CN110438801A - A kind of fabric functional modifying agent and preparation method thereof - Google Patents
A kind of fabric functional modifying agent and preparation method thereof Download PDFInfo
- Publication number
- CN110438801A CN110438801A CN201910728920.8A CN201910728920A CN110438801A CN 110438801 A CN110438801 A CN 110438801A CN 201910728920 A CN201910728920 A CN 201910728920A CN 110438801 A CN110438801 A CN 110438801A
- Authority
- CN
- China
- Prior art keywords
- parts
- nano
- modifying agent
- rare
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 44
- 239000002245 particle Substances 0.000 claims abstract description 38
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 31
- -1 rare-earth salts Chemical class 0.000 claims abstract description 31
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 23
- 239000004094 surface-active agent Substances 0.000 claims abstract description 21
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 17
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 17
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 17
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 17
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical class [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims abstract description 16
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 8
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 8
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 8
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 8
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 5
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical group CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 3
- KOVKEDGZABFDPF-UHFFFAOYSA-N n-(triethoxysilylmethyl)aniline Chemical compound CCO[Si](OCC)(OCC)CNC1=CC=CC=C1 KOVKEDGZABFDPF-UHFFFAOYSA-N 0.000 claims description 3
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 2
- 239000000376 reactant Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 2
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 claims 1
- 239000004753 textile Substances 0.000 abstract description 10
- 230000003115 biocidal effect Effects 0.000 abstract description 5
- 239000003607 modifier Substances 0.000 abstract description 5
- NGDQQLAVJWUYSF-UHFFFAOYSA-N 4-methyl-2-phenyl-1,3-thiazole-5-sulfonyl chloride Chemical compound S1C(S(Cl)(=O)=O)=C(C)N=C1C1=CC=CC=C1 NGDQQLAVJWUYSF-UHFFFAOYSA-N 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 4
- BEBXIKIXVLRHEM-UHFFFAOYSA-N [Na].C1=CC2=CC=CC=C2C(S(=O)(=O)O)=C1CC1=CC=C(C=CC=C2)C2=C1S(O)(=O)=O Chemical compound [Na].C1=CC2=CC=CC=C2C(S(=O)(=O)O)=C1CC1=CC=C(C=CC=C2)C2=C1S(O)(=O)=O BEBXIKIXVLRHEM-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 240000008564 Boehmeria nivea Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- VNBLTKHUCJLFSB-UHFFFAOYSA-N n-(trimethoxysilylmethyl)aniline Chemical compound CO[Si](OC)(OC)CNC1=CC=CC=C1 VNBLTKHUCJLFSB-UHFFFAOYSA-N 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- HMZHAVGFCHINNP-UHFFFAOYSA-N dioctyl benzene-1,2-dicarboxylate;sodium Chemical compound [Na].CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC HMZHAVGFCHINNP-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000002866 fluorescence resonance energy transfer Methods 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
- D06M11/65—Salts of oxyacids of nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a kind of fabric functional modifying agent and preparation method thereof, are prepared by the raw material of following parts by weight: 35-70 parts of nano-complex particle, 15-30 parts of rare-earth salts, 8-15 parts of silane coupling agent, 5-10 parts of polyethyleneglycol diglycidylether, 4-10 parts of surfactant, 6-12 parts of aerosol-OT salt, 2-7 parts of hydroxyethyl cellulose, 10-20 parts of n-hexane, 15-25 parts of water；Wherein the nano-complex particle is Ag TiO2@SiO2Nano-complex particle, the rare-earth salts are one or two kinds of combinations of cerous nitrate or yttrium nitrate.After modifying agent produced by the present invention handles fabric, there is good antibiotic property and uvioresistant performance, therefore, functional modifier produced by the present invention is with important application prospects in field of textiles.
Description
Technical field
The invention belongs to textile technology fields, and in particular to a kind of fabric functional modifying agent and preparation method thereof.
Background technique
With the continuous improvement of people's living standards, people are more and more to the functional requirement of textile, it is therefore, functional
Textile growth momentum in textile industry, which is always maintained at, to raise up.Nearly ten years, the kind, quality of China's textile fabric, class
Earth-shaking variation has occurred, large quantities of novel fabrics continue to bring out, and the quality of fabric has even tended to quality
The leading level in the world.One important trend of novel fabric production is: textile fabric is not only satisfied with feel, appearance etc.
Sensory comfort more focuses on functional exploitation.Functional textile will be expanded further to the fabric of every field, because
This also becomes the important trend of fabric functionalization development.
The exploitation of functional fabric is largely dependent upon the exploitation of textile function finishing agent and finishing technique, because
This, the research and development for further exploring functional modifier are the Main ways of functional fabric exploitation.TiO2As a kind of functional nano
Particle plays an important role in the arrangement of fabric, however in order to further increase TiO2Effect on fabric, has
Necessity is further modified it.
Summary of the invention
Above of the existing technology in order to solve the problems, such as, the purpose of the present invention is to provide a kind of fabric functional modifying agent
And preparation method thereof.
To achieve the goals above, the present invention the following technical schemes are provided:
A kind of fabric functional modifying agent, is prepared by the raw material of following parts by weight: 35-70 parts of nano-complex particle, rare-earth salts
15-30 parts, 8-15 parts of silane coupling agent, 5-10 parts of polyethyleneglycol diglycidylether, 4-10 parts of surfactant, sulfosuccinate
6-12 parts of dioctyl phthalate sodium salt, 2-7 parts of hydroxyethyl cellulose, 10-20 parts of n-hexane, 15-25 parts of water；
Wherein the nano-complex particle is Ag TiO2@SiO2Nano-complex particle, the rare-earth salts are cerous nitrate or nitre
One or two kinds of combinations of sour yttrium.
Preferably, a kind of fabric functional modifying agent of the present invention, is prepared: nanometer by the raw material of following parts by weight
45-60 parts of compound particle, 20-30 parts of rare-earth salts, 10-15 parts of silane coupling agent, 6-9 parts of polyethyleneglycol diglycidylether, table
Activating agent 5-8 parts of face, 7-10 parts of aerosol-OT salt, 3-6 parts of hydroxyethyl cellulose, 12-18 parts of n-hexane, water
18-23 parts.
Preferably, a kind of fabric functional modifying agent of the present invention, is prepared: nanometer by the raw material of following parts by weight
50 parts of compound particle, 20 parts of rare-earth salts, 12 parts of silane coupling agent, 7 parts of polyethyleneglycol diglycidylether, 7 parts of surfactant,
9 parts of aerosol-OT salt, 5 parts of hydroxyethyl cellulose, 15 parts of n-hexane, 20 parts of water.
Further, the silane coupling agent is gamma-aminopropyl-triethoxy-silane, γ-aminopropyl trimethoxy silicon
Alkane, phenylaminomethyl triethoxysilane or phenylaminomethyl trimethoxy silane.
Further, it is 5:(1-3 that the surfactant, which is mass ratio): the cetyl trimethyl bromination of (2-5)
Ammonium, sodium metnylene bis-naphthalene sulfonate and octyl phenol polyoxyethylene ether.
The preparation method of fabric functional modifying agent of the present invention, comprising the following steps:
(1) nano-complex particle is added in aqueous solution, silane coupling agent is added under stirring conditions, temperature is slowly increased to
40-60 DEG C, it is stirred to react 40-60min；
(2) rare-earth salts and surfactant are added into solution made from step (1), continues to be stirred to react 30-60min, is made
Mixture A；
(3) temperature of mixture A system is adjusted to 50-70 DEG C, sequentially adds n-hexane, polyethylene glycol under stirring conditions
Diglycidyl ether, aerosol-OT salt and hydroxyethyl cellulose continue to be stirred 1-3h, then by reactant
System is down to room temperature, obtains fabric functional modifying agent.
Further, the speed of agitator in the preparation process is 300-500r/min.
The utility model has the advantages that the modifying agent, which has used, to be received the present invention provides a kind of fabric functional modifying agent and preparation method thereof
As functional raw material, nano-complex particle is Ag@TiO for rice compound particle and rare-earth salts2@SiO2, Ag nano particle can use
The LSPR effect and fluorescence resonance energy transfer of itself are by TiO2Activation, so that the photocatalysis efficiency of composite material is significantly improved,
Rare earth element also can be to TiO simultaneously2The activation of photocatalysis performance plays an important role.It is obtained from test result, the present invention
After modifying agent obtained handles fabric, there is good anti-microbial property, while the uvioresistant performance of fabric meets GB/T
18830 standard, can be used as antiultraviolet product carry out using.It is learnt by comparative example, is not added with nano-complex particle
Fabric antibiotic property after modifying agent arranges is poor, and uvioresistant performance is not up to standard, after being not added with the modifying agent arrangement of rare-earth salts
Though fabric show preferable effect in terms of antibiotic property and uvioresistant performance, be still not achieved and add both raw materials
The performance that modifying agent handles fabric, so that it is important to illustrate that nano-complex particle and rare-earth salts play the raising of modifying agent performance
Effect.Therefore, functional modifier produced by the present invention is with important application prospects in field of textiles.
Specific embodiment
The invention will now be further described with reference to specific embodiments, but examples are merely exemplary, not to this hair
Bright range constitutes any restrictions.It will be understood by those skilled in the art that without departing from the spirit and scope of the invention
Can with the details and forms of the technical scheme of the invention are modified or replaced, but these modification and replacement each fall within it is of the invention
In protection scope.
Embodiment 1
A kind of fabric functional modifying agent, is prepared by the raw material of following parts by weight: 50 parts of nano-complex particle, rare-earth salts 20
Part, 12 parts of silane coupling agent, 7 parts of polyethyleneglycol diglycidylether, 7 parts of surfactant, aerosol-OT salt 9
Part, 5 parts of hydroxyethyl cellulose, 15 parts of n-hexane, 20 parts of water；
Wherein the nano-complex particle is Ag TiO2@SiO2Nano-complex particle, the rare-earth salts are cerous nitrate.
The silane coupling agent is gamma-aminopropyl-triethoxy-silane.
The surfactant be mass ratio be 5:2:3 cetyl trimethylammonium bromide, methylene dinaphthalene sulfonic acid
Sodium and octyl phenol polyoxyethylene ether.
The preparation method of fabric functional modifying agent of the present invention, comprising the following steps:
(1) nano-complex particle is added in aqueous solution, silane coupling agent is added under stirring conditions, temperature is slowly increased to
50 DEG C, it is stirred to react 50min；
(2) rare-earth salts and surfactant are added into solution made from step (1), continues to be stirred to react 45min, mixing is made
Object A；
(3) temperature of mixture A system is adjusted to 60 DEG C, sequentially adds n-hexane, polyethylene glycol two under stirring conditions
Glycidol ether, aerosol-OT salt and hydroxyethyl cellulose continue to be stirred 2h, then drop reaction system
To room temperature, fabric functional modifying agent is obtained.
Speed of agitator in the preparation process is 400r/min.
Embodiment 2
A kind of fabric functional modifying agent, is prepared by the raw material of following parts by weight: 35 parts of nano-complex particle, rare-earth salts 15
Part, 8 parts of silane coupling agent, 5 parts of polyethyleneglycol diglycidylether, 4 parts of surfactant, aerosol-OT salt 6
Part, 2 parts of hydroxyethyl cellulose, 10 parts of n-hexane, 15 parts of water；
Wherein the nano-complex particle is Ag TiO2@SiO2Nano-complex particle, the rare-earth salts are yttrium nitrate.
The silane coupling agent is γ-aminopropyltrimethoxysilane.
The surfactant be mass ratio be 5:1:2 cetyl trimethylammonium bromide, methylene dinaphthalene sulfonic acid
Sodium and octyl phenol polyoxyethylene ether.
The preparation method of fabric functional modifying agent of the present invention, comprising the following steps:
(1) nano-complex particle is added in aqueous solution, silane coupling agent is added under stirring conditions, temperature is slowly increased to
40 DEG C, it is stirred to react 40min；
(2) rare-earth salts and surfactant are added into solution made from step (1), continues to be stirred to react 30min, mixing is made
Object A；
(3) temperature of mixture A system is adjusted to 50 DEG C, sequentially adds n-hexane, polyethylene glycol two under stirring conditions
Glycidol ether, aerosol-OT salt and hydroxyethyl cellulose continue to be stirred 1h, then drop reaction system
To room temperature, fabric functional modifying agent is obtained.
Speed of agitator in the preparation process is 300r/min.
Embodiment 3
A kind of fabric functional modifying agent, is prepared by the raw material of following parts by weight: 40 parts of nano-complex particle, rare-earth salts 20
Part, 10 parts of silane coupling agent, 6 parts of polyethyleneglycol diglycidylether, 5 parts of surfactant, aerosol-OT salt 7
Part, 4 parts of hydroxyethyl cellulose, 13 parts of n-hexane, 18 parts of water；
Wherein the nano-complex particle is Ag TiO2@SiO2Nano-complex particle, it is 1 that the rare-earth salts, which is mass ratio:
1 cerous nitrate and yttrium nitrate.
The silane coupling agent is phenylaminomethyl triethoxysilane.
The surfactant be mass ratio be 5:1:3 cetyl trimethylammonium bromide, methylene dinaphthalene sulfonic acid
Sodium and octyl phenol polyoxyethylene ether.
The preparation method of fabric functional modifying agent of the present invention, comprising the following steps:
(1) nano-complex particle is added in aqueous solution, silane coupling agent is added under stirring conditions, temperature is slowly increased to
45 DEG C, it is stirred to react 45min；
(2) rare-earth salts and surfactant are added into solution made from step (1), continues to be stirred to react 40min, mixing is made
Object A；
(3) temperature of mixture A system is adjusted to 55 DEG C, sequentially adds n-hexane, polyethylene glycol two under stirring conditions
Glycidol ether, aerosol-OT salt and hydroxyethyl cellulose continue to be stirred 1.5h, then by reaction system
It is down to room temperature, obtains fabric functional modifying agent.
Speed of agitator in the preparation process is 350r/min.
Embodiment 4
A kind of fabric functional modifying agent, is prepared by the raw material of following parts by weight: 70 parts of nano-complex particle, rare-earth salts 30
Part, 15 parts of silane coupling agent, 10 parts of polyethyleneglycol diglycidylether, 10 parts of surfactant, aerosol-OT
12 parts of salt, 7 parts of hydroxyethyl cellulose, 20 parts of n-hexane, 25 parts of water；
Wherein the nano-complex particle is Ag TiO2@SiO2Nano-complex particle, the rare-earth salts are cerous nitrate.
The silane coupling agent is phenylaminomethyl trimethoxy silane.
The surfactant be mass ratio be 5:3:5 cetyl trimethylammonium bromide, methylene dinaphthalene sulfonic acid
Sodium and octyl phenol polyoxyethylene ether.
The preparation method of fabric functional modifying agent of the present invention, comprising the following steps:
(1) nano-complex particle is added in aqueous solution, silane coupling agent is added under stirring conditions, temperature is slowly increased to
60 DEG C, it is stirred to react 60min；
(2) rare-earth salts and surfactant are added into solution made from step (1), continues to be stirred to react 60min, mixing is made
Object A；
(3) temperature of mixture A system is adjusted to 70 DEG C, sequentially adds n-hexane, polyethylene glycol two under stirring conditions
Glycidol ether, aerosol-OT salt and hydroxyethyl cellulose continue to be stirred 3h, then drop reaction system
To room temperature, fabric functional modifying agent is obtained.
Speed of agitator in the preparation process is 500r/min.
Comparative example 1
Comparative example 1 the difference from embodiment 1 is that, be not added with nano-complex particle in comparative example 1.
Comparative example 2
Comparative example 2 the difference from embodiment 1 is that, be not added with rare-earth salts in comparative example 2.
Functional modifier made from embodiment 1-4 and comparative example 1-2 is subjected to impregnation, bath to ramie cotton fabric respectively
Than for 1:50, dipping temperature is 50 DEG C, dip time 2h, ramie cotton fabric is taken out into washing after handle and is dried.
The fabric of different modifier treatments is subjected to following performance test, test result is as shown in table 1, it is obtained from table 1,
After modifying agent produced by the present invention handles fabric, there is good anti-microbial property, while the uvioresistant performance symbol of fabric
Close GB/T 18830 standard, can be used as antiultraviolet product carry out using.It is learnt, is not added with nano combined by comparative example
Fabric antibiotic property after the modifying agent of particle arranges is poor, and uvioresistant performance is not up to standard, is not added with the modifying agent of rare-earth salts
Though the fabric after arrangement shows preferable effect in terms of antibiotic property and uvioresistant performance, embodiment 1-4 is still not achieved
The performance that modifying agent obtained handles fabric, to illustrate that nano-complex particle and rare-earth salts play the raising of modifying agent performance
To important role.
Table 1
。
Claims (7)
1. a kind of fabric functional modifying agent, which is characterized in that be prepared by the raw material of following parts by weight: nano-complex particle
35-70 parts, 15-30 parts of rare-earth salts, 8-15 parts of silane coupling agent, 5-10 parts of polyethyleneglycol diglycidylether, surfactant
4-10 parts, 6-12 parts of aerosol-OT salt, 2-7 parts of hydroxyethyl cellulose, 10-20 parts of n-hexane, 15-25 parts of water；
Wherein the nano-complex particle is Ag TiO2@SiO2Nano-complex particle, the rare-earth salts are cerous nitrate or nitre
One or two kinds of combinations of sour yttrium.
2. a kind of fabric functional modifying agent according to claim 1, which is characterized in that prepared by the raw material of following parts by weight
It forms: 45-60 parts of nano-complex particle, 20-30 parts of rare-earth salts, 10-15 parts of silane coupling agent, polyethyleneglycol diglycidylether
6-9 parts, 5-8 parts of surfactant, 7-10 parts of aerosol-OT salt, 3-6 parts of hydroxyethyl cellulose, n-hexane 12-
18 parts, 18-23 parts of water.
3. a kind of fabric functional modifying agent according to claim 1, which is characterized in that prepared by the raw material of following parts by weight
It forms: 50 parts of nano-complex particle, 20 parts of rare-earth salts, 12 parts of silane coupling agent, 7 parts of polyethyleneglycol diglycidylether, surface
7 parts of activating agent, 9 parts of aerosol-OT salt, 5 parts of hydroxyethyl cellulose, 15 parts of n-hexane, 20 parts of water.
4. a kind of fabric functional modifying agent according to claim 1, which is characterized in that the silane coupling agent is γ-
Aminopropyl triethoxysilane, γ-aminopropyltrimethoxysilane, phenylaminomethyl triethoxysilane or phenylaminomethyl three
Methoxy silane.
5. a kind of fabric functional modifying agent according to claim 1, which is characterized in that the surfactant is quality
Than cetyl trimethylammonium bromide, sodium metnylene bis-naphthalene sulfonate and the octyl phenol polyoxyethylene ether for 5:(1-3): (2-5).
6. the preparation method of the described in any item fabric functional modifying agent of claim 1-5, which is characterized in that including following step
It is rapid:
(1) nano-complex particle is added in aqueous solution, silane coupling agent is added under stirring conditions, temperature is slowly increased to
40-60 DEG C, it is stirred to react 40-60min；
(2) rare-earth salts and surfactant are added into solution made from step (1), continues to be stirred to react 30-60min, is made
Mixture A；
(3) temperature of mixture A system is adjusted to 50-70 DEG C, sequentially adds n-hexane, polyethylene glycol under stirring conditions
Diglycidyl ether, aerosol-OT salt and hydroxyethyl cellulose continue to be stirred 1-3h, then by reactant
System is down to room temperature, obtains fabric functional modifying agent.
7. preparation method according to claim 6, which is characterized in that the speed of agitator in the preparation process is 300-
500r/min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910728920.8A CN110438801A (en) | 2019-08-08 | 2019-08-08 | A kind of fabric functional modifying agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910728920.8A CN110438801A (en) | 2019-08-08 | 2019-08-08 | A kind of fabric functional modifying agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110438801A true CN110438801A (en) | 2019-11-12 |
Family
ID=68433843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910728920.8A Withdrawn CN110438801A (en) | 2019-08-08 | 2019-08-08 | A kind of fabric functional modifying agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110438801A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111778726A (en) * | 2020-08-03 | 2020-10-16 | 刘开江 | Antistatic textile |
| CN111979773A (en) * | 2020-09-07 | 2020-11-24 | 刘开江 | Antistatic fabric and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002370911A (en) * | 2001-04-09 | 2002-12-24 | Daikyo Kagaku Kk | Antimicrobially finishing agent and antimicrobially finishing method for textile product |
| CN1454481A (en) * | 2003-05-29 | 2003-11-12 | 四川大学 | Rare-earth-carrying nano titanium dioxide antibacterial agent and preparation method thereof |
| CN1784974A (en) * | 2005-11-10 | 2006-06-14 | 上海交通大学 | Composite photocatalitic germicide |
| CN101880961A (en) * | 2009-07-21 | 2010-11-10 | 上海工程技术大学 | Series modified nano titanium dioxide photo-catalyst textile finishing agent and preparation method |
| CN107469820A (en) * | 2017-09-27 | 2017-12-15 | 广州市澳米环保科技有限公司 | A kind of photocatalyst and preparation method thereof |
| CN108085963A (en) * | 2017-12-28 | 2018-05-29 | 安徽荣泽科技有限公司 | A kind of surface cladding mixes nano-titanium dioxide fabric finishing agent of cerium zinc oxide and preparation method thereof |
-
2019
- 2019-08-08 CN CN201910728920.8A patent/CN110438801A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002370911A (en) * | 2001-04-09 | 2002-12-24 | Daikyo Kagaku Kk | Antimicrobially finishing agent and antimicrobially finishing method for textile product |
| CN1454481A (en) * | 2003-05-29 | 2003-11-12 | 四川大学 | Rare-earth-carrying nano titanium dioxide antibacterial agent and preparation method thereof |
| CN1784974A (en) * | 2005-11-10 | 2006-06-14 | 上海交通大学 | Composite photocatalitic germicide |
| CN101880961A (en) * | 2009-07-21 | 2010-11-10 | 上海工程技术大学 | Series modified nano titanium dioxide photo-catalyst textile finishing agent and preparation method |
| CN107469820A (en) * | 2017-09-27 | 2017-12-15 | 广州市澳米环保科技有限公司 | A kind of photocatalyst and preparation method thereof |
| CN108085963A (en) * | 2017-12-28 | 2018-05-29 | 安徽荣泽科技有限公司 | A kind of surface cladding mixes nano-titanium dioxide fabric finishing agent of cerium zinc oxide and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111778726A (en) * | 2020-08-03 | 2020-10-16 | 刘开江 | Antistatic textile |
| CN111778726B (en) * | 2020-08-03 | 2022-09-06 | 杭州天钜科技有限公司 | Antistatic textile |
| CN111979773A (en) * | 2020-09-07 | 2020-11-24 | 刘开江 | Antistatic fabric and preparation method thereof |
| CN111979773B (en) * | 2020-09-07 | 2022-11-22 | 江苏广昊纺织科技有限公司 | Antistatic fabric and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110438801A (en) | A kind of fabric functional modifying agent and preparation method thereof | |
| CN103880020B (en) | Chirality mesoporous organic silica nanotube or core-shell type nanometer rod and preparation method thereof | |
| CN107163855A (en) | A kind of silica aerogel reflective insulation exterior wall paint and preparation method thereof | |
| CN107694522A (en) | Nano-particle containing organosilicon quaternary ammonium salt and its production and use | |
| CN104878592A (en) | Arranging method of single-faced super-hydrophobic cotton fabrics | |
| CN108729231A (en) | Coloured uvioresistant hydrophobic fabric and preparation method thereof | |
| CN112341854B (en) | Nano-modified antibacterial organosilicon waterproofing agent and preparation method thereof | |
| CN110079919A (en) | One kind containing nano-quantum point antibiotic cotton fiber fabric and preparation method thereof | |
| CN106468018A (en) | Anti- colour contamination fiber, anti-colour contamination cloth and preparation method thereof | |
| CN106884313A (en) | A kind of worsted fabric sol-gal process water-repellent finishing method | |
| CN100480339C (en) | Modified barite and preparation method thereof | |
| CN106835839A (en) | A kind of heat preservation wallpaper | |
| CN109487536A (en) | One kind quaternary ammonium salt containing epoxy silicones/(zinc oxide@carbon quantum dot) composite nano germicide and its preparation method and application | |
| CN109778528A (en) | A kind of preparation method of environment-friendlyantibiotic antibiotic textile product | |
| CN106315596A (en) | Production process of white carbon with low CTAB specific area and low heat build-up | |
| CN108707405A (en) | A method of addition modified nano oxide compound prepares wood artwork antibacterial and mouldproof abrasion resistant fire blocking coating | |
| CN108457090A (en) | A kind of flame retardant type textile fabric | |
| CN108642654A (en) | A kind of antimicrobial form textile fabric | |
| CN104233819A (en) | Organic-silicon anti-wrinkle and easy-care finishing agent with low-temperature self-crosslinking property, preparation and application thereof | |
| CN109403070B (en) | Preparation method of radiation-proof heat-preservation composite fabric based on double-sided heterochromatic digital printing | |
| CN105563590A (en) | Enhancing pretreating agent for anion healthcare effect of wicker for wickerwork and preparing method of enhancing pretreating agent | |
| CN105145568A (en) | Preparation method of reproducible SiO2/PAM core-shell composite nano antibacterial particles | |
| CN108560256A (en) | A kind of textile fabric fire retardant and preparation method thereof | |
| CN103643516A (en) | Preparation method of glass fiber wall cloth coating | |
| CN110158304A (en) | A kind of fabric nano functional finishing agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20191112 |