CN111196617A - Composite material and method for removing antibiotics in water body - Google Patents
Composite material and method for removing antibiotics in water body Download PDFInfo
- Publication number
- CN111196617A CN111196617A CN202010183552.6A CN202010183552A CN111196617A CN 111196617 A CN111196617 A CN 111196617A CN 202010183552 A CN202010183552 A CN 202010183552A CN 111196617 A CN111196617 A CN 111196617A
- Authority
- CN
- China
- Prior art keywords
- antibiotics
- composite material
- water
- parts
- water body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 239000002131 composite material Substances 0.000 title claims abstract description 35
- 239000003242 anti bacterial agent Substances 0.000 title claims abstract description 33
- 229940088710 antibiotic agent Drugs 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 82
- 229910052742 iron Inorganic materials 0.000 claims abstract description 41
- 239000004576 sand Substances 0.000 claims abstract description 35
- 239000004927 clay Substances 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 10
- 238000007873 sieving Methods 0.000 claims description 10
- 238000000227 grinding Methods 0.000 claims description 9
- 230000003115 biocidal effect Effects 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 238000002791 soaking Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- 239000004098 Tetracycline Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 230000001376 precipitating effect Effects 0.000 claims description 3
- 229960002180 tetracycline Drugs 0.000 claims description 3
- 229930101283 tetracycline Natural products 0.000 claims description 3
- 235000019364 tetracycline Nutrition 0.000 claims description 3
- 150000003522 tetracyclines Chemical class 0.000 claims description 3
- 229940123317 Sulfonamide antibiotic Drugs 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- LISFMEBWQUVKPJ-UHFFFAOYSA-N quinolin-2-ol Chemical compound C1=CC=C2NC(=O)C=CC2=C1 LISFMEBWQUVKPJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002910 solid waste Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 239000002351 wastewater Substances 0.000 abstract description 3
- 230000001737 promoting effect Effects 0.000 abstract description 2
- 238000004065 wastewater treatment Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 6
- 239000002699 waste material Substances 0.000 description 5
- MYSWGUAQZAJSOK-UHFFFAOYSA-N ciprofloxacin Chemical compound C12=CC(N3CCNCC3)=C(F)C=C2C(=O)C(C(=O)O)=CN1C1CC1 MYSWGUAQZAJSOK-UHFFFAOYSA-N 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- 241000237536 Mytilus edulis Species 0.000 description 3
- 239000011246 composite particle Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 235000020638 mussel Nutrition 0.000 description 3
- 238000000643 oven drying Methods 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 241000237509 Patinopecten sp. Species 0.000 description 2
- 229960003405 ciprofloxacin Drugs 0.000 description 2
- 235000020637 scallop Nutrition 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 241000490567 Pinctada Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033558 biomineral tissue development Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- SEEPANYCNGTZFQ-UHFFFAOYSA-N sulfadiazine Chemical compound C1=CC(N)=CC=C1S(=O)(=O)NC1=NC=CC=N1 SEEPANYCNGTZFQ-UHFFFAOYSA-N 0.000 description 1
- 229960004306 sulfadiazine Drugs 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
本发明涉及一种用于去除水体中抗生素的复合材料，其由如下重量份的原料制得：贝壳40~60份、铁尾矿砂20~40份、粘土10~20份。本发明还涉及利用该材料对含抗生素废水进行处理的方法。本发明处理速度快，同时也为大量固体废弃物贝壳和铁尾矿砂的开发利用及废水治理提供一条有效途径，对保护生态环境、促进工农业可持续和健康发展具有重要意义。The invention relates to a composite material for removing antibiotics in a water body, which is prepared from the following raw materials in parts by weight: 40-60 parts of shells, 20-40 parts of iron tailing sand and 10-20 parts of clay. The invention also relates to a method for treating wastewater containing antibiotics by using the material. The invention has a fast processing speed, and also provides an effective way for the development and utilization of a large number of solid waste shells and iron tailings and waste water treatment, and is of great significance for protecting the ecological environment and promoting the sustainable and healthy development of industry and agriculture.
Description
Technical Field
The invention relates to the technical field of environmental water pollution treatment, in particular to a composite material and a method for removing antibiotics in a water body.
Background
As antibiotics are widely applied in the fields of human medical treatment, agricultural production, livestock raising, aquaculture and the like, the antibiotics are detected in surface water, underground water and even drinking water, and the antibiotics remained in the water body can cause harm to various organisms, induce drug resistance and further threaten the safety of ecological environment and the health of human bodies.
The method for removing the antibiotics in the water body mainly comprises the following steps: membrane filtration, adsorption, electrochemical, photodegradation, oxidation, biological, and the like. The adsorption method is an important method for removing water body antibiotic pollution, and is low in cost, simple to operate and free of high-toxicity metabolite risk in the treatment process, and is considered to be one of the most promising effective means in the technology for treating trace pollutants in the environment, so that the development of a novel efficient adsorption material which is low in cost and easy to synthesize and is used for removing the water body antibiotic is of great significance.
Disclosure of Invention
The invention aims to provide a composite material for quickly removing antibiotics in a water body and a method for removing the antibiotics in the water body by using the composite material.
The invention adopts the following technical scheme:
a composite material for removing antibiotics in a water body is prepared from the following raw materials in parts by weight: 40-60 parts of shells, 20-40 parts of iron tailing sand and 10-20 parts of clay.
Wherein the shell is mussel, scallop, oyster, freshwater mussel, clam, pearl oyster, etc., and has no special requirement.
Wherein the iron tailing sand is solid waste discharged after the useful components are selected by grinding iron ore.
Wherein the clay is conventional clay.
Further, the preparation method comprises the following steps:
(1) soaking the shells in a hydrochloric acid solution with the mass concentration of 0.2-0.5% for 30-40 min, washing with water, drying, crushing and grinding the shells with clean surfaces, and sieving the shells with a 100-mesh sieve;
(2) respectively crushing the dried iron tailing sand and clay, and sieving by a 100-mesh sieve;
(3) uniformly mixing the shell powder, the iron tailing sand and the clay which are obtained after crushing according to the weight part ratio, wherein the water content is 45-60%, granulating in a granulator, drying at 105 ℃, and roasting at 350-750 ℃ for 2-3 hours to obtain the iron tailing sand.
Furthermore, in the step (3), the grain size of the granules is 2-3 mm.
Furthermore, the composite material can remove tetracycline, quinolone and sulfonamide antibiotics in water, such as tetracycline, Ciprofloxacin (CIP), sulfadiazine and the like, wherein the antibiotics exist in a soluble solution form.
A method for removing antibiotics in a water body by using the composite material comprises the following steps:
(I) measuring the content of antibiotics in the water body;
(II) adding a certain amount of composite material according to the content of the antibiotics, and oscillating and uniformly mixing at room temperature for 5-10 hours;
(III) filtering, precipitating or centrifuging the composite material from the water body, and recovering;
(IV) heating the recovered particles at 100-200 ℃ for 1-3 h to inactivate the antibiotics and reuse the inactivated antibiotics.
In the method, 1g of composite material is added into each liter of water body, so that at least 5mg of antibiotics in the water body can be removed.
Particularly, 5-7 mg of antibiotics in the water body can be removed by adding 1g of composite material into each liter of water body.
The invention has the beneficial effects that: with the rapid development of shellfish culture and processing industry, thousands of tons of shells are generated in China every year, the added value is low, most of the shells are directly discarded as waste except that few kinds of shells become precious medicinal materials or artware after being processed, land resources are occupied, and serious environmental pollution is caused. From the resource perspective, the shell is an organic-inorganic composite biomineralization material, wherein calcium carbonate accounts for about 95 percent, and the rest 5 percent is organic matters such as protein, polysaccharide and the like, and the special structure enables the shell powder to have better organic affinity and water sinking performance. The iron tailing sand is waste after mineral separation in the iron and steel industry, and also has the characteristics of large specific surface area, certain adsorption capacity, high density, easiness in sedimentation in water and the like.
The invention utilizes the characteristics of the shell powder and the iron tailing sand, takes the solid waste of the waste shell and the iron tailing sand as the main raw material, has large amount, low price and easy obtainment, treats the antibiotics in the water body by using the solid waste, improves the water quality, equivalently treats the pollution by using the waste, changes waste into valuable and obviously reduces the treatment cost. Secondly, the composite material only needs 5-10 hours for removing antibiotics in the water body, is quick and efficient, and is easy to precipitate, separate and recover. Third, the recycled composite material can be recycled. Fourthly, the invention provides an effective way for the development and utilization of a large amount of solid waste shells and iron tailing sand and the treatment of wastewater, and has important significance for protecting the ecological environment and promoting the sustainable and healthy development of industry and agriculture.
Detailed Description
The embodiments of the present invention are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. Unless otherwise defined, terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Further, it will be understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and will not be interpreted in an idealized or overly formal sense.
Example 1
A shell powder and iron tailing sand composite material is prepared by the following steps:
(1) soaking mussel shell in 0.2% hydrochloric acid solution for 40 min, washing with water, oven drying, pulverizing, grinding, and sieving with 100 mesh sieve.
(2) Drying, crushing and grinding the iron tailing sand, and sieving the iron tailing sand by a 100-mesh sieve;
(3) the shell powder, the iron tailing sand powder and the clay which are obtained after crushing are prepared according to the following components in parts by weight: 40 parts of shell powder, 40 parts of iron tailing sand and 20 parts of clay are proportioned and mixed uniformly, and the water content is 50%.
(4) Granulating in a granulator to obtain particles with the particle size of 2-3 mm, and drying at 105 ℃.
(5) Roasting at 500 deg.c for 2 hr and cooling to obtain composite particle.
Wherein the iron tailings sand is derived from Handan north Minghe iron ore in Hebei province, and the main chemical components are shown in Table 1.
Table 1 main chemical composition of iron tailings sand in example 1
Example 2
A shell powder and iron tailing sand composite material is prepared by the following steps:
(1) soaking scallop and oyster shell in 0.3% hydrochloric acid solution for 35 min, washing with water, oven drying the shell with clean surface, pulverizing, grinding, and sieving with 100 mesh sieve.
(2) Drying, crushing and grinding the iron tailing sand, and sieving the iron tailing sand by a 100-mesh sieve;
(3) the shell powder, the iron tailing sand powder and the clay which are obtained after crushing are prepared according to the following components in parts by weight: 55 parts of shell powder, 30 parts of iron tailing sand and 15 parts of clay are proportioned and mixed uniformly, and the water content is 60%.
(4) Granulating in a granulator to obtain particles with the particle size of 2-3 mm, and drying at 105 ℃.
(5) Roasting at 350 deg.c for 3 hr and cooling to obtain composite particle.
Wherein the iron tailing sand comes from Chengde of Hebei province, and the main chemical components are shown in Table 2.
Table 2 main chemical composition of iron tailings sand in example 2
Example 3
A shell powder and iron tailing sand composite material is prepared by the following steps:
(1) soaking clam shells in 0.5% hydrochloric acid solution for 30 min, washing with water, oven drying the shells with clean surface, pulverizing, grinding, and sieving with 100 mesh sieve.
(2) Drying, crushing and grinding the iron tailing sand, and sieving the iron tailing sand by a 100-mesh sieve;
(3) the shell powder, the iron tailing sand powder and the clay which are obtained after crushing are prepared according to the following components in parts by weight: 60 parts of shell powder, 20 parts of iron tailing sand and 10 parts of clay are proportioned and uniformly mixed, and the water content is 55%.
(4) Granulating in a granulator to obtain particles with the particle size of 2-3 mm, and drying at 105 ℃.
(5) Roasting at 700 deg.c for 2 hr and cooling to obtain composite particle.
Wherein the iron tailings are derived from Handan-jade plano iron ore in Hebei province, and the main chemical components are shown in Table 3.
Table 3 main chemical composition of iron tailings sand in example 3
Examples 4 to 12
Preparing antibiotic-containing (1-10 mg/L) solutions with different concentrations, wherein 1L of the antibiotic-containing solutions are filled in each container, and treating the solutions by respectively adopting the composite materials prepared in different embodiments.
According to the antibiotic content in the examples 4-6, the composite material is properly added, the addition amount of the composite material can be equal to or larger than 5mg per g of the antibiotic removal amount in the solution, and after the composite material is added to the antibiotic-containing solution at room temperature (10-35 ℃), the composite material is continuously vibrated and uniformly mixed for 5-10 hours. And filtering, precipitating or centrifuging the treated composite material from a water body, recovering, and heating at 100-200 ℃ for 1-3 h to inactivate antibiotics for reuse. The results shown in table 4 show that the removal rate of the composite material to the antibiotics in the water body is greater than 97%.
TABLE 4 iron tailings sand composite material treatment of cobalt-containing wastewater results
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents or improvements made within the spirit and principle of the present invention should be included in the scope of the present invention.
Claims (6)
1. The composite material for removing antibiotics in water is characterized by being prepared from the following raw materials in parts by weight: 40-60 parts of shells, 20-40 parts of iron tailing sand and 10-20 parts of clay.
2. The composite material for removing antibiotics in water bodies according to claim 1, wherein the preparation method comprises the following steps:
(1) soaking the shells in a hydrochloric acid solution with the mass concentration of 0.2-0.5% for 30-40 min, washing with water, drying, crushing and grinding the shells with clean surfaces, and sieving the shells with a 100-mesh sieve;
(2) respectively crushing the dried iron tailing sand and clay, and sieving by a 100-mesh sieve;
(3) uniformly mixing the shell powder, the iron tailing sand and the clay which are obtained after crushing according to the weight part ratio, wherein the water content is 45-60%, granulating in a granulator, drying at 105 ℃, and roasting at 350-750 ℃ for 2-3 hours to obtain the iron tailing sand.
3. The composite material for removing antibiotics in water bodies according to claim 1, wherein in the step (3), the grain size of the granules is 2-3 mm.
4. The composite material for removing antibiotics in water bodies according to claim 1, wherein tetracycline, quinolone and sulfonamide antibiotics in water bodies can be removed.
5. A method for removing antibiotics in a water body by using the composite material as claimed in any one of claims 1 to 4, which is characterized by comprising the following steps:
(I) measuring the content of antibiotics in the water body;
(II) adding a certain amount of composite material according to the content of the antibiotics, and oscillating and uniformly mixing at room temperature for 5-10 hours;
(III) filtering, precipitating or centrifuging the composite material from the water body, and recovering;
(IV) heating the recovered particles at 100-200 ℃ for 1-3 h to inactivate the antibiotics and reuse the inactivated antibiotics.
6. The method according to claim 4, wherein in the step (II), at least 5mg of the antibiotic is removed by adding 1g of the composite material per liter of the water body.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010183552.6A CN111196617B (en) | 2020-03-16 | 2020-03-16 | Composite material and method for removing antibiotics in water body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010183552.6A CN111196617B (en) | 2020-03-16 | 2020-03-16 | Composite material and method for removing antibiotics in water body |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111196617A true CN111196617A (en) | 2020-05-26 |
| CN111196617B CN111196617B (en) | 2022-05-31 |
Family
ID=70745229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010183552.6A Active CN111196617B (en) | 2020-03-16 | 2020-03-16 | Composite material and method for removing antibiotics in water body |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111196617B (en) |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004046050A1 (en) * | 2002-11-19 | 2004-06-03 | N-Viro International Corporation | Method for disinfecting and stabilizing organic wastes with mineral by-products |
| CN101215039A (en) * | 2008-01-21 | 2008-07-09 | 浙江大学 | A method for removing heterocyclic aromatic compounds in wastewater |
| CN101831304A (en) * | 2010-04-30 | 2010-09-15 | 张夫道 | Method for using major metal tailings as soil conditioners after innocent treatment |
| CN102423682A (en) * | 2011-12-07 | 2012-04-25 | 南京工业大学 | Adsorbent for removing antibiotics in water body, preparation method and application |
| CN103316628A (en) * | 2013-06-27 | 2013-09-25 | 昆明理工大学 | Preparation method and application of adsorbent |
| US20150041409A1 (en) * | 2013-08-09 | 2015-02-12 | Aquablok, Ltd. | Reactive Treatment Cell and Systems For Environmental Remediation |
| CN104383873A (en) * | 2014-11-13 | 2015-03-04 | 中国科学院兰州化学物理研究所盱眙凹土应用技术研发中心 | Method for preparing composite adsorbent by utilizing low-grade attapulgite clay |
| CN105289470A (en) * | 2015-11-18 | 2016-02-03 | 中国科学院兰州化学物理研究所 | Method for preparing charcoal-supported attapulgite nano composite by using antibiotic wastewater |
| CN106315605A (en) * | 2016-08-31 | 2017-01-11 | 中国科学院兰州化学物理研究所盱眙凹土应用技术研发中心 | Method for preparing 1.1nm tobermorite from low-grade attapulgite clay |
| CN107445216A (en) * | 2016-06-01 | 2017-12-08 | 张会君 | A kind of formula and preparation method for sewage disposal dephosphorization filler |
| KR101888829B1 (en) * | 2018-01-12 | 2018-08-16 | (주) 푸른환경산업 | Adsorption carrier using silica fume and calcium hydroxide, and method of manufacturing there of |
| CN109824055A (en) * | 2019-04-04 | 2019-05-31 | 河北工业大学 | Method for preparing nano-sheet zinc silicate composite adsorbent from iron tailings |
-
2020
- 2020-03-16 CN CN202010183552.6A patent/CN111196617B/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004046050A1 (en) * | 2002-11-19 | 2004-06-03 | N-Viro International Corporation | Method for disinfecting and stabilizing organic wastes with mineral by-products |
| CN101215039A (en) * | 2008-01-21 | 2008-07-09 | 浙江大学 | A method for removing heterocyclic aromatic compounds in wastewater |
| CN101831304A (en) * | 2010-04-30 | 2010-09-15 | 张夫道 | Method for using major metal tailings as soil conditioners after innocent treatment |
| CN102423682A (en) * | 2011-12-07 | 2012-04-25 | 南京工业大学 | Adsorbent for removing antibiotics in water body, preparation method and application |
| CN103316628A (en) * | 2013-06-27 | 2013-09-25 | 昆明理工大学 | Preparation method and application of adsorbent |
| US20150041409A1 (en) * | 2013-08-09 | 2015-02-12 | Aquablok, Ltd. | Reactive Treatment Cell and Systems For Environmental Remediation |
| CN104383873A (en) * | 2014-11-13 | 2015-03-04 | 中国科学院兰州化学物理研究所盱眙凹土应用技术研发中心 | Method for preparing composite adsorbent by utilizing low-grade attapulgite clay |
| CN105289470A (en) * | 2015-11-18 | 2016-02-03 | 中国科学院兰州化学物理研究所 | Method for preparing charcoal-supported attapulgite nano composite by using antibiotic wastewater |
| CN107445216A (en) * | 2016-06-01 | 2017-12-08 | 张会君 | A kind of formula and preparation method for sewage disposal dephosphorization filler |
| CN106315605A (en) * | 2016-08-31 | 2017-01-11 | 中国科学院兰州化学物理研究所盱眙凹土应用技术研发中心 | Method for preparing 1.1nm tobermorite from low-grade attapulgite clay |
| KR101888829B1 (en) * | 2018-01-12 | 2018-08-16 | (주) 푸른환경산업 | Adsorption carrier using silica fume and calcium hydroxide, and method of manufacturing there of |
| CN109824055A (en) * | 2019-04-04 | 2019-05-31 | 河北工业大学 | Method for preparing nano-sheet zinc silicate composite adsorbent from iron tailings |
Non-Patent Citations (3)
| Title |
|---|
| MANUEL CONDE-CIDA ET AL: "Competitive adsorption/desorption of tetracycline, oxytetracycline and chlortetracycline on pine bark, oak ash and mussel shell", 《JOURNAL OF ENVIRONMENTAL MANAGEMENT》 * |
| MANUEL CONDE-CIDA ET AL: "Competitive adsorption/desorption of tetracycline, oxytetracycline and chlortetracycline on pine bark, oak ash and mussel shell", 《JOURNAL OF ENVIRONMENTAL MANAGEMENT》, 9 September 2019 (2019-09-09), pages 4 * |
| 戴金辉等: "《无机非金属材料概论》", 31 July 2018, 哈尔滨工业大学出版社, pages: 83 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111196617B (en) | 2022-05-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109529767A (en) | The preparation method and application method of the compound magnetic modification biological Carbon Materials of chitosan | |
| CN101690882A (en) | Natural adsorbent for removing heavy metal ions in water and preparation method and application thereof | |
| CN107459204A (en) | The processing method of aquiculture waste water | |
| CN106699443B (en) | Conditioner for promoting selenium activation in selenium-containing dry land soil | |
| CN107159167A (en) | Heavy metal absorbent prepared by a kind of utilization rice straw and preparation method thereof | |
| CN109174026A (en) | A kind of method of chromium in compound microalgae biological adsorption agent microballoon and its absorption waste water | |
| CN106278769A (en) | A kind of aquaculture nutrition slow-release agent and preparation method thereof | |
| CN111186892A (en) | Ammonia nitrogen remover containing natural mineral substances and used for surface water treatment and preparation method thereof | |
| CN106277669A (en) | A kind of ecological dredging method of resource | |
| CN110981419A (en) | A kind of phosphorus removal filler suitable for Ganzhou area and preparation method thereof | |
| CN106693878A (en) | Filler particles for improving quality of aquaculture water and purifying tail water, preparation method of filler particles, and reactor comprising filler particles | |
| CN106861616A (en) | Improver of water quality used for aquiculture and preparation method thereof | |
| CN111196617A (en) | Composite material and method for removing antibiotics in water body | |
| KR20060108281A (en) | Manufacturing method of active solution containing a large amount of mineral | |
| CN109231339A (en) | A kind of water quality cleansing agent and preparation method thereof for aquaculture | |
| CN105858777A (en) | Garlic straw-nanocopper composite blue alga treatment agent and preparation method thereof | |
| CN118343708A (en) | Preparation and application of rod-shaped nano hydroxyapatite material | |
| CN107573005A (en) | A kind of preparation method of ceramic grain filter | |
| CN107149925A (en) | Heavy metal absorbent prepared by a kind of utilization bog moss and preparation method thereof | |
| CN107282019A (en) | Heavy metal absorbent prepared by a kind of utilization cereal shell and preparation method thereof | |
| CN113044905A (en) | Substrate modifier capable of building substrate sludge microecosystem in advance and preparation method thereof | |
| CN111018135A (en) | Biological algaecide for dry-wet alternative water purification treatment | |
| CN111036170A (en) | Water purification sludge composite adsorbent and application thereof | |
| CN104472565A (en) | Kaolin composite processing agent for blue-green algae and preparation method thereof | |
| CN109395699A (en) | A method of waste water is handled using microalgae and recycles phosphorus element |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |