CN110463646A - A kind of circulating water culture system that can quickly remove residual antibiotic - Google Patents
A kind of circulating water culture system that can quickly remove residual antibiotic Download PDFInfo
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- CN110463646A CN110463646A CN201910765915.4A CN201910765915A CN110463646A CN 110463646 A CN110463646 A CN 110463646A CN 201910765915 A CN201910765915 A CN 201910765915A CN 110463646 A CN110463646 A CN 110463646A
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- antibiotic
- cultivation
- cycle subsystem
- residual antibiotic
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- 230000003115 biocidal effect Effects 0.000 title claims abstract description 92
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 71
- 238000006303 photolysis reaction Methods 0.000 claims abstract description 44
- 230000015843 photosynthesis, light reaction Effects 0.000 claims abstract description 42
- 239000003814 drug Substances 0.000 claims abstract description 41
- 238000006065 biodegradation reaction Methods 0.000 claims abstract description 38
- 229940079593 drug Drugs 0.000 claims abstract description 37
- 238000009360 aquaculture Methods 0.000 claims description 17
- 230000000694 effects Effects 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 241000894006 Bacteria Species 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 239000003463 adsorbent Substances 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000011159 matrix material Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 238000011112 process operation Methods 0.000 claims description 6
- 239000013505 freshwater Substances 0.000 claims description 5
- 238000009313 farming Methods 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 230000008901 benefit Effects 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 22
- 244000144974 aquaculture Species 0.000 description 11
- 241001465754 Metazoa Species 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 6
- 244000005700 microbiome Species 0.000 description 6
- SPFYMRJSYKOXGV-UHFFFAOYSA-N Baytril Chemical compound C1CN(CC)CCN1C(C(=C1)F)=CC2=C1C(=O)C(C(O)=O)=CN2C1CC1 SPFYMRJSYKOXGV-UHFFFAOYSA-N 0.000 description 5
- 239000004098 Tetracycline Substances 0.000 description 5
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 5
- 229960000740 enrofloxacin Drugs 0.000 description 5
- 239000005416 organic matter Substances 0.000 description 5
- 239000010802 sludge Substances 0.000 description 5
- 235000019364 tetracycline Nutrition 0.000 description 5
- 150000003522 tetracyclines Chemical class 0.000 description 5
- 238000009825 accumulation Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229960002180 tetracycline Drugs 0.000 description 4
- 229930101283 tetracycline Natural products 0.000 description 4
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 3
- 238000009395 breeding Methods 0.000 description 3
- 230000001488 breeding effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000013067 intermediate product Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000000053 physical method Methods 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- AYIRNRDRBQJXIF-NXEZZACHSA-N (-)-Florfenicol Chemical compound CS(=O)(=O)C1=CC=C([C@@H](O)[C@@H](CF)NC(=O)C(Cl)Cl)C=C1 AYIRNRDRBQJXIF-NXEZZACHSA-N 0.000 description 1
- DPSPPJIUMHPXMA-UHFFFAOYSA-N 9-fluoro-5-methyl-1-oxo-6,7-dihydro-1H,5H-pyrido[3,2,1-ij]quinoline-2-carboxylic acid Chemical compound C1CC(C)N2C=C(C(O)=O)C(=O)C3=C2C1=CC(F)=C3 DPSPPJIUMHPXMA-UHFFFAOYSA-N 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 1
- KYGZCKSPAKDVKC-UHFFFAOYSA-N Oxolinic acid Chemical compound C1=C2N(CC)C=C(C(O)=O)C(=O)C2=CC2=C1OCO2 KYGZCKSPAKDVKC-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229940126575 aminoglycoside Drugs 0.000 description 1
- 229940072174 amphenicols Drugs 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 238000011953 bioanalysis Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 229960001172 doxycycline hyclate Drugs 0.000 description 1
- HALQELOKLVRWRI-VDBOFHIQSA-N doxycycline hyclate Chemical compound O.[Cl-].[Cl-].CCO.O=C1C2=C(O)C=CC=C2[C@H](C)[C@@H]2C1=C(O)[C@]1(O)C(=O)C(C(N)=O)=C(O)[C@@H]([NH+](C)C)[C@@H]1[C@H]2O.O=C1C2=C(O)C=CC=C2[C@H](C)[C@@H]2C1=C(O)[C@]1(O)C(=O)C(C(N)=O)=C(O)[C@@H]([NH+](C)C)[C@@H]1[C@H]2O HALQELOKLVRWRI-VDBOFHIQSA-N 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 229960003760 florfenicol Drugs 0.000 description 1
- 229960000702 flumequine Drugs 0.000 description 1
- PGBHMTALBVVCIT-VCIWKGPPSA-N framycetin Chemical compound N[C@@H]1[C@@H](O)[C@H](O)[C@H](CN)O[C@@H]1O[C@H]1[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](N)C[C@@H](N)[C@@H]2O)O[C@@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CN)O2)N)O[C@@H]1CO PGBHMTALBVVCIT-VCIWKGPPSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- -1 lactic norfloxacini Chemical compound 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- OGJPXUAPXNRGGI-UHFFFAOYSA-N norfloxacin Chemical compound C1=C2N(CC)C=C(C(O)=O)C(=O)C2=CC(F)=C1N1CCNCC1 OGJPXUAPXNRGGI-UHFFFAOYSA-N 0.000 description 1
- 229960001180 norfloxacin Drugs 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 229960000321 oxolinic acid Drugs 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 238000009344 polyculture Methods 0.000 description 1
- 150000007660 quinolones Chemical class 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229960004306 sulfadiazine Drugs 0.000 description 1
- SEEPANYCNGTZFQ-UHFFFAOYSA-N sulfadiazine Chemical compound C1=CC(N)=CC=C1S(=O)(=O)NC1=NC=CC=N1 SEEPANYCNGTZFQ-UHFFFAOYSA-N 0.000 description 1
- 229960002135 sulfadimidine Drugs 0.000 description 1
- ASWVTGNCAZCNNR-UHFFFAOYSA-N sulfamethazine Chemical compound CC1=CC(C)=NC(NS(=O)(=O)C=2C=CC(N)=CC=2)=N1 ASWVTGNCAZCNNR-UHFFFAOYSA-N 0.000 description 1
- 229960005404 sulfamethoxazole Drugs 0.000 description 1
- JLKIGFTWXXRPMT-UHFFFAOYSA-N sulphamethoxazole Chemical compound O1C(C)=CC(NS(=O)(=O)C=2C=CC(N)=CC=2)=N1 JLKIGFTWXXRPMT-UHFFFAOYSA-N 0.000 description 1
- 230000026676 system process Effects 0.000 description 1
- 229940040944 tetracyclines Drugs 0.000 description 1
- 229960003053 thiamphenicol Drugs 0.000 description 1
- OTVAEFIXJLOWRX-NXEZZACHSA-N thiamphenicol Chemical compound CS(=O)(=O)C1=CC=C([C@@H](O)[C@@H](CO)NC(=O)C(Cl)Cl)C=C1 OTVAEFIXJLOWRX-NXEZZACHSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000000273 veterinary drug Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K63/00—Receptacles for live fish, e.g. aquaria; Terraria
- A01K63/003—Aquaria; Terraria
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K63/00—Receptacles for live fish, e.g. aquaria; Terraria
- A01K63/04—Arrangements for treating water specially adapted to receptacles for live fish
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K63/00—Receptacles for live fish, e.g. aquaria; Terraria
- A01K63/04—Arrangements for treating water specially adapted to receptacles for live fish
- A01K63/045—Filters for aquaria
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Marine Sciences & Fisheries (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Physical Water Treatments (AREA)
- Farming Of Fish And Shellfish (AREA)
Abstract
The present invention relates to the circulating water culture systems that one kind can quickly remove residual antibiotic, including cultivation unit (1), mechanical filter unit (2), ultraviolet photolysis unit (3), Adsorption-Biodegradation unit (4) and water treatment unit (5)；Wherein, each unit is interconnected to constitute cultivation unit antibiotic medication cycle subsystem (P1)；Residual antibiotic ultraviolet photolysis cycle subsystem (P2)；Residual antibiotic Adsorption-Biodegradation cycle subsystem (P3) and system circulation cultivation cycle subsystem (P4).Compared with prior art, circulating water culture system can be achieved to the Scientific Usage of Drugs of antibiotic in the present invention, and realizes and effectively remove to residual antibiotic, has obvious economic and environmental benefits.
Description
Technical field
It is specifically a kind of quickly to remove following for residual antibiotic the present invention relates to a kind of culture environment of aquatic products protection technique
Ring water cultivating system.
Background technique
Global culture fishery is quickly grown, and China accounts for 60% or more of global aquaculture production.Aquaculture water
Domain includes fresh water, seawater, salt water three classes, and aquaculture type includes pond culture, enclosure culture in lake, mudflat aquaculture, shallow sea
With Deep sea net cage cultivation etc., aquaculture model includes extensive style, half intensive culture formula and industrial aquaculture etc..Industrial aquaculture also known as follows
Ring water cultivating system (Recirculating Aquaculture System, abbreviation RAS), is culture fishery main development side
To integrated use advanced technology and industrialization means control the living environment of aquaculture organism, scientific management are carried out, to put
The de- Natural resources conditions such as soil and water limitation, is a kind of high-density breeding mode.
As cultivation scale and cultivation density are continuously increased, water quality deterioration, disease and the environment generated in breeding process is dirty
The problems such as dye, becomes increasingly conspicuous.The various bacteriosis of aquiculture animal are controlled using antibiosis class drug, remain logical both at home and abroad
Capable countermeasure.Currently, China allow using aquatic products veterinary drug in antibiotics have 22 kinds, be concentrated mainly on 5
Major class: aminoglycoside (neomycinsulphate), Tetracyclines (Doxycycline Hyclate), amphenicols (Thiamphenicol, Florfenicol
Deng), sulfa drugs (sulphadiazine, sulfamethoxazole, sulfadimidine, Sulfamonomethoxime Sodium etc.), quinolones
Drug (Enrofloxacin, lactic norfloxacini, niacin norfloxacin, oxolinic acid, flumequine etc.).
However, the unreasonable use of antibiotic, results in many environmental problems such as antibiotic residue, resistant gene pollution.
Cultivated animals type is more, and physiological property is different, and there are greatest differences for the effect of drug and the metabolic rule to drug；Traditional aquatic products
Cultivation takes group by medicine mostly based on Polyculture, causes precisely to be administered difficult；And breeding water body multiplicity, medication effect
It is influenced by water body environment and physicochemical property.These reasons lead to aquaculture overdose, inevitably generate antibiosis
Plain medicament residue problem destroys the microecological balance of aquiculture animal, pathogenic bacteria drug resistance and the resistant gene pollution of initiation
Problem.
Currently, the minimizing technology of antibiotic is more, including bioanalysis, physical method and oxidizing process.Current degradable antibiotic
Functional microorganism mainly have bacterium and fungi two major classes.Since concentration is lower in water environment for antibiotic, so needing to use
Many advantages, such as immobilized microorganism is handled, and wherein investment is small, granule strength is high to microbiological effect due to it is mesh
The process for fixation of preceding most study.Physical method mainly includes absorption method, Coagulation Method and membrane separation process etc., wherein absorption method
Since easy to operate, low in cost, the time-consuming advantages such as short are widely used, most common adsorbent is active carbon.Oxidizing process
It include mainly chemical oxidation, photooxidation, electrochemical oxidation, ultrasonic oxidation.Wherein, the degradation speed of photochemical oxidation method is fast,
Remineralization efficacy is good, and reaction condition is mild, does not specially require to temperature, pressure etc., treatment process is simpler, is highly suitable for difficulty
In the processing of biodegradable organic pollutant, not only the inhibition of microorganism can be made to obtain by the antibiotic after ultraviolet photolysis
Alleviate, while can effectively mention its biodegradation rate.
Circulating water culture system is the system of a closure, and system can precisely be used according to the needs science of cultivated animals
Antibiotic, but remaining antibiotic in system need quickly to be removed, otherwise will affect the water treatment unit of the circulatory system
Function bacterial activity leads to whole system water quality deterioration so that biofilter water treatment capacity declines.Also lacking at present can be fast
The effective technology method of speed removal circulating water culture system residual antibiotic.
Summary of the invention
It is an object of the invention to provide realize that circulating water culture system to the Scientific Usage of Drugs of antibiotic, and realizes to being
The one kind of residual antibiotic effectively removed can quickly remove the circulating water culture system of residual antibiotic in system.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of circulating water culture system that can quickly remove residual antibiotic, including cultivation unit, mechanical filter unit, purple
Outer photodissociation unit, Adsorption-Biodegradation unit and water treatment unit；The operation of the mechanical filter unit is through entire system
It unites the cycle of operation.
Wherein, the cultivation unit and mechanical filter unit are interconnected to constitute cultivation unit antibiotic medication circulation
System；
Ultraviolet photolysis unit, cultivation unit and the mechanical filter unit, which is sequentially connected, constitutes residual antibiotic ultraviolet light
Solve cycle subsystem；
Adsorption-Biodegradation unit, cultivation unit and the mechanical filter unit is sequentially connected composition residual antibiotic
Adsorption-Biodegradation cycle subsystem；
Water treatment unit, ultraviolet photolysis unit, cultivation unit and the mechanical filter unit is sequentially connected composition system
Cyclic culture cycle subsystem.
Further, the outlet for unit being cultivated in the cultivation unit antibiotic medication cycle subsystem connects mechanical mistake
The entrance of unit is filtered, the outlet of mechanical filter unit returns to the entrance of connection cultivation unit by first circulation pipeline, described
First circulation pipeline is equipped with the first valve；
The outlet of mechanical filter unit passes through second circulation pipe in the residual antibiotic ultraviolet photolysis cycle subsystem
Road returns to the entrance of ultraviolet photolysis unit, and the second circulation pipeline is equipped with the second valve；
The outlet of mechanical filter unit is followed by third in the residual antibiotic Adsorption-Biodegradation cycle subsystem
Endless tube road returns to the entrance of Adsorption-Biodegradation unit, and the third circulating line is equipped with third valve；
The outlet of mechanical filter unit is returned by the 4th circulating line in the system circulation cultivation cycle subsystem
The entrance of water treatment unit, the 4th circulating line are equipped with the 4th valve.
Further, the mechanical filter unit use filled with porous filter pulp matrix filter column, to cultivation sludge into
Row filtering.
Further, the size of the filter pulp matrix is 2-3cm.
Further, the Adsorption-Biodegradation unit includes being mixed by high-efficiency adsorbent and immobilization biological filler
The bed of composition.
Further, the high-efficiency adsorbent is active carbon or atlapulgite；The immobilization biological filler is
Embed bacterium particle.
Further, the water treatment unit include biofilter, denitrification device or one kind of water plant or
Multiple combinations.
Further, the cultivation unit uses freshwater aquiculture or sea-farming.
Further, the cultivation unit antibiotic medication cycle subsystem process operation time is 3-6h, generally
4h；Its application method are as follows: the antibiotic such as tetracycline or Enrofloxacin are mixed with bait, are launched into cultivation unit, cultivation is single
First antibiotic medication cycle subsystem runing time can be adjusted according to function and effect of the drug to cultivated animals；
The runing time of the residual antibiotic ultraviolet photolysis cycle subsystem is 3-6h, generally 4h, the purple
Ultraviolet wavelength is 250-265nm, power 40-80W in outer photodissociation unit；
The runing time of the residual antibiotic Adsorption-Biodegradation cycle subsystem is 3-6h, generally 4h；Pass through
Adsorbent quickly removes remaining antibiotic and its intermediate product in water removal, and gradually passes through the microorganism decomposition of biomembrane, runs
Time can be adjusted according to actual adsorption effect；
The runing time of the system circulation cultivation cycle subsystem is 10-16h, generally 12h, during cultivation
The pollutants such as the organic matter and ammonia nitrogen of generation carry out decomposition and inversion, and the accumulation of the substances such as control system nitrate nitrogen.
Further, the cycle of operation of the system is 1-3 days, generally for 24 hours, achievees the effect that only to transport after removing antibiotic
Row system circulation cultivates cycle subsystem.
Further, when cultivation unit antibiotic medication cycle subsystem starting, the first valve is opened, it is closed
His valve；
When the residual antibiotic ultraviolet photolysis cycle subsystem starts, the second valve is opened, other valves are closed；
When the residual antibiotic Adsorption-Biodegradation cycle subsystem starts, third valve is opened, other valves are closed
Door；
When the system circulation cultivation cycle subsystem starts, the 4th valve is opened, other valves are closed.
Switched between each valve using automatic control.
Compared with prior art, the invention has the following advantages that
(1) it realizes and residual antibiotic is effectively removed, and then realize circulating water culture system to the science of antibiotic
Medication；
(2) multistep removes residual antibiotic by the way of in parallel, is independent of each other between subsystems；
(3) utilize natural materials, such as embed bacterium, water plant participate in whole process, have apparent economic benefit with
Environmental benefit.
Detailed description of the invention
Fig. 1 is present system process flow chart；
Fig. 2 is process flow chart in embodiment 1；
Fig. 3 is process flow chart in embodiment 2；
Shown in figure label: cultivation unit 1, mechanical filter unit 2, ultraviolet photolysis unit 3, Adsorption-Biodegradation unit
4, water treatment unit 5, the first valve 6, the second valve 7, third valve 8, the 4th valve 9, cultivation unit antibiotic medication circulation
Subsystem P1, residual antibiotic ultraviolet photolysis cycle subsystem P2, residual antibiotic Adsorption-Biodegradation cycle subsystem P3,
System circulation cultivates cycle subsystem P4.
Specific embodiment
The present invention is described in detail with specific embodiment below in conjunction with the accompanying drawings.
Embodiment 1
It is a kind of quickly to remove the circulating water culture system of residual antibiotic, as shown in Fig. 2, including；
Cultivation unit is sea-farming, and selection antibiotic medicine is Enrofloxacin, and medication process includes sequentially connected supports
Grow unit 1 and mechanical filter unit 2；Ultraviolet photolysis includes the cultivation unit 1 for being interconnected to constitute circulation, mechanical filter unit 2
With ultraviolet photolysis unit 3；Adsorption-Biodegradation includes the cultivation unit 1 for being interconnected to constitute circulation, 2 and of mechanical filter unit
Adsorption-Biodegradation unit 4；System circulation cultivation includes the cultivation unit 1 and water treatment unit 5 for being interconnected to constitute circulation.
Water treatment unit 5 includes biofilter and denitrification device.Adsorption-Biodegradation unit 4 is active carbon and embedding bacterium composition
Bed.
The first valve 6 is equipped between the outlet of mechanical filter unit 2 and the entrance of cultivation unit 1；Mechanical filter unit 2
The second valve 7 is equipped between outlet and the entrance of ultraviolet photolysis unit 3；The outlet of mechanical filter unit 2 and water treatment unit 5
The 4th valve 9 is equipped between entrance；The is equipped between the outlet of mechanical filter unit 2 and the entrance of Adsorption-Biodegradation unit 4
Three valves 8.
Medication cycle is for 24 hours, when each process operation, to open respective valves, close other process control valves, using from
Dynamic control is switched.Mechanical filter unit, which is used, carried out cultivation sludge for the filter column of matrix by the filter pulp square of 2-3cm
Filter.Cultivation unit Enrofloxacin administration time is 4h, and application method is mixed with bait, and the ultraviolet photolysis time is 4h, ultraviolet
Lamp wavelength is 254nm, power 40W, active carbon-embedding bacterium unit, residence time 4h, by granular activated carbon and embedding bacterium particle
The bed of composition is mixed, it is 12h that system circulation, which cultivates runing time, is turned using biofilter to organic matter and ammonia nitrogen
Change, using the accumulation of denitrification unit removal system nitrate nitrogen；Medication cycle can last for days, and reach after medication effect to be
System cyclic culture mode operation.
Embodiment 2
It is a kind of quickly to remove the circulating water culture system of residual antibiotic, as shown in figure 3, including；
Cultivation unit is freshwater aquiculture, and selection antibiotic medicine is tetracycline, and medication process includes sequentially connected cultivation
Unit 1 and mechanical filter unit 2；Ultraviolet photolysis includes the cultivation unit 1 for being interconnected to constitute circulation, 2 and of mechanical filter unit
Ultraviolet photolysis unit 3；Adsorption-Biodegradation includes the cultivation unit 1 for being interconnected to constitute circulation, mechanical filter unit 2 and inhales
Attached-biodegradable unit 4；System circulation cultivation includes the cultivation unit 1 and water treatment unit 5 for being interconnected to constitute circulation.Water
Processing unit 5 includes biofilter and water plant.Adsorption-Biodegradation unit 4 is active carbon and the bed for embedding bacterium composition
Layer.
The first valve 6 is equipped between the outlet of mechanical filter unit 2 and the entrance of cultivation unit 1；Mechanical filter unit 2
The second valve 7 is equipped between outlet and the entrance of ultraviolet photolysis unit 3；The outlet of mechanical filter unit 2 and water treatment unit 5
The 4th valve 9 is equipped between entrance；The is equipped between the outlet of mechanical filter unit 2 and the entrance of Adsorption-Biodegradation unit 4
Three valves 8.
Medication cycle is for 24 hours, when each process operation, to open respective valves, close other process control valves, using from
Dynamic control is switched；Mechanical filter unit uses the filter column being made of the filter pulp square of 2-3cm to be filtered cultivation sludge；
The tetracycline administration time for cultivating unit is 4h, and application method is mixed with bait；The ultraviolet photolysis time is 4h, ultraviolet lamp wave
A length of 254nm, power 40W；Active carbon-embedding bacterium unit, residence time 4h mix granular activated carbon and embedding bacterium particle
The bed of composition；It is 12h that system circulation, which cultivates runing time, is converted, is adopted to organic matter and ammonia nitrogen using biofilter
The nutrients such as nitrogen (nitrate nitrogen), phosphorus in water are absorbed with water plant (leafy vegetable etc.)；Medication cycle can last for days, and reach
With the operation of system circulation aquaculture model after medication effect.
Embodiment 3
A kind of circulating water culture system that can quickly remove residual antibiotic, with reference to Fig. 1, including cultivation unit 1, mechanical mistake
Filter unit 2, ultraviolet photolysis unit 3, Adsorption-Biodegradation unit 4 and water treatment unit 5；The operation of mechanical filter unit 2 runs through
In the whole system cycle of operation.Mechanical filter unit 2 filled with 2-3cm porous filter pulp matrix filter column, to cultivation sludge into
Row filtering.It include active carbon and embedding bacterium particle in Adsorption-Biodegradation unit 4.Water treatment unit 5 include biofilter,
Denitrification device and water plant.It cultivates unit 1 and uses freshwater aquiculture.
Wherein, it cultivates unit 1 and mechanical filter unit 2 is interconnected to constitute cultivation unit antibiotic medication cycle subsystem
P1；The entrance of the outlet connection mechanical filter unit 2 of unit 1 is cultivated, the outlet of mechanical filter unit 2 passes through first circulation pipeline
The entrance of connection cultivation unit 1 is returned to, first circulation pipeline is equipped with the first valve 6；
Ultraviolet photolysis unit 3, cultivation unit 1 and mechanical filter unit 2, which are sequentially connected, constitutes residual antibiotic ultraviolet photolysis
Cycle subsystem P2；The entrance of mechanical filter unit 2 exported through second circulation pipeline return ultraviolet photolysis unit 3, second
Circulating line is equipped with the second valve 7；
Adsorption-Biodegradation unit 4, cultivation unit 1 and mechanical filter unit 2, which are sequentially connected, constitutes residual antibiotic suction
Attached-biodegradable cycle subsystem P3；The outlet of mechanical filter unit 2 returns to Adsorption-Biodegradation by third circulating line
The entrance of unit 4, third circulating line are equipped with third valve 8；
Water treatment unit 5, ultraviolet photolysis unit 3, cultivation unit 1 and mechanical filter unit 2 are sequentially connected composition system and follow
Ring cultivates cycle subsystem P4；The outlet of mechanical filter unit 2 returns to the entrance of water treatment unit 5 by the 4th circulating line,
4th circulating line is equipped with the 4th valve 9.
The cultivation unit antibiotic medication cycle subsystem P1 process operation time is 3h；When subsystem starts, first is opened
Valve 6 closes other valves；Its application method are as follows: tetracycline is mixed with bait, launches into cultivation unit 1, cultivates unit
Antibiotic medication cycle subsystem P1 runing time can be adjusted according to function and effect of the drug to cultivated animals；
The runing time of residual antibiotic ultraviolet photolysis cycle subsystem P2 is 3h, when subsystem starts, opens the second valve
Door 7, closes other valves；Ultraviolet wavelength is 250-265nm, power 40W in ultraviolet photolysis unit 3；
The runing time of residual antibiotic Adsorption-Biodegradation cycle subsystem P3 is 3-6h；When subsystem starts, open
Third valve 8 closes other valves；Remaining antibiotic and its intermediate product in water removal are quickly removed by adsorbent, and gradually
By the microorganism decomposition of biomembrane, runing time can be adjusted according to actual adsorption effect；
The runing time that system circulation cultivates cycle subsystem P4 is 10h, when subsystem starts, opens the 4th valve 9, closes
Close other valves；The pollutants such as the organic matter generated during cultivation and ammonia nitrogen are subjected to decomposition and inversion, and control system nitric acid
The accumulation of the substances such as salt nitrogen.
Further, the cycle of operation of the system is 1 day, achievees the effect that an operating system circulation is supported after removing antibiotic
Grow cycle subsystem P4.Switched between each valve using automatic control.
Embodiment 4
A kind of circulating water culture system that can quickly remove residual antibiotic, with reference to Fig. 1, including cultivation unit 1, mechanical mistake
Filter unit 2, ultraviolet photolysis unit 3, Adsorption-Biodegradation unit 4 and water treatment unit 5；The operation of mechanical filter unit 2 runs through
In the whole system cycle of operation.Mechanical filter unit 2 filled with 2-3cm porous filter pulp matrix filter column, to cultivation sludge into
Row filtering.It include atlapulgite and embedding bacterium particle in Adsorption-Biodegradation unit 4.Water treatment unit 5 includes biofiltration
Device, denitrification device and water plant.It cultivates unit 1 and uses sea-farming.
Wherein, it cultivates unit 1 and mechanical filter unit 2 is interconnected to constitute cultivation unit antibiotic medication cycle subsystem
P1；The entrance of the outlet connection mechanical filter unit 2 of unit 1 is cultivated, the outlet of mechanical filter unit 2 passes through first circulation pipeline
The entrance of connection cultivation unit 1 is returned to, first circulation pipeline is equipped with the first valve 6；
Ultraviolet photolysis unit 3, cultivation unit 1 and mechanical filter unit 2, which are sequentially connected, constitutes residual antibiotic ultraviolet photolysis
Cycle subsystem P2；The entrance of mechanical filter unit 2 exported through second circulation pipeline return ultraviolet photolysis unit 3, second
Circulating line is equipped with the second valve 7；
Adsorption-Biodegradation unit 4, cultivation unit 1 and mechanical filter unit 2, which are sequentially connected, constitutes residual antibiotic suction
Attached-biodegradable cycle subsystem P3；The outlet of mechanical filter unit 2 returns to Adsorption-Biodegradation by third circulating line
The entrance of unit 4, third circulating line are equipped with third valve 8；
Water treatment unit 5, ultraviolet photolysis unit 3, cultivation unit 1 and mechanical filter unit 2 are sequentially connected composition system and follow
Ring cultivates cycle subsystem P4；The outlet of mechanical filter unit 2 returns to the entrance of water treatment unit 5 by the 4th circulating line,
4th circulating line is equipped with the 4th valve 9.
The cultivation unit antibiotic medication cycle subsystem P1 process operation time is 6h；When subsystem starts, first is opened
Valve 6 closes other valves；Its application method are as follows: Enrofloxacin is mixed with bait, is launched into cultivation unit 1, cultivation is single
First antibiotic medication cycle subsystem P1 runing time can be adjusted according to function and effect of the drug to cultivated animals；
The runing time of residual antibiotic ultraviolet photolysis cycle subsystem P2 is 6h, when subsystem starts, opens the second valve
Door 7, closes other valves；Ultraviolet wavelength is 250-265nm, power 80W in ultraviolet photolysis unit 3；
The runing time of residual antibiotic Adsorption-Biodegradation cycle subsystem P3 is 6h；When subsystem starts, the is opened
Three valves 8, close other valves；Remaining antibiotic and its intermediate product in water removal are quickly removed by adsorbent, and are gradually led to
The microorganism decomposition of biomembrane is crossed, runing time can be adjusted according to actual adsorption effect；
The runing time that system circulation cultivates cycle subsystem P4 is 16h, when subsystem starts, opens the 4th valve 9, closes
Close other valves；The pollutants such as the organic matter generated during cultivation and ammonia nitrogen are subjected to decomposition and inversion, and control system nitric acid
The accumulation of the substances such as salt nitrogen.
Further, the cycle of operation of the system is 3 days, achievees the effect that an operating system circulation is supported after removing antibiotic
Grow cycle subsystem P4.Switched between each valve using automatic control.
Claims (10)
1. the circulating water culture system that one kind can quickly remove residual antibiotic, which is characterized in that including cultivating unit (1), machine
Tool filter element (2), ultraviolet photolysis unit (3), Adsorption-Biodegradation unit (4) and water treatment unit (5)；
Wherein, the cultivation unit (1) and mechanical filter unit (2) are interconnected to constitute cultivation unit antibiotic medication circulation
Subsystem (P1)；
Ultraviolet photolysis unit (3), cultivation unit (1) and the mechanical filter unit (2) is sequentially connected composition residual antibiotic
Ultraviolet photolysis cycle subsystem (P2)；
It is anti-that Adsorption-Biodegradation unit (4), cultivation unit (1) and the mechanical filter unit (2) is sequentially connected composition residual
Raw element Adsorption-Biodegradation cycle subsystem (P3)；
Water treatment unit (5), ultraviolet photolysis unit (3), cultivation unit (1) and the mechanical filter unit (2) is sequentially connected
Constitute system circulation cultivation cycle subsystem (P4).
2. the circulating water culture system that one kind according to claim 1 can quickly remove residual antibiotic, which is characterized in that
The outlet of cultivation unit (1) connects mechanical filter unit (2) in the cultivation unit antibiotic medication cycle subsystem (P1)
Entrance, the outlet of mechanical filter unit (2) returns to the entrance of connection cultivation unit (1) by first circulation pipeline, described
First circulation pipeline is equipped with the first valve (6)；
The outlet of mechanical filter unit (2) passes through second circulation in the residual antibiotic ultraviolet photolysis cycle subsystem (P2)
Pipeline returns to the entrance of ultraviolet photolysis unit (3), and the second circulation pipeline is equipped with the second valve (7)；
The outlet of mechanical filter unit (2) passes through the in the residual antibiotic Adsorption-Biodegradation cycle subsystem (P3)
Three circulating lines return to the entrance of Adsorption-Biodegradation unit (4), and the third circulating line is equipped with third valve (8)；
The outlet of mechanical filter unit (2) is returned by the 4th circulating line in system circulation cultivation cycle subsystem (P4)
The entrance of return water processing unit (5), the 4th circulating line are equipped with the 4th valve (9).
3. the circulating water culture system that one kind according to claim 1 can quickly remove residual antibiotic, which is characterized in that
The mechanical filter unit (2) is using the filter column for being filled with porous filter pulp matrix.
4. the circulating water culture system that one kind according to claim 1 can quickly remove residual antibiotic, which is characterized in that
The Adsorption-Biodegradation unit (4) includes the bed that high-efficiency adsorbent and immobilization biological filler are mixed to composition.
5. the circulating water culture system that one kind according to claim 4 can quickly remove residual antibiotic, which is characterized in that
The high-efficiency adsorbent is active carbon or atlapulgite；The immobilization biological filler is embedding bacterium particle.
6. the circulating water culture system that one kind according to claim 1 can quickly remove residual antibiotic, which is characterized in that
The water treatment unit (5) includes one or more combinations of biofilter, denitrification device or water plant.
7. the circulating water culture system that one kind according to claim 1 can quickly remove residual antibiotic, which is characterized in that
The cultivation unit (1) uses freshwater aquiculture or sea-farming.
8. the circulating water culture system that one kind according to claim 1 can quickly remove residual antibiotic, which is characterized in that
Cultivation unit antibiotic medication cycle subsystem (P1) the process operation time is 3-6h；
The runing time of the residual antibiotic ultraviolet photolysis cycle subsystem (P2) is 3-6h, the ultraviolet photolysis unit
(3) ultraviolet wavelength is 250-265nm, power 40-80W in；
The runing time of the residual antibiotic Adsorption-Biodegradation cycle subsystem (P3) is 3-6h；
The runing time of system circulation cultivation cycle subsystem (P4) is 10-16h.
9. the circulating water culture system that one kind according to claim 1 can quickly remove residual antibiotic, which is characterized in that
The cycle of operation of the system is 1-3 days, achievees the effect that an operating system cyclic culture cycle subsystem after removal antibiotic
(P4)。
10. one kind according to claim 1 can quickly remove the circulating water culture system of residual antibiotic, feature exists
In when the cultivation unit antibiotic medication cycle subsystem (P1) starts, other valves are closed in unlatching the first valve (6)；
When the residual antibiotic ultraviolet photolysis cycle subsystem (P2) starts, opens the second valve (7), close other valves
Door；
When the residual antibiotic Adsorption-Biodegradation cycle subsystem (P3) starts, opens third valve (8), close it
His valve；
When system circulation cultivation cycle subsystem (P4) starts, the 4th valve (9) is opened, other valves are closed.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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