CN117393666B - Super-radiation light-emitting diode - Google Patents
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Abstract
本申请提供了一种超辐射发光二极管,包括自下而上层叠设置的衬底、缓冲层、第一限制层、第一波导层、有源层、第二波导层、第二限制层、欧姆接触层。所述有源层包括:量子点堆叠层和量子阱层。所述量子点堆叠层包括:n组量子点单元,每一组所述量子点单元包括自下而上层叠设置的量子点单层、覆盖层和间隔层。所述量子阱层的材料为InxGa(1‑x)As,其中,0.22≤x≤0.38。所述量子阱层的发光峰的位置在所述量子点堆叠层的基态发光峰和激发态发光峰之间。按照本申请中有源层的结构设置,可以在适当拓宽光谱宽度的同时,消除不同发光峰之间的dip过大的问题,以使得超辐射发光二极管应用于OCT成像系统时,能够消除成像鬼影。
This application provides a superradiant light-emitting diode, which includes a substrate, a buffer layer, a first confinement layer, a first waveguide layer, an active layer, a second waveguide layer, a second confinement layer, and an ohmic layer that are stacked from bottom to top. contact layer. The active layer includes: a quantum dot stack layer and a quantum well layer. The quantum dot stack layer includes: n groups of quantum dot units, and each group of the quantum dot units includes a quantum dot single layer, a covering layer and a spacer layer stacked from bottom to top. The material of the quantum well layer is In x Ga (1-x) As, where 0.22≤x≤0.38. The position of the luminescence peak of the quantum well layer is between the ground state luminescence peak and the excited state luminescence peak of the quantum dot stack layer. According to the structural arrangement of the active layer in this application, the spectral width can be appropriately broadened and the problem of excessive dip between different luminescence peaks can be eliminated, so that imaging ghosts can be eliminated when superradiant light-emitting diodes are used in OCT imaging systems. .
Description
技术领域Technical field
本申请涉及半导体技术领域,具体而言,涉及一种超辐射发光二极管,既能够拓宽光谱发光峰,又能够消除不同发光峰之间的dip。所述超辐射发光二极管应用于OCT(光学相干层析)成像系统时,能够消除成像鬼影。The present application relates to the field of semiconductor technology. Specifically, it relates to a superradiant light-emitting diode that can both broaden the spectral luminescence peaks and eliminate the dip between different luminescence peaks. When the superluminescent diode is used in an OCT (optical coherence tomography) imaging system, it can eliminate imaging ghosts.
背景技术Background technique
超辐射发光二极管(Super luminescent Diodes,SLD)是一种高输出功率、宽光谱范围的高稳定光源。SLD具有比半导体激光器更宽的发光谱和更低的相干长度。与发光二极管相比,SLD具有更高的输出功率,广泛应用于OCT(光学相干层析)成像、光纤陀螺、光纤传感器等系统中。Super luminescent diodes (SLD) are a highly stable light source with high output power and wide spectral range. SLDs have a wider emission spectrum and lower coherence length than semiconductor lasers. Compared with light-emitting diodes, SLDs have higher output power and are widely used in OCT (optical coherence tomography) imaging, fiber optic gyroscopes, fiber optic sensors and other systems.
对于单量子阱或均匀多量子阱超辐射发光二极管,其增益谱都相对较窄,难以获得宽光谱的输出;对于非均匀多量子阱超辐射发光二极管来说,能在一定程度上提高输出谱宽,但由于不同量子阱之间的电子能态不连续,难以获得具有规则高斯形状的光谱。For single quantum well or uniform multiple quantum well superluminescent diodes, the gain spectrum is relatively narrow, making it difficult to obtain a wide spectrum output; for non-uniform multiple quantum well superluminescent diodes, the output spectrum can be improved to a certain extent. wide, but due to the discontinuity of electronic energy states between different quantum wells, it is difficult to obtain a spectrum with a regular Gaussian shape.
对于量子点超辐射发光二极管来说,通过自组织生长的量子点在尺寸上具有一定的非均匀性,这种非均匀性的量子点对于制作宽光谱的器件来说是一个有利的因素。相关的研究结果表明,具有一定尺寸分布的量子点集合具有较宽的增益谱,尺寸非均匀性越大,峰值下降越大、展宽越强。同时,量子点的尺寸分布一般满足高斯分布,不同尺寸量子点的基态与激发态能级交叠在一起,使得量子点集合的能级近似连续分布,更易形成规则形状的输出谱。For quantum dot superradiant light-emitting diodes, quantum dots grown through self-organization have certain non-uniformity in size. This non-uniform quantum dot is a favorable factor for the production of wide spectrum devices. Relevant research results show that a collection of quantum dots with a certain size distribution has a wider gain spectrum. The greater the size non-uniformity, the greater the peak drop and the stronger the broadening. At the same time, the size distribution of quantum dots generally satisfies the Gaussian distribution. The ground state and excited state energy levels of quantum dots of different sizes overlap together, making the energy levels of the quantum dot collection approximately continuously distributed, making it easier to form a regular-shaped output spectrum.
基于上述量子点超辐射发光二极管和量子阱超辐射发光二极管的各自特性,现有技术中经常采用量子点和量子阱混合有源区的超辐射发光二极管,来拓展光谱宽度,提高器件的输出功率。但是,现有技术中提供的量子点和量子阱混合有源区的超辐射发光二极管,虽然表面上拓展了光谱宽度,但实际存在如图1所示的不同发光峰之间的dip过大的问题。具有该问题的量子点和量子阱混合有源区的超辐射发光二极管,应用到OCT(光学相干层析)成像系统中,会直接导致成像鬼影的出现。Based on the respective characteristics of the above-mentioned quantum dot superluminescent diodes and quantum well superluminescent diodes, superluminescent diodes with mixed active regions of quantum dots and quantum wells are often used in the existing technology to expand the spectral width and increase the output power of the device. . However, although superradiant light-emitting diodes with mixed active regions of quantum dots and quantum wells provided in the existing technology have expanded the spectral width on the surface, they actually have the problem of excessive dip between different luminescence peaks as shown in Figure 1. . Superradiant light-emitting diodes with mixed active regions of quantum dots and quantum wells that have this problem will directly lead to the appearance of imaging ghosts when applied to OCT (optical coherence tomography) imaging systems.
因此,亟需提供一种能够解决不同发光峰之间的dip过大的问题的超辐射发光二极管,以使得超辐射发光二极管应用于OCT(光学相干层析)成像系统时,能够消除成像鬼影。Therefore, there is an urgent need to provide a superradiant light-emitting diode that can solve the problem of excessive dip between different luminescence peaks, so that imaging ghosts can be eliminated when the superradiant light-emitting diode is used in an OCT (optical coherence tomography) imaging system.
发明内容Contents of the invention
由于现有技术中采用量子点SLD或采用量子点+量子阱SLD方案,的目的均是提高SLD的发光峰宽度,并未考虑不同发光峰之间的dip问题。本申请提供一种可应用于OCT(光学相干层析)成像系统,并且能够消除成像鬼影的超辐射发光二极管。Since quantum dot SLD or quantum dot + quantum well SLD solutions are used in the existing technology, the purpose is to increase the luminescence peak width of SLD, and the dip problem between different luminescence peaks is not considered. The present application provides a superluminescent diode that can be applied to an OCT (optical coherence tomography) imaging system and can eliminate imaging ghosts.
本申请提供的技术方案如下:The technical solutions provided by this application are as follows:
一种超辐射发光二极管,包括自下而上层叠设置的衬底、缓冲层、第一限制层、第一波导层、有源层、第二波导层、第二限制层、欧姆接触层;A superradiant light-emitting diode, including a substrate, a buffer layer, a first confinement layer, a first waveguide layer, an active layer, a second waveguide layer, a second confinement layer, and an ohmic contact layer that are stacked from bottom to top;
所述有源层包括:量子点堆叠层和量子阱层;The active layer includes: a quantum dot stack layer and a quantum well layer;
所述量子点堆叠层包括:n组量子点单元,每一组所述量子点单元包括自下而上层叠设置的量子点单层、覆盖层和间隔层;The quantum dot stack layer includes: n groups of quantum dot units, each group of the quantum dot units includes a quantum dot single layer, a covering layer and a spacer layer stacked from bottom to top;
所述量子阱层的材料为InxGa(1-x)As,其中,0.22≤x≤0.38;The material of the quantum well layer is In x Ga (1-x) As, where 0.22≤x≤0.38;
所述量子阱层发光峰对应波长的所在位置,在所述量子点堆叠层基态发光峰对应波长的所在位置和所述量子点堆叠层激发态发光峰对应波长的所在位置之间。The position of the wavelength corresponding to the luminescence peak of the quantum well layer is between the position corresponding to the wavelength of the ground state luminescence peak of the quantum dot stack layer and the position corresponding to the wavelength of the excited state luminescence peak of the quantum dot stack layer.
在一个实施例中,所述量子阱层位于所述量子点堆叠层和所述第二波导层之间;所述量子阱层的厚度为5-9nm。In one embodiment, the quantum well layer is located between the quantum dot stack layer and the second waveguide layer; the thickness of the quantum well layer is 5-9 nm.
在一个实施例中,所述量子点单层的材料为InAs,厚度为2.2-3ML;所述覆盖层的材料为InGaAs,厚度为3-7nm;所述间隔层的材料为GaAs,厚度为30-40nm;所述n的取值范围为:4≤n≤8。In one embodiment, the material of the quantum dot single layer is InAs, with a thickness of 2.2-3ML; the material of the covering layer is InGaAs, with a thickness of 3-7nm; the material of the spacer layer is GaAs, with a thickness of 30 -40nm; the value range of n is: 4≤n≤8.
在一个实施例中,所述n的取值为:n=6或8,6组或8组所述量子点单元中包括具有第一厚度的量子点单层及具有第二厚度的量子点单层;在层叠方向上,所述具有第一厚度的量子点单层的所述量子点单元和所述具有第二厚度的量子点单层的所述量子点单元相间设置,所述第一厚度不等于所述第二厚度,且所述第一厚度和所述第二厚度均在2.2ML-3ML范围内。In one embodiment, the value of n is: n=6 or 8, and the 6 or 8 groups of quantum dot units include a quantum dot single layer with a first thickness and a quantum dot single layer with a second thickness. layer; in the stacking direction, the quantum dot units of the quantum dot single layer with a first thickness and the quantum dot units of the quantum dot single layer with a second thickness are alternately arranged, the first thickness is not equal to the second thickness, and both the first thickness and the second thickness are within the range of 2.2ML-3ML.
在一个实施例中,所述n的取值为:n=5或7,5组或7组所述量子点单元中的每一组所述量子点单元中的所述量子点单层的厚度均不相同,且5组或7组所述量子点单元中自下而上设置的每一组所述量子点单元中的所述量子点单层的厚度以相同变化量增大或减小。In one embodiment, the value of n is: n=5 or 7, and the thickness of the quantum dot single layer in each of the 5 or 7 groups of quantum dot units is are different, and the thickness of the quantum dot single layer in each group of the quantum dot units arranged from bottom to top in the 5 groups or 7 groups of the quantum dot units increases or decreases by the same amount of change.
在一个实施例中,每一组所述量子点单元中的所述量子点单层的厚度均为2.7ML,所述覆盖层的厚度为5nm,所述间隔层的厚度为35nm,所述n的取值为:n=5。In one embodiment, the thickness of the quantum dot single layer in each group of the quantum dot units is 2.7 ML, the thickness of the covering layer is 5 nm, the thickness of the spacer layer is 35 nm, and the n The value is: n=5.
在一个实施例中,所述量子阱层为In0.38Ga0.62As,所述量子阱层的厚度为5nm。In one embodiment, the quantum well layer is In 0.38 Ga 0.62 As, and the thickness of the quantum well layer is 5 nm.
在一个实施例中,所述量子点堆叠层的基态发光峰位于1.3μm,所述量子点堆叠层的激发态发光峰位于1.22μm,所述量子阱层的发光峰位于1.25μm。In one embodiment, the ground state luminescence peak of the quantum dot stack layer is located at 1.3 μm, the excited state luminescence peak of the quantum dot stack layer is located at 1.22 μm, and the luminescence peak of the quantum well layer is located at 1.25 μm.
在一个实施例中,所述量子阱层位于所述量子点堆叠层和所述第二波导层之间;所述量子阱层的厚度为5-9nm;In one embodiment, the quantum well layer is located between the quantum dot stack layer and the second waveguide layer; the thickness of the quantum well layer is 5-9 nm;
所述量子点单层的材料为InAs,厚度为2.2-3ML;所述覆盖层的材料为InGaAs,厚度为3-7nm;所述间隔层的材料为GaAs,厚度为30-40nm;所述n的取值范围为:5≤n≤9。The material of the quantum dot single layer is InAs, with a thickness of 2.2-3ML; the material of the covering layer is InGaAs, with a thickness of 3-7nm; the material of the spacer layer is GaAs, with a thickness of 30-40nm; the n The value range of is: 5≤n≤9.
在一个实施例中,所述量子点单层的厚度为2.3ML,所述覆盖层的厚度为4nm,所述间隔层的厚度为40nm,所述n的取值范围为:n=5。In one embodiment, the thickness of the quantum dot single layer is 2.3ML, the thickness of the covering layer is 4nm, the thickness of the spacer layer is 40nm, and the value range of n is: n=5.
在一个实施例中,所述量子阱层为In0.35Ga0.65As,所述量子阱层的厚度为5nm。In one embodiment, the quantum well layer is In 0.35 Ga 0.65 As, and the thickness of the quantum well layer is 5 nm.
在一个实施例中,所述量子点堆叠层的基态发光峰位于1.25μm,所述量子点堆叠层的激发态发光峰位于1.1μm,所述量子阱层的发光峰位于1.18μm。In one embodiment, the ground state luminescence peak of the quantum dot stack layer is located at 1.25 μm, the excited state luminescence peak of the quantum dot stack layer is located at 1.1 μm, and the luminescence peak of the quantum well layer is located at 1.18 μm.
本申请提供的方案中,有以下有益效果:The solution provided by this application has the following beneficial effects:
1、所述量子阱层的材料为InxGa(1-x)As,其中,0.22≤x≤0.38。所述量子阱层的发光峰的位置在所述量子点堆叠层的基态发光峰和激发态发光峰之间。按照本申请中有源层的结构设置,可以基于目前量子点基态+激发态较宽发光峰的前提下,采用量子阱层补偿量子点基态发光峰和激发态发光峰之间的dip。采用本申请提供的方案,解决了传统量子点超辐射发光二极管由于基态、激发态发光导致光谱dip过深,影响OCT成像效果的问题。1. The material of the quantum well layer is In x Ga (1-x) As, where 0.22≤x≤0.38. The position of the luminescence peak of the quantum well layer is between the ground state luminescence peak and the excited state luminescence peak of the quantum dot stack layer. According to the structural arrangement of the active layer in this application, the quantum well layer can be used to compensate for the dip between the quantum dot's ground state luminescence peak and the excited state luminescence peak based on the current broad luminescence peak of the quantum dot's ground state + excited state. The solution provided by this application solves the problem of traditional quantum dot superradiant light-emitting diodes that cause the spectrum dip to be too deep due to the ground state and excited state light emission, affecting the OCT imaging effect.
2、所述量子阱层位于所述量子点堆叠层和所述第二波导层之间。可以理解为:所述量子阱层位于量子点堆叠层的上方,能够有利于量子阱层和量子点堆叠层发光效率的平衡。因为,量子点堆叠层的增益更容易增益饱和,注入载流子能够有效分布于量子阱层和量子点堆叠层中。本实施例中,将量子阱层位于量子点堆叠层的上方,可以保证注入载流子不容易被量子阱层钳制,从而使得超辐射发光二极管的发光效率更加均衡。2. The quantum well layer is located between the quantum dot stack layer and the second waveguide layer. It can be understood that: the quantum well layer is located above the quantum dot stack layer, which can be beneficial to the balance of the luminous efficiency of the quantum well layer and the quantum dot stack layer. Because the gain of the quantum dot stack layer is easier to gain saturation, the injected carriers can be effectively distributed in the quantum well layer and the quantum dot stack layer. In this embodiment, locating the quantum well layer above the quantum dot stack layer can ensure that the injected carriers are not easily clamped by the quantum well layer, thereby making the luminous efficiency of the superluminescent diode more balanced.
3、量子点堆叠层特殊的结构设计,比如啁啾量子点堆叠层结构的设计,能够充分利用量子点宽光谱的特性,更好的实现光谱的拓宽,再配合量子阱层的特殊化设计,进而能够避免量子点发光峰的dip问题,实现无dip的更宽光谱输出。3. The special structural design of the quantum dot stack layer, such as the design of the chirped quantum dot stack layer structure, can make full use of the wide spectrum characteristics of quantum dots and better realize the broadening of the spectrum. Coupled with the special design of the quantum well layer, This in turn can avoid the dip problem of quantum dot luminescence peaks and achieve wider spectral output without dip.
为使本申请的上述目的、特征和优点能更明显易懂,下文特举较佳实施例,并配合所附附图,作详细说明如下。In order to make the above-mentioned objects, features and advantages of the present application more obvious and understandable, preferred embodiments are given below and described in detail with reference to the attached drawings.
附图说明Description of drawings
为了更清楚地说明本申请实施例的技术方案,下面将对实施例中所需要使用的附图作简单地介绍, 应当理解,以下附图仅示出了本申请的某些实施例,因此不应被看作是对范围的限定,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他相关的附图。In order to explain the technical solutions of the embodiments of the present application more clearly, the drawings required to be used in the embodiments will be briefly introduced below. It should be understood that the following drawings only show some embodiments of the present application and therefore do not illustrate the technical solutions of the embodiments of the present application. It should be regarded as a limitation of the scope. For those of ordinary skill in the art, other relevant drawings can be obtained based on these drawings without exerting creative efforts.
图1为现有技术中提供的超辐射发光二极管的光谱图;Figure 1 is a spectrum diagram of a superluminescent diode provided in the prior art;
图2为本申请一个实施例提供的超辐射发光二极管的结构示意图;Figure 2 is a schematic structural diagram of a superradiant light-emitting diode provided by an embodiment of the present application;
图3为本申请一个实施例提供的超辐射发光二极管的光谱图;Figure 3 is a spectrum diagram of a superluminescent diode provided by an embodiment of the present application;
图4为本申请多个实施例中超辐射发光二极管的光谱效果示意图。FIG. 4 is a schematic diagram of the spectral effects of superradiant light-emitting diodes in various embodiments of the present application.
附图标记:Reference signs:
超辐射发光二极管100:Superradiant LED 100:
衬底10、缓冲层20、第一限制层30、第一波导层40、有源层50、第二波导层60、第二限制层70、欧姆接触层80、第一电极91、第二电极92;Substrate 10, buffer layer 20, first confinement layer 30, first waveguide layer 40, active layer 50, second waveguide layer 60, second confinement layer 70, ohmic contact layer 80, first electrode 91, second electrode 92;
量子点堆叠层51、量子阱层52;Quantum dot stack layer 51, quantum well layer 52;
量子点单元510、量子点单层511、覆盖层512、间隔层513。Quantum dot unit 510, quantum dot single layer 511, covering layer 512, and spacer layer 513.
具体实施方式Detailed ways
下面将结合本申请实施例中附图,对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本申请一部分实施例,而不是全部的实施例。通常在此处附图中描述和示出的本申请实施例的组件可以以各种不同的配置来布置和设计。因此,以下对在附图中提供的本申请的实施例的详细描述并非旨在限制要求保护的本申请的范围,而是仅仅表示本申请的选定实施例。基于本申请的实施例,本领域技术人员在没有做出创造性劳动的前提下所获得的所有其他实施例,都属于本申请保护的范围。The technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present application. Obviously, the described embodiments are only some of the embodiments of the present application, rather than all of the embodiments. The components of the embodiments of the present application generally described and illustrated in the figures herein may be arranged and designed in a variety of different configurations. Accordingly, the following detailed description of the embodiments of the application provided in the appended drawings is not intended to limit the scope of the claimed application, but rather to represent selected embodiments of the application. Based on the embodiments of this application, all other embodiments obtained by those skilled in the art without any creative work shall fall within the scope of protection of this application.
应注意到:相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步定义和解释。同时,在本申请的描述中,术语“第一”、“第二”等仅用于区分描述,而不能理解为指示或暗示相对重要性。It should be noted that similar reference numerals and letters represent similar items in the following figures, therefore, once an item is defined in one figure, it does not need further definition and explanation in subsequent figures. Meanwhile, in the description of the present application, the terms "first", "second", etc. are only used to differentiate the description and cannot be understood as indicating or implying relative importance.
如图1所示现有的超辐射发光二极管的光谱图中不同发光峰之间存在明显的dip(这里dip可以理解为两个发光峰之间存在的发光谷)。因此,针对上述缺陷,提出了本申请的技术方案。下面将对本申请的技术方案进行详细的描述。As shown in Figure 1, there is an obvious dip between different luminescence peaks in the spectrum of the existing superluminescent diode (here dip can be understood as the luminescence valley that exists between the two luminescence peaks). Therefore, in order to solve the above defects, the technical solution of the present application is proposed. The technical solution of the present application will be described in detail below.
如图2所示,本申请提供一种超辐射发光二极管100包括自下而上层叠设置的衬底10、缓冲层20、第一限制层30、第一波导层40、有源层50、第二波导层60、第二限制层70、欧姆接触层80,以及设置在两端的第一电极91和第二电极92。As shown in FIG. 2 , the present application provides a superluminescent diode 100 including a substrate 10 , a buffer layer 20 , a first confinement layer 30 , a first waveguide layer 40 , an active layer 50 , and a substrate 10 stacked from bottom to top. The second waveguide layer 60, the second confinement layer 70, the ohmic contact layer 80, and the first electrode 91 and the second electrode 92 provided at both ends.
所述衬底10可以是Si掺杂的n-GaAs(100)衬底。所述缓冲层20可以设置为n-GaAs缓冲层,其厚度可设置为300nm。所述第一限制层30可设置为n-Al0.4Ga0.6As,其厚度可设置为1400nm。所述第一波导层40可以设置为i-GaAs,其厚度可设置为70nm。所述二波导层60可设置为i-GaAs,其厚度可设置为40nm。所述第二限制层70可设置为p-Al0.4Ga0.6As,其厚度可设置为1400nm。所述欧姆接触层80可设置为GaAs,其厚度可设置为200nm。设置在两端的所述第一电极91和所述第二电极92可设置为金电极或银电极。The substrate 10 may be a Si-doped n-GaAs (100) substrate. The buffer layer 20 may be an n-GaAs buffer layer, and its thickness may be set to 300 nm. The first confinement layer 30 may be set to n-Al 0.4 Ga 0.6 As, and its thickness may be set to 1400 nm. The first waveguide layer 40 may be set to i-GaAs, and its thickness may be set to 70 nm. The second waveguide layer 60 may be configured as i-GaAs, and its thickness may be configured as 40 nm. The second confinement layer 70 may be set to p-Al 0.4 Ga 0.6 As, and its thickness may be set to 1400 nm. The ohmic contact layer 80 may be set to GaAs, and its thickness may be set to 200 nm. The first electrode 91 and the second electrode 92 provided at both ends may be provided as gold electrodes or silver electrodes.
所述有源层50包括:量子点堆叠层51和量子阱层52。The active layer 50 includes: a quantum dot stack layer 51 and a quantum well layer 52 .
所述量子点堆叠层51包括:n组量子点单元510,每一组所述量子点单元510包括自下而上层叠设置的量子点单层511、覆盖层512和间隔层513。The quantum dot stack layer 51 includes: n groups of quantum dot units 510. Each group of the quantum dot units 510 includes a quantum dot single layer 511, a covering layer 512 and a spacer layer 513 stacked from bottom to top.
所述量子阱层52的材料为InxGa(1-x)As,其中,0.22≤x≤0.38。The material of the quantum well layer 52 is In x Ga (1-x) As, where 0.22≤x≤0.38.
所述量子阱层52的发光峰的位置在所述量子点堆叠层51的基态发光峰和激发态发光峰之间。The position of the luminescence peak of the quantum well layer 52 is between the ground state luminescence peak and the excited state luminescence peak of the quantum dot stack layer 51 .
本实施例中,采用量子点和量子阱的混合有源层结构形成所述超辐射发光二极管。量子阱层52的材料为InxGa(1-x)As,其中In的组分在0.22至0.38之间,使得其量子阱层52发光峰位于所述量子点堆叠层51的基态发光峰和激发态发光峰之间。按照本实施例中有源层的结构设置,可以基于目前量子点基态+激发态较宽发光峰的前提下,采用量子阱层补偿量子点基态发光峰和激发态发光峰之间的dip,将所述超辐射发光二极管100的发光峰调整为类高斯分布(如图3中量子阱+量子点所示意的曲线为拓宽发光峰之后的类高斯分布)。采用本申请提供的方案,解决了传统量子点超辐射发光二极管由于基态、激发态发光导致光谱dip过深,影响OCT成像效果的问题。In this embodiment, a mixed active layer structure of quantum dots and quantum wells is used to form the superluminescent diode. The quantum well layer 52 is made of In between the excited state luminescence peaks. According to the structural setting of the active layer in this embodiment, based on the current broad luminescence peak of the quantum dot's ground state + excited state, the quantum well layer can be used to compensate for the dip between the quantum dot's ground state luminescence peak and the excited state luminescence peak. The luminescence peak of the superluminescent diode 100 is adjusted to a Gaussian-like distribution (the curve represented by quantum wells + quantum dots in Figure 3 is a Gaussian-like distribution after broadening the luminescence peak). The solution provided by this application solves the problem of traditional quantum dot superradiant light-emitting diodes that cause the spectrum dip to be too deep due to the ground state and excited state light emission, affecting the OCT imaging effect.
在一个实施例中,所述量子点单层511的材料为InAs,厚度为2.2-3ML;所述覆盖层512的材料为InGaAs,厚度为3-7nm,比如可以为4nm或者4.5nm。所述间隔层513的材料为GaAs,厚度为30-40nm,比如可以为32nm、35nm、38nm或者40nm。所述n的取值范围为:5≤n≤8,比如n可以为5、6、7或8。In one embodiment, the quantum dot single layer 511 is made of InAs with a thickness of 2.2-3 ML; the covering layer 512 is made of InGaAs with a thickness of 3-7 nm, such as 4 nm or 4.5 nm. The spacer layer 513 is made of GaAs and has a thickness of 30-40 nm, such as 32 nm, 35 nm, 38 nm or 40 nm. The value range of n is: 5≤n≤8, for example, n can be 5, 6, 7 or 8.
在一个实施例中,所述量子阱层52位于所述量子点堆叠层51和所述第二波导层60之间。即,所述量子阱层52位于所述量子点堆叠层51的上方,所述量子阱层52更靠近所述第二波导层60设置。所述量子阱层52的厚度为5-9nm,比如可以是5nm、6.5nm、7nm、8nm、8.5nm或9nm。In one embodiment, the quantum well layer 52 is located between the quantum dot stack layer 51 and the second waveguide layer 60 . That is, the quantum well layer 52 is located above the quantum dot stack layer 51 , and the quantum well layer 52 is disposed closer to the second waveguide layer 60 . The thickness of the quantum well layer 52 is 5-9 nm, for example, it can be 5 nm, 6.5 nm, 7 nm, 8 nm, 8.5 nm or 9 nm.
本实施例中,所述量子阱层52位于量子点堆叠层51的上方,能够有利于量子阱层52和量子点堆叠层51发光效率的平衡。因为,量子点堆叠层51的增益更容易增益饱和,注入载流子能够有效分布于量子阱层52和量子点堆叠层51中。本实施例中,将量子阱层52位于量子点堆叠层51的上方,可以保证注入载流子不容易被量子阱层钳制,从而使得超辐射发光二极管的发光效率更加均衡。In this embodiment, the quantum well layer 52 is located above the quantum dot stack layer 51, which can be beneficial to the balance of the luminous efficiency of the quantum well layer 52 and the quantum dot stack layer 51. Because the gain of the quantum dot stack layer 51 is easier to gain saturation, the injected carriers can be effectively distributed in the quantum well layer 52 and the quantum dot stack layer 51 . In this embodiment, locating the quantum well layer 52 above the quantum dot stack layer 51 can ensure that the injected carriers are not easily clamped by the quantum well layer, thereby making the luminous efficiency of the superluminescent diode more balanced.
一个实施例中,可以设置厚度为6nm、In组分为0.38的InGaAs量子阱层52,并且所述量子阱层52位于所述量子点堆叠层51的上方。按照本实施例中所述有源层50的结构设置,一方面,所述有源层50包括所述量子点堆叠层51和所述量子阱层52,可以在保证有较宽发光峰的前提下,采用厚度为6nm、In组分为0.38的InGaAs量子阱层52补偿量子点基态发光峰和激发态发光峰之间的发光峰dip,将所述超辐射发光二极管100的发光峰调整为类高斯分布,解决了传统量子点超辐射发光二极管由于基态、激发态发光导致光谱dip过深,影响OCT成像效果的问题。另一方面,所述量子阱层52位于量子点堆叠层的上方,更有利于量子点堆叠层中失效量子点和量子阱层发光效率的均衡。In one embodiment, an InGaAs quantum well layer 52 with a thickness of 6 nm and an In composition of 0.38 may be provided, and the quantum well layer 52 is located above the quantum dot stack layer 51 . According to the structural arrangement of the active layer 50 in this embodiment, on the one hand, the active layer 50 includes the quantum dot stack layer 51 and the quantum well layer 52, which can ensure a wide luminescence peak. Below, an InGaAs quantum well layer 52 with a thickness of 6 nm and an In composition of 0.38 is used to compensate the luminescence peak dip between the quantum dot's ground state luminescence peak and the excited state luminescence peak, and the luminescence peak of the superluminescent diode 100 is adjusted to be Gaussian-like. Distribution, solves the problem of traditional quantum dot superluminescent diodes that cause the spectrum dip to be too deep due to ground state and excited state emission, affecting the OCT imaging effect. On the other hand, the quantum well layer 52 is located above the quantum dot stack layer, which is more conducive to balancing the luminous efficiency of the failed quantum dots and the quantum well layer in the quantum dot stack layer.
在一个实施例中,所述量子点单层511的厚度为2.7ML,所述覆盖层512的厚度为5nm,所述间隔层513的厚度为35nm,所述n的取值范围为:n=5。所述量子阱层52为In0.38Ga0.62As,所述量子阱层52的厚度为5nm。本实施例中,所述量子点堆叠层的基态发光峰位于1.3μm,所述量子点堆叠层的激发态发光峰位于1.22μm,所述量子阱层的发光峰位于1.25μm。In one embodiment, the thickness of the quantum dot single layer 511 is 2.7ML, the thickness of the covering layer 512 is 5nm, the thickness of the spacer layer 513 is 35nm, and the value range of n is: n= 5. The quantum well layer 52 is In 0.38 Ga 0.62 As, and the thickness of the quantum well layer 52 is 5 nm. In this embodiment, the ground state luminescence peak of the quantum dot stack layer is located at 1.3 μm, the excited state luminescence peak of the quantum dot stack layer is located at 1.22 μm, and the luminescence peak of the quantum well layer is located at 1.25 μm.
在另一个实施例中,所述量子点单层511的厚度为2.3ML,所述覆盖层512的厚度为4nm,所述间隔层513的厚度为40nm,所述n的取值范围为:n=5,所述量子阱层52为In0.35Ga0.65As,所述量子阱层52的厚度为5nm。本实施例中,所述量子点堆叠层51的基态发光峰位于1.25μm,所述量子点堆叠层51的激发态发光峰位于1.1μm,所述量子阱层52的发光峰位于1.18μm。In another embodiment, the thickness of the quantum dot single layer 511 is 2.3ML, the thickness of the covering layer 512 is 4nm, the thickness of the spacer layer 513 is 40nm, and the value range of n is: n =5, the quantum well layer 52 is In 0.35 Ga 0.65 As, and the thickness of the quantum well layer 52 is 5 nm. In this embodiment, the ground state luminescence peak of the quantum dot stack layer 51 is located at 1.25 μm, the excited state luminescence peak of the quantum dot stack layer 51 is located at 1.1 μm, and the luminescence peak of the quantum well layer 52 is located at 1.18 μm.
以下列举四个不同的实施例,均能实现在适当拓宽光谱宽度的同时,消除不同发光峰之间的dip过大的问题,将所述超辐射发光二极管100的发光峰调整为类高斯分布,以使得超辐射发光二极管100应用于OCT成像系统时,能够消除成像鬼影。Four different embodiments are listed below, all of which can appropriately broaden the spectral width while eliminating the problem of excessive dip between different luminescence peaks, and adjust the luminescence peak of the superradiant light-emitting diode 100 to a Gaussian-like distribution, so as to This enables the superluminescent diode 100 to eliminate imaging ghosts when used in an OCT imaging system.
第一实施例:First embodiment:
按照如图2所示设置所述超辐射发光二极管100包括自下而上层叠设置的衬底10、缓冲层20、第一限制层30、第一波导层40、有源层50、第二波导层60、第二限制层70、欧姆接触层80,以及设置在两端的第一电极91和第二电极92。The superluminescent diode 100 is arranged as shown in FIG. 2 and includes a substrate 10, a buffer layer 20, a first confinement layer 30, a first waveguide layer 40, an active layer 50, and a second waveguide stacked from bottom to top. layer 60, the second confinement layer 70, the ohmic contact layer 80, and the first electrode 91 and the second electrode 92 provided at both ends.
所述有源层50包括:量子点堆叠层51和量子阱层52。量子阱层52位于量子点堆叠层51和第二波导层60之间。The active layer 50 includes: a quantum dot stack layer 51 and a quantum well layer 52 . The quantum well layer 52 is located between the quantum dot stack layer 51 and the second waveguide layer 60 .
所述量子点堆叠层51包括:5组量子点单元510,每一组所述量子点单元510包括自下而上层叠设置的2.7ML的InAs量子点单层511、5nm的InGaAs覆盖层512和35nm的GaAs间隔层513。The quantum dot stack layer 51 includes: 5 groups of quantum dot units 510. Each group of the quantum dot units 510 includes a 2.7ML InAs quantum dot single layer 511, a 5nm InGaAs covering layer 512 and a 2.7ML InAs quantum dot single layer 511 stacked from bottom to top. 35nm GaAs spacer layer 513.
所述量子阱层52的材料为In0.38Ga0.62As,厚度为5nm。所述量子阱层52位于量子点堆叠层51的上方,更有利于失效量子点和量子阱发光效率的均衡。所述量子阱层52的发光峰(1.25μm)的位置在所述量子点堆叠层51的基态发光峰(1.3μm)和激发态发光峰(1.22μm)之间。The quantum well layer 52 is made of In 0.38 Ga 0.62 As and has a thickness of 5 nm. The quantum well layer 52 is located above the quantum dot stack layer 51, which is more conducive to balancing the luminous efficiency of failed quantum dots and quantum wells. The position of the luminescence peak (1.25 μm) of the quantum well layer 52 is between the ground state luminescence peak (1.3 μm) and the excited state luminescence peak (1.22 μm) of the quantum dot stack layer 51 .
第二实施例:Second embodiment:
按照如图2所示设置所述超辐射发光二极管100包括自下而上层叠设置的衬底10、缓冲层20、第一限制层30、第一波导层40、有源层50、第二波导层60、第二限制层70、欧姆接触层80,以及设置在两端的第一电极91和第二电极92。The superluminescent diode 100 is arranged as shown in FIG. 2 and includes a substrate 10, a buffer layer 20, a first confinement layer 30, a first waveguide layer 40, an active layer 50, and a second waveguide stacked from bottom to top. layer 60, the second confinement layer 70, the ohmic contact layer 80, and the first electrode 91 and the second electrode 92 provided at both ends.
所述有源层50包括:量子点堆叠层51和量子阱层52。量子阱层52位于量子点堆叠层51和第二波导层60之间。The active layer 50 includes: a quantum dot stack layer 51 and a quantum well layer 52 . The quantum well layer 52 is located between the quantum dot stack layer 51 and the second waveguide layer 60 .
所述量子点堆叠层51包括:6组量子点单元510,每一组所述量子点单元510包括自下而上层叠设置的InAs量子点单层511、4nm的InGaAs覆盖层512和35nm的GaAs间隔层513。其中,6组量子点单元510中的单数组量子点单元510中的InAs量子点单层511的厚度为2.4ML。6组量子点单元510中的复数组量子点单元510中的InAs量子点单层511的厚度为3ML。所述量子点堆叠层51采用上述啁啾量子点堆叠层结构的设计,能够充分利用量子点宽光谱的特性,更好的实现光谱的拓宽,再配合量子阱层的特殊化设计,进而能够避免量子点发光峰的dip问题,实现无dip的更宽光谱输出。The quantum dot stack layer 51 includes: 6 groups of quantum dot units 510. Each group of the quantum dot units 510 includes an InAs quantum dot single layer 511, a 4 nm InGaAs covering layer 512 and a 35 nm GaAs stacked from bottom to top. Spacer layer 513. Among them, the thickness of the InAs quantum dot single layer 511 in a single group of quantum dot units 510 among the six groups of quantum dot units 510 is 2.4ML. The thickness of the InAs quantum dot single layer 511 in the plural groups of quantum dot units 510 in the six groups of quantum dot units 510 is 3ML. The quantum dot stacked layer 51 adopts the design of the chirped quantum dot stacked layer structure, which can fully utilize the wide spectrum characteristics of quantum dots and better realize the broadening of the spectrum. Coupled with the special design of the quantum well layer, it can avoid Dip problem of quantum dot luminescence peak, achieving wider spectrum output without dip.
所述量子阱层52的材料为In0.38Ga0.62As,厚度为5nm。所述量子阱层52的发光峰(1.25μm)的位置在所述量子点堆叠层51的基态发光峰(1.3μm)和激发态发光峰(1.22μm)之间。The quantum well layer 52 is made of In 0.38 Ga 0.62 As and has a thickness of 5 nm. The position of the luminescence peak (1.25 μm) of the quantum well layer 52 is between the ground state luminescence peak (1.3 μm) and the excited state luminescence peak (1.22 μm) of the quantum dot stack layer 51 .
如图4所示,在上述第一实施例和第二实施例中,虽然所述量子点堆叠层51的部分结构、材料或厚度发生微小的变化,但是所述量子点堆叠层51的基态发光峰均位于1.3μm,所述量子点堆叠层51的激发态发光峰均位于1.22μm,所述量子阱层52的发光峰均位于1.25μm。上述第一实施例和第二实施例均可以消除量子点基态发光峰和第一激发态发光峰之间的dip,将所述超辐射发光二极管100的发光峰调整为类高斯分布。As shown in FIG. 4 , in the above-mentioned first and second embodiments, although the partial structure, material or thickness of the quantum dot stack layer 51 undergoes slight changes, the ground state luminescence of the quantum dot stack layer 51 still remains. The peaks are all located at 1.3 μm, the excited state luminescence peaks of the quantum dot stack layer 51 are all located at 1.22 μm, and the luminescence peaks of the quantum well layer 52 are all located at 1.25 μm. Both the first and second embodiments described above can eliminate the dip between the quantum dot's ground state luminescence peak and the first excited state luminescence peak, and adjust the luminescence peak of the superluminescent diode 100 to a Gaussian-like distribution.
第三实施例:Third embodiment:
按照如图2所示设置所述超辐射发光二极管100包括自下而上层叠设置的衬底10、缓冲层20、第一限制层30、第一波导层40、有源层50、第二波导层60、第二限制层70、欧姆接触层80,以及设置在两端的第一电极91和第二电极92。The superluminescent diode 100 is arranged as shown in FIG. 2 and includes a substrate 10, a buffer layer 20, a first confinement layer 30, a first waveguide layer 40, an active layer 50, and a second waveguide stacked from bottom to top. layer 60, the second confinement layer 70, the ohmic contact layer 80, and the first electrode 91 and the second electrode 92 provided at both ends.
所述有源层50包括:量子点堆叠层51和量子阱层52。量子阱层52位于量子点堆叠层51和第二波导层60之间。The active layer 50 includes: a quantum dot stack layer 51 and a quantum well layer 52 . The quantum well layer 52 is located between the quantum dot stack layer 51 and the second waveguide layer 60 .
所述量子点堆叠层51包括:5组量子点单元510,每一组所述量子点单元510包括自下而上层叠设置的InAs量子点单层511、4nm的InGaAs覆盖层512和35nm的GaAs间隔层513。其中,5组量子点单元510中自下而上的InAs量子点单层511的厚度分别为2.2ML、2.3ML、2.35ML、2.4ML、2.45ML。所述量子点堆叠层51采用上述啁啾量子点堆叠层结构的设计,能够充分利用量子点宽光谱的特性,更好的实现光谱的拓宽,再配合量子阱层的特殊化设计,进而能够避免量子点发光峰的dip问题,实现无dip的更宽光谱输出。The quantum dot stack layer 51 includes: 5 groups of quantum dot units 510. Each group of the quantum dot units 510 includes an InAs quantum dot single layer 511, a 4 nm InGaAs covering layer 512 and a 35 nm GaAs stacked from bottom to top. Spacer layer 513. Among them, the thicknesses of the InAs quantum dot single layer 511 from bottom to top in the five groups of quantum dot units 510 are 2.2ML, 2.3ML, 2.35ML, 2.4ML, and 2.45ML respectively. The quantum dot stacked layer 51 adopts the design of the chirped quantum dot stacked layer structure, which can fully utilize the wide spectrum characteristics of quantum dots and better realize the broadening of the spectrum. Coupled with the special design of the quantum well layer, it can avoid Dip problem of quantum dot luminescence peak, achieving wider spectrum output without dip.
所述量子阱层52的材料为In0.35Ga0.65As,厚度为5nm。所述量子阱层52位于量子点堆叠层51的上方,更有利于失效量子点和量子阱发光效率的均衡。所述量子阱层52的发光峰(1.18μm)的位置在所述量子点堆叠层51的基态发光峰(1.25μm)和激发态发光峰(1.1μm)之间。The material of the quantum well layer 52 is In 0.35 Ga 0.65 As, and the thickness is 5 nm. The quantum well layer 52 is located above the quantum dot stack layer 51, which is more conducive to balancing the luminous efficiency of failed quantum dots and quantum wells. The position of the luminescence peak (1.18 μm) of the quantum well layer 52 is between the ground state luminescence peak (1.25 μm) and the excited state luminescence peak (1.1 μm) of the quantum dot stack layer 51 .
第四实施例:Fourth embodiment:
按照如图2所示设置所述超辐射发光二极管100包括自下而上层叠设置的衬底10、缓冲层20、第一限制层30、第一波导层40、有源层50、第二波导层60、第二限制层70、欧姆接触层80,以及设置在两端的第一电极91和第二电极92。The superluminescent diode 100 is arranged as shown in FIG. 2 and includes a substrate 10, a buffer layer 20, a first confinement layer 30, a first waveguide layer 40, an active layer 50, and a second waveguide stacked from bottom to top. layer 60, the second confinement layer 70, the ohmic contact layer 80, and the first electrode 91 and the second electrode 92 provided at both ends.
所述有源层50包括:量子点堆叠层51和量子阱层52。量子阱层52位于量子点堆叠层51和第二波导层60之间。The active layer 50 includes: a quantum dot stack layer 51 and a quantum well layer 52 . The quantum well layer 52 is located between the quantum dot stack layer 51 and the second waveguide layer 60 .
所述量子点堆叠层51包括:6组量子点单元510,每一组所述量子点单元510包括自下而上层叠设置的InAs量子点单层511、6nm的InGaAs覆盖层512和40nm的GaAs间隔层513。其中,6组量子点单元510中自下而上的InAs量子点单层511的厚度分别为2.3ML、2.3ML、2.4ML、2.4ML、2.5ML、2.5ML。所述量子点堆叠层51采用上述啁啾量子点堆叠层结构的设计,能够充分利用量子点宽光谱的特性,更好的实现光谱的拓宽,再配合量子阱层的特殊化设计,进而能够避免量子点发光峰的dip问题,实现无dip的更宽光谱输出。The quantum dot stack layer 51 includes: 6 groups of quantum dot units 510. Each group of the quantum dot units 510 includes an InAs quantum dot single layer 511, a 6 nm InGaAs covering layer 512 and a 40 nm GaAs stacked from bottom to top. Spacer layer 513. Among them, the thicknesses of the InAs quantum dot single layer 511 from bottom to top in the six groups of quantum dot units 510 are 2.3ML, 2.3ML, 2.4ML, 2.4ML, 2.5ML, and 2.5ML respectively. The quantum dot stacked layer 51 adopts the design of the chirped quantum dot stacked layer structure, which can fully utilize the wide spectrum characteristics of quantum dots and better realize the broadening of the spectrum. Coupled with the special design of the quantum well layer, it can avoid Dip problem of quantum dot luminescence peak, achieving wider spectrum output without dip.
所述量子阱层52的材料为In0.35Ga0.65As,厚度为6nm。所述量子阱层52的发光峰(1.18μm)的位置在所述量子点堆叠层51的基态发光峰(1.25μm)和激发态发光峰(1.1μm)之间。The material of the quantum well layer 52 is In 0.35 Ga 0.65 As, and the thickness is 6 nm. The position of the luminescence peak (1.18 μm) of the quantum well layer 52 is between the ground state luminescence peak (1.25 μm) and the excited state luminescence peak (1.1 μm) of the quantum dot stack layer 51 .
如图4所示,在上述第三实施例和第四实施例中,虽然所述量子点堆叠层51的部分结构、材料或厚度发生微小的变化,但是所述量子点堆叠层51的基态发光峰均位于1.25μm,所述量子点堆叠层51的激发态发光峰均位于1.1μm,所述量子阱层52的发光峰均位于1.18μm。上述第三实施例和第四实施例均可以消除量子点基态发光峰和第一激发态发光峰之间的dip,将所述超辐射发光二极管100的发光峰调整为类高斯分布。As shown in FIG. 4 , in the above third and fourth embodiments, although the partial structure, material or thickness of the quantum dot stack layer 51 undergoes slight changes, the ground state luminescence of the quantum dot stack layer 51 still remains. The peaks are all located at 1.25 μm, the excited state luminescence peaks of the quantum dot stack layer 51 are all located at 1.1 μm, and the luminescence peaks of the quantum well layer 52 are all located at 1.18 μm. Both the third embodiment and the fourth embodiment described above can eliminate the dip between the quantum dot's ground state luminescence peak and the first excited state luminescence peak, and adjust the luminescence peak of the superluminescent diode 100 to a Gaussian-like distribution.
以上所述仅为本申请的优选实施例而已,并不用于限制本申请,对于本领域的技术人员来说,本申请可以有各种更改和变化。凡在本申请的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本申请的保护范围之内。应注意到:相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步定义和解释。The above descriptions are only preferred embodiments of the present application and are not intended to limit the present application. For those skilled in the art, the present application may have various modifications and changes. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of this application shall be included in the protection scope of this application. It should be noted that similar reference numerals and letters represent similar items in the following figures, therefore, once an item is defined in one figure, it does not need further definition and explanation in subsequent figures.
以上所述,仅为本申请的具体实施方式,但本申请的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本申请揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本申请的保护范围之内。因此,本申请的保护范围应所述以权利要求的保护范围为准。The above are only specific embodiments of the present application, but the protection scope of the present application is not limited thereto. Any person familiar with the technical field can easily think of changes or substitutions within the technical scope disclosed in the present application. should be covered by the protection scope of this application. Therefore, the protection scope of this application should be determined by the protection scope of the claims.
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