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CN103588441B - Environment-friendlycolor color dry-powder crack-sealer and preparation method thereof - Google Patents

Environment-friendlycolor color dry-powder crack-sealer and preparation method thereof Download PDF

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Publication number
CN103588441B
CN103588441B CN201310541406.6A CN201310541406A CN103588441B CN 103588441 B CN103588441 B CN 103588441B CN 201310541406 A CN201310541406 A CN 201310541406A CN 103588441 B CN103588441 B CN 103588441B
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powder
environment
agent
water
steel slag
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CN103588441A (en
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马小翠
张炎
张劲
王雪
马娇丽
陆文雄
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Shanghai Fupei New Material Technology Co ltd
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SHANGHAI YUPEI SPECIAL BUILDING MATERIAL CO Ltd
University of Shanghai for Science and Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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Abstract

The present invention relates to a kind of Environment-friendlycolor color dry-powder crack-sealer and preparation method thereof.Raw material composition of the present invention and weight percent thereof are: cement 25 ~ 35%; Superfine steel slag micropowder 15 ~ 20%; Sand 40 ~ 50%; Calcite in powder 10 ~ 15; Redispersible latex powder 2 ~ 3%; Adhesion promotor 0.1 ~ 0.2%; Alkali inhibitor 0.5 ~ 1.5%; Hydrophober 0.1 ~ 0.2%; Thickening material 0.05 ~ 0.1%; Tinting material 0.3 ~ 0.5%; Mineral dye 2 ~ 5%.Environment-friendlycolor color dry-powder crack-sealer of the present invention has that caking ability is high, water proof anti-seepage, splitting resistance are good, suppresses the excellent properties such as the accumulation of salt in the surface soil, rich color.Simultaneously due to this jointing agent with industrial solid castoff superfine steel slag micropowder for raw material; with low cost; production technique and equipment simple; for industrial solid castoff opens the new way of a recycling; while protecting environment; also a saving natural resources, there is good economic benefit, social benefit and environmental benefit, be suitable for suitability for industrialized production and apply.

Description

环保型彩色干粉勾缝剂及其制备方法Environment-friendly colored dry powder pointing agent and preparation method thereof

技术领域 technical field

本发明涉及一种干粉勾缝剂及其制备方法,特别是一种环保型彩色干粉勾缝剂及其制备方法。 The invention relates to a dry powder pointing agent and a preparation method thereof, in particular to an environment-friendly colored dry powder pointing agent and a preparation method thereof.

背景技术 Background technique

钢渣是炼钢过程中排放的一种工业固体废弃物。近几年来,我国排放的钢渣将近亿吨,而且每年仍以8000万吨的速度递增。然而,我国的钢渣利用率不足17%,造成大量钢渣堆积,不仅占用了大量的土地资源,而且给当地的环境带来严重的污染。在钢渣资源化利用的过程中,将钢渣应用于建筑行业一直是人们研究的热点,其中包括勾缝剂。 Steel slag is an industrial solid waste discharged during the steelmaking process. In recent years, my country has discharged nearly 100 million tons of steel slag, and it is still increasing at a rate of 80 million tons every year. However, the utilization rate of steel slag in my country is less than 17%, resulting in a large amount of steel slag accumulation, which not only occupies a large amount of land resources, but also brings serious pollution to the local environment. In the process of resource utilization of steel slag, the application of steel slag in the construction industry has always been a research hotspot, including pointing agents.

勾缝剂又名填缝剂、沟缝剂,主要用于填充瓷砖或石材间缝隙的材料,与瓷砖、石材等装饰材料相配合提供美观的饰面及保证饰面砖之间的粘接和防渗。传统的勾缝材料主要以水泥、石英砂及各种助剂复配而成,普遍存在粘结力差、易脱落、防水性差、易泛碱,收缩率大、易开裂,颜色单一等问题,从而影响整个建筑的质量和美观。本发明制备的新型勾缝剂以工业固体废弃物----超细钢渣微粉为原料,不仅具有粘结力强、抑制泛碱、收缩率小、颜色多样等特点,而且开辟了固体废弃物钢渣资源化利用的新途径,保护了自然环境、节约了资源和能源。 Pointing agent, also known as caulking agent and grouting agent, is mainly used to fill the gaps between tiles or stones, and cooperate with decorative materials such as tiles and stones to provide beautiful finishes and ensure the bonding and anti-corrosion between facing tiles. Seep. Traditional jointing materials are mainly made of cement, quartz sand and various additives, which generally have problems such as poor adhesion, easy to fall off, poor water resistance, easy to efflorescence, large shrinkage, easy to crack, and single color. Thus affecting the quality and aesthetics of the entire building. The new jointing agent prepared by the present invention uses industrial solid waste---ultrafine steel slag micropowder as raw material, which not only has the characteristics of strong cohesive force, inhibition of efflorescence, small shrinkage rate, and various colors, but also opens up the possibility of solid waste A new way of resource utilization of steel slag protects the natural environment and saves resources and energy.

发明内容 Contents of the invention

本发明的目的之一在于提供一种环保型彩色干粉勾缝剂,以解决传统勾缝材料粘结力差、易泛碱、易开裂、颜色单一等问题。 One of the objects of the present invention is to provide an environment-friendly colored dry powder pointing agent to solve the problems of poor adhesion, easy efflorescence, easy cracking and single color of traditional pointing materials.

本发明的目的i之二在于提供该环保型彩色干粉勾缝剂的制备方法。 The second object of the present invention is to provide the preparation method of this environment-friendly colored dry powder grouting agent.

一种环保型彩色干粉勾缝剂,其特征在于该勾缝剂的组成及重量百分含量为: An environment-friendly colored dry powder pointing agent is characterized in that the composition and weight percentage of the pointing agent are:

水泥               25~35%     超细钢渣微粉               15~20% Cement 25~35% Superfine steel slag powder 15~20%

硅砂               40~50%     方解石粉                   10~15% Silica sand 40~50% Calcite powder 10~15%

可再分散性乳胶粉     2~3%     助粘剂                     0.1~0.2% Redispersible latex powder 2~3% Adhesion promoter 0.1~0.2%

碱抑制剂           0.5~1.5%   憎水剂                     0.1~0.2% Alkali inhibitor 0.5~1.5% Hydrophobic agent 0.1~0.2%

增稠剂             0.05~0.1%   着色剂                    0.3~0.5% Thickener 0.05~0.1% Colorant 0.3~0.5%

无机颜料           2~5%; Inorganic pigments 2-5%;

以上各组成的质量百分比之和为100%; The sum of the mass percentages of the above components is 100%;

所述水泥为42.5级普通硅酸盐水泥; Described cement is 42.5 grade ordinary portland cement;

所述的超细钢渣微粉为转炉或电炉钢渣,经磁选除铁处理后粉磨,其比表面 The ultra-fine steel slag micropowder is converter or electric furnace steel slag, which is ground after magnetic separation and iron removal treatment, and its specific surface area

≥600m2/kg,粒径小于30μm的超细钢渣微粉占总质量的90%以上,金属铁含量≤0.5%; ≥600m 2 /kg, ultra-fine steel slag powder with a particle size of less than 30μm accounts for more than 90% of the total mass, and the metallic iron content is ≤0.5%;

所述的硅砂粒径为0.05~0.5mm; The particle size of the silica sand is 0.05-0.5mm;

所述的方解石粉,其细度为200目; Described calcite powder, its fineness is 200 orders;

所述的可再分散乳胶粉为一种遇水可再分散的憎水性的乙烯/月桂酸乙烯酯/氯乙烯三元共聚胶粉,其细度为100目; The redispersible latex powder is a hydrophobic ethylene/vinyl laurate/vinyl chloride ternary copolymer powder that can be redispersed in water, and its fineness is 100 mesh;

所述的助粘剂为聚乙烯醇; Described adhesion promoter is polyvinyl alcohol;

所述的碱抑制剂为丙烯酸胶粉; Described alkali inhibitor is acrylic acid rubber powder;

所述的憎水剂是一种采用溶于水的保护胶体和抗结块剂,通过喷雾干燥将硅烷包裹后获得的改性硅烷/硅氧烷的粉末高效憎水剂; The water-repellent agent is a modified silane/siloxane powder high-efficiency water-repellent agent obtained by spray-drying and wrapping silane with a water-soluble protective colloid and an anti-caking agent;

所述的增稠剂为甲基纤维素、乙基纤维素、羟乙基纤维素、羟乙基甲基纤维素、羟丙基甲基纤维素中至少一种,细度为100目; The thickener is at least one of methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxyethylmethylcellulose, and hydroxypropylmethylcellulose, and the fineness is 100 mesh;

所述的着色剂为钛白粉; Described colorant is titanium dioxide;

所述的无机颜料是有色金属的氧化物或不溶性的金属盐。 The said inorganic pigments are colored metal oxides or insoluble metal salts.

上述的溶于水的保护胶体为:EVA可分散乳胶粉 有机硅粉末 The above water-soluble protective colloids are: EVA dispersible latex powder, silicone powder

上述的溶于水的抗结块剂为:硬质酸钙。 The above-mentioned water-soluble anti-caking agent is: calcium hardate.

上述的所述的有色金属的氧化物为:氧化铁红 氧化铁黑。 The oxides of the above-mentioned non-ferrous metals are: iron oxide red iron oxide black.

上述的所述的不溶性的金属盐为:铬黄。 The aforementioned insoluble metal salt is: chrome yellow.

一种制备上述的环保型彩色干粉勾缝剂的制备方法,其特征在于该方法的具体步骤为:将上述配方充分混合均匀,即得环保型彩色干粉勾缝剂。使用时加水,水灰比为0.5:1,充分搅拌均匀。 A preparation method for the above-mentioned environment-friendly colored dry powder pointing agent is characterized in that the specific steps of the method are: fully mixing the above formula evenly to obtain an environment-friendly colored dry powder pointing agent. Add water when using, the water-cement ratio is 0.5:1, fully stir evenly.

本发明制备的勾缝剂是一种新型环保彩色干粉勾缝剂,它具有如下特点: The pointing agent prepared by the present invention is a new type of environmentally friendly colored dry powder pointing agent, and it has the following characteristics:

1.本发明使用钢渣作为原料来制备勾缝剂,减少了水泥用量,为工业固体废弃物的综合利用开辟了新的途径。本发明不仅降低了勾缝剂的生产成本,而且达到了环保、利废的双重功效。 1. The present invention uses steel slag as a raw material to prepare jointing agent, which reduces the amount of cement and opens up a new way for the comprehensive utilization of industrial solid waste. The invention not only reduces the production cost of the pointing agent, but also achieves the dual effects of environmental protection and waste utilization.

 2.本发明添加有效量的憎水剂和碱抑制剂,提高了新型环保勾缝剂防水抗渗和抑制泛碱性能,保障了其耐候持久。 2. The present invention adds an effective amount of water-repellent agent and alkali inhibitor, which improves the waterproof, anti-seepage and anti-pan-alkaline performance of the new environmentally friendly pointing agent, and ensures its long-lasting weather resistance.

3. 本发明添加有效量的增稠剂和助粘剂,能使产品的保水率高、收缩率小,增强了产品的抗裂性和粘结性。 3. The invention adds an effective amount of thickener and adhesion promoter, which can make the product have high water retention rate and small shrinkage rate, and enhance the crack resistance and adhesion of the product.

4. 本发明添加有效量的各种颜料和着色剂,增大了用户的个性化选择,增强了建筑的装饰性效果。 4. The invention adds effective amounts of various pigments and colorants, which increases the user's personalized choice and enhances the decorative effect of the building.

具体实施方式 Detailed ways

现将本发明的具体实施例叙述于后。 Specific embodiments of the present invention are described below.

实施例1 Example 1

本实施例以制备100kg勾缝剂为例,其制备方法如下。 In this embodiment, the preparation of 100 kg of jointing agent is taken as an example, and its preparation method is as follows.

按规定配比称量配料,各原料的用量为: Weigh the ingredients according to the prescribed ratio, and the amount of each raw material is:

水泥                             25kg Cement 25kg

超细钢渣微粉                     15kg Ultra-fine steel slag powder 15kg

砂子                             44kg Sand 44kg

方解石粉                         10kg Calcite powder 10kg

可再分散性乳胶粉                 2.4kg Redispersible latex powder 2.4kg

助粘剂                           0.1kg Adhesion promoter 0.1kg

碱抑制剂                         1kg Alkali Inhibitors 1kg

憎水剂                           0.15kg Hydrophobic agent 0.15kg

增稠剂                           0.05kg Thickener 0.05kg

着色剂                           0.3kg Colorant 0.3kg

氧化铁类颜料                     2kg Iron oxide pigments 2kg

将上述各种原料放入混合机中,经充分混合均匀后,即得新型环保彩色干粉勾缝剂,使用时加入适量水调和均匀即可。 Put the above-mentioned various raw materials into the mixer, and after fully mixing evenly, a new type of environmentally friendly colored dry powder pointing agent can be obtained. When using, add appropriate amount of water to adjust evenly.

上述实施案例所制得的新型环保彩色干粉勾缝剂按照JG158-2004 《胶粉聚苯颗粒外墙外保温系统》标准中关于勾缝剂的规定进行测试,其各项技术性能指标均符合国家相关标准规定。 The new environment-friendly colored dry powder pointing agent obtained from the above implementation cases was tested according to the provisions on pointing agent in the standard of JG158-2004 "Rubber Powder Polystyrene Particle Exterior Wall External Thermal Insulation System", and its various technical performance indicators all meet the requirements of the national standard. relevant standards.

实施例2 Example 2

本实施例以制备100kg勾缝剂为例,其制备方法如下。 In this embodiment, the preparation of 100 kg of jointing agent is taken as an example, and its preparation method is as follows.

按规定配比称量配料,各原料的用量为: Weigh the ingredients according to the prescribed ratio, and the amount of each raw material is:

水泥                             30kg Cement 30kg

超细钢渣微粉                     16kg Ultra-fine steel slag powder 16kg

砂子                             30kg Sand 30kg

方解石粉                         15kg Calcite powder 15kg

可再分散性乳胶粉                 3kg Redispersible latex powder 3kg

助粘剂                           0.2kg Adhesion promoter 0.2kg

碱抑制剂                         1.5kg Alkali Inhibitors 1.5kg

憎水剂                           0.1kg Hydrophobic agent 0.1kg

增稠剂                           0.1kg Thickener 0.1kg

着色剂                           0.5kg Colorant 0.5kg

氧化铁类颜料                     3.6kg Iron oxide pigments 3.6kg

将上述各种原料放入混合机中,经充分混合均匀后,即得新型环保彩色干粉勾缝剂,使用时加入适量水调和均匀即可。 Put the above-mentioned various raw materials into the mixer, and after fully mixing evenly, a new type of environmentally friendly colored dry powder pointing agent can be obtained. When using, add appropriate amount of water to adjust evenly.

上述实施案例所制得的新型环保彩色干粉勾缝剂按照JG158-2004 《胶粉聚苯颗粒外墙外保温系统》标准中关于勾缝剂的规定进行测试,其各项技术性能指标均符合国家相关标准规定。 The new environment-friendly colored dry powder jointing agent prepared by the above implementation cases was tested according to the provisions on jointing agent in the standard of JG158-2004 "Rubber Powder Polystyrene Particle Exterior Wall External Thermal Insulation System", and its technical performance indicators all meet the requirements of the national standard. relevant standards.

Claims (4)

1.一种环保型彩色干粉勾缝剂,其特征在于该勾缝剂的组成及重量百分含量为: 1. An environment-friendly colored dry powder pointing agent is characterized in that the composition and weight percentage of the pointing agent are: 水泥               25~35%     超细钢渣微粉               15~20% Cement 25~35% Superfine steel slag powder 15~20% 硅砂               40~50%     方解石粉                   10~15% Silica sand 40~50% Calcite powder 10~15% 可再分散性乳胶粉     2~3%     助粘剂                     0.1~0.2% Redispersible latex powder 2~3% Adhesion promoter 0.1~0.2% 碱抑制剂           0.5~1.5%   憎水剂                     0.1~0.2% Alkali inhibitor 0.5~1.5% Hydrophobic agent 0.1~0.2% 增稠剂             0.05~0.1%   着色剂                    0.3~0.5% Thickener 0.05~0.1% Colorant 0.3~0.5% 无机颜料           2~5%; Inorganic pigments 2-5%; 以上各组成的质量百分比之和为100%; The sum of the mass percentages of the above components is 100%; 所述水泥为42.5级普通硅酸盐水泥; Described cement is 42.5 grade ordinary portland cement; 所述的超细钢渣微粉为转炉或电炉钢渣,经磁选除铁处理后粉磨,其比表面 The ultra-fine steel slag micropowder is converter or electric furnace steel slag, which is ground after magnetic separation and iron removal treatment, and its specific surface area ≥600m2/kg,粒径小于30μm的超细钢渣微粉占总质量的90%以上,金属铁含量≤0.5%; ≥600m 2 /kg, ultra-fine steel slag powder with a particle size of less than 30μm accounts for more than 90% of the total mass, and the metallic iron content is ≤0.5%; 所述的硅砂粒径为0.05~0.5mm; The particle size of the silica sand is 0.05-0.5 mm; 所述的方解石粉,其细度为200目; Described calcite powder, its fineness is 200 orders; 所述的可再分散乳胶粉为一种遇水可再分散的憎水性的乙烯/月桂酸乙烯酯/氯乙烯三元共聚胶粉,其细度为100目; The redispersible latex powder is a hydrophobic ethylene/vinyl laurate/vinyl chloride ternary copolymer powder that can be redispersed in water, and its fineness is 100 mesh; 所述的助粘剂为聚乙烯醇; Described adhesion promoter is polyvinyl alcohol; 所述的碱抑制剂为丙烯酸胶粉; Described alkali inhibitor is acrylic acid rubber powder; 所述的憎水剂是一种采用溶于水的保护胶体和抗结块剂,通过喷雾干燥将硅烷包裹后获得的改性硅烷/硅氧烷的粉末高效憎水剂; The water-repellent agent is a modified silane/siloxane powder high-efficiency water-repellent agent obtained by spray-drying and wrapping silane with a water-soluble protective colloid and anti-caking agent; 所述的增稠剂为甲基纤维素、乙基纤维素、羟乙基纤维素、羟乙基甲基纤维素、羟丙基甲基纤维素中至少一种,细度为100目; The thickener is at least one of methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxyethylmethylcellulose, and hydroxypropylmethylcellulose, and the fineness is 100 mesh; 所述的着色剂为钛白粉; Described colorant is titanium dioxide; 所述的无机颜料是有色金属的氧化物或不溶性的金属盐。 The said inorganic pigments are colored metal oxides or insoluble metal salts. 2.根据权利要求1所述的环保型彩色干粉勾缝剂,其特征在于所述的溶于水的保护胶体为:EVA可分散乳胶粉或有机硅粉末。 2. The environment-friendly colored dry powder pointing agent according to claim 1, characterized in that the water-soluble protective colloid is: EVA dispersible latex powder or organic silicon powder. 3.根据权利要求1所述的环保型彩色干粉勾缝剂,其特征在于所述的不溶性的金属盐为:铬黄。 3. The environment-friendly colored dry powder pointing agent according to claim 1, characterized in that said insoluble metal salt is: chrome yellow. 4.一种制备根据权利要求1所述的环保型彩色干粉勾缝剂的制备方法,其特征在于该方法的具体步骤为:将上述配方充分混合均匀,即得环保型彩色干粉勾缝剂,使用时加水,水灰比为0.5:1,充分搅拌均匀。 4. A preparation method for preparing an environment-friendly colored dry powder pointing agent according to claim 1, characterized in that the specific steps of the method are: fully mixing the above-mentioned formula to obtain an environment-friendly colored dry powder pointing agent, Add water when using, the water-cement ratio is 0.5:1, and stir well.
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CN104876501A (en) * 2015-04-21 2015-09-02 济宁跃峰建材科技有限公司 Crack sealer for building exterior wall tile, and preparation method and construction process thereof
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