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CN111721832B - Passiflora edulis pulp substance detection device and detection method thereof - Google Patents

Passiflora edulis pulp substance detection device and detection method thereof Download PDF

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CN111721832B
CN111721832B CN202010640069.6A CN202010640069A CN111721832B CN 111721832 B CN111721832 B CN 111721832B CN 202010640069 A CN202010640069 A CN 202010640069A CN 111721832 B CN111721832 B CN 111721832B
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mass spectrometer
friction
main body
rotating shaft
base
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CN111721832A (en
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邓有展
韦璐阳
陈永森
王运儒
梁宏合
杜国冬
吴静娜
吴凤
李今朝
蒋越华
李冬桂
李乾坤
张莉娟
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Guangxi Subtropical Crops Research Institute
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/62Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating the ionisation of gases, e.g. aerosols; by investigating electric discharges, e.g. emission of cathode
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    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
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    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
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    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/28Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
    • G01N1/44Sample treatment involving radiation, e.g. heat
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/28Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
    • G01N1/40Concentrating samples
    • G01N1/4055Concentrating samples by solubility techniques
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Abstract

The invention discloses a passion flower pulp detection device, which comprises a mass spectrometer main body, wherein a base is arranged on the lower side of the mass spectrometer main body, and the mass spectrometer main body is fixedly connected with the base; the base includes the base main part, and the inside cavity of base main part sets up, and the wall mounting has selected the regulation formula themogenesis mechanism in the base main part, selects the regulation formula themogenesis mechanism including bearing the seat, and it has the slide to bore in bearing the seat, and sliding connection has the friction piece in the slide, is equipped with the block groove on the lateral wall of friction piece, and the block inslot is equipped with friction portion, and it has the chamber of placing to bore in the friction piece. According to the invention, through the matching arrangement of the selective adjusting type heat generating mechanism and the spin stirring mechanism, the pretreatment can be carried out before the measured medium enters the mass spectrometer, the phenomenon that the measured medium enters a vacuum environment from the atmospheric pressure and is crystallized is greatly reduced, the blockage of a sample inlet pipeline of the mass spectrometer is avoided, the substance of the measured medium can be fully detected, and the detection effect of the mass spectrometer is greatly improved.

Description

一种西番莲果肉物质检测装置及其检测方法A kind of passion fruit pulp substance detection device and detection method thereof

技术领域technical field

本发明属于西番莲果肉检测技术领域,具体涉及一种西番莲果肉物质检测装置及其检测方法。The invention belongs to the technical field of passion fruit pulp detection, and in particular relates to a passion fruit pulp substance detection device and a detection method thereof.

背景技术Background technique

西番莲,为多年生常绿攀缘木质藤本植物,是一种芳香可口的水果,有“果汁之王”的美誉;又名受难果、巴西果、藤桃、热情果、转心莲、西洋鞠,转枝莲、洋酸茄花,时计草;据测定,西番莲果实含有超过135种以上的芳香物质,最适于加工成果汁,或与其它水果(如芒果、菠萝、番石榴、柑橙和苹果等)加工混配成混合果汁,可以显著地提高这些水果汁的口感与香味;可以做雪糕或其它食品的添加剂以增进香味,改进品质。Passiflora, a perennial evergreen climbing woody vine, is a fragrant and delicious fruit, known as the "King of Juice"; , twig lotus, sour eggplant flower, time meter grass; according to the determination, the passion fruit fruit contains more than 135 kinds of aromatic substances, and is most suitable for processing into fruit juice, or with other fruits (such as mango, pineapple, guava, Oranges and apples, etc.) are processed and blended into mixed fruit juices, which can significantly improve the taste and aroma of these fruit juices; it can be used as an additive for ice cream or other foods to enhance the aroma and improve the quality.

在进行西番莲物质检测时,会用到质谱仪设备,质谱仪又称质谱计,其主要是分离和检测不同同位素的仪器;即根据带电粒子在电磁场中能够偏转的原理,按物质原子、分子或分子碎片的质量差异进行分离和检测物质组成的一类仪器;质谱仪按应用范围分为同位素质谱仪、无机质谱仪和有机质谱仪;按分辨本领分为高分辨、中分辨和低分辨质谱仪;按工作原理分为静态仪器和动态仪器。Mass spectrometer equipment is used in the detection of passionflower substances. Mass spectrometers, also known as mass spectrometers, are mainly instruments for separating and detecting different isotopes; A type of instrument that separates and detects the composition of substances based on the mass difference of molecules or molecular fragments; mass spectrometers are divided into isotope mass spectrometers, inorganic mass spectrometers, and organic mass spectrometers according to the scope of application; Mass spectrometer; according to the working principle, it is divided into static instrument and dynamic instrument.

质谱仪进样系统的好坏直接影响到样品是否能顺利进入到检测仪器中,并被检测仪器检测到,现有技术中的质谱仪在使用时,都是直接将被测介质通入到质谱仪中,但由于被测介质从大气压中进入到真空环境中容易发生相变,使得质谱仪的进样管口会出现结晶现象,久而久之就容易造成进样管路的堵塞,使得某些物质无法被检测,影响质谱仪的检测效果。The quality of the mass spectrometer sampling system directly affects whether the sample can smoothly enter the detection instrument and be detected by the detection instrument. When the mass spectrometer in the prior art is in use, it directly passes the measured medium into the mass spectrometer. However, since the measured medium enters the vacuum environment from the atmospheric pressure, it is easy to undergo a phase change, which will cause crystallization at the injection nozzle of the mass spectrometer. Over time, it will easily cause the blockage of the sampling pipeline, making certain substances unable to detected, affecting the detection effect of the mass spectrometer.

因此,针对上述技术问题,有必要提供一种西番莲果肉物质检测装置及其检测方法。Therefore, at above-mentioned technical problem, be necessary to provide a kind of passion fruit pulp substance detection device and detection method thereof.

发明内容Contents of the invention

本发明的目的在于提供一种西番莲果肉物质检测装置及其检测方法,以解决上述的质谱仪在发生相变时,进样管路容易产生结晶堵塞管路,导致某些物质检测不到,影响检测效果的问题。The object of the present invention is to provide a passion fruit pulp substance detection device and detection method thereof, to solve the above-mentioned mass spectrometer when the phase transition occurs, the sample injection pipeline is prone to crystallization to block the pipeline, resulting in some substances not being detected , a problem that affects the detection effect.

为了实现上述目的,本发明一实施例提供的技术方案如下:In order to achieve the above object, the technical solution provided by an embodiment of the present invention is as follows:

一种西番莲果肉物质检测装置,包括质谱仪主体,所述质谱仪主体的下侧设有底座,且质谱仪主体与底座固定连接;A passion fruit pulp substance detection device, comprising a mass spectrometer main body, the underside of the mass spectrometer main body is provided with a base, and the mass spectrometer main body is fixedly connected to the base;

所述底座包括底座主体,所述底座主体内部中空设置,所述底座主体内底壁上安装有选调式生热机构,所述选调式生热机构包括承载座,所述承载座内开凿有滑道,所述滑道内滑动连接有摩擦件,所述摩擦件的侧壁上设有卡合槽,所述卡合槽内设有摩擦部,所述摩擦件内开凿有放置腔,所述放置腔内设有与摩擦部相匹配的摩擦块,所述摩擦件贯通摩擦块设置,所述承载座远离底座主体的一面上设有多个均匀分布的通孔,所述通孔与放置腔相连通,所述摩擦件远离卡座的一端固定连接有卡块,所述承载座的上侧设有搅拌机构,所述承载座与搅拌机构之间连接有连接座,所述连接座内设有第二轴承,所述第二轴承套设于转轴的外侧,所述搅拌机构包括转轴,所述转轴的侧壁上连接有一对自旋搅拌机构,所述转轴靠近摩擦件的一端上设有与卡块相匹配的放置槽,所述转轴内设有电磁铁。The base includes a base body, the base body is hollow inside, and an adjustable heat generating mechanism is installed on the inner bottom wall of the base body, and the adjustable heat generating mechanism includes a bearing seat, and a slide is dug inside the bearing seat. There is a friction part slidingly connected in the slideway, an engaging groove is provided on the side wall of the friction part, a friction part is arranged in the engaging groove, a placement cavity is dug in the friction part, and the placing A friction block matching the friction part is provided in the chamber, the friction member is set through the friction block, and a plurality of evenly distributed through holes are provided on the side of the bearing seat away from the base body, and the through holes are connected to the placement cavity The end of the friction member away from the deck is fixedly connected with a block, the upper side of the bearing seat is provided with a stirring mechanism, and a connecting seat is connected between the bearing seat and the stirring mechanism, and the connecting seat is provided with The second bearing, the second bearing is sleeved on the outside of the rotating shaft. The stirring mechanism includes a rotating shaft. The block is placed in a matching groove, and an electromagnet is arranged in the rotating shaft.

进一步地,所述质谱仪主体内设有隔板,所述隔板与质谱仪主体之间形成有安装腔,所述安装腔内设有电动机和水泵,所述电动机与转轴转动连接,电动机用于驱动转轴进行转动,从而可以带动自旋搅拌机构进行转动,对底座主体内的溶液进行搅拌,水泵用于将底座主体内的溶液进行输送,利用质谱仪主体进行检测,所述水泵上连接有进液管和出液管,所述进液管贯通底座主体设置,所述出液管贯通隔板设置。Further, the main body of the mass spectrometer is provided with a baffle, and an installation cavity is formed between the baffle and the main body of the mass spectrometer. A motor and a water pump are arranged in the installation cavity, and the motor is rotatably connected to the rotating shaft. The rotating shaft is driven to rotate, so that the spin stirring mechanism can be driven to rotate, and the solution in the main body of the base is stirred. The water pump is used to transport the solution in the main body of the base, and the main body of the mass spectrometer is used for detection. The water pump is connected with A liquid inlet pipe and a liquid outlet pipe, the liquid inlet pipe is arranged through the main body of the base, and the liquid outlet pipe is arranged through the partition plate.

进一步地,所述摩擦件位于滑道内的一端连接有卡座,所述承载座上设有与卡座相匹配的容纳槽,所述容纳槽与滑道相连通,使用者不需要使用摩擦件时,通过卡座卡合容纳槽进行收纳。Further, one end of the friction member located in the slideway is connected with a card holder, and the bearing seat is provided with a receiving groove matching the holder, and the receiving groove is connected with the slideway, and the user does not need to use the friction member When it is used, it is stored through the card seat engaging the receiving groove.

进一步地,所述卡座内设有配重块,便于增加摩擦件的整体重量,使得电磁铁在不通电时,摩擦件依靠自身重力以及配重块的重力下降,卡合在容纳槽内,所述配重块为金属材质,所述承载座内设有与配重块相匹配的磁铁,通过磁铁吸引配重块,进一步固定摩擦件。Further, a counterweight is provided in the deck, which is convenient for increasing the overall weight of the friction member, so that when the electromagnet is not energized, the friction member falls by its own gravity and the gravity of the counterweight, and is engaged in the accommodating groove. The counterweight is made of metal, and the bearing seat is provided with a magnet matching the counterweight, and the counterweight is attracted by the magnet to further fix the friction parts.

进一步地,所述卡块的形状为六边形,提高摩擦件与转轴的连接稳定性,避免摩擦件与转轴连接时,发生错位。Further, the block is hexagonal in shape, which improves the stability of the connection between the friction member and the rotating shaft, and prevents misalignment when the friction member is connected to the rotating shaft.

进一步地,所述通孔上盖设有金属网,所述金属网为100筛目,所述金属网套设于连接座的外侧,避免摩擦部磨损下来的杂质进入到溶液内。Further, the upper cover of the through hole is provided with a metal mesh, the metal mesh is 100 meshes, and the metal mesh is sleeved on the outside of the connection seat to prevent impurities from the friction part from entering the solution.

进一步地,所述自旋搅拌机构包括安装板,所述转轴与安装板之间连接有连接件,所述安装板远离连接件的一面上连接有一对固定轴,所述固定轴上套设有第一轴承,所述第一轴承上固定连接有扇叶,安装板跟随转轴进行转动,安装板上的扇叶在溶液的作用下围绕第一轴承进行转动,提高扇叶对溶液的搅拌效果,避免溶液出现浓度不均匀的现象,避免结晶的产生,同时大幅提高选调式生热机构的散热效果,提高溶液温度,进一步避免溶液出现结晶。Further, the spin stirring mechanism includes a mounting plate, a connecting piece is connected between the rotating shaft and the mounting plate, a pair of fixed shafts are connected to the side of the mounting plate away from the connecting piece, and the fixed shafts are sleeved with The first bearing, the first bearing is fixedly connected with fan blades, the mounting plate rotates with the rotating shaft, and the fan blades on the mounting plate rotate around the first bearing under the action of the solution, so as to improve the stirring effect of the fan blades on the solution, Avoid the phenomenon of uneven concentration of the solution, avoid the generation of crystallization, and at the same time greatly improve the heat dissipation effect of the selected heat generating mechanism, increase the temperature of the solution, and further avoid the crystallization of the solution.

进一步地,所述固定轴的侧壁上设有一对卡合件,所述第一轴承上设有与卡合件相匹配的卡槽,限位第一轴承,避免第一轴承脱离固定轴。Further, a pair of engaging parts is provided on the side wall of the fixed shaft, and a slot matching the engaging parts is provided on the first bearing to limit the first bearing and prevent the first bearing from detaching from the fixed shaft.

进一步地,所述电磁铁包括铁芯,所述铁芯的外侧套设有导电线组,所述导电线组的一端连接有电池,所述质谱仪主体上设有按钮,所述导电线组的另一端与按钮相连接,电磁铁通电带有强磁,强磁可以吸引卡块,使得摩擦件与转轴充分固定,从而可以保证摩擦部与摩擦块的摩擦生热,所述电磁铁的外侧设有屏蔽网,避免强磁对第二轴承的吸引,方便第二轴承进行转动。Further, the electromagnet includes an iron core, the outer side of the iron core is covered with a conductive wire group, one end of the conductive wire group is connected to a battery, the mass spectrometer body is provided with a button, and the conductive wire group The other end of the electromagnet is connected to the button, and the electromagnet is powered with a strong magnet, which can attract the block, so that the friction part and the rotating shaft are fully fixed, thereby ensuring the friction between the friction part and the friction block to generate heat. The outer side of the electromagnet A shielding net is provided to prevent strong magnetism from attracting the second bearing and facilitate the rotation of the second bearing.

一种西番莲果肉物质检测装置的检测方法,包括以下步骤:A detection method of a passion fruit pulp substance detection device, comprising the following steps:

S1.将西番莲果肉利用磁力加热搅拌器以及超声波震荡仪进行搅拌,得到均匀的西番莲果肉溶液;S1. the passion fruit pulp is stirred with a magnetic heating stirrer and an ultrasonic oscillator to obtain a uniform passion fruit pulp solution;

S2.利用旋转蒸发仪对上述步骤中得到的西番莲果肉溶液进行萃取,提取溶液以及溶液气体;S2. Utilize rotary evaporator to extract the passion fruit pulp solution obtained in the above steps, extract solution and solution gas;

S3.将上述步骤中萃取溶液通过入液管通入到底座主体内,进行质谱仪分析前的准备;S3. Pass the extraction solution in the above steps into the main body of the base through the liquid inlet pipe to prepare for mass spectrometer analysis;

S4.通过质谱仪主体上相应的按钮使得电磁铁带电,电磁铁通电产生较大的磁力,吸引承载座内的摩擦件在滑道内滑动,使得摩擦件上的卡块卡合在转轴上的放置槽内,实现转轴与摩擦件的连接,同时摩擦件侧壁上的摩擦部与摩擦块进行接触,控制电动机的运转;S4. The electromagnet is charged through the corresponding button on the main body of the mass spectrometer, and the electromagnet is energized to generate a large magnetic force, which attracts the friction parts in the bearing seat to slide in the slideway, so that the blocks on the friction parts are engaged on the rotating shaft. In the groove, the connection between the rotating shaft and the friction part is realized, and at the same time, the friction part on the side wall of the friction part is in contact with the friction block to control the operation of the motor;

S5.电动机转动带动与其相连的转轴进行转动,转轴上的连接的摩擦件跟随转动,摩擦件上的摩擦部摩擦摩擦块并产生大量的热,热通过通孔排出,对底座主体内的萃取溶液进行加热,同时转轴侧壁上的自旋搅拌机构也开始旋转,对底座主体内萃取的溶液进行搅拌,避免萃取溶液出现浓度不均匀的情况,也方便将摩擦产生的热进行分散,避免萃取溶液的温度过低而产生结晶;S5. The rotation of the motor drives the rotating shaft connected to it to rotate, and the connected friction parts on the rotating shaft follow the rotation. The friction part on the friction parts rubs against the friction block and generates a lot of heat. The heat is discharged through the through hole, and the extraction solution in the main body of the base Heating, at the same time, the spin stirring mechanism on the side wall of the rotating shaft also starts to rotate, stirring the extracted solution in the main body of the base, avoiding the uneven concentration of the extraction solution, and also facilitating the dispersion of the heat generated by friction, avoiding the extraction solution The temperature is too low to produce crystallization;

S6.电动机工作一段时间后,打开水泵的开关,水泵通过进液管将底座主体内萃取的溶液吸入到质谱仪主体内进行分析,同时将S2中得到的溶液气体通入质谱仪主体进行分析;S6. After the motor works for a period of time, turn on the switch of the water pump, and the water pump sucks the solution extracted in the base body into the mass spectrometer body through the liquid inlet pipe for analysis, and simultaneously passes the solution gas obtained in S2 into the mass spectrometer body for analysis;

S7.对上述步骤分析出的结果绘制色谱图,用NIST谱库捜索,确定西番莲果肉溶液以及溶液气体的化学组成。S7. draw chromatogram to the result analyzed in above-mentioned steps, search with NIST spectral library, determine the chemical composition of passion fruit pulp solution and solution gas.

与现有技术相比,本发明具有以下优点:Compared with the prior art, the present invention has the following advantages:

本发明通过选调式生热机构和自旋搅拌机构的配合设置,可以在被测介质进入到质谱仪前进行预处理,大幅减少被测介质从大气压中进入到真空环境中出现结晶的现象,避免质谱仪进样管路的堵塞,可以充分检测被测介质的物质,大幅提高质谱仪的检测效果。In the present invention, through the coordinated setting of the selected heat generating mechanism and the spin stirring mechanism, pretreatment can be performed before the measured medium enters the mass spectrometer, which greatly reduces the phenomenon of crystallization of the measured medium entering the vacuum environment from atmospheric pressure, avoiding The blockage of the mass spectrometer's sampling pipeline can fully detect the substance of the measured medium and greatly improve the detection effect of the mass spectrometer.

附图说明Description of drawings

为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明中记载的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the following will briefly introduce the drawings that need to be used in the description of the embodiments or the prior art. Obviously, the accompanying drawings in the following description are only These are some embodiments described in the present invention. Those skilled in the art can also obtain other drawings based on these drawings without creative work.

图1为本发明一实施例中一种西番莲果肉物质检测装置的立体图;Fig. 1 is the perspective view of a kind of passion fruit pulp substance detection device in an embodiment of the present invention;

图2为本发明一实施例中一种西番莲果肉物质检测装置的剖面图;Fig. 2 is the sectional view of a kind of passion fruit pulp substance detection device in an embodiment of the present invention;

图3为本发明一实施例中选调式生热机构的立体图;Fig. 3 is a perspective view of an adjustable heat generating mechanism in an embodiment of the present invention;

图4为本发明一实施例中摩擦件的立体图;Fig. 4 is a perspective view of a friction member in an embodiment of the present invention;

图5为本发明一实施例中选调式生热机构的立体剖面图;Fig. 5 is a three-dimensional sectional view of an adjustable heat generating mechanism in an embodiment of the present invention;

图6为本发明一实施例中图2中A处结构示意图;Fig. 6 is a schematic structural diagram of A in Fig. 2 in an embodiment of the present invention;

图7为本发明一实施例中图2中B处结构示意图。Fig. 7 is a schematic diagram of the structure at B in Fig. 2 in an embodiment of the present invention.

图中:1.质谱仪主体、101.隔板、102.电动机、103.水泵、104.进液管、105.出液管、2.底座、201.底座主体、202.入液管、203.承载座、204.滑道、205.摩擦件、206.卡座、207.容纳槽、208.摩擦部、209.放置腔、210.摩擦块、211.卡块、212.配重块、213.磁铁、214.通孔、3.搅拌机构、301.转轴、302.安装板、303.连接件、304.固定轴、305.第一轴承、306.扇叶、307.卡合件、308.放置槽、309.电磁铁、310.屏蔽网、4.连接座、401.第二轴承。In the figure: 1. Mass spectrometer main body, 101. Partition plate, 102. Motor, 103. Water pump, 104. Liquid inlet pipe, 105. Liquid outlet pipe, 2. Base, 201. Base main body, 202. Liquid inlet pipe, 203 .Bearing seat, 204. Slideway, 205. Friction piece, 206. Deck seat, 207. Accommodating groove, 208. Friction part, 209. Placement cavity, 210. Friction block, 211. Block block, 212. Counterweight block, 213. Magnet, 214. Through hole, 3. Stirring mechanism, 301. Rotating shaft, 302. Mounting plate, 303. Connecting piece, 304. Fixed shaft, 305. First bearing, 306. Fan blade, 307. Fastening piece, 308. placement slot, 309. electromagnet, 310. shielding net, 4. connecting seat, 401. second bearing.

具体实施方式detailed description

以下将结合附图所示的各实施方式对本发明进行详细描述。但该等实施方式并不限制本发明,本领域的普通技术人员根据该等实施方式所做出的结构、方法、或功能上的变换均包含在本发明的保护范围内。The present invention will be described in detail below in conjunction with various embodiments shown in the drawings. However, these embodiments do not limit the present invention, and structural, method, or functional changes made by those skilled in the art according to these embodiments are included in the protection scope of the present invention.

本发明公开了一种西番莲果肉物质检测装置,参图1-图7所示,包括质谱仪主体1、用于预处理的底座2、用于搅拌的搅拌机构3以及连接底座2和搅拌机构3的连接座4。The invention discloses a passion fruit pulp substance detection device, as shown in Fig. 1-Fig. Connection seat 4 of mechanism 3.

参图1-图6所示,质谱仪主体1的下侧设有底座2,且质谱仪主体1与底座2固定连接,质谱仪主体1内设有隔板101,隔板101与质谱仪主体1之间形成有安装腔,安装腔内设有电动机102和水泵103,电动机102与转轴301转动连接,电动机102用于驱动转轴301进行转动,从而可以带动自旋搅拌机构进行转动,对底座主体201内的溶液进行搅拌,避免溶液因浓度和温度不均匀出现结晶,水泵103用于将底座主体201内的溶液进行输送,利用质谱仪主体1进行检测,水泵103上连接有进液管104和出液管105,进液管104贯通底座主体201设置,出液管105贯通隔板101设置。Referring to Fig. 1-shown in Fig. 6, the underside of mass spectrometer main body 1 is provided with base 2, and mass spectrometer main body 1 is fixedly connected with base 2, and mass spectrometer main body 1 is provided with partition 101, and partition 101 and mass spectrometer main body An installation cavity is formed between 1, and a motor 102 and a water pump 103 are arranged in the installation cavity. The motor 102 is connected to the rotating shaft 301 in rotation, and the motor 102 is used to drive the rotating shaft 301 to rotate, so that the spin stirring mechanism can be driven to rotate, and the main body of the base The solution in 201 is stirred to avoid crystallization of the solution due to uneven concentration and temperature. The water pump 103 is used to transport the solution in the base body 201, and the mass spectrometer body 1 is used for detection. The water pump 103 is connected with a liquid inlet pipe 104 and The liquid outlet pipe 105 and the liquid inlet pipe 104 are arranged through the base body 201 , and the liquid outlet pipe 105 is arranged through the partition plate 101 .

参图2-图6所示,底座2包括底座主体201,用于存储溶液,底座主体201内部中空设置,底座主体201内底壁上安装有选调式生热机构,方便使用者是否对溶液进行加温,选调式生热机构包括承载座203,一方面,可以固定转轴301,另一方面方便存储摩擦件205,承载座203内开凿有滑道204,便于摩擦件205的滑动,滑道204内滑动连接有摩擦件205,摩擦件205位于滑道204内的一端连接有卡座206,承载座203上设有与卡座206相匹配的容纳槽207,容纳槽207与滑道204相连通,当使用者不需要使用摩擦件205时,通过卡座206卡合容纳槽207进行收纳。As shown in Figures 2-6, the base 2 includes a base body 201 for storing the solution. The base body 201 is hollow inside, and an optional heat generating mechanism is installed on the inner bottom wall of the base body 201 to facilitate the user whether to use the solution. The heating and adjustable heat generating mechanism includes a bearing seat 203. On the one hand, the rotating shaft 301 can be fixed, and on the other hand, the friction member 205 is conveniently stored. A slideway 204 is dug in the bearing seat 203 to facilitate the sliding of the friction member 205. The slideway 204 The inner slide is connected with a friction member 205, and one end of the friction member 205 located in the slideway 204 is connected with a card seat 206, and the bearing seat 203 is provided with a receiving groove 207 matching the card holder 206, and the receiving groove 207 communicates with the slideway 204 , when the user does not need to use the friction member 205, the holder 206 is engaged with the accommodating groove 207 for storage.

参图2-图6所示,摩擦件205的侧壁上设有卡合槽,卡合槽内设有摩擦部208,摩擦部208可以为金属、砂纸、木材或者橡胶,优选的,本发明采用金属,摩擦件205内开凿有放置腔209,放置腔209内设有与摩擦部208相匹配的摩擦块210,摩擦块210为金属材质,金属具有良好的导热性,热传递过程中,热量流失少,摩擦部208与摩擦块210相互摩擦产生大量的热,热经过摩擦块210进行传递,在通过承载座203上的通孔214散发出承载座203内,对底座主体201内的溶液进行加热,避免溶液因温度过低而出现结晶现象,摩擦件205贯通摩擦块210设置,承载座203远离底座主体201的一面上设有多个均匀分布的通孔214,大幅提高热的散发,可以对溶液进行加热,通孔214与放置腔209相连通。2-6, the side wall of the friction member 205 is provided with an engaging groove, and a friction part 208 is arranged in the engaging groove. The friction part 208 can be metal, sandpaper, wood or rubber. Preferably, the present invention Metal is used, and a placement cavity 209 is dug in the friction member 205, and a friction block 210 matching the friction part 208 is arranged in the placement cavity 209. The friction block 210 is made of metal, and metal has good thermal conductivity. The loss is small, the friction part 208 and the friction block 210 rub against each other to generate a large amount of heat, the heat is transmitted through the friction block 210, and is emitted into the carrying seat 203 through the through hole 214 on the carrying seat 203, and the solution in the base body 201 is carried out. Heating, to avoid crystallization of the solution due to too low temperature, the friction member 205 is set through the friction block 210, and the side of the bearing seat 203 away from the base body 201 is provided with a plurality of evenly distributed through holes 214, which greatly improves the heat dissipation and can The solution is heated, and the through hole 214 communicates with the placement cavity 209 .

参图1-图6所示,摩擦件205远离卡座206的一端固定连接有卡块211,卡块211为金属材质,方便电磁铁309通电产生强磁的吸引,从而可以固定摩擦件205和转轴301,卡块211的形状为六边形,提高摩擦件205与转轴301的连接稳定性,避免摩擦件205与转轴301连接时,发生错位。Referring to Figures 1-6, the end of the friction member 205 away from the deck 206 is fixedly connected with a block 211, and the block 211 is made of metal, which is convenient for the electromagnet 309 to generate strong magnetic attraction, thereby fixing the friction member 205 and The rotating shaft 301 and the locking block 211 are hexagonal in shape, which improves the connection stability between the friction member 205 and the rotating shaft 301 and prevents misalignment when the friction member 205 is connected to the rotating shaft 301 .

其中,通孔214上盖设有金属网,金属网为100筛目,金属网套设于连接座4的外侧,避免摩擦部208磨损下来的杂质进入到溶液内,造成检测的不准确。Wherein, the upper cover of the through hole 214 is provided with a metal mesh, the metal mesh is 100 meshes, and the metal mesh is sleeved on the outside of the connecting seat 4, so as to prevent the impurities worn off by the friction part 208 from entering the solution, resulting in inaccurate detection.

参图5-图6所示,卡座206内设有配重块212,便于增加摩擦件205的整体重量,使得电磁铁309在不通电时,摩擦件205依靠自身重力以及配重块212的重力下降,卡合在容纳槽207内,实现摩擦件205的固定,配重块212为金属材质,承载座203内设有与配重块212相匹配的磁铁213,通过磁铁213吸引配重块212,大幅提高摩擦件205的固定效果,避免摩擦件205在不使用时与转轴301发生碰撞。As shown in Figures 5-6, a counterweight 212 is provided in the card seat 206, which is convenient for increasing the overall weight of the friction member 205, so that when the electromagnet 309 is not powered, the friction member 205 relies on its own gravity and the weight of the counterweight 212. Gravity drops, and it is engaged in the accommodation groove 207 to realize the fixation of the friction member 205. The counterweight 212 is made of metal, and the bearing seat 203 is provided with a magnet 213 that matches the counterweight 212, and the counterweight is attracted by the magnet 213 212 , greatly improving the fixing effect of the friction member 205 to prevent the friction member 205 from colliding with the rotating shaft 301 when not in use.

参图2所示,承载座203的上侧设有搅拌机构3,用于对溶液进行搅拌,避免出现浓度差,同时也利于选调式生热机构热量的散发,承载座203与搅拌机构3之间连接有连接座4,连接座4内设有第二轴承401,第二轴承401上设有密封圈,避免溶液进入到承载座203内,大幅提高承载座203的保护效果,第二轴承401套设于转轴301的外侧,大幅提高底座2与搅拌机构3的固定效果,使得搅拌机构3在转动时不晃动,提高搅拌机构3的稳定性。As shown in Fig. 2, a stirring mechanism 3 is provided on the upper side of the bearing seat 203, which is used to stir the solution to avoid concentration differences, and is also beneficial to the distribution of heat from the optional heat generating mechanism. A connection seat 4 is connected between them, and a second bearing 401 is arranged in the connection seat 4, and a sealing ring is provided on the second bearing 401 to prevent the solution from entering the bearing seat 203, and greatly improve the protection effect of the bearing seat 203. The second bearing 401 Sleeved on the outside of the rotating shaft 301, the fixing effect between the base 2 and the stirring mechanism 3 is greatly improved, so that the stirring mechanism 3 does not shake when rotating, and the stability of the stirring mechanism 3 is improved.

参图2-图7所示,搅拌机构3包括转轴301,转轴301与电动机102固定连接,转轴301的侧壁上连接有一对自旋搅拌机构,自旋搅拌机构包括安装板302,转轴301与安装板302之间连接有连接件303,安装板302远离连接件303的一面上连接有一对固定轴304,固定轴304上套设有第一轴承305,方便扇叶306进行转动,第一轴承305上固定连接有扇叶306,扇叶306为塑料材质,安装板302跟随转轴301进行转动,安装板302上的扇叶306在溶液的作用下围绕第一轴承305进行转动,大幅提高扇叶306对溶液的搅拌效果,避免溶液出现浓度不均匀的现象,避免结晶的产生,同时大幅提高选调式生热机构的散热效果,提高溶液温度,进一步避免溶液出现结晶。Referring to Fig. 2-shown in Fig. 7, stirring mechanism 3 comprises rotating shaft 301, and rotating shaft 301 is fixedly connected with motor 102, is connected with a pair of spin stirring mechanism on the side wall of rotating shaft 301, and spin stirring mechanism comprises mounting plate 302, and rotating shaft 301 and A connecting piece 303 is connected between the mounting plates 302. A pair of fixed shafts 304 are connected to the side of the mounting plate 302 away from the connecting piece 303. The fixed shaft 304 is provided with a first bearing 305 to facilitate the rotation of the fan blade 306. The first bearing 305 is fixedly connected with a fan blade 306, the fan blade 306 is made of plastic material, the mounting plate 302 rotates with the rotating shaft 301, and the fan blade 306 on the mounting plate 302 rotates around the first bearing 305 under the action of the solution, greatly improving the The stirring effect of 306 on the solution can avoid the phenomenon of uneven concentration of the solution and avoid the generation of crystallization.

具体地,固定轴304的侧壁上设有一对卡合件307,第一轴承305上设有与卡合件307相匹配的卡槽,限位第一轴承305,避免第一轴承305脱离固定轴304。Specifically, a pair of engaging parts 307 are provided on the side wall of the fixed shaft 304, and a slot matching the engaging parts 307 is provided on the first bearing 305 to limit the first bearing 305 and prevent the first bearing 305 from being detached from the fixed position. shaft 304 .

参图7所示,转轴301靠近摩擦件205的一端上设有与卡块211相匹配的放置槽308,转轴301内设有电磁铁309,电磁铁309包括铁芯,铁芯的外侧套设有导电线组,导电线组的一端连接有电池,质谱仪主体1上设有按钮,导电线组的另一端与按钮相连接,电磁铁309通电带有强磁,强磁可以吸引卡块211,使得摩擦件205与转轴301充分固定,从而可以保证摩擦部208与摩擦块210的摩擦生热,电磁铁309的外侧设有屏蔽网310,避免强磁对第二轴承401的吸引,方便第二轴承401进行转动。As shown in Figure 7, the end of the rotating shaft 301 close to the friction member 205 is provided with a placement groove 308 matching the block 211, and an electromagnet 309 is arranged inside the rotating shaft 301. The electromagnet 309 includes an iron core, and the outer side of the iron core is sleeved There is a conductive wire group, one end of the conductive wire group is connected to a battery, a button is provided on the mass spectrometer body 1, the other end of the conductive wire group is connected to the button, and the electromagnet 309 is powered with a strong magnet, which can attract the block 211 , so that the friction member 205 and the rotating shaft 301 are fully fixed, so as to ensure that the friction between the friction part 208 and the friction block 210 generates heat. The outer side of the electromagnet 309 is provided with a shielding net 310 to avoid the attraction of the strong magnet to the second bearing 401, which is convenient for the second bearing 401. The second bearing 401 rotates.

一种西番莲果肉物质检测装置的检测方法,包括以下步骤:A detection method of a passion fruit pulp substance detection device, comprising the following steps:

S1.将西番莲果肉利用磁力加热搅拌器以及超声波震荡仪进行搅拌,得到均匀的西番莲果肉溶液;S1. the passion fruit pulp is stirred with a magnetic heating stirrer and an ultrasonic oscillator to obtain a uniform passion fruit pulp solution;

S2.利用旋转蒸发仪对上述步骤中得到的西番莲果肉溶液进行萃取,提取溶液以及溶液气体;S2. Utilize rotary evaporator to extract the passion fruit pulp solution obtained in the above steps, extract solution and solution gas;

S3.将上述步骤中萃取溶液通过入液管202通入到底座主体201内,进行质谱仪主体1分析前的准备;S3. Pass the extraction solution in the above steps into the base main body 201 through the liquid inlet pipe 202, and perform the preparation before the analysis of the mass spectrometer main body 1;

S4.通过质谱仪主体1上相应的按钮使得电磁铁309带电,电磁铁309通电产生较大的磁力,吸引承载座203内的摩擦件205在滑道204内滑动,使得摩擦件205上的卡块211卡合在转轴301上的放置槽308内,实现转轴301与摩擦件205的连接,同时摩擦件205侧壁上的摩擦部208与摩擦块210进行接触,控制电动机102的运转;S4. The electromagnet 309 is charged through the corresponding button on the mass spectrometer main body 1, and the electromagnet 309 is energized to generate a large magnetic force, which attracts the friction member 205 in the bearing seat 203 to slide in the slideway 204, so that the friction member 205 is locked. The block 211 is engaged in the placement groove 308 on the rotating shaft 301 to realize the connection between the rotating shaft 301 and the friction member 205, and at the same time, the friction portion 208 on the side wall of the friction member 205 contacts the friction block 210 to control the operation of the motor 102;

S5.电动机102转动带动与其相连的转轴301进行转动,转轴301上的连接的摩擦件205跟随转动,摩擦件205上的摩擦部208摩擦摩擦块210并产生大量的热,热通过通孔214排出,对底座主体201内的萃取溶液进行加热,同时转轴301侧壁上的自旋搅拌机构也开始旋转,对底座主体201内萃取的溶液进行搅拌,避免萃取溶液出现浓度不均匀的情况,也方便将摩擦产生的热进行分散,避免萃取溶液的温度过低而产生结晶;S5. The rotation of the motor 102 drives the rotating shaft 301 connected to it to rotate, and the connected friction member 205 on the rotating shaft 301 rotates accordingly, and the friction part 208 on the friction member 205 rubs against the friction block 210 and generates a large amount of heat, which is discharged through the through hole 214 , the extraction solution in the base body 201 is heated, and at the same time the spin stirring mechanism on the side wall of the rotating shaft 301 also starts to rotate, and the extraction solution in the base body 201 is stirred to avoid uneven concentration of the extraction solution, which is also convenient Disperse the heat generated by friction to avoid crystallization when the temperature of the extraction solution is too low;

S6.电动机102工作一段时间后,打开水泵103的开关,水泵103通过进液管104将底座主体201内萃取的溶液吸入到质谱仪主体1内进行分析,同时将S2中得到的溶液气体通入质谱仪主体1进行分析;S6. After the motor 102 works for a period of time, turn on the switch of the water pump 103, and the water pump 103 sucks the solution extracted in the base body 201 into the mass spectrometer body 1 through the liquid inlet pipe 104 for analysis, and simultaneously passes the solution gas obtained in S2 into Mass spectrometer main body 1 is analyzed;

S7.对上述步骤分析出的结果绘制色谱图,用NIST谱库捜索,确定西番莲果肉溶液以及溶液气体的化学组成。S7. draw chromatogram to the result analyzed in above-mentioned steps, search with NIST spectral library, determine the chemical composition of passion fruit pulp solution and solution gas.

由以上技术方案可以看出,本发明具有以下有益效果:As can be seen from the above technical solutions, the present invention has the following beneficial effects:

本发明通过选调式生热机构和自旋搅拌机构的配合设置,可以在被测介质进入到质谱仪前进行预处理,大幅减少被测介质从大气压中进入到真空环境中出现结晶的现象,避免质谱仪进样管路的堵塞,可以充分检测被测介质的物质,大幅提高质谱仪的检测效果。In the present invention, through the coordinated setting of the selected heat generating mechanism and the spin stirring mechanism, pretreatment can be performed before the measured medium enters the mass spectrometer, which greatly reduces the phenomenon of crystallization of the measured medium entering the vacuum environment from atmospheric pressure, avoiding The blockage of the mass spectrometer's sampling pipeline can fully detect the substance of the measured medium and greatly improve the detection effect of the mass spectrometer.

对于本领域技术人员而言,显然本发明不限于上述示范性实施例的细节,而且在不背离本发明的精神或基本特征的情况下,能够以其他的具体形式实现本发明。因此,无论从哪一点来看,均应将实施例看作是示范性的,而且是非限制性的,本发明的范围由所附权利要求而不是上述说明限定,因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。不应将权利要求中的任何附图标记视为限制所涉及的权利要求。It will be apparent to those skilled in the art that the invention is not limited to the details of the above-described exemplary embodiments, but that the invention can be embodied in other specific forms without departing from the spirit or essential characteristics of the invention. Accordingly, the embodiments should be regarded in all points of view as exemplary and not restrictive, the scope of the invention being defined by the appended claims rather than the foregoing description, and it is therefore intended that the scope of the invention be defined by the appended claims rather than by the foregoing description. All changes within the meaning and range of equivalents of the elements are embraced in the present invention. Any reference sign in a claim should not be construed as limiting the claim concerned.

此外,应当理解,虽然本说明书按照实施例加以描述,但并非每个实施例仅包含一个独立的技术方案,说明书的这种叙述方式仅仅是为清楚起见,本领域技术人员应当将说明书作为一个整体,各实施例中的技术方案也可以经适当组合,形成本领域技术人员可以理解的其他实施方式。In addition, it should be understood that although the specification is described according to the embodiments, not each embodiment only includes an independent technical solution, and this description in the specification is only for clarity, and those skilled in the art should take the specification as a whole , the technical solutions in the various embodiments can also be properly combined to form other implementations that can be understood by those skilled in the art.

Claims (6)

1. A passion flower pulp substance detection device comprises a mass spectrometer main body (1), and is characterized in that a base (2) is arranged on the lower side of the mass spectrometer main body (1), and the mass spectrometer main body (1) is fixedly connected with the base (2);
the base (2) comprises a base body (201), the base body (201) is arranged in a hollow manner, a selective-adjustment type heat generating mechanism is arranged on the inner bottom wall of the base body (201) and comprises a bearing seat (203), a slide way (204) is drilled in the bearing seat (203), a friction piece (205) is connected in the slide way (204) in a sliding manner, a clamping groove is formed in the side wall of the friction piece (205), a friction part (208) is arranged in the clamping groove, a placing cavity (209) is further drilled in the bearing seat (203), a friction block (210) matched with the friction part (208) is arranged in the placing cavity (209), the friction piece (205) is arranged by penetrating through the friction block (210), a plurality of uniformly distributed through holes (214) are formed in one surface of the bearing seat (203) far away from the base body (201), the through holes (214) are communicated with the placing cavity (209), one end of the friction piece (205) far away from the clamping seat (206) is fixedly connected with a clamping block (211), a stirring mechanism (3) is arranged on the upper side of the bearing seat (203), a second shaft (401) is sleeved with a stirring mechanism (3), and the bearing seat (401) is arranged between the second shaft (401), the stirring mechanism (3) comprises a rotating shaft (301), a pair of self-rotating stirring mechanisms is connected to the side wall of the rotating shaft (301), a placing groove (308) matched with the clamping block (211) is formed in one end, close to the friction piece (205), of the rotating shaft (301), and an electromagnet (309) is arranged in the rotating shaft (301);
one end of the friction piece (205) positioned in the slide way (204) is connected with a clamping seat (206), a containing groove (207) matched with the clamping seat (206) is arranged on the bearing seat (203), and the containing groove (207) is communicated with the slide way (204);
a balancing weight (212) is arranged in the clamping seat (206), the balancing weight (212) is made of metal, and a magnet (213) matched with the balancing weight (212) is arranged in the bearing seat (203);
the spinning stirring mechanism comprises a mounting plate (302), a connecting piece (303) is connected between the rotating shaft (301) and the mounting plate (302), one surface, far away from the connecting piece (303), of the mounting plate (302) is connected with a pair of fixed shafts (304), a first bearing (305) is sleeved on each fixed shaft (304), and fan blades (306) are fixedly connected to each first bearing (305);
a pair of clamping pieces (307) are arranged on the side wall of the fixed shaft (304), and clamping grooves matched with the clamping pieces (307) are formed in the first bearing (305).
2. The passion flower pulp detection device as recited in claim 1, wherein a partition plate (101) is arranged in the mass spectrometer body (1), an installation cavity is formed between the partition plate (101) and the mass spectrometer body (1), a motor (102) and a water pump (103) are arranged in the installation cavity, the motor (102) is rotatably connected with a rotating shaft (301), a liquid inlet pipe (104) and a liquid outlet pipe (105) are connected to the water pump (103), the liquid inlet pipe (104) penetrates through the base body (201), and the liquid outlet pipe (105) penetrates through the partition plate (101).
3. The passion flower pulp detection device as recited in claim 1, wherein the shape of the fixture block (211) is hexagonal.
4. The passion flower pulp detection device as recited in claim 1, wherein a metal mesh is covered on the through hole (214), the metal mesh is 100 meshes, and the metal mesh is sleeved outside the connection seat (4).
5. The passion flower pulp detection device as claimed in claim 1, wherein the electromagnet (309) comprises an iron core, a conductive wire set is sleeved on the outer side of the iron core, a battery is connected to one end of the conductive wire set, a button is arranged on the mass spectrometer body (1), the other end of the conductive wire set is connected with the button, and a shielding net (310) is arranged on the outer side of the electromagnet (309).
6. A method of testing a passion flower pulp testing device as claimed in claim 1, comprising the steps of:
s1, stirring passion fruit pulp by using a magnetic heating stirrer and an ultrasonic oscillator to obtain a uniform passion fruit pulp solution;
s2, extracting the passion fruit pulp solution obtained in the step by using a rotary evaporator, and extracting the solution and solution gas;
s3, introducing the extraction solution obtained in the step into the base main body (201) through the liquid inlet pipe (202) to prepare the mass spectrometer main body (1) before analysis;
s4, the electromagnet (309) is electrified through a corresponding button on the mass spectrometer main body (1), the electromagnet (309) is electrified to generate a large magnetic force, the friction piece (205) in the bearing seat (203) is attracted to slide in the slide way (204), the clamping block (211) on the friction piece (205) is clamped in the placing groove (308) on the rotating shaft (301), the rotating shaft (301) is connected with the friction piece (205), meanwhile, the friction part (208) on the side wall of the friction piece (205) is contacted with the friction block (210), and the running of the motor (102) is controlled;
s5, the motor (102) rotates to drive the rotating shaft (301) connected with the motor to rotate, the friction piece (205) connected with the rotating shaft (301) rotates along with the rotating shaft, the friction part (208) on the friction piece (205) rubs the friction block (210) and generates a large amount of heat, the heat is discharged through the through hole (214) to heat the extraction solution in the base main body (201), meanwhile, the spin stirring mechanism on the side wall of the rotating shaft (301) also starts to rotate to stir the solution extracted in the base main body (201), the situation that the concentration of the extraction solution is uneven is avoided, the heat generated by friction is conveniently dispersed, and the phenomenon that the temperature of the extraction solution is too low to generate crystals is avoided;
s6, after the motor (102) works for a period of time, a switch of the water pump (103) is turned on, the water pump (103) sucks the solution extracted from the base main body (201) into the mass spectrometer main body (1) through the liquid inlet pipe (104) for analysis, and meanwhile, the solution gas obtained in the S2 is introduced into the mass spectrometer main body (1) for analysis;
s7, drawing a chromatogram of the result analyzed in the step, searching by using an NIST library, and determining the chemical composition of the passion fruit pulp solution and the solution gas.
CN202010640069.6A 2020-07-06 2020-07-06 Passiflora edulis pulp substance detection device and detection method thereof Active CN111721832B (en)

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