CN110218480A - A kind of environment-friendly solvent-free UV, EB curing glass function ink and preparation method - Google Patents
A kind of environment-friendly solvent-free UV, EB curing glass function ink and preparation method Download PDFInfo
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- CN110218480A CN110218480A CN201910611653.6A CN201910611653A CN110218480A CN 110218480 A CN110218480 A CN 110218480A CN 201910611653 A CN201910611653 A CN 201910611653A CN 110218480 A CN110218480 A CN 110218480A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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Abstract
The present invention relates to ultraviolet curing glass function ink fields, specifically a kind of environment-friendly solvent-free UV, EB curing glass function ink, is made of: the organic wax 0.5%-3% of organic-inorganic hybrid prepolymer 20%-60%, modified resin 10%-20%, activated monomer 5%-30%, pigment toner 5%-40%, macromolecule, modified manometer silicon dioxide 5%-15%, modified Nano mica sheet 1%-3%, dispersing agent and auxiliary agent 3%-25%, photoinitiator 5%-10%, organic siliconresin 1%-3% the raw material below according to mass percent.Also disclose a kind of preparation method of environment-friendly solvent-free UV, EB curing glass function ink.The present invention can realize adherence, and be free of organic solvent using the environmental protection ink of ultraviolet light fast solidification on the glass material of the overwhelming majority, affine to environment.
Description
Technical field
The present invention relates to ultraviolet curing glass function ink field, specifically a kind of environment-friendly solvent-free UV, EB curing glass
Function ink and preparation method.
Background technique
Glass product is component part important in national economy production activity, very big for the demand of coating.Because of glass
The physical property of material itself causes to be difficult to coating, adherence is traditionally realized using high temperature baking vanish, but energy consumption is high, time-consuming for high temperature baking vanish
It is long, and contain a large amount of volatile organic solvents in component, seriously pollute environment.
Part manufacturer attempts to release photocurable glass attachment product, but because of the limitation of technology, still contains in system
A large amount of solvent, and the pure adhesion after curing of coating it is bad, intolerant to bubble, covering power is weak, weatherability is poor the defects of.Therefore it limits
Photocuring product has been made in the popularization and application of glass substrate product.
Therefore, for the above status, there is an urgent need to develop a kind of environment-friendly solvent-free UV, EB curing glass function ink and preparations
Method, to overcome the shortcomings of in currently practical application.
Summary of the invention
The embodiment of the present invention is designed to provide a kind of environment-friendly solvent-free UV, EB curing glass function ink and preparation side
Method, to solve the problems mentioned in the above background technology.
To achieve the above object, the embodiment of the present invention provides the following technical solutions:
A kind of environment-friendly solvent-free UV, EB curing glass function ink, is made of: organic the raw material below according to mass percent
Inorganic hybridization prepolymer 20%-60%, modified resin 10%-20%, activated monomer 5%-30%, pigment toner 5%-40%,
The organic wax 0.5%-3% of macromolecule, modified manometer silicon dioxide 5%-15%, modified Nano mica sheet 1%-3%, dispersing agent and
Auxiliary agent 3%-25%, photoinitiator 5%-10%, organic siliconresin 1%-3%.
As a further solution of the present invention: the organic-inorganic hybrid prepolymer is at least to contain 0.5mmol/g-
The nano-inorganic substance component of 10mmol/g, and the acrylate content in organic-inorganic hybrid prepolymer is 0.5mmol/g-
5mmol/g。
As a further solution of the present invention: the modified resin is urethane acrylate, epoxy acrylate, gathers
The mixing of one or more of ester acrylate, acrylate.
As a further solution of the present invention: the activated monomer is second lactone acrylate, ring trihydroxy methyl ring second
Base acrylate, cobasis acrylate, tetrahydrofuran acrylate, isobornyl acrylate, 1,6- glycol diacrylate,
Ethoxylated neopentylglycol diacrylate, three (2- ethoxy) isocyanuric acids, diacrylate, Tricyclodecane Dimethanol dipropyl
Olefin(e) acid ester, three (2- ethoxy) isocyanuric acid triacrylates, double pentaerythritol methacrylate, 4- hydroxy butyl vinyl ether,
The mixing of one or more of triethyleneglycol divinylether.
As a further solution of the present invention: the photoinitiator is benzophenone, bis- (2,4, the 6- trimethylbenzenes of phenyl
Formic acid acyl group) phosphine oxide, 2- isopropyl thioxanthone, diethyl thioxanthone, 2- chlorothiaxanthenone, 1- hydroxy-cyclohexyl benzene first
Ketone, 2- methyl-1-(2- methyl mercapto phenyl)-2- morpholine-1- acetone, 2- benzyl-2- dimethylamino-1- (2- morphine phenyl)-1 fourth
The mixing of one or more of ketone.
As a further solution of the present invention: the organic wax of the macromolecule is polytetrafluoroethylwax wax, polyethylene wax, polyamides
One or both of amine wax, microwax.
As a further solution of the present invention: the dispersing agent and auxiliary agent is by dispersing agent, defoaming agent, levelling agent, filler
Formed with flatting silica, and dispersing agent, defoaming agent, levelling agent, filler and flatting silica weight proportion be 1-100:1-5:1-5:30-
100:30-350.
As a further solution of the present invention: the dispersing agent be BASF TO-5, BASF TO-7, BYK-161,
The mixing of one or more of BYK-183；The defoaming agent is BYK-1798, BYK-1799, BYK-1788, BYK-
1790, the mixing of one or more of BYK-1794, BYK-088, BYK-1752, BYK-1791；The levelling agent
For one in BYK-307, BYK-3760, BYK-361N, BYK-3455, BYK-3535, Digao 450, Digao 2100, Digao 410
Kind or two or more mixing；The filler is the mixing of one or more of talcum powder, silicon-carbon stone, barium sulfate；
The flatting silica is one or both of E-1011, OK500.
As a further solution of the present invention: the pigment toner is rutile type titanium white, carbon black, phthalocyanine blue face
The mixing of one or more of material, ultramarine pigment.
A kind of preparation method of environment-friendly solvent-free UV, EB curing glass function ink, comprising the following steps:
1) organic-inorganic hybrid prepolymer, modified resin, activated monomer, pigment toner, the organic wax of macromolecule, modification are received
Rice silica, modified Nano mica sheet, photoinitiator and organic siliconresin are put in proportion into dispersion bucket, use high speed disperser
Disperse 1-2h under the revolving speed of 1000-3000rpm, is uniformly mixed raw material；
2) in the scattered intermediate products investment grinding machine obtained step 1), being ground to partial size is 3-10 μm, is packed into
Turnover barrel is stand-by；
3) it in the ground intermediate products investment high speed disperser for obtaining step 2), is disposably put in proportion into afterwards point
Powder and auxiliary agent, after dispersing 1-2h under the revolving speed of 800-1200rpm with high speed disperser, pressure filtration obtains environmental protection without molten
Agent UV, EB curing glass function ink.
Compared with prior art, the beneficial effect of the embodiment of the present invention is:
Environment-friendly solvent-free UV, EB curing glass function ink proposed by the present invention, can utilize ultraviolet light fast solidification
Environmentally friendly ink can realize adherence on the glass material of the overwhelming majority, and be free of organic solvent, affine to environment.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment 1
A kind of environment-friendly solvent-free UV, EB curing glass function ink, is made of: organic the raw material below according to mass percent
The organic wax 0.5% of inorganic hybridization prepolymer 20%, modified resin 10%, activated monomer 5%, pigment toner 40%, macromolecule changes
Property nano silica 5%, modified Nano mica sheet 1%, dispersing agent and auxiliary agent 12.5%, photoinitiator 5%, organic siliconresin
1%.
Wherein, the organic-inorganic hybrid prepolymer is at least nano-inorganic substance component containing 0.5mmol/g, and is had
Acrylate content in machine inorganic hybridization prepolymer is 0.5mmol/g；
The modified resin is urethane acrylate；
The activated monomer is second lactone acrylate；
The photoinitiator is benzophenone；
The organic wax of the macromolecule is polytetrafluoroethylwax wax；
The dispersing agent and auxiliary agent is made of dispersing agent, defoaming agent, levelling agent, filler and flatting silica, and dispersing agent, is disappeared
Infusion, levelling agent, filler and flatting silica weight proportion be 1:1:1:30:30；
The dispersing agent is BASF TO-5；The defoaming agent is BYK-1798；The levelling agent is BYK-
307；The filler is talcum powder；The flatting silica is E-1011；
The pigment toner is rutile type titanium white.
A kind of preparation method of environment-friendly solvent-free UV, EB curing glass function ink, comprising the following steps:
1) organic-inorganic hybrid prepolymer, modified resin, activated monomer, pigment toner, the organic wax of macromolecule, modification are received
Rice silica, modified Nano mica sheet, photoinitiator and organic siliconresin are put in proportion into dispersion bucket, use high speed disperser
Disperse 1h under the revolving speed of 1000rpm, is uniformly mixed raw material；
2) in the scattered intermediate products investment grinding machine obtained step 1), being ground to partial size is 3 μm, is packed into turnover
Bucket is stand-by；
3) it in the ground intermediate products investment high speed disperser for obtaining step 2), is disposably put in proportion into afterwards point
Powder and auxiliary agent, after dispersing 1h under the revolving speed of 800rpm with high speed disperser, pressure filtration obtains environment-friendly solvent-free UV, EB
Curing glass function ink.
Embodiment 2
A kind of environment-friendly solvent-free UV, EB curing glass function ink, is made of: organic the raw material below according to mass percent
The organic wax 0.5% of inorganic hybridization prepolymer 60%, modified resin 10%, activated monomer 5%, pigment toner 5%, macromolecule changes
Property nano silica 5%, modified Nano mica sheet 1%, dispersing agent and auxiliary agent 3%, photoinitiator 7.5%, organic siliconresin
3%.
Wherein, the organic-inorganic hybrid prepolymer is at least nano-inorganic substance component containing 10mmol/g, and is had
Acrylate content in machine inorganic hybridization prepolymer is 5mmol/g；
The modified resin is the mixing of epoxy acrylate, polyester acrylate, acrylate；
The activated monomer is ring trihydroxy methyl ring ethyl propylene acid esters, cobasis acrylate, tetrahydrofuran acrylic acid
Ester, isobornyl acrylate, 1,6- glycol diacrylate, ethoxylated neopentylglycol diacrylate, three (2- hydroxyl second
Base) isocyanuric acid, diacrylate, Tricyclodecane Dimethanol diacrylate, three (2- ethoxy) isocyanuric acids, three acrylic acid
The mixing of ester, double pentaerythritol methacrylate, 4- hydroxy butyl vinyl ether, triethyleneglycol divinylether；
The photoinitiator is bis- (2,4, the 6- trimethylbenzoic acid acyl group) phosphine oxides of phenyl, 2- isopropyl thioxanthone anthracene
Ketone, diethyl thioxanthone, 2- chlorothiaxanthenone, 1- hydroxycyclohexyl phenylketone, 2- methyl-1-(2- methyl mercapto phenyl)-2-
The mixing of morpholine -1- acetone, 2- benzyl -2- dimethylamino -1- (2- morphine phenyl) -1 butanone；
The organic wax of the macromolecule is the mixing of polyethylene wax, polyamide wax；
The dispersing agent and auxiliary agent is made of dispersing agent, defoaming agent, levelling agent, filler and flatting silica, and dispersing agent, is disappeared
Infusion, levelling agent, filler and flatting silica weight proportion be 100:5:5:100:350；
The dispersing agent is the mixing of BASF TO-7, BYK-161, BYK-183；The defoaming agent is BYK-
1799, the mixing of BYK-1788, BYK-1790, BYK-1794, BYK-088, BYK-1752, BYK-1791；The levelling agent
For the mixing of BYK-3760, BYK-361N, BYK-3455, BYK-3535, Digao 450, Digao 2100, Digao 410；Described fills out
Material is the mixing of silicon-carbon stone, barium sulfate；The flatting silica is the mixing of E-1011, OK500；
The pigment toner is the mixing of carbon black, phthalocyanine blue pigment, ultramarine pigment.
A kind of preparation method of environment-friendly solvent-free UV, EB curing glass function ink, comprising the following steps:
1) organic-inorganic hybrid prepolymer, modified resin, activated monomer, pigment toner, the organic wax of macromolecule, modification are received
Rice silica, modified Nano mica sheet, photoinitiator and organic siliconresin are put in proportion into dispersion bucket, use high speed disperser
Disperse 2h under the revolving speed of 3000rpm, is uniformly mixed raw material；
2) in the scattered intermediate products investment grinding machine obtained step 1), being ground to partial size is 10 μm, is packed into week
Turning barrel is stand-by；
3) it in the ground intermediate products investment high speed disperser for obtaining step 2), is disposably put in proportion into afterwards point
Powder and auxiliary agent, after dispersing 2h under the revolving speed of 1200rpm with high speed disperser, pressure filtration obtains environment-friendly solvent-free UV, EB
Curing glass function ink.
Embodiment 3
A kind of environment-friendly solvent-free UV, EB curing glass function ink, is made of: organic the raw material below according to mass percent
The organic wax 3% of inorganic hybridization prepolymer 20%, modified resin 20%, activated monomer 30%, pigment toner 12%, macromolecule changes
Property nano silica 5%, modified Nano mica sheet 1%, dispersing agent and auxiliary agent 3%, photoinitiator 5%, organic siliconresin
1%.
Wherein, the organic-inorganic hybrid prepolymer is at least nano-inorganic substance component containing 5mmol/g, and organic
Acrylate content in inorganic hybridization prepolymer is 2.5mmol/g；
The modified resin be urethane acrylate, epoxy acrylate, polyester acrylate, acrylate it is mixed
It closes；
The activated monomer be second lactone acrylate, ring trihydroxy methyl ring ethyl propylene acid esters, cobasis acrylate,
Tetrahydrofuran acrylate, isobornyl acrylate, 1,6- glycol diacrylate, ethoxylated neopentylglycol diacrylate
Ester, three (2- ethoxy) isocyanuric acids, diacrylate, Tricyclodecane Dimethanol diacrylate, three (2- ethoxy) isocyanides
Urea acid triacrylate, double pentaerythritol methacrylate, 4- hydroxy butyl vinyl ether, triethyleneglycol divinylether it is mixed
It closes；
The photoinitiator is benzophenone, phenyl bis- (2,4,6- trimethylbenzoic acid acyl group) phosphine oxides, 2- isopropyl
Base thioxanthone, diethyl thioxanthone, 2- chlorothiaxanthenone, 1- hydroxycyclohexyl phenylketone, 2- methyl-1-(2- methyl mercapto
Phenyl) -2- morpholine -1- acetone, the mixing in 2- benzyl -2- dimethylamino -1- (2- morphine phenyl) -1 butanone；
The organic wax of the macromolecule is the mixing of polyamide wax, microwax；
The dispersing agent and auxiliary agent is made of dispersing agent, defoaming agent, levelling agent, filler and flatting silica, and dispersing agent, is disappeared
Infusion, levelling agent, filler and flatting silica weight proportion be 52:3:3:65:140；
The dispersing agent is the mixing of BASF TO-5, BASF TO-7, BYK-161, BYK-183；The defoaming
Agent is BYK-1798, BYK-1799, BYK-1788, BYK-1790, BYK-1794, BYK-088, BYK-1752, BYK-1791's
Mixing；The levelling agent is BYK-307, BYK-3760, BYK-361N, BYK-3455, BYK-3535, Digao 450, Digao
2100, the mixing of Digao 410；The filler is the mixing of talcum powder, silicon-carbon stone, barium sulfate；The flatting silica is E-
1011, the mixing of OK500；
The pigment toner is the mixing of rutile type titanium white, carbon black, phthalocyanine blue pigment, ultramarine pigment.
A kind of preparation method of environment-friendly solvent-free UV, EB curing glass function ink, comprising the following steps:
1) organic-inorganic hybrid prepolymer, modified resin, activated monomer, pigment toner, the organic wax of macromolecule, modification are received
Rice silica, modified Nano mica sheet, photoinitiator and organic siliconresin are put in proportion into dispersion bucket, use high speed disperser
Disperse 1.5h under the revolving speed of 2000rpm, is uniformly mixed raw material；
2) in the scattered intermediate products investment grinding machine obtained step 1), being ground to partial size is 6.5 μm, is packed into week
Turning barrel is stand-by；
3) it in the ground intermediate products investment high speed disperser for obtaining step 2), is disposably put in proportion into afterwards point
Powder and auxiliary agent, after dispersing 1.5h under the revolving speed of 1000rpm with high speed disperser, pressure filtration, obtain environment-friendly solvent-free UV,
EB curing glass function ink.
Embodiment 4
A kind of environment-friendly solvent-free UV, EB curing glass function ink, is made of: organic the raw material below according to mass percent
The organic wax 0.5% of inorganic hybridization prepolymer 20%, modified resin 10%, activated monomer 5%, pigment toner 10.5%, macromolecule,
Modified manometer silicon dioxide 15%, modified Nano mica sheet 3%, dispersing agent and auxiliary agent 25%, photoinitiator 10%, organosilicon tree
Rouge 1%.
Wherein, the organic-inorganic hybrid prepolymer is at least nano-inorganic substance component containing 5mmol/g, and organic
Acrylate content in inorganic hybridization prepolymer is 2.5mmol/g；
The modified resin be urethane acrylate, epoxy acrylate, polyester acrylate, acrylate it is mixed
It closes；
The activated monomer be second lactone acrylate, ring trihydroxy methyl ring ethyl propylene acid esters, cobasis acrylate,
Tetrahydrofuran acrylate, isobornyl acrylate, 1,6- glycol diacrylate, ethoxylated neopentylglycol diacrylate
Ester, three (2- ethoxy) isocyanuric acids, diacrylate, Tricyclodecane Dimethanol diacrylate, three (2- ethoxy) isocyanides
Urea acid triacrylate, double pentaerythritol methacrylate, 4- hydroxy butyl vinyl ether, triethyleneglycol divinylether it is mixed
It closes；
The photoinitiator is benzophenone, phenyl bis- (2,4,6- trimethylbenzoic acid acyl group) phosphine oxides, 2- isopropyl
Base thioxanthone, diethyl thioxanthone, 2- chlorothiaxanthenone, 1- hydroxycyclohexyl phenylketone, 2- methyl-1-(2- methyl mercapto
Phenyl) -2- morpholine -1- acetone, the mixing in 2- benzyl -2- dimethylamino -1- (2- morphine phenyl) -1 butanone；
The organic wax of the macromolecule is the mixing of polyamide wax, microwax；
The dispersing agent and auxiliary agent is made of dispersing agent, defoaming agent, levelling agent, filler and flatting silica, and dispersing agent, is disappeared
Infusion, levelling agent, filler and flatting silica weight proportion be 52:3:3:65:140；
The dispersing agent is the mixing of BASF TO-5, BASF TO-7, BYK-161, BYK-183；The defoaming
Agent is BYK-1798, BYK-1799, BYK-1788, BYK-1790, BYK-1794, BYK-088, BYK-1752, BYK-1791's
Mixing；The levelling agent is BYK-307, BYK-3760, BYK-361N, BYK-3455, BYK-3535, Digao 450, Digao
2100, the mixing of Digao 410；The filler is the mixing of talcum powder, silicon-carbon stone, barium sulfate；The flatting silica is E-
1011, the mixing of OK500；
The pigment toner is the mixing of rutile type titanium white, carbon black, phthalocyanine blue pigment, ultramarine pigment.
A kind of preparation method of environment-friendly solvent-free UV, EB curing glass function ink, comprising the following steps:
1) organic-inorganic hybrid prepolymer, modified resin, activated monomer, pigment toner, the organic wax of macromolecule, modification are received
Rice silica, modified Nano mica sheet, photoinitiator and organic siliconresin are put in proportion into dispersion bucket, use high speed disperser
Disperse 1.5h under the revolving speed of 2000rpm, is uniformly mixed raw material；
2) in the scattered intermediate products investment grinding machine obtained step 1), being ground to partial size is 6.5 μm, is packed into week
Turning barrel is stand-by；
3) it in the ground intermediate products investment high speed disperser for obtaining step 2), is disposably put in proportion into afterwards point
Powder and auxiliary agent, after dispersing 1.5h under the revolving speed of 1000rpm with high speed disperser, pressure filtration, obtain environment-friendly solvent-free UV,
EB curing glass function ink.
The ink of environment-friendly solvent-free UV, EB curing glass function made of 1-4 through the foregoing embodiment carries out color, fineness, glues
Degree, gloss, attachment depth and residual solvent inspection result it is as shown in table 1 below:
1 inspection result of table
| Inspection project | Standard criterion | As a result | Whether meet |
| Color/scrape sample colorimetric | GB9761-88 | It is | |
| Fineness/μm | GB6753.1-86 | 3μm-10μm | It is |
| Viscosity/s | GB/T1723-93 | 1500cps/s | It is |
| Gloss/% | GB/T1743-89 | 5% | It is |
| Adhere to depth | GB/T9286-88 | 0 grade | It is |
| Residual solvent | Gas chromatograph | It does not measure | It is |
Environment-friendly solvent-free UV, EB curing glass function ink proposed by the present invention, can utilize ultraviolet light fast solidification
Environmentally friendly ink can realize adherence on the glass material of the overwhelming majority, and be free of organic solvent, affine to environment.
Using organic-inorganic hybrid prepolymer as matrix resin, it is formed by curing fine and close cross-linked three D structure through UV, simultaneously
Because of the presence of modified manometer silicon dioxide, extremely strong adherence is generated to glass, hydrone is caused to be difficult to permeate and destroy film,
UV coating is efficiently solved on glass intolerant to the industry problems of bubble.In addition, organic-inorganic hybrid prepolymer is with high
Curing rate, while effectively inhibiting volume of the system in UV solidification process using the rigid particles of the inorganic segment of resin and receiving
Rate is followed, the generation of oxygen inhibition is greatly reduced, realizes the rapid draing of high color density.
Activated monomer of the present invention is the mixed component for having multiple high-ranking official's monomers Yu low official's monomer, high-ranking official's monomer energy
It effectively increases the reactivity of the photocuring factor, improves photocuring reaction speed, low official's monomer there are curing rates slow, degree of cross linking
Low defect, but can effectively inhibit the contraction of volume in the curing process, by reasonably combined, it both ensure that the solidification speed of system
Degree, and restrained effectively volume contraction, the adhesive force of system is improved indirectly, directly improves the compactness of system film forming.
Photoinitiator of the present invention realizes that optical channel expands, optical absorption intensity increases under the conditions of high color density, from
And the characteristics of effectively improving curing rate and double bond conversion ratio.
The modified Nano mica sheet that the present invention adds is arranged in comparatively dense continuous phase, effective ground resistance in the curing process
Every the permeability of hydrone, the ability of resistance to bubble in the water resistance of film layer, and paint is improved.
The above are merely the preferred embodiment of the present invention, it is noted that for those skilled in the art, not
Under the premise of being detached from present inventive concept, several modifications and improvements can also be made, these also should be considered as protection model of the invention
It encloses, these all will not influence the effect and patent practicability that the present invention is implemented.
Claims (10)
1. a kind of environment-friendly solvent-free UV, EB curing glass function ink, which is characterized in that by below according to the raw material of mass percent
Composition: organic-inorganic hybrid prepolymer 20%-60%, modified resin 10%-20%, activated monomer 5%-30%, pigment toner
The organic wax 0.5%-3% of 5%-40%, macromolecule, modified manometer silicon dioxide 5%-15%, modified Nano mica sheet 1%-
3%, dispersing agent and auxiliary agent 3%-25%, photoinitiator 5%-10%, organic siliconresin 1%-3%.
2. environment-friendly solvent-free UV, EB curing glass function ink according to claim 1, which is characterized in that described is organic
Inorganic hybridization prepolymer is at least nano-inorganic substance component containing 0.5mmol/g-10mmol/g, and organic inorganic hybridization pre-polymerization
Acrylate content in object is 0.5mmol/g-5mmol/g.
3. environment-friendly solvent-free UV, EB curing glass function ink according to claim 1 or 2, which is characterized in that described changes
Property resin be one or more of urethane acrylate, epoxy acrylate, polyester acrylate, acrylate
Mixing.
4. environment-friendly solvent-free UV, EB curing glass function ink according to claim 3, which is characterized in that the activity
Monomer be second lactone acrylate, ring trihydroxy methyl ring ethyl propylene acid esters, cobasis acrylate, tetrahydrofuran acrylate,
Isobornyl acrylate, 1,6- glycol diacrylate, ethoxylated neopentylglycol diacrylate, three (2- ethoxys) are different
It is cyanurate, diacrylate, Tricyclodecane Dimethanol diacrylate, three (2- ethoxy) isocyanuric acid triacrylates, double
One or more of six acrylate of pentaerythrite, 4- hydroxy butyl vinyl ether, triethyleneglycol divinylether mix
It closes.
5. environment-friendly solvent-free UV, EB curing glass function ink according to claim 4, which is characterized in that the light draws
Hair agent is benzophenone, phenyl bis- (2,4,6- trimethylbenzoic acid acyl group) phosphine oxides, 2- isopropyl thioxanthone, diethyl sulfide
Miscellaneous anthrone, 2- chlorothiaxanthenone, 1- hydroxycyclohexyl phenylketone, 2- methyl-1-(2- methyl mercapto phenyl)-2- morpholine-1- acetone,
The mixing of one or more of 2- benzyl -2- dimethylamino -1- (2- morphine phenyl) -1 butanone.
6. environment-friendly solvent-free UV, EB curing glass function ink according to claim 5, which is characterized in that the high score
The organic wax of son is one or both of polytetrafluoroethylwax wax, polyethylene wax, polyamide wax, microwax.
7. environment-friendly solvent-free UV, EB curing glass function ink according to claim 6, which is characterized in that the dispersion
Agent and auxiliary agent are made of dispersing agent, defoaming agent, levelling agent, filler and flatting silica, and dispersing agent, defoaming agent, levelling agent, filler and
The weight proportion of flatting silica is 1-100:1-5:1-5:30-100:30-350.
8. environment-friendly solvent-free UV, EB curing glass function ink according to claim 7, which is characterized in that the dispersion
Agent is the mixing of one or more of BASF TO-5, BASF TO-7, BYK-161, BYK-183；The defoaming
Agent is in BYK-1798, BYK-1799, BYK-1788, BYK-1790, BYK-1794, BYK-088, BYK-1752, BYK-1791
One or more kinds of mixing；The levelling agent is BYK-307, BYK-3760, BYK-361N, BYK-3455, BYK-
3535, the mixing of one or more of Digao 450, Digao 2100, Digao 410；The filler is talcum powder, silicon-carbon
The mixing of one or more of stone, barium sulfate；The flatting silica is one or both of E-1011, OK500.
9. environment-friendly solvent-free UV, EB curing glass function ink according to claim 7, which is characterized in that the pigment
Toner is the mixing of one or more of rutile type titanium white, carbon black, phthalocyanine blue pigment, ultramarine pigment.
10. a kind of preparation method of such as described in any item environment-friendly solvent-free UV, EB curing glass function ink of claim 1-9,
Characterized by comprising the following steps:
1) by organic-inorganic hybrid prepolymer, modified resin, activated monomer, pigment toner, the organic wax of macromolecule, modified Nano two
Silica, modified Nano mica sheet, photoinitiator and organic siliconresin are put in proportion into dispersion bucket, are existed with high speed disperser
Disperse 1-2h under the revolving speed of 1000-3000rpm；
2) in the scattered intermediate products investment grinding machine obtained step 1), being ground to partial size is 3-10 μm, is packed into turnover
Bucket is stand-by；
3) in the ground intermediate products investment high speed disperser for obtaining step 2), it is disposably put in proportion into dispersing agent afterwards
And auxiliary agent, after dispersing 1-2h under the revolving speed of 800-1200rpm with high speed disperser, pressure filtration, obtain environment-friendly solvent-free UV,
EB curing glass function ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910611653.6A CN110218480A (en) | 2019-07-08 | 2019-07-08 | A kind of environment-friendly solvent-free UV, EB curing glass function ink and preparation method |
Applications Claiming Priority (1)
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| CN201910611653.6A CN110218480A (en) | 2019-07-08 | 2019-07-08 | A kind of environment-friendly solvent-free UV, EB curing glass function ink and preparation method |
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| CN111518432A (en) * | 2020-06-05 | 2020-08-11 | 苏州市博来特油墨有限公司 | High-temperature-resistant UV (ultraviolet) curing printing ink |
| CN114874651A (en) * | 2022-06-14 | 2022-08-09 | 连云港森永达新材料科技有限公司 | Solvent-free electron beam curing release agent and preparation process thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111518432A (en) * | 2020-06-05 | 2020-08-11 | 苏州市博来特油墨有限公司 | High-temperature-resistant UV (ultraviolet) curing printing ink |
| CN114874651A (en) * | 2022-06-14 | 2022-08-09 | 连云港森永达新材料科技有限公司 | Solvent-free electron beam curing release agent and preparation process thereof |
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Application publication date: 20190910 |