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CN117085468A - Energy-saving marine carbon capture system - Google Patents

Energy-saving marine carbon capture system Download PDF

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Publication number
CN117085468A
CN117085468A CN202311353061.1A CN202311353061A CN117085468A CN 117085468 A CN117085468 A CN 117085468A CN 202311353061 A CN202311353061 A CN 202311353061A CN 117085468 A CN117085468 A CN 117085468A
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CN
China
Prior art keywords
liquid
desorption
way valve
tower
capture system
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Granted
Application number
CN202311353061.1A
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Chinese (zh)
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CN117085468B (en
Inventor
魏颖
薛宇
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Zhongtaihai Carbon Shanghai Environmental Protection Technology Co ltd
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Zhongtaihai Carbon Shanghai Environmental Protection Technology Co ltd
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Priority to CN202311353061.1A priority Critical patent/CN117085468B/en
Publication of CN117085468A publication Critical patent/CN117085468A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1412Controlling the absorption process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425Regeneration of liquid absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1475Removing carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493Selection of liquid materials for use as absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20Organic absorbents
    • B01D2252/204Amines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

The invention discloses an energy-saving marine carbon capture system, which comprises: the device comprises an absorption tower, a desorption tower, a first heat exchanger, a cooler, a plurality of pipelines and pumps; the flue gas exhausted by the main engine and/or the auxiliary engine of the ship is led to the absorption tower; the amine liquid of the absorption tower absorbs the flue gas to form rich liquid; the rich liquid passes through a cylinder sleeve of the main engine and/or the auxiliary engine and is used as a cylinder sleeve cooling medium to exchange heat with the cylinder sleeve, and then enters the desorption tower for desorption to form lean liquid; before entering cylinder sleeves of the main engine and/or the auxiliary engine, the rich liquid exchanges heat with the lean liquid through a first heat exchanger; the lean solution sequentially passes through the first heat exchanger and the cooler from the desorption tower and finally returns to the absorption tower. According to the invention, the amine liquid is used as a cylinder liner cooling medium to directly absorb the heat of the cylinder liner, and the heat energy generated by the main engine and/or the auxiliary engine is utilized to carry out desorption, so that the limited energy on the ship is utilized to the maximum extent, and the energy is saved.

Description

Energy-saving marine carbon capture system
Technical Field
The invention relates to the technical field of ship engineering, in particular to an energy-saving type carbon capture system for a ship.
Background
Along with environmental deterioration, energy conservation and emission reduction in various fields have become a trend. In the aspect of ships, carbon capture systems are also gradually started to absorb, seal and utilize carbon dioxide discharged by main engines and auxiliary engines of the ships.
The marine carbon capture system comprises an absorption tower and a desorption tower. In most cases, the absorption and desorption of carbon dioxide are carried out by using an amine liquid as a medium. Because the absorption and desorption temperatures of the amine liquid for carbon dioxide are different, the existing marine carbon capture system needs to continuously heat and cool the amine liquid, the energy consumption is additionally increased in the heating process, and the emission of pollutants is further increased.
Disclosure of Invention
The invention aims to reduce the energy consumption of a marine carbon capture system and further realize the energy conservation and emission reduction of a ship.
In order to achieve the above object, the present invention provides an energy-saving type carbon capture system for a ship, comprising: the device comprises an absorption tower, a desorption tower, a first heat exchanger, a cooler, a plurality of pipelines and pumps;
the flue gas exhausted by the main engine and/or the auxiliary engine of the ship is led to the absorption tower; the amine liquid of the absorption tower absorbs the flue gas to form rich liquid; the rich liquid passes through a cylinder sleeve of the main engine and/or the auxiliary engine and is used as a cylinder sleeve cooling medium to exchange heat with the cylinder sleeve, and then enters the desorption tower for desorption to form lean liquid;
before entering cylinder sleeves of the main engine and/or the auxiliary engine, the rich liquid exchanges heat with the lean liquid through a first heat exchanger; the lean solution sequentially passes through the first heat exchanger and the cooler from the desorption tower and finally returns to the absorption tower.
Preferably, the rich liquid is split into a stream for cooling the turbine end of the main machine.
Optionally, the system is further provided with a first three-way valve and a second heat exchanger; after the rich liquid exchanges heat with the cylinder sleeve, the first three-way valve divides the rich liquid into two streams, and one stream enters the second heat exchanger to exchange heat with the flue gas again; and the two rich solutions are combined and then enter a desorption tower.
Preferably, before absorbing the flue gas, the ph=7 to 9 of the amine solution before absorbing the flue gas.
Preferably, the surface of the cylinder sleeve is covered with a protective layer.
Further, the protective layer is a metal plating layer, and the metal is at least one of chromium, cobalt and nickel.
Preferably, the gas obtained after desorption in the desorption tower sequentially enters the compression equipment, the liquefaction equipment and the liquid carbon dioxide storage tank.
The beneficial effects of the invention include:
according to the invention, the amine liquid is used as a cylinder sleeve cooling medium to directly absorb the heat of the cylinder sleeve, so that limited energy on a ship is utilized to the maximum extent, and energy is saved.
According to the invention, through setting the alkalinity of the amine liquid and the material of the cylinder sleeve, the condition that the amine liquid corrodes the cylinder sleeve is reduced to the greatest extent.
According to the invention, the first three-way valve and the second heat exchanger are arranged, so that on one hand, the heat of the flue gas is further utilized, and on the other hand, the heat absorbed by the amine liquid of the carbon capture system is regulated, so that the complex working conditions possibly occurring on the ship are dealt with.
According to the invention, the second three-way valve, the third three-way valve and the corresponding connecting pipelines are arranged, so that the carbon trapping system can be stably started and stopped.
Drawings
FIG. 1 is a schematic diagram of an energy efficient marine carbon capture system of the present invention.
Reference numerals: 1-a main engine cylinder sleeve; 2-auxiliary engine cylinder sleeve; 3-an absorption tower; 4-a first heat exchanger; 5-a desorption tower; a 6-cooler; 7-rich stream; 8-lean liquid stream; 9-flue gas stream; 10-a host computer flattening end; 11-a second heat exchanger; 12-a first three-way valve; 13-a second three-way valve; 14-a third three-way valve.
Detailed Description
The following description of the embodiments of the present invention will be made apparent and fully in view of the accompanying drawings, in which some, but not all embodiments of the invention are shown. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
In the description of the present invention, it should be noted that the directions or positional relationships indicated by the terms "upper", "lower", "front", "rear", "inner", "outer", "top", "bottom", etc. are based on the directions or positional relationships shown in fig. 1, are merely for convenience of describing the present invention and simplifying the description, and do not indicate or imply that the devices or elements to be referred to must have a specific orientation, be configured and operated in a specific orientation, and thus should not be construed as limiting the present invention.
Furthermore, the terms "first," "second," and the like, are used for descriptive purposes only and are not intended to be limiting with respect to time sequence, number, or importance, but are not to be construed as indicating or implying a relative importance or implicitly indicating the number of features indicated, but merely for distinguishing one feature from another in the present disclosure. Thus, a feature defining "a first" or "a second" may explicitly or implicitly include one or more such feature. In the description of the present invention, the meaning of "a plurality" is two or more, unless explicitly specified otherwise. Likewise, the appearances of the phrase "a" or "an" in this document are not meant to be limiting, but rather describing features that have not been apparent from the foregoing. Likewise, unless a particular quantity of a noun is to be construed as encompassing both the singular and the plural, both the singular and the plural may be included in this disclosure. Likewise, modifiers similar to "about" and "approximately" appearing before a number in this document generally include the number, and their specific meaning should be understood in conjunction with the context.
In the description of the present invention, it should be noted that, unless explicitly specified and limited otherwise, the terms "mounted," "connected," and "connected" are to be construed broadly, and may be either fixedly connected, detachably connected, or integrally connected, for example; may be a mechanical connection; can be directly connected or indirectly connected through an intermediate medium, and can be communication between two elements. The specific meaning of the above terms in the present invention will be understood in specific cases by those of ordinary skill in the art.
Each aspect or embodiment defined herein may be combined with any other aspect or embodiment unless clearly indicated to the contrary. In particular, any feature indicated as being preferred or advantageous may be combined with any other feature or features indicated as being preferred or advantageous.
The invention discloses an energy-saving marine carbon capture system, as shown in figure 1, comprising: absorption tower 3, desorption tower 5, first heat exchanger 4, cooler 6 and a plurality of pipelines and pumps. The main engine of the ship is used for providing power, the auxiliary engine is used for generating power for other equipment on the ship, and the main engine and the auxiliary engine are both diesel engines, so that a large amount of smoke is generated by the main engine cylinder sleeve 1 and the auxiliary engine cylinder sleeve 2, and especially the smoke generated by the main engine cylinder sleeve 1 is more, and the smoke forms a smoke stream 9. The flue gas is led to the absorption tower 3; the amine liquid in the absorption tower 3 absorbs carbon dioxide in the flue gas to form rich liquid; the residual gas is discharged from the top of the absorption tower 3; the rich liquid flow 7 passes through the main engine cylinder sleeve 1 and/or the auxiliary engine cylinder sleeve 2 and is heated to the temperature (about 80-125 ℃) required by desorption of carbon dioxide by the amine liquid after being used as a cylinder sleeve cooling medium to exchange heat with the cylinder sleeve, and then enters the desorption tower for desorption to form lean liquid. The rich liquid is used as a cylinder liner cooling medium for cooling the main engine cylinder liner 1 and the auxiliary engine cylinder liner 2, so that the heat of the cylinder liner is recycled, and the energy consumption of a carbon capture system is reduced.
Before entering the cylinder sleeve of the main engine and/or the auxiliary engine, the rich liquid firstly enters the first heat exchanger 4; the rich stream 7 and the lean stream 8 exchange heat within said first heat exchanger 4; the lean liquid sequentially passes through the first heat exchanger 4 and the cooler 6, and finally returns to the absorption tower 3. The first heat exchanger 4 may be used to achieve preheating of the rich liquid stream 7 and pre-cooling of the lean liquid stream 8, the cooler 6 being used to further cool the lean liquid to a temperature (about 10 c to 60 c) required for absorption of carbon dioxide by the amine liquid.
In some embodiments, the rich liquid may be split after being preheated by the first heat exchanger 4, and used for cooling the main machine leveling end 10. The rich liquid is recombined after cooling the main engine cylinder sleeve 1, the auxiliary engine cylinder sleeve 2 and the main engine flat end 10 respectively so as to utilize the heat of the main engine flat end 10.
In some embodiments, the carbon capture system further comprises a second heat exchanger 11, the second heat exchanger 11 is used for partially absorbing heat of the flue gas, and the rich liquid is heated for the third time, so that the temperature of the rich liquid is ensured to be heated to the desorption temperature. In the second heat exchanger 11, the inlet end of the rich liquid is communicated with the main engine cylinder sleeve 1 and/or the auxiliary engine cylinder sleeve 2 and the main engine horizontal end 10, and the outlet end is communicated with the desorption tower 5; the inlet end of the flue gas is communicated with the main engine cylinder sleeve 1 and/or the auxiliary engine cylinder sleeve 2, and the outlet end is communicated with the absorption tower 3.
Further, the carbon capturing system further comprises a first three-way valve 12, wherein the first three-way valve 12 divides the rich liquid flowing out of the cylinder sleeve into two streams, and one stream enters the second heat exchanger 11 to exchange heat with the flue gas again; the two rich liquids are combined and then enter a desorption tower 5. A flow control valve is also arranged on the pipeline where the second heat exchanger 11 is located so as to control the quantity of rich liquid exchanging heat with the flue gas, and the distribution proportion of the two rich liquids is adjusted so as to cope with the possibly occurring complex working conditions on the ship.
In some embodiments, the carbon capture system further comprises a second three-way valve 13 and a third three-way valve 14. The inlet and outlet of the absorption column 3 and the desorption column 5 also include control valves to control opening and closing. The lean solution enters the second three-way valve 13 before entering the absorption tower 3, and the rich solution enters the third three-way valve 14 before entering the desorption tower 5. One end of the second three-way valve 13 is communicated with the rich liquid outlet end of the absorption tower 3, one end of the third three-way valve 14 is communicated with the lean liquid outlet end of the desorption tower 5, one side of the second three-way valve 13, which is communicated with the rich liquid outlet end of the absorption tower 3, is closed under the condition that the carbon capturing system operates normally, and one side of the third three-way valve 14, which is communicated with the lean liquid outlet end of the desorption tower 5, is closed.
When the carbon capture system is in a starting state, the auxiliary machine is started in advance, and then a pump in the system is started, so that the amine liquid flows. At this time, the inlets and outlets of the absorption tower 3 and the desorption tower 5 are closed, and one side of the second three-way valve 13, which is communicated with the rich liquid outlet end of the absorption tower 3, is opened, and one side of the third three-way valve 14, which is communicated with the lean liquid outlet end of the desorption tower 5, is opened by adjusting the second three-way valve 13 and the third three-way valve 14; so that the amine liquid is circulated to the main engine cylinder sleeve 1 and the auxiliary engine cylinder sleeve 2 again without passing through the absorption tower 3 and the desorption tower 5. The cooler 6 also does not introduce cold streams and does not cool the amine liquid. The auxiliary cylinder sleeve 2 heats itself, and the continuous heating of the amine liquid is realized. The heat of the amine liquid can be transferred to the main engine cylinder sleeve 1, so that the main engine cylinder sleeve 1 is heated, after the main engine cylinder sleeve 1 is heated to a proper working temperature, the cooler 6 starts to introduce cold flow, and the amine liquid is cooled, so that the amine liquid is maintained in a temperature range suitable for the operation of the main engine cylinder sleeve 1. At this time, the operator may selectively adjust the second three-way valve 13 and the third three-way valve 14 such that one side of the second three-way valve 13, which communicates with the rich liquid outlet end of the absorption tower 3, is closed, one side of the third three-way valve 14, which communicates with the lean liquid outlet end of the desorption tower 5, is closed, and the control valves of the inlets and outlets of the absorption tower 3 and the desorption tower 5 are opened, so that carbon dioxide recovery is started.
When the carbon capturing system starts to stop, the host stops running, the inlets and outlets of the absorption tower 3 and the desorption tower 5 are closed, one side of the rich liquid outlet end of the absorption tower 3 is opened by the second three-way valve 13 which is communicated with the rich liquid outlet end of the absorption tower 3, and one side of the lean liquid outlet end of the desorption tower 5 is opened by the third three-way valve 14 which is communicated with the rich liquid outlet end of the desorption tower 5; so that the amine liquid is circulated to the main engine cylinder sleeve 1 and the auxiliary engine cylinder sleeve 2 again without passing through the absorption tower 3 and the desorption tower 5. After a certain period of time after the auxiliary machine is turned off, the cold flow to the cooler 6 is stopped and the pump in the carbon capture system is turned off.
In some embodiments, the ph=7 to 9 before the amine solution absorbs the flue gas by dilution because the metal is easily corroded under strong alkaline conditions. To reduce the corrosion of the amine liquid to the cylinder liner.
From the perspective of corrosion prevention, a protective layer can be covered on the surface of the cylinder sleeve. Further, the protective layer is a metal plating layer, and the metal is at least one of chromium, cobalt and nickel. The anti-corrosion effect can be further improved.
In some embodiments, the gas obtained after desorption in the desorption tower sequentially enters a compression device, a liquefaction device and a liquid carbon dioxide storage tank to finally finish capturing and storing carbon dioxide.
In summary, the invention takes the amine liquid as the cooling medium of the cylinder sleeve to directly absorb the heat of the cylinder sleeve, thereby utilizing the limited energy on the ship to the maximum extent and saving the energy. According to the invention, through setting the alkalinity of the amine liquid and the material of the cylinder sleeve, the condition that the amine liquid corrodes the cylinder sleeve is reduced to the greatest extent. According to the invention, the first three-way valve and the second heat exchanger are arranged, so that on one hand, the heat of the flue gas is further utilized, and on the other hand, the heat absorbed by the amine liquid of the carbon capture system is regulated, so that the complex working conditions possibly occurring on the ship are dealt with. According to the invention, the second three-way valve, the third three-way valve and the corresponding connecting pipelines are arranged, so that the carbon trapping system can be stably started and stopped.
While the present invention has been described in detail through the foregoing description of the preferred embodiment, it should be understood that the foregoing description is not to be considered as limiting the invention. Many modifications and substitutions of the present invention will become apparent to those of ordinary skill in the art upon reading the foregoing. Accordingly, the scope of the invention should be limited only by the attached claims.

Claims (8)

1. An energy efficient marine carbon capture system comprising: the device comprises an absorption tower, a desorption tower, a first heat exchanger, a cooler, a plurality of pipelines and pumps; it is characterized in that the method comprises the steps of,
the flue gas exhausted by the main engine and/or the auxiliary engine of the ship is led to the absorption tower; the amine liquid of the absorption tower absorbs the flue gas to form rich liquid; the rich liquid passes through a cylinder sleeve of the main engine and/or the auxiliary engine and is used as a cylinder sleeve cooling medium to exchange heat with the cylinder sleeve, and then enters the desorption tower for desorption to form lean liquid;
before entering cylinder sleeves of the main engine and/or the auxiliary engine, the rich liquid exchanges heat with the lean liquid through a first heat exchanger; the lean solution sequentially passes through the first heat exchanger and the cooler from the desorption tower and finally returns to the absorption tower.
2. The energy efficient marine carbon capture system of claim 1, wherein the rich liquid splits off into a stream for cooling a turbine end of the host machine.
3. The energy efficient marine carbon capture system of claim 1, further comprising a first three-way valve and a second heat exchanger; after the rich liquid exchanges heat with the cylinder sleeve, the first three-way valve divides the rich liquid into two streams, and one stream enters the second heat exchanger to exchange heat with the flue gas again; and the two rich solutions are mixed and then enter a desorption tower.
4. The energy-saving type marine carbon capture system according to claim 1, further comprising a second three-way valve and a third three-way valve; the lean solution enters the second three-way valve before entering the absorption tower, and the rich solution enters the third three-way valve before entering the desorption tower; one end of the second three-way valve is communicated with the rich liquid outlet end of the absorption tower, and one end of the third three-way valve is communicated with the lean liquid outlet end of the desorption tower.
5. The energy-efficient marine carbon capture system of claim 1, wherein the amine solution has a pH = 7-9 prior to absorption of the flue gas.
6. The energy efficient marine carbon capture system of claim 1, wherein the cylinder liner surface is covered with a protective layer.
7. The energy efficient marine carbon capture system according to claim 6, wherein the protective layer is a metal coating and the metal is at least one of chromium, cobalt, and nickel.
8. The energy-saving type carbon capture system for a ship according to claim 1, wherein the gas obtained after the desorption of the desorption tower sequentially enters a compression device, a liquefaction device and a liquid carbon dioxide storage tank.
CN202311353061.1A 2023-10-19 2023-10-19 Energy-saving marine carbon capture system Active CN117085468B (en)

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KR20170041531A (en) * 2015-10-07 2017-04-17 대우조선해양 주식회사 Carbon Dioxide Recovery System from Exhaust Gas of Engine on Ship and Method the Same
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CN111392019A (en) * 2020-03-27 2020-07-10 大连船舶重工集团有限公司 Clean ship power system who discharges
US20210046418A1 (en) * 2018-02-14 2021-02-18 Taminco Bvba Improved contaminant removal process
CN112833325A (en) * 2021-02-05 2021-05-25 青岛科技大学 Decarbonization system for LNG power ship by using cold energy of fuel
CN113623089A (en) * 2021-08-11 2021-11-09 中国船舶重工集团柴油机有限公司 Marine ammonia supply system and boats and ships
CN216935390U (en) * 2022-03-16 2022-07-12 陕西科技大学 A high temperature hot-blast furnace flue gas carbon dioxide entrapment system for waste heat recovery

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080307968A1 (en) * 2007-06-04 2008-12-18 Posco Apparatus and Method for Recovering Carbon Dioxide from Flue Gas Using Ammonia Water
JP2009214101A (en) * 2008-02-14 2009-09-24 Research Institute Of Innovative Technology For The Earth Carbon dioxide separating agent and method for selectively separating carbon dioxide
JP2010069435A (en) * 2008-09-19 2010-04-02 Taikisha Ltd Solvent recovering facility
KR20110114189A (en) * 2010-04-13 2011-10-19 한국전력공사 Carbon capture and storage system, and heat pump
US20150151248A1 (en) * 2012-05-15 2015-06-04 University Of Newcastle Upon Tyne Carbon capture
CN104826475A (en) * 2015-05-08 2015-08-12 大连海事大学 Ship exhaust gas mixed type desulfurization device and working method thereof
CN204952597U (en) * 2015-07-03 2016-01-13 中国华能集团清洁能源技术研究院有限公司 Extraction of rich solution self -driven divides congruence to tear palingenetic CO2 entrapment device
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US20210046418A1 (en) * 2018-02-14 2021-02-18 Taminco Bvba Improved contaminant removal process
CN111392019A (en) * 2020-03-27 2020-07-10 大连船舶重工集团有限公司 Clean ship power system who discharges
CN112833325A (en) * 2021-02-05 2021-05-25 青岛科技大学 Decarbonization system for LNG power ship by using cold energy of fuel
CN113623089A (en) * 2021-08-11 2021-11-09 中国船舶重工集团柴油机有限公司 Marine ammonia supply system and boats and ships
CN216935390U (en) * 2022-03-16 2022-07-12 陕西科技大学 A high temperature hot-blast furnace flue gas carbon dioxide entrapment system for waste heat recovery

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