CN116200010A - Polyester composition and preparation method and application thereof - Google Patents
Polyester composition and preparation method and application thereof Download PDFInfo
- Publication number
- CN116200010A CN116200010A CN202211707007.8A CN202211707007A CN116200010A CN 116200010 A CN116200010 A CN 116200010A CN 202211707007 A CN202211707007 A CN 202211707007A CN 116200010 A CN116200010 A CN 116200010A
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- China
- Prior art keywords
- polyester composition
- acid
- resin
- plasticizer
- phosphate
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 229920000728 polyester Polymers 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 46
- 239000011347 resin Substances 0.000 claims abstract description 46
- 239000004014 plasticizer Substances 0.000 claims abstract description 24
- 150000002148 esters Chemical class 0.000 claims abstract description 11
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000000835 fiber Substances 0.000 claims abstract description 4
- 239000005357 flat glass Substances 0.000 claims abstract description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- 150000005690 diesters Chemical class 0.000 claims description 8
- 150000005691 triesters Chemical class 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000004611 light stabiliser Substances 0.000 claims description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 5
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 4
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- 150000008064 anhydrides Chemical class 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- JQCXWCOOWVGKMT-UHFFFAOYSA-N diheptyl phthalate Chemical compound CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 claims description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 3
- 125000002723 alicyclic group Chemical group 0.000 claims description 3
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- APVVRLGIFCYZHJ-UHFFFAOYSA-N trioctyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCCCOC(=O)CC(O)(C(=O)OCCCCCCCC)CC(=O)OCCCCCCCC APVVRLGIFCYZHJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 claims description 2
- ALKCLFLTXBBMMP-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl hexanoate Chemical compound CCCCCC(=O)OC(C)(C=C)CCC=C(C)C ALKCLFLTXBBMMP-UHFFFAOYSA-N 0.000 claims description 2
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 claims description 2
- VOWAEIGWURALJQ-UHFFFAOYSA-N Dicyclohexyl phthalate Chemical compound C=1C=CC=C(C(=O)OC2CCCCC2)C=1C(=O)OC1CCCCC1 VOWAEIGWURALJQ-UHFFFAOYSA-N 0.000 claims description 2
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 2
- KRADHMIOFJQKEZ-UHFFFAOYSA-N Tri-2-ethylhexyl trimellitate Chemical compound CCCCC(CC)COC(=O)C1=CC=C(C(=O)OCC(CC)CCCC)C(C(=O)OCC(CC)CCCC)=C1 KRADHMIOFJQKEZ-UHFFFAOYSA-N 0.000 claims description 2
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 229940067597 azelate Drugs 0.000 claims description 2
- IHTSDBYPAZEUOP-UHFFFAOYSA-N bis(2-butoxyethyl) hexanedioate Chemical compound CCCCOCCOC(=O)CCCCC(=O)OCCOCCCC IHTSDBYPAZEUOP-UHFFFAOYSA-N 0.000 claims description 2
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 claims description 2
- PUFGCEQWYLJYNJ-UHFFFAOYSA-N didodecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCC PUFGCEQWYLJYNJ-UHFFFAOYSA-N 0.000 claims description 2
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 claims description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 2
- 239000011736 potassium bicarbonate Substances 0.000 claims description 2
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 2
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 2
- 235000011181 potassium carbonates Nutrition 0.000 claims description 2
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- RJIFVNWOLLIBJV-UHFFFAOYSA-N tributyl benzene-1,2,4-tricarboxylate Chemical compound CCCCOC(=O)C1=CC=C(C(=O)OCCCC)C(C(=O)OCCCC)=C1 RJIFVNWOLLIBJV-UHFFFAOYSA-N 0.000 claims description 2
- 239000001069 triethyl citrate Substances 0.000 claims description 2
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims description 2
- 235000013769 triethyl citrate Nutrition 0.000 claims description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 2
- BGNTUSKZDOUZCZ-UHFFFAOYSA-N tris(1-butoxyethyl) phosphate Chemical compound CCCCOC(C)OP(=O)(OC(C)OCCCC)OC(C)OCCCC BGNTUSKZDOUZCZ-UHFFFAOYSA-N 0.000 claims description 2
- GTRSAMFYSUBAGN-UHFFFAOYSA-N tris(2-chloropropyl) phosphate Chemical compound CC(Cl)COP(=O)(OCC(C)Cl)OCC(C)Cl GTRSAMFYSUBAGN-UHFFFAOYSA-N 0.000 claims description 2
- LIPMRGQQBZJCTM-UHFFFAOYSA-N tris(2-propan-2-ylphenyl) phosphate Chemical compound CC(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)C)OC1=CC=CC=C1C(C)C LIPMRGQQBZJCTM-UHFFFAOYSA-N 0.000 claims description 2
- 230000005684 electric field Effects 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 abstract description 13
- 238000002834 transmittance Methods 0.000 abstract description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 9
- 238000002791 soaking Methods 0.000 abstract description 3
- 229920000638 styrene acrylonitrile Polymers 0.000 description 17
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 16
- 238000003466 welding Methods 0.000 description 12
- 229920001707 polybutylene terephthalate Polymers 0.000 description 11
- 239000000463 material Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 238000013329 compounding Methods 0.000 description 8
- -1 Polybutylene terephthalate Polymers 0.000 description 7
- 239000003513 alkali Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 3
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 1
- WBWXVCMXGYSMQA-UHFFFAOYSA-N 3,9-bis[2,4-bis(2-phenylpropan-2-yl)phenoxy]-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C=1C=C(OP2OCC3(CO2)COP(OC=2C(=CC(=CC=2)C(C)(C)C=2C=CC=CC=2)C(C)(C)C=2C=CC=CC=2)OC3)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 WBWXVCMXGYSMQA-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- SWZOQAGVRGQLDV-UHFFFAOYSA-N 4-[2-(4-hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)ethoxy]-4-oxobutanoic acid Chemical compound CC1(C)CC(O)CC(C)(C)N1CCOC(=O)CCC(O)=O SWZOQAGVRGQLDV-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229920006127 amorphous resin Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229920006038 crystalline resin Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- QQVHEQUEHCEAKS-UHFFFAOYSA-N diundecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCC QQVHEQUEHCEAKS-UHFFFAOYSA-N 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229920006150 hyperbranched polyester Polymers 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000004023 plastic welding Methods 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a polyester composition, a preparation method and application thereof, and the components comprise: PBT resin, compound resin flat glass fiber, ester plasticizer, carbonate and other auxiliary agents. The polyester composition can simultaneously meet the conditions that the retention rate of tensile strength performance is more than or equal to 60%, the retention rate of unnotched impact strength performance is more than or equal to 40% and the laser transmittance of a sample wafer of 2.5mm is more than or equal to 30% under the condition of soaking in 10% NaOH solution at 60 ℃ for 200 hours, and is particularly suitable for the fields of automobiles and electronic appliances.
Description
Technical Field
The invention belongs to the field of engineering plastics, and particularly relates to a polyester composition, and a preparation method and application thereof.
Background
Polybutylene terephthalate (PBT) is widely used in fields of automobiles, electronics and electricity, construction, etc., due to its excellent mechanical strength, solvent resistance, abrasion resistance, electrical insulation, dimensional stability, etc. For example, in the automotive field, connectors, dispensers, ignition coils, sensors, control units, etc.; it is used for connectors, switching elements, relays, coil components, etc. in the field of electronics and electrical. The concrete embedded bolt can be used for sanitary parts and concrete embedded bolts in the field of construction. Among them, some plastic parts having complicated structures and shapes cannot be formed at one time, and an adhesive, screw fixation, snap-fit, hot plate welding, ultrasonic welding, etc. are required to join a plurality of formed parts.
Compared with the traditional plastic welding process, the laser welding is an efficient and precise welding method which uses a laser beam with high energy density as a heat source, and the rapid temperature rise and reduction rate can greatly reduce the vibration stress and the thermal stress of the product; in addition, the welding process of laser welding is stable, the surface and the internal quality of the welding seam are very good, the welding can be performed in vacuum, air or other gas environments, the requirement on a welding medium is not high, and the welding can be performed through glass or other materials transparent to light beams. Because of its unique advantages, laser welding is used more and more frequently in applications requiring secondary fusion processes.
However, polyester resins have relatively low laser permeability as semi-crystalline resins as compared with amorphous resins such as polycarbonate resins and polystyrene resins, and thus have a narrow window of processing conditions, and it is necessary to increase laser power or irradiation rate at the time of welding or to reduce the thickness of molded articles of laser-irradiated portions so as to achieve good joining effects. However, increasing the laser power or irradiation rate may cause burning whitening of the material surface with a decrease in weld strength. There are various known methods for improving the laser transparency of PBT. Laser transparent polyesters are disclosed in, for example, CN102892819B, which relates to thermoplastic molded bodies for the production of laser transparent molded parts, said thermoplastic molded bodies comprising as main components by adding Na 2 CO 3 、K 2 CO 3 、NaHCO 3 、KHCO 3 Although the alkaline substances can improve the laser transmittance of the PBT material, the ester groups of the material are easy to accelerate hydrolysis under alkaline conditions, so that the material is rapidly degraded and cannot meet the use requirements. Even worse, the materials may also be used in alkaline environments such as snow-melting agents, toilet cleaners, bathroom cleaners, bleaches, cements, and the like. The prior art can not meet the requirements of alkali resistance and higher light transmittance.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide a polyester composition, and a preparation method and application thereof.
The invention relates to a polyester composition, which comprises the following components in parts by weight:
wherein the compound resin is styrene-acrylonitrile SAN resin and styrene-maleic anhydride SMA resin, and the mass ratio of the SAN resin to the SMA resin is (3-6): 1.
The concentration of carboxyl end groups of the PBT resin is not more than 15mol/t.
Further, the concentration of the carboxyl end groups of the PBT resin is 0.01-15mol/t.
Preferably, the mass ratio of the SAN resin to the SMA resin is (4-5): 1.
the mass ratio of the SAN resin to the SMA resin is optimized, so that the polyester composition has better laser permeability and mechanical property retention rate.
The aspect ratio of the cross section of the flat glass fiber is 2-6:1.
the ester plasticizer is at least one of a diester plasticizer and a triester plasticizer.
Preferably, the diester plasticizer is a diester plasticizer formed by at least one acid selected from phthalic acid, terephthalic acid, adipic acid, maleic acid, azelaic acid, sebacic acid, and anhydrides thereof, and at least one alcohol selected from aliphatic alcohols, alicyclic alcohols, and aromatic alcohols.
Further preferably, the diester-based plasticizer is one or more of butyl benzyl phthalate, dilauryl phthalate, bisundecyl phthalate, diheptyl phthalate, dicyclohexyl phthalate, diisodecyl phthalate, dioctyl adipate, diisodecyl adipate, di (butoxyethyl) adipate, bis-2-ethylhexyl azelate, bis-2-ethylhexyl maleate, dibutyl maleate, dioctyl sebacate, dibutyl sebacate.
Preferably, the triester plasticizer is a triester plasticizer formed by at least one acid selected from citric acid, trimellitic acid, phosphoric acid and anhydrides thereof and at least one alcohol selected from aliphatic alcohol, alicyclic alcohol and aromatic alcohol.
Further preferably, the triester plasticizer is one or more of triethyl citrate, tributyl citrate, trioctyl citrate, tributyl trimellitate, tri (2-ethylhexyl) trimellitate, tricresyl phosphate, tri (isopropylphenyl) phosphate, trioctyl phosphate, tri (butoxyethyl) phosphate, tri (beta-chloropropyl) phosphate, triphenyl phosphate, and octyl diphenyl phosphate.
Preferably, the carbonate is one or more of sodium carbonate, sodium bicarbonate, potassium carbonate and potassium bicarbonate.
Preferably, the polyester composition also contains 0.5 to 5 parts of other auxiliary agents, wherein the other auxiliary agents are one or more of light stabilizer, antioxidant and lubricant.
Further, 0.6-2 parts of other auxiliary agents.
Further, the light stabilizers include, but are not limited to, the Cyasorb UV-3346 light stabilizer, the Uvinul4050H light stabilizer, the Tinuvin622 light stabilizer, and the Chimassor b944 light stabilizer.
Further, the lubricant includes, but is not limited to, one or more of silicone, oxidized polyolefin wax, hyperbranched polyester, aliphatic fatty acid ester, or ethylene-acrylic acid copolymer.
Further, the antioxidant includes, but is not limited to, any one or more of N, N' -bis- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionyl) hexamethylenediamine (antioxidant 1098), tris [2, 4-di-tert-butylphenyl ] phosphite (antioxidant 168), tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] pentaerythritol ester (antioxidant 1010), bis (2, 4-dicumylphenyl) pentaerythritol diphosphite (antioxidant S9228) or phosphite antioxidants.
Preferably, the components comprise, by weight:
the preparation method of the polyester composition comprises the following steps:
weighing the components according to the proportion, uniformly mixing, adding into a double-screw extruder, melting, mixing, extruding and granulating to obtain the polyester composition.
Preferably, the extrusion granulation temperature is 220-280 ℃.
One of the polyester compositions of the present invention is used in automobiles or electronic appliances, such as ignition coils, electrical control boxes, sensors, connectors, and the like.
According to the polyester composition, the compound resin SAN resin and the SMA resin are added into the PBT, so that on one hand, the SMA resin improves the compatibility of a PBT phase and a SAN phase, reduces the two-phase size, is beneficial to obtaining good laser transmission, and meanwhile, the alkali resistance of a system is improved due to the introduction of a benzene ring; on the other hand, the maleic anhydride group of the SMA can react with the terminal carboxyl group of the PBT, so that the rupture of the ester group in an alkaline environment is slowed down, and meanwhile, the ester plasticizer plays a role in improving alkali resistance, so that an alkaline solution in the external environment can be prevented from entering, a matrix is effectively protected, the deterioration of the mechanical property of the material caused by carbonate serving as a laser transmission improving agent is eliminated, and the alkali resistance of the material is greatly improved compared with the traditional polycarbodiimide hydrolysis resisting agent.
Advantageous effects
The polyester composition can simultaneously meet the conditions that the retention rate of tensile strength performance is more than or equal to 60%, the retention rate of unnotched impact strength performance is more than or equal to 40% and the laser transmittance of a sample wafer of 2.5mm is more than or equal to 30% under the condition of soaking in 10% NaOH solution at 60 ℃ for 200 hours, and is particularly suitable for the fields of automobiles and electronic appliances.
Detailed Description
The invention will be further illustrated with reference to specific examples. It is to be understood that these examples are illustrative of the present invention and are not intended to limit the scope of the present invention. Further, it is understood that various changes and modifications may be made by those skilled in the art after reading the teachings of the present invention, and such equivalents are intended to fall within the scope of the claims appended hereto.
1. The raw material sources are as follows:
PBT resin: PBT GX121J, ceremony petrochemical industry, carboxyl end group concentration of 9mol/t
Flat glass fiber: glass fiber TFG-3.0-T436, aspect ratio of cross section 4:1, a step of; shandong Taishan glass fiber Co., ltd;
SAN resin: SAN NF2200AK taiwan platform company (taiwan region corporation of china);
SMA resin: SMA-725K, jiaxing Hua chemical Co., ltd;
PTW ethylene-acrylate-glycidyl methacrylate, duPont;
ester plasticizer-1: trioctyl citrate, a western reagent;
ester plasticizer-2: diundecyl phthalate, beijing Olympic pharmaceutical technology Co
Ester plasticizer-3: dioctyl adipate, shandong chemical Co., ltd
Hydrolysis resistance agent: polycarbodiimide Stabaxol P400, rhine chemical Co., germany
Carbonate: sodium carbonate: ara Ding Shiji
Other auxiliaries: the mass ratio of the antioxidant 1098 to the antioxidant 168 is 1:1;
compounding resin-1: the mass ratio of SAN resin to SMA resin is 4:1;
compounding resin-2: the mass ratio of SAN resin to SMA resin is 5:1;
compounding resin-3: the mass ratio of SAN resin to SMA resin is 3:1;
compounding resin-4: the mass ratio of SAN resin to SMA resin is 6:1;
compounding resin-5: the mass ratio of SAN resin to SMA resin is 1:1;
compounding resin-6: the mass ratio of SAN resin to SMA resin is 8:1;
compounding resin-7: the mass ratio of SAN resin to PTW resin is 4:1;
the sodium carbonate and other adjuvants used in the parallel examples and comparative examples are all the same commercial products.
2. Preparation methods of examples and comparative examples
Weighing the components according to the proportion, uniformly mixing, adding into a double-screw extruder, melting, mixing, extruding and granulating to obtain the polyester composition. The extrusion granulating temperature is 220-280 ℃.
3. Test criteria and methods
Mechanical property test:
tensile strength: the tensile rate was 10mm/min according to ISO527-2-2012, test conditions: 23 ℃,50% rh;
non notched impact strength: spline dimensions 80mm x 10mm x 4mm, test conditions according to ISO 179-1-2010: 23 ℃,50% rh.
Alkali resistance experiment: and placing the injection molded tensile sample bar and the non-notch impact strength sample bar in a 10% NaOH solution with mass percent concentration, soaking at 60 ℃ for 200 hours, taking out, placing in a 23 ℃/50% RH environment for 24 hours, performing mechanical property test, and comparing with the original performance, calculating the performance retention rate.
The performance retention rate calculation method comprises the following steps: px/P0×100%, wherein P0 is initial mechanical property, and Px is mechanical property after alkali resistance experiment treatment.
Laser transmittance test:
a80 mm by 50mm by 2mm template (thickness 2 mm) was molded separately using an injection molding machine, with a cylinder temperature of 280℃and a mold temperature of 120 ℃. The transmittance at 1064nm was measured by measuring the transmittance at the center of the sample plate using a near infrared spectrometer (wavelength 900-1700nm, NIRQUest spectrometer, ocean optics).
Table 1 shows the proportions (parts by weight) of the examples
Table 2 example formulation (parts by weight)
Table 3 comparative examples ratio (parts by weight)
Table 4 shows example performance effect data
Table 5 example performance effect data
Table 6 comparative example performance effect data
Examples 1, 11-13 and comparative examples 1-5, 7, 8 and 12 show that the requirements of the tensile strength performance retention of more than or equal to 60%, the performance retention of the unnotched impact strength of more than or equal to 40% and the laser transmittance of a 2mm sample wafer of more than or equal to 30% can be met only by compounding SAN resin and SMA resin in a specific range and fixing the content of the ester plasticizer.
Example 1 and comparative examples 6 and 11 show that the ester plasticizer can greatly improve the alkali resistance of the material and has less negative effect on the laser transmittance compared with the traditional hydrolysis resistance agent.
Examples 1, 14-16 and comparative examples 9-10 show that the ratio of the compound resin is fixed, and the ratio of the ester plasticizer can meet the requirements that the tensile strength performance retention rate is more than or equal to 60%, the performance retention rate of the unnotched impact strength is more than or equal to 40% and the laser transmittance of a 2mm sample wafer is more than or equal to 30% only by 0.5-6 parts.
Examples 1-16 and comparative examples 6 and 12 show that the compound resin and the ester plasticizer in the system need to exist simultaneously and the proportion is within a specific range to simultaneously meet the requirements that the tensile strength performance retention rate is more than or equal to 60%, the performance retention rate of the unnotched impact strength is more than or equal to 40% and the laser transmittance of the 2mm sample wafer is more than or equal to 30%.
Claims (10)
1. The polyester composition is characterized by comprising the following components in parts by weight:
wherein the compound resin is SAN resin and SMA resin, and the mass ratio of the SAN resin to the SMA resin is (3-6): 1.
2. The polyester composition of claim 1, wherein the PBT resin has a carboxyl end group concentration of not more than 15mol/t.
3. The polyester composition of claim 1, wherein the mass ratio of SAN resin to SMA resin is (4-5): 1.
4. The polyester composition of claim 1, wherein the flat glass fiber has a cross-sectional aspect ratio of 2 to 6:1, a step of; the carbonate is one or more of sodium carbonate, sodium bicarbonate, potassium carbonate and potassium bicarbonate.
5. The polyester composition of claim 1, wherein the ester plasticizer is at least one of a diester-based plasticizer or a triester-based plasticizer;
the diester plasticizer is a diester plasticizer formed by at least one acid selected from phthalic acid, terephthalic acid, adipic acid, maleic acid, azelaic acid, sebacic acid and anhydrides thereof and at least one alcohol selected from aliphatic alcohol, alicyclic alcohol and aromatic alcohol;
the triester plasticizer is a triester plasticizer formed by at least one acid selected from citric acid, trimellitic acid, phosphoric acid and anhydrides thereof and at least one alcohol selected from aliphatic alcohol, alicyclic alcohol and aromatic alcohol.
6. The polyester composition according to claim 5, wherein the diester-based plasticizer is one or more of butylbenzyl phthalate, bisundecyl phthalate, dilauryl phthalate, diheptyl phthalate, dicyclohexyl phthalate, diisodecyl phthalate, dioctyl adipate, diisodecyl adipate, di (butoxyethyl) adipate, bis-2-ethylhexyl azelate, bis-2-ethylhexyl maleate, dibutyl maleate, dioctyl sebacate, dibutyl sebacate;
the triester plasticizer is one or more of triethyl citrate, tributyl citrate, trioctyl citrate, tributyl trimellitate, tri (2-ethylhexyl) trimellitate, tricresyl phosphate, tri (isopropylphenyl) phosphate, trioctyl phosphate, tri (butoxyethyl) phosphate, tri (beta-chloropropyl) phosphate, triphenyl phosphate and octyl diphenyl phosphate.
7. The polyester composition according to claim 1, wherein the polyester composition further comprises 0.5 to 5 parts of other auxiliary agents; wherein the other auxiliary agent is one or more of light stabilizer, antioxidant and lubricant.
8. The polyester composition of claim 1, wherein the components comprise, in parts by weight:
9. a process for preparing the polyester composition of claim 1 comprising:
weighing the components according to the proportion, mixing, adding into a double-screw extruder, melting, mixing, extruding and granulating to obtain the polyester composition.
10. Use of the polyester composition of claim 1 in the automotive and electrical fields.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102892819A (en) * | 2010-05-18 | 2013-01-23 | 巴斯夫欧洲公司 | Laser-transparent polyester |
| CN103724953A (en) * | 2014-01-16 | 2014-04-16 | 厦门市天宇塑料工业有限公司 | Special low-warpage flame-retardant reinforced PBT (polybutylene terephthalate) material for relay and application of material |
| CN110862655A (en) * | 2019-12-11 | 2020-03-06 | 宁波华腾首研新材料有限公司 | PBT/SAN composite material and preparation method and application thereof |
| CN114230953A (en) * | 2021-12-17 | 2022-03-25 | 金发科技股份有限公司 | Transparent resin composition with stable size and enhanced mechanics, preparation method and application thereof |
-
2022
- 2022-12-29 CN CN202211707007.8A patent/CN116200010A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102892819A (en) * | 2010-05-18 | 2013-01-23 | 巴斯夫欧洲公司 | Laser-transparent polyester |
| CN103724953A (en) * | 2014-01-16 | 2014-04-16 | 厦门市天宇塑料工业有限公司 | Special low-warpage flame-retardant reinforced PBT (polybutylene terephthalate) material for relay and application of material |
| CN110862655A (en) * | 2019-12-11 | 2020-03-06 | 宁波华腾首研新材料有限公司 | PBT/SAN composite material and preparation method and application thereof |
| CN114230953A (en) * | 2021-12-17 | 2022-03-25 | 金发科技股份有限公司 | Transparent resin composition with stable size and enhanced mechanics, preparation method and application thereof |
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