CN103666677A - Hot-rolling lubricant for silver and silver alloy plate strip - Google Patents
Hot-rolling lubricant for silver and silver alloy plate strip Download PDFInfo
- Publication number
- CN103666677A CN103666677A CN201310585258.8A CN201310585258A CN103666677A CN 103666677 A CN103666677 A CN 103666677A CN 201310585258 A CN201310585258 A CN 201310585258A CN 103666677 A CN103666677 A CN 103666677A
- Authority
- CN
- China
- Prior art keywords
- silver
- alloy plate
- rolling lubricant
- plate strip
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000004332 silver Substances 0.000 title claims abstract description 29
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 28
- 239000000314 lubricant Substances 0.000 title claims abstract description 18
- 238000005098 hot rolling Methods 0.000 title claims abstract description 16
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title description 20
- 229910001316 Ag alloy Inorganic materials 0.000 title description 2
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 15
- 239000000956 alloy Substances 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000002199 base oil Substances 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 6
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 6
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 6
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 6
- 239000002270 dispersing agent Substances 0.000 claims abstract description 6
- 239000003607 modifier Substances 0.000 claims abstract description 6
- 239000003921 oil Substances 0.000 claims abstract description 6
- 239000002131 composite material Substances 0.000 claims abstract description 4
- 239000006078 metal deactivator Substances 0.000 claims description 4
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 4
- FLIACVVOZYBSBS-UHFFFAOYSA-N Methyl hexadecanoate Natural products CCCCCCCCCCCCCCCC(=O)OC FLIACVVOZYBSBS-UHFFFAOYSA-N 0.000 claims description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical group CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 2
- 229920002367 Polyisobutene Polymers 0.000 claims description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical group O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 235000019271 petrolatum Nutrition 0.000 claims description 2
- 229940083037 simethicone Drugs 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- 229960002317 succinimide Drugs 0.000 claims description 2
- -1 Dioctyl compound Chemical class 0.000 claims 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims 2
- 239000004264 Petrolatum Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 229940066842 petrolatum Drugs 0.000 claims 1
- 238000005096 rolling process Methods 0.000 abstract description 5
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 238000005202 decontamination Methods 0.000 abstract description 3
- 230000003588 decontaminative effect Effects 0.000 abstract description 3
- 230000009849 deactivation Effects 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 3
- 235000013305 food Nutrition 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910001361 White metal Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229910000898 sterling silver Inorganic materials 0.000 description 1
- 239000010934 sterling silver Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000010969 white metal Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
一种银及其合金板带材热轧润滑剂，采用15号工业白油作为基础油，配合多种复合添加剂，包括：抗磨剂、油性剂、抗氧剂、抗泡剂、金属减活剂、助剂、摩擦改进剂、分散剂。具备必要的分隔介质、减少摩擦、抗磨损的性能；对轧件和轧辊其化学性能都是稳定的；能防止在轧机和轧制产品上产生粘附物，具有良好的去垢性能，以便清除可能落到板带材或辊道上的轧制润滑剂。A lubricant for hot rolling of silver and its alloy plates and strips, using No. 15 industrial white oil as the base oil, combined with a variety of composite additives, including: anti-wear agent, oily agent, antioxidant, anti-foaming agent, metal deactivation Agents, additives, friction modifiers, dispersants. It has the necessary performance of separating media, reducing friction and anti-wear; it is stable to the chemical properties of the rolled piece and the roll; it can prevent adhesions on the rolling mill and rolled products, and has good decontamination performance for easy removal Rolling lubricants that may fall onto the strip or roll tables.
Description
技术领域technical field
本发明属银及其合金板带材热轧润滑剂领域。The invention belongs to the field of hot-rolling lubricants for silver and its alloy plates and strips.
背景技术Background technique
纯银是一种美丽的银白色的金属，它具有很好的延展性，其导电性和传热性在所有的金属中都是最高的。银常用来制作灵敏度极高的物理仪器元件，各种自动化装置、火箭、潜水艇、计算机、核装置以及通讯系统，所有这些设备中的大量的接触点都是用银制作的。在使用期间，每个接触点要工作上百万次，必须耐磨且性能可靠，能承受严格的工作要求，银完全能满足种种要求。如果在银中加入稀土元素，性能就更加优良。用这种加稀土元素的银制作的接触点，寿命可以延长好几倍。元素用途：用于制合金、焊药、银箔、银盐、化学仪器等，并用于制银币和底银等方面。银还是一种可为人类食用的金属，在我国和印度均有用银箔包裹食品和丸药服用的记载。同时银还是某些生物的食物。由于银独有的优良特性，人们曾赋予它货币和装饰双重价值，英镑和我国解放前用的银元，就是以银为主的银、铜合金。由于银热轧温度较高，其润滑剂成分相对同周期元素而言更复杂一些。Sterling silver is a beautiful silver-white metal that is very malleable and has the highest conductivity and heat transfer properties of all metals. Silver is commonly used to make the extremely high physical instrument element of sensitivity, and in various automation installation, rocket, undersea boat, computer, nuclear installation and communication system, a large amount of point of contact in all these equipments is all made of silver. During use, each contact point will work millions of times, must be wear-resistant and reliable, and can withstand strict work requirements. Silver can fully meet various requirements. If rare earth elements are added to silver, the performance will be even better. The lifespan of the contact point made of silver added with rare earth elements can be extended several times. Element use: used for making alloys, welding powder, silver foil, silver salts, chemical instruments, etc., and for making silver coins and bottom silver, etc. Silver is also a metal that can be eaten by humans. There are records of wrapping food and pills in silver foil in my country and India. At the same time, silver is also the food of some organisms. Due to the unique and excellent characteristics of silver, people once gave it double value as currency and decoration. The British pound and the silver dollar used before the liberation of our country are silver-based silver and copper alloys. Due to the high hot rolling temperature of silver, its lubricant composition is more complex than that of elements of the same period.
发明内容Contents of the invention
本发明要解决的技术问题是提供一种具备必要的分隔介质、减少摩擦、抗磨损的性能、能防止在轧机和轧制产品上产生粘附物，具有良好的去垢性能的银及其合金板带材热轧润滑剂。The technical problem to be solved by the present invention is to provide a silver and its alloys with the necessary separation medium, friction reduction, anti-wear performance, prevention of adhesions on rolling mills and rolled products, and good decontamination performance Lubricant for hot rolling of plate and strip.
本发明以如下技术方案解决上述技术问题：采用15号工业白油作为基础油，配合多种复合添加剂，其各组分及其质量百分数为：The present invention solves the above-mentioned technical problems with the following technical solutions: No. 15 industrial white oil is used as the base oil, combined with various composite additives, and its components and their mass percentages are:
基础油是15号工业白油。The base oil is No. 15 industrial white oil.
抗磨剂是质量比40%～50%的磷酸三甲酚酯与60%～50%的癸二酸二辛酯复合。The antiwear agent is composed of tricresyl phosphate with a mass ratio of 40% to 50% and dioctyl sebacate at 60% to 50%.
油性剂是质量比60%～70%的硫化蓖麻油与40%～30%的棕榈酸甲酯复合。The oily agent is compounded by mass ratio of 60%-70% sulfurized castor oil and 40%-30% methyl palmitate.
抗氧剂是质量比60%～50%的2,6-二叔丁基对甲酚与40%～50%的N-苯基-a-萘胺复合。The antioxidant is a compound of 2,6-di-tert-butyl-p-cresol and 40%-50% of N-phenyl-a-naphthylamine with a mass ratio of 60% to 50%.
抗泡剂是二甲基硅油。The antifoaming agent is simethicone.
金属减活剂是苯三唑衍生物。Metal deactivators are benzotriazole derivatives.
助剂是皂用蜡。The auxiliary agent is soap wax.
分散剂是聚异丁烯丁二酰亚胺。The dispersant is polyisobutylene succinimide.
摩擦改进剂是工业凡士林。The friction modifier is industrial petroleum jelly.
本发明的银及其合金板带材热轧润滑剂，采用15号工业白油作为基础油，配合多种复合添加剂，包括抗磨剂、油性剂、抗氧剂、抗泡剂、金属减活剂、助剂、摩擦改进剂、分散剂。具备必要的分隔介质、减少摩擦、抗磨损的性能；对轧件和轧辊其化学性能都是稳定的；能防止在轧机和轧制产品上产生粘附物，具有良好的去垢性能，以便清除可能落到板带材或辊道上的轧制润滑剂。The silver and alloy plate and strip hot-rolling lubricant of the present invention adopts No. 15 industrial white oil as the base oil, and cooperates with various composite additives, including anti-wear agent, oily agent, antioxidant, anti-foaming agent, metal deactivation agent Agents, additives, friction modifiers, dispersants. It has the necessary performance of separating media, reducing friction and anti-wear; it is stable to the chemical properties of the rolled piece and the roll; it can prevent adhesions on the rolling mill and rolled products, and has good decontamination performance for easy removal Rolling lubricants that may fall onto the strip or roll tables.
具体实施方式Detailed ways
实施例1：Example 1:
将下列组分按质量百分比调和而成：The following components are blended according to mass percentage:
以上组分总和为100%。The sum of the above components is 100%.
实施例2：Example 2:
将下列质量百分比调和而成：Blend the following mass percentages:
以上组分总和为100%。The sum of the above components is 100%.
实施例3：Example 3:
将下列质量百分比调和而成：Blend the following mass percentages:
以上组分总和为100%。The sum of the above components is 100%.
以下是实施例1产品的主要理化指标：The following are the main physical and chemical indicators of the product of Example 1:
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310585258.8A CN103666677B (en) | 2013-11-19 | 2013-11-19 | Hot-rolling lubricant for silver and silver alloy plate strip |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310585258.8A CN103666677B (en) | 2013-11-19 | 2013-11-19 | Hot-rolling lubricant for silver and silver alloy plate strip |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666677A true CN103666677A (en) | 2014-03-26 |
| CN103666677B CN103666677B (en) | 2015-04-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310585258.8A Expired - Fee Related CN103666677B (en) | 2013-11-19 | 2013-11-19 | Hot-rolling lubricant for silver and silver alloy plate strip |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666677B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106544109A (en) * | 2016-11-04 | 2017-03-29 | 广西大学 | A kind of silver alloy cutting technology lubricant compositions |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004263087A (en) * | 2003-03-03 | 2004-09-24 | Kao Corp | Lubricating oil for use in hot rolling oil for aluminum plate |
| CN101705144A (en) * | 2009-11-20 | 2010-05-12 | 王恩臣 | Lubricating oil for methanol fuel engine and preparation method thereof |
| CN103232884A (en) * | 2013-04-28 | 2013-08-07 | 广西大学 | Universal oil composition for environment-friendly energy-saving engineering machinery |
-
2013
- 2013-11-19 CN CN201310585258.8A patent/CN103666677B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004263087A (en) * | 2003-03-03 | 2004-09-24 | Kao Corp | Lubricating oil for use in hot rolling oil for aluminum plate |
| CN101705144A (en) * | 2009-11-20 | 2010-05-12 | 王恩臣 | Lubricating oil for methanol fuel engine and preparation method thereof |
| CN103232884A (en) * | 2013-04-28 | 2013-08-07 | 广西大学 | Universal oil composition for environment-friendly energy-saving engineering machinery |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106544109A (en) * | 2016-11-04 | 2017-03-29 | 广西大学 | A kind of silver alloy cutting technology lubricant compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103666677B (en) | 2015-04-29 |
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| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
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Granted publication date: 20150429 |