CN115340319A - Engineering rock mass heterogeneous simulation test piece based on rock-like resin material and preparation method and application thereof - Google Patents
Engineering rock mass heterogeneous simulation test piece based on rock-like resin material and preparation method and application thereof Download PDFInfo
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Abstract
本发明公开了一种工程岩体非均质性模拟试件及其制备与应用,旨在解决现有试件难以模拟矿物颗粒所带来的岩体非均质性问题。试件包括由透明树脂材料和骨料混合浇注成型的类岩体,及埋设于类岩体内的节理面。所述石英砂骨料试件在‑15~‑10℃下有良好类岩石特征,抗压和抗拉强度比高达9.12,比未加石英砂前显著增强;所述浇注料由CY‑39型树脂、YS‑T31型固化剂和促进剂按100:34:4的质量比组成;所述石英砂为粒径0.6~0.8 mm的透明颗粒;所述节理面由云母片制成。此外,试件骨料的材质、形态和添加量可根据被模拟的岩石进行变化,以制作出相同的内部结构和力学性能,且试件高透明、可清晰观察到内部裂纹演化过程,能有效用于骨料大小和形态对岩石机理的影响研究。
The invention discloses an engineering rock mass heterogeneity simulation test piece and its preparation and application, aiming at solving the rock mass heterogeneity problem caused by the difficulty in simulating mineral particles in the existing test pieces. The test piece includes a rock-like body formed by mixing transparent resin material and aggregate, and a joint surface embedded in the rock-like body. The quartz sand aggregate specimen has good rock-like characteristics at -15 to -10°C, and the ratio of compressive and tensile strength is as high as 9.12, which is significantly stronger than before adding quartz sand; the castable is made of CY-39 type Resin, YS-T31 type curing agent and accelerator are composed in a mass ratio of 100:34:4; the quartz sand is transparent particles with a particle size of 0.6-0.8 mm; the joint surface is made of mica sheets. In addition, the material, shape and addition amount of the aggregate of the specimen can be changed according to the simulated rock to produce the same internal structure and mechanical properties, and the specimen is highly transparent, and the internal crack evolution process can be clearly observed, which can be Effective in the study of the effect of aggregate size and shape on rock mechanisms.
Description
技术领域technical field
本发明涉及岩土工程技术领域,具体涉及一种工程岩体非均质模拟试件及其制备方法与应用。The invention relates to the technical field of geotechnical engineering, in particular to an engineering rock mass heterogeneity simulation test piece and its preparation method and application.
背景技术Background technique
天然岩石是一种赋存有大量矿物颗粒的非均质材料,矿物颗粒的大小和形态对岩石的力学及变形性质影响显著。岩石材料的失稳与破坏、剪切带等热点问题的解决也离不开对岩石材料复杂性的研究,特别是非均质性的研究。因此对于岩石材料非均质结构特性和破坏机理的研究,具有重要的学术价值和工程意义。此外,工程岩体中普遍含有许多宏观软弱节理面,也强烈地影响着岩体的变形和强度特性,对三维裂隙的扩展与演化规律研究也是岩石力学的重点内容之一。Natural rock is a heterogeneous material with a large number of mineral particles. The size and shape of mineral particles have a significant impact on the mechanical and deformation properties of rocks. The solution to hot issues such as instability and failure of rock materials and shear bands is also inseparable from the study of the complexity of rock materials, especially the study of heterogeneity. Therefore, the research on the heterogeneous structure characteristics and failure mechanism of rock materials has important academic value and engineering significance. In addition, there are many macroscopically weak joints in engineering rock mass, which also strongly affect the deformation and strength characteristics of rock mass. The study of the expansion and evolution of three-dimensional cracks is also one of the key contents of rock mechanics.
室内试验是开展岩土工程研究的重要手段,当前常用的岩石模拟材料有水泥砂浆、陶瓷、石膏、有机玻璃、光敏树脂等,但上述材料在制作含骨料非均质模拟试件以及试件内部预置节理裂隙方面,均存在极大困难,不能和工程岩体保持一致。此外,水泥砂浆、陶瓷和石膏的缺点是不透明,观察不到内部裂纹的扩展演化过程;有机玻璃的缺点是和岩石特性相差过大,代表性极低;光敏树脂是3D打印技术的一种原材料,缺点是通过逐层打印、固化的方式来制作试件,因此导致试件整体性差,且光敏树脂塑性度高,与岩石相似性差。Indoor testing is an important means to carry out geotechnical engineering research. Currently, commonly used rock simulation materials include cement mortar, ceramics, gypsum, plexiglass, photosensitive resin, etc. In terms of internal preset joints and fissures, there are great difficulties, which cannot be consistent with the engineering rock mass. In addition, the disadvantage of cement mortar, ceramics and gypsum is that it is opaque, and the expansion and evolution process of internal cracks cannot be observed; the disadvantage of plexiglass is that it is too different from the characteristics of rocks, and its representation is extremely low; photosensitive resin is a raw material for 3D printing technology The disadvantage is that the test piece is made by printing and curing layer by layer, which leads to poor integrity of the test piece, and the photosensitive resin has high plasticity and poor similarity to rocks.
因此如何寻找一种透明类岩石材料,在其内部制作出与岩石结构一致的非均质孔隙结构特征,肉眼直接观察内部的损伤和裂纹扩展过程,并能预置三维裂隙以开展工程岩体失稳机理的室内试验研究,将具有重要的学术价值和工程意义。Therefore, how to find a transparent rock-like material, create heterogeneous pore structure characteristics consistent with the rock structure inside, directly observe the internal damage and crack propagation process with the naked eye, and pre-set three-dimensional cracks to carry out engineering rock mass failure. The indoor experimental research on the stability mechanism will have important academic value and engineering significance.
公开于该背景技术部分的信息仅仅旨在加深对本发明总体背景技术的理解,而不应当被视为承认或以任何形式暗示该信息构成本领域技术人员所公知的现有技术。The information disclosed in this background section is only intended to enhance the understanding of the general background of the present invention, and should not be considered as an acknowledgment or any form of suggestion that the information constitutes the prior art that is known to those skilled in the art.
发明内容Contents of the invention
本发明的目的在于提供一种工程岩体非均质性模拟试件及其制备与应用,以解决现有类岩石材料难以有效模拟真实岩石高脆性和非均质性的技术问题。The purpose of the present invention is to provide an engineering rock mass heterogeneity simulation test piece and its preparation and application, so as to solve the technical problem that existing rock-like materials are difficult to effectively simulate the high brittleness and heterogeneity of real rock.
为解决上述技术问题,本发明采用如下技术方案:In order to solve the problems of the technologies described above, the present invention adopts the following technical solutions:
设计一种非均质性类岩石试件,包括由高脆性透明树脂、石英砂混合浇注成型的类岩体及埋设于类岩体内的节理面;所述高脆性透明树脂由CY-39型树脂、YS-T31型固化剂、二硫代二苯并噻唑固化促进剂按100:34:4的质量比组成;所述节理面由对应形状的透明云母片制成。Design a heterogeneous rock-like specimen, including a rock-like body formed by mixed casting of high-brittle transparent resin and quartz sand, and a joint surface embedded in the rock-like body; the high-brittle transparent resin is composed of CY-39 type Resin, YS-T31 type curing agent, and dithiodibenzothiazole curing accelerator are composed in a mass ratio of 100:34:4; the joint surface is made of transparent mica sheets of corresponding shapes.
例如,图1(a)为该非均质类岩石试件的截面,图1(b)为自然界真实岩石的截面,可以看出,两者在细观骨料/矿物颗粒的尺度和分布上是一致的,说明了该试件在模拟真实岩石内部结构方面的有效性。For example, Fig. 1(a) is the cross-section of the heterogeneous rock specimen, and Fig. 1(b) is the cross-section of real rock in nature. are consistent, indicating the effectiveness of the specimen in simulating the internal structure of real rocks.
所述石英砂粒径为0.6~0.8 mm的透明颗粒,颗粒密度与液体树脂的不同。The quartz sand is a transparent particle with a particle diameter of 0.6-0.8 mm, and the particle density is different from that of the liquid resin.
设计一种非均质性类岩石试件的制备方法,包括如下具体步骤:Design a method for preparing a heterogeneous rock-like specimen, including the following specific steps:
(1)树脂浇注料制备:取CY-39型树脂、YS-T31型固化剂和二硫代二苯并噻唑固化促进剂,按100:34:4的质量比混合均匀并去除气泡;(1) Preparation of resin castable: Take CY-39 resin, YS-T31 curing agent and dithiodibenzothiazole curing accelerator, mix them evenly at a mass ratio of 100:34:4 and remove air bubbles;
(2)骨料拌合:按上步所得混合料质量的5%向其中添加石英砂,振捣充分后放置离心台处理2分钟,再搅拌均匀后进行除气泡处理;(2) Aggregate mixing: Add quartz sand to it according to 5% of the mass of the mixture obtained in the previous step, place it on a centrifuge table for 2 minutes after the vibration is sufficient, and then perform air removal after stirring evenly;
(3)节理面布设:在对应的试件浇注模具中排布并固定试验所需的节理面;(3) Joint surface layout: Arrange and fix the joint surface required for the test in the corresponding specimen casting mold;
(4)试件浇注及养护成型:向节理面布设完成后的试件浇注模具中引流浇入所述树脂浇注料,并经除气泡处理后,于20℃下恒温养护35 h后脱模,再于70~80℃下恒温养护48 h。如图2所示为一制作完成的试件。(4) Specimen casting and curing molding: Drainage and pouring the resin castable into the casting mold of the test piece after the joint surface layout is completed, and after removing air bubbles, it is cured at 20°C for 35 hours and then removed from the mold. Then maintain at a constant temperature of 70-80°C for 48 hours. Figure 2 shows a finished sample.
所述试件浇注模具为有机高分子硅胶(HTV)模具;如图3所示。The casting mold of the test piece is an organopolymer silicone (HTV) mold; as shown in FIG. 3 .
所述节理面是由厚0.1 mm云母片冲压而成的圆形或椭圆形薄片,图4为用于加工云母片的钢模具结构图和实物图;如图5所示为一制作完成的云母片节理面。Described joint surface is the circular or elliptical sheet that is stamped by thick 0.1 mm mica sheet, and Fig. 4 is the steel mold structural diagram and physical figure that are used to process mica sheet; As shown in Fig. 5, it is a finished mica Slice joint surface.
所述石英砂粒径为0.6~0.8 mm的透明石英砂,前期对骨料的颜色、性能和体形进行了漫长的探索过程,尝试了数十种材质和不同粒径。由于石英砂的颗粒密度与液体树脂的不同,因此会产生沉淀、上浮或集聚等现象(参见图6部分失败样例),不能在试件中有效分布,导致实验失败。除常规振捣、离心、搅拌等处置措施外,采用的方法是在混合料中加入二硫代二苯并噻唑固化促进剂,加快其初凝速度,确保在30 min内完成初凝;之后的缓慢凝固过程中,将不会再出现上述病害现象。The quartz sand is transparent quartz sand with a particle size of 0.6-0.8 mm. In the early stage, a long process of exploration was carried out on the color, performance and shape of the aggregate, and dozens of materials and different particle sizes were tried. Because the particle density of quartz sand is different from that of liquid resin, it will cause precipitation, floating or aggregation (see some failure samples in Figure 6), which cannot be effectively distributed in the test piece, resulting in the failure of the experiment. In addition to conventional vibrating, centrifuging, stirring and other disposal measures, the method adopted is to add dithiodibenzothiazole curing accelerator to the mixture to speed up the initial setting speed and ensure that the initial setting is completed within 30 minutes; During the slow solidification process, the above-mentioned disease phenomena will no longer occur.
在所述步骤(4)中,脱模后于70℃下恒温干燥养护24 h,可以得到抗压强度96.7MPa的试件。In the step (4), after demoulding, dry and cure at a constant temperature of 70°C for 24 hours, and a specimen with a compressive strength of 96.7MPa can be obtained.
与现有技术相比,本发明的主要有益技术效果在于:Compared with the prior art, the main beneficial technical effects of the present invention are:
(1)本发明的透明类岩石树脂试件,对研究非均质性对岩石材料力学性质的影响机制具有重要意义。(1) The transparent rock-like resin specimen of the present invention is of great significance for studying the mechanism of heterogeneity affecting the mechanical properties of rock materials.
(2)本发明基于骨料增脆降韧所制得透明的类岩石树脂试件,其与真实岩石具有相似的内部结构和力学性能,在较低温度下具有良好的脆性和透明度;能有效的模拟岩石内部存在矿物颗粒分布不均、孔隙、节理等缺陷带来的非均质性;并且进一步选取透明石英砂作为骨料不影响试件的高透明度,也不会影响试件的变形和裂隙的扩展,较之纯树脂类岩石试件更接近真实岩石,脆性度也有了显著提高(达到9.12);比之3D打印光敏树脂整体性更强,力学性能更加接近真实岩石。(2) The transparent rock-like resin specimen prepared by the present invention based on aggregate brittleness and toughness reduction has similar internal structure and mechanical properties to real rocks, and has good brittleness and transparency at relatively low temperatures; it can effectively The simulated rock has heterogeneity caused by uneven distribution of mineral particles, pores, joints and other defects; and the further selection of transparent quartz sand as aggregate does not affect the high transparency of the specimen, nor does it affect the deformation and deformation of the specimen. The expansion of cracks is closer to real rocks than pure resin rock specimens, and the brittleness has also been significantly improved (up to 9.12); compared with 3D printed photosensitive resins, the integrity is stronger, and the mechanical properties are closer to real rocks.
(3)该非均质性类岩石试件的非均质内部构造,可以根据不同工程岩体实际情况对骨料的材质、添加量和体形参数,如图7所示,进行调整和变化,以和被模拟岩石的非均质体构造和形态,以及弹性模量,保持一致。(3) The heterogeneous internal structure of the heterogeneous rock specimen can be adjusted and changed according to the actual conditions of different engineering rock masses, the aggregate material, addition amount and shape parameters, as shown in Figure 7, To be consistent with the heterogeneous structure and shape of the simulated rock, as well as the elastic modulus.
骨料添加量计算方法如下:当颗粒缺陷与岩石主体骨架的密度相同或相差在10%以内时,先获取真实岩石(水泥砂浆试件亦可)中的细观颗粒/骨料质量百分比信息(记为ω1),则步骤2中骨料的添加量为ω2=138ω1/(1-ω1),以此可定向制得骨料含量为ω1的类岩石试件。骨料体形参数方面,先采用CT扫描获取自然岩石内部颗粒缺陷的圆形度、球形度、扁平度等信息,再加工出一致的骨料形态和拌合掺量进行试件制作,必要时可将骨料用胶水粘接牢固再放入模具中布设。图8为选用不同骨料添加量和体形参数时所制作完成的试件。The calculation method of the amount of aggregate added is as follows: when the density of particle defects and the main rock skeleton is the same or the difference is within 10%, first obtain the mesoscopic particle/aggregate mass percentage information ( denoted as ω 1 ), then the amount of aggregate added in step 2 is ω 2 =138ω 1 /(1-ω 1 ), so that a rock-like specimen with aggregate content of ω 1 can be oriented. In terms of aggregate shape parameters, first use CT scanning to obtain information such as circularity, sphericity, and flatness of particle defects inside natural rocks, and then process consistent aggregate shapes and mixing volumes to make test pieces. The aggregate is firmly bonded with glue and then put into the mold for layout. Figure 8 shows the completed specimens with different aggregate additions and shape parameters.
当颗粒缺陷与岩石主体骨架的密度相差大于10%时,骨料的添加量为:When the difference between particle defects and the density of the main rock skeleton is greater than 10%, the amount of aggregate added is:
(1), (1),
式中:为骨料的体积比含量,为树脂材料的弹性模量,为被模拟岩石的弹性模量,为骨料的体形参数,为树脂材料的泊松比。Where: is the volume ratio content of the aggregate, is the elastic modulus of the resin material, is the elastic modulus of the simulated rock, is the shape parameter of the aggregate, and is the Poisson's ratio of the resin material.
其中,为骨料体形参数和树脂材料泊松比的函数,计算如下:Among them, is the function of the shape parameter of the aggregate and the Poisson's ratio of the resin material, calculated as follows:
(2); (2);
式中:为骨料几何轮廓中切线角的最小值。Where: is the minimum value of the tangent angle in the aggregate geometry profile.
(4)在本发明中进一步选用硅胶材质的浇注试件模具改进为,与常规使用的玻璃、不锈钢、聚甲基丙烯酸甲酯(PMMA)、聚氯乙烯(PVC)等材质的模具相比,其内壁不易附着气泡,如图9所示,其为因模具材质问题而导致制备失败的部分样例;试件成型后更易于脱模;其具有的高透明度,可以清晰地观察到试件的固化过程;硅胶质软方便钻孔拉线定位节理位置,容易预置多种情况的节理面,开展节理尺寸、位置、倾角等对裂隙扩展的研究,多个节理面数目、相对位置、相对角度等对裂隙扩展的影响,及多节理面之间的相互作用等研究。(4) In the present invention, the pouring test piece mold made of silica gel is further selected to be improved. Its inner wall is not easy to attach air bubbles, as shown in Figure 9, which is a part of the sample that failed due to mold material problems; it is easier to demould after the specimen is molded; it has high transparency, and can clearly observe the shape of the specimen. Curing process; the silicone is soft and convenient for drilling and pulling wires to locate the joint position, and it is easy to preset joint surfaces in various situations, and carry out research on crack expansion such as joint size, position, inclination angle, etc., the number, relative position, and relative angle of multiple joint surfaces, etc. The influence on crack propagation, and the interaction between multi-joint surfaces, etc.
附图说明Description of drawings
图1为本申请一实施例中试件和自然界真实岩石的截面对比图;其中a为本发明试件,b为玄武岩。Fig. 1 is a cross-sectional comparison diagram of a test piece in an embodiment of the present application and a real rock in nature; wherein a is the test piece of the present invention, and b is basalt.
图2为本申请一实施例中制作完成的试件,包括不含预制节理试件和预制节理试件。Fig. 2 shows the completed test pieces in one embodiment of the present application, including test pieces without prefabricated joints and prefabricated joints.
图3为本申请一实施例中浇筑试件的有机高分子硅胶(HTV)模具。Fig. 3 is an organopolymer silicone (HTV) mold for pouring a test piece in an embodiment of the present application.
图4为本发明中用于加工云母片节理的钢模具;其中a为结构图,b为实物图。Fig. 4 is the steel mold used for processing mica sheet joints in the present invention; wherein a is a structural diagram, and b is a physical diagram.
图5为本申请一实施例中所制备的以透明云母片为材质的节理面;其中a为12(短轴)×17 mm(长轴)椭圆形,b为φ15 mm圆型,c为15×20 mm椭圆形,d为13×20 mm椭圆形。Figure 5 is a joint surface made of transparent mica sheets prepared in an embodiment of the present application; where a is 12 (short axis) × 17 mm (major axis) ellipse, b is φ15 mm round, and c is 15 ×20 mm oval, d is 13×20 mm oval.
图6为本申请一实施例中实施过程中骨料选择不当导致制备失败的试件;其中,a为因骨料密度过大而导致沉底,b为骨料与树脂等原材料发生胶结反应导致试件膨胀。Figure 6 is a test piece that failed due to improper selection of aggregates in the implementation process of an embodiment of the present application; among them, a is the sinking of the bottom due to excessive aggregate density, and b is the result of cementation reactions between aggregates and resins and other raw materials The specimen expands.
图7为本申请一实施例中中骨料采用不同体形参数时的示意图。Fig. 7 is a schematic diagram of different shape parameters of aggregates in an embodiment of the present application.
图8为本申请一实施例中不同骨料添加量和体形参数时所制作完成的试件;其中a为2 mm粒径蓝色橡胶颗粒,b为1.2 mm粒径聚乙烯塑料颗粒。Fig. 8 shows the completed test pieces with different aggregate additions and body shape parameters in an embodiment of the present application; where a is blue rubber particles with a particle size of 2 mm, and b is polyethylene plastic particles with a particle size of 1.2 mm.
图9为本申请一实施例中模具材质问题导致制备失败的试件;其中,a为模具脱模后在试件表面形成密集的气泡,b为因模具不耐高温而被试件固化过程产生的热量扭曲变形。Figure 9 is a test piece that failed to be prepared due to mold material problems in an embodiment of the present application; where, a is the formation of dense air bubbles on the surface of the test piece after the mold is demoulded, and b is the formation of dense air bubbles on the surface of the test piece due to the inability of the mold to withstand high temperatures. distorted by heat.
图10为本申请另一实施例中内置单节理试件裂纹发展前期的现象,其中a为试件的正视图,b为试件的侧视图。Fig. 10 shows the early stage of crack development of the built-in single-joint test piece in another embodiment of the present application, where a is the front view of the test piece, and b is the side view of the test piece.
图11为本申请另一实施例中内置单节理试件裂纹发展后期的现象;其中a为试件的正视图,b为试件的侧视图。Fig. 11 is the phenomenon of the later stage of crack development of the built-in single-joint test piece in another embodiment of the present application; where a is the front view of the test piece, and b is the side view of the test piece.
具体实施方式Detailed ways
下面结合附图和实施例来说明本申请的具体实施方式,但以下实施例只是用来详细说明本申请,并不以任何方式限制本发明的范围。The specific implementation of the present application will be described below in conjunction with the accompanying drawings and examples, but the following examples are only used to describe the present application in detail, and do not limit the scope of the present invention in any way.
在以下实施例中所涉及的仪器设备如无特别说明,均为常规仪器设备;所涉及的原材料如无特别说明,均为市售常规原材料;所涉及的检测方法及试验方法,如无特别说明则均为常规方法。The instruments and equipment involved in the following examples are conventional instruments and equipment unless otherwise specified; the raw materials involved are commercially available conventional raw materials unless otherwise specified; the detection methods and test methods involved are all conventional if not specified are conventional methods.
岩体内部大量矿物颗粒、孔隙、裂纹和节理的存在其内部结构极为复杂,而且对实际工程应用影响较大;因此对于岩体中裂隙等的研究非常重要。为了模拟岩石的非均质性,改善类岩石材料的力学性能,在纯树脂材料的基础上,加入透明石英砂,预置三维内置节理面,采用整体浇铸制作类岩石试件进行室内实验。通过实验选取合适的骨料来模拟岩石的非均质性,骨料的材质、粒径、物理化学性质、力学性能等都需要着重考虑,骨料的选材与粒径的选择是需要解决的重难点。岩体内部的宏观裂隙通过在模具中预先埋设三维内置裂隙进行模拟,预制三维裂隙的选材、切割、定位是实验成功的关键。The existence of a large number of mineral particles, pores, cracks and joints in the rock mass has an extremely complex internal structure, and has a great impact on practical engineering applications; therefore, it is very important for the study of cracks in rock mass. In order to simulate the heterogeneity of rocks and improve the mechanical properties of rock-like materials, on the basis of pure resin materials, transparent quartz sand is added, three-dimensional built-in joint surfaces are preset, and rock-like specimens are made by integral casting for indoor experiments. To simulate the heterogeneity of rock by selecting suitable aggregates through experiments, the material, particle size, physical and chemical properties, and mechanical properties of aggregates need to be considered emphatically. difficulty. The macroscopic cracks inside the rock mass are simulated by pre-burying the three-dimensional built-in cracks in the mold. The material selection, cutting and positioning of the prefabricated three-dimensional cracks are the key to the success of the experiment.
实施例一:基于骨料增脆降韧的透明类岩石树脂材料试件制备方法,具体包括如下步骤:Embodiment 1: A method for preparing a transparent rock-like resin material specimen based on aggregate brittleness and toughness reduction, which specifically includes the following steps:
(1)树脂、固化剂、固化促进剂的配制(1) Preparation of resin, curing agent and curing accelerator
称量CY-39型树脂1000 g,YS-T31型固化剂340 g,二硫代二苯并噻唑固化促进剂40 g,将其倒入搅拌桶中,用玻璃棒不断搅拌使之充分混合形成混合料,容器侧壁和底部的树脂也要充分混合,之后放入真空箱中做除气泡处理。Weigh 1000 g of CY-39 type resin, 340 g of YS-T31 type curing agent, and 40 g of dithiodibenzothiazole curing accelerator, pour them into the mixing bucket, stir continuously with a glass rod to fully mix to form The mixture, the resin on the side wall and bottom of the container should also be fully mixed, and then placed in a vacuum box for debubbling.
所选CY-39型树脂无味无害、稳定性好、粘结力强、固化速度快、固化反应后强度高等优点;在加入固化剂YS-T31后,会发生交联反应,生成具有三维网络的热固性材料,强度大大增高,固化后的试件力学性能与岩石非常相似。固化剂的选择和用量是影响其力学性能的最大因素。The selected CY-39 type resin has the advantages of odorless and harmless, good stability, strong adhesion, fast curing speed, and high strength after curing reaction; after adding curing agent YS-T31, a crosslinking reaction will occur, forming a three-dimensional network The strength of the thermosetting material is greatly increased, and the mechanical properties of the cured specimen are very similar to those of the rock. The choice and amount of curing agent is the biggest factor affecting its mechanical properties.
(2)骨料的拌合(2) Mixing of aggregates
在步骤(1)除气泡处理后的混合料中,加入占混合料质量5%的骨料,振捣充分后放置离心台处理2分钟,再搅拌均匀后进行4分钟的除气泡处理。Add aggregates accounting for 5% of the mass of the mixture to the mixture after step (1) degassing treatment, place it on a centrifuge table for 2 minutes after sufficient vibration, and then perform 4 minutes of degassing treatment after stirring evenly.
对于类岩石试件中骨料材质的选择,进行大量的试验探索,其中包括选取统一粒径的多种材料进行探索的试验,如聚乙烯塑料颗粒、亚克力实心圆珠、PVC注塑颗粒、天蓝色亚克力微珠、蓝色亚克力微珠、透明石英砂等,结果表明:透明石英砂密度与混合料相近,混合后能均匀分布在混合料中,不会与树脂原料发生反应,颜色透明不影响试件的透明度;而其它所选材料在浇铸试件时,骨料质量太轻会很容易聚集,无法均匀的分布在树脂混合料中,不能满足孔隙分布特征要求;密度过大过小都会使得骨料分布不均匀,导致沉底或者漂浮在试件上部,无法满足对骨料分布的均匀程度和致密程度的要求(见图9);颜色过深会影响试件的透明度,不方便观察试件固化过程以及裂隙扩展过程。For the selection of aggregate materials in rock-like specimens, a large number of experimental explorations have been carried out, including the selection of various materials with uniform particle sizes, such as polyethylene plastic particles, acrylic solid beads, PVC injection particles, sky blue Acrylic microbeads, blue acrylic microbeads, transparent quartz sand, etc. The results show that the density of transparent quartz sand is similar to that of the mixture. The transparency of the piece; while other selected materials are too light to aggregate easily when casting the test piece, and cannot be evenly distributed in the resin mixture, which cannot meet the requirements of the pore distribution characteristics; too large or too small density will make the bone The uneven distribution of aggregates leads to sinking or floating on the upper part of the specimen, which cannot meet the requirements for the uniformity and compactness of aggregate distribution (see Figure 9); if the color is too dark, it will affect the transparency of the specimen, making it inconvenient to observe the specimen solidification process and crack propagation process.
在此期间,进一步研究了骨料粒径大小对试件力学特性的影响,例如,选用6组不同粒径(0.1~0.2 mm、0.2~0.4 mm、0.4~0.85 mm、0.85~2 mm、2~3.5 mm、3.5~5 mm)的石英砂作为骨料,制备了6组不同粒径的类岩石试件,对其进行多种力学实验研究骨料的粒径对于试件力学性能的影响;结果表明:随着粒径的增大,试件的抗压强度呈现增加的趋势,且逐渐转变为脆性破坏;而骨料粒径较小时对试件力学性能改善不明显,并且不利于观察,粒径过大的情况下试件胶结程度较低,孔隙增多,试样接近张拉破坏,确定石英砂粒径为0.6~0.8 mm较适宜。确定骨料粒径以后进一步经过实验与分析,得出结果:将骨料制成中空结构,更接近天然岩石的内部构造,其力学性能得到改善,更符合对骨料结构上的要求。此种情况下制备出的试件强度高,能够清晰地观察到试件截面骨料颗粒的分布,不会影响试件的变形特征,力学性能与多种岩石较为接近。During this period, the effect of aggregate particle size on the mechanical properties of the specimen was further studied. For example, six groups of different particle sizes (0.1-0.2 mm, 0.2-0.4 mm, 0.4-0.85 mm, ~3.5 mm, 3.5~5 mm) quartz sand was used as aggregate, and 6 groups of rock-like specimens with different particle sizes were prepared, and a variety of mechanical experiments were carried out on them to study the influence of aggregate particle size on the mechanical properties of the specimens; The results show that: with the increase of the particle size, the compressive strength of the specimen shows an increasing trend, and gradually transforms into brittle failure; and when the aggregate particle size is small, the mechanical properties of the specimen are not significantly improved, and it is not conducive to observation. When the particle size is too large, the degree of cementation of the specimen is low, the pores increase, and the sample is close to tensile failure. It is determined that the particle size of quartz sand is 0.6-0.8 mm. After determining the particle size of the aggregate, after further experiments and analysis, the results are obtained: the aggregate is made into a hollow structure, which is closer to the internal structure of natural rock, and its mechanical properties are improved, which is more in line with the requirements for the aggregate structure. In this case, the strength of the prepared specimen is high, and the distribution of aggregate particles in the cross-section of the specimen can be clearly observed without affecting the deformation characteristics of the specimen, and the mechanical properties are close to those of various rocks.
(3)预制节理的埋设(3) Embedding of prefabricated joints
在硅胶模具两侧确定节理面的投影点,钻孔,用棉线牵引实现节理面的定位,本例在试件中心位置处预埋节理面,设置节理与水平面呈45°夹角。Determine the projection point of the joint surface on both sides of the silicone mold, drill holes, and use cotton thread to pull to realize the positioning of the joint surface. In this example, the joint surface is pre-embedded at the center of the test piece, and the angle between the joint and the horizontal plane is set to be 45°.
本例中预制节理面选用厚度为0.1 mm的云母片,云母片本身作为一种层状岩石,相较于金属、塑料、树脂、不锈钢片等材质,其刚度低不会影响试件的强度和变形;化学性质稳定,不会与树脂、固化剂发生反应;定位方便用来模拟天然岩石中存在的中空裂隙非常适合。云母片使用定制钢模具进行冲压,裁制成固定尺寸的椭圆形预制裂隙。制作不同尺寸的裂隙,可以研究裂隙尺寸、倾角、位置等对于试件强度和裂隙扩展的影响;拓展可以研究多裂隙数目、间距、相对位置、相对张开度等对裂隙扩展和岩体破坏的影响。In this example, the prefabricated joint surface uses a mica sheet with a thickness of 0.1 mm. The mica sheet itself is a layered rock. Compared with metal, plastic, resin, stainless steel sheets and other materials, its low stiffness will not affect the strength and Deformation; stable chemical properties, will not react with resins and curing agents; easy to locate, very suitable for simulating hollow cracks existing in natural rocks. The mica sheet is stamped using a custom steel die and cut into oval prefabricated slits of fixed dimensions. Cracks of different sizes can be made to study the effects of crack size, inclination, position, etc. on the strength of the specimen and crack expansion; expansion can be used to study the number, spacing, relative position, and relative opening of multiple cracks. The influence of crack expansion and rock mass damage.
所述加工预制三维裂隙的钢模具由金属底座和冲击柱组成,冲击柱可以在椭圆形孔洞内自由活动。制作了三种尺寸的椭圆型钢模具,用来对云母片进行冲压加工,解决了以往手工裁剪云母片,会出现的毛边,尖角,截面粗糙引起应力集中的问题。使用钢模具裁制的云母片尺寸精确,截面光滑,可以精确控制云母片的尺寸,减少人工误差。The steel mold for processing and prefabricating three-dimensional cracks is composed of a metal base and an impact column, and the impact column can move freely in the oval hole. Three sizes of elliptical steel molds were made to stamp mica sheets, which solved the problem of stress concentration caused by burrs, sharp corners, and rough cross-sections in the past when cutting mica sheets by hand. The size of the mica sheet cut by the steel mold is accurate, and the cross section is smooth, which can accurately control the size of the mica sheet and reduce manual errors.
上述制备试件的硅胶模具是上部开口的方形盒体,并通过有机绝缘硅脂密封形成一个整体,可以根据试验所需定制相应的尺寸。相比前人所用的玻璃、不锈钢、聚甲基丙烯酸甲酯(PMMA)、聚氯乙烯(PVC)等模具,硅胶化学性质稳定、内壁不易附着气泡,质软易于脱模。另外硅胶具有高透明性,可以清晰的观察到试件固化过程。此外,硅胶模具内置三维节理面通过钻孔,牵拉细线定位更为方便,在模具两侧不同位置钻孔,可以制作含不同数量、不同角度、不同相对位置的试件。The above-mentioned silicone mold for preparing the test piece is a square box with an upper opening, and is sealed with organic insulating silicone grease to form a whole, and the corresponding size can be customized according to the test requirements. Compared with glass, stainless steel, polymethyl methacrylate (PMMA), polyvinyl chloride (PVC) and other molds used by the predecessors, the chemical properties of silicone are stable, the inner wall is not easy to attach air bubbles, and it is soft and easy to demould. In addition, the silica gel has high transparency, and the curing process of the specimen can be clearly observed. In addition, the built-in three-dimensional joint surface of the silicone mold is drilled, and it is more convenient to pull the thin wire for positioning. Drilling holes at different positions on both sides of the mold can make test pieces with different numbers, different angles, and different relative positions.
(4)试件的浇筑(4) Pouring of test pieces
将预埋好节理面的硅胶模具置于工作台上,将步骤(2)加入骨料的混合料用玻璃棒引流入模具浇筑成型;浇筑后将模具放入真空箱做除气泡处理25分钟,然后放入18℃恒温干燥鼓风箱养护40小时,即可拆模。Place the silicone mold with pre-embedded joint surface on the workbench, and pour the mixture added with aggregate in step (2) into the mold with a glass rod for casting; after pouring, put the mold in a vacuum box for 25 minutes to remove air bubbles. Then put it into a 18°C constant temperature drying blower box for curing for 40 hours, and then the mold can be removed.
(5)试件的养护(5) Maintenance of specimens
之后将试件放入恒温干燥鼓风箱,设置不同的养护温度和时间进行养护,本实例设置养护温度为70℃,养护时间为24小时,得到与岩石脆性特性非常相似的骨料增脆降韧的透明类岩石树脂试件,其在-15~-10℃条件下脆性度达到9.12,较之前人所制备的纯树脂类岩石试件和3D打印光敏树脂试件有了大幅提升,力学性能与岩石更为接近;较之水泥砂浆类岩石材料,强度有所提升,透明度及其可视度是不可比拟的优势;与多种真实岩石的力学性能较为接近。本发明树脂材料在-15~-10℃下的主要力学参数如表1所示,此外,Dyskin和Wong的实验温度为-50℃、Song的实验温度为-20℃。Afterwards, put the specimen into the constant temperature drying blower box, and set different curing temperatures and times for curing. In this example, the curing temperature is set at 70°C, and the curing time is 24 hours. The brittleness and toughness of aggregates that are very similar to those of rock brittleness are obtained. The transparent rock resin specimen has a brittleness of 9.12 at -15 to -10°C, which is greatly improved compared with the pure resin rock specimens and 3D printed photosensitive resin specimens prepared before. The rock is closer; compared with the cement mortar rock material, the strength has been improved, and the transparency and visibility are incomparable advantages; the mechanical properties of a variety of real rocks are closer. The main mechanical parameters of the resin material of the present invention at -15 to -10°C are shown in Table 1. In addition, the experimental temperature of Dyskin and Wong is -50°C, and the experimental temperature of Song is -20°C.
表1 本发明的非均质树脂试件和其它透明类岩石材料以及部分真实岩石的物理力学参数对比Table 1 Comparison of physical and mechanical parameters between the heterogeneous resin specimen of the present invention and other transparent rock-like materials and some real rocks
。 .
从表1中可以看出,本发明的非均质树脂试样与真实岩石的力学参数比较接近,因此能够在一定程度上模拟这些岩石,且本发明所得试件具有高透明性、易于肉眼直接观察等特点。As can be seen from Table 1, the heterogeneous resin sample of the present invention is relatively close to the mechanical parameters of real rocks, so these rocks can be simulated to a certain extent, and the obtained test piece of the present invention has high transparency and is easy to be directly seen by naked eyes. Observation and other characteristics.
实施例二:验证试验Embodiment two: Verification test
本发明制备的试件易于制取、可重复性强,通过制作一组内置裂隙完全相同的类岩石试件,对其进行多种力学实验,如单轴压缩、巴西劈裂等,将其各自加载到某一状态后进行卸载,拍照记录,可以得到内置裂隙扩展演化全过程,如图10为加压到20 MPa后卸载得到的裂隙发展前期的现象,图11为加压到90 MPa后卸载得到的裂隙发展后期的现象。全程应力应变曲线可由一个试件全程压缩过程获得。The test piece prepared by the present invention is easy to prepare and has strong repeatability. By making a group of rock-like test pieces with identical built-in cracks, various mechanical experiments are carried out on them, such as uniaxial compression, Brazilian splitting, etc., and their respective After loading to a certain state, unload and take pictures to record, the whole process of the built-in crack expansion and evolution can be obtained. Figure 10 shows the phenomenon in the early stage of crack development obtained by unloading after pressurizing to 20 MPa, and Figure 11 shows the unloading after pressurizing to 90 MPa The resulting phenomenon of the later stages of crack development. The whole stress-strain curve can be obtained from the whole compression process of a specimen.
对内含单节理类岩石树脂试件加压,观察裂隙扩展演化过程,分析岩石破坏规律。试件在加压条件下裂隙扩展演化经历初始阶段,之后进入弹性变形阶段,这一阶段预制节理上端有翼裂纹萌生,随后,预制裂隙上下端部均生成翼裂纹,且扩展规模都近似同步。随着压力增大,进入裂纹扩展阶段,此时,在预制裂隙上端的包裹式翼裂纹两侧附近,分别有1个和2个特别明显的花斑形裂纹,而预制裂隙下端,与包裹式翼裂纹两侧紧邻,各有1个相对较小的花斑形裂纹。最后进入裂纹加速扩展阶段,花瓣形裂纹和竖直型裂纹继续沿着加载方向扩展,试件承载力开始下降,同时听到试件发出密集的噼啪声,竖直型大裂纹形成宏观破裂面最终将试件劈开,呈现脆性劈裂破坏。Pressurize the rock resin specimen containing single joints, observe the crack expansion and evolution process, and analyze the rock failure law. Under the condition of pressure, the crack propagation evolution of the specimen went through the initial stage, and then entered the elastic deformation stage. In this stage, wing cracks were initiated at the upper end of the prefabricated joints. Subsequently, wing cracks were generated at the upper and lower ends of the prefabricated cracks, and the expansion scales were approximately synchronous. As the pressure increases, it enters the stage of crack propagation. At this time, near the two sides of the wrapped wing crack at the upper end of the prefabricated crack, there are 1 and 2 particularly obvious mottled cracks respectively, while the lower end of the prefabricated crack, and the wrapped wing crack The two sides of the wing cracks are adjacent to each other, and each has a relatively small piebald crack. Finally, it enters the stage of accelerated crack growth, petal-shaped cracks and vertical cracks continue to expand along the loading direction, and the bearing capacity of the specimen begins to decline. At the same time, dense crackling sounds are heard from the specimen. The specimen was split open, showing brittle splitting failure.
上面结合附图和实施例对本发明作了详细的说明,但是,所属技术领域的技术人员能够理解,在不脱离本发明构思的前提下,还可以对上述实施例中的各个具体参数进行变更,或者是对相关部件、结构及材料进行等同替代,从而形成多个具体的实施例,均为本发明的常见变化范围,在此不再一一详述。The present invention has been described in detail above in conjunction with the accompanying drawings and embodiments. However, those skilled in the art can understand that without departing from the concept of the present invention, the specific parameters in the above embodiments can also be changed. Alternatively, relevant components, structures, and materials are equivalently substituted to form multiple specific embodiments, all of which are common variation scopes of the present invention, and will not be described in detail here.
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