CN110358243A - A kind of soft elastic force glue material, preparation method and application resistant to high temperature - Google Patents
A kind of soft elastic force glue material, preparation method and application resistant to high temperature Download PDFInfo
- Publication number
- CN110358243A CN110358243A CN201910636182.4A CN201910636182A CN110358243A CN 110358243 A CN110358243 A CN 110358243A CN 201910636182 A CN201910636182 A CN 201910636182A CN 110358243 A CN110358243 A CN 110358243A
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- China
- Prior art keywords
- parts
- elastic force
- glue material
- force glue
- high temperature
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Classifications
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/14—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined made of sponge, rubber, or plastic materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of soft elastic force glue material, preparation method and application resistant to high temperature, elastic force glue material includes the component of following parts by weight: 40-47.5 parts of SEBS；22.5-30 parts of white oil；10 parts of talcum powder；19.5 parts of silica gel；0.5 part of antioxidant.Elastic force glue material provided by the invention, hardness is 5 degree of -20 degree, compared to the hardness such as conventional use of insole material such as EVA or PU are lower now on the market, it is comfortable and easy to wear, by adjusting the parts by weight of SEBS and white oil, it can get the different elastic force glue material of hardness, meet the insole demand of different weight crowd.The present invention utilizes SEBS and the good combination of white oil, makes the elastic force glue material high temperature resistant obtained, does not deform within 200 DEG C, have a good application prospect in insole field.
Description
Technical field
The present invention relates to elastic material field more particularly to a kind of soft elastic force glue materials resistant to high temperature, its preparation side
Method and application.
Background technique
Existing insole is generally EVA shoe pad (ethene-vinyl acetate copolymer insole) on the market, (foaming is poly- for PU insole
Urethane insole) or TPE insole (hydrogenated styrene insole), but this kind of material hardness is generally spent at 30 degree -40, hardness is higher to be led
Cause dress uncomfortable, and non-refractory.
Summary of the invention
The purpose of the present invention is to provide a kind of soft elastic force glue material, preparation method and applications resistant to high temperature, come
Solve the problems, such as that existing insole is with high hardness.
To achieve this purpose, the present invention adopts the following technical scheme:
A kind of soft elastic force glue material resistant to high temperature, the component including following parts by weight:
40-47.5 parts of SEBS；
22.5-30 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
Optionally, the hardness of the elastic force glue material is 5 degree of -20 degree, is not deformed within 200 DEG C.
Optionally, the antioxidant includes BASF antioxidant 1076 and BASF irgasfos 168；The BASF antioxygen
The parts by weight of agent 1076 are 0.3 part, and the parts by weight of the BASF irgasfos 168 are 0.2 part.
Optionally, the elastic force glue material includes the component of following parts by weight:
40 parts of SEBS；
30 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
Optionally, the elastic force glue material includes the component of following parts by weight:
42.5 parts of SEBS；
27.5 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
Optionally, the elastic force glue material includes the component of following parts by weight:
45 parts of SEBS；
25 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
Optionally, the elastic force glue material includes the component of following parts by weight:
47.5 parts of SEBS；
22.5 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
A kind of preparation method of soft elastic force glue material resistant to high temperature, comprising the following steps:
According to the component preparation raw material of following parts by weight: 40-47.5 parts of SEBS；22.5-30 parts of white oil；Talcum powder 10
Part；19.5 parts of silica gel；0.5 part of antioxidant；Mix raw material raw material stirring 120min；
Heating plasticizing 2min in screw machine is added in mixed raw material, is squeezed out from screw machine obtain elastic force glue material later
Material.
Optionally, the screw machine is divided into 12 sections, and each section of technological parameter is as follows: one section: 120-160 DEG C, two sections:
140-180 DEG C, three sections: 146-200 DEG C, four sections-six sections: 180-220 DEG C, seven sections: 190-230 DEG C, eight sections: 130-170 DEG C, nine
Section: 80-120 DEG C, ten section-ten two sections: 90-130 DEG C.
Elastic force glue material made from elastic force glue material as described above or preparation method as described above, as answering for insole
With.
Compared with prior art, the invention has the following advantages:
Elastic force glue material provided by the invention, hardness are 5 degree of -20 degree, compared to present conventional use of insole on the market
The hardness such as material such as EVA or PU are lower, comfortable and easy to wear, and by adjusting the parts by weight of SEBS and white oil, it is different to can get hardness
Elastic force glue material, meet the insole demand of different weight crowd.The present invention utilizes SEBS and the good combination of white oil, makes to obtain
Elastic force glue material high temperature resistant, do not deform within 200 DEG C, have a good application prospect in insole field.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Existing insole is generally EVA shoe pad (ethene-vinyl acetate copolymer insole) on the market, (foaming is poly- for PU insole
Urethane insole) or TPE insole (hydrogenated styrene insole), but this kind of material hardness is generally spent at 30 degree -40, hardness is higher to be led
It is not particularly comfortable for causing to wear, and non-refractory.
The present invention provides a kind of soft elastic force glue material resistant to high temperature, the component including following parts by weight:
40-47.5 parts of SEBS；
22.5-30 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
Elastic force glue material provided by the invention, hardness are 5 degree of -20 degree, compared to present conventional use of insole on the market
The hardness such as material such as EVA or PU are lower, comfortable and easy to wear, and high temperature resistant, do not deform within 200 DEG C, therefore in insole
Field has a good application prospect.
In an embodiment of the present invention, it is preferable to use BASF antioxidant 1076s and BASF antioxidant for the antioxidant
168 compoundings, the formula of compounding are 0.3 part of BASF antioxidant 1076,0.2 part of BASF irgasfos 168.By using compounding
Antioxidant, so that elastic force glue material is had the function of anti-yellowing, ultraviolet light and anti-aging.
Ratio of the present invention by adjusting white oil, the hardness of adjustable elastic force glue material, to adapt to the people of different weight
Group, the hardness for increasing the mass fraction of white oil then elastic force glue material reduce, and reduce the mass fraction of white oil then elastic force glue material
Hardness increases.When adjusting white oil ratio, the ratio of SEBS needs correspondingly to be changed, and increases n parts of white oils and then needs to reduce n
Part SEBS.
SEBS (hydrogenated styrene-butadiene block copolymer) in the present invention is using polystyrene as end segment, with poly-
The ethylene-butene copolymer that butadiene hydrogenation obtains is the linear tri-block copolymer of intermediate elastic block.In SEBS, to rubber segments
Unsaturated key carries out hydrotreating, and SEBS is without unsaturated double-bond after adding hydrogen, therefore, white oil can preferably with the rubber of SEBS
Section combines, and is not in free oil, therefore, elastic force glue material high temperature resistant provided by the invention, 200 DEG C or less (containing 200 DEG C)
Keep stable form.Silica gel has filling effect in the present invention.
The present invention also provides a kind of preparation methods of soft elastic force glue material resistant to high temperature, comprising the following steps:
According to the component preparation raw material of following parts by weight: 40-47.5 parts of SEBS；22.5-30 parts of white oil；Talcum powder 10
Part；19.5 parts of silica gel；0.5 part of antioxidant；Mix raw material raw material stirring 120min；
Heating plasticizing 2min in screw machine is added in mixed raw material, is squeezed out from screw machine obtain elastic force glue material later
Material.
Wherein, selection of antioxidant etc. is as previously mentioned, details are not described herein.
In the preparation method of soft elastic force glue material resistant to high temperature provided by the invention, screw machine is divided into 12 sections, respectively
The technological parameter of section is as follows: one section: 120-160 DEG C, two sections: 140-180 DEG C, three sections: 146-200 DEG C, four section-six sections: 180-
220 DEG C, seven sections: 190-230 DEG C, eight sections: 130-170 DEG C, nine sections: 80-120 DEG C, ten section-ten two sections: 90-130 DEG C.
Preferably, each section of technological parameter of screw machine is as follows: one section: 140 DEG C, two sections: 160 DEG C, and three sections: 170 DEG C, four
- six sections: 200 DEG C, seven sections: 210 DEG C, eight sections: 150 DEG C, nine sections: 100 DEG C, ten section-ten two sections: 110 DEG C of section.
The present invention from screw machine extrusion obtain elastic force glue material after, elastic force glue material can also be handled:
Pelletizing is carried out after the cooling 30s of the elastic force glue material squeezed out from screw machine, 30s is dehydrated by centrifuge later；
Dewatered elastic force glue material is subjected to air-cooled, wind speed 3.5m/s, time 4min；Sorting and storing later；
Elastic force glue material after storing heats the 20min that dries by stirring, and is packed later.
It, can further protective packing by crossing that stirring heating dries since elastic force glue material can generate micro hydropower after storing
Elastic force glue material is in drying regime.
The preparation method of soft elastic force glue material resistant to high temperature provided by the invention, preparation process is simple, application prospect
Extensively.
For a further understanding of the application, below with reference to embodiment to a kind of soft bullet resistant to high temperature provided by the present application
Power glue material is specifically described.
In following embodiment, related antioxidant is that BASF antioxidant 1076 and BASF irgasfos 168 compound,
The formula of compounding is 0.3 part of BASF antioxidant 1076,0.2 part of BASF irgasfos 168.
Following embodiment is all made of above-mentioned preparation method preparation, only changes the mass fraction of raw material components.Implement below
The hardness test standard that example uses is GB/T6031-2017 or ISO048:2010.
Embodiment 1
The elastic force glue material that the present embodiment 1 provides includes the component of following parts by weight:
40 parts of SEBS；
30 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
The hardness of the elastic force glue material of the present embodiment 1 is 5 degree.
Embodiment 2
The elastic force glue material that the present embodiment 2 provides includes the component of following parts by weight:
42.5 parts of SEBS；
27.5 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
The hardness of the elastic force glue material of the present embodiment 2 is 10 degree.
Embodiment 3
The elastic force glue material that the present embodiment 3 provides includes the component of following parts by weight:
45 parts of SEBS；
25 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
The hardness of the elastic force glue material of the present embodiment 3 is 15 degree.
Embodiment 4
The elastic force glue material that the present embodiment 4 supplies includes the component of following parts by weight:
47.5 parts of SEBS；
22.5 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
The hardness of the elastic force glue material of the present embodiment 4 is 20 degree.
As seen from the above embodiment, elastic force glue material provided by the invention makes material using SEBS and the good combination of white oil
Expect high temperature resistant.By adjusting the parts by weight of SEBS and white oil, it can get the different elastic force glue material of hardness, meet different weight
The insole demand of crowd is with a wide range of applications in insole field.
The above, the above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although referring to before
Stating embodiment, invention is explained in detail, those skilled in the art should understand that: it still can be to preceding
Technical solution documented by each embodiment is stated to modify or equivalent replacement of some of the technical features；And these
It modifies or replaces, the spirit and scope for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution.
Claims (10)
1. a kind of soft elastic force glue material resistant to high temperature, which is characterized in that the component including following parts by weight:
40-47.5 parts of SEBS；
22.5-30 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
2. a kind of soft elastic force glue material resistant to high temperature according to claim 1, which is characterized in that the elastic force glue material
The hardness of material is 5 degree of -20 degree, is not deformed within 200 DEG C.
3. a kind of soft elastic force glue material resistant to high temperature according to claim 1, which is characterized in that the antioxidant packages
Include BASF antioxidant 1076 and BASF irgasfos 168；The parts by weight of the BASF antioxidant 1076 are 0.3 part, institute
The parts by weight for stating BASF irgasfos 168 are 0.2 part.
4. a kind of soft elastic force glue material resistant to high temperature according to claim 1, which is characterized in that the elastic force glue material
Material includes the component of following parts by weight:
40 parts of SEBS；
30 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
5. a kind of soft elastic force glue material resistant to high temperature according to claim 1, which is characterized in that the elastic force glue material
Material includes the component of following parts by weight:
42.5 parts of SEBS；
27.5 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
6. a kind of soft elastic force glue material resistant to high temperature according to claim 1, which is characterized in that the elastic force glue material
Material includes the component of following parts by weight:
45 parts of SEBS；
25 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
7. a kind of soft elastic force glue material resistant to high temperature according to claim 1, which is characterized in that the elastic force glue material
Material includes the component of following parts by weight:
47.5 parts of SEBS；
22.5 parts of white oil；
10 parts of talcum powder；
19.5 parts of silica gel；
0.5 part of antioxidant.
8. a kind of preparation method of soft elastic force glue material resistant to high temperature, which comprises the following steps:
According to the component preparation raw material of following parts by weight: 40-47.5 parts of SEBS；22.5-30 parts of white oil；10 parts of talcum powder；Silicon
19.5 parts of glue；0.5 part of antioxidant；Mix raw material raw material stirring 120min；
Heating plasticizing 2min in screw machine is added in mixed raw material, is squeezed out from screw machine obtain elastic force glue material later.
9. a kind of preparation method of soft elastic force glue material resistant to high temperature according to claim 8, which is characterized in that institute
It states screw machine and is divided into 12 sections, each section of technological parameter is as follows: one section: 120-160 DEG C, two sections: 140-180 DEG C, three sections: 146-
200 DEG C, four sections-six sections: 180-220 DEG C, seven sections: 190-230 DEG C, eight sections: 130-170 DEG C, nine sections: 80-120 DEG C, ten section-ten
Two sections: 90-130 DEG C.
10. any claim in the elastic force glue material or claim 8-9 as described in any claim in claim 1-7
Elastic force glue material made from the preparation method, the application as insole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910636182.4A CN110358243A (en) | 2019-07-15 | 2019-07-15 | A kind of soft elastic force glue material, preparation method and application resistant to high temperature |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910636182.4A CN110358243A (en) | 2019-07-15 | 2019-07-15 | A kind of soft elastic force glue material, preparation method and application resistant to high temperature |
Publications (1)
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|---|---|
| CN110358243A true CN110358243A (en) | 2019-10-22 |
Family
ID=68219183
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| CN201910636182.4A Pending CN110358243A (en) | 2019-07-15 | 2019-07-15 | A kind of soft elastic force glue material, preparation method and application resistant to high temperature |
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|---|---|---|---|---|
| CN1555395A (en) * | 2001-09-18 | 2004-12-15 | Jsr��ʽ���� | Thermoplastic elastomer composition and process for producing the same |
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| CN103192573A (en) * | 2013-03-16 | 2013-07-10 | 上虞舜美高分子材料有限公司 | Manufacture method of TPR (thermoplastic rubber) soft rubber insole |
| CN109627768A (en) * | 2018-11-30 | 2019-04-16 | 广东省石油与精细化工研究院 | A kind of thermoplastic dynamic vulcanized silicon rubber of high-flexibility and preparation method thereof |
-
2019
- 2019-07-15 CN CN201910636182.4A patent/CN110358243A/en active Pending
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|---|---|---|---|---|
| CN1555395A (en) * | 2001-09-18 | 2004-12-15 | Jsr��ʽ���� | Thermoplastic elastomer composition and process for producing the same |
| CN1884367A (en) * | 2006-06-04 | 2006-12-27 | 浙江三博聚合物有限公司 | Expansion type low-smoke halogen-free thermoplastic flame-retardant rubber and its production method |
| CN101492563A (en) * | 2009-02-18 | 2009-07-29 | 晋江市蓝牙高分子科技开发有限公司 | Rubber plastic material for producing shoe pad, shoe pad and manufacturing method thereof |
| CN103192573A (en) * | 2013-03-16 | 2013-07-10 | 上虞舜美高分子材料有限公司 | Manufacture method of TPR (thermoplastic rubber) soft rubber insole |
| CN109627768A (en) * | 2018-11-30 | 2019-04-16 | 广东省石油与精细化工研究院 | A kind of thermoplastic dynamic vulcanized silicon rubber of high-flexibility and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 佚名: "白油SEBS对性能的影响，https://www.doc88.com/p-5126498459021.html", 《道客巴巴》 * |
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Application publication date: 20191022 |