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CN103688989A - Ultra-low volume liquid containing silafluofen and organophosphorus insecticide - Google Patents

Ultra-low volume liquid containing silafluofen and organophosphorus insecticide Download PDF

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Publication number
CN103688989A
CN103688989A CN201310680711.3A CN201310680711A CN103688989A CN 103688989 A CN103688989 A CN 103688989A CN 201310680711 A CN201310680711 A CN 201310680711A CN 103688989 A CN103688989 A CN 103688989A
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low volume
ultra low
volume liquids
silafluofene
oil
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Inventor
王群利
卢镇
唐卫
朱华龙
黄华
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Guangxi Tianyuan Biochemical Co Ltd
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Guangxi Tianyuan Biochemical Co Ltd
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Abstract

The invention discloses an ultra-low volume liquid containing silafluofen and an organophosphorus insecticide, belonging to the field of pesticides. The ultra-low volume liquid comprises the silafluofen and an active constituent (II), which are compounded into an active constituent, and the balance of a surfactant and a solvent; and the active constituent (II) is selected from any one of fenitrothion phosphorus, quinalphos, triazophos, diazinon, phoxim, fenitrothion, profenofos, chlorpyrifos, malathion, and isocarbophos. The ultra-low volume liquid disclosed by the invention is convenient to process, low in cost, good in pesticide effect, long in lasting period, high in coordinated synergism and capable of saving water, and can be used to reduce environment pollution, improve the utilization ratio and application amount of the pesticide.

Description

The ultra low volume liquids of fluorine silicon chrysanthemum ester and organophosphorus insecticides
Technical field
The present invention relates to pesticide field, is the ultra low volume liquids of fluorine silicon chrysanthemum ester and organophosphorus insecticides specifically, mainly by ultra low volume spraying, low-gallonage spraying or ultra low volume electrostatic spray, realizes the effective control to crop pest.
Background technology
At present for easily producing the control of insect of resistance in agricultural, what main way was exploitation and existing kind without between the new composition of cross resistance or existing pesticide species is composite, the former is because required development cost is high, the cycle is long, and the speed that development rate produces less than pest resistance to insecticide far away at present.Therefore, for the different existing pesticide species of the mechanism of action, being mixed is a kind of selection of the best.If reasonable mixture ratio, can produce significant synergistic effect, make field control effect significantly be better than the effect of each single dose.On agricultural insect pests control, usually there is certain defect in the insecticide that contains single-activity composition, continuous several times is used and is not only made insect easily develop immunity to drugs, and easily cause the pollution to food and environment, by rational mixture between pesticide active ingredient, can overcome above shortcoming.The reasonably composite synergistic effect that active ingredient is produced simultaneously, can improve preventive effect, reduce effective ingredient consumption, cost-saving, delay the drug-fast generation of insect, closely can alleviate and even avoid the pollution of agricultural chemicals to food and environment, and the efficient novel pesticide of the low toxicity that the present invention researchs and develops, not only target drug effect is significantly strengthened, and very low on the impact of people, crop, non-target and environment.
Silafluofene chemical name is (4-ethoxyl phenenyl)-[3-(the fluoro-3-phenoxy group-phenyl of 4-) propyl group] dimethylsilane; Molecular formula is C25H29FO2Si, and English name is Silafluofen, and chemical structural formula is:
Figure BDA0000437094790000021
Silafluofene is siliceous novel organic insecticide, there is stomach toxicity and action of contace poison, without interior suction conduction, active high, stable chemical nature, the speed of knocking down is fast, insecticidal spectrum is wide, termite is shown to good repellent action, family expenses aspect, as termite preventing and controlling agent, dress material insect-proof agent, in agricultural production, can prevent and treat the insects such as plant hopper, leafhopper class, stinkbug class, rice leaf roller, locust.Silafluofene, to mammal and fish low toxicity, can be used safely in paddy field.
In the present invention, the chemical name of the related organophosphorus insecticides of active component II is as follows:
The chemical name that kills snout moth's larva phosphorus is O, O-dimethyl-O-(3-methyl-4-nitrobenzophenone) thiophosphate;
The chemical name of quinalphos is O, O-diethyl-O-(diethquinalphione) thiophosphate;
The chemical name of Hostathion is O, O-diethyl-O-(1-phenyl-1,2,4-triazole-3-group) thiophosphate;
The chemical name of diazinon is O, O-diethyl-O-[6-methyl-2-(1-Methylethyl)-4-pyrimidine radicals] thiophosphate;
The chemical name of phoxim is 0,0-diethyl-0-(benzene acetonitrile ketoxime) thiophosphate;
The chemical name of sumithion is O, O-dimethyl-O-(3-methyl-4-nitrobenzophenone) thiophosphate;
The chemical name of Profenofos is O-ethyl-O-(the bromo-2-chlorphenyl of 4-)-S-propyl dithiocarbamate phosphate;
The chemical name of chlopyrifos is O, O-diethyl-O-(3,5,6-trichloro-2-pyridyl) D2EHDTPA;
The chemical name of malathion is O, O-dimethyl-S-[1,2-bis-(ethoxy carbonyl) ethyl] phosphorodithioate; ;
The chemical name of isocarbophos is O-methyl-O-(2-isopropoxy carboxyl phenyl) thio-phosphamide.
The inventor is by studies have shown that, silafluofene with kill the ultra low volume liquids that the arbitrary pesticide active ingredient in snout moth's larva phosphorus, quinalphos, Hostathion, diazinon, phoxim, sumithion, Profenofos, chlopyrifos, malathion, isocarbophos is re-dubbed target pest had to high synergistic effect.
The solvent that ultra low volume liquids is low by screening volatility, flash-point is high, good to former medicine dissolubility, low to chemical injury of crops, viscosity is low, during dispenser, be not watered, but directly use with ultra low volume sprayer tool, low-gallonage spraying apparatus or ultra low volume electrostatic spray apparatus.Ultra low volume spraying is owing to not containing high volatile volatile composition in droplet, and its size does not have significant change with quality from leave spraying apparatus arrival target process, has reduced and has volatilized with elegant.Droplet is tiny and even, meets " biological best granula " requirement, has significantly improved deposition.Owing to using without being watered, ultra low volume liquids is suitable for water scarcity, damage by disease and insect fulminant large area occurs and the occasion of dispenser on a large scale in the palpus short time, and ultra low volume spraying simultaneously reduces operator's labour intensity greatly.
Summary of the invention
The object of this invention is to provide the ultra low volume liquids preparation of a kind of fluorine silicon chrysanthemum ester and organophosphorus insecticides, and the preparation method of described ultra low volume liquids is provided.
The ultra low volume liquids formulation that the present invention makes, it be take silafluofene and active component II composite be active component, all the other supply 100% with surfactant and solvent; Active component II kills any one in snout moth's larva phosphorus, quinalphos, Hostathion, diazinon, phoxim, sumithion, Profenofos, chlopyrifos, malathion, isocarbophos.
This ultra low volume liquids take silafluofene and active component II composite be active component, the weight content of its total amount is 0.2%~45%, the weight content of silafluofene is 0.1%~15%, the weight content of active component II is 0.1%~30%, the weight content of auxiliary agent is 1%~10%, and solvent complements to 100%.
Applicable surfactant is selected from fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, Ben-zylphenol Polyoxyethyl Ether, castor oil ethylene oxide adduct, aliphatic alcohol polyoxyvinethene phosphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, N-methyl fatty acyl group sodium taurocholate, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, aliphatic alcohol sulfate, OPEO, lauryl sodium sulfate, calcium dodecyl benzene sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, penetrant t, bleeding agent OT, azone, organosilicon.
Applicable solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and polar solvent; Aromatic hydrocarbon solvent comprises trimethylbenzene, o-dichlorohenzene, durene, diethylbenzene, methyl-propyl benzene, methoxy toluene, benzyl methyl ether, butylbenzene, methyl naphthalene, repefral, dibutyl phthalate, dioctyl phthalate, two wires oil; Plant oil solvent comprises soybean oil, epoxidized soybean oil, cottonseed oil, rapeseed oil, corn oil, castor oil, turpentine oil, methyl oleate, ethyl oleate; Polar solvent comprises acetophenone, cyclohexanone, butanone, phenmethylol, methyl-sulfoxide, 1-METHYLPYRROLIDONE, N, dinethylformamide, DMA, n-hexyl alcohol, n-octyl alcohol, isoamyl alcohol, Liquid Macrogol, PEG400,2-butyl acetate, diethylene glycol acetate, terpineol, ethanol.
The preparation method of ultra low volume liquids of the present invention is, in the reaction vessel stirring at band, first with solvent by after active component stirring and dissolving, then add auxiliary component, fully be uniformly mixed, obtain the ultra low volume liquids of fluorine silicon chrysanthemum ester and organophosphorus insecticides; Technological parameter is: it is 60~150 revs/min that mixing speed is controlled, and mixing time is 15~60 minutes, and temperature is normal temperature, and pressure is normal pressure.
Applicable target crop is the cereal crops such as paddy rice, wheat, the economic crops such as sugarcane, banana, rubber, cotton, tea tree, oranges and tangerines, apple, hawthorn, peach, the vegetable crops such as tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, the ground family crops such as cucumber, pumpkin, watermelon.
Ultra low volume liquids of the present invention is applicable to control rice fulgorid, rice leaf roller, brown planthopper, white-backed planthopper, small brown rice planthopper, striped rice borer, rice thrips, rice gall midge, rice leafhopper, rice leafhopper, rice spider rafter stinkbug, resembles star stinkbug, green rice bug resembles, red must fleahopper, the negative mixed worm of rice, rice cylinder water snout moth's larva, oryza chinensis, Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving.The cured a red-spotted lizard in angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge, tomato Liriomyza.
The method for optimizing of using ultra low volume liquids of the present invention is ultra low volume spraying, is secondly low-gallonage spraying and ultra low volume electrostatic spray, and according to controlling object, a situation arises determines suitable dosage, and formulation rate is 75~150g a.i./hm conventionally 2.
Ultra low volume liquids of the present invention is easy to process, with low cost, good drug efficacy, holding effect long, coordinate synergy high, save water; Can reduce environmental pollution, improve agricultural chemicals availability, reduce applications of pesticide amount.
Embodiment
Below in conjunction with embodiment, the present invention is further described, but do not limit the scope of the invention.
Embodiment 1
Prepare 2.1% silafluofene and kill snout moth's larva phosphorus ultra low volume liquids
Figure BDA0000437094790000061
Preparation technology: in the reaction vessel stirring at band, first with solvent by silafluofene with kill after snout moth's larva phosphorus stirring and dissolving, then add auxiliary component, be fully uniformly mixed, obtain 2.1% silafluofene and kill snout moth's larva phosphorus ultra low volume liquids; Technological parameter is: it is 60~150 revs/min that mixing speed is controlled, and mixing time is 15~60 minutes, and temperature is normal temperature, and pressure is normal pressure.
According to the step of preparation process identical with embodiment 1, can prepare following examples.
Embodiment 2
Prepare 12.1% silafluofene and kill snout moth's larva phosphorus ultra low volume liquids
Figure BDA0000437094790000071
Embodiment 3
Prepare 30% silafluofene and kill snout moth's larva phosphorus ultra low volume liquids
Figure BDA0000437094790000072
Figure BDA0000437094790000081
Embodiment 4
Prepare 45% silafluofene and kill snout moth's larva phosphorus ultra low volume liquids
Figure BDA0000437094790000082
Embodiment 5
Prepare 7.1% quinalphos silafluofene ultra low volume liquids
Figure BDA0000437094790000083
Embodiment 6
Prepare 20.1% quinalphos silafluofene ultra low volume liquids
Figure BDA0000437094790000092
Figure BDA0000437094790000101
Embodiment 7
Prepare 32% silafluofene quinalphos ultra low volume liquids
Figure BDA0000437094790000102
Embodiment 8
Prepare 45% silafluofene quinalphos ultra low volume liquids
Figure BDA0000437094790000103
Figure BDA0000437094790000111
Embodiment 9
Prepare 8.1% silafluofene Hostathion ultra low volume liquids
Figure BDA0000437094790000112
Figure BDA0000437094790000121
Embodiment 10
Prepare 15.1% silafluofene Hostathion ultra low volume liquids
Figure BDA0000437094790000122
Embodiment 11
Prepare 18% silafluofene Hostathion ultra low volume liquids
Figure BDA0000437094790000131
Embodiment 12
Prepare 45.0% silafluofene Hostathion ultra low volume liquids
Figure BDA0000437094790000132
Embodiment 13
Prepare 5.1% silafluofene diazinon ultra low volume liquids
Figure BDA0000437094790000142
Embodiment 14
Prepare 25.1% silafluofene diazinon ultra low volume liquids
Figure BDA0000437094790000151
Embodiment 15
Prepare 33% silafluofene diazinon low capacity liquor
Figure BDA0000437094790000152
Figure BDA0000437094790000161
Embodiment 16
Prepare 45% silafluofene diazinon low capacity liquor
Figure BDA0000437094790000162
Embodiment 17
Prepare 13.1% phoxim silafluofene ultra low volume liquids
Figure BDA0000437094790000163
Figure BDA0000437094790000171
Embodiment 18
Prepare 30.1% phoxim silafluofene ultra low volume liquids
Figure BDA0000437094790000172
Figure BDA0000437094790000181
Embodiment 19
Prepare 25% phoxim silafluofene ultra low volume liquids
Figure BDA0000437094790000182
Embodiment 20
Prepare 45% phoxim silafluofene ultra low volume liquids
Figure BDA0000437094790000183
Embodiment 21
Prepare 7.1% sumithion silafluofene ultra low volume liquids
Figure BDA0000437094790000192
Figure BDA0000437094790000201
Embodiment 22
Prepare 15.1% sumithion silafluofene ultra low volume liquids
Figure BDA0000437094790000202
Embodiment 23
Prepare 30% sumithion silafluofene ultra low volume liquids
Figure BDA0000437094790000203
Figure BDA0000437094790000211
Embodiment 24
Prepare 45.0% sumithion silafluofene ultra low volume liquids
Figure BDA0000437094790000212
Figure BDA0000437094790000221
Embodiment 25
Prepare 10.1% silafluofene Profenofos ultra low volume liquids
Figure BDA0000437094790000222
Embodiment 26
Prepare 25.1% silafluofene Profenofos ultra low volume liquids
Figure BDA0000437094790000223
Figure BDA0000437094790000231
Embodiment 27
Prepare 24% silafluofene Profenofos ultra low volume liquids
Figure BDA0000437094790000232
Figure BDA0000437094790000241
Embodiment 28
Prepare 45.0% silafluofene Profenofos ultra low volume liquids
Figure BDA0000437094790000242
Embodiment 29
Prepare 12.1% silafluofene chlopyrifos ultra low volume liquids
Figure BDA0000437094790000243
Figure BDA0000437094790000251
Embodiment 30
Prepare 20.1% silafluofene chlopyrifos ultra low volume liquids
Figure BDA0000437094790000252
Embodiment 31
Prepare 35% silafluofene chlopyrifos ultra low volume liquids
Figure BDA0000437094790000261
Embodiment 32
Prepare 45.0% silafluofene chlopyrifos ultra low volume liquids
Figure BDA0000437094790000262
Figure BDA0000437094790000271
Embodiment 33
Prepare 15.1% silafluofene malathion ultra low volume liquids
Figure BDA0000437094790000272
Embodiment 34
Prepare 30.1% silafluofene malathion ultra low volume liquids
Figure BDA0000437094790000282
Embodiment 35
Prepare 29% silafluofene malathion ultra low volume liquids
Figure BDA0000437094790000283
Figure BDA0000437094790000291
Embodiment 36
Prepare 45.0% silafluofene malathion ultra low volume liquids
Figure BDA0000437094790000292
Embodiment 37
Prepare 5.1% silafluofene isocarbophos ultra low volume liquids
Figure BDA0000437094790000301
Embodiment 38
Prepare 30.1% silafluofene isocarbophos ultra low volume liquids
Figure BDA0000437094790000311
Embodiment 39
Prepare 35% silafluofene isocarbophos ultra low volume liquids
Figure BDA0000437094790000312
Embodiment 40
Prepare 45.0% silafluofene isocarbophos ultra low volume liquids
Figure BDA0000437094790000321
Prepared fluorine silicon chrysanthemum ester and the ultra low volume liquids outward appearance of organophosphorus insecticides are homogeneous oily liquids; Under 5 ℃ of conditions of the good , of low-temperature phase capacitive –, refrigeration 7d is crystallization and suspension not; Volatility is low, and filter paper hangs sends out measurement result, and volatility is lower than 30%; To plant safety, without poisoning; The employing method of remaining silent is measured, and flash-point is greater than 70 ℃; Viscosity is less than 30mPas; Conductance is 1 * 10 -6~1 * 10 -10within the scope of s/cm.
The furthermore bright beneficial effect of the present invention of field efficacy measurement result carrying out in conjunction with the application embodiment of the present invention more below.
Application Example of the present invention is the method that adopts Toxicity Determination and field control effectiveness test to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80 < CTC < 120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field control effectiveness test.
Application Example 1
Controlling object: rice fulgorid
Experiment place: Wuming County rice field, Nanning City
Application method: ultra low volume spraying
Formulation rate: 120g a.i./hm 2
Contrast medicament: 25% pymetrozine wp, preparation mu consumption 16g, is diluted with water to the conventional spraying of 30L
Table 1: control rice fulgorid field control effectiveness test result
Figure BDA0000437094790000331
As can be seen from Table 1: ultra low volume liquids of the present invention adopts ultra low volume spraying method control rice fulgorid, and than contrasting, the conventional spraying of medicament quick-acting is strong, control efficiency good, the lasting period is longer.
Application Example 2
Controlling object: aphid
Experiment place: Nanning City's three pool sugarcane fields
Application method: ultra low volume spraying
Formulation rate: 120g a.i./hm 2.
Contrast medicament: 10% Imidacloprid wp, preparation mu consumption 25g, is diluted with water to the conventional spraying of 30L
Table 2: control sugarcane Control of Aphids result
Figure BDA0000437094790000341
As can be seen from Table 2: ultra low volume liquids of the present invention adopts ultra low volume spraying method control sugarcane aphid, and than contrasting, the conventional spraying of medicament quick-acting is strong, control efficiency good, the lasting period is longer.

Claims (5)

1. the ultra low volume liquids of fluorine silicon chrysanthemum ester and organophosphorus insecticides, is characterized in that: it be take silafluofene and active component II composite be active component, all the other supply 100% ultra low volume liquids with surfactant and solvent; Active component II kills any one of snout moth's larva phosphorus, quinalphos, Hostathion, diazinon, phoxim, sumithion, Profenofos, chlopyrifos, malathion, isocarbophos.
2. the ultra low volume liquids of fluorine silicon chrysanthemum ester according to claim 1 and organophosphorus insecticides, it is characterized in that: silafluofene and active component II are composite is active component, the weight content of its total amount is 0.2%~45%, the weight content of silafluofene is 0.1%~15%, the weight content of active component II is 0.1%~30%, the weight content of auxiliary agent is 1%~10%, and solvent complements to 100%.
3. the ultra low volume liquids of fluorine silicon chrysanthemum ester according to claim 1 and organophosphorus insecticides, it is characterized in that: described surfactant is fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, Ben-zylphenol Polyoxyethyl Ether, castor oil ethylene oxide adduct, aliphatic alcohol polyoxyvinethene phosphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, N-methyl fatty acyl group sodium taurocholate, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, aliphatic alcohol sulfate, OPEO, lauryl sodium sulfate, calcium dodecyl benzene sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, penetrant t, bleeding agent OT, azone, the combination of one or more in organosilicon.
4. the ultra low volume liquids of fluorine silicon chrysanthemum ester according to claim 1 and organophosphorus insecticides, is characterized in that: described solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and polar solvent; Aromatic hydrocarbon solvent comprises trimethylbenzene, o-dichlorohenzene, durene, diethylbenzene, methyl-propyl benzene, methoxy toluene, benzyl methyl ether, butylbenzene, methyl naphthalene, repefral, dibutyl phthalate, dioctyl phthalate, two wires oil; Plant oil solvent comprises soybean oil, epoxidized soybean oil, cottonseed oil, rapeseed oil, corn oil, castor oil, turpentine oil, methyl oleate, ethyl oleate; Polar solvent comprises acetophenone, cyclohexanone, butanone, phenmethylol, methyl-sulfoxide, 1-METHYLPYRROLIDONE, N, dinethylformamide, DMA, n-hexyl alcohol, n-octyl alcohol, isoamyl alcohol, Liquid Macrogol, PEG400,2-butyl acetate, diethylene glycol acetate, terpineol, ethanol.
5. the ultra low volume liquids of fluorine silicon chrysanthemum ester according to claim 1 and organophosphorus insecticides, it is characterized in that: the preparation method of described ultra low volume liquids is, in the reaction vessel stirring at band, first with solvent by after active component stirring and dissolving, add again auxiliary component, fully be uniformly mixed, obtain the ultra low volume liquids of fluorine silicon chrysanthemum ester and organophosphorus insecticides; Technological parameter is: it is 60~150 revs/min that mixing speed is controlled, and mixing time is 15~60 minutes, and temperature is normal temperature, and pressure is normal pressure.
CN201310680711.3A 2013-12-13 2013-12-13 Ultra-low volume liquid containing silafluofen and organophosphorus insecticide Pending CN103688989A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106259317A (en) * 2016-08-09 2017-01-04 山东科源化工有限公司 A kind of Profenofos ultra low volume liquids and preparation method thereof
CN106259421A (en) * 2016-08-09 2017-01-04 山东科源化工有限公司 A kind of cypermethrin Profenofos ultra low volume liquids and preparation method thereof
CN107251895A (en) * 2017-06-08 2017-10-17 深圳诺普信农化股份有限公司 Spray adjuvantses and its preparation and application

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997040692A1 (en) * 1996-04-29 1997-11-06 Novartis Ag Pesticidal compositions
CN101356924A (en) * 2008-09-19 2009-02-04 江苏丘陵地区镇江农业科学研究所 Composite insecticide containing silafluofene

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997040692A1 (en) * 1996-04-29 1997-11-06 Novartis Ag Pesticidal compositions
CN101356924A (en) * 2008-09-19 2009-02-04 江苏丘陵地区镇江农业科学研究所 Composite insecticide containing silafluofene

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106259317A (en) * 2016-08-09 2017-01-04 山东科源化工有限公司 A kind of Profenofos ultra low volume liquids and preparation method thereof
CN106259421A (en) * 2016-08-09 2017-01-04 山东科源化工有限公司 A kind of cypermethrin Profenofos ultra low volume liquids and preparation method thereof
CN107251895A (en) * 2017-06-08 2017-10-17 深圳诺普信农化股份有限公司 Spray adjuvantses and its preparation and application

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Application publication date: 20140402