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CN113584385A - Controlled cooling method for martensite/bainite-based high-strength annealing-free welding wire rod - Google Patents

Controlled cooling method for martensite/bainite-based high-strength annealing-free welding wire rod Download PDF

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Publication number
CN113584385A
CN113584385A CN202110844405.3A CN202110844405A CN113584385A CN 113584385 A CN113584385 A CN 113584385A CN 202110844405 A CN202110844405 A CN 202110844405A CN 113584385 A CN113584385 A CN 113584385A
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Prior art keywords
wire rod
temperature
bainite
martensite
salt bath
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Pending
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CN202110844405.3A
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Inventor
李阳
王广顺
刘澄
亓奉友
侯建伟
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Qingdao Special Steel Co ltd
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Qingdao Special Steel Co ltd
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Priority to CN202110844405.3A priority Critical patent/CN113584385A/en
Publication of CN113584385A publication Critical patent/CN113584385A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/065Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/001Austenite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention provides a controlled cooling method of a martensite/bainite high-strength annealing-free welding wire rod, which comprises the following steps: the initial rolling temperature of the continuous casting billet is 1000-1100 ℃; the temperature of the wire rod in the rolling process, namely the inlet temperature of a finishing mill, the reducing diameter inlet temperature and the spinning temperature are controlled to 880-920 ℃ by adjusting the pressure and the flow of cooling water in each cooling water tank; after spinning, the wire rod is wholly immersed into a salt bath with the temperature lower than the Ms point of the steel in a state of loose coil and flat laying, and the isothermal time is more than 30 seconds; the wire rod is conveyed to a coil collecting station for collection after being discharged from the salt bath and entering a heat-preserving cover roller way; the finished wire rod obtains fine and uniform martensite/bainite and stable retained austenite microstructure. By controlling the temperature in the wire rod rolling process, the cooling mode after spinning and the roller speed, martensite, bainite and residual austenite structures with small and uniform sizes are obtained, and the comprehensive mechanical property is improved.

Description

Controlled cooling method for martensite/bainite-based high-strength annealing-free welding wire rod
Technical Field
The invention relates to the technical field of high-speed wire rod production, in particular to a controlled cooling method of a martensite/bainite-based high-strength annealing-free welding wire rod.
Background
After the production of a 50 kg-grade welding steel such as ER50-6E wire rod, spinning is carried out at a lower temperature, and then a delayed cooling (slow cooling) process is adopted on a stelmor line, a microstructure mainly comprising ferrite and pearlite can be obtained, and a downstream user can directly draw the steel to the size of a finished welding wire without annealing. The 80 kg-level welding steel contains more alloy elements (Cr, Ni, Mo, Ti and the like), so that the pearlite transformation temperature is lower, the incubation period is longer, the stelmor length is limited, even if the lower spinning temperature and the slowest roller table speed are adopted for slow cooling, the microstructure of the wire rod is ferrite and a large number of blocky horse/bainite tissues, the drawing performance is poor, and downstream users need to carry out annealing heat treatment and then carry out drawing processing. In addition, the difference of the thicknesses of the overlapping area and the non-overlapping area of the wire rod on the stelmor line is large, so that the difference of the cooling rates of the wire rod is large, and the poor same-circle organization performance of the wire rod is also an important factor for restricting the improvement of the drawing performance of the wire rod.
Disclosure of Invention
The invention aims to provide a controlled cooling method of a martensite/bainite-based high-strength annealing-free welding wire rod, which can realize annealing-free multi-pass drawing of 80 kg-grade welding steel wire rods without wire breakage, has low energy consumption and high production efficiency, and greatly reduces the production cost of downstream users.
In order to achieve the purpose, the invention provides the following technical scheme: the controlled cooling method of the horse/bainite high-strength annealing-free welding wire rod comprises the following steps: the initial rolling temperature of the continuous casting billet is 1000-1100 ℃; the temperature of the continuous casting billet in the rolling process, namely the inlet temperature of a finishing mill, the inlet temperature of a reducing diameter and the spinning temperature are controlled to 880-920 ℃ by adjusting the pressure and the flow of cooling water of each cooling water tank; after spinning, the wire rod is wholly immersed into a salt bath with the temperature lower than the Ms point of the steel in a state of loose coil and flat laying, and the isothermal time is more than 30 seconds; the wire rod is conveyed to a coil collecting station for collection after being discharged from the salt bath and entering a heat-preserving cover roller way; the finished wire rod obtains fine and uniform martensite/bainite and stable retained austenite microstructure.
Preferably, the continuous casting slab comprises the following components in percentage by weight: 0.06-0.10 wt.%, Si: 0.40-0.70 wt.%, Mn: 1.40-1.80 wt.%, Ni: 1.60-2.40 wt.%, Cr: 0.3-0.60 wt.%, Mo: 0.30-0.50 wt.%, Ti ≤ 0.10 wt.%, and P: 0.025 wt.%, S: less than or equal to 0.025 wt.%; the balance being Fe and inevitable impurities.
Preferably, the continuous casting slab is heated to the initial rolling temperature and is rolled after being kept at the initial rolling temperature for 1-3 hours.
Preferably, the rolling speed of the continuous casting slab is 110 m/s.
Preferably, the salt bath is a constant-temperature salt bath, and the temperature is controlled at 280-315 ℃.
The invention has the beneficial effects that:
by controlling the temperature in the wire rod rolling process, the cooling mode after spinning and the roller speed, martensite, bainite and residual austenite structures with small and uniform sizes are obtained, and the comprehensive mechanical property is improved. In addition, the cooling mode of completely immersing in the constant-temperature salt bath solves the inherent defect that the cooling speed of the lapping point and the non-lapping point of the wire rod is inconsistent when the traditional stelmor wire upper cover heat preservation cover is slowly cooled, so that the wire rod obtains good through-loop microstructure and mechanical property uniformity.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Examples
This example illustrates the controlled cooling method for a horse/bainite based high strength anneal free wire rod, and the hot rolled wire rod for 80 kg grade wire used in the example has the chemical composition shown in table 1.
Table 1 chemical composition/wt.% of the example wire rod
Figure BDA0003179952380000031
Heating a continuous casting billet with the size of 180 x 240mm to the initial rolling temperature of 1000 ℃, keeping the temperature for 1-3h, and then performing initial rolling at the rolling speed of 110 m/s. The temperature in the rolling process and the spinning temperature are controlled as shown in Table 2, the wire rod is conveyed by a roller way in a loose-coil and flat-laid state through a constant-temperature salt bath at the temperature of 280-315 ℃, and the medium-temperature time of the wire rod in the salt bath is 1-5 minutes; and (4) immediately entering a heat-preserving cover for slow cooling after the salt bath is discharged out until the salt bath is collected by a coil collecting station.
TABLE 2 examples controlled cooling parameters after rolling and rolling process
Figure BDA0003179952380000032
The structural properties of the wire rod obtained in this example are shown in table 3 in comparison with those of the wire rod obtained by the conventional process. The traditional process has the wire rod structure of partial ferrite and a large amount of massive martensite/bainite structure, and if the wire rod structure is not annealed, a user generates micro-cracks due to uneven stress distribution of the ferrite and the martensite/bainite in the drawing process so as to generate drawing fracture. In the embodiment, the wire rod directly enters the constant-temperature salt bath for quenching after spinning, a martensite/bainite + stable residual austenite structure with small and uniform size is obtained, although the tensile strength of the wire rod is 50-60MPa higher than that of the traditional process, the reduction of area is improved at the same time, and the wire rod is not easy to break in the drawing process.
Table 3 comparison of the structural properties of the wire rod of the examples with those of the wire rod of the conventional process
Figure BDA0003179952380000041
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (5)

1. A controlled cooling method for a martensite/bainite high-strength annealing-free welding wire rod is characterized by comprising the following steps: the initial rolling temperature of the continuous casting billet is 1000-1100 ℃; the temperature of the wire rod in the rolling process, namely the inlet temperature of a finishing mill, the reducing diameter inlet temperature and the spinning temperature are controlled to 880-920 ℃ by adjusting the pressure and the flow of cooling water in each cooling water tank; after spinning, the wire rod is wholly immersed into a salt bath with the temperature lower than the Ms point of the steel in a state of loose coil and flat laying, and the isothermal time is more than 30 seconds; the wire rod is conveyed to a coil collecting station for collection after being discharged from the salt bath and entering a heat-preserving cover roller way; the finished wire rod obtains fine and uniform martensite/bainite and stable retained austenite microstructure.
2. The controlled cooling method of the horse/bainite-based high-strength annealing-free wire rod according to claim 1, wherein the components of the continuous casting billet are, in weight percent, C: 0.06-0.10 wt.%, Si: 0.40-0.70 wt.%, Mn: 1.40-1.80 wt.%, Ni: 1.60-2.40 wt.%, Cr: 0.3-0.60 wt.%, Mo: 0.30-0.50 wt.%, Ti ≤ 0.10 wt.%, and P: 0.025 wt.%, S: less than or equal to 0.025 wt.%; the balance being Fe and inevitable impurities.
3. The method for controlled cooling of a horse/bainite-based high strength anneal-free wire rod according to claim 1, wherein: and heating the continuous casting blank to the initial rolling temperature, and keeping the temperature for 1-3 hours before rolling.
4. The method for controlled cooling of a horse/bainite-based high strength anneal-free wire rod according to claim 3, wherein: the rolling speed of the continuous casting billet is 110 m/s.
5. The method for controlled cooling of a horse/bainite-based high strength anneal-free wire rod according to claim 1, wherein: the salt bath is a constant-temperature salt bath, and the temperature is controlled at 280-315 ℃.
CN202110844405.3A 2021-07-26 2021-07-26 Controlled cooling method for martensite/bainite-based high-strength annealing-free welding wire rod Pending CN113584385A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114293107A (en) * 2021-12-31 2022-04-08 江苏永钢集团有限公司 Gas shielded welding alloy welding wire steel wire rod and production method thereof
CN114875332A (en) * 2022-05-30 2022-08-09 湖南华菱湘潭钢铁有限公司 Production method of annealing-free wire rod for high-strength alloy welding wire of 80 kilograms or more
CN117127002A (en) * 2023-10-26 2023-11-28 江苏永钢集团有限公司 Online flexible heat treatment production line and production process for high-speed wire of high-grade special steel
CN118007026A (en) * 2024-04-09 2024-05-10 江苏永钢集团有限公司 Hot-rolled 1300 MPa-level B-containing spring steel wire rod and production process thereof
CN118207405A (en) * 2024-05-21 2024-06-18 江苏永钢集团有限公司 10.9-Grade high Cr annealing-free cold heading steel hot rolled wire rod and manufacturing method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114293107A (en) * 2021-12-31 2022-04-08 江苏永钢集团有限公司 Gas shielded welding alloy welding wire steel wire rod and production method thereof
CN114875332A (en) * 2022-05-30 2022-08-09 湖南华菱湘潭钢铁有限公司 Production method of annealing-free wire rod for high-strength alloy welding wire of 80 kilograms or more
CN117127002A (en) * 2023-10-26 2023-11-28 江苏永钢集团有限公司 Online flexible heat treatment production line and production process for high-speed wire of high-grade special steel
CN118007026A (en) * 2024-04-09 2024-05-10 江苏永钢集团有限公司 Hot-rolled 1300 MPa-level B-containing spring steel wire rod and production process thereof
CN118207405A (en) * 2024-05-21 2024-06-18 江苏永钢集团有限公司 10.9-Grade high Cr annealing-free cold heading steel hot rolled wire rod and manufacturing method thereof

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Application publication date: 20211102