetration degree as required, under molten state, add the extraction oil or the coal tar that are rich in aromatic hydrocarbons and concoct out the basic asphalt mixture, add SBS and linking agent again, under high shear, under melting condition (150-230 ℃) hybrid reaction 10-30 minute, make thermoplastic elastic rubber swelling fully in pitch, keep temperature-resistant, add EVA and ABS resin again, continue reaction 10-60 minute, form stable bituminous composition.
Add an amount of rich aromatic hydrocarbon oil in pitch, can strengthen the stability of polymkeric substance/bituminous composition, the adding of the good ABS resin of oil-proofness simultaneously can significantly improve the oil resistant characteristic of bituminous composition.Add extraction oil or the coal tar that is rich in aromatic hydrocarbons in the oil resistant bituminous composition of the present invention, make thermoplastic elastic rubber abundant swelling in pitch, increased the thermoplastic rubber in the bituminous dispersive ability.The while linking agent makes thermoplastic rubber self generation glue join reaction and also and between pitch produces graft reaction, and the network structure of formation is wrapped up pitch wherein with the EVA and the ABS that are dispersed in the pitch, prevents that the composition generation is separated.Therefore do not produce segregation and layering after said composition is at high temperature stored.The dissolving of anti-fuel of bituminous composition and oil product and etch ability improve, 3
#Soak at room temperature is 24 hours in the boat coal, and penetration degree changes less than 30, and quality change is less than 1%.Oil resistant bitumen production technology of the present invention is simple, shelf-stable, oil resistant dissolving and etch ability are strong, and high and low temperature road surface use properties is good simultaneously.
Embodiment
The present invention is further described for following example.The SBS that wherein relates to is that Synthetic Rubber Plant, Yueyang Petro-Chem. Complex produces, universal 701 (melt flow rate (MFR) 1.0-1.4g/10min, 94 ℃ of dimension card soft spots, the relative densities 1.05) that ABS resin is produced for Lanzhou chemical industrial company.
Embodiment 1
Needle selection in-degree 96 1/10mm, the pitch that softening temperature is 43.4 ℃ are matrix pitch, and extract oily gross weight meter 8% phenol treating based on matrix pitch and phenol treating out and extract oil (＞350 ℃ cuts) out and be mixed and made into the basic asphalt mixture.With above-mentioned basic asphalt mixture 100 weight parts, add in the matrix pitch mixture with linear SBS1301 (molecular weight 100000) and 0.13 part of sulphur distillation of 4 parts, under high shear, in 170 ℃ mix 5 minutes after, drop into 2 parts EVA28150 (VA content 28%, melt index 150) and 1 part of ABS resin, continue reaction 20 minutes, make stable bituminous composition.Its character sees Table 1.163 ℃ of heat storages of said composition 48 hours, segregation softening temperature differ from 0.5 ℃ (pressing the test of ASTMD5976-96 experimental technique).In 3
#Soak at room temperature is 24 hours in the aviation kerosene, and penetration degree changes 20 units before and after the immersion oil, and quality change is less than 1% (with reference to the ASTMD5329-96 test method).
Embodiment 2
Prepare bituminous composition according to embodiment 1 method, different is that the ABS resin add-on is 2 parts.Its character sees Table 1, and said composition segregation softening temperature differs from 0.8 ℃, in 3
#Soak at room temperature is 24 hours in the aviation kerosene, and penetration degree changes 23 units before and after the immersion oil, and quality change is less than 1%.
Embodiment 3
Prepare bituminous composition according to embodiment 1 method, different is that thermoplastic elastic rubber SBS1301 add-on is 5 parts.Its character sees Table 1, and said composition segregation softening temperature differs from 1.0 ℃.In 3
#Soak at room temperature is after 24 hours in the aviation kerosene, and penetration degree changes 26 units before and after the immersion oil, and quality change is less than 1%.
Embodiment 4
Prepare bituminous composition according to embodiment 1 method, different is that thermoplastic elastic rubber SBS1301 add-on is 5 parts, and used vinyl-vinyl acetate copolymer (EVA) is EVA3345 (VA content is 33%, melt index 45), and add-on is 3 parts.Its character sees Table 1, and said composition segregation softening temperature differs from 0.7 ℃.In 3
#Soak at room temperature is after 24 hours in the aviation kerosene, and penetration degree changes 24 units before and after the immersion oil, and quality change is less than 1%.
Comparative example 1
Prepare bituminous composition according to embodiment 1 method, different is not add ABS resin.Its character sees Table 1, and said composition segregation softening temperature differs from 0.8 ℃, in 3
#Soak at room temperature is after 24 hours in the aviation kerosene, and penetration degree changes 33 units before and after the immersion oil, and quality change is less than 1%.
From table 1 data as can be seen, the bituminous composition of the present invention prescription makes the oil resistance of product improve greatly owing to added ABS resin.
Table 1 embodiment and comparative example bituminous composition are formed and character
| Numbering | Embodiment 1 embodiment 2 embodiment 3 embodiment 4 comparative examples 1 |
| The basic asphalt mixture, weight part SBS1301, parts of EVA 28150, parts of EVA 3345, the weight part ABS resin, the weight part linking agent, weight part penetration degree (25 ℃), the 1/mm softening temperature, ℃ isolation test softening temperature is poor, ℃ penetration degree changes, (25 ℃), the 1/10mm quality change, % | 100??????100??????100??????100??????100 4.0??????4.0??????5.0??????5.0??????4.0 2.0??????2.0??????2.0??????/????????2.0 /????????/????????/????????3.0??????/ 1.0??????2.0??????1.0??????1.0??????/ 0.13?????0.13?????0.13?????0.13?????0.13 120??????112??????103??????106??????127 58.5?????60.5?????73.9?????74.6?????56.7 0.5??????0.8??????0.6??????0.7??????0.8 20???????23???????26???????24???????33 -0.44????-0.68????0.38?????-0.46????0.76 |
Claims (10)
1, a kind of oil resistant bituminous composition is characterized in that comprising by weight following component:
Basic asphalt: 100 parts;
Styrene-butadiene-styrene triblock copolymer (being called for short SBS): 1～10 part;
Vinyl-vinyl acetate copolymer (being called for short EVA): 0.5～8 part;
Acrylonitrile, divinyl and three kinds of monomers of vinylbenzene are through polymerization, mixing synthetic thermoplastic resin (being called for short ABS): 1～4 part;
Linking agent: 0.1～0.3 part.
2,, it is characterized in that per 100 parts of basic asphalts add 2～7 parts of SBS according to the described bituminous composition of claim 1.
3,, it is characterized in that per 100 parts of basic asphalts add 1～4 part of EVA according to the described bituminous composition of claim 1.
4, according to the described bituminous composition of claim 1, the penetration degree that it is characterized in that basic asphalt is 60-2001/10mm.
5,, it is characterized in that containing in the basic asphalt＜the extraction oil or the coal tar that are rich in aromatic hydrocarbons of 20wt% according to claim 1 or 4 described bituminous compositions.
6, according to claim 1 or 2 described bituminous compositions, the molecular weight that it is characterized in that described SBS is 50000-300000, and SBS is linear or star.
7, according to claim 1 or 3 described bituminous compositions, it is characterized in that vinyl-acetic ester among the described EVA (VA) content 25-40wt%, melt index is 5～400.
8,, it is characterized in that vinyl-acetic ester among the described EVA (VA) content 25-35wt% according to the described bituminous composition of claim 7.
9,, it is characterized in that described ABS resin is that propylene is fine, divinyl, styrene copolymer, melt flow rate (MFR) 1.0-2.0g/10min, Vicat softening point 90-100 ℃, relative density 1.03-1.07 according to the described bituminous composition of claim 1; Described linking agent is selected from the sulphur distillation, and active sulphur and sulphur give in the composition a kind of.
10, the preparation method of the described bituminous composition of a kind of claim 1, its process is as follows: with basic asphalt under molten state, add the extraction oil or the coal tar that are rich in aromatic hydrocarbons and concoct out the basic asphalt mixture, add SBS and linking agent again, under high shear, under 150-230 ℃ of temperature hybrid reaction 10-30 minute, make thermoplastic elastic rubber swelling fully in pitch, keep temperature-resistant, add EVA and ABS resin again, continue reaction 10-60 minute, form stable bituminous composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310104980 CN1259374C (en) | 2003-10-31 | 2003-10-31 | Oil-proof asphalt composition and its preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310104980 CN1259374C (en) | 2003-10-31 | 2003-10-31 | Oil-proof asphalt composition and its preparing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1611552A true CN1611552A (en) | 2005-05-04 |
| CN1259374C CN1259374C (en) | 2006-06-14 |
Family
ID=34757138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200310104980 Expired - Lifetime CN1259374C (en) | 2003-10-31 | 2003-10-31 | Oil-proof asphalt composition and its preparing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1259374C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440709A (en) * | 2015-12-26 | 2016-03-30 | 廖鹏程 | Water-resistant modified matrix asphalt and processing method thereof |
| CN107663380A (en) * | 2016-07-30 | 2018-02-06 | 甘肃西盟公路新材料科技有限公司 | A kind of bituminous composition and preparation method thereof |
| CN109943086A (en) * | 2019-04-08 | 2019-06-28 | 上海道淳交通科技有限公司 | A kind of oil rub resistance modified pitch and preparation method thereof |
| CN111378465A (en) * | 2018-12-27 | 2020-07-07 | 中国石油天然气股份有限公司 | Matrix asphalt, modified asphalt and preparation method |
| CN115678289A (en) * | 2021-07-27 | 2023-02-03 | 中国石油化工股份有限公司 | Anti-shedding sulfur asphalt and preparation method and application thereof |
-
2003
- 2003-10-31 CN CN 200310104980 patent/CN1259374C/en not_active Expired - Lifetime
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440709A (en) * | 2015-12-26 | 2016-03-30 | 廖鹏程 | Water-resistant modified matrix asphalt and processing method thereof |
| CN107663380A (en) * | 2016-07-30 | 2018-02-06 | 甘肃西盟公路新材料科技有限公司 | A kind of bituminous composition and preparation method thereof |
| CN111378465A (en) * | 2018-12-27 | 2020-07-07 | 中国石油天然气股份有限公司 | Matrix asphalt, modified asphalt and preparation method |
| CN111378465B (en) * | 2018-12-27 | 2022-02-01 | 中国石油天然气股份有限公司 | Matrix asphalt, modified asphalt and preparation method |
| CN109943086A (en) * | 2019-04-08 | 2019-06-28 | 上海道淳交通科技有限公司 | A kind of oil rub resistance modified pitch and preparation method thereof |
| CN109943086B (en) * | 2019-04-08 | 2021-07-20 | 上海道淳交通科技有限公司 | Oil-stain-resistant modified asphalt and preparation method thereof |
| CN115678289A (en) * | 2021-07-27 | 2023-02-03 | 中国石油化工股份有限公司 | Anti-shedding sulfur asphalt and preparation method and application thereof |
| CN115678289B (en) * | 2021-07-27 | 2023-09-01 | 中国石油化工股份有限公司 | Anti-drop sulfur asphalt and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1259374C (en) | 2006-06-14 |
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