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CN116005031A - Ceramic bearing manufacturing method - Google Patents

Ceramic bearing manufacturing method Download PDF

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Publication number
CN116005031A
CN116005031A CN202211663707.1A CN202211663707A CN116005031A CN 116005031 A CN116005031 A CN 116005031A CN 202211663707 A CN202211663707 A CN 202211663707A CN 116005031 A CN116005031 A CN 116005031A
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powder
bearing
ceramic
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manufacturing
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庄清荣
吴红
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Shenzhen Rare Conduction Technology Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02T10/86Optimisation of rolling resistance, e.g. weight reduction 

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Abstract

The invention provides a method for manufacturing a ceramic bearing, which belongs to the technical field of bearing manufacturing, and comprises the following steps: uniformly mixing ceramic matrix powder and nanometer copper powder to form a blank; the blank is impact formed at high speed in a vacuum environment. Wherein: the nano copper powder is used as a binder, blanks are compacted through a high-speed impact forming process, instantaneous friction force among blank powder generates instantaneous high temperature to melt the nano copper powder, and the blanks are subjected to plastic shaping instantaneously to obtain the ceramic bearing. Compared with the prior art, the invention has the advantages of simple process, rapid forming, low cost and easy mass production, and meanwhile, the rotating speed of the manufactured bearing can reach over 9000 revolutions per minute, no noise exists in the rotating process, and the requirements of equipment on high rotating speed and silence are met. In addition, the bearing does not depend on lubricating oil in use, so that the service life of the bearing can be prolonged.

Description

一种陶瓷轴承制造方法A kind of ceramic bearing manufacturing method

技术领域technical field

本发明涉及精密轴承制造技术领域,特别是涉及一种陶瓷轴承制造方法。The invention relates to the technical field of precision bearing manufacture, in particular to a method for manufacturing a ceramic bearing.

背景技术Background technique

轴承是各类机械装备的重要基础零部件,其主要功能是支撑机械旋转体,用以降低其在传动过程中的摩擦系数,并保证其回转精度。按运动原件摩擦性质的不同,轴承可分为滚动轴承和滑动轴承两类。其中:滑动轴承由耐磨材料制成,用于低速、轻载、维护困难的机械转动部位,需要具有良好的耐高温性、耐腐蚀性、导热性、抗疲劳强度等特性。Bearing is an important basic component of various mechanical equipment. Its main function is to support the mechanical rotating body to reduce its friction coefficient during the transmission process and ensure its rotation accuracy. According to the different friction properties of moving parts, bearings can be divided into rolling bearings and sliding bearings. Among them: sliding bearings are made of wear-resistant materials and are used in low-speed, light-load, and difficult-to-maintain mechanical rotating parts. They need to have good high temperature resistance, corrosion resistance, thermal conductivity, and fatigue resistance.

陶瓷材料由于耐高温性能、耐腐蚀、弹性模量高、使用寿命长等优点,通常采用陶瓷烧结的工艺来制造陶瓷轴承。这种传统的陶瓷轴承烧结工艺至少存在以下缺陷:Due to the advantages of high temperature resistance, corrosion resistance, high elastic modulus and long service life of ceramic materials, ceramic sintering technology is usually used to manufacture ceramic bearings. This traditional ceramic bearing sintering process has at least the following defects:

1、现有的烧结工艺对生产条件要求苛刻,制造周期长,成本高。1. The existing sintering process has strict requirements on production conditions, long manufacturing cycle and high cost.

2、轴承在旋转过程中噪音大,转速低,已无法满足设备对静音和高转速的需求。2. During the rotation of the bearing, the noise is large and the speed is low, which can no longer meet the needs of the equipment for quietness and high speed.

3、轴承在使用中必须使用润滑油,没有润滑油后很快就报废。3. Lubricating oil must be used in the bearing, and it will be scrapped soon after there is no lubricating oil.

发明内容Contents of the invention

本发明旨在提出一种陶瓷轴承制造方法,以期至少部分地解决上述技术问题中的至少之一。The present invention aims to propose a ceramic bearing manufacturing method, in order to at least partly solve at least one of the above technical problems.

为解决上述技术问题,本发明提供了一种陶瓷轴承制造方法,包括:In order to solve the above technical problems, the present invention provides a ceramic bearing manufacturing method, including:

将陶瓷基体粉末和纳米铜粉混合均匀形成坯料;Mix ceramic matrix powder and nano-copper powder evenly to form a billet;

在真空环境中将坯料高速冲击成形。The blank is impact-formed at high speed in a vacuum environment.

根据本发明一种优选实施方式,所述陶瓷基体选自氮化硼、氮化硅、氧化铝、碳化硅、氧化锆中的至少一种。According to a preferred embodiment of the present invention, the ceramic substrate is selected from at least one of boron nitride, silicon nitride, alumina, silicon carbide, and zirconia.

根据本发明一种优选实施方式,所述陶瓷基体粉末为氮化硼粉末,氮化硼粉末质量百分比为:55~85%,纳米铜粉质量百分比为:45~15%。According to a preferred embodiment of the present invention, the ceramic matrix powder is boron nitride powder, the mass percentage of boron nitride powder is 55-85%, and the mass percentage of nano-copper powder is 45-15%.

根据本发明一种优选实施方式,所述陶瓷基体粉末为氮化硼粉末和氮化硅粉末,氮化硼粉末质量百分比为:35~45%,氮化硅粉末质量百分比为:25~35%,纳米铜粉质量百分比为:25~30%。According to a preferred embodiment of the present invention, the ceramic matrix powder is boron nitride powder and silicon nitride powder, the mass percentage of boron nitride powder is: 35-45%, and the mass percentage of silicon nitride powder is: 25-35% , the mass percentage of nanometer copper powder is: 25-30%.

根据本发明一种优选实施方式,所述陶瓷基体粉末为氮化硼粉末、氮化硅粉末和氧化铝粉末,氮化硼粉末质量百分比为:35~55%,氮化硅粉末质量百分比为:15~25%,氧化铝粉末质量百分比为:10~18%,纳米铜粉质量百分比为:15~20%。According to a preferred embodiment of the present invention, the ceramic matrix powder is boron nitride powder, silicon nitride powder and alumina powder, the mass percentage of boron nitride powder is: 35-55%, and the mass percentage of silicon nitride powder is: 15-25%, the mass percentage of alumina powder is 10-18%, and the mass percentage of nano-copper powder is 15-20%.

根据本发明一种优选实施方式,混合之前,还加入质量百分比在0.15~0.25%的分散剂。According to a preferred embodiment of the present invention, before mixing, 0.15-0.25% by mass dispersant is also added.

根据本发明一种优选实施方式,所述陶瓷基体粉末的粒径在15~120μm。According to a preferred embodiment of the present invention, the particle size of the ceramic matrix powder is 15-120 μm.

根据本发明一种优选实施方式,将陶瓷基体粉末和纳米铜粉通过湿法球磨处理或球磨处理混合均匀形成坯料;其中:According to a preferred embodiment of the present invention, the ceramic matrix powder and nano-copper powder are uniformly mixed to form a billet through wet ball milling or ball milling; wherein:

所述湿法球磨处理为:球料质量比为5~30:1,混合转速80~600r/min,混合时间为1~6h;所述湿法球磨处理中加入的溶剂为水、酒精或丙酮;The wet ball milling process is as follows: the mass ratio of balls to materials is 5-30:1, the mixing speed is 80-600r/min, and the mixing time is 1-6h; the solvent added in the wet ball milling process is water, alcohol or acetone ;

所述球磨处理为:球料质量比为10~20:1,混合转速为50~400r/min,混合时间为12~24h。The ball milling treatment is as follows: the mass ratio of balls to materials is 10-20:1, the mixing speed is 50-400 r/min, and the mixing time is 12-24 hours.

根据本发明一种优选实施方式,所述在真空环境中将坯料高速冲击成形包括:According to a preferred embodiment of the present invention, the high-speed impact forming of the blank in a vacuum environment includes:

将轴承真空腔抽真空;Vacuum the bearing vacuum chamber;

将坯料填入轴承真空腔内;Fill the blank into the vacuum cavity of the bearing;

施加50~70MPa压力并以50~70m/s的速度冲击压实坯料,持续1~2min,使坯料发生塑性变形得到轴承;Apply a pressure of 50-70MPa and impact and compact the billet at a speed of 50-70m/s for 1-2min, so that the billet undergoes plastic deformation to obtain a bearing;

打开轴承真空腔出口,轴承掉入成品盒。Open the outlet of the bearing vacuum chamber, and the bearing will drop into the finished product box.

综上所述,本发明的陶瓷轴承制造方法,将陶瓷基体粉末和纳米铜粉混合均匀形成坯料,在真空环境中将坯料高速冲击成形。其中:纳米铜粉作为粘结剂,在真空环境中熔点(40℃左右)较低,通过高速冲击成形工艺压实坯料,坯料粉末之间的瞬时摩擦力产生瞬时高温将纳米铜粉融化,瞬间将坯料塑性定型,得到陶瓷轴承。相较于现有技术,本发明至少具有如下有益效果:To sum up, in the manufacturing method of the ceramic bearing of the present invention, the ceramic matrix powder and nano-copper powder are uniformly mixed to form a billet, and the billet is impact-formed at high speed in a vacuum environment. Among them: nano-copper powder is used as a binder, and its melting point (about 40°C) is low in a vacuum environment. The billet is compacted through a high-speed impact forming process, and the instantaneous friction between the billet powders generates an instantaneous high temperature to melt the nano-copper powder. The blank is plastically shaped to obtain a ceramic bearing. Compared with the prior art, the present invention has at least the following beneficial effects:

1、工艺简单、可快速成型、成本低、易于批量生产。1. Simple process, rapid prototyping, low cost, and easy mass production.

2、制成的轴承转速可达每分钟9000转以上,且旋转过程中无噪音,满足设备对高转速和静音的需求。2. The speed of the manufactured bearing can reach more than 9,000 revolutions per minute, and there is no noise during the rotation process, which meets the needs of the equipment for high speed and silence.

3、采用高速冲击成形工艺,使轴承表面光滑,轴承在使用中不依赖润滑油,可延长轴承使用寿命。3. The high-speed impact forming process is adopted to make the bearing surface smooth, and the bearing does not rely on lubricating oil during use, which can prolong the service life of the bearing.

附图说明Description of drawings

图1是本发明实施例提供的一种陶瓷轴承制造方法的流程示意图。Fig. 1 is a schematic flowchart of a method for manufacturing a ceramic bearing provided by an embodiment of the present invention.

具体实施方式Detailed ways

下面将详细描述本发明的各个方面的特征和示例性实施例,为了使本发明的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本发明进行进一步详细描述。应理解,此处所描述的具体实施例仅被配置为解释本发明,并不被配置为限定本发明。对于本领域技术人员来说,本发明可以在不需要这些具体细节中的一些细节的情况下实施。下面对实施例的描述仅仅是为了通过示出本发明的示例来提供对本发明更好的理解。The characteristics and exemplary embodiments of various aspects of the present invention will be described in detail below. In order to make the purpose, technical solutions and advantages of the present invention more clear, the present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described here are only configured to explain the present invention, not to limit the present invention. It will be apparent to one skilled in the art that the present invention may be practiced without some of these specific details. The following description of the embodiments is only to provide a better understanding of the present invention by showing examples of the present invention.

需要说明的是,在本文中,诸如第一和第二等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来,而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。而且,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。在没有更多限制的情况下,由语句“包括……”限定的要素,并不排除在包括所述要素的过程、方法、物品或者设备中还存在另外的相同要素。It should be noted that in this article, relational terms such as first and second are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply that there is a relationship between these entities or operations. There is no such actual relationship or order between them. Furthermore, the term "comprises", "comprises" or any other variation thereof is intended to cover a non-exclusive inclusion such that a process, method, article, or apparatus comprising a set of elements includes not only those elements, but also includes elements not expressly listed. other elements of or also include elements inherent in such a process, method, article, or device. Without further limitations, an element defined by the statement "comprising..." does not exclude the presence of additional same elements in the process, method, article or device comprising said element.

本发明提供一种陶瓷轴承制造方法,如图1所示,所述方法包括:The present invention provides a method for manufacturing a ceramic bearing, as shown in Figure 1, the method comprising:

S1、将陶瓷基体粉末和纳米铜粉混合均匀形成坯料;S1, uniformly mixing ceramic matrix powder and nano-copper powder to form a billet;

其中:所述陶瓷基体可以选自氮化硼、氮化硅、氧化铝、碳化硅、氧化锆中的至少一种。陶瓷基体粉末的粒径在15~120μm,纳米铜粉作为粘结剂。Wherein: the ceramic substrate can be selected from at least one of boron nitride, silicon nitride, aluminum oxide, silicon carbide, and zirconium oxide. The particle size of the ceramic matrix powder is 15-120 μm, and the nano-copper powder is used as a binder.

陶瓷基体粉末与纳米铜粉的质量百分比根据陶瓷基体粉末的组分而定。在一种示例中,陶瓷基体粉末为氮化硼粉末,氮化硼粉末质量百分比为:55~85%,纳米铜粉质量百分比为:45~15%。在另一种示例种,陶瓷基体粉末为氮化硼粉末和氮化硅粉末,氮化硼粉末质量百分比为:35~45%,氮化硅粉末质量百分比为:25~35%,纳米铜粉质量百分比为:25~30%。在又一示例中,陶瓷基体粉末为氮化硼粉末、氮化硅粉末和氧化铝粉末,氮化硼粉末质量百分比为:35~55%,氮化硅粉末质量百分比为:15~25%,氧化铝粉末质量百分比为:10~18%,纳米铜粉质量百分比为:15~20%。The mass percentage of the ceramic matrix powder and the nano-copper powder is determined according to the components of the ceramic matrix powder. In one example, the ceramic matrix powder is boron nitride powder, the mass percentage of boron nitride powder is 55-85%, and the mass percentage of nano-copper powder is 45-15%. In another example, the ceramic matrix powder is boron nitride powder and silicon nitride powder, the mass percentage of boron nitride powder is: 35-45%, the mass percentage of silicon nitride powder is: 25-35%, and nano-copper powder The mass percentage is: 25-30%. In yet another example, the ceramic matrix powder is boron nitride powder, silicon nitride powder and alumina powder, the mass percentage of boron nitride powder is: 35-55%, the mass percentage of silicon nitride powder is: 15-25%, The mass percentage of alumina powder is 10-18%, and the mass percentage of nano-copper powder is 15-20%.

进一步的,为了避免粉末在混合过程中自发凝并,发生团聚,在混合之前可以在各粉末原料中加入适量的分散剂,以在粉末颗粒表面形成保护层,降低粉末间的团聚效应。可选的,分散剂可以是:铁酸醋偶联剂、桂酸醋偶联剂、硬脂酸、油酸等。其中:铁酸醋偶联剂、桂酸醋偶联剂以共价键的形式吸附在颗粒表面,硬脂酸、油酸通过路易斯酸碱反应以氢键的方式吸附在颗粒表面。本实施例中,分散剂的质量百分比控制在0.15~0.25%,以免堵塞粘结剂的热裂解排出通道阻碍粘结剂排出,在表面形成气泡、裂纹等缺陷。Further, in order to avoid spontaneous coagulation and agglomeration of powders during the mixing process, an appropriate amount of dispersant can be added to each powder raw material before mixing to form a protective layer on the surface of powder particles and reduce the agglomeration effect between powders. Optionally, the dispersant may be: ferric ester coupling agent, lauric acid ester coupling agent, stearic acid, oleic acid, etc. Among them: ferric acid ester coupling agent and lauric acid ester coupling agent are adsorbed on the surface of particles in the form of covalent bonds, and stearic acid and oleic acid are adsorbed on the surface of particles in the form of hydrogen bonds through Lewis acid-base reaction. In this embodiment, the mass percentage of the dispersant is controlled at 0.15-0.25%, so as not to block the pyrolysis discharge channel of the binder, prevent the discharge of the binder, and form defects such as bubbles and cracks on the surface.

本实施例中,可以采用:湿法球磨或球磨的方式对粉末原料进行混合。具体混合时间及混合转速根据所采用的混合方式而定。在一种示例中,采用湿法球磨处理,所述湿法球磨处理为:球料质量比为5~30:1,混合转速80~600r/min,混合时间为1~6h;所述湿法球磨处理中加入的溶剂为水、酒精或丙酮。在另一种示例中,采用球磨处理,所述球磨处理为:球料质量比为10~20:1,混合转速为50~400r/min,混合时间为12~24h。In this embodiment, powder raw materials may be mixed by wet ball milling or ball milling. The specific mixing time and mixing speed depend on the mixing method used. In one example, wet ball milling treatment is adopted, and the wet ball milling treatment is as follows: the mass ratio of ball to material is 5-30:1, the mixing speed is 80-600r/min, and the mixing time is 1-6h; The solvent added in the ball milling process is water, alcohol or acetone. In another example, ball milling treatment is adopted, and the ball milling treatment is as follows: the mass ratio of balls to materials is 10-20:1, the mixing speed is 50-400 r/min, and the mixing time is 12-24 hours.

S2、在真空环境中将坯料高速冲击成形。S2. High-speed impact forming of the billet in a vacuum environment.

其中:高速冲击成形是指以能量的突然释放产生的瞬时冲击力对材料进行塑性加工成形的工艺。本实施例通过在真空环境中控制冲击速度将坯料高速冲击成形。在高速冲击成形过程中:纳米铜粉作为粘结剂,在真空环境中熔点(40℃左右)较低,通过高速冲击力压实坯料,坯料粉末之间的瞬时摩擦力产生瞬时高温将纳米铜粉融化,瞬间将坯料塑性定型,得到陶瓷轴承。Among them: high-speed impact forming refers to the process of plastic processing and forming of materials with instantaneous impact force generated by sudden release of energy. In this embodiment, the billet is impact-formed at high speed by controlling the impact velocity in a vacuum environment. In the high-speed impact forming process: nano-copper powder is used as a binder, and its melting point (about 40°C) is low in a vacuum environment. The billet is compacted by high-speed impact force, and the instantaneous friction between the billet powders generates instantaneous high temperature. The powder is melted, and the billet is plastically shaped instantly to obtain a ceramic bearing.

示例性的,本步骤可以包括:Exemplarily, this step may include:

S21、将轴承真空腔抽真空;S21, vacuumize the bearing vacuum chamber;

其中:轴承真空腔中可安装各个形状和寸尺的轴承模具。在本步骤之前,可以根据待制造的轴承形状和尺寸选取轴承模具,并将其安装于轴承真空腔内,采用真空泵将整个轴承真空腔抽真空。Among them: Bearing molds of various shapes and sizes can be installed in the bearing vacuum chamber. Before this step, a bearing mold can be selected according to the shape and size of the bearing to be manufactured, installed in the bearing vacuum cavity, and the entire bearing vacuum cavity is evacuated by a vacuum pump.

S22、将坯料填入轴承真空腔内;S22, filling the blank into the bearing vacuum cavity;

本实施例中,每次填入轴承真空腔的坯料根据待制造轴承的形状和尺寸确定,以保证制造的轴承满足形状和尺寸要求,提供轴承精度。In this embodiment, the blanks filled into the bearing vacuum cavity each time are determined according to the shape and size of the bearing to be manufactured, so as to ensure that the manufactured bearing meets the shape and size requirements and provide bearing accuracy.

示例性的,在本步骤之前,可以预先根据待制造轴承的形状和尺寸计算待制造轴承的体积V,每次填入轴承真空腔的坯料体积为n(1.2~1.5)V之间。其中:n为每次填料可生产出轴承的个数。Exemplarily, before this step, the volume V of the bearing to be manufactured can be calculated in advance according to the shape and size of the bearing to be manufactured, and the volume of the blank filled into the vacuum cavity of the bearing each time is between n (1.2-1.5)V. Among them: n is the number of bearings that can be produced for each filling.

S23、施加50~70MPa压力并以50~70m/s的速度冲击压实坯料,持续1~2min,使坯料发生塑性变形得到轴承;S23. Applying a pressure of 50-70 MPa and impacting and compacting the billet at a speed of 50-70 m/s for 1-2 minutes, causing the billet to undergo plastic deformation to obtain a bearing;

通过高速冲击力压实坯料,坯料粉末之间的瞬时摩擦力产生瞬时高温将纳米铜粉融化,瞬间将坯料塑性定型,得到陶瓷轴承。The billet is compacted by high-speed impact force, and the instantaneous friction between the powders of the billet generates instantaneous high temperature to melt the nano-copper powder, and the billet is plastically shaped instantly to obtain a ceramic bearing.

S24、打开轴承真空腔出口,轴承掉入成品盒。S24. Open the outlet of the bearing vacuum chamber, and the bearing falls into the finished product box.

通过S21~S24,1个轴承生产成型,重复循环S24生产其他轴承,直到轴承真空腔内坯料用完,一批次的轴承生产成型。重复循环S1~S24生产其他批次的轴承。Through S21-S24, one bearing is produced and formed, and the cycle S24 is repeated to produce other bearings until the blank in the bearing vacuum chamber is used up, and a batch of bearings are produced and formed. The cycle S1-S24 is repeated to produce other batches of bearings.

下面结合具体实施例对本发明作进一步说明,但并不局限于此。The present invention will be further described below in conjunction with specific examples, but is not limited thereto.

实施例1Example 1

一种陶瓷轴承制造方法,所述方法包括:A method of manufacturing a ceramic bearing, the method comprising:

S101、制备粒径75μm的氮化硼粉末和纳米铜粉。S101, preparing boron nitride powder and nano-copper powder with a particle size of 75 μm.

本步骤中,可以将氮化硼粉末多次过200目筛,得到粒径75μm的氮化硼粉末。其中:纳米铜粉指粒径在1~100nm之间的铜粒子粉末,可以通过化学气相沉积法、蒸发凝聚法、机械粉碎法等制备。In this step, the boron nitride powder can be passed through a 200-mesh sieve several times to obtain boron nitride powder with a particle size of 75 μm. Among them: nano-copper powder refers to copper particle powder with a particle size between 1 and 100 nm, which can be prepared by chemical vapor deposition, evaporation condensation, mechanical pulverization, and the like.

S102、按照质量百分比称取75.20%的氮化硼粉末,24.62%的纳米铜粉,0.18%的分散剂。S102. Weigh 75.20% of boron nitride powder, 24.62% of nano-copper powder, and 0.18% of dispersant according to mass percentage.

其中:分散剂可以是:铁酸醋偶联剂、桂酸醋偶联剂、硬脂酸、或者油酸,本发明不做具体限定。Wherein: the dispersant can be: ferric ester coupling agent, lauric acid ester coupling agent, stearic acid, or oleic acid, which is not specifically limited in the present invention.

S103、将氮化硼粉末、纳米铜粉和分散剂通过湿法球磨处理混合均匀形成坯料;S103, uniformly mixing the boron nitride powder, nano-copper powder and dispersant through wet ball milling to form a billet;

可选的,可以先将氮化硼粉末和纳米铜粉真空干燥,选取球料质量比为28:1的磨球,混合转速为:100r/min,混合时间为3h;并在湿法球磨处理中加入水作为溶剂。湿法球磨处理完成后进行真空干燥,得到坯料。Optionally, the boron nitride powder and nano-copper powder can be vacuum-dried first, and balls with a mass ratio of ball to material of 28:1 are selected, the mixing speed is 100r/min, and the mixing time is 3h; Water was added as a solvent. After the wet ball milling process is completed, vacuum drying is carried out to obtain a billet.

S104、将轴承真空腔抽真空;S104, vacuumize the bearing vacuum chamber;

S105、将体积为1.35nV的坯料填入轴承真空腔内;S105, filling the blank with a volume of 1.35nV into the vacuum cavity of the bearing;

其中:V为待制造轴承的体积,可以通过待制造轴承的形状和尺寸计算得到。n为每次填料可生产出轴承的个数,可以根据生产要求配置。Where: V is the volume of the bearing to be manufactured, which can be calculated from the shape and size of the bearing to be manufactured. n is the number of bearings that can be produced for each filling, which can be configured according to production requirements.

S106、施加65MPa压力并以65m/s的速度冲击压实坯料,持续2min,使坯料发生塑性变形得到轴承;S106. Applying a pressure of 65MPa and impacting and compacting the billet at a speed of 65m/s for 2 minutes, causing the billet to undergo plastic deformation to obtain a bearing;

S107、打开轴承真空腔出口,轴承掉入成品盒。S107, open the outlet of the vacuum chamber of the bearing, and drop the bearing into the finished product box.

实施例2Example 2

一种陶瓷轴承制造方法,所述方法包括:A method of manufacturing a ceramic bearing, the method comprising:

S201、制备粒径18μm的氮化硼粉末和纳米铜粉。S201, preparing boron nitride powder and nano-copper powder with a particle size of 18 μm.

本步骤中,可以将氮化硼粉末多次过800目筛,得到粒径18μm的氮化硼粉末。其中:纳米铜粉指粒径在1~100nm之间的铜粒子粉末,可以通过化学气相沉积法、蒸发凝聚法、机械粉碎法等制备。In this step, the boron nitride powder can be passed through an 800-mesh sieve several times to obtain a boron nitride powder with a particle size of 18 μm. Among them: nano-copper powder refers to copper particle powder with a particle size between 1 and 100 nm, which can be prepared by chemical vapor deposition, evaporation condensation, mechanical pulverization, and the like.

S202、按照质量百分比称取82.15%的氮化硼粉末,17.62%的纳米铜粉,0.23%的分散剂。S202. Weigh 82.15% of boron nitride powder, 17.62% of nano-copper powder, and 0.23% of dispersant according to mass percentage.

其中:分散剂可以是:铁酸醋偶联剂、桂酸醋偶联剂、硬脂酸、或者油酸,本发明不做具体限定。Wherein: the dispersant can be: ferric ester coupling agent, lauric acid ester coupling agent, stearic acid, or oleic acid, which is not specifically limited in the present invention.

S203、将氮化硼粉末、纳米铜粉和分散剂通过球磨处理混合均匀形成坯料;S203, uniformly mixing boron nitride powder, nano-copper powder and dispersant through ball milling to form a billet;

可选的,可以先将氮化硼粉末和纳米铜粉真空干燥,选取球料质量比为17:1的磨球,其中:磨球可以使用无压烧结到碳化硅制成。混合转速为320r/min,混合时间为18h。球磨处理完成后进行干燥,得到坯料。Optionally, the boron nitride powder and nano-copper powder can be vacuum-dried first, and a grinding ball with a ball-to-material mass ratio of 17:1 can be selected, wherein: the grinding ball can be made by pressureless sintering to silicon carbide. The mixing speed is 320r/min, and the mixing time is 18h. After the ball milling treatment, drying is carried out to obtain a billet.

S204、将轴承真空腔抽真空;S204, vacuumize the bearing vacuum chamber;

S205、将体积为1.45nV的坯料填入轴承真空腔内;S205, filling the blank with a volume of 1.45nV into the vacuum cavity of the bearing;

其中:V为待制造轴承的体积,可以通过待制造轴承的形状和尺寸计算得到。n为每次填料可生产出轴承的个数,可以根据生产要求配置。Where: V is the volume of the bearing to be manufactured, which can be calculated from the shape and size of the bearing to be manufactured. n is the number of bearings that can be produced for each filling, which can be configured according to production requirements.

S206、施加53MPa压力并以58m/s的速度冲击压实坯料,持续1.2min,使坯料发生塑性变形得到轴承;S206. Applying a pressure of 53MPa and impacting and compacting the billet at a speed of 58m/s for 1.2min, causing the billet to undergo plastic deformation to obtain a bearing;

S207、打开轴承真空腔出口,轴承掉入成品盒。S207. Open the outlet of the bearing vacuum chamber, and drop the bearing into the finished product box.

实施例3Example 3

一种陶瓷轴承制造方法,所述方法包括:A method of manufacturing a ceramic bearing, the method comprising:

S301、制备粒径75μm的氮化硼粉末、粒径75μm的氧化铝粉末、粒径75μm的氧化锆粉末和纳米铜粉。S301. Prepare boron nitride powder with a particle size of 75 μm, alumina powder with a particle size of 75 μm, zirconia powder with a particle size of 75 μm, and nano copper powder.

本步骤中,可以将氮化硼粉末、氧化铝粉末、氧化锆粉末分别多次过200目筛,得到粒径75μm的氮化硼粉末、粒径75μm的氧化铝粉末、粒径75μm的氧化锆粉末。In this step, boron nitride powder, alumina powder, and zirconia powder can be passed through a 200-mesh sieve several times to obtain boron nitride powder with a particle size of 75 μm, alumina powder with a particle size of 75 μm, and zirconia powder with a particle size of 75 μm. powder.

其中:纳米铜粉指粒径在1~100nm之间的铜粒子粉末,可以通过化学气相沉积法、蒸发凝聚法、机械粉碎法等制备。Among them: nano-copper powder refers to copper particle powder with a particle size between 1 and 100 nm, which can be prepared by chemical vapor deposition, evaporation condensation, mechanical pulverization, and the like.

S302、按照质量百分比称取50.00%的氮化硼粉末,16.00%的氧化铝粉末,17.22%的氧化锆粉末,16.62%的纳米铜粉,0.16%的分散剂。S302. Weigh 50.00% of boron nitride powder, 16.00% of alumina powder, 17.22% of zirconia powder, 16.62% of nanometer copper powder, and 0.16% of dispersant according to mass percentage.

其中:分散剂可以是:铁酸醋偶联剂、桂酸醋偶联剂、硬脂酸、或者油酸,本发明不做具体限定。Wherein: the dispersant can be: ferric ester coupling agent, lauric acid ester coupling agent, stearic acid, or oleic acid, which is not specifically limited in the present invention.

S303、将氮化硼粉末、氧化铝粉末、氧化锆粉末、纳米铜粉和分散剂通过球磨处理混合均匀形成坯料;S303, uniformly mixing boron nitride powder, alumina powder, zirconia powder, nano-copper powder and dispersant through ball milling to form a billet;

可选的,选取球料质量比为19:1的磨球,其中:磨球可以使用无压烧结到碳化硅制成。混合转速为380r/min,混合时间为23h。球磨处理完成后进行干燥,得到坯料。Optionally, a grinding ball with a mass ratio of ball to material of 19:1 is selected, wherein: the grinding ball can be made by pressureless sintering to silicon carbide. The mixing speed is 380r/min, and the mixing time is 23h. After the ball milling treatment, drying is carried out to obtain a billet.

S304、将轴承真空腔抽真空;S304, vacuumize the bearing vacuum chamber;

S305、将体积为1.32nV的坯料填入轴承真空腔内;S305, filling the blank with a volume of 1.32nV into the vacuum chamber of the bearing;

其中:V为待制造轴承的体积,可以通过待制造轴承的形状和尺寸计算得到。n为每次填料可生产出轴承的个数,可以根据生产要求配置。Where: V is the volume of the bearing to be manufactured, which can be calculated from the shape and size of the bearing to be manufactured. n is the number of bearings that can be produced for each filling, which can be configured according to production requirements.

S306、施加48MPa压力并以47m/s的速度冲击压实坯料,持续1.8min,使坯料发生塑性变形得到轴承;S306. Applying a pressure of 48MPa and impacting and compacting the billet at a speed of 47m/s for 1.8min, causing the billet to undergo plastic deformation to obtain a bearing;

S307、打开轴承真空腔出口,轴承掉入成品盒。S307. Open the outlet of the bearing vacuum chamber, and drop the bearing into the finished product box.

实施例4Example 4

一种陶瓷轴承制造方法,所述方法包括:A method of manufacturing a ceramic bearing, the method comprising:

S401、制备粒径18μm的氮化硼粉末、粒径23μm的氮化硅粉末和纳米铜粉。S401. Prepare boron nitride powder with a particle size of 18 μm, silicon nitride powder with a particle size of 23 μm, and nanometer copper powder.

本步骤中,可以将氮化硼粉末多次过800目筛,得到粒径18μm的氮化硼粉末;将氮化硅粉末多次过600目筛,得到粒径23μm的氮化硅粉末。In this step, the boron nitride powder can be passed through an 800 mesh sieve several times to obtain a boron nitride powder with a particle size of 18 μm; the silicon nitride powder can be passed through a 600 mesh sieve several times to obtain a silicon nitride powder with a particle size of 23 μm.

其中:纳米铜粉指粒径在1~100nm之间的铜粒子粉末,可以通过化学气相沉积法、蒸发凝聚法、机械粉碎法等制备。Among them: nano-copper powder refers to copper particle powder with a particle size between 1 and 100 nm, which can be prepared by chemical vapor deposition, evaporation condensation, mechanical pulverization, and the like.

S402、按照质量百分比称取45.22%的氮化硼粉末,30.35%的氮化硅粉末,24.22%的纳米铜粉,0.21%的分散剂。S402. Weigh 45.22% of boron nitride powder, 30.35% of silicon nitride powder, 24.22% of nanometer copper powder, and 0.21% of dispersant according to mass percentage.

其中:分散剂可以是:铁酸醋偶联剂、桂酸醋偶联剂、硬脂酸、或者油酸,本发明不做具体限定。Wherein: the dispersant can be: ferric ester coupling agent, lauric acid ester coupling agent, stearic acid, or oleic acid, which is not specifically limited in the present invention.

S403、将氮化硼粉末、碳化硅粉末、纳米铜粉和分散剂通过球磨处理混合均匀形成坯料;S403, uniformly mixing boron nitride powder, silicon carbide powder, nano-copper powder and dispersant through ball milling to form a billet;

可选的,选取球料质量比为10:1的磨球,其中:磨球可以使用无压烧结到碳化硅制成。混合转速为250r/min,混合时间为20h。球磨处理完成后进行干燥,得到坯料。Optionally, a grinding ball with a mass ratio of ball to material of 10:1 is selected, wherein: the grinding ball can be made by pressureless sintering to silicon carbide. The mixing speed is 250r/min, and the mixing time is 20h. After the ball milling treatment, drying is carried out to obtain a billet.

S404、将轴承真空腔抽真空;S404, vacuumize the bearing vacuum chamber;

S405、将体积为1.22nV的坯料填入轴承真空腔内;S405, filling the blank with a volume of 1.22nV into the vacuum chamber of the bearing;

其中:V为待制造轴承的体积,可以通过待制造轴承的形状和尺寸计算得到。n为每次填料可生产出轴承的个数,可以根据生产要求配置。Where: V is the volume of the bearing to be manufactured, which can be calculated from the shape and size of the bearing to be manufactured. n is the number of bearings that can be produced for each filling, which can be configured according to production requirements.

S406、施加55MPa压力并以65m/s的速度冲击压实坯料,持续1min,使坯料发生塑性变形得到轴承;S406. Applying a pressure of 55 MPa and impacting and compacting the billet at a speed of 65 m/s for 1 min, causing the billet to undergo plastic deformation to obtain a bearing;

S407、打开轴承真空腔出口,轴承掉入成品盒。S407, open the outlet of the vacuum chamber of the bearing, and drop the bearing into the finished product box.

实施例5Example 5

一种陶瓷轴承制造方法,所述方法包括:A method of manufacturing a ceramic bearing, the method comprising:

S501、制备粒径90μm的氮化硼粉末、粒径80μm的氮化硅粉末、粒径75μm的氧化铝粉末和纳米铜粉。S501. Prepare boron nitride powder with a particle size of 90 μm, silicon nitride powder with a particle size of 80 μm, alumina powder with a particle size of 75 μm, and nano copper powder.

本步骤中,可以将氮化硼粉末多次过170目筛,得到粒径90μm的氮化硼粉末;将氮化硅粉末多次过180目筛,得到粒径80μm的氮化硅粉末;将氧化铝粉末多次过200目筛,得到粒径75μm的氧化铝粉末。In this step, the boron nitride powder can be passed through a 170 mesh sieve several times to obtain a boron nitride powder with a particle size of 90 μm; the silicon nitride powder can be passed through a 180 mesh sieve several times to obtain a silicon nitride powder with a particle size of 80 μm; The alumina powder was passed through a 200-mesh sieve several times to obtain alumina powder with a particle size of 75 μm.

其中:纳米铜粉指粒径在1~100nm之间的铜粒子粉末,可以通过化学气相沉积法、蒸发凝聚法、机械粉碎法等制备。Among them: nano-copper powder refers to copper particle powder with a particle size between 1 and 100 nm, which can be prepared by chemical vapor deposition, evaporation condensation, mechanical pulverization, and the like.

S502、按照质量百分比称取38.45%的氮化硼粉末,20.32%的氮化硅粉末,16.79%的氧化铝粉末,24.22%的纳米铜粉,0.22%的分散剂。S502. Weigh 38.45% of boron nitride powder, 20.32% of silicon nitride powder, 16.79% of aluminum oxide powder, 24.22% of nanometer copper powder, and 0.22% of dispersant according to mass percentage.

其中:分散剂可以是:铁酸醋偶联剂、桂酸醋偶联剂、硬脂酸、或者油酸,本发明不做具体限定。Wherein: the dispersant can be: ferric ester coupling agent, lauric acid ester coupling agent, stearic acid, or oleic acid, which is not specifically limited in the present invention.

S503、将氮化硼粉末、碳化硅粉末、氧化铝粉末、纳米铜粉和分散剂通过球磨处理混合均匀形成坯料;S503, uniformly mixing boron nitride powder, silicon carbide powder, alumina powder, nano-copper powder and dispersant through ball milling to form a billet;

可选的,选取球料质量比为15:1的磨球,其中:磨球可以使用无压烧结到碳化硅制成。混合转速为350r/min,混合时间为22h。球磨处理完成后进行干燥,得到坯料。Optionally, a grinding ball with a mass ratio of ball to material of 15:1 is selected, wherein: the grinding ball can be made by pressureless sintering to silicon carbide. The mixing speed is 350r/min, and the mixing time is 22h. After the ball milling treatment, drying is carried out to obtain a billet.

S504、将轴承真空腔抽真空;S504, vacuumize the bearing vacuum chamber;

S505、将体积为1.42nV的坯料填入轴承真空腔内;S505, filling the blank with a volume of 1.42nV into the vacuum cavity of the bearing;

其中:V为待制造轴承的体积,可以通过待制造轴承的形状和尺寸计算得到。n为每次填料可生产出轴承的个数,可以根据生产要求配置。Where: V is the volume of the bearing to be manufactured, which can be calculated from the shape and size of the bearing to be manufactured. n is the number of bearings that can be produced for each filling, which can be configured according to production requirements.

S506、施加68MPa压力并以68m/s的速度冲击压实坯料,持续1.5min,使坯料发生塑性变形得到轴承;S506. Applying a pressure of 68MPa and impacting and compacting the billet at a speed of 68m/s for 1.5min, causing the billet to undergo plastic deformation to obtain a bearing;

S507、打开轴承真空腔出口,轴承掉入成品盒。S507. Open the outlet of the bearing vacuum chamber, and drop the bearing into the finished product box.

通过本发明制造的陶瓷轴承,转速可达到9000~12000r/min,且不会产生噪音,满足高转速和静音的需求。由于高转速会使轴承温度比较高,添加润滑剂会烧焦轴承,因此,本发明制造的陶瓷轴承在使用过程中也不需要添加润滑剂,延长轴承寿命。The rotational speed of the ceramic bearing manufactured by the invention can reach 9000-12000 r/min without generating noise, and meets the requirements of high rotational speed and quietness. Because the high rotating speed will make the temperature of the bearing relatively high, adding lubricant will burn the bearing, therefore, the ceramic bearing manufactured by the present invention does not need to add lubricant during use, prolonging the service life of the bearing.

下面对各个实施例中制造的陶瓷轴承作进一步性能检测;其中:The ceramic bearings manufactured in each embodiment are further tested for performance below; wherein:

转速:将制成的陶瓷轴承安装到台架上,不添加润滑剂,在轴承运行温度恒定时,测试旋转速度;Rotation speed: Install the manufactured ceramic bearing on the bench without adding lubricant, and test the rotation speed when the operating temperature of the bearing is constant;

噪声:根据标准GB12348-2008,采用环境噪声自动检测仪;Noise: According to the standard GB12348-2008, the environmental noise automatic detector is adopted;

硬度:维氏硬度计,载荷350gf,保载时间15s;Hardness: Vickers hardness tester, load 350gf, load time 15s;

抗拉强度:根据标准GB-T 228.1-2010,在电子万能试验机上进行测定,拉伸速率为1.5mm/min;径向压溃强度:根据标准GB-T 6804-2008,在电子万能试验机上进行测定,压缩速率为1.2mm/min;Tensile strength: according to the standard GB-T 228.1-2010, measured on an electronic universal testing machine, the tensile rate is 1.5mm/min; radial crushing strength: according to the standard GB-T 6804-2008, on an electronic universal testing machine To measure, the compression rate is 1.2mm/min;

摩擦系数:室温球盘接触旋转磨损方式,载荷6N,摩擦转速2500rmp,摩擦半径2.5mm,摩擦时间40min。测试结果见表1所示。Friction coefficient: room temperature ball-disk contact rotation wear mode, load 6N, friction speed 2500rmp, friction radius 2.5mm, friction time 40min. The test results are shown in Table 1.

Figure BDA0004013832930000101
Figure BDA0004013832930000101

表1各个实施例陶瓷轴承的性能测试结果Table 1 performance test results of ceramic bearings of various embodiments

由表1可知:通过本发明制造的陶瓷轴承转速可达到9000~12000r/min,且旋转过程中噪音均低于30,可以认为是静音。整个使用过程中无需润滑油,且具有较高的硬度、抗拉强度和摩擦系数,综合性能优异,实用性强。It can be seen from Table 1 that the rotational speed of the ceramic bearing manufactured by the present invention can reach 9000-12000r/min, and the noise during the rotation is lower than 30, which can be considered as quiet. No lubricating oil is needed during the whole use process, and it has high hardness, tensile strength and friction coefficient, excellent comprehensive performance and strong practicability.

需要明确的是,本发明并不局限于上文所描述并在图中示出的特定结构和处理。为了简明起见,这里省略了对已知方法的详细描述。在上述实施例中,描述和示出了若干具体的步骤作为示例。但是,本发明的方法过程并不限于所描述和示出的具体步骤,本领域的技术人员可以在领会本发明的精神后,作出各种改变、修改和添加,或者改变步骤之间的顺序。It is to be understood that the invention is not limited to the specific structures and processes described above and shown in the drawings. For conciseness, detailed descriptions of known methods are omitted here. In the above embodiments, several specific steps are described and shown as examples. However, the method process of the present invention is not limited to the specific steps described and shown, and those skilled in the art can make various changes, modifications and additions, or change the sequence of steps after understanding the spirit of the present invention.

还需要说明的是,本发明中提及的示例性实施例,基于一系列的步骤或者装置描述一些方法或系统。但是,本发明不局限于上述步骤的顺序,也就是说,可以按照实施例中提及的顺序执行步骤,也可以不同于实施例中的顺序,或者若干步骤同时执行。It should also be noted that the exemplary embodiments mentioned in the present invention describe some methods or systems based on a series of steps or devices. However, the present invention is not limited to the order of the above steps, that is, the steps may be performed in the order mentioned in the embodiment, or may be different from the order in the embodiment, or several steps may be performed simultaneously.

以上所述,仅为本发明的具体实施方式,所属领域的技术人员可以清楚地了解到,为了描述的方便和简洁,上述描述的系统、模块和单元的具体工作过程,可以参考前述方法实施例中的对应过程,在此不再赘述。应理解,本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到各种等效的修改或替换,这些修改或替换都应涵盖在本发明的保护范围之内。The above is only a specific implementation of the present invention, and those skilled in the art can clearly understand that for the convenience and brevity of description, the specific working process of the above-described systems, modules and units can refer to the foregoing method embodiments The corresponding process in , will not be repeated here. It should be understood that the protection scope of the present invention is not limited thereto. Any person skilled in the art can easily think of various equivalent modifications or replacements within the technical scope disclosed in the present invention, and these modifications or replacements should cover all Within the protection scope of the present invention.

Claims (9)

1. A method of manufacturing a ceramic bearing, comprising:
uniformly mixing ceramic matrix powder and nanometer copper powder to form a blank;
the blank is impact formed at high speed in a vacuum environment.
2. The method of manufacturing a ceramic bearing according to claim 1, wherein the ceramic substrate is at least one selected from the group consisting of boron nitride, silicon nitride, aluminum oxide, silicon carbide, and zirconium oxide.
3. The method of manufacturing a ceramic bearing according to claim 2, wherein the ceramic base powder is boron nitride powder, and the mass percentage of the boron nitride powder is: 55-85% of nanometer copper powder by mass percent: 45-15%.
4. The method of manufacturing a ceramic bearing according to claim 2, wherein the ceramic base powder is a boron nitride powder and a silicon nitride powder, the boron nitride powder being in mass percent: 35-45% of silicon nitride powder by mass percent: 25-35% of nanometer copper powder by mass percent: 25-30%.
5. The method of manufacturing a ceramic bearing according to claim 2, wherein the ceramic base powder is a boron nitride powder, a silicon nitride powder, and an aluminum oxide powder, the boron nitride powder being in mass percent: 35-55% of silicon nitride powder by mass percent: 15-25% of aluminum oxide powder by mass percent: 10-18% of nanometer copper powder, which comprises the following components in percentage by mass: 15-20%.
6. The method according to any one of claims 3 to 5, wherein a dispersant is further added in an amount of 0.15 to 0.25% by mass before mixing.
7. The method of manufacturing a ceramic bearing according to claim 1, wherein the particle size of the ceramic base powder is 15 to 120 μm.
8. The method for manufacturing a ceramic bearing according to claim 1, wherein the ceramic base powder and the nano copper powder are uniformly mixed by wet ball milling treatment or ball milling treatment to form a blank; wherein:
the wet ball milling treatment comprises the following steps: the mass ratio of the ball material is 5-30: 1, the mixing rotating speed is 80-600 r/min, and the mixing time is 1-6 h; the solvent added in the wet ball milling treatment is water, alcohol or acetone;
the ball milling treatment is as follows: the mass ratio of the ball materials is 10-20: 1, the mixing rotating speed is 50-400 r/min, and the mixing time is 12-24 h.
9. The method of manufacturing a ceramic bearing according to claim 1, wherein the high-speed impact forming of the blank in a vacuum environment comprises:
vacuumizing the bearing vacuum cavity;
filling the blank into a bearing vacuum cavity;
applying 5-7 MPa pressure and impacting and compacting the blank at the speed of 50-70 m/s for 1-2 min to enable the blank to be plastically deformed to obtain the bearing;
and opening the outlet of the bearing vacuum cavity, and dropping the bearing into the finished product box.
CN202211663707.1A 2022-12-23 2022-12-23 Ceramic bearing manufacturing method Pending CN116005031A (en)

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Citations (1)

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Publication number Priority date Publication date Assignee Title
CN1455820A (en) * 2000-07-25 2003-11-12 Ck管理股份公司 Method of producing ceramic body by coalescence and ceramic body produced

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CN1455820A (en) * 2000-07-25 2003-11-12 Ck管理股份公司 Method of producing ceramic body by coalescence and ceramic body produced
CN1457277A (en) * 2000-07-25 2003-11-19 Ck管理股份公司 Method of producing composite body by coalescence and composite body produced

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