CN110607108A - Jasmine flower art pigment and preparation method thereof - Google Patents
Jasmine flower art pigment and preparation method thereof Download PDFInfo
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- CN110607108A CN110607108A CN201910993477.7A CN201910993477A CN110607108A CN 110607108 A CN110607108 A CN 110607108A CN 201910993477 A CN201910993477 A CN 201910993477A CN 110607108 A CN110607108 A CN 110607108A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D103/00—Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09D103/02—Starch; Degradation products thereof, e.g. dextrin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention relates to the technical field of pigment production processes, in particular to a jasmine flower art pigment and a preparation method thereof, wherein the jasmine flower art pigment comprises the following raw materials in parts by weight: 8-10 parts of jasmine flower powder; 12-16 parts of pigment powder; 5-7 parts of Arabic gum; 20-30 parts of polyacrylic acid emulsion; 0.2-0.5 part of oxgall; 3-5 parts of glycerol; 1-2 parts of potassium sorbate; 20-35 parts of cassava starch; 1-1.5 parts of maltodextrin; 0.5-1 part of chitosan; 0.5-1.5 parts of bacteriostatic agent; 30-35 parts of distilled water. The jasmine flower art pigment prepared by the method is bright in color, strong in tinting strength, resistant to high temperature and humid environment, not easy to fall off and change color when being illuminated, good in durability, not easy to embrittle and turn yellow, good in high color retention, and has a jasmine flower fragrance; the painting made by the pigment has natural color and is not easy to mildew during storage.
Description
Technical Field
The invention relates to the technical field of pigment production processes, and particularly relates to a jasmine flower art pigment and a preparation method thereof.
Background
The pigment is a powdery substance for coloring which is insoluble in a medium such as water, oil, resin or organic solvent, but can be uniformly dispersed in the medium to color the medium, and has a certain hiding power. Pigments are commonly used materials in art design and are in many kinds. Since ancient times, the source of pigments has been classified mainly into pigments of mineral origin, pigments of vegetable or animal origin and pigments of modern chemical synthesis. The colorful pigment creates colorful color world and art, and is the most precious cultural treasure up to now. The pigment is colored fine particle powdery substance, and can be divided into inorganic pigment and organic pigment from chemical composition, wherein the inorganic pigment mainly comprises metal oxide, chromate, carbonate, sulfate, sulfide and the like, and can also be divided into metal pigment, white covering pigment, coloring pigment, antirust pigment and the like, and the pigment is the pigment with the largest application amount and the widest application range in the coating industry; they can be classified into natural pigments and synthetic pigments from raw material sources.
The pigment is a commonly used art product and can be divided into traditional Chinese painting pigment, oil painting pigment and gouache pigment; the art pigment basically requires that the finer the particles, the brighter the color, and the longer the color, the better the color will not change (the better the stability). Some organic pigments and synthetic pigments contain formaldehyde, have certain toxicity, are inconvenient to use in practice, and are particularly dangerous when used by children; and the existing pigments are relatively complex in manufacturing work, so that the production efficiency of the pigments is relatively low, and the actual use requirements cannot be met. The common pigments in the current market have the defects that most of the pigments are made of chemical raw materials, the pigments are not healthy and environment-friendly enough, the colors are not natural enough, the existing painting pigments have the problems of large dry-wet color difference and unsmooth painting, and the aging problems of yellowing of a coating film and the like can occur when works are stored for a long time under the action of air, water and ultraviolet lamps; meanwhile, the problems of mildew and the like easily occur due to improper storage, the common pigment on the market does not have special smell such as fragrance, and the made picture works have visual perception and no olfactory perception.
Disclosure of Invention
The invention aims to provide a jasmine flower art pigment and a preparation method thereof, aiming at the defects of art painting pigments in the prior art. The jasmine flower art pigment prepared by the method is bright in color and strong in tinting strength, has a jasmine flower fragrance, is resistant to high temperature and humid environments, is not easy to fall off and change color when being illuminated, and has good high color retention.
In order to achieve the purpose, the invention adopts the following technical scheme:
a jasmine flower art pigment comprises the following raw materials in parts by weight:
8-10 parts of jasmine flower powder; 12-16 parts of pigment powder; 5-7 parts of Arabic gum; 20-30 parts of polyacrylic acid emulsion; 0.2-0.5 part of oxgall; 3-5 parts of glycerol; 1-2 parts of potassium sorbate; 20-35 parts of cassava starch; 1-1.5 parts of maltodextrin; 0.5-1 part of chitosan; 0.5-1.5 parts of bacteriostatic agent; 30-35 parts of distilled water.
According to the jasmine flower art pigment, the jasmine flower powder is obtained by drying fresh jasmine flowers, carrying out superfine grinding and sieving with a 800-mesh sieve. The jasmine flower powder added into the pigment can endow the pigment jasmine flower with the fragrance, and has the effect of removing peculiar smell.
In the jasmine flower art pigment, the pigment powder is natural plant pigment, and comprises one or more of indigo blue, gardenia blue, lemon yellow, curcumin, seabuckthorn yellow, alkannin, beet red, capsanthin, roselle red, plant carbon black or cherokee rose brown.
In the jasmine art pigment, the bacteriostatic agent is 2-methyl-4-isothiazoline-3-ketone.
The preparation method of the jasmine flower art pigment comprises the following steps:
(1) according to the weight parts, firstly adding the gum arabic and the maltodextrin into water, stirring and swelling for 1-1.5 hours at 70 ℃, then heating to 90 ℃, and heating for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, tapioca starch and potassium sorbate, stirring for 5-10min, sequentially adding flos Jasmini sambac powder, fel bovis Seu Bubali, bacteriostatic agent, chitosan and glycerol under stirring, mixing and stirring to obtain coarse slurry;
(3) and adding the coarse slurry into a hopper of a three-roll grinder, grinding for 3-5 times by the three-roll grinder, and cooling a roller by circulating water to obtain the jasmine flower art pigment.
The gum arabic used in the invention is a natural plant gum produced in the desert area of the south of the sahara desert in Africa, mainly comprises arabinose, galactose, glucuronic acid and the like, has wide application in food, medicine, cosmetics and other industries, is a safe and harmless thickening agent, can play a role of a binding agent, and can enable the prepared pigment to have more bright gloss and color. The polyacrylic acid emulsion is milky white viscous liquid which is easy to dissolve in water, and the solid content of the polyacrylic acid emulsion is 38-40%.
The used oxgall is a watercolor painting medium, can improve the wettability of watercolor, enhance the fluidity of watercolor, reduce the surface tension of water, prevent water from aggregating into water drops, improve the combination degree of a pigment layer and paper, and can play a role in wetting, enable the watercolor to form a halation effect and increase the coloring of watercolor paper.
The potassium sorbate used in the invention is colorless to white flaky crystal or crystalline powder and is mainly used as a food preservative, and the potassium sorbate can effectively inhibit the activity of mould, yeast and aerobic bacteria, thereby effectively prolonging the preservation time of food and keeping the flavor of the original food; the preservative is a high-efficiency and safe preservative recommended by the international food and agriculture organization and the health organization, is widely applied to the industries of food, beverage, tobacco, pesticide, cosmetics and the like, and is used as a food preservative, a fruit and vegetable preservative, a washing cosmetic, a feed preservative and the like. According to the invention, potassium sorbate is added during pigment preparation, so that the anti-corrosion performance of the pigment can be improved, and the pigment can resist a humid environment and is not easy to mildew and deteriorate.
The chitosan (chitosan) is obtained by deacetylation of chitin (chitin) widely existing in nature, and has a chemical name of polyglucosamine (1-4) -2-amino-B-D glucose, and a relative molecular mass of 2 × 105～7×105The chitosan has excellent biological properties such as broad-spectrum antibacterial property, biological functionality, biocompatibility, low toxicity, biodegradability and the like, has good antibacterial activity, and can inhibit the growth and the propagation of fungi, bacteria and viruses. The chitosan is used for preparing the pigment, so that the antibacterial property of the pigment can be improved.
The bacteriostatic agent 2-methyl-4-isothiazoline-3-ketone is a high-activity bactericide, has the minimum inhibitory concentration of less than 10mg/l for a plurality of microorganisms, has extremely strong killing and inhibiting effects on bacteria, mould, microzyme and algae, and is effective at low concentration. The product has good safety, low toxicity, biodegradability, no teratogenic and mutagenic reaction, and stability in acidic and oxidative environments; when added into the paint, the coating can prevent the putrefaction and deterioration of the paint, improve the corrosion resistance of the paint and enable a coating film to have the capability of resisting the attack of mould.
The invention has the beneficial effects that:
1. the jasmine flower art pigment and the preparation method thereof have the advantages that various raw materials are safe and environment-friendly substances, formaldehyde is not contained, and toxic and harmful gases are not generated in the using process; the prepared painting pigment has the advantages of excellent performance, good texture, no toxicity and no pollution.
2. According to the invention, the jasmine flower powder is used as the raw material to prepare the art pigment, so that the prepared pigment has light jasmine flower fragrance and plays a role in removing peculiar smell to a certain extent.
3. According to the invention, potassium sorbate, chitosan, bacteriostatic agent and other substances are added during the preparation of the pigment, so that the antibacterial and mildew-proof performance of the prepared pigment can be greatly improved, and the prepared pigment is resistant to humid environment and is not easy to breed mildew in humid environment after being used for art painting.
4. The jasmine flower art pigment prepared by the invention has bright color, strong tinting strength, high temperature and humidity resistance, is not easy to fall off and change color when being illuminated by light, has better durability, can not embrittle and turn yellow, has better high color retention, and has natural color and difficult mildew problem when being stored.
5. The prepared jasmine art pigment does not contain substances harmful to human bodies, such as toxic heavy metals or formaldehyde, is safe and environment-friendly, has stable quality, strong tinting strength and bright color, has good stability, and is convenient for drawing; meets the requirements of people on safety and painting effect, and is suitable for industrial production.
Detailed Description
Example 1
A jasmine flower art pigment comprises the following raw materials in parts by weight:
8 parts of jasmine flower powder; 12 parts of pigment powder; 5 parts of Arabic gum; 20 parts of polyacrylic acid emulsion; 0.2 part of oxgall; 3 parts of glycerol; 1 part of potassium sorbate; 20 parts of cassava starch; 1 part of maltodextrin; 0.5 part of chitosan; bacteriostatic agent 2-methyl-4-isothiazoline-3-ketone 0.5 part; 30 parts of distilled water; the jasmine flower powder is obtained by drying fresh jasmine flowers, carrying out superfine grinding and sieving with a 800-mesh sieve; the pigment powder is indigo;
the preparation method of the jasmine flower art pigment comprises the following steps:
(1) according to the weight parts, firstly adding the gum arabic and the maltodextrin into water, stirring and swelling for 1 hour at 70 ℃, then heating to 90 ℃ for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, tapioca starch and potassium sorbate, stirring for 5min, sequentially adding flos Jasmini sambac powder, fel bovis Seu Bubali, bacteriostatic agent, chitosan and glycerol under stirring, mixing and stirring to obtain coarse slurry;
(3) and adding the coarse slurry into a hopper of a three-roll grinder, grinding for 3 times by the three-roll grinder, and cooling a roller by adopting circulating water to obtain the jasmine flower art pigment.
Example 2
A jasmine flower art pigment comprises the following raw materials in parts by weight:
9 parts of jasmine flower powder; 13 parts of pigment powder; 6 parts of Arabic gum; 25 parts of polyacrylic acid emulsion; 0.3 part of oxgall; 4 parts of glycerol; 1.5 parts of potassium sorbate; 30 parts of cassava starch; 1.2 parts of maltodextrin; 0.8 part of chitosan; 1 part of bacteriostatic agent 2-methyl-4-isothiazoline-3-ketone; 33 parts of distilled water; the jasmine flower powder is obtained by drying fresh jasmine flowers, carrying out superfine grinding and sieving with a 800-mesh sieve; the pigment powder is lemon yellow, curcumin and seabuckthorn yellow;
the preparation method of the jasmine flower art pigment comprises the following steps:
(1) according to the weight parts, firstly adding the gum arabic and the maltodextrin into water, stirring and swelling for 1.2 hours at 70 ℃, then heating to 90 ℃ for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, tapioca starch and potassium sorbate, stirring for 8min, sequentially adding flos Jasmini sambac powder, fel bovis Seu Bubali, bacteriostatic agent, chitosan and glycerol under stirring, mixing and stirring to obtain coarse slurry;
(3) and adding the coarse slurry into a hopper of a three-roll grinder, grinding for 4 times by the three-roll grinder, and cooling a roller by circulating water to obtain the jasmine flower art pigment.
Example 3
A jasmine flower art pigment comprises the following raw materials in parts by weight:
10 parts of jasmine flower powder; 16 parts of pigment powder; 7 parts of Arabic gum; 30 parts of polyacrylic acid emulsion; 0.5 part of oxgall; 5 parts of glycerol; 2 parts of potassium sorbate; 35 parts of cassava starch; 1.5 parts of maltodextrin; 1 part of chitosan; 1.5 parts of bacteriostatic agent 2-methyl-4-isothiazoline-3-ketone; 35 parts of distilled water; the jasmine flower powder is obtained by drying fresh jasmine flowers, carrying out superfine grinding and sieving with a 800-mesh sieve; the pigment powder is one of indigo, gardenia blue, lemon yellow, curcumin, seabuckthorn yellow, alkannin, beet red, capsanthin, roselle red, plant carbon black or cherokee rose brown;
the preparation method of the jasmine flower art pigment comprises the following steps:
(1) according to the weight parts, firstly adding the gum arabic and the maltodextrin into water, stirring and swelling for 1.5 hours at 70 ℃, then heating to 90 ℃ for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, tapioca starch and potassium sorbate, stirring for 10min, sequentially adding flos Jasmini sambac powder, fel bovis Seu Bubali, bacteriostatic agent, chitosan and glycerol under stirring, mixing and stirring to obtain coarse slurry;
(3) and adding the coarse slurry into a hopper of a three-roll grinder, grinding for 5 times by the three-roll grinder, and cooling a roller by circulating water to obtain the jasmine flower art pigment.
Example 4
A jasmine flower art pigment comprises the following raw materials in parts by weight:
8 parts of jasmine flower powder; 14 parts of pigment powder; 5 parts of Arabic gum; 27 parts of polyacrylic acid emulsion; 0.3 part of oxgall; 5 parts of glycerol; 1.8 parts of potassium sorbate; 30 parts of cassava starch; 1.5 parts of maltodextrin; 0.8 part of chitosan; 1.2 parts of bacteriostatic agent 2-methyl-4-isothiazoline-3-ketone; 33 parts of distilled water; the jasmine flower powder is obtained by drying fresh jasmine flowers, carrying out superfine grinding and sieving with a 800-mesh sieve; the pigment powder is natural plant pigment, including one or more of indigo blue, gardenia blue, lemon yellow, curcumin, seabuckthorn yellow, alkannin, beet red, capsanthin, hibiscus sabdariffa red, plant carbon black or cherokee rose brown.
The preparation method of the jasmine flower art pigment comprises the following steps:
(1) according to the weight parts, firstly adding the gum arabic and the maltodextrin into water, stirring and swelling for 1-1.5 hours at 70 ℃, then heating to 90 ℃, and heating for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, tapioca starch and potassium sorbate, stirring for 5-10min, sequentially adding flos Jasmini sambac powder, fel bovis Seu Bubali, bacteriostatic agent, chitosan and glycerol under stirring, mixing and stirring to obtain coarse slurry;
(3) and adding the coarse slurry into a hopper of a three-roll grinder, grinding for 3 times by the three-roll grinder, and cooling a roller by adopting circulating water to obtain the jasmine flower art pigment.
Example 5
A jasmine flower art pigment comprises the following raw materials in parts by weight:
9 parts of jasmine flower powder; 13 parts of pigment powder; 5 parts of Arabic gum; 23 parts of polyacrylic acid emulsion; 0.2 part of oxgall; 4 parts of glycerol; 1.5 parts of potassium sorbate; 28 parts of cassava starch; 1.3 parts of maltodextrin; 0.7 part of chitosan; 1 part of bacteriostatic agent 2-methyl-4-isothiazoline-3-ketone; 33 parts of distilled water; the jasmine flower powder is obtained by drying fresh jasmine flowers, carrying out superfine grinding and sieving with a 800-mesh sieve; the pigment powder is natural plant pigment, including one or more of indigo blue, gardenia blue, lemon yellow, curcumin, seabuckthorn yellow, alkannin, beet red, capsanthin, hibiscus sabdariffa red, plant carbon black or cherokee rose brown.
The preparation method of the jasmine flower art pigment comprises the following steps:
(1) according to the weight parts, firstly adding the gum arabic and the maltodextrin into water, stirring and swelling for 1 hour at 70 ℃, then heating to 90 ℃ for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, tapioca starch and potassium sorbate, stirring for 5-10min, sequentially adding flos Jasmini sambac powder, fel bovis Seu Bubali, bacteriostatic agent, chitosan and glycerol under stirring, mixing and stirring to obtain coarse slurry;
(3) and adding the coarse slurry into a hopper of a three-roll grinder, grinding for 3-5 times by the three-roll grinder, and cooling a roller by circulating water to obtain the jasmine flower art pigment.
Performance testing
The jasmine art pigment prepared in example 2 of the present invention was subjected to a performance test, and the results thereof are shown in table 1 below.
As can be seen from the above table 1, the jasmine flower art pigment prepared by the method is fine and smooth, and has good light resistance and heat resistance, and good cold resistance and mildew resistance.
Claims (5)
1. The jasmine art pigment is characterized by comprising the following raw materials in parts by weight:
8-10 parts of jasmine flower powder; 12-16 parts of pigment powder; 5-7 parts of Arabic gum; 20-30 parts of polyacrylic acid emulsion; 0.2-0.5 part of oxgall; 3-5 parts of glycerol; 1-2 parts of potassium sorbate; 20-35 parts of cassava starch; 1-1.5 parts of maltodextrin; 0.5-1 part of chitosan; 0.5-1.5 parts of bacteriostatic agent; 30-35 parts of distilled water.
2. The jasmine art pigment of claim 1, wherein the jasmine powder is prepared by drying fresh jasmine, micronizing, and sieving with 800 mesh sieve.
3. The jasmine art pigment as set forth in claim 1, wherein the pigment powder is a natural plant pigment including one or more of indigo blue, gardenia blue, lemon yellow, curcumin, seabuckthorn yellow, alkannin, beet red, capsanthin, hibiscus red, plant carbon black, or cherokee rose brown.
4. The jasmine art pigment of claim 1, wherein the bacteriostatic agent is 2-methyl-4-isothiazolin-3-one.
5. The jasmine art pigment as set forth in claim 1, wherein the preparation method comprises the steps of:
(1) according to the weight parts, firstly adding the gum arabic and the maltodextrin into water, stirring and swelling for 1-1.5 hours at 70 ℃, then heating to 90 ℃, and heating for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, tapioca starch and potassium sorbate, stirring for 5-10min, sequentially adding flos Jasmini sambac powder, fel bovis Seu Bubali, bacteriostatic agent, chitosan and glycerol under stirring, mixing and stirring to obtain coarse slurry;
(3) and adding the coarse slurry into a hopper of a three-roll grinder, grinding for 3-5 times by the three-roll grinder, and cooling a roller by circulating water to obtain the jasmine flower art pigment.
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Cited By (6)
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| CN112574671A (en) * | 2020-12-29 | 2021-03-30 | 盐城工业职业技术学院 | Painting pigment and preparation method thereof |
| CN112980227A (en) * | 2021-03-22 | 2021-06-18 | 颜开 | Tea pigment, preparation method and application |
| CN114133818A (en) * | 2021-11-05 | 2022-03-04 | 临沂职业学院 | Environment-friendly odorless art painting pigment and preparation method thereof |
| CN114591642A (en) * | 2020-12-03 | 2022-06-07 | 濮阳职业技术学院 | Process for preparing environment-friendly odorless pigment for art |
| CN115725208A (en) * | 2021-08-30 | 2023-03-03 | 福建波普画材科技有限公司 | Pigment for art painting and preparation method thereof |
| CN117264457A (en) * | 2023-11-02 | 2023-12-22 | 北京首华建设经营有限公司 | Colored drawing pigment for ancient architecture repair and preparation method thereof |
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| CN112574671A (en) * | 2020-12-29 | 2021-03-30 | 盐城工业职业技术学院 | Painting pigment and preparation method thereof |
| CN112980227A (en) * | 2021-03-22 | 2021-06-18 | 颜开 | Tea pigment, preparation method and application |
| CN115725208A (en) * | 2021-08-30 | 2023-03-03 | 福建波普画材科技有限公司 | Pigment for art painting and preparation method thereof |
| CN114133818A (en) * | 2021-11-05 | 2022-03-04 | 临沂职业学院 | Environment-friendly odorless art painting pigment and preparation method thereof |
| CN114133818B (en) * | 2021-11-05 | 2022-05-03 | 临沂职业学院 | Environment-friendly odorless art painting pigment and preparation method thereof |
| CN117264457A (en) * | 2023-11-02 | 2023-12-22 | 北京首华建设经营有限公司 | Colored drawing pigment for ancient architecture repair and preparation method thereof |
| CN117264457B (en) * | 2023-11-02 | 2024-04-16 | 北京首华建设经营有限公司 | Colored drawing pigment for ancient architecture repair and preparation method thereof |
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Application publication date: 20191224 |