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CN110065208A - A kind of polyethylene insulation pellet mixing method - Google Patents

A kind of polyethylene insulation pellet mixing method Download PDF

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Publication number
CN110065208A
CN110065208A CN201910342473.2A CN201910342473A CN110065208A CN 110065208 A CN110065208 A CN 110065208A CN 201910342473 A CN201910342473 A CN 201910342473A CN 110065208 A CN110065208 A CN 110065208A
Authority
CN
China
Prior art keywords
sample
extruder
polyethylene
mixing method
sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910342473.2A
Other languages
Chinese (zh)
Inventor
许俊桃
王暄
李鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Harbin University of Science and Technology
Original Assignee
Harbin University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Harbin University of Science and Technology filed Critical Harbin University of Science and Technology
Priority to CN201910342473.2A priority Critical patent/CN110065208A/en
Publication of CN110065208A publication Critical patent/CN110065208A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/025General arrangement or layout of plant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/14Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the particular extruding conditions, e.g. in a modified atmosphere or by using vibration
    • B29C48/144Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the particular extruding conditions, e.g. in a modified atmosphere or by using vibration at the plasticising zone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a kind of polyethylene insulation pellet mixing method, which comprises the following steps: a. proportionally prepares a certain amount of mixing sample, i.e. polyethylene, crosslinking agent and ultraviolet absorbing agent;B. oven temperature is set as 200 DEG C, and the sample (under air-proof condition) for being put into the ratio of having prepared dries nearly 4h.During this, is once rocked every half an hour, be then allowed to stand 12h;C. certain antioxidant is added before being squeezed out with extruder, the temperature that four sections every section of extruder is set as 130 DEG C, 140 DEG C, 160 DEG C, 180 DEG C.Extruding sheet mixture;D. mixture is pressed into using vulcanizing press the small pieces of 1mm thickness, then carries out ultraviolet radiation.Plaques are finally cut into dumbbell shaped with sheet-punching machine.Disclosed insulation pellet mixing method, which is kneaded, to be uniformly mixed, and good dispersion has the mechanical properties such as excellent stretching strength, tensile strength, elongation at break, and reduces environmental pollution, saves resource, and equipment investment is small, it can be achieved that industrialized production.

Description

A kind of polyethylene insulation pellet mixing method
Technical field
The present invention relates to a kind of mixing method of actual production insulating material of polyethylene.It belongs to sample preparation technology field, Suitable for producing the sample of suitable polyethylenes insulating layer superior performance.
Background technique
With the development of domestic economy, the production of polyethylene wire and cable no longer meets the needs of power industry.Although Polyethylene has obtained cable industry by the performances such as its outstanding electrical insulation capability, good chemical-resistance, easy to process Height favor, and be widely used in the insulation of cable and the covering material of sheath.But its fusing point is lower, cannot work compared with Under high environment temperature, so it can not preferably be applied in cable industry.And the mechanical strength of polyethylene is lower, this Limit its extensive use.No matter in terms of electrical performance or in terms of mechanical property, existing production technology cannot be produced Meet the cable insulation of development out.
Ultraviolet light cross-linking polyethylene new technology with its industrial equipment simple, small investment, it is easily operated, easy to maintain, to ring To the damage of polyethylene ontology during border is pollution-free, security protection is not harsh, volume production rate is high, operating cost is low and ultraviolet light cross-linking Hurt the advantages that small, extensive use has been obtained in its related fields, passes through the industry processes being applied to cable.Though Right UV crosslinking polyethylene insulation is applied well, but produces the method efficiency of this insulation again without being mentioned Height can preferably make this new technology be widely used so a kind of new method is needed to improve production efficiency.
Summary of the invention
In view of the above-mentioned problems, solving base-material the invention discloses a kind of insulation pellet mixing method mixes uneven, mechanics The problems such as performance, insuperior electric property.
The present invention is a kind of insulation pellet mixing method, which comprises the following steps: a. proportionally prepares one Quantitative mixing sample, i.e. polyethylene, crosslinking agent and ultraviolet absorbing agent;B. oven temperature is set as 200 DEG C, is put into and has been prepared The sample (under air-proof condition) of ratio dries nearly 4h.During this, is once rocked every half an hour, be then allowed to stand 12h;c. It is added certain antioxidant before being squeezed out with extruder, the temperature that four sections every section of extruder is set as 130 DEG C, and 140 DEG C, 160 DEG C, 180℃.Extruding sheet mixture;D. mixture is pressed into using vulcanizing press the small pieces of 1mm thickness, then carries out ultraviolet light Radiation.Plaques are finally cut into dumbbell shaped with sheet-punching machine.
Preferably, extruder used in step c is electromagnetic dynamic plasticizing extruder, polymer plasticization squeezes out overall process It is completed in the rotor internal cavity of driving motor.Each section in figure are as follows: 1- ventilation opening;2- screw rod;3- barrel;4- rotor;5- stator; 6- base;7- hopper.
Preferably, belonging to laboratory hand sheet punching apparatus using sheet-punching machine in step d, convenient for rushing polyethylene kind sample It is cut into standard regulation sample.
Disclosed insulation pellet mixing method, which is kneaded, to be uniformly mixed, and good dispersion is determined to stretch by force with excellent Mechanical properties such as degree, tensile strength, elongation at break, and reduce environmental pollution, save resource, equipment investment it is small, it can be achieved that Industrialized production.
Detailed description of the invention
Following specific implementation and attached drawing of the invention are described in detail for ease of explanation,.
Fig. 1 is the electromagnetic dynamic plasticizing extruder device in step c of the present invention.
Specific embodiment
Specific embodiments of the present invention are broadly divided into following steps:
1. proportionally preparing a certain amount of mixing sample, i.e. polyethylene, crosslinking agent and ultraviolet absorbing agent;
2. setting oven temperature as 200 DEG C, the sample (under air-proof condition) for being put into the ratio of having prepared dries nearly 4h.During this, It is once rocked every half an hour, is then allowed to stand 12h;
3. certain antioxidant is added before being squeezed out with extruder, totally four sections and every section of temperature is set as 130 DEG C to extruder, 140 DEG C, 160 DEG C, 180 DEG C.Extruding sheet mixture carries out envelope preservation;
4. mixture is pressed into using vulcanizing press the small pieces of 1mm thickness, ultraviolet light cross-linking radiation is then carried out.Finally with punching Plaques are cut into dumbbell shaped by piece machine, are done heat and are extended experiment, test the degree of cross linking.
The present invention is not limited to above-mentioned specific embodiment, and persons skilled in the art are disclosed interior according to the present invention Hold, the contents of the present invention or all using design structure of the invention can be implemented using other a variety of specific embodiments And thinking, simple change or change are done, protection scope of the present invention is both fallen within.

Claims (5)

1. the dress that extruder used in described in step c of the present invention is a kind of production application electromagnetic dynamic plasticizing extruder It sets, it belongs to sample preparation technology field, which is characterized in that it is contained in ventilation opening, screw rod, barrel, rotor, stator, base, Hopper.
2. the screw rod in device is axial vibration system, including armature, magnet exciting coil group, magnetic cylinder, spiral shell according to claim 1 Bar, barrel.
3. a kind of device of production application electromagnetic dynamic plasticizing extruder according to claim 1, defeated in polymer It send, fusion plastification and extrusion overall process all have been introduced into mechanical oscillation field caused by electromagnetic field.
4. device polymer plasticization squeezes out overall process and completes in the rotor internal cavity of driving motor according to claim 1.
5. sheet-punching machine described in step d of the present invention belongs to laboratory hand sheet punching apparatus, convenient for polyethylene kind sample is punched into Standard provides sample.
CN201910342473.2A 2019-04-26 2019-04-26 A kind of polyethylene insulation pellet mixing method Pending CN110065208A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910342473.2A CN110065208A (en) 2019-04-26 2019-04-26 A kind of polyethylene insulation pellet mixing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910342473.2A CN110065208A (en) 2019-04-26 2019-04-26 A kind of polyethylene insulation pellet mixing method

Publications (1)

Publication Number Publication Date
CN110065208A true CN110065208A (en) 2019-07-30

Family

ID=67369087

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910342473.2A Pending CN110065208A (en) 2019-04-26 2019-04-26 A kind of polyethylene insulation pellet mixing method

Country Status (1)

Country Link
CN (1) CN110065208A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1306556A (en) * 1998-05-18 2001-08-01 陶氏化学公司 Articles having elevated temp. elasticity made from irradiated and crosslinked ethylene polymers and method for making same
CN106633287A (en) * 2016-11-29 2017-05-10 中广核三角洲(苏州)新材料研发有限公司 Preparation method of wear-resistant heat-conducting irradiation-crosslinking ultra-high molecular weight polyethylene
WO2019076653A1 (en) * 2017-10-16 2019-04-25 FEDDEM GmbH & Co. KG Device and method for impregnating fibre bundles with a polymer melt
CN209395226U (en) * 2018-11-19 2019-09-17 哈尔滨理工大学 A kind of production application electromagnetic dynamic plasticizing extruder device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1306556A (en) * 1998-05-18 2001-08-01 陶氏化学公司 Articles having elevated temp. elasticity made from irradiated and crosslinked ethylene polymers and method for making same
CN106633287A (en) * 2016-11-29 2017-05-10 中广核三角洲(苏州)新材料研发有限公司 Preparation method of wear-resistant heat-conducting irradiation-crosslinking ultra-high molecular weight polyethylene
WO2019076653A1 (en) * 2017-10-16 2019-04-25 FEDDEM GmbH & Co. KG Device and method for impregnating fibre bundles with a polymer melt
CN209395226U (en) * 2018-11-19 2019-09-17 哈尔滨理工大学 A kind of production application electromagnetic dynamic plasticizing extruder device

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Application publication date: 20190730

WD01 Invention patent application deemed withdrawn after publication