CN1332290A - Uvioresistant fabric coating material - Google Patents
Uvioresistant fabric coating material Download PDFInfo
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- CN1332290A CN1332290A CN 00109816 CN00109816A CN1332290A CN 1332290 A CN1332290 A CN 1332290A CN 00109816 CN00109816 CN 00109816 CN 00109816 A CN00109816 A CN 00109816A CN 1332290 A CN1332290 A CN 1332290A
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Abstract
The fabric coating material of anti-ultraviolet ray of the present invention is made from silicon dioxide, titanium dioxide, mica powder, resin, and solvent as main raw materials, meanwhile with dispersant, anti-precipitant, germ resistant, anti-static agent, age resister and color paste etc. auxiliary agent being added, by stirring with high speed, sanding, sifting out, mixing colors processes. The said material has excellent capability of reflecting ultraviolet ray, sunlight and infrared ray as well as good stability and practicability. With the features of waterproof with good hand feeling and fastness to washing its widely used in umbrella, cushion etc. as textile coating layer.
Description
The present invention relates to a kind of fabric face coating material, is a kind of coating adhesive that fabric face plays uv reflectance and solar heat that is used for.
At present, because the change of ecological environment cause the amount of radiation on the ultraviolet ray arrival ground in the sunshine to increase, and ultraviolet too much irradiation is seriously influencing the health of human body.Along with improving constantly that people's self-protection is realized, come on the referred gradually agenda of Ultraviolet rays protection problem.People are more and more higher to the requirement of fabric and various protective materialss, and it is various functional to require fabric to have; Require various protective articless except that having its safeguard function that should have, also should be personalized, can be fit to people to requirement attractive in appearance.Therefore the fiber that has the people will have the uv reflectance function is made into cloth, and this fabric has just had anti-ultraviolet performance, but this processing mode, all influential to fabrication processes and equipment, and the cost height, therefore up to the present, the domestic industrialization product of not seeing as yet.Also there is the people to plate layer of metal film at polymer surfaces, change its anti-ultraviolet property, but the material feel that this mode makes is not good enough, outward appearance is single, and because that metal coating has is not corrosion-resistant, easily lose reflective characteristic, transcalent shortcoming, so on the scope of application, be restricted, be difficult to large-scale popularization.
The object of the present invention is to provide a kind of fabric surface treatments material that can be used for antiultraviolet, sunshine (heat), to overcome the deficiencies in the prior art.
The invention provides a kind of solvent-borne type fabric face coating material.With superfine silicon dioxide, titanium dioxide and mica powder is main reflecting material, and resin is main bonding and film forming matter, and solvent is a decentralized medium.
Silica used in the present invention, titanium dioxide and mica powder particle diameter are between 0.01～0.3 μ m, and wherein, the content of titanium dioxide is between 1～15%, and silica is between 1～10%, and mica powder is between 0～5%.According to the difference of instructions for use, select different-grain diameter titanium dioxide for use, can make the coating adhesive of different purposes.Use ordinary titanium dioxide, can be made into and be used for the coating adhesive that umbrella, parasols, tent, Mongolian fort, Bicycles and Motorcycles cushion are used; Can make with nano titanium oxide and to be mainly used in the coating adhesive that shirt, socks, clothes etc. are had relatively high expectations to color.
Resin used in the present invention is mainly vinyl chloride, vinyl isobutyl ether resin, polyacrylic resin, cinnamic acrylic ester copolymer resins, HCPE etc., or its combination, and resin demand is between 10～40%.
This coating material solvent for use is mainly acetone, toluene, dimethylbenzene, cyclohexane, ethyl acetate, butyl acetate, ethanol, ethylene glycol monobutyl ether etc., or its combination, and consumption is between 30～80%.
The auxiliary agent that this material uses mainly contains: the inorganic pigment dispersant, comprise sodium polyphosphate, polycarboxylic acids sodium type, polyacrylate type, phosphoric acid ester etc., consumption be generally amount of pigment 0.5～2% between; Aerosil antisettling agent, consumption are generally between 0～4%; Anti-microbial inoculum is mainly the adjacent ketone of s-triazine or isothiazole, and consumption is generally between 0～1%; Antistatic agent, comprise (stearmide ethyl dimethyl-beta-hydroxyethyl ammonium) nitrate (SN), (dodecanamide propyl trimethyl ammonium) Methylsulfate salt (CyastatLS), alkylaryl sulfonates, polyethylene glycol oxide alkylamine etc., consumption is generally between 0.001～0.5%; Age resister, consumption is generally between 0.001～0.5%.
Production process of the present invention is simple, and product cost is lower.Capital equipment is high speed dispersor, sand mill.Production process is mainly: 1～15g titanium dioxide, 1～10g silica, 0～5g mica powder and 20～60g solvent are added homogenizer, add inorganic pigment dispersant 0～2g successively under low speed, be uniformly dispersed.Use the horizontal sand mill dispersed color, measure the scraping blade fineness at any time, when the scraper plate fineness is lower than 20 μ m, stop sand milling.
Pigment suspension behind the sand milling is put back in the dispersion tank, add 40～100g film-forming resin solution, fully disperse, add 0～1g bactericide, 0～4g aerosil antisettling agent, 0.001～0.5g antistatic agent, 0.001～0.5g age resister then successively and adjust the flexibility auxiliary agent in right amount, use 10～20g solvent then, regulate viscosity, the discharging of sieving.
Material of the present invention can be adapted to the surface treatment of different fabrics.This product can be directly in fabric face blade coating and spraying, and also available its handled fiber surface, is made into cloth with it again.Better with appearance of fabrics and feel that this product treatment is crossed, also can make the final products of different colours.
This material has water resistance concurrently, has creatively solved solar heat and the ultraviolet ray direct irradiation problem to human body, thus method resulting fabric have good feel, excellent washable, resistance to acids and bases and wash after wearing property.This product is good to visible light, infrared ray and ultraviolet reflecting effect, and behind blade coating on the white 190 order woven dacrons one time, the solar heat reflection rate can reach more than 80%, and ultraviolet permeability is lower than 5%.
Further specify the present invention below in conjunction with embodiment.
Example 1
According to the desired properties requirement, calculate standard recipe and technical recipe, be ready to clean high speed dispersor, add 5g titanium dioxide (R～902), 2g silica, 1g mica powder, 25g acetone-toluene mixed solvent, 0.02g unsaturated polyester carboxylic acid, 0.05g AT-06,0.23g modified polyorganosiloxane (SP-3), 0.5g aerosil antisettling agent, high speed dispersion.Disperse to pump into the sand mill sand milling after 20 minutes, measure fineness at any time, when fineness is 20 μ m, stop sand milling.
10g highly-chlorinated polyethylene, 5g vinyl chloride-ethylene base isobutyl ether resin are dissolved in respectively in 40g acetone-toluene mixed solvent.Pigment dispersing thing behind the sand milling is added in the resin solution, add 0.1g antistatic agent, the anti-microbial inoculum of 0.05g, 0.05g age resister, add 11g acetone-toluene mixed solvent again and stir.Obtain even, fine and smooth, stable mixing coating fluid.
This coating fluid, behind blade coating on the white 190 order umbrella cloth one time, 130 ℃ of oven dry half a minute, the solar heat reflection rate that obtains being coated with once can reach 83%, and ultraviolet ray transmissivity is lower than 5%.
Example 2
In high speed dispersor, add 4g rutile titanium dioxide (R～902), 2g part silica, 2g mica powder, 31g acetone-butyl acetate-toluene mixed solvent, 0.02g unsaturated polyester carboxylic acid, 0.05gAT-06,0.23g modified polyorganosiloxane (SP-3), 0.5g aerosil antisettling agent, high speed dispersion.Disperse to pump into the sand mill sand milling after 20 minutes, measure fineness at any time, when fineness is 20 μ m, stop sand milling.
10g polyacrylic resin, 10g vinyl chloride-ethylene base isobutyl ether resin are dissolved in respectively in 40g acetone-butyl acetate-toluene mixed solvent mixed solvent.Pigment dispersing thing behind the sand milling is added in the resin solution, add 0.1g antistatic agent, the anti-microbial inoculum of 0.05g, 0.05g age resister, stir.Obtain even, fine and smooth, stable mixing coating fluid.
This coating fluid, behind blade coating on the white 190 order umbrella cloth one time, 130 ℃ of oven dry half a minute, the solar heat reflection rate that obtains being coated with once can reach 81%, and ultraviolet ray transmissivity is lower than 5%.
Example 3
In high speed dispersor, be sieved into nano titanium oxide 5g, 34g acetone-butyl acetate-toluene mixed solvent, 0.02g unsaturated polyester carboxylic acid, 0.05g AT-06,0.23g modified polyorganosiloxane (SP-3), 0.4g aerosil antisettling agent, high speed dispersion with mesh screen.Disperse to pump into the sand mill sand milling after 20 minutes, measure fineness at any time, when fineness is 15 μ m, stop sand milling.
10g polyacrylic resin, 10g vinyl chloride-ethylene base isobutyl ether resin are dissolved in respectively in 40g acetone-butyl acetate-toluene mixed solvent.Pigment dispersing thing behind the sand milling is added in the resin solution, add 0.1g antistatic agent, the anti-microbial inoculum of 0.15g, 0.05g age resister, stir.Obtain even, fine and smooth, stable mixing coating fluid.
This coating fluid, behind blade coating on the white 190 order umbrella cloth one time, 130 ℃ of oven dry half a minute, the solar heat reflection rate that obtains coating can reach 80%, and ultraviolet ray transmissivity is lower than 5%.
Claims (9)
1. fabric face coating material, it is a main raw material with silica, titanium dioxide, mica, resin, solvent, add auxiliary agents such as dispersant, antisettling agent, anti-microbial inoculum, antistatic additive, age resister and mill base simultaneously, through high-speed stirred, ball milling, sieve, process such as toning forms.It is characterized in that it is to be made by the raw material of following weight (g) ratio:
Solvent 30～80 resins 10～40
Silica 1～10 titanium dioxide 1～15
Mica powder 0～5 dispersant 0.5～2
Antisettling agent 0～4 anti-microbial inoculum 0～1
Antistatic agent 0.001～0.5 age resister 0.001～0.5.
2. coating material according to claim 1 is characterized in that: employed resin, be mainly vinyl chloride, vinyl isobutyl ether resin, polyacrylic resin, cinnamic acrylic ester copolymer resins, HCPE etc., or its combination.
3. coating material according to claim 1 is characterized in that: employed silica, titanium dioxide and mica powder, its particle diameter are 0.01～0.3 μ m.
4. coating material according to claim 1 is characterized in that: employed solvent for use is mainly acetone, toluene, dimethylbenzene, cyclohexane, ethyl acetate, butyl acetate, ethanol, ethylene glycol monobutyl ether etc.
5. coating material according to claim 1 is characterized in that: employed inorganic pigment dispersant comprises sodium polyphosphate, polycarboxylic acids sodium type, polyacrylate type, phosphoric acid ester etc.
6. coating material according to claim 1 is characterized in that: employed anti-microbial inoculum is mainly the adjacent ketone of s-triazine or isothiazole.
7. coating material according to claim 1, it is characterized in that: employed antistatic agent, comprise (stearmide ethyl dimethyl-beta-hydroxyethyl ammonium) nitrate (SN), (dodecanamide propyl trimethyl ammonium) Methylsulfate salt (CyastatLS), alkylaryl sulfonates, polyethylene glycol oxide alkylamine etc.
8. the preparation method of a fabric face coating material, it is characterized in that: it is that to utilize titanium dioxide, silica, mica powder etc. be reflecting material, resin is as film forming matter, after reflecting material being disperseed with high speed dispersor, after with sand mill pigment fully being disperseed, add resin and various auxiliary agent, form through stirring.
9. the preparation method of a kind of fabric face coating material according to claim 8, its feature also is: described auxiliary agent is dispersant, anti-settling agent, anti-microbial inoculum, antistatic agent, age resister.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00109816 CN1332290A (en) | 2000-07-06 | 2000-07-06 | Uvioresistant fabric coating material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00109816 CN1332290A (en) | 2000-07-06 | 2000-07-06 | Uvioresistant fabric coating material |
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| Publication Number | Publication Date |
|---|---|
| CN1332290A true CN1332290A (en) | 2002-01-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00109816 Pending CN1332290A (en) | 2000-07-06 | 2000-07-06 | Uvioresistant fabric coating material |
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|---|---|---|---|---|
| CN1313825C (en) * | 2004-09-23 | 2007-05-02 | 东华大学 | Texitile light ageing test instrument |
| CN101063023B (en) * | 2006-10-26 | 2010-06-16 | 杭州天堂伞业集团有限公司 | Imaginary powder type umbrella face fabric coating and coating method thereof |
| CN101311398B (en) * | 2007-05-25 | 2011-09-14 | 东丽纤维研究所（中国）有限公司 | Nanometer durable ultraviolet ray resistant textiles |
| CN102328465A (en) * | 2010-07-12 | 2012-01-25 | 南通全技纺织涂层有限公司 | Thermally insulating coating fabric with multiple structure of reflection layer and radiation layer |
| CN102604532A (en) * | 2012-03-05 | 2012-07-25 | 南京信息工程大学 | High-reflectivity paint as well as preparation method and application thereof |
| CN102943397A (en) * | 2012-11-12 | 2013-02-27 | 王洪福 | Efficient heat-insulated uvioresistant breathable light textile garment material printing and dyeing paint and preparation method thereof |
| CN102995406A (en) * | 2012-11-29 | 2013-03-27 | 陈小康 | Preparation method of ultraviolet-proof coating |
| CN103015182A (en) * | 2012-11-29 | 2013-04-03 | 陈小康 | Ultraviolet-proof coating |
| CN103046340A (en) * | 2012-12-25 | 2013-04-17 | 浙江蓝星控股集团有限公司 | Coating process for waterproof and anti-ultraviolet fabric |
| CN103333560A (en) * | 2013-06-13 | 2013-10-02 | 常熟市九洲电器设备有限公司 | Anti-aging polyvinyl chloride electrical appliance insulating paint |
| CN103355772A (en) * | 2013-07-29 | 2013-10-23 | 太仓明静纺织有限公司 | Sun-protecting clothing with hood |
| CN103469556A (en) * | 2013-08-21 | 2013-12-25 | 昆山铁牛衬衫厂 | Ultraviolet-proof antibacterial finishing agent |
| CN103952910A (en) * | 2014-03-25 | 2014-07-30 | 安徽柏拉图涂层织物有限公司 | Coating material for ship sail surface material |
| CN104005228A (en) * | 2014-05-22 | 2014-08-27 | 浙江蓝星印染有限公司 | Semi-transparent coating process of umbrella cloth |
| CN104131465A (en) * | 2014-08-14 | 2014-11-05 | 浙江辰鸿纺织品科技有限公司 | Coating and mordanting process for semi-shading window decoration |
| CN104153197A (en) * | 2014-08-14 | 2014-11-19 | 浙江辰鸿纺织品科技有限公司 | Mordanting process for half shading window decoration |
| CN104179012A (en) * | 2014-08-26 | 2014-12-03 | 无锡市奇盛针织手套厂 | Mould inhibitor for woolen fabric |
| CN104195814A (en) * | 2014-08-29 | 2014-12-10 | 句容市石狮冲压件厂 | Fabric treatment agent |
| CN104233781A (en) * | 2014-08-29 | 2014-12-24 | 句容市石狮冲压件厂 | Treating agent for fabric of outdoor tent |
| CN104233782A (en) * | 2014-08-29 | 2014-12-24 | 句容市石狮冲压件厂 | Fabric treating agent for outdoor clothes |
| CN104725907A (en) * | 2013-12-21 | 2015-06-24 | 海安县盛泰冷拉型钢有限公司 | Emulsion paint used for interior wall |
| CN104818611A (en) * | 2015-05-07 | 2015-08-05 | 哈尔滨工业大学 | Method of improving anti-ultraviolet performance of M5 fiber with tubular titanium dioxide |
| CN105200775A (en) * | 2015-11-12 | 2015-12-30 | 长兴县高强纺织有限公司 | Antibacterial soft finishing process of dacron fabric |
| CN105220459A (en) * | 2015-11-12 | 2016-01-06 | 长兴县高强纺织有限公司 | A kind of antibiotic soft finishing auxiliaries of polyester fabric |
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| CN105442300A (en) * | 2015-12-31 | 2016-03-30 | 李栋军 | Coating material for fabric coating finishing |
| CN105696351A (en) * | 2013-09-05 | 2016-06-22 | 浙江台华新材料股份有限公司 | Ultraviolet-proof fabric and ultraviolet-proof paint |
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| CN106023855A (en) * | 2016-07-26 | 2016-10-12 | 安徽饰界广告有限公司 | Rotary road flag |
| CN106164397A (en) * | 2014-01-31 | 2016-11-23 | 戴卡特隆有限公司 | Sun protection device |
| CN106205426A (en) * | 2016-07-26 | 2016-12-07 | 安徽饰界广告有限公司 | A kind of rotatable road flag |
| CN108329841A (en) * | 2018-03-12 | 2018-07-27 | 澳洋集团有限公司 | A kind of formula of thermodurable textile coating solution |
| CN108575444A (en) * | 2018-04-18 | 2018-09-28 | 浙江格林豪斯户外用品有限公司 | A kind of boxlike gardening tent of good fixing effect |
| CN109736075A (en) * | 2018-12-28 | 2019-05-10 | 杭州蓝色倾情服饰有限公司 | Uvioresistant fabrics and preparation method thereof |
| CN114311884A (en) * | 2021-12-15 | 2022-04-12 | 山东金宝电子股份有限公司 | Radiation-resistant anti-aging copper-clad laminate and preparation method thereof |
-
2000
- 2000-07-06 CN CN 00109816 patent/CN1332290A/en active Pending
Cited By (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1313825C (en) * | 2004-09-23 | 2007-05-02 | 东华大学 | Texitile light ageing test instrument |
| CN101063023B (en) * | 2006-10-26 | 2010-06-16 | 杭州天堂伞业集团有限公司 | Imaginary powder type umbrella face fabric coating and coating method thereof |
| CN101311398B (en) * | 2007-05-25 | 2011-09-14 | 东丽纤维研究所（中国）有限公司 | Nanometer durable ultraviolet ray resistant textiles |
| CN102328465A (en) * | 2010-07-12 | 2012-01-25 | 南通全技纺织涂层有限公司 | Thermally insulating coating fabric with multiple structure of reflection layer and radiation layer |
| CN102604532B (en) * | 2012-03-05 | 2013-09-18 | 南京信息工程大学 | High-reflectivity paint as well as preparation method and application thereof |
| CN102604532A (en) * | 2012-03-05 | 2012-07-25 | 南京信息工程大学 | High-reflectivity paint as well as preparation method and application thereof |
| CN102943397A (en) * | 2012-11-12 | 2013-02-27 | 王洪福 | Efficient heat-insulated uvioresistant breathable light textile garment material printing and dyeing paint and preparation method thereof |
| CN102995406A (en) * | 2012-11-29 | 2013-03-27 | 陈小康 | Preparation method of ultraviolet-proof coating |
| CN103015182A (en) * | 2012-11-29 | 2013-04-03 | 陈小康 | Ultraviolet-proof coating |
| CN103015182B (en) * | 2012-11-29 | 2014-08-13 | 陈小康 | Ultraviolet-proof coating |
| CN103046340A (en) * | 2012-12-25 | 2013-04-17 | 浙江蓝星控股集团有限公司 | Coating process for waterproof and anti-ultraviolet fabric |
| CN103046340B (en) * | 2012-12-25 | 2014-07-16 | 浙江蓝星控股集团有限公司 | Coating process for waterproof and anti-ultraviolet fabric |
| CN103333560A (en) * | 2013-06-13 | 2013-10-02 | 常熟市九洲电器设备有限公司 | Anti-aging polyvinyl chloride electrical appliance insulating paint |
| CN103355772A (en) * | 2013-07-29 | 2013-10-23 | 太仓明静纺织有限公司 | Sun-protecting clothing with hood |
| CN103469556A (en) * | 2013-08-21 | 2013-12-25 | 昆山铁牛衬衫厂 | Ultraviolet-proof antibacterial finishing agent |
| CN105696351B (en) * | 2013-09-05 | 2018-08-21 | 浙江台华新材料股份有限公司 | Uvr Protective Fabric, anti-ultraviolet paint |
| CN105696351A (en) * | 2013-09-05 | 2016-06-22 | 浙江台华新材料股份有限公司 | Ultraviolet-proof fabric and ultraviolet-proof paint |
| CN104725907A (en) * | 2013-12-21 | 2015-06-24 | 海安县盛泰冷拉型钢有限公司 | Emulsion paint used for interior wall |
| CN106164397B (en) * | 2014-01-31 | 2019-08-16 | 戴卡特隆有限公司 | Sun protection device |
| CN106164397A (en) * | 2014-01-31 | 2016-11-23 | 戴卡特隆有限公司 | Sun protection device |
| CN103952910B (en) * | 2014-03-25 | 2016-01-20 | 安徽柏拉图涂层织物有限公司 | A kind of sail fabric coating and preparation method thereof |
| CN103952910A (en) * | 2014-03-25 | 2014-07-30 | 安徽柏拉图涂层织物有限公司 | Coating material for ship sail surface material |
| CN104005228A (en) * | 2014-05-22 | 2014-08-27 | 浙江蓝星印染有限公司 | Semi-transparent coating process of umbrella cloth |
| CN104131465A (en) * | 2014-08-14 | 2014-11-05 | 浙江辰鸿纺织品科技有限公司 | Coating and mordanting process for semi-shading window decoration |
| CN104153197A (en) * | 2014-08-14 | 2014-11-19 | 浙江辰鸿纺织品科技有限公司 | Mordanting process for half shading window decoration |
| CN104131465B (en) * | 2014-08-14 | 2016-08-17 | 浙江辰鸿纺织品科技有限公司 | A kind of coating mordanting technique of half shading window decorations |
| CN104153197B (en) * | 2014-08-14 | 2016-01-13 | 浙江辰鸿纺织品科技有限公司 | A kind of mordanting technique of half shading window decorations |
| CN104179012A (en) * | 2014-08-26 | 2014-12-03 | 无锡市奇盛针织手套厂 | Mould inhibitor for woolen fabric |
| CN104233782A (en) * | 2014-08-29 | 2014-12-24 | 句容市石狮冲压件厂 | Fabric treating agent for outdoor clothes |
| CN104195814A (en) * | 2014-08-29 | 2014-12-10 | 句容市石狮冲压件厂 | Fabric treatment agent |
| CN104233781B (en) * | 2014-08-29 | 2016-05-25 | 句容市石狮冲压件厂 | A kind of fabric-treating agent for outdoor tent |
| CN104233781A (en) * | 2014-08-29 | 2014-12-24 | 句容市石狮冲压件厂 | Treating agent for fabric of outdoor tent |
| CN104818611B (en) * | 2015-05-07 | 2016-10-19 | 哈尔滨工业大学 | A kind of method that tubulose titanium dioxide improves M5 fiber uvioresistant performance |
| CN104818611A (en) * | 2015-05-07 | 2015-08-05 | 哈尔滨工业大学 | Method of improving anti-ultraviolet performance of M5 fiber with tubular titanium dioxide |
| CN105714474A (en) * | 2015-09-18 | 2016-06-29 | 安徽义林塑业有限公司 | Anti-aging PP spun-bonded nonwoven fabric and preparation method thereof |
| CN105200775A (en) * | 2015-11-12 | 2015-12-30 | 长兴县高强纺织有限公司 | Antibacterial soft finishing process of dacron fabric |
| CN105220459A (en) * | 2015-11-12 | 2016-01-06 | 长兴县高强纺织有限公司 | A kind of antibiotic soft finishing auxiliaries of polyester fabric |
| CN105256537A (en) * | 2015-11-13 | 2016-01-20 | 浙江森悦纺织科技有限公司 | Sun-screening finishing agent for polyester fabric |
| CN105442300A (en) * | 2015-12-31 | 2016-03-30 | 李栋军 | Coating material for fabric coating finishing |
| CN106023855A (en) * | 2016-07-26 | 2016-10-12 | 安徽饰界广告有限公司 | Rotary road flag |
| CN106205426A (en) * | 2016-07-26 | 2016-12-07 | 安徽饰界广告有限公司 | A kind of rotatable road flag |
| CN108329841A (en) * | 2018-03-12 | 2018-07-27 | 澳洋集团有限公司 | A kind of formula of thermodurable textile coating solution |
| CN108575444A (en) * | 2018-04-18 | 2018-09-28 | 浙江格林豪斯户外用品有限公司 | A kind of boxlike gardening tent of good fixing effect |
| CN109736075A (en) * | 2018-12-28 | 2019-05-10 | 杭州蓝色倾情服饰有限公司 | Uvioresistant fabrics and preparation method thereof |
| CN114311884A (en) * | 2021-12-15 | 2022-04-12 | 山东金宝电子股份有限公司 | Radiation-resistant anti-aging copper-clad laminate and preparation method thereof |
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