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CN113773718A - Cross flow fan and air conditioner regulator - Google Patents

Cross flow fan and air conditioner regulator Download PDF

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Publication number
CN113773718A
CN113773718A CN202010522118.6A CN202010522118A CN113773718A CN 113773718 A CN113773718 A CN 113773718A CN 202010522118 A CN202010522118 A CN 202010522118A CN 113773718 A CN113773718 A CN 113773718A
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China
Prior art keywords
mass
coupling agent
surfactant
primer
finish paint
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Application number
CN202010522118.6A
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Chinese (zh)
Inventor
李云蹊
温博
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Hisense Shandong Air Conditioning Co Ltd
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Hisense Shandong Air Conditioning Co Ltd
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Priority to CN202010522118.6A priority Critical patent/CN113773718A/en
Publication of CN113773718A publication Critical patent/CN113773718A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/002Priming paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2248Oxides; Hydroxides of metals of copper
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2275Ferroso-ferric oxide (Fe3O4)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/005Additives being defined by their particle size in general
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)

Abstract

The invention discloses a cross-flow fan and an air conditioner regulator, and belongs to the field of air conditioner regulators. The surface of the cross-flow fan is provided with a composite coating layer, wherein the composite coating layer comprises a primer layer and a finish paint layer, the primer layer comprises 10-25 mass% of film-forming resin, 0.5-5 mass% of first coupling agent, 0.01-3 mass% of surfactant and 70-89 mass% of water; the finishing paint layer comprises 5-20 mass% of film-forming resin, 0.5-5 mass% of graphite, 0.2-3 mass% of inorganic nanoparticles, 0.5-5 mass% of second coupling agent, 0.01-3 mass% of surfactant, 2-30 mass% of auxiliary agent and 70-93 mass% of water. The invention is applied to the aspect of cleaning of an air conditioner regulator, solves the problem that the antistatic and dustproof performance of the existing fan blade is not durable, and has the characteristics of strong and durable antistatic capability, good antifouling performance to diversified dirt, capability of inhibiting the growth of water drops and excellent durability.

Description

Cross flow fan and air conditioner regulator
Technical Field
The invention belongs to the field of air conditioner regulators, and particularly relates to a cross-flow fan and an air conditioner regulator.
Background
The cross flow fan is one of the important air conditioner functions, and the fan blade which is the mainstream at present is a resin base material, wherein AS resin is mainly used. However, the AS resin material has a surface that is prone to dust adhesion due to factors such AS high surface energy and strong surface polar groups; meanwhile, as the fan resin base material has insulativity, the fan resin base material is rubbed with air in the operation process to cause electrostatic accumulation so as to adsorb dust in the air, and the humidity of the internal environment of the air conditioner is higher, so that the adhesion and accumulation of the dust are aggravated. According to investigation and measurement, 20% -30% of dust in the air conditioner is accumulated on the surface of the fan at present, the dust is one of the most serious parts in the air conditioner, and further bacteria can be bred to pollute indoor air. Therefore, the improvement of the antifouling performance of the fan blades has important significance for ensuring the quality of the air conditioner.
Chinese patent CN106634157A discloses a fan blade, a preparation method thereof and a fan, comprising a primer layer and a finish paint layer; the primer layer comprises 5-20% of film-forming resin, 0.5-10% of matting powder, 0.5-2% of first coupling agent and 70-94% of first mixed solvent; the finishing paint layer comprises 0.3-5% of nano inorganic particles, 0.5-5% of antistatic agent, 0.5-5% of second coupling agent, 0.1-5% of dispersing agent, 0.5-5% of auxiliary agent and 75-98% of second mixed solvent. The surface of the fan blade has higher antistatic performance, low dust amount adsorbed and accumulated in long-term operation and long service life.
However, although the fan blade has high antistatic performance, the antistatic and dustproof performance of the fan blade is not durable due to small interaction among the components.
Disclosure of Invention
Aiming at the defects in the prior art, the main problem to be solved by the invention is to overcome the problem that the antistatic and dustproof performance of the conventional fan blade is not durable, and provide the cross-flow fan and the air conditioner regulator which have strong and durable antistatic capability, good antifouling performance on diversified dirt, capability of inhibiting the growth of water drops and excellent durability.
In order to solve the technical problem, the technical scheme adopted by the invention is as follows:
the invention provides a cross-flow fan, wherein the surface of the cross-flow fan is provided with a composite coating, the composite coating comprises a primer layer and a finish paint layer, the primer layer comprises 10-25 mass% of film-forming resin, 0.5-5 mass% of first coupling agent, 0.01-3 mass% of surfactant and 70-89 mass% of water;
the finishing paint layer comprises 5-20 mass% of film-forming resin, 0.5-5 mass% of graphite, 0.2-3 mass% of inorganic nanoparticles, 0.5-5 mass% of second coupling agent, 0.01-3 mass% of surfactant, 0-1 mass% of auxiliary agent and 70-93 mass% of water.
Preferably, the film-forming resin is at least one selected from the group consisting of acrylic resins, polyurethane resins, alkyd resins, fluorine resins, and epoxy resins.
Preferably, the surfactant is selected from an anionic surfactant or a polymeric surfactant;
the anionic surfactant is selected from at least one of sodium dodecyl benzene sulfonate, stearic acid and sodium dodecyl sulfate;
the high molecular type surfactant is at least one selected from sodium polymethacrylate, polyacrylamide, polyvinylpyrrolidone, polyoxyethylene stearate, acrylamide copolymer, polyethylene benzyl trimethyl ammonium salt and sodium carboxymethyl cellulose.
Preferably, the first coupling agent and the second coupling agent are each independently selected from at least one of a silane coupling agent, a bimetallic coupling agent, a titanate coupling agent, and an aluminate coupling agent,
optionally, the first coupling agent and the second coupling agent are each independently selected from at least one of n-octyltrimethoxysilane, dodecyltrimethoxysilane, octadecyltrimethoxysilane, octadecyltrichlorosilane, tridecafluorooctyltrimethoxysilane, tridecafluorooctyltriethoxysilane, perfluorodecyltriethoxysilane, perfluorodecyltrichlorosilane, methoxytrimethylsilane, hexamethyldisilazane, 2-bis (allyloxymethyl) -1-butoxytris (dioctylphosphonoxy) titanate, distearoyloxyisopropoxy aluminate, and (ethyl acetoacetate) diisopropoxyaluminate.
Preferably, the inorganic nanoparticles are selected from at least one of nano-silica, nano-alumina, nano-magnesia, nano-titania and nano-copper oxide; the average particle diameter of the inorganic nanoparticles is 10-100 nm.
Preferably, the auxiliary agent comprises a leveling agent.
Preferably, the primer layer has a thickness of 1 to 10 μm, and the topcoat layer has a thickness of 1 to 5 μm.
Preferably, the cross-flow fan is obtained by the following method:
adding 10-25 mass% of film-forming resin, 0.5-5 mass% of first coupling agent and 0.01-3 mass% of surfactant into 70-89 mass% of water, and uniformly mixing to obtain primer solution;
uniformly mixing 5-20 mass% of film-forming resin, 0.5-5 mass% of graphite, 0.2-3 mass% of inorganic nanoparticles, 0.5-5 mass% of second coupling agent, 0.01-3 mass% of surfactant, 0-1 mass% of auxiliary agent and 70-93 mass% of water to form a finish paint liquid;
spraying the primer liquid on the surface of the cross-flow fan substrate to form a primer layer;
and spraying the finish paint liquid on the surface of the primer layer to form a finish paint layer, and obtaining the cross-flow fan.
The invention also provides an air conditioner regulator which comprises the cross flow fan in any technical scheme.
Compared with the prior art, the invention has the beneficial effects that:
the cross-flow fan provided by the invention has the characteristics of strong and durable anti-static capability, good anti-fouling performance on diversified fouling, capability of inhibiting the growth of water drops and excellent durability, and is more environment-friendly because the traditional organic solvent is not used in a composite coating; the air conditioner regulator comprising the cross flow fan has better dustproof performance, improves the quality of the air conditioner, and ensures the health of human bodies.
Detailed Description
The technical solutions in the embodiments of the present invention will be fully described in detail below. It is obvious that the described embodiments are only some specific embodiments, not all embodiments, of the general technical solution of the present invention. All other embodiments, which can be derived by a person skilled in the art from the general idea of the invention, fall within the scope of protection of the invention.
The invention provides a cross-flow fan, wherein the surface of the cross-flow fan is provided with a composite coating, the composite coating comprises a primer layer and a finish paint layer, the primer layer comprises 10-25 mass% of film-forming resin, 0.5-5 mass% of first coupling agent, 0.01-3 mass% of surfactant and 70-89 mass% of water; the finishing paint layer comprises 5-20 mass% of film-forming resin, 0.5-5 mass% of graphite, 0.2-3 mass% of inorganic nanoparticles, 0.5-5 mass% of second coupling agent, 0.01-3 mass% of surfactant, 0-1 mass% of auxiliary agent and 70-93 mass% of water. The cross-flow fan has the characteristics of strong and durable anti-static capability, good antifouling performance to diversified dirt, capability of inhibiting growth of water drops and excellent durability. The raw materials of the composite coating do not use the traditional organic solvent, but the surfactant is added into the water to fully activate the molecules of the film-forming resin in the water, so that the film-forming resin is dispersed in the water, the use of the organic solvent is greatly reduced, and the use of the surfactant reduces the use of the organic solvent, so that the composite coating is more environment-friendly.
Further, the addition amount of the film-forming resin in the primer layer is limited to 10-25% of the total mass of the primer layer liquid, because the curing time of the coating is prolonged due to the excessively high content of the film-forming resin, the production efficiency is reduced, and the cost is increased; the film forming effect of the coating is not good easily caused by the low content of the film forming resin; the addition amount of the first coupling agent is limited to 0.5-5 mass percent, because the first coupling agent cannot play a role in crosslinking when the content of the first coupling agent is too low, so that the film forming property of the coating is poor, and the crosslinking degree of the coating is increased easily when the content of the first coupling agent is too high, the coating is hardened and the toughness of the coating is poor; the wear resistance of the composite coating can be further improved by adding the inorganic nano particles into the finish paint layer,the roughness of the composite coating is reduced, the addition amount of the inorganic nano particles is limited to be 0.5-5% of the total mass of the finishing paint liquid by the technical scheme, and the reason is that the formation of the coating is difficult to control due to the excessively high addition amount of the inorganic nano particles, the cost is greatly increased, and the wear resistance of the coating is poor due to the excessively low content of the inorganic nano particles; the graphite structure is relatively stable, cracking and breaking are not easy to occur, the effect is durable, the graphite is not easy to break to provide a carbon source for growth and attachment of microorganisms for small molecules, and meanwhile, the graphite and inorganic nanoparticles such as nano titanium dioxide and the like are jointly used as raw materials of a finish paint layer, so that on one hand, the nano zinc oxide and the nano titanium dioxide can play a role of an opacifier, and the long-term irradiation of ultraviolet light is prevented from causing the service life attenuation of the graphite; on the other hand, graphite can be mixed with part of inorganic nanoparticles (TiO)2、CuO、Cu2O、Fe3O4) The complex formulation can shorten the forbidden bandwidth of inorganic nano particles, or can excite electron-hole pairs to separate and decompose dust when potential energy such as temperature changes, and further improve the dustproof effect, so that the surface of the cross flow fan can have permanent antistatic performance by adding graphite into the finish paint layer, and the technical scheme also limits the addition amount of the graphite to be 0.5-5% of the total mass of the finish paint liquid, because the composite coating has stronger antistatic performance in the range; the addition amount of the second coupling agent is limited to 0.5-5 mass%, because the second coupling agent cannot play a role in crosslinking when the content of the second coupling agent is too low, so that the film forming property of the coating is poor, and the crosslinking degree of the coating is increased easily when the content of the second coupling agent is too high, the coating becomes hard, and the toughness of the coating is poor. Further, the embodiment also limits the addition of the film-forming resin in the finish paint layer, because the film-forming resin can enhance the bonding effect of the finish paint material, improve the material strength, improve the surface hardness and improve the corrosion resistance of the finish paint.
In a preferred embodiment, the film-forming resin is at least one selected from the group consisting of acrylic resin, polyurethane resin, alkyd resin, fluororesin, and epoxy resin. The technical scheme particularly limits the types of the film-forming resins, and the reason is that at least one of the film-forming resins can effectively improve the film-forming property of the primer layer, so that the performance of the composite coating is improved. It will be appreciated that the film-forming resin may also be other materials reasonably selected by one skilled in the art in combination with common general knowledge in the art.
In a preferred embodiment, the surfactant is selected from an anionic surfactant or a polymeric surfactant; the anionic surfactant is selected from at least one of sodium dodecyl benzene sulfonate, stearic acid and sodium dodecyl sulfate; the high molecular type surfactant is at least one selected from sodium polymethacrylate, polyacrylamide, polyvinylpyrrolidone, polyoxyethylene stearate, acrylamide copolymer, polyethylene benzyl trimethyl ammonium salt and sodium carboxymethyl cellulose. The technical solution defines the kind of surfactant in particular, it being understood that the surfactant may also be other substances reasonably selected by the person skilled in the art in combination with the common general knowledge in the art.
In a preferred embodiment, the first coupling agent and the second coupling agent are each independently selected from at least one of a silane coupling agent, a bimetallic coupling agent, a titanate coupling agent, and an aluminate coupling agent, optionally, the first coupling agent and the second coupling agent are each independently selected from at least one of n-octyltrimethoxysilane, dodecyltrimethoxysilane, octadecyltrimethoxysilane, octadecyltrichlorosilane, tridecafluoroctyltrimethoxysilane, tridecafluoroctyltriethoxysilane, perfluorodecyltriethoxysilane, perfluorodecyltrichlorosilane, methoxytrimethylsilane, hexamethyldisilazane, 2-bis (allyloxymethyl) -1-butoxytris (dioctylphosphonoxy) titanate, distearoyloxyisopropoxy aluminate, and (acetoacetic acid ethyl) diisopropoxyaluminate. The present solution defines in particular the type of first and second coupling agents, it being understood that the first and second coupling agents may also be other substances reasonably chosen by the person skilled in the art in combination with the common general knowledge in the field.
In a preferred embodiment, the inorganic nanoparticles are selected from at least one of nano-silica, nano-alumina, nano-magnesia, nano-titania and nano-copper oxide; the average particle diameter of the inorganic nanoparticles is 10-100 nm. The technical scheme further defines the types and average particle sizes of the inorganic nanoparticles, which is beneficial to further improving the wear resistance of the composite coating and obviously reducing the roughness of the composite coating, and it can be understood that the inorganic nanoparticles can also be other substances reasonably selected by the skilled person in combination with the common general knowledge in the art, and the average particle size can also be any point value within the ranges of 20nm, 30nm, 40nm, 50nm, 60nm, 70nm, 80nm and 90 nm.
In a preferred embodiment, the auxiliary agent comprises a leveling agent. The technical scheme specifically limits the types of the auxiliary agents, and it is understood that the auxiliary agents can also be other substances reasonably selected by the person skilled in the art in combination with the common knowledge in the field. It should be noted that the addition of the additive is beneficial to improving the performance of the composite coating, the cost is obviously increased due to the excessively high content of the additive, and the performance cannot be obviously improved continuously; if the content of the inorganic acid is too low, the performance of the composite coating is not obviously improved.
In a preferred embodiment, the primer layer has a thickness of 1-10 μm and the topcoat layer has a thickness of 1-5 μm. The technical scheme limits the thicknesses of the primer layer and the finish paint layer, and has the advantages that the cost is obviously increased due to overhigh thicknesses of the primer layer and the finish paint layer, the performance is not greatly increased, and the stability is reduced; the problem of poor wear resistance of the composite coating is easily caused when the thicknesses of the primer layer and the finishing paint layer are too low.
In a preferred embodiment, the cross-flow fan is obtained by:
adding 10-25 mass% of film-forming resin, 0.5-5 mass% of first coupling agent and 0.01-3 mass% of surfactant into 70-89 mass% of water, and uniformly mixing to obtain primer solution;
uniformly mixing 5-20 mass% of film-forming resin, 0.5-5 mass% of graphite, 0.2-3 mass% of inorganic nanoparticles, 0.5-5 mass% of second coupling agent, 0.01-3 mass% of surfactant, 0-1 mass% of auxiliary agent and 70-93 mass% of water to form a finish paint liquid;
spraying the primer liquid on the surface of the cross-flow fan substrate to form a primer layer;
and spraying the finish paint liquid on the surface of the primer layer to form a finish paint layer, and obtaining the cross-flow fan.
The invention also provides an air conditioner regulator which comprises the cross flow fan in any technical scheme. The air conditioner regulator has better dustproof performance, improves the quality of the air conditioner, and ensures the health of human bodies.
In order to more clearly and specifically describe a cross-flow fan and an air conditioner according to embodiments of the present invention, the following description will be made with reference to specific embodiments.
Example 1
Preparing a primer:
adding 20g of epoxy resin, 1g of first coupling agent dodecyl trimethoxy silane and 2g of surfactant dodecyl sodium benzenesulfonate into 75g of water, uniformly mixing, and stirring by adopting a high-speed stirrer at the rotating speed of 1500r/min for 60min so as to uniformly mix the ingredients to obtain the primer solution.
Preparation of the topcoat
Uniformly mixing 15g of epoxy resin, 3g of graphite, 0.5g of inorganic nano-particle titanium dioxide, 1g of second coupling agent methoxy trimethylsilane, 2g of surfactant sodium dodecyl benzene sulfonate, 0.5g of assistant leveling agent and 80g of water to form a finish paint liquid; and reacting the finish paint liquid at 50-70 ℃ for 2-6 h to obtain the finish paint. Specifically, at 50-70 ℃, the components can be uniformly dispersed or dissolved in a solvent to form a uniform solution within a certain time.
Forming a primer layer
In this step, a primer is sprayed on the surface of the fan blade base material to form a primer layer. Specifically, the fan blade substrate sprayed with the primer is dried in a ventilation hood at 120 ℃ for 2h, and the primer can be effectively cured on the surface of the cross-flow fan substrate so as to form the primer layer.
Forming a topcoat layer
In this step, a top coat is sprayed on the surface of the primer layer to form a top coat layer, and a cross flow fan with a composite coating is obtained. Specifically, due to the low boiling point of water used for preparing the finish paint, the fan blade substrate sprayed with the finish paint is dried in a ventilation kitchen for 4 hours at 120 ℃, so that the finish paint can be effectively cured on the surface of the primer, a finish paint layer is formed, and the cross-flow fan with the composite coating is obtained.
Example 2
Preparing a primer:
adding 18g of polyurethane, 1g of first coupling agent of methoxytrimethylsilane and 2g of surfactant of sodium dodecyl benzene sulfonate stearate into 75g of water, uniformly mixing, and stirring for 60min at the rotating speed of 1500r/min by using a high-speed stirrer so as to uniformly mix the ingredients to obtain the base paint liquid.
Preparation of the topcoat
Uniformly mixing 16g of film-forming resin, 4g of graphite, 0.6g of inorganic nano-particle silicon dioxide, 1g of second coupling agent dodecyl trimethoxy silane, 1.5g of surfactant dodecyl sodium sulfate, 0.5g of auxiliary agent leveling agent and 80g of water to form a finish paint liquid; and reacting the finish paint liquid at 50-70 ℃ for 2-6 h to obtain the finish paint. Specifically, at 50-70 ℃, the components can be uniformly dispersed or dissolved in a solvent to form a uniform solution within a certain time.
Forming a primer layer
In this step, a primer is sprayed on the surface of the fan blade base material to form a primer layer. Specifically, the fan blade substrate sprayed with the primer is dried in a ventilation hood at 120 ℃ for 2h, and the primer can be effectively cured on the surface of the cross-flow fan substrate so as to form the primer layer.
Forming a topcoat layer
In this step, a top coat is sprayed on the surface of the primer layer to form a top coat layer, and a cross flow fan with a composite coating is obtained. Specifically, due to the low boiling point of water used for preparing the finish paint, the fan blade substrate sprayed with the finish paint is dried in a ventilation kitchen for 4 hours at 120 ℃, so that the finish paint can be effectively cured on the surface of the primer, a finish paint layer is formed, and the cross-flow fan with the composite coating is obtained.
Example 3
Preparing a primer:
in aqueous solution, acrylic resin is prepared by reacting acrylic monomer with azodiisobutyronitrile as chain initiator and acrylic amide as surfactant.
Adding 22g of acrylic resin, 1g of first coupling agent diisopropoxyaluminate and 1.5g of surfactant acrylamide into 72g of water, uniformly mixing, and stirring by adopting a high-speed stirrer at the rotating speed of 1500r/min for 60min so as to uniformly mix the ingredients to obtain the primer solution.
Preparation of the topcoat
In aqueous solution, acrylic resin is prepared by reacting acrylic monomer with azodiisobutyronitrile as chain initiator and acrylic amide as surfactant.
Uniformly mixing 17g of acrylic resin, 3g of graphite, 0.5g of inorganic nano-particle cuprous oxide, 1g of second coupling agent, 0.5g of surfactant acrylamide sodium dodecyl benzene sulfonate and 75g of water to form a finish paint liquid; and reacting the finish paint liquid at 50-70 ℃ for 2-6 h to obtain the finish paint. Specifically, at 50-70 ℃, the components can be uniformly dispersed or dissolved in a solvent to form a uniform solution within a certain time.
Forming a primer layer
In this step, a primer is sprayed on the surface of the fan blade base material to form a primer layer. Specifically, the fan blade base material sprayed with the primer is dried in a ventilation kitchen for 2-6 hours at 120 ℃, and the primer can be effectively solidified on the surface of the cross-flow fan base material, so that the primer layer is formed.
Forming a topcoat layer
In this step, a top coat is sprayed on the surface of the primer layer to form a top coat layer, and a cross flow fan with a composite coating is obtained. Specifically, because the boiling point of water used for preparing the finish paint is low, the fan blade base material sprayed with the finish paint is dried in a ventilation kitchen for 2-6 hours at 120 ℃, so that the finish paint can be effectively cured on the surface of the primer, a finish paint layer is formed, and the cross-flow fan with the composite coating is obtained.
Example 4
Preparing a primer:
adding 18g of acrylic resin, 1g of first coupling agent dodecyl trimethoxy silane and 2g of surfactant dodecyl benzene sulfonate into 75g of water, uniformly mixing, and stirring by adopting a high-speed stirrer at the rotating speed of 1500r/min for 60min so as to uniformly mix the ingredients to obtain the primer solution.
Preparation of the topcoat
Mixing 17g of acrylic resin, 4g of graphite, 0.5g of inorganic nano-particle ferroferric oxide, 1g of second coupling agent, namely methoxytrimethylsilane, 2g of surfactant, namely sodium dodecyl sulfate, 0.5g of auxiliary agent, and 80g of water uniformly to form a finish paint liquid; and reacting the finish paint liquid at 50-70 ℃ for 2-6 h to obtain the finish paint. Specifically, at 50-70 ℃, the components can be uniformly dispersed or dissolved in a solvent to form a uniform solution within a certain time.
Forming a primer layer
In this step, a primer is sprayed on the surface of the fan blade base material to form a primer layer. Specifically, the fan blade base material sprayed with the primer is dried in a ventilation kitchen for 2-6 hours at 120 ℃, and the primer can be effectively solidified on the surface of the cross-flow fan base material, so that the primer layer is formed.
Forming a topcoat layer
In this step, a top coat is sprayed on the surface of the primer layer to form a top coat layer, and a cross flow fan with a composite coating is obtained. Specifically, because the boiling point of water used for preparing the finish paint is low, the fan blade base material sprayed with the finish paint is dried in a ventilation kitchen for 2-6 hours at 120 ℃, so that the finish paint can be effectively cured on the surface of the primer, a finish paint layer is formed, and the cross-flow fan with the composite coating is obtained.
Comparative example 1
Preparing a primer:
adding 18g of polyurethane, 1g of first coupling agent of methoxytrimethylsilane and 2g of surfactant of sodium dodecyl benzene sulfonate stearate into 75g of water, uniformly mixing, and stirring for 60min at the rotating speed of 1500r/min by using a high-speed stirrer so as to uniformly mix the ingredients to obtain the base paint liquid.
Preparation of the topcoat
Uniformly mixing 18g of film-forming resin, 0.6g of inorganic nano-particle magnesium oxide, 1g of second coupling agent dodecyl trimethoxy silane, 1.5g of surfactant lauryl sodium sulfate, 0.5g of auxiliary agent leveling agent and 80g of water to form a finish paint liquid; and reacting the finish paint liquid at 50-70 ℃ for 2-6 h to obtain the finish paint. Specifically, at 50-70 ℃, the components can be uniformly dispersed or dissolved in a solvent to form a uniform solution within a certain time.
Forming a primer layer
In this step, a primer is sprayed on the surface of the fan blade base material to form a primer layer. Specifically, the fan blade substrate sprayed with the primer is dried in a ventilation hood at 120 ℃ for 2h, and the primer can be effectively cured on the surface of the cross-flow fan substrate so as to form the primer layer.
Forming a topcoat layer
In this step, a top coat is sprayed on the surface of the primer layer to form a top coat layer, and a cross flow fan with a composite coating is obtained. Specifically, due to the low boiling point of water used for preparing the finish paint, the fan blade substrate sprayed with the finish paint is dried in a ventilation kitchen for 4 hours at 120 ℃, so that the finish paint can be effectively cured on the surface of the primer, a finish paint layer is formed, and the cross-flow fan with the composite coating is obtained.
Forming a primer layer
In this step, a primer is sprayed on the surface of the fan blade base material to form a primer layer. Specifically, the fan blade base material sprayed with the primer is dried in a ventilation kitchen for 2-6 hours at 120 ℃, and the primer can be effectively solidified on the surface of the cross-flow fan base material, so that the primer layer is formed.
Forming a topcoat layer
In this step, a top coat is sprayed on the surface of the primer layer to form a top coat layer, and a cross flow fan with a composite coating is obtained. Specifically, because the boiling point of water used for preparing the finish paint is low, the fan blade base material sprayed with the finish paint is dried in a ventilation kitchen for 2-6 hours at 120 ℃, so that the finish paint can be effectively cured on the surface of the primer, a finish paint layer is formed, and the cross-flow fan with the composite coating is obtained.
Comparative example 2
Preparing a primer:
adding 18g of acrylic resin, 1g of first coupling agent dodecyl trimethoxy silane and 2g of surfactant dodecyl benzene sulfonate into 75g of water, uniformly mixing, and stirring by adopting a high-speed stirrer at the rotating speed of 1500r/min for 60min so as to uniformly mix the ingredients to obtain the primer solution.
Preparation of the topcoat
Uniformly mixing 17g of acrylic resin, 4g of graphite, 1g of second coupling agent methoxy trimethylsilane, 2g of surfactant lauryl sodium sulfate, 0.5g of assistant leveling agent and 80g of water to form a finish paint liquid; and reacting the finish paint liquid at 50-70 ℃ for 2-6 h to obtain the finish paint. Specifically, at 50-70 ℃, the components can be uniformly dispersed or dissolved in a solvent to form a uniform solution within a certain time.
Forming a primer layer
In this step, a primer is sprayed on the surface of the fan blade base material to form a primer layer. Specifically, the fan blade base material sprayed with the primer is dried in a ventilation kitchen for 2-6 hours at 120 ℃, and the primer can be effectively solidified on the surface of the cross-flow fan base material, so that the primer layer is formed.
Forming a topcoat layer
In this step, a top coat is sprayed on the surface of the primer layer to form a top coat layer, and a cross flow fan with a composite coating is obtained. Specifically, because the boiling point of water used for preparing the finish paint is low, the fan blade base material sprayed with the finish paint is dried in a ventilation kitchen for 2-6 hours at 120 ℃, so that the finish paint can be effectively cured on the surface of the primer, a finish paint layer is formed, and the cross-flow fan with the composite coating is obtained.
Performance testing
The cross flow fans having the composite coatings prepared in examples 1 to 4 and comparative examples 1 to 2 were subjected to surface resistivity and surface electrostatic voltage tests, and the test results are shown in table 1.
TABLE 1 test results
Surface resistivity Surface electrostatic voltage
Example 1 107Ω/cm 36V
Example 2 106Ω/cm 14V
Example 3 108Ω/cm 91V
Example 4 106Ω/cm 11V
Comparative example 1 1015Ω/cm 346V
Comparative example 2 107Ω/cm 24V

Claims (9)

1. A crossflow fan having a composite coating on its surface, the composite coating comprising a primer layer and a topcoat layer,
the primer layer comprises 10 to 25 mass% of a film-forming resin, 0.5 to 5 mass% of a first coupling agent, 0.01 to 3 mass% of a surfactant, and 70 to 89 mass% of water;
the finishing paint layer comprises 5-20 mass% of film-forming resin, 0.5-5 mass% of graphite, 0.2-3 mass% of inorganic nanoparticles, 0.5-5 mass% of second coupling agent, 0.01-3 mass% of surfactant, 0-1 mass% of auxiliary agent and 70-93 mass% of water.
2. The crossflow fan of claim 1, wherein the film-forming resin is at least one selected from the group consisting of acrylic resin, urethane resin, alkyd resin, fluororesin, and epoxy resin.
3. The crossflow fan of claim 1, wherein the surfactant is selected from an anionic surfactant or a polymeric surfactant;
the anionic surfactant is selected from at least one of sodium dodecyl benzene sulfonate, stearic acid and sodium dodecyl sulfate;
the high molecular type surfactant is at least one selected from sodium polymethacrylate, polyacrylamide, polyvinylpyrrolidone, polyoxyethylene stearate, acrylamide copolymer, polyethylene benzyl trimethyl ammonium salt and sodium carboxymethyl cellulose.
4. The crossflow fan of claim 1, wherein the first coupling agent and the second coupling agent are each independently selected from at least one of a silane coupling agent, a bimetallic coupling agent, a titanate coupling agent, and an aluminate coupling agent,
optionally, the first coupling agent and the second coupling agent are each independently selected from at least one of n-octyltrimethoxysilane, dodecyltrimethoxysilane, octadecyltrimethoxysilane, octadecyltrichlorosilane, tridecafluorooctyltrimethoxysilane, tridecafluorooctyltriethoxysilane, perfluorodecyltriethoxysilane, perfluorodecyltrichlorosilane, methoxytrimethylsilane, hexamethyldisilazane, 2-bis (allyloxymethyl) -1-butoxytris (dioctylphosphonoxy) titanate, distearoyloxyisopropoxy aluminate, and (ethyl acetoacetate) diisopropoxyaluminate.
5. The crossflow fan of claim 1 wherein the inorganic nanoparticles are selected from at least one of nano-silica, nano-alumina, nano-magnesia, nano-titania, nano-copper oxide; the average particle diameter of the inorganic nanoparticles is 10-100 nm.
6. A crossflow fan as claimed in claim 1, characterized in that the auxiliary agent comprises a levelling agent.
7. The crossflow fan of claim 1 wherein the primer layer has a thickness of 1-10 μm and the topcoat layer has a thickness of 1-5 μm.
8. A crossflow fan as claimed in claim 1, which is obtained by:
adding 10-25 mass% of film-forming resin, 0.5-5 mass% of first coupling agent and 0.01-3 mass% of surfactant into 70-89 mass% of water, and uniformly mixing to obtain primer solution;
uniformly mixing 5-20 mass% of film-forming resin, 0.5-5 mass% of graphite, 0.2-3 mass% of inorganic nanoparticles, 0.5-5 mass% of second coupling agent, 0.01-3 mass% of surfactant, 0-1 mass% of auxiliary agent and 70-93 mass% of water to form a finish paint liquid;
spraying the primer liquid on the surface of the cross-flow fan substrate to form a primer layer;
and spraying the finish paint liquid on the surface of the primer layer to form a finish paint layer, and obtaining the cross-flow fan.
9. An air conditioner characterized by comprising the cross flow fan as recited in any one of claims 1 to 8.
CN202010522118.6A 2020-06-10 2020-06-10 Cross flow fan and air conditioner regulator Pending CN113773718A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004292686A (en) * 2003-03-27 2004-10-21 Asahi Kasei Chemicals Corp Aqueous composition for coating material
CN101189314A (en) * 2005-04-18 2008-05-28 陶氏康宁公司 Architectural coating compositions containing silicone resins
CN102010642A (en) * 2010-11-19 2011-04-13 东莞市金河田实业有限公司 Protective agent for radiator fan
CN105949970A (en) * 2016-07-08 2016-09-21 福建华夏蓝新材料科技有限公司 Waterborne coating with cracking effect
CN106317757A (en) * 2016-09-30 2017-01-11 美的集团股份有限公司 Antistatic and easy-to-clean material and preparation method thereof
CN106634157A (en) * 2016-12-29 2017-05-10 美的集团股份有限公司 Fan blade and preparing method thereof and fan
CN106854405A (en) * 2016-12-30 2017-06-16 美的集团股份有限公司 Antistatic coating and its application

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004292686A (en) * 2003-03-27 2004-10-21 Asahi Kasei Chemicals Corp Aqueous composition for coating material
CN101189314A (en) * 2005-04-18 2008-05-28 陶氏康宁公司 Architectural coating compositions containing silicone resins
CN102010642A (en) * 2010-11-19 2011-04-13 东莞市金河田实业有限公司 Protective agent for radiator fan
CN105949970A (en) * 2016-07-08 2016-09-21 福建华夏蓝新材料科技有限公司 Waterborne coating with cracking effect
CN106317757A (en) * 2016-09-30 2017-01-11 美的集团股份有限公司 Antistatic and easy-to-clean material and preparation method thereof
CN106634157A (en) * 2016-12-29 2017-05-10 美的集团股份有限公司 Fan blade and preparing method thereof and fan
CN106854405A (en) * 2016-12-30 2017-06-16 美的集团股份有限公司 Antistatic coating and its application

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