CN103709863B - A kind of Flame-retardant aerosol paint for mine mark - Google Patents
A kind of Flame-retardant aerosol paint for mine mark Download PDFInfo
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- CN103709863B CN103709863B CN201310681159.XA CN201310681159A CN103709863B CN 103709863 B CN103709863 B CN 103709863B CN 201310681159 A CN201310681159 A CN 201310681159A CN 103709863 B CN103709863 B CN 103709863B
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Abstract
The invention discloses a kind of Flame-retardant aerosol paint for mine mark, by propelling agent, non-combustible quick-drying solvent, ethylene glycol monobutyl ether, wetting dispersing agent, anti-settling agent, membrane-forming agent, filler, tinting material.The present invention by GHS(the whole world chemical homogeneous classification and labeling system) in aerosol products classification combustibility test, belong to non-combustible, without the need to identifying dangerous inflammable mark.The present invention is aerosol products, very easy to use, can coordinate 360 bottom valve doors that the multi-direction injections such as the upright handstand of product are used, also can be arranged in pairs or groups by the nozzle of various structures, allow product reach various thickness of lines, large fog horn covering of the fan jeting effect with satisfied different user demand.The present invention is mainly used for the places such as hole, ore deposit, playground, road, building site, the color mark carrying out obviously with various color desired location, be satisfied with.
Description
[technical field]
The present invention relates to a kind of aerosol paint, particularly relate to a kind of Flame-retardant aerosol paint for mine mark, belong to the aerosol spray technique field of coating.
[background technology]
Mine workspace often can carry out setting-out mark with coating; but coating is in the market mostly inflammableness coating; for in this kind of inflammable workspace in picture mining district, use this type of coating abnormally dangerous, and in application aspect; because the inflammableness of coating; be all liquid state mostly, avoid using spray-like product, reduce dangerous; but adopt area with a varied topography like this, minery for mine like this, brushing class coating uses and very inconvenient.
[summary of the invention]
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of easy to use, can spraying effect be enriched, the Flame-retardant aerosol paint for mine mark of Environmental Safety.
The present invention to achieve these goals, by the following technical solutions:
For a Flame-retardant aerosol paint for mine mark, it is characterized in that being made up of following mass percentage component:
The present invention selects non-flammable tetrafluoeopropene, Tetrafluoroethane, and carbonic acid gas, as propelling agent, can be used alone wherein a kind of, also can any two kinds be combined into two propelling agent, to reach the atomizing effect of product optimum and most economical cost.Wherein the addition of Tetrafluoroethane and tetrafluoeopropene is 10 ~ 20%, and the addition of carbonic acid gas is 1 ~ 5%.
Non-combustible quick-drying solvent in the present invention is selected from nine fluorine butyl methyl ethers, 3-pentafluorobutane, Decafluoropentane, one or several in a fluorine ethylene dichloride (141b) and methylene dichloride, to obtain suitable evaporation rate, reaches preferred film-formation result and glossiness.
Ethylene glycol monobutyl ether is more traditional and suitable solubility promoter.
Wetting dispersing agent in the present invention is ANTI-TERRA, is produced by German BYK company.
Anti-settling agent in the present invention is selected from aerosil, kaolin, one or several in organobentonite.
Membrane-forming agent in the present invention is selected from acrylic resin, Synolac, one or several in petroleum resin, and the different sticking power that can meet variant production require and cost requirement.
Filler in the present invention is selected from one in titanium dioxide and calcium carbonate or two kinds.
Tinting material in the present invention is pigment, is selected from common toner, fluorescent material, in pearlescence and noctilucence toner one or several, pigment optimization heavy metal meets the American-European pigment required.The present invention can make common look, fluorescence color, pearly-lustre look and luminous color four series by demand, can meet the demand of different occasion, user.Product has in bright gay color, that hiding power is strong, sticking power is lasting feature.
In the present invention, tinting material and the filler particle diameter in aerosol products is 15-25 μm.
Preparation method of the present invention is: by ethylene glycol monobutyl ether, wetting dispersing agent, anti-settling agent, membrane-forming agent, filler and tinting material dissolve and are dispersed in non-combustible quick-drying solvent, and the particle diameter being then ground to filler and tinting material by sand mill is 15 μm, refilter, check colors, verify as qualified dose of liquid, finally agent liquid is poured in inhalator jar, dress valve, sealing, filling propelling agent, water-bath, dress nozzle, dress enclosing cover.
The present invention, relative to prior art, has following advantage:
The present invention by GHS(the whole world chemical homogeneous classification and labeling system) in aerosol products classification combustibility test, belong to non-combustible, without the need to identifying dangerous inflammable mark.
The present invention possesses non-VOC(volatile organic compounds), low GWP value (global alternating temperature dive value), harmless ozonosphere, has the feature of environmental protection advantage of low toxicity.
The present invention is aerosol products, very easy to use, can coordinate 360 bottom valve doors that the multi-direction injections such as the upright handstand of product are used, also can be arranged in pairs or groups by the nozzle of various structures, allow product reach various thickness of lines, large fog horn covering of the fan jeting effect with satisfied different user demand.
The present invention is mainly used for the places such as hole, ore deposit, playground, road, building site, the color mark carrying out obviously with various color desired location, be satisfied with.Due to easy to use, successful, multiple color that is common and fluorescence of can arranging in pairs or groups, well meets the demand of the required consumer group both at home and abroad, has good Social benefit and economic benefit.
[embodiment]
Below in conjunction with specific embodiment, the invention will be further described, and the degree in embodiment is mass percentage content:
Embodiment 1:
Take agent fluid component raw material nine fluorine butyl methyl ether 43.27%, ethylene glycol monobutyl ether 1.54%, ANTI-TERRA0.79%, aerosil 2.9%, acrylic resin 10%, calcium carbonate 8%, fluorescent orange pigment 20%;
Propelling agent chooses the Tetrafluoroethane of 12% and the carbonic acid gas of 1.5%;
The preparation method of embodiment 1 is:
By ethylene glycol monobutyl ether, wetting dispersing agent, anti-settling agent, membrane-forming agent, filler and tinting material dissolve and are dispersed in non-combustible quick-drying solvent, and the particle diameter being then ground to filler and tinting material by sand mill is 15 μm, refilter, check colors, verify as qualified dose of liquid, finally agent liquid is poured in inhalator jar, dress valve, sealing, filling propelling agent, water-bath, dress nozzle, dress enclosing cover.Embodiment 2:
Take agent fluid component raw material methylene dichloride 45.21%, ANTI-TERRA2%, organic Peng Run soil 2%, acrylic resin 7%, calcium carbonate 5%, titanium dioxide 10%;
The Tetrafluoroethane of 30% chosen by propelling agent;
The preparation method of embodiment 2 is with embodiment 1, and in embodiment 2, the particle diameter of filler and tinting material is 18 μm.
Embodiment 3:
Take agent fluid component raw material 3-pentafluorobutane 50%, ethylene glycol monobutyl ether 3%, ANTI-TERRA0.79%, kaolin 2%, Synolac 7.21%, calcium carbonate 10%, blue pigments 15%;
Tetrafluoeopropene 10% chosen by propelling agent, carbonic acid gas 2%;
The preparation method of embodiment 3 is with embodiment 1, and in embodiment 3, the particle diameter of filler and tinting material is 20 μm.
Embodiment 4:
Take agent fluid component raw material methylene dichloride 50%, ethylene glycol monobutyl ether 3%, ANTI-TERRA1%, kaolin 1.5%, acrylic resin 8%, calcium carbonate 10%, noctilucence yellow pigment 5%;
Tetrafluoroethane 20% chosen by propelling agent, carbonic acid gas 1.5%;
The preparation method of embodiment 4 is with embodiment 1, and in embodiment 4, the particle diameter of filler and tinting material is 23 μm.
Embodiment 5:
Take agent fluid component raw material 141b50%, ethylene glycol monobutyl ether 3%, ANTI-TERRA1%, kaolin 1.5%, acrylic resin 8%, calcium carbonate 10%, pearly-lustre purple dye 5%;
Tetrafluoroethane 20% chosen by propelling agent, carbonic acid gas 1.5%;
The preparation method of embodiment 5 is with embodiment 1, and in embodiment 5, the particle diameter of filler and tinting material is 25 μm.
Embodiment 6:
Take agent fluid component raw material 3-pentafluorobutane 50%, Decafluoropentane 20%, ethylene glycol monobutyl ether 5%, ANTI-TERRA0.1%, kaolin 0.1%, petroleum resin 5%, calcium carbonate 1%, pearly-lustre phthalocyanine 8.8%;
Tetrafluoeopropene 10% chosen by propelling agent
The preparation method of embodiment 6 is with embodiment 1, and in embodiment 6, the particle diameter of filler and tinting material is 20 μm.
Embodiment 7:
Take agent fluid component raw material one fluorine ethylene dichloride 40%, ethylene glycol monobutyl ether 2%, ANTI-TERRA0.5%, kaolin 1%, aerosil 1%, acrylic resin 5%, Synolac 10%, calcium carbonate 5%, noctilucence white pigments 10.5%;
Tetrafluoeopropene 20% chosen by propelling agent, carbonic acid gas 5%;
The preparation method of embodiment 7 is with embodiment 1, and in embodiment 7, the particle diameter of filler and tinting material is 20 μm.
Embodiment 8:
Take agent fluid component raw material one fluorine ethylene dichloride 20%, 3-pentafluorobutane 20%, methylene dichloride 17%, ethylene glycol monobutyl ether 4%, ANTI-TERRA1%, aerosil 2%, acrylic resin 5%, Synolac 5%, petroleum resin 5%, calcium carbonate 5%, titanium dioxide 3%, pearly-lustre yellow pigment 2%;
Tetrafluoeopropene 10% chosen by propelling agent, carbonic acid gas 1%;
The preparation method of embodiment 8 is with embodiment 1, and in embodiment 8, the particle diameter of filler and tinting material is 20 μm.
Embodiment 9:
Take agent fluid component raw material methylene dichloride 44%, ANTI-TERRA1%, aerosil 2%, acrylic resin 5%, calcium carbonate 5%, pearly-lustre yellow pigment 32%;
Tetrafluoroethane 10% chosen by propelling agent, carbonic acid gas 1%;
The preparation method of embodiment 9 is with embodiment 1, and in embodiment 9, the particle diameter of filler and tinting material is 20 μm.
Embodiment 10:
Take agent fluid component raw material 3-pentafluorobutane 10%, Decafluoropentane 10%, methylene dichloride 10%, 141b20%, ANTI-TERRA1%, aerosil 2%, acrylic resin 5%, calcium carbonate 5%, pearly-lustre yellow pigment 32%;
Carbonic acid gas 5% chosen by propelling agent;
The preparation method of embodiment 10 is with embodiment 1, and in embodiment 10, the particle diameter of filler and tinting material is 20 μm.
Carry out non-combustibility test to embodiment 1-10, its result is as shown in table 1:
Table 1:
| Project | The hot sum of each component combustion | Distance is lighted during spraying | The enclosed space detonation time |
| Embodiment 1 | Be less than 20KJ/g | Be less than 15cm | Be greater than 300s/m 3 |
| Embodiment 2 | Be less than 20KJ/g | Be less than 15cm | Be greater than 300s/m 3 |
| Embodiment 3 | Be less than 20KJ/g | Be less than 15cm | Be greater than 300s/m 3 |
| Embodiment 4 | Be less than 20KJ/g | Be less than 15cm | Be greater than 300s/m 3 |
| Embodiment 5 | Be less than 20KJ/g | Be less than 15cm | Be greater than 300s/m 3 |
| Embodiment 6 | Be less than 20KJ/g | Be less than 15cm | Be greater than 300s/m 3 |
| Embodiment 7 | Be less than 20KJ/g | Be less than 15cm | Be greater than 300s/m 3 |
| Embodiment 8 | Be less than 20KJ/g | Be less than 15cm | Be greater than 300s/m 3 |
| Embodiment 9 | Be less than 20KJ/g | Be less than 15cm | Be greater than 300s/m 3 |
| Embodiment 10 | Be less than 20KJ/g | Be less than 15cm | Be greater than 300s/m 3 |
As shown in Table 1, each of component combustion heat of various embodiments of the present invention is all less than 20KJ/g, and during spraying, light distance and be all less than 15cm, enclosed space is lighted in test, and the detonation time is all greater than 300s/m
3, by the combustibility test of aerosol products classification in GHS, belong to non-combustible, without the need to identifying dangerous inflammable mark.
Claims (7)
1., for a Flame-retardant aerosol paint for mine mark, it is characterized in that being made up of following mass percentage component:
Described propelling agent is selected from Tetrafluoroethane, one or several in tetrafluoeopropene and carbonic acid gas;
Described non-combustible quick-drying solvent is selected from nine fluorine butyl methyl ethers, 3-pentafluorobutane, Decafluoropentane, one or several in a fluorine ethylene dichloride and methylene dichloride.
2. a kind of Flame-retardant aerosol paint for mine mark according to claim 1, is characterized in that described wetting dispersing agent is ANTI-TERRA.
3. a kind of Flame-retardant aerosol paint for mine mark according to claim 1, is characterized in that described anti-settling agent is selected from aerosil, kaolin, one or several in organobentonite.
4. a kind of Flame-retardant aerosol paint for mine mark according to claim 1, is characterized in that described membrane-forming agent is selected from acrylic resin, Synolac, one or several in petroleum resin.
5. a kind of Flame-retardant aerosol paint for mine mark according to claim 1, is characterized in that described filler is selected from one in titanium dioxide and calcium carbonate or two kinds.
6. a kind of Flame-retardant aerosol paint for mine mark according to claim 1, is characterized in that described tinting material is pigment, is selected from common toner, fluorescent material, in pearlescence and noctilucence toner one or several.
7. a kind of Flame-retardant aerosol paint for mine mark according to claim 1, is characterized in that described filler and the tinting material particle diameter in aerosol paint is 15-25 μm.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310681159.XA CN103709863B (en) | 2013-12-13 | 2013-12-13 | A kind of Flame-retardant aerosol paint for mine mark |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310681159.XA CN103709863B (en) | 2013-12-13 | 2013-12-13 | A kind of Flame-retardant aerosol paint for mine mark |
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| CN103709863A CN103709863A (en) | 2014-04-09 |
| CN103709863B true CN103709863B (en) | 2016-04-20 |
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| CN201310681159.XA Active CN103709863B (en) | 2013-12-13 | 2013-12-13 | A kind of Flame-retardant aerosol paint for mine mark |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105505098B (en) * | 2015-12-16 | 2018-01-26 | 中山市大田汽车护理用品有限公司 | Fire protection flame retarding mark self-spraying paint and preparation method thereof |
| CN105820635A (en) * | 2016-05-20 | 2016-08-03 | 中山市天图精细化工有限公司 | Aerosol for beautifying glass |
| CN105820700B (en) * | 2016-06-06 | 2018-12-21 | 广东莱雅化工有限公司 | A kind of high-flash silver lustre aerosol spray paint and preparation method thereof |
| CN115707742A (en) * | 2021-08-18 | 2023-02-21 | 中山市珉和化工科技有限公司 | Water-based environment-friendly aerosol paint and preparation method thereof |
| CN115707750A (en) * | 2021-08-18 | 2023-02-21 | 中山市珉和化工科技有限公司 | Environment-friendly aerosol paint and preparation method thereof |
| CN116082897B (en) * | 2022-10-18 | 2024-09-06 | 广东自由能科技股份有限公司 | Aerosol paint suitable for underground parking lot scribing and preparation method thereof |
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| US4518734A (en) * | 1981-06-22 | 1985-05-21 | Rust-Oleum Corporation | Water based aerosol coatings |
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| CN101165135A (en) * | 2006-10-17 | 2008-04-23 | 浙江莹光化工有限公司 | Non-combustible aerosol composition |
| CN102702875A (en) * | 2012-06-14 | 2012-10-03 | 天长市银狐漆业有限公司 | Flame-retardant coating composition |
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|---|---|---|---|---|
| US4518734A (en) * | 1981-06-22 | 1985-05-21 | Rust-Oleum Corporation | Water based aerosol coatings |
| CN1346856A (en) * | 2001-10-12 | 2002-05-01 | 深圳市清华彩虹纳米材料高科技有限公司 | Luminescent aerosol paint composition |
| CN101165135A (en) * | 2006-10-17 | 2008-04-23 | 浙江莹光化工有限公司 | Non-combustible aerosol composition |
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| CN103709863A (en) | 2014-04-09 |
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Effective date of registration: 20160302 Address after: 528445, No. 28, Di Di Lu, golden carp Industrial Zone, triangle town, Guangdong, Zhongshan Applicant after: Zhongshan Tentop Fine Chemical Co., Ltd. Address before: 528400, No. 28, Di Di Lu, golden carp Industrial Zone, triangle town, Guangdong, Zhongshan Applicant before: Yang Jianming |
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Inventor after: Wen Junfan Inventor after: Liang Gaojian Inventor after: Zhang Weijing Inventor after: Lai Yunlong Inventor before: Yang Jianming |