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CN116750993A - Functional polyurethane exposed stone pavement and preparation method thereof - Google Patents

Functional polyurethane exposed stone pavement and preparation method thereof Download PDF

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Publication number
CN116750993A
CN116750993A CN202310688937.1A CN202310688937A CN116750993A CN 116750993 A CN116750993 A CN 116750993A CN 202310688937 A CN202310688937 A CN 202310688937A CN 116750993 A CN116750993 A CN 116750993A
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CN
China
Prior art keywords
aggregate
functional polyurethane
pavement
polyurethane
exposed stone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202310688937.1A
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Chinese (zh)
Inventor
徐剑
王杰
常嵘
王鹏
曾蔚
耿爽
黄伟
冯国利
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Research Institute of Highway Ministry of Transport
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Research Institute of Highway Ministry of Transport
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Filing date
Publication date
Application filed by Research Institute of Highway Ministry of Transport filed Critical Research Institute of Highway Ministry of Transport
Priority to CN202310688937.1A priority Critical patent/CN116750993A/en
Publication of CN116750993A publication Critical patent/CN116750993A/en
Pending legal-status Critical Current

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    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00Coherent pavings made in situ
    • E01C7/08Coherent pavings made in situ made of road-metal and binders
    • E01C7/30Coherent pavings made in situ made of road-metal and binders of road-metal and other binders, e.g. synthetic material, i.e. resin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/16Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/53After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete
    • C04B41/5323After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete to make grain visible, e.g. for obtaining exposed aggregate concrete
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/91After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics involving the removal of part of the materials of the treated articles, e.g. etching
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C19/00Machines, tools or auxiliary devices for preparing or distributing paving materials, for working the placed materials, or for forming, consolidating, or finishing the paving
    • E01C19/12Machines, tools or auxiliary devices for preparing or distributing paving materials, for working the placed materials, or for forming, consolidating, or finishing the paving for distributing granular or liquid materials
    • E01C19/18Devices for distributing road-metals mixed with binders, e.g. cement, bitumen, without consolidating or ironing effect
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C23/00Auxiliary devices or arrangements for constructing, repairing, reconditioning, or taking-up road or like surfaces
    • E01C23/06Devices or arrangements for working the finished surface; Devices for repairing or reconditioning the surface of damaged paving; Recycling in place or on the road
    • E01C23/08Devices or arrangements for working the finished surface; Devices for repairing or reconditioning the surface of damaged paving; Recycling in place or on the road for roughening or patterning; for removing the surface down to a predetermined depth high spots or material bonded to the surface, e.g. markings; for maintaining earth roads, clay courts or like surfaces by means of surface working tools, e.g. scarifiers, levelling blades
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00Coherent pavings made in situ
    • E01C7/08Coherent pavings made in situ made of road-metal and binders
    • E01C7/085Aggregate or filler materials therefor; Coloured reflecting or luminescent additives therefor
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mining & Mineral Resources (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Road Paving Structures (AREA)

Abstract

The application relates to the technical field of pavement construction, in particular to the field of IPC E01C7, and more particularly relates to a functional polyurethane exposed stone pavement and a preparation method thereof. The components comprise: cementing material, aggregate and surface flushing agent; the cement comprises polyurethane. The melting temperature of the polyurethane is 280-320 ℃, the tensile strength is 15-25MPa, the elongation at break is 180-300%, the bonding performance and the skid resistance can be improved, and meanwhile, the bonding effect with the original pavement structure and the underlying layer is excellent; the aggregate comprises a first aggregate and a second aggregate, wherein the particle size of the first aggregate is 3-9.5mm, the particle size of the second aggregate is 9.5-15mm, and the weight ratio of the first aggregate to the second aggregate is (2-4): (6-8) the strength, the anti-skid property and the high and low temperature property of the pavement can be further improved.

Description

Functional polyurethane exposed stone pavement and preparation method thereof
Technical Field
The application relates to the technical field of pavement construction, in particular to the field of IPC E01C7, and more particularly relates to a functional polyurethane exposed stone pavement and a preparation method thereof.
Background
In the construction process of the expressway, since the running speed of the vehicle is high, the expressway pavement is required to have excellent anti-slip and anti-dazzle functions, and the exposed stone concrete has excellent anti-slip, noise reduction, anti-dazzle and drainage functions. The existing preparation of the exposed stone concrete pavement comprises the following steps: after the cement concrete on the surface layer is poured and vibrated, a certain time is reserved, then a certain amount of stone exposing agent is sprayed on the surface of the cement concrete, the cement mortar on the surface layer is subjected to materialization treatment, and then the pavement is washed.
CN114835450a discloses a highway pavement high-performance exposed stone concrete and a construction method thereof. The raw materials comprise 126kg/m 3 Water of 370kg/m 3 Low heat portland cement of 703kg/m 3 River sand of which the grain diameter is not more than 2.36mm and 1251kg/m 3 Is a non-alkali activated crushed stone of 9.5-13.2mm and 9.25kg/m 3 The retarding type high-efficiency air-entraining water reducer ensures that the skid resistance and the noise reduction performance of the exposed concrete pavement are obviously improved.
CN111187044B discloses a exposed stone concrete and a construction method thereof, which comprises the following exposed stone concrete raw materials in parts by weight: 250-300 parts of cement, 1100-1200 parts of coarse aggregate, 750-850 parts of fine aggregate, 80-120 parts of mineral powder, 8-12 parts of water reducer and 140-180 parts of water; the construction method of the exposed stone concrete comprises the following steps: preparing a stone-exposing agent, preparing concrete, pouring a pavement and maintaining the pavement.
CN103232218B discloses a high-performance concrete stone remover and a preparation and application method thereof, the stone remover containing fluorosilicate and organic phosphorus is used for improving the retarding efficiency of the stone remover, reducing the dosage of the stone remover, being used for preparing the stone-removing concrete and improving the anti-slip and drainage properties of the stone-removing concrete. The fluorosilicate is not friendly to the environment, and brings a certain harm to the construction environment of the exposed stone concrete.
The cement is used as the cementing material, so that the cement concrete has light color and serious glare, and meanwhile, the construction process of the cement pavement is complex, and the flatness is controlled by vibrating, water collecting and plastering, so that the flatness directly relates to the effect of stone exposure. The concrete pavement has long life time and complex construction process. In addition, because the rigidity is high, the joint cutting is needed to avoid shrinkage cracks, so that the driving comfort is poor, and because the adhesion between the cement material and aggregate is poor, the phenomena of loosening, particle falling and the like are easy to occur after the cement material is molded.
Disclosure of Invention
The first aspect of the application provides a functional polyurethane exposed stone pavement, which comprises the following components: cementing material, aggregate and surface flushing agent.
The inventor researches find that the cementing material comprises polyurethane, wherein the melting temperature of the polyurethane is 280-320 ℃, the tensile strength of the polyurethane is 15-25MPa, the elongation at break is 180-300%, the cementing property and the anti-slip property can be improved, and the cementing material is especially characterized in that the cementing material comprises (2-4) of two weight ratios of 4.75-9.5mm of particle size and 9.5-13.2mm of particle size: the aggregate of (6-8) is compounded for use, the strength and the skid resistance of the pavement and the performance at high and low temperatures can be further improved, the two aggregates are compounded in proportion, the large-particle aggregate can play a role in skid resistance and skeleton support, the small-particle aggregate properly fills gaps, collapse caused by overlarge gaps is reduced, if the gaps are overlarge, the cementing material is difficult to adhere the aggregate, rainwater can enter the interior of a road structure more easily, the interface between the aggregate and the cementing material is stripped, so that serious water loss is generated on the pavement, the service life of the pavement is greatly reduced, the strength is reduced, meanwhile, the rigid skeleton formed by compounding the aggregates in a specific proportion limits the shrinkage effect of the cementing material, so that the performance of the pavement at high and low temperatures is improved, the dispersion performance of the pavement is improved, the dispersion time of the system is shortened, and the polyurethane possibly has extremely strong adhesive performance and can be matched with the acidic granite, so that the aggregate is well wrapped by the polyurethane. Meanwhile, the price of the acidic granite is low, and the general road aggregate has better performances of limestone and basalt, but the price is high.
The cementing material comprises polyurethane, wherein the melting temperature of the polyurethane is 280-320 ℃, the tensile strength of the polyurethane is 15-25MPa, and the elongation at break is 180-300%.
Preferably, the cementing material comprises single-component polyurethane, wherein the melting temperature of the polyurethane is 290-320 ℃, the tensile strength is 15-20MPa, and the elongation at break is 180-230%.
Further preferred, the cement comprises a one-component polyurethane having a melting temperature of 309.7 ℃, a tensile strength of 18.6MPa, an elongation at break of 210%, and a one-component polyurethane available from Wanhua chemical groups Co., ltd (test data reference: GB/T19250).
The aggregate comprises at least one of granite, basalt, meteoroid and limestone.
Preferably, the aggregate comprises acidic granite.
The aggregate comprises a first aggregate and a second aggregate, wherein the particle size of the first aggregate is 3-9.5mm, and the particle size of the second aggregate is 9.5-15mm.
Preferably, the aggregate comprises a first aggregate and a second aggregate, the first aggregate having a particle size of 4.75-9.5mm and the second aggregate having a particle size of 9.5-13.2mm.
The weight ratio of the first aggregate to the second aggregate is (2-4): (6-8).
Preferably, the weight ratio of the first aggregate to the second aggregate is 3:7.
the cementing material accounts for 2.5-6 weight percent of the aggregate.
Preferably, the binder comprises 4.8 weight percent of the aggregate.
The surface flushing agent comprises at least one of methyl ethyl ketone, acetone, ethyl acetate, dimethylacetamide and butyl acetate.
Preferably, the surface flushing agent comprises acetone and ethyl acetate, wherein the weight ratio of the acetone to the ethyl acetate is (13-15): (5-7).
Further preferably, the surface flushing agent comprises acetone and ethyl acetate, wherein the weight ratio of the acetone to the ethyl acetate is 7:3.
the application provides a preparation method of a functional polyurethane exposed stone pavement, which comprises the following steps:
s1, mixing cementing materials and aggregate, paving and rolling, and waiting for 3-5h for curing and forming;
s2, spraying a surface flushing agent on the surface of the solidified and formed product for soaking;
s3, cleaning by brushing to expose aggregate, and obtaining the modified asphalt.
The cementing material and the aggregate are mixed specifically comprising: the aggregate is dedusted and dried by a conveyor belt and then conveyed into a mixing pot, polyurethane is sprayed into the mixing pot for stirring for 2-3min, and the stirring speed is 60-70rpm.
Preferably, the cementing material and the aggregate mixture specifically comprise: the aggregate is dedusted and dried by a conveyor belt and then conveyed into a mixing pot, polyurethane is sprayed into the mixing pot for stirring for 3min, and the stirring speed is 60rpm.
The spraying amount is 0.12-0.20kg/m 2
Preferably, the amount of the spray is 0.15kg/m 2
The soaking time is 5-20min.
Preferably, the soaking time is 10min.
The depth of the exposed aggregate is 2-3.5mm.
Preferably, the depth of exposed aggregate is 2.5mm.
The thickness of the exposed stone pavement is 3.5-5cm.
Preferably, the thickness of the exposed stone pavement is 4cm.
The beneficial effects are that:
1. the cementing material comprises polyurethane, wherein the melting temperature of the polyurethane is 280-320 ℃, the tensile strength of the polyurethane is 15-25MPa, the elongation at break is 180-300%, the binding performance, the service life and the skid resistance can be improved, and meanwhile, the cementing material has excellent binding effect with the original pavement structure and the underlying layer.
2. The aggregate comprises a first aggregate and a second aggregate, wherein the particle size of the first aggregate is 3-9.5mm, the particle size of the second aggregate is 9.5-15mm, and the weight ratio of the first aggregate to the second aggregate is (2-4): (6-8) the strength, the anti-skid property and the high and low temperature property of the pavement can be further improved.
3. The spraying amount is 0.12-0.20kg/m 2 The soaking time is 5-20min, so that the pavement efficiency can be improved, and the anti-skid performance and the driving comfort can be improved. The flushing agent is insufficient in spraying quantity, cannot be soaked and dissolved to reach the proper dew Dan Shendu, the anti-slip performance is reduced, the soaking time is insufficient, the dissolving effect is insufficient, the surface is uneven, and the depth of the dew stone is insufficient.
4. The surface flushing agent comprises acetone and ethyl acetate, wherein the weight ratio of the acetone to the ethyl acetate is (13-15): (5-7), the reaction time can be reduced, the uniformity of the exposed stone surface can be improved, the depth of exposed aggregate can be controlled, and the water loss resistance and the fatigue life can be improved.
5. The acid aggregate granite and polyurethane are compounded for use, the thickness of the exposed stone pavement is 3.5-5cm, so that the pavement color is adjustable, the performance is designable, the construction process is simple, the service life is long, the maintenance period is long, the overall pavement structure is too low, the overall strength is reduced, and the construction is very easy to push due to the fact that the thickness of the structural layer is thinner.
6. The cementing material accounts for 2.5-6 weight percent of the aggregate, the strength and the high-low temperature performance can be improved, the dosage of the cementing material is too low, the surface of granite cannot be completely wrapped, and the particles of the aggregate are easy to loose due to insufficient dosage of the cementing material.
Detailed Description
Example 1
A functional polyurethane exposed stone pavement comprises the following components: cementing material, aggregate and surface flushing agent.
The cement was a one-component polyurethane having a melting temperature of 309.7 ℃and a tensile strength of 18.6MPa and an elongation at break of 210%, a one-component polyurethane available from Wanhua chemical group Co., ltd., model 6750F (test data reference: GB/T19250)
The aggregate is acid granite, the acid granite is a first aggregate and a second aggregate, the particle size of the first aggregate is 4.75-9.5mm, the particle size of the second aggregate is 9.5-13.2mm, and the weight ratio of the first aggregate to the second aggregate is 3:7.
the cementing material accounts for 4.8 weight percent of the aggregate.
The surface flushing agent is acetone and ethyl acetate, and the weight ratio of the acetone to the ethyl acetate is 7:3.
a preparation method of a functional polyurethane exposed stone pavement comprises the following steps:
s1, mixing cementing materials and aggregate, paving and rolling, and waiting for 4 hours for curing and forming;
s2, spraying a surface flushing agent on the surface of the solidified and formed product for soaking;
s3, cleaning by brushing to expose aggregate, and obtaining the modified asphalt.
The concrete steps of the cementing material and the aggregate are as follows: the aggregate is dedusted and dried by a conveyor belt and then conveyed into a mixing pot, polyurethane is sprayed into the mixing pot for stirring for 3min, and the stirring speed is 60rpm.
The amount of the spray was 0.15kg/m 2 The soaking time is 10min, and the depth of the exposed aggregate is 2.5mm.
The thickness of the exposed stone pavement is 4cm.
Comparative example 1
The detailed description is the same as example 1; except that in comparative example 1: the aggregate is acid granite, and the particle size of the acid granite is 9.5-13.2mm.
Comparative example 2
The detailed description is the same as example 1; except that in comparative example 2: the weight ratio of the acetone to the ethyl acetate is 1:1.
comparative example 3
The detailed description is the same as example 1; except that in comparative example 3: the surface rinse is methanol.
Comparative example 4
The detailed description is the same as example 1; except that in comparative example 4: the surface rinse is butyrolactam.
Comparative example 5
The detailed description is the same as example 1; except that in comparative example 5: the polyurethane is used in an amount of 3%.
Comparative example 6
The detailed description is the same as example 1; except that in comparative example 6: the spraying amount of the flushing agent is 0.1kg/m 2
Comparative example 7
The detailed description is the same as example 1; except that in comparative example 7: the soaking time of the flushing agent after spraying is 5min.
Comparative example 8
The detailed description is the same as example 1; except that in comparative example 8: the thickness of the polyurethane exposed stone pavement is 3cm.
Performance test method
Performance tests were performed in examples and comparative examples and the test data are listed in table 1.
1. Uniaxial penetration strength (high temperature performance): reference is made to JTG D50-2017.
2. Exposed stone depth: exposed height of aggregate after flushing.
3. Low temperature crack resistance: low Wen Xiaoliang bend test (JTG T0715).
4. Water loss resistance: freeze thawing cleavage test (JTG T0729).
5. Fatigue life: four-point bending fatigue test (JTG T0739).
6. Road friction coefficient BPN: reference is made to T0964.
7. Surface texture depth TD: reference is made to T0961.
Performance test data
TABLE 1

Claims (10)

1. The functional polyurethane exposed stone pavement is characterized by comprising the following components: cementing material, aggregate and surface flushing agent; the cement comprises polyurethane.
2. The functional polyurethane slab-stock pavement of claim 1 wherein the aggregate comprises at least one of granite, basalt, flow rock, and limestone.
3. The functional polyurethane aggregate pavement of claim 2, wherein the aggregate comprises a first aggregate and a second aggregate, the first aggregate having a particle size of 3-9.5mm, and the second aggregate having a particle size of 9.5-15mm.
4. A functional polyurethane exposed stone pavement according to claim 3, wherein the weight ratio of the first aggregate to the second aggregate is (2-4): (6-8).
5. The functional polyurethane masonry pavement according to claim 1 or 4, wherein the binder comprises 2.5-6 weight percent of aggregate.
6. The functional polyurethane masonry pavement according to claim 1 or 5, wherein the surface-flushing agent comprises at least one of methyl ethyl ketone, acetone, ethyl acetate, dimethylacetamide, butyl acetate.
7. The functional polyurethane exposed stone pavement according to claim 6, wherein the surface flushing agent comprises acetone and ethyl acetate, and the weight ratio of the acetone to the ethyl acetate is (13-15): (5-7).
8. A method for preparing the functional polyurethane exposed stone pavement according to claim 1, which is characterized by comprising the following steps:
s1, mixing cementing materials and aggregate, paving and rolling, and waiting for 3-5h for curing and forming;
s2, spraying a surface flushing agent on the surface of the solidified and formed product for soaking;
s3, cleaning by brushing to expose aggregate, and obtaining the modified asphalt.
9. The method for preparing a functional polyurethane dew stone pavement according to claim 8, wherein the spraying amount is 0.12-0.20kg/m 2
10. The method for preparing a functional polyurethane exposed stone pavement according to claim 9, wherein the soaking time is 5-20min.
CN202310688937.1A 2023-06-12 2023-06-12 Functional polyurethane exposed stone pavement and preparation method thereof Pending CN116750993A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310688937.1A CN116750993A (en) 2023-06-12 2023-06-12 Functional polyurethane exposed stone pavement and preparation method thereof

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Application Number Priority Date Filing Date Title
CN202310688937.1A CN116750993A (en) 2023-06-12 2023-06-12 Functional polyurethane exposed stone pavement and preparation method thereof

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CN116750993A true CN116750993A (en) 2023-09-15

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109761538A (en) * 2019-01-30 2019-05-17 浙江广天构件股份有限公司 A kind of dew aggregate concrete and its construction method
CN111187044A (en) * 2020-03-21 2020-05-22 陕西隆生建材有限公司 Exposed concrete and construction method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109761538A (en) * 2019-01-30 2019-05-17 浙江广天构件股份有限公司 A kind of dew aggregate concrete and its construction method
CN111187044A (en) * 2020-03-21 2020-05-22 陕西隆生建材有限公司 Exposed concrete and construction method thereof

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