CN1587162A - Luminous reflective concrete floor tile and its producing method - Google Patents
Luminous reflective concrete floor tile and its producing method Download PDFInfo
- Publication number
- CN1587162A CN1587162A CN 200410080257 CN200410080257A CN1587162A CN 1587162 A CN1587162 A CN 1587162A CN 200410080257 CN200410080257 CN 200410080257 CN 200410080257 A CN200410080257 A CN 200410080257A CN 1587162 A CN1587162 A CN 1587162A
- Authority
- CN
- China
- Prior art keywords
- luminous
- concrete
- floor tile
- granulated glass
- reflective
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Landscapes
- Floor Finish (AREA)
Abstract
The production process of luminous reflective concrete floor tile includes making base layer of common concrete material including cement, sand and stone, concrete additive and water, and through mixing, molding and vibrating; mixing the luminous reflective layer materials including cement, graded glass beads, luminous powder, color powder, concrete additive, dispersive glue powder and water via stirring; pouring the mixture on the freshly formed base layer; vibrating to densify and combine the base layer and the luminous reflective layer; demolding and curing. The luminous reflective concrete floor tile may be produced in plant or in site, and may be used widely in expressway, highway, sports ground, warehouse, building and other places needing luminous or fluorescent indication and warning.
Description
(1) technical field
The present invention relates to a kind of building slab and production method thereof, particularly a kind of floor tile and production method thereof.
(2) background technology
Existing floor tile such as concrete floor brick, concrete, polymkeric substance are synthetic floor tile configured, floor tile etc., and base layer is made by silicate materials such as concrete, clays, no luminous, the reflective characteristic in surface.On floor tile, increase luminous function if desired, generally, be coated on the floor tile base layer, or be stained with one deck luminescent screen making luminous paint after the mixing such as luminescent powder, resin, concrete admixture.Because luminescent layer is luminescent film coating or adhesive linkage that organic materials is formed, luminescent layer and base layer are two kinds of diverse materials and material, and therefore, luminescent coating is not easy to combine closely with coagulation great soil group base layer, can not obtain secular illumination effect.This floor tile is being used after a period of time, and luminescent layer just comes off easily and wears out, and perhaps weares and teares totally, and promptly its wear resisting property and lasting luminescent properties are relatively poor.On the other hand, after existing floor tile is subjected to irradiate light, the no-reflection characteristic.
(3) summary of the invention
The purpose of this invention is to provide a kind of luminous reflective concrete floor tile and production method thereof, the luminescent layer that solves floor tile come off easily and wear out, wear resisting property and the technical problem of luminescent properties difference lastingly; And solve existing floor tile and be subjected to opaque technical problem after the irradiate light.
Technical scheme of the present invention: this luminous reflective concrete floor tile, comprise matrix and luminous surface layer, it is characterized in that: be solidified as one by concrete substrate layer and the luminous reflecting surface layer that contains granulated glass sphere, the mixing ratio by weight of its luminous reflecting surface layer is as follows:
Cement 5～30%
Granulated glass sphere 60～85%
Luminescent powder 0～5%
Toner 0～5%
Concrete admixture 0.1-6%
Above-mentioned luminescent powder is the mixture of ZnS luminescent powder or ZnS luminescent powder and reflective beads.
Above-mentioned granulated glass sphere is the granulated glass sphere of grating, and wherein the range of choice of granulated glass sphere particle diameter is 20 orders, 30 orders, 40 orders, 60 orders, 80 orders, 100 orders, 200 orders and 325 orders, and specific refractory power is 1.5-1.75.
The proportioning of above-mentioned granulated glass sphere grating: 20 order 10-20%, 40 order 20-40%, 100 order 45-60% or 60 order 30-40%, 100 order 60-70%.
The kind selected of above-mentioned concrete admixture comprises cement water reducing agent 0.1～3%, concrete hardeners 0%～3% or redispersable latex powder: 0%～3%.
The production method 1 of this luminous reflective concrete floor tile is characterized in that following steps are arranged:
(1), cement, sandstone, concrete admixture, water are stirred, pour vibration, the closely knit base layer that is shaped in the mould into by the proportioning of making normal concrete;
(2), again with granulated glass sphere 60～85%, luminescent powder 0～5%, toner 0～5%, concrete admixture 0.1-6%, the re-dispersible glue powder 0%～3% of cement 5～30%, grating, adding water stirs, and be poured on the base layer of fresh moulding in the above-mentioned steps (1), form the luminous reflecting surface layer, through the vibratory compaction moulding, making concrete substrate layer and the luminous reflecting surface layer coagulation that contains granulated glass sphere is one again;
(3), after the demoulding, carry out maintenance, go out prefabricated luminous reflective concrete floor tile finished product in factory.
After the above-mentioned steps (3), carry out step (4): finished surface is washed, is polished, and obtains high reflective luminous floor tile.
The production method 2 of this luminous reflective concrete floor tile is characterized in that following steps are arranged:
(1), cement, sandstone, concrete admixture, water are stirred, pour vibration, the closely knit base layer that is shaped in the mould into by the proportioning of making normal concrete;
(2), again with granulated glass sphere 60～85%, luminescent powder 0～5%, toner 0～5%, concrete admixture 0.1-6%, the re-dispersible glue powder 0%～3% of cement 5～30%, grating, be stirred into the dryness powder, be sprinkling upon on the concrete substrate laminar surface of bleeding phase;
(3), condensed seven days after, adopt the way of sandblast and polishing to obtain the luminous reflective concrete floor tile of field fabrication.
Add slag in the normal concrete in the above-mentioned steps (1).
Add toner in the normal concrete in the above-mentioned steps (1).
The present invention utilizes the light of granulated glass sphere reflected illumination on concrete, utilizes luminescent powder to make the floor tile surface light emitting, utilizes reflective beads that the luminous reflectance of luminescent powder is amplified again, strengthens the luminescent properties on floor tile surface; Utilize cement, rubber powder and the concrete admixture caking agent as luminous and light reflecting material, make it to be consolidated securely, form the surface layer that has the luminous reflecting performance simultaneously, the present invention has following beneficial effect:
1., luminous reflecting surface layer and base layer material are same class material---concrete material, luminous reflecting surface layer and fresh concrete base layer coagulation are one, form the long-acting luminous reflecting surface layer of combining closely with base layer, no sharp interface layer between two-layer, condense firmly, product strength height, surface layer and base layer can not come off, layering; And production method is simple, practical, has reduced the cost of product.
2., because the thick 10～30mm that reaches of luminous reflecting surface layer, improved the wear resisting property and the lasting luminescent properties of floor tile luminescent layer, and solved existing floor tile and be subjected to opaque technical problem after the irradiate light.Still has luminous, reflecting effect after the concrete weathering.
3., in the concrete substrate formable layer, can add slag, flyash equal industrial residue, substitute the part cement consumption, help environment protection.
The present invention can prefabrication production, also can make at the construction field (site).Can extensively be used in the place that expressway, road, playground, warehouse, buildings etc. need noctilucence or fluorescence to indicate, warn, but and beautifying city night scene.
(4) description of drawings
Fig. 1 is the structural representation in luminous reflective concrete floor tile of the present invention longitudinal section.
(5) embodiment
Luminous reflective concrete floor tile embodiment of the present invention is referring to Fig. 1, and this luminous reflective concrete floor tile is solidified as one by concrete substrate layer 1 and the luminous reflecting surface layer 2 that contains granulated glass sphere.The thickness of its base layer 1 is 50-500mm, the thickness 10-30mm of luminous reflecting surface layer 2.
The mixing ratio by weight of concrete substrate layer 1 calculates by general normal concrete.
The mixing ratio by weight alternate embodiments of luminous reflecting surface layer 2 is as follows:
| Cement % | Granulated glass sphere % | Luminescent powder % | Toner % | Water reducer % | Concrete hardeners % | Re-dispersible glue powder % |
| 5 | 85 | 1.9 | 5.0 | 0.1 | 3.0 | 0 |
| 10 | 80 | 0 | 4.0 | 2.5 | 2.5 | 1.0 |
| 15 | 75 | 2.0 | 3.0 | 1.0 | 2.0 | 2.0 |
| 20 | 70 | 2.0 | 2.0 | 2.0 | 1.5 | 2.5 |
| 25 | 65 | 4.0 | 0.5 | 3.0 | 1.0 | 1.5 |
| 30 | 60 | 5.0 | 0 | 2.0 | 0 | 3.0 |
Cement content scope: 5～30%.
The granulated glass sphere content range: 60～85%, the grating of granulated glass sphere: can select particle diameter is that 20 orders, 30 orders, 40 orders, 60 orders, 80 orders, 100 orders, 200 orders, 325 orders, specific refractory power are the granulated glass sphere of 1.5-1.75.
The proportioning example of granulated glass sphere grating when higher-strength requires:
20 order granulated glass spherees 15%, 40 order granulated glass spherees 30%, 100 order granulated glass spherees 55%.
20 order granulated glass spherees 10%, 30 order granulated glass spherees 5%, 40 order granulated glass spherees 15%, 60 order granulated glass spherees 15%, 80 order granulated glass spherees 25%, 100 order granulated glass spherees 25%, 200 order granulated glass spherees 3%.325 order granulated glass spherees 2%.
The proportioning example of granulated glass sphere grating during general requirement:
60 order granulated glass spherees: 100 order granulated glass spherees 35%: 65%.
40 order granulated glass spherees: 60 order granulated glass spherees 5%: 80 order granulated glass spherees 30%: 100 order granulated glass spherees 15%: 50%.
The luminescent powder content range: 0～5%, above-mentioned luminescent powder is the mixture of ZnS luminescent powder or ZnS luminescent powder and reflective beads.Make the color reflective brick: select color reflective granulated glass sphere or colourless reflective beads color matching powder for use.Above-mentioned toner is to have good alkali-proof inorganic salt pigment, can select various different colours such as red iron oxide look as a setting, and the light of emission different colours can have: colors such as white, magneta colour, redness, fluorescence.Under rayed, reflective luminous brick reflection 60-85% light.
Concrete admixture content range: 0.1-6%, concrete admixture comprise water reducer 0.1～3%, concrete hardeners 0%～3%, re-dispersible glue powder: 0%～3%.
Production method embodiment one of the present invention:
(1), cement, sandstone, slag, toner, concrete admixture, water are stirred, pour vibration, the closely knit base layer that is shaped in the mould into by the proportioning of making normal concrete.
(2), again cement 5～30%, granulated glass sphere 60～85%, luminescent powder 0～5%, toner 0～5%, concrete admixture 0.1-6%, reflective beads, re-dispersible glue powder, Jia Shui are stirred, and be poured on the base layer of fresh moulding in the above-mentioned steps (1), form the luminous reflecting surface layer, through the vibratory compaction moulding, making concrete substrate layer and the luminous reflecting surface layer coagulation that contains granulated glass sphere is one again.
(3), after the demoulding, carry out maintenance, go out prefabricated luminous reflective concrete floor tile finished product in factory.
(4), finished surface is washed and sandblast, polishing, obtains high reflective luminous floor tile.
Production method embodiment two of the present invention:
(1), cement, sandstone, slag, toner, concrete admixture, water are stirred, pour vibration, the closely knit base layer that is shaped in the mould into by the proportioning of making normal concrete.
(2), again with granulated glass sphere 60～85%, luminescent powder 0～5%, toner 0～5%, concrete admixture 0.1-6%, reflective beads, the re-dispersible glue powder of cement 5～30%, grating, be stirred into the dryness powder, be sprinkling upon on the concrete substrate laminar surface of bleeding phase, it is closely knit to carry out press polish.
(3), condensed seven days after, adopt the way of sandblast and polishing to obtain the luminous reflective concrete floor tile of field fabrication.
Cement, granulated glass sphere, toner, ZnS luminescent powder, reflective beads, cement water reducing agent, concrete hardeners, redispersable latex powder, slag all have finished product to sell on market.
Claims (10)
1, a kind of luminous reflective concrete floor tile comprises matrix and luminous surface layer, it is characterized in that: be solidified as one by concrete substrate layer and the luminous reflecting surface layer that contains granulated glass sphere, the mixing ratio by weight of its luminous reflecting surface layer is as follows:
Cement 5～30%
Granulated glass sphere 60～85%
Luminescent powder 0～5%
Toner 0～5%
Concrete admixture 0.1-6%
2, luminous reflective concrete floor tile according to claim 1 is characterized in that: described luminescent powder is the mixture of ZnS luminescent powder or ZnS luminescent powder and reflective beads.
3, luminous reflective concrete floor tile according to claim 1, it is characterized in that: described granulated glass sphere is the granulated glass sphere of grating, wherein the range of choice of granulated glass sphere particle diameter is 20 orders, 30 orders, 40 orders, 60 orders, 80 orders, 100 orders, 200 orders and 325 orders, and specific refractory power is 1.5-1.75.
4, luminous reflective concrete floor tile according to claim 3 is characterized in that: the proportioning of described granulated glass sphere grating: 20 order 10-20%, 40 order 20-40%, 100 order 45-60% or 60 order 30-40%, 100 order 60-70%.
5, luminous reflective concrete floor tile according to claim 1 is characterized in that: the kind selected of described concrete admixture comprises cement water reducing agent 0.1～3%, concrete hardeners 0%～3% or redispersable latex powder: 0%～3%.
6, a kind of production method of luminous reflective concrete floor tile is characterized in that following steps are arranged:
(1), cement, sandstone, concrete admixture, water are stirred, pour vibration, the closely knit base layer that is shaped in the mould into by the proportioning of making normal concrete;
(2), again with granulated glass sphere 60～85%, luminescent powder 0～5%, toner 0～5%, concrete admixture 0.1-6%, the re-dispersible glue powder 0%～3% of cement 5～30%, grating, adding water stirs, and be poured on the base layer of fresh moulding in the above-mentioned steps (1), form the luminous reflecting surface layer, through the vibratory compaction moulding, making concrete substrate layer and the luminous reflecting surface layer coagulation that contains granulated glass sphere is one again;
(3), after the demoulding, carry out maintenance, go out prefabricated luminous reflective concrete floor tile finished product in factory.
7, the production method of luminous reflective concrete floor tile according to claim 6 is characterized in that: after the described step (3), carry out step (4): finished surface is washed, is polished, and obtains high reflective luminous floor tile.
8, a kind of production method of luminous reflective concrete floor tile is characterized in that following steps are arranged:
(1), cement, sandstone, concrete admixture, water are stirred, pour vibration, the closely knit base layer that is shaped in the mould into by the proportioning of making normal concrete;
(2), again with granulated glass sphere 60～85%, luminescent powder 0～5%, toner 0～5%, concrete admixture 0.1-6%, the re-dispersible glue powder 0%～3% of cement 5～30%, grating, be stirred into the dryness powder, be sprinkling upon on the concrete substrate laminar surface of bleeding phase;
(3), condensed seven days after, adopt the way of sandblast and polishing to obtain the luminous reflective concrete floor tile of field fabrication.
9, according to the production method of claim 6 or 8 described luminous reflective concrete floor tiles, it is characterized in that: add slag in the normal concrete in the described step (1).
10, according to the production method of claim 6 or 8 described luminous reflective concrete floor tiles, it is characterized in that: add toner in the normal concrete in the described step (1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410080257 CN1268570C (en) | 2004-09-29 | 2004-09-29 | Luminous reflective concrete floor tile and its producing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410080257 CN1268570C (en) | 2004-09-29 | 2004-09-29 | Luminous reflective concrete floor tile and its producing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1587162A true CN1587162A (en) | 2005-03-02 |
| CN1268570C CN1268570C (en) | 2006-08-09 |
Family
ID=34605055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410080257 Expired - Fee Related CN1268570C (en) | 2004-09-29 | 2004-09-29 | Luminous reflective concrete floor tile and its producing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1268570C (en) |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100355689C (en) * | 2005-06-06 | 2007-12-19 | 封拴虎 | High-intensity reflecting cement |
| WO2008075973A1 (en) * | 2006-12-20 | 2008-06-26 | Larry Arthur Bellamy | Stratifield cementitious composite |
| CN101805608A (en) * | 2010-03-08 | 2010-08-18 | 南昌大学 | Luminescent transparent cement-based material |
| CN102653980A (en) * | 2012-03-05 | 2012-09-05 | 姜鹏 | Light-emitting glass floor tile |
| CN103437259A (en) * | 2013-09-13 | 2013-12-11 | 中建商品混凝土成都有限公司 | Non-radioactive environment-friendly energy-accumulation luminous pervious concrete pavement and construction method thereof |
| CN103880354A (en) * | 2014-02-18 | 2014-06-25 | 安徽润杨电力器材有限公司 | Fluorescent concrete luminous pole and preparation method thereof |
| CN103896522A (en) * | 2014-03-05 | 2014-07-02 | 山东建筑大学 | High hardness concrete block capable of emitting light at night |
| US20140272284A1 (en) * | 2013-03-15 | 2014-09-18 | David M. Franke | Multi zone cementitious product and method |
| CN105803881A (en) * | 2016-05-05 | 2016-07-27 | 漳州市华瑞建材有限公司 | Road brick with self-luminous function and preparation method of road brick |
| CN106007514A (en) * | 2016-05-23 | 2016-10-12 | 华砂砂浆有限责任公司 | Energy-saving, environment-friendly and moisture-proof type fluorescent mortar |
| CN106946517A (en) * | 2016-12-20 | 2017-07-14 | 梁洲辅 | A kind of luminous water-permeable brick and preparation method thereof |
| CN106988181A (en) * | 2016-12-19 | 2017-07-28 | 梁洲辅 | A kind of luminous building block brick and preparation method thereof |
| CN107032694A (en) * | 2016-12-19 | 2017-08-11 | 梁洲辅 | A kind of luminous high pressure brick and preparation method thereof |
| AU2016202071B2 (en) * | 2006-12-20 | 2017-12-21 | Stratified Concrete Technologies Limited | Stratified cementitious composite |
| CN108529970A (en) * | 2018-05-09 | 2018-09-14 | 中建商品混凝土有限公司 | A kind of luminous pattern concrete and preparation method thereof, application |
| CN110386791A (en) * | 2019-08-23 | 2019-10-29 | 长安大学 | A kind of hydrophobic self-luminous fluorescent pavement material and preparation method thereof |
| CN110540378A (en) * | 2019-10-10 | 2019-12-06 | 四川蓝色星球科技有限公司 | Colored pavement material and preparation process thereof |
| CN111805692A (en) * | 2020-06-29 | 2020-10-23 | 成都市东宇市政设施制造厂 | Production process of PC (polycarbonate) luminous brick |
| CN112321263A (en) * | 2020-10-14 | 2021-02-05 | 武汉轻工大学 | Mixed luminescent material for road construction and preparation method thereof |
| CN113003997A (en) * | 2021-02-05 | 2021-06-22 | 广东至道先进土木工程材料技术研究有限公司 | Self-luminous light-transmitting concrete wallboard and preparation method thereof |
| US11117832B2 (en) | 2019-03-19 | 2021-09-14 | Jiangsu Arit New Materials Co., Ltd. | Fluorescent polycarboxylate superplasticizer and preparation method thereof |
| CN114956688A (en) * | 2022-05-30 | 2022-08-30 | 佛山市东鹏陶瓷有限公司 | Long-afterglow luminous flexible building material and preparation method thereof |
-
2004
- 2004-09-29 CN CN 200410080257 patent/CN1268570C/en not_active Expired - Fee Related
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100355689C (en) * | 2005-06-06 | 2007-12-19 | 封拴虎 | High-intensity reflecting cement |
| AU2016202071B2 (en) * | 2006-12-20 | 2017-12-21 | Stratified Concrete Technologies Limited | Stratified cementitious composite |
| WO2008075973A1 (en) * | 2006-12-20 | 2008-06-26 | Larry Arthur Bellamy | Stratifield cementitious composite |
| US8323782B2 (en) | 2006-12-20 | 2012-12-04 | Larry Arthur Bellamy | Stratified cementitious composite |
| CN101805608A (en) * | 2010-03-08 | 2010-08-18 | 南昌大学 | Luminescent transparent cement-based material |
| CN102653980B (en) * | 2012-03-05 | 2014-03-19 | 胡文超 | Light-emitting glass floor tile |
| CN102653980A (en) * | 2012-03-05 | 2012-09-05 | 姜鹏 | Light-emitting glass floor tile |
| US20140272284A1 (en) * | 2013-03-15 | 2014-09-18 | David M. Franke | Multi zone cementitious product and method |
| CN103437259A (en) * | 2013-09-13 | 2013-12-11 | 中建商品混凝土成都有限公司 | Non-radioactive environment-friendly energy-accumulation luminous pervious concrete pavement and construction method thereof |
| CN103437259B (en) * | 2013-09-13 | 2015-07-01 | 中建商品混凝土成都有限公司 | Non-radioactive environment-friendly energy-accumulation luminous pervious concrete pavement and construction method thereof |
| CN103880354A (en) * | 2014-02-18 | 2014-06-25 | 安徽润杨电力器材有限公司 | Fluorescent concrete luminous pole and preparation method thereof |
| CN103896522A (en) * | 2014-03-05 | 2014-07-02 | 山东建筑大学 | High hardness concrete block capable of emitting light at night |
| CN105803881A (en) * | 2016-05-05 | 2016-07-27 | 漳州市华瑞建材有限公司 | Road brick with self-luminous function and preparation method of road brick |
| CN106007514A (en) * | 2016-05-23 | 2016-10-12 | 华砂砂浆有限责任公司 | Energy-saving, environment-friendly and moisture-proof type fluorescent mortar |
| CN106007514B (en) * | 2016-05-23 | 2018-09-04 | 华砂砂浆有限责任公司 | A kind of energy conservation and environmental protection damp-proof fluorescence mortar |
| CN107032694A (en) * | 2016-12-19 | 2017-08-11 | 梁洲辅 | A kind of luminous high pressure brick and preparation method thereof |
| CN106988181A (en) * | 2016-12-19 | 2017-07-28 | 梁洲辅 | A kind of luminous building block brick and preparation method thereof |
| CN106946517A (en) * | 2016-12-20 | 2017-07-14 | 梁洲辅 | A kind of luminous water-permeable brick and preparation method thereof |
| CN108529970A (en) * | 2018-05-09 | 2018-09-14 | 中建商品混凝土有限公司 | A kind of luminous pattern concrete and preparation method thereof, application |
| US11117832B2 (en) | 2019-03-19 | 2021-09-14 | Jiangsu Arit New Materials Co., Ltd. | Fluorescent polycarboxylate superplasticizer and preparation method thereof |
| CN110386791A (en) * | 2019-08-23 | 2019-10-29 | 长安大学 | A kind of hydrophobic self-luminous fluorescent pavement material and preparation method thereof |
| CN110540378A (en) * | 2019-10-10 | 2019-12-06 | 四川蓝色星球科技有限公司 | Colored pavement material and preparation process thereof |
| CN111805692A (en) * | 2020-06-29 | 2020-10-23 | 成都市东宇市政设施制造厂 | Production process of PC (polycarbonate) luminous brick |
| CN112321263A (en) * | 2020-10-14 | 2021-02-05 | 武汉轻工大学 | Mixed luminescent material for road construction and preparation method thereof |
| CN113003997A (en) * | 2021-02-05 | 2021-06-22 | 广东至道先进土木工程材料技术研究有限公司 | Self-luminous light-transmitting concrete wallboard and preparation method thereof |
| CN113003997B (en) * | 2021-02-05 | 2022-10-11 | 广东至道先进土木工程材料技术研究有限公司 | Self-luminous light-transmitting concrete wallboard and preparation method thereof |
| CN114956688A (en) * | 2022-05-30 | 2022-08-30 | 佛山市东鹏陶瓷有限公司 | Long-afterglow luminous flexible building material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1268570C (en) | 2006-08-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1268570C (en) | Luminous reflective concrete floor tile and its producing method | |
| CN1888317A (en) | Illuminating light reflective concrete curb and producing method thereof | |
| CN1135281C (en) | Paving method of water-permeable concrete | |
| CN1040033C (en) | Skid-resistant pavement markings | |
| CN100554584C (en) | Spary forms on the porous polymer concrete facing colored road surface and job practices | |
| CN100529261C (en) | Rolled polymer modified cement-concrete sprayed colour road surface structure, and its construction method | |
| CN100552136C (en) | Spary forms on the honeycombed cement concrete pavement colored road surface and job practices | |
| CN1745218A (en) | Composite brick | |
| CN1152174C (en) | Surface finish of cementitous nature and containing glass beads | |
| KR100982653B1 (en) | Rapid setting polymer cement mortar composite, manufacturing method of boundary block using the composite and boundary block manufactured by the method | |
| KR101310333B1 (en) | Separation block with permeability and the identity and its manufacturing method | |
| CN101074577A (en) | Anti-skid penetrating color brick of lump pyrite fired slag and its production | |
| CN1201052C (en) | Construction method of walking typhlosole with integrally poured decorative concrete on site | |
| US20110121484A1 (en) | Method of producing a color enhanced surface seeded exposed aggregate concrete | |
| KR100775993B1 (en) | Color permeable stone and pavement method thereof | |
| CN1197810C (en) | Ground tile having natural color and lustre and process for producing same | |
| CN1255467A (en) | colour floor tiles and production technology thereof | |
| EP2644341B1 (en) | Method for manufacturing a reflective construction element. | |
| KR100945591B1 (en) | Mineral liquid pigment for paving color of road, and the method for paving colored road using thereof | |
| KR930011265B1 (en) | Ceramic packing block | |
| CN1292132C (en) | Reinforced manhole cover and its making method | |
| CN2734891Y (en) | Luminous and reflecting concrete floor tile | |
| CN200952122Y (en) | Illuminating reflective concrete curb | |
| KR20020072684A (en) | Double structural curb attached polymer concrete and manufacturing method thereof | |
| CN114908627B (en) | Basic magnesium sulfate cement-based self-luminous brick material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060809 Termination date: 20170929 |