CN103937327B - A kind of Water-soluble ceramic ink - Google Patents
A kind of Water-soluble ceramic ink Download PDFInfo
- Publication number
- CN103937327B CN103937327B CN201410130100.6A CN201410130100A CN103937327B CN 103937327 B CN103937327 B CN 103937327B CN 201410130100 A CN201410130100 A CN 201410130100A CN 103937327 B CN103937327 B CN 103937327B
- Authority
- CN
- China
- Prior art keywords
- weight part
- water
- ceramic ink
- tabular alumina
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
A kind of Water-soluble ceramic ink, comprising: tabular alumina 8 ~ 25 weight part, grind resin 5 ~ 20 weight part, lubricant 7 ~ 25 weight part, dispersion agent 0.7 ~ 5 weight part, stablizer 0.5 ~ 3 weight part and distilled water 30 ~ 75 weight part.Ceramic ink high thermal resistance of the present invention is good, and chromogenic rate is high, and in colour-stable; Not easily precipitate, good stability.
Description
Technical field
The present invention relates to a kind of Water-soluble ceramic ink.
Background technology
Along with the fast development of computer printing technology, digitizing technique is also applied in traditional ceramics industry.In ceramic decoration field also by original planography excessively to glue roller printing, even now up-to-date inkjet technology.Inkjet technology is a kind of decoration technique of great potential, and by the Digital Control of computer, ink being formed required pattern by the nozzle ejection on printhead to the surface of base substrate or glaze paint, can be monochromatic or polychromatic combination.
Ceramic generally needs the high-temperature firing of more than 1,000 degree, and the ink adapted with it also needs to bear this temperature, so organic dye and low temperature pigment are not suitable for making ceramic ink.Existing disclosed ceramic ink mainly with zirconium based raw material as carrier as Dow enamel frit makeing (CN201010117934.5) etc.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of Water-soluble ceramic ink, and high thermal resistance is good, and the chromogenic rate of ink is high, and in colour-stable.
The present invention solves the problems of the technologies described above by the following technical programs: a kind of Water-soluble ceramic ink, comprises following composition: tabular alumina 8 ~ 25 weight part, grind resin 5 ~ 20 weight part, lubricant 7 ~ 25 weight part, dispersion agent 0.7 ~ 5 weight part, stablizer 0.5 ~ 3 weight part and distilled water 30 ~ 75 weight part;
Described tabular alumina is coating tabular alumina, or is doped with the colored tabular alumina of coloring ion, and the particle diameter of tabular alumina be 1 ~ 60um, particle diameter/Thickness Ratio is 10 ~ 100.
Further, described grind resin is one or more arbitrary combination in acrylic resin, modified rosin resin, water-soluble epoxy resin, PA66 resin;
Described lubricant is one or more arbitrary combination in glycol ether, glycerol, propylene glycol, butanols, ethylene glycol, diethylene glycol ether, propylene glycol monomethyl ether, Virahol, ethanol, ethylene glycol ethyl ether, 1-Methoxy-2-propyl acetate, alkylphenol polyvinyl ether, polyoxyethylene glycol alkyl ester;
Described dispersion agent is one or more arbitrary combination of OP-10, AEO-9, TX-10, KH570, KR-212, PE-100, dispersion agent 5040, trolamine and HRE-40, povidone;
Described stablizer is thickening material, defoamer, softening agent and sanitas.
Further, described grind resin is acrylic resin.
Further, described stablizer is one or more arbitrary combination in polyvinyl alcohol, wilkinite, polynite, silicone emulsion, polythene wax emulsion, GPE defoamer, TS-807, benzoglyoxaline and BHT.
Further, the performance perameter of described ceramic ink is as follows:
PH value is 7 ~ 9, and viscosity is 6.9 ~ 20mPa.S, and grain diameter is 50 ~ 900nm, and surface tension is 20 ~ 48mN/m.
Further, the preparation method of described ceramic ink, comprises the following steps:
(1) distilled water of the dispersion agent of the tabular alumina of 8 ~ 25 weight parts, 0.7 ~ 5 weight part and 60% of 30 ~ 75 weight parts is mixed, and with stirrer rapid stirring to even;
(2) add the lubricant rapid stirring 15min again of 7 ~ 25 weight parts, the grind resin then adding 5 ~ 20 weight parts under stirring at low speed continues to stir 30min;
(3) stablizer of 0.5 ~ 3 weight part and remaining distilled water is finally added, stir 30min to obtain slurry, being sent into by slurry in ball mill and being milled to slurry granularity is 50 ~ 900nm, or slurry being sent into high pressure homogenizer, to carry out homogenization treatment to slurry granularity be 50 ~ 900nm, obtains product.
Beneficial effect of the present invention is: have good high thermal resistance, can bear the temperature of ceramic sintering completely; Substantially increase the chromogenic rate of ink, and in colour-stable; Ceramic ink not easily precipitates, good stability.
Embodiment
A kind of Water-soluble ceramic ink, comprises following composition: tabular alumina 8 ~ 25 weight part, grind resin 5 ~ 20 weight part, lubricant 7 ~ 25 weight part, dispersion agent 0.7 ~ 5 weight part, stablizer 0.5 ~ 3 weight part and distilled water 30 ~ 75 weight part.The performance perameter of described ceramic ink is as follows: pH value is 7 ~ 9, and viscosity is 6.9 ~ 20mPa.S, and surface tension is 20 ~ 48mN/m, and grain diameter is 50 ~ 900nm, and Granular composite is even.
Described tabular alumina is coating tabular alumina, or be doped with the colored tabular alumina of coloring ion, coating tabular alumina is the tabular alumina in the certain color of tabular alumina surface parcel, and the particle diameter of tabular alumina be 1 ~ 60um, particle diameter/Thickness Ratio (i.e. radius-thickness ratio) is 10 ~ 100, be preferably particle diameter 2 ~ 40um, thickness be 0.1-0.5um.
Described grind resin is one or more arbitrary combination in acrylic resin, modified rosin resin, water-soluble epoxy resin, PA66 resin; Wherein, described grind resin is preferably acrylic resin.
Described lubricant is one or more arbitrary combination in glycol ether, glycerol, propylene glycol, butanols, ethylene glycol, diethylene glycol ether, propylene glycol monomethyl ether, Virahol, ethanol, ethylene glycol ethyl ether, 1-Methoxy-2-propyl acetate, alkylphenol polyvinyl ether, polyoxyethylene glycol alkyl ester.
Described dispersion agent is OP-10 (polyoxyethylene nonylphenol ether), AEO-9 (fatty alcohol-polyoxyethylene ether), TX-10 (Value 3608), KH570 (γ-(methacryloxypropyl) propyl trimethoxy silicane), KR-212 (two (dioctylphosphato) metatitanic acid second diester), PE-100 (alkylphenol polyoxyethylene), dispersion agent 5040 (sodium polyacrylate disperant), trolamine and HRE-40 (modified hydrogenated Viscotrol C), one or more arbitrary combination of povidone,
Described stablizer is thickening material, defoamer, softening agent and sanitas; Described stablizer is preferably one or more arbitrary combination in polyvinyl alcohol, wilkinite, polynite, silicone emulsion, polythene wax emulsion, GPE defoamer (polyoxypropylene ethylene oxide glyceryl ether), TS-807 (polyquaternium), benzoglyoxaline and BHT (2,6 di tert butyl 4 methyl phenol).
For clearly the present invention being described, as follows especially exemplified by embodiment:
The raw material of the Water-soluble ceramic ink of each embodiment and proportioning situation respectively shown in table, are mass parts as follows.
Embodiment 1
Composition of raw materials table
Embodiment 2
Composition of raw materials table
Embodiment 3
Composition of raw materials table
Embodiment 4
Composition of raw materials table
Embodiment 5
Composition of raw materials table
Embodiment 6
Composition of raw materials table
The method that the various embodiments described above prepare described Water-soluble ceramic ink is as follows:
(1) by 60% distilled water mixing of tabular alumina, dispersion agent and 30 ~ 75 weight parts, and with stirrer rapid stirring to even;
(2) add lubricant rapid stirring 15min again, under stirring at low speed, then add grind resin continue to stir 30min;
(3) stablizer and remaining distilled water is finally added, stir 30min to obtain slurry, being sent into by slurry in ball mill and being milled to slurry granularity is 50 ~ 900nm, or slurry being sent into high pressure homogenizer, to carry out homogenization treatment to slurry granularity be 50 ~ 900nm, obtains product.
The ceramic ink that above-described embodiment 1-6 is obtained carries out Performance Detection, and by spray ink Printing on ceramic green or glaze paint, furnace cooling after the resistance furnace high-temperature firing insulation 1h of 1200 DEG C, observes its color development and colouring effect.
| example 1 | example 2 | example 3 | example 4 | example 5 | example 6 | |
| pH value | 7.2 | 9.0 | 7.3 | 7.2 | 7.9 | 7.0 |
| viscosity mPa.S | 20.0 | 15.7 | 16.2 | 13.6 | 6.9 | 16.5 |
| surface tension mN/m. | 48.0 | 32.2 | 29.7 | 23.5 | 20.0 | 25.6 |
| particle diameter nm | 50 ~ 900 | 50 ~ 900 | 50 ~ 900 | 50 ~ 900 | 50 ~ 900 | 50 ~ 900 |
| color development stability △ E | ≤ 5 | ≤ 5 | ≤ 5 | ≤ 5 | ≤ 5 | ≤ 5 |
| print performance | good | good | good | good | good | good |
Water-soluble ceramic ink of the present invention has good high thermal resistance, the complete temperature bearing ceramic sintering, the color of ceramic ink carrys out colour generation by tabular alumina, the colored tabular alumina of its tabular alumina coloring ion that can be self-mixing may also be the tabular alumina in the certain color of its surface parcel, the sheet crystal formation of its uniqueness substantially increases the chromogenic rate of ink, and in colour-stable.The ceramic ink adopting tabular alumina to prepare not easily precipitates, good stability.
Claims (6)
1. a Water-soluble ceramic ink, is characterized in that: comprise following composition: tabular alumina 8 ~ 25 weight part, grind resin 5 ~ 20 weight part, lubricant 7 ~ 25 weight part, dispersion agent 0.7 ~ 5 weight part, stablizer 0.5 ~ 3 weight part and distilled water 30 ~ 75 weight part;
Described tabular alumina is coating tabular alumina, or is doped with the colored tabular alumina of coloring ion, and the particle diameter of tabular alumina be 1 ~ 60um, particle diameter/Thickness Ratio is 10 ~ 100.
2. a kind of Water-soluble ceramic ink as claimed in claim 1, is characterized in that: described grind resin is one or more arbitrary combination in acrylic resin, modified rosin resin, water-soluble epoxy resin, PA66 resin;
Described lubricant is one or more arbitrary combination in glycol ether, glycerol, propylene glycol, butanols, ethylene glycol, diethylene glycol ether, propylene glycol monomethyl ether, Virahol, ethanol, ethylene glycol ethyl ether, 1-Methoxy-2-propyl acetate, alkylphenol polyvinyl ether, polyoxyethylene glycol alkyl ester;
Described dispersion agent is one or more arbitrary combination of OP-10, AEO-9, TX-10, KH570, KR-212, PE-100, dispersion agent 5040, trolamine and HRE-40, povidone;
Described stablizer is thickening material, defoamer, softening agent and sanitas.
3. a kind of Water-soluble ceramic ink as claimed in claim 2, is characterized in that: described grind resin is acrylic resin.
4. a kind of Water-soluble ceramic ink as claimed in claim 2, is characterized in that: described stablizer is one or more arbitrary combination in polyvinyl alcohol, wilkinite, polynite, silicone emulsion, polythene wax emulsion, GPE defoamer, TS-807, benzoglyoxaline and BHT.
5. a kind of Water-soluble ceramic ink as claimed in claim 1, is characterized in that: the performance perameter of described ceramic ink is as follows:
PH value is 7 ~ 9, and viscosity is 6.9 ~ 20mPa.S, and grain diameter is 50 ~ 900nm, and surface tension is 20 ~ 48mN/m.
6. a kind of Water-soluble ceramic ink as claimed in claim 1, is characterized in that: the preparation method of described ceramic ink comprises the following steps:
(1) distilled water of the dispersion agent of the tabular alumina of 8 ~ 25 weight parts, 0.7 ~ 5 weight part and 60% of 30 ~ 75 weight parts is mixed, and with stirrer rapid stirring to even;
(2) add the lubricant rapid stirring 15min again of 7 ~ 25 weight parts, the grind resin then adding 5 ~ 20 weight parts under stirring at low speed continues to stir 30min;
(3) stablizer of 0.5 ~ 3 weight part and remaining distilled water is finally added, stir 30min to obtain slurry, being sent into by slurry in ball mill and being milled to slurry granularity is 50 ~ 900nm, or slurry being sent into high pressure homogenizer, to carry out homogenization treatment to slurry granularity be 50 ~ 900nm, obtains product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410130100.6A CN103937327B (en) | 2014-04-02 | 2014-04-02 | A kind of Water-soluble ceramic ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410130100.6A CN103937327B (en) | 2014-04-02 | 2014-04-02 | A kind of Water-soluble ceramic ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103937327A CN103937327A (en) | 2014-07-23 |
| CN103937327B true CN103937327B (en) | 2016-04-27 |
Family
ID=51185213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410130100.6A Expired - Fee Related CN103937327B (en) | 2014-04-02 | 2014-04-02 | A kind of Water-soluble ceramic ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103937327B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3194511A1 (en) * | 2014-09-19 | 2017-07-26 | Zschimmer & Schwarz Ceramco S.P.A. | Ceramic ink for inkjet printing |
| KR101573790B1 (en) * | 2015-07-28 | 2015-12-02 | (주) 더몰론코리아 | Composition of ceramic printing ink with antimicrobial function |
| CN106497217A (en) * | 2016-11-24 | 2017-03-15 | 无锡奔牛生物科技有限公司 | A kind of Natural environment-friendlyink ink |
| CN107474737A (en) * | 2017-08-15 | 2017-12-15 | 南宁东印时代广告有限公司 | A kind of paster making oil polish and preparation method thereof |
| CN107936698A (en) * | 2017-12-14 | 2018-04-20 | 佛山市彩贵新型材料有限公司 | High dispersive blue ceramic ink |
| CN110055538B (en) * | 2019-05-27 | 2022-01-25 | 方复(上海)新材料科技有限公司 | Alumina slurry and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101278015B (en) * | 2005-10-03 | 2012-09-05 | 大日精化工业株式会社 | Pearlescent pigment, method for producing the same, coating composition, and coating film composition |
| CN103224727A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Eco-friendly glaze ink for ceramic jet printing and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3242561B2 (en) * | 1995-09-14 | 2001-12-25 | メルク・ジヤパン株式会社 | Flaky aluminum oxide, pearlescent pigment and method for producing the same |
| KR20140015435A (en) * | 2011-03-08 | 2014-02-06 | 메르크 파텐트 게엠베하 | Formulations of printable aluminium oxide inks |
| US20130164529A1 (en) * | 2011-12-21 | 2013-06-27 | Silberline Manufacturing Company, Inc. | Colored platelets |
| CN102964920B (en) * | 2012-11-27 | 2015-07-22 | 广东道氏技术股份有限公司 | Ink for ceramic ink-jet printing and method for preparing same |
-
2014
- 2014-04-02 CN CN201410130100.6A patent/CN103937327B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101278015B (en) * | 2005-10-03 | 2012-09-05 | 大日精化工业株式会社 | Pearlescent pigment, method for producing the same, coating composition, and coating film composition |
| CN103224727A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Eco-friendly glaze ink for ceramic jet printing and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103937327A (en) | 2014-07-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103937327B (en) | A kind of Water-soluble ceramic ink | |
| CN102115622B (en) | Alcoholic group liquid ink capable of realizing high-speed printing and preparation method thereof | |
| CN103992690B (en) | Compound oil ink is printed in novel environment friendly high speed | |
| CN103965687B (en) | A kind of have ceramic ink of sagging effect and preparation method thereof | |
| CN108641483B (en) | Ceramic ink-jet printing ink capable of promoting color development and preparation method thereof | |
| CN106833113B (en) | Ink suitable for glass hot bending forming and application of ink in mobile phone | |
| CN101942252B (en) | Non-benzene imaging layer for laser hot stamping foil and preparation method thereof | |
| CN101469153A (en) | Environment friendly transparent iron oxide black superfine aqueous color sizing dispersion and preparation thereof | |
| CN101891984A (en) | Printing ink combination, printing ink and method for forming image on ceramic surface | |
| CN105131716A (en) | Ceramic glossy glaze ink and preparation method thereof | |
| CN102363934A (en) | Environmentally-friendly quick drying aqueous glass imitation card transfer paint and preparation method as well as application thereof | |
| CN104449030A (en) | Solvent type gravure pearlescent ink and preparation method thereof | |
| CN105907178B (en) | A kind of ceramic ink jet printing is with pushing glaze ink aside | |
| CN105153812A (en) | Ceramic anti-skid glaze ink and preparation method thereof | |
| CN102399472B (en) | Printing ink substituting gold stamping anodized aluminium | |
| CN104804521A (en) | Toning process of ink for environment-friendly water-based paint | |
| CN101158130A (en) | Applying liquid for digit design paper and process for preparing digit design paper by employing the same | |
| CN106543807A (en) | A kind of preparation method that high safety redness mill base is printed for medicated napkin | |
| CN101469156A (en) | Environment friendly transparent iron oxide brown superfine aqueous color sizing dispersion and preparation thereof | |
| CN105670383B (en) | A kind of production method of environment-friendly type aqueous high temperature resistant ink | |
| CN107418309A (en) | E-inks printing coating composition with pearl effect and preparation method thereof | |
| CN101469155A (en) | Environment friendly transparent iron oxide yellow superfine aqueous color sizing dispersion and preparation thereof | |
| CN110028832A (en) | A kind of environment-friendlyink ink and preparation method thereof | |
| CN110240408A (en) | A kind of formula and preparation method thereof of ceramics isolation glaze | |
| CN103952033A (en) | Universal ink as well as preparation method and use method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160427 Termination date: 20200402 |