CN114636637B - In-situ measurement device for suspended matter concentration and working method - Google Patents
In-situ measurement device for suspended matter concentration and working method Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及海洋原位观测技术领域,具体而言,特别涉及一种悬浮物浓度的原位测定装置及工作方法。The invention relates to the technical field of marine in-situ observation, in particular to an in-situ measuring device and working method for the concentration of suspended matter.
背景技术Background technique
浊度计结合抽滤标定是当前海洋悬浮物浓度观测的主流方式。浊度计是通过测定样品的光学(或声学)后向散射强度间接测量悬浮物浓度的常规海洋观测设备,由于悬浮物颗粒形态、粒径组份存在差异,取水样抽滤标定浊度计仍是当前海洋观测不可或缺的环节。The turbidity meter combined with suction filtration calibration is the current mainstream way to observe the concentration of suspended matter in the ocean. The turbidity meter is a conventional ocean observation device that indirectly measures the concentration of suspended solids by measuring the optical (or acoustic) backscattering intensity of the sample. Due to the differences in the shape and particle size components of the suspended solids, the turbidimeter is calibrated by taking water samples and suction filtration. It is still an indispensable part of current ocean observation.
抽滤是海洋悬浮物富集取样不可替代的重要手段,广泛应用于海洋悬浮沉积物、海洋微塑料、海洋颗粒污染物等科学研究。传统取水抽滤测定悬浮物浓度的方法,往往存在样品自然沉淀、取样不均、样品量不足、反复取水环境扰动大、作业时间长、船时成本高等问题。Suction filtration is an irreplaceable important means of enrichment and sampling of marine suspended matter, and is widely used in scientific research on marine suspended sediments, marine microplastics, and marine particulate pollutants. The traditional method of water extraction and suction filtration to determine the concentration of suspended solids often has problems such as natural sedimentation of samples, uneven sampling, insufficient sample volume, large environmental disturbance of repeated water intake, long operation time, and high cost of ship time.
专利CN202120515500.4公开了一种海洋多通道原位抽滤装置,通过过滤装置、水下泵、水下电磁选通阀组、水下过滤集成装置、水下数字流量计及水下中控与供电装置,可实现水下对水体悬沙进行原位分时次进行取样和过滤,具有节省人力、原位保真获取样品等优点。Patent CN202120515500.4 discloses a marine multi-channel in-situ suction filtration device, through the filtration device, underwater pump, underwater electromagnetic gating valve group, underwater filtering integrated device, underwater digital flowmeter and underwater central control and The power supply device can realize in-situ and time-sharing sampling and filtering of suspended sediment underwater, which has the advantages of saving manpower and obtaining samples in situ with fidelity.
上述专利中重点涉及海洋取样设备,同时提及悬浮颗粒物浓度测定的功能期许,但若要实现准确测定功能仍存在以下几点问题需要解决:(1)后抽滤得到的样品会掺杂前面样品残留影响,且未考虑自然沉降影响,测定结果并不准确。上述专利申请中水泵进水口连接粗过滤装置,出水口连接电磁阀再连接到过滤装置,其本质是加压过滤而非负压抽滤。且不讨论粗过滤器对悬浮物是否有筛选影响,样品随水流先后通过粗过滤装置、水泵体、电磁阀,最后经过过滤器被富集捕捉。在实施过程中前一次抽滤过程不可避免在粗过滤器管道、水泵腔体等部位残留样品,而下一次抽滤时残留样品又随机比例地混入了下一样品,同时又有新的残留引入。此外,上述发明也没有考虑并解决装置收放过程水体交换以及悬浮物长期自然沉降对样品结果准确性的影响。(2)逐个抽滤存在一定局限性,简单设定抽滤体积或抽滤时间控制抽滤效果的方式存在很大不确定性。实验室抽滤的实施经验可知:不同层位、不同水体、不同悬浮物的取样水量并不唯一,逐个样品抽滤效率低。如果水体悬浮物含量很低,抽滤体积小或抽滤时间短,会出现样品量富集不足的问题;如果水体悬浮物含量很高,会出现抽滤体积无法在有限时间达到的问题,或者长时间高压、低流量滤膜破损的情况。The above-mentioned patents focus on marine sampling equipment, and at the same time mention the functional expectation of the measurement of suspended particulate matter concentration, but there are still the following problems to be solved in order to achieve accurate measurement functions: (1) The sample obtained by post-suction filtration will be mixed with the previous sample Residual effects, and the effects of natural settlement are not considered, the measurement results are not accurate. In the above-mentioned patent application, the water inlet of the water pump is connected to the coarse filter device, and the water outlet is connected to the solenoid valve and then connected to the filter device, which is essentially pressurized filtration rather than negative pressure suction filtration. Regardless of whether the coarse filter has an effect on the screening of suspended solids, the sample passes through the coarse filter device, the water pump body, the solenoid valve successively with the water flow, and finally passes through the filter to be enriched and captured. In the implementation process, the previous suction filtration process inevitably left samples in the coarse filter pipe, water pump cavity, etc., and the residual samples were randomly mixed into the next sample in the next suction filtration, and new residues were introduced at the same time. . In addition, the above-mentioned invention does not consider and solve the impact of water body exchange and long-term natural settlement of suspended matter on the accuracy of sample results during the retraction process of the device. (2) There are certain limitations in one-by-one suction filtration, and there is great uncertainty in the way of simply setting the suction filtration volume or suction filtration time to control the suction filtration effect. The implementation experience of laboratory suction filtration shows that the sampling water volume of different layers, different water bodies, and different suspended solids is not unique, and the efficiency of suction filtration one by one is low. If the content of suspended solids in the water body is very low, the suction filtration volume is small or the suction filtration time is short, there will be a problem of insufficient sample enrichment; if the content of suspended solids in the water body is high, there will be a problem that the suction filtration volume cannot be reached within a limited time, or Long-term high-pressure, low-flow filter membrane damage.
发明内容Contents of the invention
为了弥补现有技术的不足,本发明提供了一种悬浮物浓度的原位测定装置及工作方法,能够克服水体自然交换、悬浮物长期沉降以及不同样品测定过程的残留影响,有效保证了测定结果的准确性。同时,本发明创新地提出流量速率反馈控制方法,若干过滤器根据需要可预设任意编组,对浓度差异较大的水体具有更强的自动适应性。In order to make up for the deficiencies of the prior art, the present invention provides an in-situ measuring device and working method for the concentration of suspended solids, which can overcome the natural exchange of water bodies, long-term settlement of suspended solids, and the residual influence of different sample measurement processes, effectively ensuring the measurement results accuracy. At the same time, the present invention innovatively proposes a flow rate feedback control method, and several filters can be preset and grouped arbitrarily according to needs, which has stronger automatic adaptability to water bodies with large concentration differences.
本发明是通过如下技术方案实现的:一种悬浮物浓度的原位测定装置,包括主体框架,以及安装在其内部的水密控制舱、调速液泵、过滤器、夹式流量计和刚性连接管,主体框架分为上下两层,依次为上层的六棱锥框架和中层的六棱柱框架,六棱柱框架的六个侧棱向下延伸并且其底端安装有可拆卸配重块,上层的六棱锥框架的顶端设有框架吊点,六棱柱框架的中部设有固定抱箍,固定抱箍用于水密控制舱、调速液泵、夹式流量计和刚性连接管安装;The present invention is achieved through the following technical solutions: an in-situ measuring device for suspended solids concentration, including a main body frame, and a watertight control cabin installed inside it, a governor liquid pump, a filter, a clip-on flowmeter and rigid connections Tube, the main frame is divided into upper and lower layers, followed by the hexagonal pyramid frame on the upper layer and the hexagonal prism frame in the middle layer. The top of the pyramid frame is provided with a frame lifting point, and the middle part of the hexagonal frame is provided with a fixed hoop, which is used for the installation of the watertight control cabin, the governor liquid pump, the clip-type flowmeter and the rigid connection pipe;
水密控制舱通过水密线缆与调速液泵、夹式流量计连接进行供电、信号传输和反馈,水密控制舱的舱盖上同时设有水密连接器,其通过USB或串口线连接PC上位机,调速液泵的顶部设置有调速液泵进水口,和调速液泵出水口;The watertight control cabin is connected with the governor liquid pump and clip-type flowmeter through watertight cables for power supply, signal transmission and feedback. The hatch cover of the watertight control cabin is also equipped with a watertight connector, which is connected to the PC host computer through a USB or serial port cable. , the top of the speed regulating liquid pump is provided with a water inlet of the speed regulating liquid pump and a water outlet of the speed regulating liquid pump;
过滤器位于装置水体交换的最前端,安装在上层的六棱锥框架和中层的六棱柱框架之间的六边形框架上,每个六边形框架上均安装有一组过滤器,每组过滤器包括中空基座、电磁阀、下半壳、滤筛、滤膜、防溢球、上半壳和防尘帽,中空基座的一端设有基座出水口以及中空基座表面上设置的6个基座进水口,基座出水口通过刚性连接管依次与夹式流量计和调速液泵的调速液泵进水口相连,每个基座进水口处均装有电磁阀,电磁阀的一端与基座进水口相连,下半壳和上半壳均为圆锥形,下半壳的底端开设有下半壳出水口,下半壳出水口与电磁阀的另一端相连,下半壳的上部两侧分别设有下半壳固定孔并通过其与框架通过螺丝固定连接,下半壳的上部内侧设置有凹槽,滤筛安装在下半壳凹槽内,滤筛上面覆盖滤膜,上半壳压在滤膜之上,防溢球放置在上半壳和滤膜之间空腔内,上半壳的顶端开设有上半壳进水口,上半壳上方盖有防尘帽。The filter is located at the forefront of the water exchange of the device, installed on the hexagonal frame between the upper hexagonal pyramid frame and the middle hexagonal prism frame, each hexagonal frame is equipped with a set of filters, each set of filters It includes a hollow base, a solenoid valve, a lower half shell, a filter screen, a filter membrane, an anti-spill ball, an upper half shell and a dustproof cap. One end of the hollow base is provided with a water outlet of the base and 6 holes set on the surface of the hollow base. The water inlet of the base, the water outlet of the base is connected with the clip-type flowmeter and the water inlet of the speed regulating liquid pump of the speed regulating liquid pump in turn through a rigid connecting pipe, and each water inlet of the base is equipped with a solenoid valve, and the solenoid valve One end is connected to the water inlet of the base, the lower half shell and the upper half shell are both conical, the bottom of the lower half shell is provided with a water outlet of the lower half shell, and the water outlet of the lower half shell is connected with the other end of the solenoid valve, the lower half shell The lower half-shell fixing holes are respectively provided on both sides of the upper part of the upper part, and the lower half-shell is fixedly connected with the frame by screws. The upper inner side of the lower half-shell is provided with a groove, and the filter screen is installed in the groove of the lower half-shell, and the filter screen is covered with a filter membrane. The upper half shell is pressed on the filter membrane, the anti-spill ball is placed in the cavity between the upper half shell and the filter membrane, the top of the upper half shell is provided with an upper half shell water inlet, and the upper half shell is covered with a dustproof cap.
作为优选方案,调速液泵采用深海无刷直流电机驱动、PWM控制调速配合隔膜式真空液泵实现。As a preferred solution, the speed-regulating liquid pump is driven by a deep-sea brushless DC motor, PWM-controlled speed regulation and a diaphragm-type vacuum liquid pump.
作为优选方案,下半壳的凹槽处设有磁性块用于磁吸连接并夹紧固定滤膜。As a preferred solution, a magnetic block is provided at the groove of the lower half shell for magnetic connection and clamping to fix the filter membrane.
进一步地,防尘帽的内壁上设有磁体采用磁吸连接的方式盖在上半壳上,并且使得防尘帽和上半壳之间形成狭缝。Further, a magnet is provided on the inner wall of the dustproof cap to cover the upper half-shell in a magnetic connection, and a slit is formed between the dust-proof cap and the upper half-shell.
作为优选方案,防溢球的密度小于水,且其直径大于上半壳进水口的直径。As a preferred solution, the density of the anti-spill ball is lower than that of water, and its diameter is larger than that of the water inlet of the upper half shell.
作为优选方案,所述原位测定装置的底端通过钢缆依次连接声学释放器和配重,原位测定装置的顶端通过钢缆依次连接第二台原位测定装置和浮体材料。As a preferred solution, the bottom end of the in-situ measuring device is sequentially connected to the acoustic releaser and the counterweight through a steel cable, and the top of the in-situ measuring device is sequentially connected to the second in-situ measuring device and the buoyant material through a steel cable.
一种悬浮物浓度的原位测定装置的工作方法,具体包括以下步骤:A working method of an in-situ measuring device for suspended matter concentration, specifically comprising the following steps:
S1装置使用及布放:装置使用前用蒸馏水将过滤器、刚性连接管等清洗干净,更换提前烘干称前重的新滤膜并记录编号,用蒸馏水充分饱和排出装置管道和泵体空气,安装磁吸上半壳,从上半壳进水口缓慢注入蒸馏水,使防溢球上浮堵住过滤器上半壳进水口并安装磁吸防尘帽,避免装置布放、回收和原位长期过程中的水体及所含悬浮物交换进入过滤器中。连接PC上位机控制所有电磁阀处于初始常闭状态,通过输入程序参数设定抽滤时间序列。按照观测和取样需求,或点阵式布放于海底,或链式串联在锚系不同深度位置;S1 device use and layout: clean the filter and rigid connecting pipes with distilled water before using the device, replace the new filter membrane that has been dried and weighed in advance and record the serial number, and fully saturate the device pipe and pump body with distilled water. Install the magnetic upper half shell, slowly inject distilled water from the water inlet of the upper half shell, make the anti-spill ball float up to block the water inlet of the upper half shell of the filter and install the magnetic dustproof cap to avoid the long-term process of device deployment, recovery and in-situ The water body and the suspended matter contained in it are exchanged into the filter. Connect the PC host computer to control all solenoid valves to be in the initial normally closed state, and set the time sequence of suction and filtration by inputting program parameters. According to the requirements of observation and sampling, it can be arranged on the seabed in a dot matrix, or in series at different depths of the mooring system;
S2装置工作过程:到达程序预设时间,控制程序先控制对应编组若干电磁阀打开,接着启动调速液泵提供负压抽滤,通过夹式流量计实时获取抽滤速率,反馈调整液泵转速控制抽滤压力;水流在压差驱动下从防尘帽和上半壳之间狭缝进入,先后经过上半壳进水口、滤膜、滤筛、下半壳出水口、刚性连接管和调速液泵进水口,最后从调速液泵出水口排出;水中悬浮物随水流进入过滤器并停留富集在滤膜上;抽滤结束后,关闭电磁阀,停止调速液泵,记录过滤器编号和抽滤水样体积,完成一组次抽滤;防溢球在浮力作用下上浮堵住过滤器上半壳进水口,再次隔绝水体及悬浮物交换;待程序执行下一个时间序列,对下一编组过滤器重复执行上述步骤,完成所有原位抽滤取样;Working process of S2 device: When the preset time of the program is reached, the control program first controls the opening of several solenoid valves in the corresponding group, and then starts the speed-regulating liquid pump to provide negative pressure suction filtration, obtains the suction filtration rate in real time through the clip-on flowmeter, and adjusts the speed of the liquid pump with feedback Control the suction filtration pressure; the water flow enters from the slit between the dust cap and the upper half shell driven by the pressure difference, and passes through the water inlet of the upper half shell, the filter membrane, the filter screen, the water outlet of the lower half shell, the rigid connecting pipe and the regulating valve. The water inlet of the speed liquid pump is finally discharged from the water outlet of the speed control liquid pump; the suspended matter in the water enters the filter with the water flow and stays enriched on the filter membrane; after the suction filtration is completed, close the solenoid valve, stop the speed control liquid pump, and record the filtration The filter number and the volume of the filtered water sample are used to complete a set of suction filtration; the anti-spill ball floats up under the action of buoyancy to block the water inlet of the upper half shell of the filter, and again isolates the exchange of water and suspended matter; when the program executes the next time sequence, Repeat the above steps for the next group of filters to complete all in-situ sampling;
S3装置回收后处理:观测结束后,将装置回收并连接PC上位机,取下过滤器的磁吸防尘帽,手动控制电磁阀打开并继续抽滤至对应过滤器中无水残留;从上半壳进水口缓慢注入蒸馏水清洗过滤器上半壳内壁,注意控制注入速度不要溢出,重复清洗操作直至悬浮物全部冲洗富集至滤膜上;将剩余液体抽干,取下上半壳,完成滤膜收集并保存;逐一完成所有滤膜收集工作,将装置用淡水冲洗维护并妥善存放;S3 Device recycling post-processing: After the observation is over, recover the device and connect it to the PC host computer, remove the magnetic dustproof cap of the filter, manually control the solenoid valve to open and continue to filter until there is no water residue in the corresponding filter; Slowly inject distilled water into the water inlet of the half-shell to clean the inner wall of the upper half-shell of the filter, pay attention to control the injection speed so as not to overflow, repeat the cleaning operation until all the suspended matter is washed and enriched on the filter membrane; drain the remaining liquid, remove the upper half-shell, and complete Collect and store the filter membranes; complete all the filter membrane collection work one by one, rinse and maintain the device with fresh water and store it properly;
S4浓度计算:将富集后的滤膜烘干、称后重记录,根据前重m1、后重m2及抽滤体积V计算即可获得悬浮物质量浓度Cm=(m2-m1)/V。S4 Concentration Calculation: Dry the enriched filter membrane, weigh and record, and calculate the suspended matter mass concentration C m = (m 2 -m 1 )/V.
本发明由于采用了以上技术方案,与现有技术相比使其具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects due to the adoption of the above technical scheme:
1. 本发明装置独特的防尘帽和防水体交换设计,可以有效避免水体交换和悬浮物自然沉降等外源影响,同时将过滤器置于水体交换最前端,悬浮物直接进入过滤器富集捕获,样品间无互相干扰,保证了样品纯度,有效提升了浓度测定结果准确性。1. The unique dust-proof cap and waterproof body exchange design of the device of the present invention can effectively avoid external influences such as water body exchange and natural settlement of suspended solids, and at the same time, the filter is placed at the forefront of water body exchange, and suspended solids directly enter the filter for enrichment Capture, no mutual interference between samples, ensure the purity of the samples, and effectively improve the accuracy of the concentration determination results.
2. 本发明装置创新地提出了抽滤体积速率反馈控制法,能够应对浓度差异较大的悬浮物原位抽滤测定情况,保证了能够富集捕获足够样品的同时避免滤膜损坏失效,适应性更广。2. The device of the present invention innovatively proposes a suction filtration volume rate feedback control method, which can cope with the in-situ suction filtration measurement of suspended matter with large concentration differences, and ensures that sufficient samples can be enriched and captured while avoiding filter membrane damage and failure, adapting to Broader.
3、本发明装置兼具长时间序列原位观测和富集取样两种功能,可以搭载CTD、浊度计等观测传感器,既可点阵式布放于海底,也能以链式串联在锚系不同深度位置,有助于长期观测捕捉事件过程中目标悬浮物的连续变化过程,可更好的为海洋观测提供技术补充。3. The device of the present invention has two functions of long-term in-situ observation and enrichment sampling. It can be equipped with observation sensors such as CTD and turbidimeter. The different depth positions of the system are helpful for long-term observation and capture of the continuous change process of the target suspended matter during the event, and can better provide technical supplements for ocean observation.
4. 本发明结构设计合理,工作过程稳定,应用范围广,具有较高的科学和商业价值。4. The invention has reasonable structural design, stable working process, wide application range and high scientific and commercial value.
本发明的附加方面和优点将在下面的描述部分中变得明显,或通过本发明的实践了解到。Additional aspects and advantages of the invention will become apparent in the description which follows, or may be learned by practice of the invention.
附图说明Description of drawings
本发明的上述和/或附加的方面和优点从结合下面附图对实施例的描述中将变得明显和容易理解,其中:The above and/or additional aspects and advantages of the present invention will become apparent and understandable from the description of the embodiments in conjunction with the following drawings, wherein:
图1为本发明的整体结构示意图;Fig. 1 is the overall structure schematic diagram of the present invention;
图2为本发明的部分结构示意图;Fig. 2 is a partial structural representation of the present invention;
图3为本发明中过滤器整体示意图;Fig. 3 is the overall schematic view of the filter in the present invention;
图4为本发明中防尘、防水体交换过滤器结构示意图;Fig. 4 is dustproof, waterproof body exchange filter structural representation among the present invention;
图5为本发明中防尘、防水体交换过滤器半剖结构示意图;Fig. 5 is the schematic diagram of half-section structure of dust-proof and water-proof body exchange filter in the present invention;
图6为本发明的两种布放方式示意图,Figure 6 is a schematic diagram of two deployment methods of the present invention,
其中,图1至图6中附图标记与部件之间的对应关系为:Wherein, the corresponding relationship between reference numerals and components in Fig. 1 to Fig. 6 is:
1框架,101六棱锥框架,102六棱柱框架,11框架吊点,12配重块,13固定抱箍,2水密控制舱,21水密连接器,3调速液泵,31调速液泵进水口,32调速液泵出水口,4过滤器,41中空基座,411基座进水口,412基座出水口,42电磁阀,43下半壳,431固定孔,432下半壳出水口,433磁性块,44滤筛,45滤膜,46防溢球,47上半壳,471上半壳进水口,472磁体,473狭缝,48防尘帽,5夹式流量计,6刚性连接管,7浮球或浮体材料,8配重,9钢缆,10声学释放器。1 frame, 101 hexagonal pyramid frame, 102 hexagonal prism frame, 11 frame lifting point, 12 counterweight, 13 fixed hoop, 2 watertight control cabin, 21 watertight connector, 3 speed regulating liquid pump, 31 speed regulating liquid pump inlet Water outlet, 32 water outlet of speed regulating liquid pump, 4 filters, 41 hollow base, 411 water inlet of base, 412 water outlet of base, 42 solenoid valve, 43 lower half shell, 431 fixing hole, 432 water outlet of lower half shell , 433 magnetic block, 44 filter screen, 45 filter membrane, 46 anti-spill ball, 47 upper half shell, 471 upper half shell water inlet, 472 magnet, 473 slit, 48 dust cap, 5 clip-on flow meter, 6 rigid Connecting pipe, 7 floating ball or floating body material, 8 counterweight, 9 steel cable, 10 acoustic releaser.
具体实施方式Detailed ways
为了能够更清楚地理解本发明的上述目的、特征和优点,下面结合附图和具体实施方式对本发明进行进一步的详细描述。需要说明的是,在不冲突的情况下,本申请的实施例及实施例中的特征可以相互组合。In order to understand the above-mentioned purpose, features and advantages of the present invention more clearly, the present invention will be further described in detail below in conjunction with the accompanying drawings and specific embodiments. It should be noted that, in the case of no conflict, the embodiments of the present application and the features in the embodiments can be combined with each other.
在下面的描述中阐述了很多具体细节以便于充分理解本发明,但是,本发明还可以采用其他不同于在此描述的方式来实施,因此,本发明的保护范围并不受下面公开的具体实施例的限制。In the following description, many specific details are set forth in order to fully understand the present invention. However, the present invention can also be implemented in other ways different from those described here. Therefore, the protection scope of the present invention is not limited by the specific implementation disclosed below. Example limitations.
下面结合图1至图6对本发明的实施例的悬浮物浓度的原位测定装置及工作方法进行具体说明。The in-situ measuring device and working method of the concentration of suspended solids according to the embodiment of the present invention will be described in detail below with reference to FIG. 1 to FIG. 6 .
如图图1至图5所示,本发明提出了一种悬浮物浓度的原位测定装置,包括主体框架1,以及安装在其内部的水密控制舱2、调速液泵3、过滤器4、夹式流量计5和刚性连接管6,主体框架1是整个装置的承载基础,附图给出了框架的一种实现形式,主体框架1分为上下两层,依次为上层的六棱锥框架101和中层的六棱柱框架102,六棱柱框架102的六个侧棱向下延伸并且其底端安装有可拆卸配重块12,用于调节装置整体重量和重心。上层的六棱锥框架101的顶端设有框架吊点11用于装置运输吊装,六棱柱框架102的中部设有固定抱箍13,固定抱箍13用于水密控制舱2、调速液泵3、夹式流量计5和刚性连接管6安装;As shown in Figures 1 to 5, the present invention proposes an in-situ measuring device for suspended solids concentration, including a main body frame 1, and a watertight control cabin 2, a speed regulating liquid pump 3, and a filter 4 installed inside it. , clip-type flowmeter 5 and rigid connecting pipe 6, the main frame 1 is the load-bearing basis of the whole device, and the accompanying drawing shows a realization form of the frame, the main frame 1 is divided into upper and lower layers, followed by the hexagonal pyramid frame of the upper layer 101 and the hexagonal prism frame 102 of the middle layer, the six side edges of the hexagonal prism frame 102 extend downwards and a detachable counterweight 12 is installed at its bottom end for adjusting the overall weight and center of gravity of the device. The top of the hexagonal pyramid frame 101 on the upper floor is provided with a frame lifting point 11 for device transportation and hoisting, and the middle part of the hexagonal prism frame 102 is provided with a fixed hoop 13, which is used for the watertight control cabin 2, the governor liquid pump 3, Clip-on flowmeter 5 and rigid connecting pipe 6 are installed;
水密控制舱2内设有电池组和控制电路,通过水密线缆与调速液泵3、夹式流量计5连接进行供电、信号传输和反馈,自动控制抽滤过程。水密控制舱2的舱盖上同时设有水密连接器21,其通过USB或串口线连接PC上位机,可根据需要将若干过滤器任意编组,预设抽滤序列,控制抽滤启停、记录抽滤体积和时间、实时反馈抽滤体积速率、控制液泵转速进而控制抽滤压力等。调速液泵3的顶部设置有调速液泵进水口31,和调速液泵出水口32;The watertight control cabin 2 is equipped with a battery pack and a control circuit, which are connected to the governor liquid pump 3 and the clip-on flowmeter 5 through watertight cables for power supply, signal transmission and feedback, and automatically control the suction and filtration process. The hatch cover of the watertight control cabin 2 is also equipped with a watertight connector 21, which is connected to the PC host computer through a USB or serial port line, and a number of filters can be grouped arbitrarily according to the needs, and the suction filtration sequence is preset to control the start and stop of the suction filtration and record Filtration volume and time, real-time feedback of filtration volume rate, control of liquid pump speed and further control of filtration pressure, etc. The top of the speed regulating liquid pump 3 is provided with a speed regulating liquid pump water inlet 31 and a speed regulating liquid pump water outlet 32;
过滤器4位于装置水体交换的最前端,安装在上层的六棱锥框架101和中层的六棱柱框架102之间的六边形框架上,每个六边形框架上均安装有一组过滤器4,每组过滤器4包括中空基座41、电磁阀42、下半壳43、滤筛44、滤膜45、防溢球46、上半壳47和防尘帽48,中空基座41的一端设有基座出水口412以及中空基座41表面上设置的6个基座进水口411,基座出水口412通过刚性连接管6依次与夹式流量计5和调速液泵3的调速液泵进水口31相连,每个基座进水口411处均装有电磁阀42,电磁阀42的一端与基座进水口411相连,下半壳43和上半壳47均为圆锥形,下半壳43的底端开设有下半壳出水口432,下半壳出水口432与电磁阀42的另一端相连,下半壳43的上部两侧分别设有下半壳固定孔431并通过其与框架通过螺丝固定连接,下半壳43的上部内侧设置有凹槽,滤筛44安装在下半壳43凹槽内,滤筛44上面覆盖滤膜45,上半壳47压在滤膜45之上,防溢球46放置在上半壳47和滤膜45之间空腔内,上半壳47的顶端开设有上半壳进水口471,上半壳47上方盖有防尘帽48。抽滤时环境水体从防尘帽48和上半壳47之间吸入,流经滤膜45和滤筛44时悬浮物被富集捕获,过滤后的水体从下半壳出水口432先后流经电磁阀42、中空基座41、刚性连接管6、夹式流量计5和调速液泵3,最终从调速液泵出水口32流出。如此,悬浮物随环境水体经过过滤器时即被富集捕获,不会在后续管道和泵体中留存,从而避免了不同过滤器间的相互影响。同时,不抽滤时防溢球和电磁阀分别将进、出水口封闭,环境水体与过滤器不交换,悬浮物自然沉降也不能进入过滤器,阻断了水体交换和外源引入。The filter 4 is located at the forefront of the water body exchange of the device, and is installed on the hexagonal frame between the hexagonal pyramid frame 101 of the upper layer and the hexagonal prism frame 102 of the middle layer, and a group of filters 4 are installed on each hexagonal frame, Every group of filters 4 comprises a hollow base 41, a solenoid valve 42, a lower half shell 43, a filter screen 44, a filter membrane 45, an anti-spill ball 46, an upper half shell 47 and a dustproof cap 48, and one end of the hollow base 41 is provided with There are base water outlets 412 and six base water inlets 411 provided on the surface of the hollow base 41. The base water outlets 412 are sequentially connected with the clip-type flowmeter 5 and the governor fluid of the governor fluid pump 3 through the rigid connecting pipe 6. The pump water inlet 31 is connected, each base water inlet 411 is equipped with a solenoid valve 42, one end of the solenoid valve 42 is connected with the base water inlet 411, the lower half shell 43 and the upper half shell 47 are conical, the lower half The bottom of the shell 43 is provided with a lower half shell water outlet 432, the lower half shell water outlet 432 is connected with the other end of the electromagnetic valve 42, and the upper two sides of the lower half shell 43 are respectively provided with a lower half shell fixing hole 431 and through it. The frame is fixedly connected by screws, the upper inner side of the lower half shell 43 is provided with a groove, the filter screen 44 is installed in the groove of the lower half shell 43, the filter screen 44 is covered with a filter membrane 45, and the upper half shell 47 is pressed on the filter membrane 45 The anti-spill ball 46 is placed in the cavity between the upper half shell 47 and the filter membrane 45, the top of the upper half shell 47 is provided with an upper half shell water inlet 471, and the upper half shell 47 is covered with a dust cap 48. During suction filtration, the ambient water is inhaled from between the dust cap 48 and the upper half shell 47, and the suspended solids are enriched and captured when flowing through the filter membrane 45 and the filter screen 44, and the filtered water flows through the water outlet 432 of the lower half shell successively. Electromagnetic valve 42 , hollow base 41 , rigid connecting pipe 6 , clip-on flow meter 5 and speed regulating liquid pump 3 finally flow out from water outlet 32 of speed regulating liquid pump. In this way, the suspended solids are enriched and captured when the ambient water passes through the filter, and will not remain in the subsequent pipeline and pump body, thereby avoiding the mutual influence between different filters. At the same time, the anti-overflow ball and the solenoid valve respectively seal the water inlet and outlet when the filter is not in use, so that the ambient water does not exchange with the filter, and the suspended matter cannot enter the filter due to natural sedimentation, which blocks the exchange of water and the introduction of external sources.
作为优选方案,调速液泵3采用深海无刷直流电机驱动、PWM控制调速配合隔膜式真空液泵实现。随着过滤器上悬浮物逐渐富集,抽滤体积速率逐渐变慢,调速液泵3运转速度也随压力和流量计反馈的抽滤速率而实时调整,维持抽滤压力稳定。抽滤启动条件为预设时间序列,停止条件优选设定抽滤速率阈值,即夹式流量计5检测到实时流量速率V≤预设值c*当前编组过滤器数量n。抽滤速率阈值根据滤膜面积、孔径大小、悬浮物特性等实验室经验获得。如此,可以在不确定悬浮物浓度特性情况下,既能够获取足够悬浮物样品,同时又保证滤膜不会破损失效。As a preferred solution, the speed-regulating liquid pump 3 is driven by a deep-sea brushless DC motor, PWM-controlled speed regulation and a diaphragm-type vacuum liquid pump. With the gradual enrichment of suspended matter on the filter, the suction filtration volume rate gradually slows down, and the operating speed of the governor liquid pump 3 is also adjusted in real time according to the pressure and the suction filtration rate fed back by the flowmeter, so as to maintain a stable suction filtration pressure. The start condition of the suction filtration is a preset time sequence, and the stop condition is preferably to set the suction filtration rate threshold, that is, the real-time flow rate V detected by the clip-on flowmeter 5 ≤ the preset value c*the number of filters in the current group n. The filtration rate threshold is obtained based on laboratory experience such as membrane area, pore size, and suspended solids characteristics. In this way, it is possible to obtain sufficient samples of suspended solids without determining the characteristics of the suspended solids concentration, and at the same time ensure that the filter membrane will not be damaged or invalidated.
作为优选方案,下半壳43的凹槽处设有磁性块433用于磁吸连接并夹紧固定滤膜45。As a preferred solution, a magnetic block 433 is provided at the groove of the lower half shell 43 for magnetic connection and clamping to fix the filter membrane 45 .
进一步地,防尘帽48的内壁上设有磁体472采用磁吸连接的方式盖在上半壳47上,并且使得防尘帽48和上半壳47之间形成狭缝473。Further, a magnet 472 is provided on the inner wall of the dust-proof cap 48 to cover the upper half-shell 47 in a magnetic connection manner, and a slit 473 is formed between the dust-proof cap 48 and the upper half-shell 47 .
作为优选方案,防溢球46的密度小于水,且其直径大于上半壳进水口471的直径。As a preferred solution, the density of the anti-spill ball 46 is lower than that of water, and its diameter is larger than that of the water inlet 471 of the upper half shell.
作为优选方案,本发明附图展示的六边形框架仅是本发明的一种具体实现形式,其结构包括但不限于图示。同时本发明框架可搭载CTD、浊度计等传感设备,根据需要配合浮球或浮体材料、释放器、配重块等,既能以点阵式布放于海底,也能以链式串联在锚系不同深度位置,使用方式灵活。所述原位测定装置的底端通过钢缆9依次连接声学释放器10和配重8,原位测定装置的顶端通过钢缆9依次连接第二台原位测定装置和浮体材料7。As a preferred solution, the hexagonal frame shown in the drawings of the present invention is only a specific implementation form of the present invention, and its structure includes but is not limited to the illustration. At the same time, the framework of the present invention can be equipped with sensing equipment such as CTD and turbidimeter, and can be equipped with floating balls or floating body materials, releasers, counterweights, etc. as required, and can be placed on the seabed in a dot matrix or in series in a chain It can be used flexibly at different depths of the mooring system. The bottom end of the in-situ measuring device is sequentially connected to the acoustic releaser 10 and the counterweight 8 through the steel cable 9 , and the top of the in-situ measuring device is connected to the second in-situ measuring device and the floating body material 7 through the steel cable 9 in turn.
一种悬浮物浓度的原位测定装置的工作方法,具体包括以下步骤:A working method of an in-situ measuring device for suspended matter concentration, specifically comprising the following steps:
S1装置使用及布放:装置使用前用蒸馏水将过滤器4、刚性连接管6等清洗干净,更换提前烘干称前重的新滤膜45并记录编号,用蒸馏水充分饱和排出装置管道和泵体空气,安装磁吸上半壳47,从上半壳进水口471缓慢注入蒸馏水,使防溢球46上浮堵住过滤器上半壳进水口471并安装磁吸防尘帽48,避免装置布放、回收和原位长期过程中的水体及所含悬浮物交换进入过滤器中。连接PC上位机控制所有电磁阀42处于初始常闭状态,通过输入程序参数设定抽滤时间序列。按照观测和取样需求,或点阵式布放于海底,如图6左所示,或链式串联在锚系不同深度位置,如图6右所示;S1 device use and deployment: clean the filter 4 and rigid connecting pipe 6 with distilled water before using the device, replace the new filter membrane 45 that has been dried and weighed in advance and record the serial number, fully saturate the device pipes and pumps with distilled water Install the magnetic suction upper half shell 47, inject distilled water slowly from the upper half shell water inlet 471, make the anti-spill ball 46 float up to block the filter upper half shell water inlet 471 and install the magnetic suction dustproof cap 48 to prevent the device from The water body and the suspended matter contained in the discharge, recovery and in-situ long-term process are exchanged into the filter. Connect the PC host computer to control all solenoid valves 42 to be in the initial normally closed state, and set the suction filtration time sequence by inputting program parameters. According to the requirements of observation and sampling, they can be laid on the seabed in a dot matrix, as shown in the left of Figure 6, or in series at different depths of the mooring system, as shown in the right of Figure 6;
S2装置工作过程:到达程序预设时间,控制程序先控制对应编组若干电磁阀42打开,接着启动调速液泵3提供负压抽滤,通过夹式流量计5实时获取抽滤速率,反馈调整液泵转速控制抽滤压力;水流在压差驱动下从防尘帽48和上半壳47之间狭缝473进入,先后经过上半壳进水口471、滤膜45、滤筛44、下半壳出水口432、刚性连接管6和调速液泵进水口31,最后从调速液泵出水口32排出;水中悬浮物随水流进入过滤器并停留富集在滤膜上;抽滤结束后,关闭电磁阀42,停止调速液泵3,记录过滤器编号和抽滤水样体积,完成一组次抽滤;防溢球46在浮力作用下上浮堵住过滤器上半壳进水口471,再次隔绝水体及悬浮物交换;待程序执行下一个时间序列,对下一编组过滤器重复执行上述步骤,完成所有原位抽滤取样;Working process of the S2 device: when the preset time of the program is reached, the control program first controls the opening of several solenoid valves 42 corresponding to the group, and then starts the speed regulating liquid pump 3 to provide negative pressure suction filtration, obtains the suction filtration rate in real time through the clip-on flowmeter 5, and feedbacks adjustment The speed of the liquid pump controls the filtration pressure; the water flow enters from the slit 473 between the dust cap 48 and the upper half shell 47 under the pressure difference drive, and passes through the water inlet 471 of the upper half shell, the filter membrane 45, the filter screen 44, and the lower half shell successively. The shell outlet 432, the rigid connecting pipe 6 and the water inlet 31 of the speed regulating liquid pump are finally discharged from the water outlet 32 of the speed regulating liquid pump; the suspended matter in the water enters the filter with the water flow and stays and accumulates on the filter membrane; , close the electromagnetic valve 42, stop the governor liquid pump 3, record the filter number and the volume of the filtered water sample, and complete a set of suction filtration; the anti-overflow ball 46 floats up under the action of buoyancy to block the water inlet 471 of the upper half shell of the filter , to isolate the exchange of water and suspended matter again; after the program executes the next time series, repeat the above steps for the next group of filters to complete all in-situ suction sampling;
S3装置回收后处理:观测结束后,将装置回收并连接PC上位机,取下过滤器的磁吸防尘帽48,手动控制电磁阀42打开并继续抽滤至对应过滤器中无水残留;从上半壳进水口471缓慢注入蒸馏水清洗过滤器上半壳内壁,注意控制注入速度不要溢出,重复清洗操作直至悬浮物全部冲洗富集至滤膜上;将剩余液体抽干,取下上半壳47,完成滤膜收集并保存;逐一完成所有滤膜收集工作,将装置用淡水冲洗维护并妥善存放;S3 Treatment after device recovery: After the observation, recover the device and connect it to the PC host computer, remove the magnetic dustproof cap 48 of the filter, manually control the solenoid valve 42 to open and continue to filter until there is no water residue in the corresponding filter; Slowly inject distilled water from the water inlet 471 of the upper half shell to clean the inner wall of the upper half shell of the filter, pay attention to control the injection speed so as not to overflow, repeat the cleaning operation until all the suspended matter is washed and enriched on the filter membrane; drain the remaining liquid, and remove the upper half Shell 47, complete the filter membrane collection and storage; complete all the filter membrane collection work one by one, rinse and maintain the device with fresh water and store it properly;
S4浓度计算:将富集后的滤膜烘干、称后重记录,根据前重m1、后重m2及抽滤体积V计算即可获得悬浮物质量浓度Cm=(m2-m1)/V。S4 Concentration Calculation: Dry the enriched filter membrane, weigh and record, and calculate the suspended matter mass concentration C m = (m 2 -m 1 )/V.
在本发明的描述中,术语“多个”则指两个或两个以上,除非另有明确的限定,术语“上”、“下”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制;术语“连接”、“安装”、“固定”等均应做广义理解,例如,“连接”可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是直接相连,也可以通过中间媒介间接相连。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, the term "plurality" refers to two or more than two. Unless otherwise clearly defined, the orientation or positional relationship indicated by the terms "upper", "lower" and so on is based on the orientation shown in the accompanying drawings. Orientation or positional relationship is only for the convenience of describing the present invention and simplifying the description, but does not indicate or imply that the referred device or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be construed as limiting the present invention; The terms "connection", "installation" and "fixation" should be understood in a broad sense, for example, "connection" can be fixed connection, detachable connection, or integral connection; it can be directly connected or through an intermediate The medium is indirectly connected. For those of ordinary skill in the art, the specific meanings of the above terms in the present invention can be understood according to specific situations.
在本说明书的描述中,术语“一个实施例”、“一些实施例”、“具体实施例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或实例。而且,描述的具体特征、结构、材料或特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, descriptions of the terms "one embodiment", "some embodiments", "specific embodiments" and the like mean that specific features, structures, materials or characteristics described in conjunction with the embodiment or example are included in the present invention In at least one embodiment or example of . In this specification, schematic representations of the above terms do not necessarily refer to the same embodiment or example. Furthermore, the specific features, structures, materials or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
以上仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included within the protection scope of the present invention.
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