CN1426576A - Sound absorptive material - Google Patents
Sound absorptive material Download PDFInfo
- Publication number
- CN1426576A CN1426576A CN01808532.6A CN01808532A CN1426576A CN 1426576 A CN1426576 A CN 1426576A CN 01808532 A CN01808532 A CN 01808532A CN 1426576 A CN1426576 A CN 1426576A
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- Prior art keywords
- cement
- composition
- filler
- agent
- water
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
- C04B28/065—Calcium aluminosulfate cements, e.g. cements hydrating into ettringite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28C—PREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28C5/00—Apparatus or methods for producing mixtures of cement with other substances, e.g. slurries, mortars, porous or fibrous compositions
- B28C5/003—Methods for mixing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/14—Minerals of vulcanic origin
- C04B14/18—Perlite
- C04B14/185—Perlite expanded
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- G—PHYSICS
- G10—MUSICAL INSTRUMENTS; ACOUSTICS
- G10K—SOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
- G10K11/00—Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/16—Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
- G10K11/162—Selection of materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/52—Sound-insulating materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Civil Engineering (AREA)
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Multimedia (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Building Environments (AREA)
Abstract
Cement base composition includes water, cement mixture and a filling. Said filling not only provides volume but also provides air holes for absorbing sound. Said air holes exist in filling materials. It also includes a kind of air-entraining agent for producing air bubbles thus further providing air holes.
Description
Invention field
The preparation method who relates to cement base composition and said composition that the present invention is total.More specifically, the present invention relates to a kind of improved cement base composition and preparation method thereof with sound-absorbing character.
Background of invention
Durable has the sound absorption properties of enhancing and has fire line, makes cement-based material (cementitious materials) receive welcome in the extreme.
At present, realizing the highly acoustical performance of cement base composition, is by adding gas-development agent in composition, causing the various chemical reactions that produce gas before cement-based material generation hydro-combination process or in the process.Adding gas-development agent in composition needs a stage and combination process complexity usually, also needs extra and more complicated mixing apparatus.Therefore, the purpose of this invention is to provide a kind of cement base composition that does not use complicated gas-development agent but have remarkable sound absorption properties, it can be made by simpler method.
Summary of the invention
Therefore, the invention provides a kind of cement base composition, it contains water, cement admixture (cementmix) and a kind of filler (aggregate), and this filler not only can provide volume to assemble (bulk), and the pore that is used to absorb sound (air pores) is provided.These pores itself are present in the filler material, can not be fully in producing the fusion process of acoustical material and water compatible, thereby be not excluded fully.In addition, also provide a kind of compound that produces gas, this compound is reflected at initial stage of hydration process and cement and produces bubble in the cement base composition, in order to pore or hole (voids) further are provided in composition.
In preferred embodiments, this filler with pore is expanded perlite or expanded vermiculite, and it is with preventing that agent (water repelling admixture) is pretreated.Cement admixture comprises cement, Portland cement (OPC) and for finishing common hydration reaction for example, and give needed rigidizer of composition intensity (hardening admixture) and water reducer (waterreducing admixture) as early as possible.The aerogenesis compound is aluminium powder preferably, and preferably provides a kind of reinforcing fiber to improve intensity.Aluminium powder and cement admixture reaction increase hole.In the most preferred embodiment, gypsum, unslaked lime and a kind of correctives (modulator/regulator) also are added in the potpourri.
Those skilled in the art are based on the instruction of following disclosure, can determine the combination and the consumption of said components according to the quantity of required compressive strength of material and required pore.Method and composition of the present invention can produce void content 15%-80% and 200kg/m
3-1000kg/m
3The porous structure of dry density (drydensity).
The method for optimizing of making this material prevents the agent pretreated filler with a kind of before being included in and mixing with other component of composition, and/or makes this filler carry out prehydration to react.
A kind of method of making this acoustical material may further comprise the steps:
(a), or use a kind of with preventing the filler that agent is pretreated with preventing that agent from carrying out pre-service to filler;
(b) with cement and the even dried one that blendes together of fiber;
(c) water reducer, air entraining agent (gas forming admixture), correctives, unslaked lime and gypsum are mixed with suitable quantity of water;
(d) potpourri with step (a) mixes with the blending ingredients of step (b);
(e) potpourri with step (d) mixes with the potpourri of step (c);
(f) final mixture of step (e) is cast and solidify.
Major advantage of the present invention is: cement base composition has constituted can directly be used for making concrete material of main part.And this acoustical material uses the mixing apparatus of simple mixed method and standard to make.Another advantage is: the sound-absorbing character of this material, that is, void content can be controlled by the ratio that changes each component in the composition, rather than changes mixed process.This wet mixture also has low relatively water cut, makes mixed process relatively easy, and curing and dry run are very quick.
The accompanying drawing summary
Fig. 1 is the synoptic diagram of moulding product, and it can improve cement-based material sound absorption qualities of the present invention.All sizes all are millimeters (mm).
Detailed Description Of The Invention
In this instructions and following claim book, the implication of term " composition ", " comprising " and " containing " all is open, is construed as the implication of " comprise but do not limit ... ".
Comprise following component in the preferred embodiment of the invention:
1, cement admixture comprises:
(a) cement: sulphur aluminium cement (Sulphur Aluminate Cement) or Portland cement;
(b) early strength agent (hardening accelerator) or hardening agent potpourri (hardeningadmixture), for example ferrous sulphate (FeSO
4), and water reducer, the example of indefiniteness is Sikament163 EX, from Hong Kong New Territories, and Sika Hongkong Ltd.of Shatin.
2, the filler of handling: be that maximal density is 120kg/m
3, diameter is less than or equal to the expanded perlite of 3mm, and with preventing that agent from handling, guarantees that the water-intake rate of filler is less than or equal to 150% of perlite volume.
3, water
4, air entraining agent, for example purity is at least at 98% aluminium powder;
5, correctives, for example purity is at least at 98% potassium hydroxide (KOH);
6, unslaked lime (CaO);
7, gypsum
8, reinforcing fiber (Strengthening fibers): mekralon; With
9, water-proofing treatment optionally: silicon resin base is handled.
The preferred blending ratio of each component is listed in table 1
| Sequence number | Component | Preferred blending ratio scope |
| ????1 | Cement: filler | 1: 3-1: 8 (volume ratio) |
| ????2 | Water reducer | 0.8%-1.2% based on cement weight |
| ????3 | Aluminium powder | 0.1%-1% based on cement weight |
| ????4 | Correctives (KOH) | 0.06%-0.1% based on cement weight |
| ????5 | Hardening agent (iron sulfate) | 3%-5% based on cement weight |
| ????6 | Gypsum | 0.5%-2% based on cement weight |
| ????7 | Unslaked lime | 1.5%-2.5% based on cement weight |
| ????8 | Mekralon | 0.005%-0.5% based on cement weight |
| ????9 | Cement: water | ????1∶0.7-1∶1.7 |
| ????10 | Compressibility coefficient | ????1.1-1.8 |
The embodiment of a mixed process is shown in table 2.
| Project | Process |
| ??1 | The pre-service of filler: the pre-service expanded perlite prevents that with convention amount agent material jet expansion perlite is till filling surface is coated |
| ??2 | The prehydration of filler: change project 3 immediately over to behind the expanded perlite in above-mentioned 1 and the water mixing homogeneous |
| ??3 | Following component was mixed 10 minutes according to the record ratio of above-mentioned table 1 or until fibrous material is dispersed (selecting preferably result) 3.3.1 cement 3.3.2 water reducer 3.3.3 gypsum 3.3.4 quick lime 3.3.5 hardening agent 3.3.6 reinforcing fiber 3.3.7 water |
| ??4 | Ratio according to above-mentioned table 1 record added following composition mixing 1 minute or reached homogeneous 4.1 air entraining agents 4.2 correctivess until mixing then |
| ??5 | Add filler (expanded perlite) then and also continue to mix to be capped gradually, and the color of potpourri is even until perlitic surf zone |
| ??6 | After above-mentioned project 5, can use mixing |
In case mix and to finish, potpourri is poured into a suitable mold at once and is compressed to desired compressibility air entraining agent with cement rapid reaction generation gas.Described compression also can comprise with concrete formation being the forming step of desirable profile.In preferred embodiments, the air-generating reaction of aluminium is to finish when the hydration process is finished.
In case predetermined profile forms, keep this cement base composition of saturated preferably at least 3 angels of this material to solidify, this coating material can be placed air drying a period of time then, 5 days at the most, maybe, for example following 18 hours at 110 ℃ with this material oven dry.
Desiccated surface at final products optionally sprays a kind of waterproof sealing agent, and organic siliconresin for example is to reduce hydroscopicity, the patience of reinforcing material.Final cement-based material is a kind of porous honeycomb structure of opening, and it has strengthened the absorbability of sound and do not absorbed moisture content, 100% not containing asbestos deposit fibres, polystyrene and cellulose, and 100% fire prevention.The void content of material is the 15-80% of dry density, and the dry density that has is 200-1000kg/m
3, compressive strength is up to 4.2Mpa.
A concrete example of spendable this material is shown in table 3.The method of material is set forth in table 4 shown in concrete mixture table 3.Adopt the method shown in described material of table 3 and the table 4, this acoustical material will have 560kg/m at least
3Density and the compressive strength of 2.75Mpa at least.The sound-absorption coefficient of this material surpasses listed standard in the table 5.A sample that has used the material of producing according to the instruction of table 3 and table 4 to make profile shown in Figure 1, " utilize the acoustic absorption of reverberation chamber method and the standard method of test of sound absorption coefficient " according to ASTM (American Society for Tests and Materials) C423-84A (Standard Test Method for Sound Absorption and Sound AbsorptionCoefficients by the Reverberation Room Method) or ISO (International Standards Organization) 354 " measure the standard of absorption coefficient " (Standard Method for theMeasurements of Absorption Coefficients in a Reverberation Room) in reverberation chamber, measured its actual sound absorption coefficient, its result is referring to table 6.
Table 3
| ??1 | The blending ratio of cement and filler is every 0.08-1m 3Perlite mix 30 kilograms of cement, this perlitic density is no more than 120kg/m 3, and diameter 0.05-3mm |
| ??2 | The blending ratio of water reducer is 0.8% of a cement weight |
| ??3 | The blending ratio of air entraining agent (aluminium powder) is 0.7% of a cement weight |
| ??4 | The blending ratio of correctives (KOH) is 0.08% of a cement weight |
| ??5 | The blending ratio of early strength agent (iron sulfate) is 4% of a cement weight |
| ??6 | The blending ratio of gypsum is 1.7% of a cement weight |
| ??7 | The blending ratio of unslaked lime is 2.5% of a cement weight |
| ??8 | Fibrous material (U.S. Orange Hill Bbrothers Chemical company, or similarly) add mixing with 02% of cement weight |
| ??9 | The ratio of water-cement: 0.7-1.0 |
| ??10 | Compressibility coefficient: 1.3 |
Table 4
| (a) | With preventing the agent pretreated filler, guarantee that water absorption coefficient is less than or equal to 150% of perlite volume. |
| (b) | Mix cement and fiber are dried. |
| (c) | With an amount of water water reducer, air entraining agent, correctives, unslaked lime and gypsum are mixed |
| (d) | Potpourri in (a) is mixed with the blending ingredients of (b) |
| (e) | (d) potpourri mixes with the potpourri of (c) |
The typical standard of table 5--sound absorption coefficient
| Sound absorption coefficient | ||||||
| Frequency (Hz) | ????125 | ????250 | ????500 | ????1000 | ????2000 | ????4000 |
| Coefficient | ????0.20 | ????0.60 | ????0.75 | ????0.85 | ????0.90 | ????0.90 |
The actual sound-absorption coefficient of a table 6--product that goes out constructed in accordance
| Sound absorption coefficient | ||||||
| Frequency (Hz) | ????125 | ????250 | ????500 | ????1000 | ????2000 | ????4000 |
| Coefficient | ????0.21 | ????0.66 | ????0.91 | ????0.93 | ????1.06 | ????0.98 |
Other performance according to the material of table 3 and the described manufacturing of table 4 is as shown in table 7.
Table 7
| Performance | Testing standard | The result |
| Density | ASTM?E761 | ?665kg/m 3 |
| Compressive strength | ASTM?E761 | -4.2MPa |
| Bond strength flame spread and smog expansion value | BA?5270?App.F ASTM?E84-87 | ?0.35Mpa ?0 |
| Noncombustibility | ASTM?E136 | ?0 |
Although the present invention is narrated, especially emphasized to have the component of particular range according to top table 1-6, should be appreciated that these forms only are to be used for explanation, can not be construed as limiting the present invention.Can expect that those of ordinary skill in the art can make multiple variation and modification fully under the prerequisite of not leaving flesh and blood described in the invention and scope.For example, used cement is Portland cement preferably, but other cement with similarity also can be used as substitute.Reinforcing fiber described in the table 2 is a mekralon, still, other reinforcing fiber, for example zirconium silicate fibre or their mixing also can be used.The preferable range of zirconium silicate fibre is 0.05-3%, and the scope of mekralon is 0.005-0.5%, is more preferably 0.005-0.02%.
Filler is preferably with preventing expanded perlite or expanded vermiculite or their potpourri that agent was handled.Cement: the proportional range by volume of filler is 1: 2-1: 9, preferred 1: 3-1: 8, and most preferably 1: 4-1: 5.Therefore the effect of water reducer has reduced the water-intake capacity of perlite or zirconates, has also reduced with cement and has mixed the needed water yield fully, has finally reduced drying time and has improved the intensity of final material.These all are to prevent agent owing to having used, the attendant advantages except that the effect that produces the hole at final acoustical material.
The preferred superfine aluminium power of aerating material, its concentration is 0.05-1% in cement weight, preferred 0.1-0.5% is more preferably 0.3-0.5%.Aluminium powder and portland cement reaction releasing hydrogen gas, hydrogen then produces hole in last hardening composition.Except in filler, finding the pore, can also find that these holes are in the inner existence of cement.The combination of hole in the cement and the pore in the filler provides the improvement effect of the sound-absorption coefficient of the product that the present invention makes just.The size in hole and quantity can be adjusted according to the particle diameter and the employed amount of filler and aluminium powder.As an indefiniteness example, use above-mentioned aluminium powder can in hardened cement, produce the hole of 0.1-1mm.
Claims (11)
1, a kind of cement base composition with sound absorbing power, described composition has the air hole structure that accounts for described material 15-80%, and the air dry density scope is 200kg/m3-1000kg/m3, and described composition contains: (a) cement admixture
(b) filler, and
(c) air entraining agent
Described material is characterised in that used filler with preventing that agent is pretreated, prevents the resident water of said pore part in the made process; Air entraining agent produces hole in the hardened cement potpourri.
2, according to the composition of claim 1, wherein, described said cement admixture comprises Portland cement, water reducer and hardening agent.
3, according to the composition of claim 2, the volume ratio of wherein said cement and filler is 1: 2-1: 9.
4, according to the composition of claim 3, also provide reinforcing fiber in the said composition.
5, according to the composition of claim 3, wherein said air entraining agent material is that concentration is the aluminium powder of the 0.05-1% of cement.
6, according to the composition of claim 3, wherein said filler is an expanded perlite, and cement is 1 with the dry volume ratio of expanded perlite: 2-1: 9.
7, according to the composition of claim 3, wherein, described fiber is a mekralon, and its concentration is the 0.005-0.5% of cement weight.
8, according to the composition of claim 2, wherein, this hardening agent is an iron sulfate, and it is the 3-5% of cement weight.
9, according to the composition of claim 3, it comprises that also concentration is the gypsum of 0.5-2% of cement weight and the unslaked lime of 1.5-2.5%.
10, make the method for cement based acoustical material, this acoustical material comprises cement, water reducer, correctives, reinforcing fiber, filler, air entraining agent and hardening agent; Described method comprises step:
(a) with preventing the agent pretreated filler;
(b) dry mixing cement and fiber make it evenly to be integral;
(c) water with water reducer, air entraining agent, correctives, unslaked lime and gypsum and requirement is mixed into one;
(d) potpourri with step (a) mixes with the blending ingredients of step (b);
(e) potpourri with step (d) mixes with the potpourri of step (c);
(f) final mixture in the step (e) is cast and solidify.
11, a kind of composition comprises:
(a) Portland cement
(b) filler, cement: the volume ratio of filler is 1: 3 to 1: 8;
(c) 0.8% of cement weight to 1.2% water reducer;
(d) 0.1% of cement weight to 1% aluminium powder;
(e) 0.06% of cement weight to 0.1% potassium hydroxide;
(f) 3% of cement weight to 5% iron sulfate;
(g) 0.5% of cement weight to 2% gypsum;
(h) 1.5% of cement weight to 2.5% unslaked lime;
(i) 0.005% of cement weight to 0.5% mekralon; With
(j) water, cement: water is 1: 0.7-1: 1.17;
The feature of said composition is that also mentioned component is combined and compacting, and compressibility coefficient is 1: 1-1: 8.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2001/001270 WO2003022776A1 (en) | 2001-08-24 | 2001-08-24 | Sound absorption material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1426576A true CN1426576A (en) | 2003-06-25 |
| CN1235186C CN1235186C (en) | 2006-01-04 |
Family
ID=4574849
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN01808532.6A Expired - Fee Related CN1235186C (en) | 2001-08-24 | 2001-08-24 | Sound absorptive material |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN1235186C (en) |
| HK (1) | HK1042818A2 (en) |
| WO (1) | WO2003022776A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103253953A (en) * | 2013-05-02 | 2013-08-21 | 湖南博通新型建材有限公司 | Energy-saving environment-friendly composite thermal insulation material for building |
| CN105330219A (en) * | 2015-12-01 | 2016-02-17 | 武汉大学 | Biomass power plant ash-based autoclaving-free aerated concrete sound absorbing and insulating brick and preparation method thereof |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003900156A0 (en) * | 2003-01-15 | 2003-01-30 | Commonwealth Scientific And Industrial Research Organisation | Cementitious products |
| DE102006005899B4 (en) | 2006-02-09 | 2009-01-08 | Knauf Perlite Gmbh | building board |
| US8070878B2 (en) * | 2007-07-05 | 2011-12-06 | United States Gypsum Company | Lightweight cementitious compositions and building products and methods for making same |
| DE102012020841A1 (en) * | 2011-12-05 | 2013-06-06 | Franken Maxit Mauermörtel GmbH & Co. | Mineral foam and method of making the same |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4978726A (en) * | 1972-12-05 | 1974-07-30 | ||
| DE2442183A1 (en) * | 1974-09-03 | 1976-03-11 | Bayer Ag | PROCESS FOR THE PRODUCTION OF SCREEDS FROM INORGANIC BINDERS IN THE FLOW PROCESS |
| FR2575457B2 (en) * | 1979-02-01 | 1987-02-13 | Marchand Pierre | NEW LIGHT AGGREGATE MATERIAL |
| JPS5572546A (en) * | 1979-11-05 | 1980-05-31 | Koizou Miyazumi | Sound absorbing panel for waterrrepellent building material |
| DE3150701C2 (en) * | 1981-12-21 | 1988-06-16 | Hans Kramer GmbH & Co KG, 4000 Düsseldorf | Process for the production of a flowable mass from a moist, crumbly, inorganic mixture of perlite or perlite and vermiculite, hydraulic binder, as well as surface-active and water-retaining agents by transferring to a liquid state by means of stirring or vibration, shaping pouring or adhesive application to surfaces |
| JPS6186471A (en) * | 1984-10-04 | 1986-05-01 | 日本シポレツクス工業株式会社 | Lightweight foamed concrete |
| AT389300B (en) * | 1985-04-22 | 1989-11-10 | Terranova Ind Gmbh | METHOD FOR PLASTERING WET AND / OR SALTY MASONRY, AND DRY MIXTURE FOR A CELL PRIMER FOR CARRYING OUT THE METHOD |
| DE3635260A1 (en) * | 1986-10-16 | 1988-04-28 | Wacker Chemie Gmbh | METHOD FOR MAKING WATER REPELLENT OF SUCTIONABLE INORGANIC CONSTRUCTION MATERIALS |
| IT8821413A0 (en) * | 1988-07-19 | 1988-07-19 | Isoren Anstalt | PROCEDURE FOR THE FORMATION OF SHEET-SHAPED ELEMENTS FOR BUILDINGS WITH HIGH THERMAL, ACOUSTIC INSULATION AND WATER-REPELLENCE CHARACTERISTICS AND SHEET-SHAPED ELEMENTS MADE WITH THE SAID PROCEDURE. |
-
2001
- 2001-08-24 WO PCT/CN2001/001270 patent/WO2003022776A1/en active Application Filing
- 2001-08-24 CN CN01808532.6A patent/CN1235186C/en not_active Expired - Fee Related
-
2002
- 2002-04-03 HK HK02102484A patent/HK1042818A2/en not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103253953A (en) * | 2013-05-02 | 2013-08-21 | 湖南博通新型建材有限公司 | Energy-saving environment-friendly composite thermal insulation material for building |
| CN103253953B (en) * | 2013-05-02 | 2015-06-03 | 湖南博通新型建材有限公司 | Energy-saving environment-friendly composite thermal insulation material for building |
| CN105330219A (en) * | 2015-12-01 | 2016-02-17 | 武汉大学 | Biomass power plant ash-based autoclaving-free aerated concrete sound absorbing and insulating brick and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| HK1042818A2 (en) | 2002-08-16 |
| CN1235186C (en) | 2006-01-04 |
| WO2003022776A1 (en) | 2003-03-20 |
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