CN103820739B - 铁素体耐热铸钢及其制备方法和应用 - Google Patents
铁素体耐热铸钢及其制备方法和应用 Download PDFInfo
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- CN103820739B CN103820739B CN201410071850.0A CN201410071850A CN103820739B CN 103820739 B CN103820739 B CN 103820739B CN 201410071850 A CN201410071850 A CN 201410071850A CN 103820739 B CN103820739 B CN 103820739B
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- cast steel
- resistant cast
- steel
- ferrite heat
- heat
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- 229910001208 Crucible steel Inorganic materials 0.000 title claims abstract description 95
- 229910000859 α-Fe Inorganic materials 0.000 title claims abstract description 77
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 79
- 239000010959 steel Substances 0.000 claims abstract description 79
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 49
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 40
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 32
- 239000000956 alloy Substances 0.000 claims abstract description 32
- 229910052742 iron Inorganic materials 0.000 claims abstract description 24
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 22
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 20
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 18
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 16
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 15
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 13
- 239000012535 impurity Substances 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 11
- 229910052702 rhenium Inorganic materials 0.000 claims abstract description 10
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 10
- 238000002844 melting Methods 0.000 claims abstract description 8
- 230000008018 melting Effects 0.000 claims abstract description 8
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 37
- 150000002910 rare earth metals Chemical class 0.000 claims description 33
- 239000004411 aluminium Substances 0.000 claims description 27
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 27
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 25
- 239000007788 liquid Substances 0.000 claims description 23
- 229910000519 Ferrosilicon Inorganic materials 0.000 claims description 21
- 238000005266 casting Methods 0.000 claims description 19
- 239000010955 niobium Substances 0.000 claims description 17
- 239000011575 calcium Substances 0.000 claims description 16
- 229910052791 calcium Inorganic materials 0.000 claims description 15
- 238000001816 cooling Methods 0.000 claims description 11
- 239000002893 slag Substances 0.000 claims description 10
- 229910052788 barium Inorganic materials 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 6
- 229910000600 Ba alloy Inorganic materials 0.000 claims description 5
- 229910000616 Ferromanganese Inorganic materials 0.000 claims description 5
- 229910000592 Ferroniobium Inorganic materials 0.000 claims description 5
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims description 5
- -1 aluminum silicon calcium barium Chemical compound 0.000 claims description 5
- 238000004458 analytical method Methods 0.000 claims description 5
- 239000010425 asbestos Substances 0.000 claims description 5
- 239000010882 bottom ash Substances 0.000 claims description 5
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 claims description 5
- ZFGFKQDDQUAJQP-UHFFFAOYSA-N iron niobium Chemical compound [Fe].[Fe].[Nb] ZFGFKQDDQUAJQP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims description 5
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052895 riebeckite Inorganic materials 0.000 claims description 5
- 230000003595 spectral effect Effects 0.000 claims description 5
- 229910000604 Ferrochrome Inorganic materials 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 3
- 230000006698 induction Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 15
- 230000003647 oxidation Effects 0.000 abstract description 14
- 238000010438 heat treatment Methods 0.000 abstract description 4
- 230000002929 anti-fatigue Effects 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 28
- 239000011651 chromium Substances 0.000 description 22
- 239000000463 material Substances 0.000 description 14
- 239000011572 manganese Substances 0.000 description 13
- 239000010813 municipal solid waste Substances 0.000 description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 8
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 229910001566 austenite Inorganic materials 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 208000025599 Heat Stress disease Diseases 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 238000009661 fatigue test Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000013021 overheating Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 208000020442 loss of weight Diseases 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 201000001376 Familial Combined Hyperlipidemia Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Treatment Of Steel In Its Molten State (AREA)
Abstract
Description
C | Si | Mn | P | S | Cr | Ni | Nb | Re | N | Al | |
实施例1 | 0.25 | 0.91 | 0.43 | 0.023 | 0.078 | 14.55 | 1.15 | 0.20 | 0.02 | 0.027 | 0.01 |
实施例2 | 0.20 | 1.20 | 0.45 | 0.022 | 0.10 | 15.00 | 1.10 | 0.17 | 0.02 | 0.034 | 0.07 |
实施例3 | 0.16 | 1.16 | 0.42 | 0.016 | 0.11 | 15.79 | 0.97 | 0.30 | 0.05 | 0.046 | 0.09 |
实施例4 | 0.21 | 1.07 | 0.50 | 0.018 | 0.096 | 15.22 | 1.05 | 0.75 | 0.058 | 0.049 | 0.11 |
实施例5 | 0.18 | 0.95 | 0.48 | 0.020 | 0.089 | 16.14 | 1.16 | 0.92 | 0.051 | 0.041 | 0.14 |
对比例1 | 0.21 | 1.59 | 0.59 | 0.015 | 0.075 | 21.47 | 1.03 | 1.00 | 0.01 | 0.055 | 0.17 |
对比例2 | 0.21 | 1.46 | 0.44 | 0.024 | 0.084 | 20.12 | 1.05 | 2.96 | 0.03 | 0.048 | 0.08 |
抗拉强度Rm(RPa) | 塑性强度Rp0.2(RPa) | 伸长率A(%) | |
实施例1 | 886 | 599 | 4.5 |
实施例2 | 698 | 432 | 16.5 |
实施例3 | 634 | 430 | 20.0 |
实施例4 | 735 | 528 | 5.0 |
实施例5 | 750 | 499 | 11 |
对比例1 | 414 | / | 0.5 |
对比例2 | 511 | 326 | 4.5 |
Claims (12)
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CN103820739A CN103820739A (zh) | 2014-05-28 |
CN103820739B true CN103820739B (zh) | 2017-10-27 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106987759B (zh) * | 2017-03-29 | 2019-01-08 | 海城市欣锐铸件有限公司 | 一种含稀土元素的耐腐蚀螺纹钢冶炼方法 |
US11193195B2 (en) * | 2017-05-24 | 2021-12-07 | Tocalo Co., Ltd. | Component for hot-dip metal plating bath |
CN107321920A (zh) * | 2017-07-05 | 2017-11-07 | 天长市兴宇铸造有限公司 | 一种用于精铸件铸造的浇注方法 |
CN116334499B (zh) * | 2023-03-05 | 2024-02-02 | 襄阳金耐特机械股份有限公司 | 一种铁素体耐热铸钢及其用途 |
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CN1004287B (zh) * | 1987-10-31 | 1989-05-24 | 冶金工业部钢铁研究总院 | 稀土、高铬铁素体耐热铸钢 |
JP3605874B2 (ja) * | 1995-02-17 | 2004-12-22 | 大同特殊鋼株式会社 | 耐熱鋳鋼 |
JP3508095B2 (ja) * | 1999-06-15 | 2004-03-22 | 株式会社クボタ | 耐熱疲労性・耐腐食疲労性およびドリル加工性等に優れたフェライト−オーステナイト二相ステンレス鋼および製紙用サクションロール胴部材 |
JP5168713B2 (ja) * | 2006-02-23 | 2013-03-27 | 大同特殊鋼株式会社 | 薄肉鋳物部品及びその製造方法 |
CN100445411C (zh) * | 2006-12-31 | 2008-12-24 | 宁波市鄞州文教精密铸造厂 | 含稀土元素的铸钢 |
JP4521470B1 (ja) * | 2009-04-27 | 2010-08-11 | アイシン高丘株式会社 | フェライト系耐熱鋳鋼および排気系部品 |
WO2011125901A1 (ja) * | 2010-03-31 | 2011-10-13 | 日立金属株式会社 | 常温靭性に優れたフェライト系耐熱鋳鋼及びそれからなる排気系部品 |
CN102304671B (zh) * | 2011-08-29 | 2012-10-31 | 遵化市新宏宇冶金机械有限公司 | 一种多元低合金耐磨铸钢斗齿及其制备方法 |
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Address after: 213011 258 Wuyi Road, Changzhou, Jiangsu Patentee after: CRRC Qishuyan Locomotive and Rolling Stock Technology Research Institute Co.,Ltd. Country or region after: China Patentee after: CHANGZHOU LANGRUI CASTING Co.,Ltd. Address before: 213011 258 Wuyi Road, Changzhou, Jiangsu Patentee before: CRRC QISHUYAN INSTITUTE Co.,Ltd. Country or region before: China Patentee before: CHANGZHOU LANGRUI CASTING Co.,Ltd. |
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