CN111620564B - Luminous glaze with humidity adjusting function - Google Patents
Luminous glaze with humidity adjusting function Download PDFInfo
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- CN111620564B CN111620564B CN202010373154.0A CN202010373154A CN111620564B CN 111620564 B CN111620564 B CN 111620564B CN 202010373154 A CN202010373154 A CN 202010373154A CN 111620564 B CN111620564 B CN 111620564B
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- 239000000463 material Substances 0.000 claims abstract description 27
- 239000002994 raw material Substances 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 11
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 8
- 239000002270 dispersing agent Substances 0.000 claims abstract description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- 229910017623 MgSi2 Inorganic materials 0.000 claims description 10
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 9
- 229910052693 Europium Inorganic materials 0.000 claims description 7
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 229910052593 corundum Inorganic materials 0.000 claims description 6
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 4
- 229910052681 coesite Inorganic materials 0.000 claims description 4
- 229910052906 cristobalite Inorganic materials 0.000 claims description 4
- 229910052634 enstatite Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 229910052682 stishovite Inorganic materials 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 229910052905 tridymite Inorganic materials 0.000 claims description 4
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 claims description 4
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- 239000004113 Sepiolite Substances 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 239000011499 joint compound Substances 0.000 claims description 2
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 239000008262 pumice Substances 0.000 claims description 2
- 229910052624 sepiolite Inorganic materials 0.000 claims description 2
- 235000019355 sepiolite Nutrition 0.000 claims description 2
- 239000004575 stone Substances 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- 230000003750 conditioning effect Effects 0.000 claims 2
- 238000009841 combustion method Methods 0.000 claims 1
- 239000000919 ceramic Substances 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 9
- 238000010304 firing Methods 0.000 abstract description 7
- 239000000741 silica gel Substances 0.000 abstract description 6
- 229910002027 silica gel Inorganic materials 0.000 abstract description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract description 5
- 229910052656 albite Inorganic materials 0.000 abstract description 5
- 229940072033 potash Drugs 0.000 abstract description 5
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract description 5
- 235000015320 potassium carbonate Nutrition 0.000 abstract description 5
- 230000001105 regulatory effect Effects 0.000 abstract description 5
- 238000005034 decoration Methods 0.000 abstract description 3
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 238000004020 luminiscence type Methods 0.000 abstract description 2
- 239000011449 brick Substances 0.000 description 16
- 238000000227 grinding Methods 0.000 description 8
- 239000011812 mixed powder Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 5
- 239000011858 nanopowder Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000029058 respiratory gaseous exchange Effects 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Luminescent Compositions (AREA)
Abstract
The invention discloses a noctilucent glaze with a humidity adjusting function, which comprises the following raw material components in parts by weight: 35-55 parts of potash albite, 5-15 parts of a humidity control material, 1-3 parts of silica gel, 0.1-1.2 parts of yttrium zirconate, 0.5-4.5 parts of noctilucent powder, 20-25 parts of low-temperature frit and 1-2 parts of a dispersing agent. According to the invention, through the adjustment and special selection of raw material components, the ceramic glaze is adapted to a low-temperature glaze firing process, and the obtained ceramic glaze has the humidity regulating function and the noctilucent decoration effect, and is excellent in humidity regulating performance and stable and lasting in night luminescence effect.
Description
Technical Field
The invention relates to the field of ceramic glaze, in particular to luminous glaze with a humidity adjusting function.
Background
The functional ceramic tile has some special functions of common decorative ceramic tile, such as heating tile, negative ion tile, water permeable tile, antiskid tile, breathing tile, self-cleaning ceramic tile, etc. and is mainly characterized by utilizing non-mechanical property material to implement functionalization of ceramic tile. The humidity-regulating brick belongs to one of breathing bricks, the production process of the humidity-regulating brick is basically the same as that of other ceramic products, and the humidity-regulating brick is also subjected to ball milling, spray drying, press forming, glazing, firing and the like, but the raw materials of the humidity-regulating brick are different from those of a common brick. The humidity-regulating brick is prepared by firing a large amount of natural environment-friendly materials such as natural clay rich in micropores, marine ancient organism sedimentary minerals and the like at a scientific ratio at a high temperature, and a blank body of the humidity-regulating brick is formed with a large amount of fine pores, so that the humidity-regulating brick has the reversible function of effectively absorbing and releasing water vapor and the like, can absorb water into the brick body when the humidity is high, and can release water when the humidity is high, so that the humidity-regulating brick has the effect of regulating the humidity of indoor air, and is named as the humidity-regulating brick. Because of the particularity of the green body of the humidity-controlling brick, the humidity-controlling brick has special requirements on the coated ceramic glaze, so that the surface of the current humidity-controlling brick green body can only adopt simple surface treatment, and the humidity-controlling brick cannot have the defect of special decorative effect.
Disclosure of Invention
The invention aims to overcome the defects in the prior art, and provides a noctilucent glaze material with a humidity adjusting function, which has a porous structure after being sintered at high temperature, can realize the humidity adjusting function and has a noctilucent decoration effect.
The technical scheme adopted by the invention is as follows: a noctilucent glaze with humidity adjusting function comprises the following raw material components in parts by weight:
specifically, yttrium zirconate is introduced to be compounded with noctilucent powder to serve as a noctilucent material, and the noctilucent powder is endowed with more remarkable noctilucent performance by utilizing the transparent effect of the yttrium zirconate formed in a glass phase in the glaze firing process. The silica gel in the invention is beneficial to improving the mechanical property of the glaze surface after the glaze material is fired, has good compatibility with low-temperature frit, and can further reduce the firing temperature of the glaze material. Meanwhile, the silica gel in the invention is also beneficial to the formation of a uniform porous structure of the humidity-controlling material in the sintering process.
As a further improvement of the above aspect, the humidity controlling material is at least one selected from diatomaceous earth, volcanic mud, sepiolite, zeolite, medical stone, and pumice. Specifically, the humidity controlling material of the invention not only can endow the glaze surface with a good porous structure to realize the humidity controlling function of the glaze, but also can be used as a carrier of the noctilucent powder, so that the noctilucent powder has a more obvious noctilucent effect.
As a further improvement of the proposal, the luminous powder is silicate-based long-afterglow luminescent material which is selected from Sr2MgSi207:Eu,Dy、Ca2MgSi207:Eu,Dy、MgSi03At least one of Mn, Eu and Dy. Particularly, the noctilucent powder disclosed by the invention has excellent dispersity and compatibility with other glaze components, so that the noctilucent effect of the glaze is stable and durable.
As a further improvement of the above scheme, the low-temperature frit comprises the following chemical components in percentage by weight: 66.1% SiO23.5% of Al2O36.15% of B2O317.88% of Bi3O20.74% of MgO and 2.58% of K2O, 1.63% of Na2O, 1.42% Li2O。
As a further improvement of the scheme, the yttrium zirconate is prepared by mixing zirconium nitrate and yttrium oxide according to the molar ratio of Zr to Y of 1:1, then carrying out combustion, and further carrying out ball milling treatment to obtain yttrium zirconate nano-powder with the particle size of 150-300 nm. The limitation of yttrium zirconate by the invention is beneficial to forming a uniform glass phase in the glaze firing process.
As a further improvement of the above scheme, the dispersant is selected from one of carboxymethyl cellulose, sodium tripolyphosphate and polyacrylic acid, which is beneficial to improving the dispersion efficiency of raw materials in the glaze mixing process.
The invention has the beneficial effects that: according to the invention, through the adjustment and special selection of raw material components, the ceramic glaze is adapted to a low-temperature glaze firing process, and the obtained ceramic glaze has the humidity regulating function and the noctilucent decoration effect, and is excellent in humidity regulating performance and stable and lasting in night luminescence effect.
Detailed Description
The present invention is specifically described below with reference to examples in order to facilitate understanding of the present invention by those skilled in the art. It should be particularly noted that the examples are given solely for the purpose of illustration and are not to be construed as limitations on the scope of the invention, as non-essential improvements and modifications to the invention may occur to those skilled in the art, which fall within the scope of the invention as defined by the appended claims. Meanwhile, the raw materials mentioned below are not specified in detail and are all commercial products; the process steps or preparation methods not mentioned in detail are all process steps or preparation methods known to the person skilled in the art.
Example 1
A noctilucent glaze with humidity adjusting function comprises the following raw material components in parts by weight:
wherein the silicate-based long-afterglow luminescent material is Sr2MgSi207Eu, Dy and Ca2MgSi207Eu and D are mixed according to the mass ratio of 1: 1. The low-temperature frit comprises 66.1% of SiO (silicon dioxide) in percentage by weight23.5% of Al2O36.15% of B2O317.88% of Bi3O20.74% of MgO and 2.58% of K2O, 1.63% of Na2O, 1.42% Li2O。
The preparation method comprises the following steps:
1) uniformly mixing the potash albite, the silica gel and the low-temperature frit according to the weight parts of the raw materials, and grinding to obtain mixed powder;
2) adding yttrium zirconate nano powder, silicate-based long-afterglow luminescent material, carboxymethyl cellulose and water into the mixed powder in sequence according to the weight parts of the raw materials, stirring and mixing the materials, and uniformly grinding the materials to obtain the finished product of the example 1.
Comparative example 1
A noctilucent glaze with humidity adjusting function comprises the following raw material components in parts by weight:
wherein the silicate-based long-afterglow luminescent material is Sr2MgSi207Eu, Dy and Ca2MgSi207Eu and D are mixed according to the mass ratio of 1: 1. The low-temperature frit comprises 66.1% of SiO (silicon dioxide) in percentage by weight23.5% of Al2O36.15% of B2O317.88% of Bi3O20.74% of MgO and 2.58% of K2O, 1.63% of Na2O, 1.42% Li2O。
The preparation method comprises the following steps:
1) uniformly mixing the potash albite and the low-temperature frit according to the weight parts of the raw materials, and grinding to obtain mixed powder;
2) adding the silicate-based long-afterglow luminescent material, the carboxymethyl cellulose and the water into the mixed powder in sequence according to the weight parts of the raw materials, stirring and mixing the materials, and grinding the materials uniformly to obtain a finished product of the comparative example 1.
Example 2
A noctilucent glaze with humidity adjusting function comprises the following raw material components in parts by weight:
wherein the silicate-based long-afterglow luminescent material is MgSi03Mn, Eu, Dy. The low-temperature frit comprises the following chemical components in percentage by weight: 66.1% SiO23.5% of Al2O36.15% of B2O317.88% of Bi3O20.74% of MgO and 2.58% of K2O, 1.63% of Na2O, 1.42% Li2O。
The preparation method comprises the following steps:
1) uniformly mixing the potash albite, the silica gel and the low-temperature frit according to the weight parts of the raw materials, and grinding to obtain mixed powder;
2) adding yttrium zirconate nano powder, a silicate-based long-afterglow luminescent material, sodium tripolyphosphate and water into the mixed powder in sequence according to the weight parts of the raw materials, stirring, mixing and grinding uniformly to obtain a finished product in the example 2.
Example 3
A noctilucent glaze with humidity adjusting function comprises the following raw material components in parts by weight:
wherein the silicate-based long-afterglow luminescent material is Sr2MgSi207:Eu,Dy、Ca2MgSi207Eu, Dy and MgSi03Mn, Eu and Dy are mixed according to the mass ratio of 1:1: 1. The low-temperature frit is prepared by weight percentThe chemical components are as follows: 66.1% SiO23.5% of Al2O36.15% of B2O317.88% of Bi3O20.74% of MgO and 2.58% of K2O, 1.63% of Na2O, 1.42% Li2O。
The preparation method comprises the following steps:
1) uniformly mixing the potash albite, the silica gel and the low-temperature frit according to the weight parts of the raw materials, and grinding to obtain mixed powder;
2) and sequentially adding yttrium zirconate nano powder, a silicate-based long-afterglow luminescent material, a dispersing agent and water into the mixed powder according to the weight parts of the raw materials, stirring, mixing and grinding uniformly to obtain a finished product in the example 3.
Example 4: performance detection
The finished products of examples 1-3 and the finished product of comparative example 1 were equally distributed on the same ceramic tile with decorative pattern texture, and were fired at 850 ℃ in a kiln to obtain samples, and the test results were as shown in table 1 below.
TABLE 1 results of measurements of the relevant Properties of the samples
The above embodiments are preferred embodiments of the present invention, and all similar processes and equivalent variations to those of the present invention should fall within the scope of the present invention.
Claims (3)
1. A luminous glaze with humidity adjusting function is characterized in that: the material comprises the following raw materials in parts by weight:
the humidity adjusting material is at least one of diatomite, volcanic mud, sepiolite, zeolite, medical stone and pumice;
the noctilucent powder is a silicate-based long-afterglow luminescent material;
the silicate-based long-afterglow luminescent material is selected from Sr2MgSi207:Eu,Dy、Ca2MgSi207:Eu,Dy、MgSi03At least one of Mn, Eu and Dy;
the yttrium zirconate is prepared by mixing zirconium nitrate and yttrium oxide according to the molar ratio of Zr to Y of 1:1 and then carrying out a combustion method;
the particle size of the yttrium zirconate is 150-300 nm.
2. The luminous glaze with humidity conditioning function as claimed in claim 1, wherein: the low-temperature frit comprises the following chemical components in percentage by weight: 66.1% SiO23.5% of Al2O36.15% of B2O317.88% of Bi3O20.74% of MgO and 2.58% of K2O, 1.63% of Na2O, 1.42% Li2O。
3. The luminous glaze with humidity conditioning function as claimed in claim 1, wherein: the dispersing agent is selected from one of carboxymethyl cellulose, sodium tripolyphosphate and polyacrylic acid.
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| CN111620564B true CN111620564B (en) | 2022-03-25 |
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| CN114477767A (en) * | 2022-04-06 | 2022-05-13 | 佛山市东鹏陶瓷发展有限公司 | Glaze with humidity adjusting function and preparation method of ceramic tile using glaze |
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| CN107651851A (en) * | 2017-09-30 | 2018-02-02 | 佛山欧神诺陶瓷股份有限公司 | A kind of photocatalysis glaze applied to damping Ceramic Tiles and preparation method thereof |
| CN108892496A (en) * | 2018-07-03 | 2018-11-27 | 佛山欧神诺陶瓷有限公司 | A kind of damping Ceramic Tiles and preparation method thereof with high moisture adsorption and releasing amount |
| CN108892383A (en) * | 2018-08-16 | 2018-11-27 | 醴陵市良盛陶瓷制造有限公司 | The unleaded metal glaze of silver color and its preparation process |
| CN109206013A (en) * | 2018-09-17 | 2019-01-15 | 泉州市陶瓷科学技术研究所 | A kind of long afterglow that glaze paint is not cracked ceramics and its manufacture craft |
| CN109354412A (en) * | 2018-12-25 | 2019-02-19 | 佛山科学技术学院 | A kind of luminescent ceramic glazed tile |
| CN110615674A (en) * | 2019-09-29 | 2019-12-27 | 福建省德化臻南陶瓷有限公司 | Preparation process of non-cracking glaze-surface over-glaze decoration craft porcelain |
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