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CN112409016A - High-strength foam concrete and preparation method thereof - Google Patents

High-strength foam concrete and preparation method thereof Download PDF

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Publication number
CN112409016A
CN112409016A CN201910775541.4A CN201910775541A CN112409016A CN 112409016 A CN112409016 A CN 112409016A CN 201910775541 A CN201910775541 A CN 201910775541A CN 112409016 A CN112409016 A CN 112409016A
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parts
mixing
water
cement
sodium
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Chinese (zh)
Inventor
李雷
燕同凯
陈刚全
田治宪
王宁宁
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Shandong Keda Infrastructure Co ltd
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Shandong Keda Infrastructure Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention provides high-strength foam concrete and a preparation method thereof, wherein the raw materials comprise: alpha-sodium alkenyl sulfonate, sodium dodecyl sulfate, sodium carboxymethylcellulose, a foam stabilizer, silicone oil, citric acid, bentonite, attapulgite, potassium titanate whiskers, a silane coupling agent, cement, fly ash, mineral powder, polypropylene fibers, a water reducing agent and water. The preparation method comprises the steps of adding alpha-sodium alkenyl sulfonate and sodium dodecyl sulfate into water, heating and preserving heat, adding sodium carboxymethyl cellulose, a foam stabilizer, silicone oil and citric acid, dispersing and foaming to obtain the composite foaming agent; then mixing bentonite, attapulgite and potassium titanate whiskers, adding a silane coupling agent, and carrying out ball milling and mixing to obtain a modification reinforcing agent; the module is prepared by mixing cement, mineral powder, fly ash, broken stone, river sand and polypropylene fiber, and adding water, water reducing agent, composite foaming agent and modified reinforcing agent. The foam concrete has good compressive strength, water absorption and heat conductivity coefficient.

Description

High-strength foam concrete and preparation method thereof
Technical Field
The invention belongs to the technical field of building materials, and particularly relates to high-strength foam concrete and a preparation method thereof.
Background
The foam concrete (also called foaming cement and light concrete) is a novel building energy-saving material which is waste-utilizing, environment-friendly, energy-saving, low-cost and non-combustible, and is a concrete product which is formed by introducing air or gases such as nitrogen, carbon dioxide gas, oxygen and the like into concrete slurry in a chemical or physical mode, and reasonably curing and forming, contains a large amount of fine closed air holes and has considerable strength.
Along with the increasing of road traffic volume and traffic load in China, reconstruction and expansion projects of part of early-stage expressways and urban roads are continuously increased, and problems of land occupation removal, soft soil foundation treatment, frozen soil damage, pipe culvert external heat insulation construction and the like in construction have important influence on the quality and durability of road base layers and surface layers, and a plurality of key technologies are not effectively solved. As a novel road base material with good self-standing property, heat preservation, frost resistance, wide source and low price, the foam concrete has certain application and development in road construction in recent years, but has the problems of unstable foam, low strength, overlarge water absorption rate and the like.
Disclosure of Invention
The invention aims to provide high-strength foam concrete by preparing a high-efficiency foaming agent.
A high-strength foam concrete comprises the following raw materials in parts by weight: 0.5-1 part of alpha-sodium alkenyl sulfonate, 0.1-0.2 part of sodium dodecyl sulfate, 0.2-0.4 part of sodium carboxymethylcellulose, 0.3-0.5 part of foam stabilizer, 0.05-0.1 part of silicone oil, 0.02-0.05 part of citric acid, 2-7 parts of bentonite, 1-4 parts of attapulgite, 1-3 parts of potassium titanate whisker, 0.3-0.8 part of silane coupling agent, 200 parts of cement 100-containing materials, 20-40 parts of fly ash, 30-50 parts of mineral powder, 0.3-0.7 part of polypropylene fiber, 1-2 parts of water reducer and 50-100 parts of water.
Further, the foam stabilizer is an organic silicon foam stabilizer FM.
Further, the cement is a mixture of P.II 42.5-grade portland cement and CA-60 aluminate cement, and the mass ratio of the P.II 42.5-grade portland cement to the CA-60 aluminate cement is 8: 2.
further, the silane coupling agent is KH 550.
The preparation method of the foam concrete comprises the following steps:
step 1, adding alpha-sodium alkenyl sulfonate and sodium dodecyl sulfate into 100 times of water by weight, heating to 40-50 ℃, preserving heat for 30min, adding sodium carboxymethyl cellulose, a foam stabilizer, silicone oil and citric acid under the stirring condition, dispersing, and foaming under high pressure to obtain a composite foaming agent;
step 2, mixing bentonite, attapulgite and potassium titanate whiskers, adding a silane coupling agent, and carrying out ball milling and mixing to obtain a modification reinforcing agent;
and 3, adding cement, mineral powder, fly ash, broken stone, river sand and polypropylene fiber into a stirrer, stirring and mixing, adding water and a water reducing agent, stirring and mixing, adding the composite foaming agent obtained in the step 1 and the modified reinforcing agent obtained in the step 2, mixing, pouring into a mold, and performing standard maintenance for 24 hours to prepare a module.
Further, step 2 is to mix bentonite, attapulgite and potassium titanate whisker, then put them into 10% sulphuric acid solution to be soaked, then add silane coupling agent to be ball milled and mixed.
The invention adopts alpha-sodium alkenyl sulfonate, sodium dodecyl sulfate, sodium carboxymethylcellulose, organosilicon foam stabilizer FM, silicone oil and citric acid to prepare a mixed foaming agent with good stability; the prepared foam concrete has good compressive strength, water absorption and heat conductivity coefficient.
Detailed Description
Example 1
A high-strength foam concrete comprises the following raw materials in parts by weight: 0.5 part of alpha-sodium alkenyl sulfonate, 0.1 part of sodium dodecyl sulfate, 0.2 part of sodium carboxymethylcellulose, 0.3 part of foam stabilizer, 0.05 part of silicone oil, 0.02 part of citric acid, 2 parts of bentonite, 1 part of attapulgite, 1 part of potassium titanate whisker, 0.3 part of silane coupling agent, 100 parts of cement, 20 parts of fly ash, 30 parts of mineral powder, 0.3 part of polypropylene fiber, 1 part of water reducer and 50 parts of water.
The foam stabilizer is an organic silicon foam stabilizer FM.
The cement is a mixture of P & II 42.5-grade portland cement and CA-60 aluminate cement, and the mass ratio of the P & II 42.5-grade portland cement to the CA-60 aluminate cement is 8: 2.
the silane coupling agent is KH 550.
The preparation method of the foam concrete comprises the following steps:
step 1, adding alpha-sodium alkenyl sulfonate and sodium dodecyl sulfate into 100 times of water by weight, heating to 40-50 ℃, preserving heat for 30min, adding sodium carboxymethyl cellulose, a foam stabilizer, silicone oil and citric acid under the stirring condition, dispersing, and foaming under high pressure to obtain a composite foaming agent;
step 2, mixing bentonite, attapulgite and potassium titanate whiskers, adding a silane coupling agent, and carrying out ball milling and mixing to obtain a modification reinforcing agent;
and 3, adding cement, mineral powder, fly ash, broken stone, river sand and polypropylene fiber into a stirrer, stirring and mixing, adding water and a water reducing agent, stirring and mixing, adding the composite foaming agent obtained in the step 1 and the modified reinforcing agent obtained in the step 2, mixing, pouring into a mold, and performing standard maintenance for 24 hours to prepare a module.
Example 2
A high-strength foam concrete comprises the following raw materials in parts by weight: 0.7 part of alpha-sodium alkenyl sulfonate, 0.15 part of sodium dodecyl sulfate, 0.3 part of sodium carboxymethylcellulose, 0.4 part of foam stabilizer, 0.07 part of silicone oil, 0.04 part of citric acid, 4 parts of bentonite, 3 parts of attapulgite, 2 parts of potassium titanate whisker, 0.6 part of silane coupling agent, 150 parts of cement, 30 parts of fly ash, 40 parts of mineral powder, 0.5 part of polypropylene fiber, 1.5 parts of water reducer and 80 parts of water.
The foam stabilizer is an organic silicon foam stabilizer FM.
The cement is a mixture of P & II 42.5-grade portland cement and CA-60 aluminate cement, and the mass ratio of the P & II 42.5-grade portland cement to the CA-60 aluminate cement is 8: 2.
the silane coupling agent is KH 550.
The preparation method of the foam concrete comprises the following steps:
step 1, adding alpha-sodium alkenyl sulfonate and sodium dodecyl sulfate into 100 times of water by weight, heating to 40-50 ℃, preserving heat for 30min, adding sodium carboxymethyl cellulose, a foam stabilizer, silicone oil and citric acid under the stirring condition, dispersing, and foaming under high pressure to obtain a composite foaming agent;
step 2, mixing bentonite, attapulgite and potassium titanate whiskers, adding a silane coupling agent, and carrying out ball milling and mixing to obtain a modification reinforcing agent;
and 3, adding cement, mineral powder, fly ash, broken stone, river sand and polypropylene fiber into a stirrer, stirring and mixing, adding water and a water reducing agent, stirring and mixing, adding the composite foaming agent obtained in the step 1 and the modified reinforcing agent obtained in the step 2, mixing, pouring into a mold, and performing standard maintenance for 24 hours to prepare a module.
Example 3
A high-strength foam concrete comprises the following raw materials in parts by weight: 1 part of alpha-sodium alkenyl sulfonate, 0.2 part of sodium dodecyl sulfate, 0.4 part of sodium carboxymethylcellulose, 0.5 part of foam stabilizer, 0.1 part of silicone oil, 0.05 part of citric acid, 7 parts of bentonite, 4 parts of attapulgite, 3 parts of potassium titanate whisker, 0.8 part of silane coupling agent, 200 parts of cement, 40 parts of fly ash, 50 parts of mineral powder, 0.7 part of polypropylene fiber, 2 parts of water reducer and 100 parts of water.
The foam stabilizer is an organic silicon foam stabilizer FM.
The cement is a mixture of P & II 42.5-grade portland cement and CA-60 aluminate cement, and the mass ratio of the P & II 42.5-grade portland cement to the CA-60 aluminate cement is 8: 2.
the silane coupling agent is KH 550.
The preparation method of the foam concrete comprises the following steps:
step 1, adding alpha-sodium alkenyl sulfonate and sodium dodecyl sulfate into 100 times of water by weight, heating to 40-50 ℃, preserving heat for 30min, adding sodium carboxymethyl cellulose, a foam stabilizer, silicone oil and citric acid under the stirring condition, dispersing, and foaming under high pressure to obtain a composite foaming agent;
step 2, mixing bentonite, attapulgite and potassium titanate whiskers, adding a silane coupling agent, and carrying out ball milling and mixing to obtain a modification reinforcing agent;
and 3, adding cement, mineral powder, fly ash, broken stone, river sand and polypropylene fiber into a stirrer, stirring and mixing, adding water and a water reducing agent, stirring and mixing, adding the composite foaming agent obtained in the step 1 and the modified reinforcing agent obtained in the step 2, mixing, pouring into a mold, and performing standard maintenance for 24 hours to prepare a module.
Example 4
This example differs from example 3 in that: and 2, mixing bentonite, attapulgite and potassium titanate whiskers, soaking in a 10% sulfuric acid solution, adding a silane coupling agent, and performing ball milling and mixing.
A high-strength foam concrete comprises the following raw materials in parts by weight: 1 part of alpha-sodium alkenyl sulfonate, 0.2 part of sodium dodecyl sulfate, 0.4 part of sodium carboxymethylcellulose, 0.5 part of foam stabilizer, 0.1 part of silicone oil, 0.05 part of citric acid, 7 parts of bentonite, 4 parts of attapulgite, 3 parts of potassium titanate whisker, 0.8 part of silane coupling agent, 200 parts of cement, 40 parts of fly ash, 50 parts of mineral powder, 0.7 part of polypropylene fiber, 2 parts of water reducer and 100 parts of water.
The foam stabilizer is an organic silicon foam stabilizer FM.
The cement is a mixture of P & II 42.5-grade portland cement and CA-60 aluminate cement, and the mass ratio of the P & II 42.5-grade portland cement to the CA-60 aluminate cement is 8: 2.
the silane coupling agent is KH 550.
The preparation method of the foam concrete comprises the following steps:
step 1, adding alpha-sodium alkenyl sulfonate and sodium dodecyl sulfate into 100 times of water by weight, heating to 40-50 ℃, preserving heat for 30min, adding sodium carboxymethyl cellulose, a foam stabilizer, silicone oil and citric acid under the stirring condition, dispersing, and foaming under high pressure to obtain a composite foaming agent;
step 2, mixing bentonite, attapulgite and potassium titanate whiskers, then placing the mixture into a 10% sulfuric acid solution for soaking for 30-50min, taking out the mixture, then adding a silane coupling agent, and carrying out ball milling and mixing to obtain a modification reinforcing agent;
and 3, adding cement, mineral powder, fly ash, broken stone, river sand and polypropylene fiber into a stirrer, stirring and mixing, adding water and a water reducing agent, stirring and mixing, adding the composite foaming agent obtained in the step 1 and the modified reinforcing agent obtained in the step 2, mixing, pouring into a mold, and performing standard maintenance for 24 hours to prepare a module.
The foam concrete obtained in examples 1 to 4 was subjected to a performance test, and the results were as follows:
Figure DEST_PATH_IMAGE002
the invention adopts alpha-sodium alkenyl sulfonate, sodium dodecyl sulfate, sodium carboxymethylcellulose, an organic silicon foam stabilizer FM, silicone oil and citric acid to prepare a mixed foaming agent, the mixed foaming agent has 27.5mL of bleeding amount in 1h and 1.9mm of settling distance in 1h, and has good stability; the prepared foam concrete has good compressive strength, water absorption and heat conductivity coefficient. The mixture of bentonite, attapulgite and potassium titanate whiskers is used as a reinforcing agent, and internal gaps can be filled, so that the later strength of the concrete is improved; the surface modification is carried out by adopting the silane coupling agent, so that the binding power between each component in the reinforcing agent and concrete can be improved, the filling effect is promoted, the bentonite, the attapulgite and the potassium titanate whisker are firstly placed in a sulfuric acid solution for soaking, and then the surface modification is carried out by adopting the silane coupling agent, so that the structure and distribution of air holes can be improved, the uniformity is improved, and the strength is further improved.

Claims (6)

1. A high-strength foam concrete is characterized in that: the raw materials comprise the following components in parts by weight: 0.5-1 part of alpha-sodium alkenyl sulfonate, 0.1-0.2 part of sodium dodecyl sulfate, 0.2-0.4 part of sodium carboxymethylcellulose, 0.3-0.5 part of foam stabilizer, 0.05-0.1 part of silicone oil, 0.02-0.05 part of citric acid, 2-7 parts of bentonite, 1-4 parts of attapulgite, 1-3 parts of potassium titanate whisker, 0.3-0.8 part of silane coupling agent, 200 parts of cement 100-containing materials, 20-40 parts of fly ash, 30-50 parts of mineral powder, 0.3-0.7 part of polypropylene fiber, 1-2 parts of water reducer and 50-100 parts of water.
2. The high stability foamed concrete according to claim 1, wherein: the foam stabilizer is an organic silicon foam stabilizer FM.
3. The high stability foamed concrete according to claim 1, wherein: the cement is a mixture of P & II 42.5-grade portland cement and CA-60 aluminate cement, and the mass ratio of the P & II 42.5-grade portland cement to the CA-60 aluminate cement is 8: 2.
4. the high stability foamed concrete according to claim 1, wherein: the silane coupling agent is KH 550.
5. The method of producing a foamed concrete according to claim 1, wherein: the method comprises the following steps:
step 1, adding alpha-sodium alkenyl sulfonate and sodium dodecyl sulfate into 100 times of water by weight, heating to 40-50 ℃, preserving heat for 30min, adding sodium carboxymethyl cellulose, a foam stabilizer, silicone oil and citric acid under the stirring condition, dispersing, and foaming under high pressure to obtain a composite foaming agent;
step 2, mixing bentonite, attapulgite and potassium titanate whiskers, adding a silane coupling agent, and carrying out ball milling and mixing to obtain a modification reinforcing agent;
and 3, adding cement, mineral powder, fly ash, broken stone, river sand and polypropylene fiber into a stirrer, stirring and mixing, adding water and a water reducing agent, stirring and mixing, adding the composite foaming agent obtained in the step 1 and the modified reinforcing agent obtained in the step 2, mixing, pouring into a mold, and performing standard maintenance for 24 hours to prepare a module.
6. The method of producing a foamed concrete according to claim 5, characterized in that: and 2, mixing bentonite, attapulgite and potassium titanate whiskers, soaking in a 10% sulfuric acid solution, adding a silane coupling agent, and performing ball milling and mixing.
CN201910775541.4A 2019-08-21 2019-08-21 High-strength foam concrete and preparation method thereof Pending CN112409016A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114561846A (en) * 2022-03-01 2022-05-31 江西省交通工程集团建设有限公司 Construction method of foamed asphalt warm-mix recycled pavement
TWI793716B (en) * 2021-08-12 2023-02-21 高啓峯 Durable and high temperature resistant plate body
CN116332581A (en) * 2023-04-19 2023-06-27 安徽省公路桥梁工程有限公司 Light foam soil and preparation method thereof
CN117819926A (en) * 2024-03-05 2024-04-05 石家庄铁道大学 Potassium titanate whisker reinforced ultra-high performance recycled concrete and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI793716B (en) * 2021-08-12 2023-02-21 高啓峯 Durable and high temperature resistant plate body
CN114561846A (en) * 2022-03-01 2022-05-31 江西省交通工程集团建设有限公司 Construction method of foamed asphalt warm-mix recycled pavement
CN116332581A (en) * 2023-04-19 2023-06-27 安徽省公路桥梁工程有限公司 Light foam soil and preparation method thereof
CN117819926A (en) * 2024-03-05 2024-04-05 石家庄铁道大学 Potassium titanate whisker reinforced ultra-high performance recycled concrete and preparation method thereof
CN117819926B (en) * 2024-03-05 2024-04-30 石家庄铁道大学 Potassium titanate whisker reinforced ultra-high performance recycled concrete and preparation method thereof

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Application publication date: 20210226