CN1676686A - Protein-containing functional fiber - Google Patents
Protein-containing functional fiber Download PDFInfo
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- CN1676686A CN1676686A CN 200410010167 CN200410010167A CN1676686A CN 1676686 A CN1676686 A CN 1676686A CN 200410010167 CN200410010167 CN 200410010167 CN 200410010167 A CN200410010167 A CN 200410010167A CN 1676686 A CN1676686 A CN 1676686A
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Abstract
This invention publishes a kind of functional fiber which contains protein. It is made up of protein, high polymer and the substances containing non-metallic element. Among these, the protein takes up A of the total quantity, the high polymer taking up B and the substances containing non-metallic element taking up C. Then we get 1<=A<=67, 10<=B<99 and 0<C<=23. This invention also publishes the producing method of this fiber. This fiber makes the skin feeling comfortable and has good wetness conductivity. Also, it has high ratio of bacteriostasis and occultation, and it can send out far IR, producing high ratio of negative ions. What is more, it has the UV-absorbing ratio of 99.8% and it can absorb the Hertz wave and it offers radiation protection, and so on.
Description
Technical field
The invention belongs to synthetic fiber, relate in particular to fiber with functional effect.
Background technology
General synthetic fiber skin-friendly, gas permeability are relatively poor, I am that ZL99116636.1, name are called " synthetic plant protein filaments and manufacture method thereof " and application number and are 03111814.3, are called in the document of " a kind of soylon and manufacture method thereof " and disclose proteinaceous fiber and manufacture method in the patent No. for this reason, the fiber that makes by foregoing invention, skin-friendly, lead moist, pliability and gloss all fine, but these fibers do not have other functional effect.
Summary of the invention
The object of the present invention is to provide a kind of not only skin-friendly, lead moist better, and have antibacterial, antibiotic, uvioresistant, radiation proof, absorption electromagnetic wave function and have far-infrared functional and the fiber of negative oxygen ion radiation function.
The objective of the invention is to be achieved through the following technical solutions: a kind of functional fiber that contains protein, it is made up of protein, high molecular polymer and the material that contains nonmetalloid.
Protein accounts for A part of total amount, and high molecular polymer accounts for B part of total amount, and the material that contains nonmetalloid accounts for C part of total amount, then: 1≤A≤67,10≤B＜99,0＜C≤23.
Described protein is at least a in phytoprotein and the animal protein.
Described high molecular polymer is at least a in polyvinyl alcohol, polyacrylonitrile and the acrylonitrile.
Described high molecular polymer is a cellulose.
Described high molecular polymer is a vinyl acetate.
Described nonmetalloid is a kind of nonmetalloid.
Described nonmetalloid is at least two kinds of different nonmetalloids.
The described material that contains nonmetalloid is non-metallic atom, nonmetal molecule, nonmetallic ion, nonmetal oxide, nonmetallic compound, contain the composition of nonmetalloid.
This functional fiber can be made by the following method: produce spinning solution earlier, again spinning solution is carried out after the deaeration with wet method or dry-jet wet spinning spinning, silk by the spinning machine ejection enters coagulation bath, after drawing-off, enter and make semi-finished product in the style keeping liquid, semi-finished product are finished product again after dyeing and finishing of dyeing and finishing liquid and acetalation, in this process, the material that contains nonmetalloid should add at least a liquid in spinning solution, coagulation bath, style keeping liquid and the dyeing and finishing liquid.
This functional fiber also can be made by the following method: produce spinning solution earlier, again spinning solution is carried out carrying out dry spinning after the deaeration, enter after drawing-off by the silk of spinning machine ejection and to make semi-finished product in the style keeping liquid, semi-finished product are finished product again after dyeing and finishing of dyeing and finishing liquid and acetalation, in this process, the material that contains nonmetalloid should add at least a liquid in spinning solution, style keeping liquid and the dyeing and finishing liquid.
Fiber internal cause with manufacturing of the present invention contains protein and high molecular polymer, therefore its institutional framework is changed to some extent, produced preferably skin-friendly and led moistly, because of the content difference of fiber inner macromolecule polymer, therefore can produce flexible in various degree fiber again according to people's needs.The sample of this fiber detects through detection department of country and learns, have higher bacteriostasis rate and screening rate simultaneously with a kind of fabric, has far-infrared transmitting function, and can produce higher negative ion concentration, also have 99.8% absorption of UV and absorb multiple good function such as electromagnetic wave, radiation proof.
The specific embodiment
Embodiment 1, get animal protein and polyvinyl alcohol is made spinning solution, containing doing of animal protein in this spinning solution, to measure A admittedly be 50 weight portions, it is 49.5 weight portions that the doing of polyvinyl alcohol measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains silica, it is 0.5 weight portion that the doing of silica measured C admittedly, then tow is made semi-finished product again after air draft, wet bath drawing-off, dried drawing-off and HEAT SETTING, and semi-finished product promptly become finished product again after arrangement and acetalation.
Embodiment 2, get phytoprotein and polyvinyl alcohol is made spinning solution, containing doing of phytoprotein in this spinning solution, to measure A admittedly be 67 weight portions, it is 10 weight portions that the doing of polyvinyl alcohol measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains 13 weight portion phosphorus pentoxides, then tow is again through air draft, wet bath drawing-off and dried drawing-off, enter the style keeping liquid that contains 10 weight portion tourmaline again and then make semi-finished product, semi-finished product promptly become finished product again after arrangement and acetalation.
Embodiment 3, get phytoprotein and polyacrylonitrile is made spinning solution, containing doing of phytoprotein in this spinning solution, to measure A admittedly be 27 weight portions, it is 55 weight portions that the doing of polyacrylonitrile measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains 10 weight portion calcium carbonate, then tow is made semi-finished product again after air draft, wet bath drawing-off, dried drawing-off and HEAT SETTING, semi-finished product promptly become finished product after entering the interior dyeing and finishing of the dyeing and finishing body lotion that contains 8 weight portion silica again.
Embodiment 4, get protein and polyacrylonitrile is made spinning solution, proteinaceously in this spinning solution do that to measure A admittedly be 20.9 weight portions, it is 70 weight portions that the doing of polyacrylonitrile measured B admittedly, protein herein is the mixture of phytoprotein and animal protein, wherein the dried solid amount of phytoprotein is 8 weight portions, it is 12.9 weight portions that animal protein is done solid amount, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains 4.1 weight portion boron carbides, then tow is again through air draft, wet bath drawing-off and dried drawing-off, then enter in the curling liquid that contains 3 weight portion boron element particulates and carry out making semi-finished product after the HEAT SETTING, semi-finished product promptly become finished product after putting into the dyeing and finishing body lotion dyeing and finishing that contains 2 weight portion carbon blacks again.
Embodiment 5, get animal protein and polyvinyl alcohol is made spinning solution, containing doing of phytoprotein in this spinning solution, to measure A admittedly be 50 weight portions, it is 37 weight portions that the doing of polyvinyl alcohol measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters coagulation bath, enter after drawing-off in the curling liquid that contains 2.4 weight portion talcum powder and 10.6 weight portion apatite, making behind the semi-finished product promptly becomes finished product again after arrangement and acetalation.
Embodiment 6, get phytoprotein and polyacrylonitrile is made spinning solution, containing doing of phytoprotein in this spinning solution, to measure A admittedly be 1 weight portion, it is 96 weight portions that the doing of polyacrylonitrile measured B admittedly, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath, then tow is again through air draft, wet bath drawing-off, make semi-finished product after doing drawing-off and HEAT SETTING, semi-finished product are put into and are contained 1.5 weight portion mica powders, carry out dyeing and finishing in the dyeing and finishing body lotion of 1 weight portion zeolite powder and 0.5 weight portion carborundum, then become finished product.
Embodiment 7, get protein and polyvinyl alcohol is made spinning solution, proteinaceously in this spinning solution do that to measure A admittedly be 60 weight portions, it is 35.5 weight portions that the doing of polyacrylonitrile measured B admittedly, protein herein is the mixture of phytoprotein and animal protein, wherein phytoprotein and animal protein respectively account for 50% of total protein, spinning solution is carried out adopting wet spinning after the deaeration, the synthetic fibre tows that is come out by spinning machine enters in the coagulation bath that contains silicon nitride, after drawing-off, enter in the curling liquid that contains boron and finalize the design, make semi-finished product, put into the dyeing and finishing body lotion that contains carbon black and boron carbide again and carry out dyeing and finishing, then become finished product, add that the material that contains nonmetalloid does solid amount with C be 5 parts, wherein silicon nitride and boron respectively are 1 part, carbon black and boron carbide respectively are 1.5 parts.
Embodiment 8, phytoprotein and cellulose solution are mixed, containing doing of phytoprotein in the solution, to measure A admittedly be 30 weight portions, cellulose is done and measured B admittedly is 66 weight portions, in this solution, add nano level boron carbide element then, it is 4 weight portions that the doing of boron carbide element measured C admittedly, make their copolymerization make spinning solution, then spinning solution is carried out adopting dry spinning to make tow after the deaeration, this tow becomes finished product after drawing-off, typing, arrangement and acetalation.
Embodiment 9, animal protein, phytoprotein, vinyl acetate and polyvinyl alcohol are made solution respectively, then they are mixed, in this mixed liquor, add carborundum and the silicon nitride of particle diameter again less than 100 nanometers, make spinning solution, the solid amount of doing of animal protein and phytoprotein is 20 weight portions in the spinning solution, vinyl acetate and polyvinyl alcohol are 28 weight portions, carborundum is 1 weight portion, silicon nitride is 2 weight portions, spinning solution adopts wet spinning after deaeration, fiber enters in the coagulation bath that contains 1 weight portion carbon black, and after drawing-off, typing, arrangement and acetalation become finished product.
Embodiment 10, make solution jointly with animal protein and polyacrylonitrile, wherein the dried solid amount of animal protein is 1 weight portion, it is 98.89 weight portions that polyacrylonitrile is done solid amount, in this mixed liquor, add the particle diameter of 0.01 weight portion less than 1 micron the phosphorus pentoxide and the silica of 0.1 weight portion, make spinning solution jointly, after deaeration, adopt dry spinning, and after typing, arrangement and acetalation become finished product.
Embodiment 11, make spinning solution with phytoprotein, polyvinyl alcohol and acrylonitrile, wherein the dried solid amount of phytoprotein is 57 weight portions, it is 10 weight portions that polyvinyl alcohol is done solid amount, it is 13 weight portions that acrylonitrile is done solid amount, use wet spinning after the spinning solution deaeration, tow enters in the coagulation bath, through drawing-off, typing, then enters to contain in 10 weight portion boron carbides and the bentonitic dyeing and finishing body lotion of 10 weight portions and carries out becoming finished product after the dyeing and finishing.
Embodiment 12, make spinning solution with animal protein and polyacrylonitrile, the dried solid amount of animal protein is 15 weight portions, it is 84 weight portions that polyacrylonitrile is done solid amount, carry out spinning with dry-jet wet spinning after the spinning solution deaeration, tow enters coagulation bath, through drawing-off, then enter in the style keeping liquid that contains 1 weight portion silicon nitride, after arrangement and acetalation, become finished product again.
Embodiment 13, make spinning solution with the tourmaline of animal protein, polyacrylonitrile, acrylonitrile and particle diameter 100 nanometers, the dried solid amount of animal protein is 30 weight portions, it is 20 weight portions that polyacrylonitrile is done solid amount, it is 45.5 weight portions that acrylonitrile is done solid amount, tourmaline is 1 weight portion, use the dry-jet wet spinning spinning after the spinning solution deaeration, tow enters and contains in the kaolinic coagulation bath of 2 weight portions, after drawing-off, enter in the style keeping liquid that contains 1 weight portion boron and finalize the design, after carrying out dyeing and finishing in the dyeing and finishing body lotion through containing 0.5 weight portion selenium again, become finished product.
Embodiment 14, animal protein and polyvinyl alcohol are made spinning solution, the dried solid amount of animal protein is 30 weight portions, it is 65.5 weight portions that polyvinyl alcohol is done solid amount, adopt dry spinning after the spinning solution deaeration, tow enters after drawing-off in the curling liquid that contains 4.5 weight portion silica and finalizes the design, and becomes finished product again after arrangement and acetalation.
Embodiment 15, phytoprotein and polyvinyl alcohol, acrylonitrile are made spinning solution, the dried solid amount of phytoprotein is 35 weight portions, it is 30 weight portions that polyvinyl alcohol is done solid amount, it is 30 weight portions that acrylonitrile is done solid amount, adopt dry spinning after the spinning solution deaeration, tow is after drawing-off, typing, and entering in the dyeing and finishing body lotion that contains 5 weight portion selenium becomes finished product after the dyeing and finishing.
Embodiment 16, make solution with phytoprotein, animal protein and polyacrylonitrile, in solution, add apatite and make spinning solution, spinning solution adopts dry spinning after deaeration is filtered, tow enters in the curling liquid that contains the boron element particulate and finalizes the design, after entering the interior dyeing and finishing of the dyeing and finishing body lotion that contains silica again, become finished product, wherein the dried solid amount of phytoprotein is 10 weight portions, it is 10 weight portions that animal protein is done solid amount, it is 70 weight portions that polyacrylonitrile is done solid amount, apatite is 5 weight portions, and boron is 3 weight portions, and silica is 2 weight portions.
Embodiment 17, make spinning solution with animal protein, polyvinyl alcohol and titanium oxalate, after deaeration, use the wet spinning spinning, tow enters and contains in the talcous coagulation bath, enter in the curling liquid that contains boron carbide again and finalize the design, then be finished product through arrangement and acetalation again, wherein the dried solid amount of phytoprotein is 50 weight portions, it is 35 weight portions that polyvinyl alcohol is done solid amount, titanium oxalate is 5 weight portions, and talcum powder is 9 weight portions, and boron carbide is 1 weight portion.
Embodiment 18, use animal protein, phytoprotein and cellulose are made mixed liquor, in mixed liquor, add kaolin and make spinning solution, after deaeration, use wet spinning, tow enters in the coagulation bath, then enter in the curling liquid that contains the selenium elementary particle and finalize the design, after entering the interior dyeing and finishing of the dyeing and finishing body lotion that contains bentonite and zeolite again, become finished product, wherein the dried solid amount of animal protein is 10 weight portions, and it is 15 weight portions that phytoprotein is done solid measuring, and it is 70 weight portions that cellulose is done solid amount, kaolin is 2 weight portions, selenium is 0.5 weight portion, and bentonite is 1 weight portion, and zeolite is 1.5 weight portions.
Embodiment 19, use animal protein, phytoprotein and vinyl acetate are made mixed liquor, in mixed liquor, add nano level phosphorus and make spinning solution, use wet spinning after the spinning solution deaeration, tow enters in the coagulation bath that contains the nanoscale borax, after drawing-off and HEAT SETTING, after entering the interior dyeing and finishing of the dyeing and finishing body lotion that contains apatite and carborundum, become finished product, wherein, it is 30 weight portions that animal protein is done solid amount, it is 15 weight portions that phytoprotein is done solid amount, it is 35 weight portions that vinyl acetate is done solid amount, and phosphorus is 2 weight portions, and borax is 2 weight portions, apatite is 8 weight portions, and carborundum is 8 weight portions.
Embodiment 20, make mixed liquor with phytoprotein and polyacrylonitrile, in mixed liquor, add zeolite powder, make spinning solution, use wet spinning after the spinning solution deaeration, tow enters in the coagulation bath that contains mica powder, after drawing-off, enter in the curling liquid that contains boron carbide particulate and finalize the design, be finished product through arrangement and acetalation again, wherein the dried solid amount of phytoprotein is 28 weight portions, it is 57 weight portions that polyacrylonitrile is done solid amount, zeolite powder is 5 weight portions, and mica powder is 5 weight portions, and boron carbide is 5 weight portions.
Embodiment 21, make mixed liquor with phytoprotein and polyacrylonitrile, in mixed liquor, add floats, make spinning solution, use wet spinning after the spinning solution deaeration, tow enters in the coagulation bath that contains calcium phosphate, after drawing-off, typing, enter in the dyeing and finishing body lotion that contains carbon black particle and be finished product after the dyeing and finishing, wherein the dried solid amount of phytoprotein is 8 weight portions, and it is 80 weight portions that polyacrylonitrile is done solid measuring, and floats are 3 weight portions, calcium phosphate is 4 weight portions, and carbon black is 5 weight portions.
Embodiment 22, make mixed liquor with phytoprotein, polyacrylonitrile, the particulate that in mixed liquor, adds selenium, make spinning solution, use wet spinning after the spinning solution deaeration, tow enters in the coagulation bath that contains kaolin and zeolite powder, be finished product through drawing-off, typing, arrangement and acetalation, wherein phytoprotein 45 is done to measure admittedly and is that it is 45 weight portions that weight portion, polyacrylonitrile are done solid measuring, and selenium is 2 weight portions, kaolin is 4 weight portions, and zeolite powder is 4 weight portions.
The material that contains nonmetalloid among the present invention described in each embodiment is any non-metallic atom, nonmetal molecule, nonmetallic ion, nonmetal oxide or nonmetallic compound, also can select for use and contain nonmetallic composition, if nonmetal oxide in an embodiment or compound are soluble, then can the solution form add or add with particulate form, also can add nano level nonmetalloid, but the size of particulate can not influence the weaving of fiber.
In each embodiment, if adopt wet spinning technology, then can use dry-jet wet spinning process instead, same if adopt dry-jet wet spinning process, also can use wet spinning technology instead.
Claims (11)
1, a kind of functional fiber that contains protein is characterized in that: it is made up of protein, high molecular polymer and the material that contains nonmetalloid.
2, the functional fiber that contains protein according to claim 1 is characterized in that: protein accounts for A part of total amount, and high molecular polymer accounts for B part of total amount, the material that contains nonmetalloid accounts for C part of total amount, then: 1≤A≤67,10≤B＜99,0＜C≤23.
3, the functional fiber that contains protein according to claim 1 is characterized in that: described protein is at least a in phytoprotein and the animal protein.
4, the functional fiber that contains protein according to claim 1 is characterized in that: described high molecular polymer is at least a in polyvinyl alcohol, polyacrylonitrile and the acrylonitrile.
5, the functional fiber that contains protein according to claim 1 is characterized in that: described high molecular polymer is a cellulose.
6, the functional fiber that contains protein according to claim 1 is characterized in that: described high molecular polymer is a vinyl acetate.
7, the functional fiber that contains protein according to claim 1 is characterized in that: described nonmetalloid is a kind of nonmetalloid.
8, the functional fiber that contains protein according to claim 1, it is characterized in that: described nonmetalloid is at least two kinds of different nonmetalloids.
9, according to claim 7 or the 8 described functional fibers that contain protein, it is characterized in that: the described material that contains nonmetalloid is non-metallic atom, nonmetal molecule, nonmetallic ion, nonmetal oxide, nonmetallic compound, contain the composition of nonmetalloid.
10, manufacturing is as the method for claim 1,2,3,4,5,6,7 or 8 described fibers, it is characterized in that: produce spinning solution earlier, again spinning solution is carried out after the deaeration with wet method or dry-jet wet spinning spinning, silk by the spinning machine ejection enters coagulation bath, after drawing-off, enter and make semi-finished product in the style keeping liquid, semi-finished product are finished product again after dyeing and finishing of dyeing and finishing liquid and acetalation, in this process, the material that contains nonmetalloid should add at least a liquid in spinning solution, coagulation bath, style keeping liquid and the dyeing and finishing liquid.
11, manufacturing is as the method for claim 1,2,3,4,5,6,7 or 8 described fibers, it is characterized in that: produce spinning solution earlier, again spinning solution is carried out carrying out dry spinning after the deaeration, enter after drawing-off by the silk of spinning machine ejection and to make semi-finished product in the style keeping liquid, semi-finished product are finished product again after dyeing and finishing of dyeing and finishing liquid and acetalation, in this process, the material that contains nonmetalloid should add at least a liquid in spinning solution, style keeping liquid and the dyeing and finishing liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410010167 CN1676686A (en) | 2004-03-30 | 2004-03-30 | Protein-containing functional fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410010167 CN1676686A (en) | 2004-03-30 | 2004-03-30 | Protein-containing functional fiber |
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| CN1676686A true CN1676686A (en) | 2005-10-05 |
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| CN 200410010167 Pending CN1676686A (en) | 2004-03-30 | 2004-03-30 | Protein-containing functional fiber |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008140337A1 (en) | 2007-05-09 | 2008-11-20 | Instytut Wlókien Naturalnych (Institute Of Natural Fibres) | Cellulose fibre textiles containing nanolignins, a method of applying nanolignins onto textiles and the use of nanolignins in textile production |
| CN106700565A (en) * | 2016-12-02 | 2017-05-24 | 江苏新瑞贝科技股份有限公司 | Imitated protein fiber fabric printing masterbatch suitable for print-forming technology |
-
2004
- 2004-03-30 CN CN 200410010167 patent/CN1676686A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008140337A1 (en) | 2007-05-09 | 2008-11-20 | Instytut Wlókien Naturalnych (Institute Of Natural Fibres) | Cellulose fibre textiles containing nanolignins, a method of applying nanolignins onto textiles and the use of nanolignins in textile production |
| CN106700565A (en) * | 2016-12-02 | 2017-05-24 | 江苏新瑞贝科技股份有限公司 | Imitated protein fiber fabric printing masterbatch suitable for print-forming technology |
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