CN103563961A - Compound pesticidal composition containing thiacloprid and methoxyfenozide and application thereof - Google Patents
Compound pesticidal composition containing thiacloprid and methoxyfenozide and application thereof Download PDFInfo
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- CN103563961A CN103563961A CN201210281594.9A CN201210281594A CN103563961A CN 103563961 A CN103563961 A CN 103563961A CN 201210281594 A CN201210281594 A CN 201210281594A CN 103563961 A CN103563961 A CN 103563961A
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Abstract
The invention discloses a compound pesticidal composition containing thiacloprid and methoxyfenozide and application thereof. The pesticidal composition uses thiacloprid and methoxyfenozide as main effective components, wherein the weight ratio of the thiacloprid to the methoxyfenozide is (0.1-80):(0.5-80). The pesticidal composition can generate higher synergic effect, overcomes and postpones the drug resistance of pests, has the advantages of high pesticidal speed and long duration time, lowers the pesticide cost, and has obviously higher preventing and treating effects than a single agent. The pesticidal composition can be used for preventing and treating Homoptera, Lepidoptera, Hemiptera, Coleoptera, Hymenoptera, Diptera, Thysanoptera and acarid pests on crops, especially has specially good effect on preventing and treating planthoppers, aleyrodids, leafhoppers and aphids in Homoptera, cabbage moths, cotton bollworms and asparagus caterpillars in Lepidoptera, thrips in Thysanoptera, acarids and other pests, and has obviously higher effect than a single agent.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of compound pesticide compositions containing thiacloprid and methoxyfenozide and uses thereof.
Background technology
Thiacloprid (Thiacloprid), chemical name: (3-((6-chloro-3-pyridyl base) methyl)-1,3-thiazoles quinoline-2-subunit) cyanamide, structural formula is:
The former medicine of thiacloprid (Thiacloprid) is developed cooperatively by Bayer Bitterfeld GmbH Nong Hua company and Japanese Bayer Nong Hua company, is novel chloro nicotinic insecticide.Its mechanism of action and other conventional pesticides are different.Its Main Function engages caudacoria in insect nerve, by being combined with nAChR, and interference insect nervous system normal conduction, cause the obstruction of neural channel, cause a large amount of accumulation of acetylcholine, thereby make insect exaltation, whole body spasm, paralysis and dead.There is stronger interior suction, tag and stomach poison function, there is no cross resistance with common insecticides as pyrethroid, organic phosphates and carbamates, thereby can be used for resistance management.For wide spectrum, systemic insecticide.Be mainly used in paddy rice, fruit, vegetables, cotton and prevent and kill off most of insects.
Methoxyfenozide, chemical name: the N-tert-butyl group-N'-(3-methoxyl group-2-methyl benzoyl)-3,5-dimethyl benzene formylhydrazine.Structural formula is:
Sterling is white powder, fusing point 202-205 ℃.Water solubility < 1mg/L in the time of 20 ℃.Solvability in other solvents: dimethyl sulfoxide (DMSO) 11g/L, cyclohexanone 9.9g/L, acetone 9g/L.Stable storage at 25 ℃, 25 ℃, PH=5,7,9 times hydrolysis.
Methoxyfenozide preparation low toxicity, rat acute LD50 of passing through mouth is 5000mg/kg, acute through skin LD50>2000mg/kg.
Methoxyfenozide is a kind of of insect growth regulator, IGR, is mainly that the normal growth of interference insect is grown, though insect molting and dead, and can suppress to ingest.This product is strong to controlling object selectivity, is mainly used in the control of lepidoptera pest.
But aleyrodid, plant hopper, leafhopper, aphid, diamond-back moth, cotton bollworm and thrips are under the condition of current long-term prescription, and resistance increases gradually, and agricultural chemicals single dose declines gradually to the effect of control of insect.Inventor finds after deliberation, and the synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, not yet finds up to now the Pesticidal combination of relevant thiacloprid and methoxyfenozide.
Summary of the invention
The object of this invention is to provide a kind of compound pesticide compositions containing thiacloprid and methoxyfenozide, this Pesticidal combination is the multifunctional insecticide composition of control Homoptera, Lepidoptera, coleoptera, thrips or mite pest.
Another object of the present invention is to provide this compound pesticide compositions and prevents and treats the application on the insecticidal materials of any one or a few insect in resistance Homoptera, Lepidoptera, coleoptera, thrips and mite class in preparation, the particularly application on the insecticidal materials of any one or a few insect in preparation control plant hopper, aleyrodid, leafhopper, aphid, diamond-back moth, cotton bollworm, beet armyworm, thrips and mite class.
The object of the invention is to be achieved through the following technical solutions:
Containing a compound pesticide compositions for thiacloprid and methoxyfenozide, it is main active ingredient that this Pesticidal combination be take thiacloprid and methoxyfenozide, and wherein, the weight ratio of thiacloprid and methoxyfenozide is 0.1 ~ 80:0.5 ~ 80.Be preferably 0.5 ~ 50:2 ~ 50, more preferably 0.5 ~ 10:4 ~ 30.In this Pesticidal combination, effective ingredient is present in composition with synergy effective dose.
In compound pesticide compositions of the present invention, the two weight percentage in this compound pesticide compositions of thiacloprid and methoxyfenozide is 3% ~ 80%.Be preferably 5% ~ 55%, most preferably 10% ~ 40%.
Compound pesticide compositions of the present invention be take thiacloprid and methoxyfenozide and is mixed with any one formulation allowing on agricultural chemicals, the preferred missible oil of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion or water dispersible granules as main active ingredient and insecticides adjuvant and excipient.
Auxiliary agent can adopt calcium dodecyl benzene sulfonate, agriculture breast 600#, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), polyoxyethylene nonylphenol ether etc., excipient comprises cyclohexanone, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can alone or and use.
Compound pesticide compositions containing thiacloprid and methoxyfenozide of the present invention is prevented and treated the application on the insecticidal materials of any one or a few insect in resistance Homoptera, Lepidoptera, coleoptera, thrips and mite class in preparation.Especially in preparation control plant hopper, aleyrodid, leafhopper, aphid, diamond-back moth, cotton bollworm, beet armyworm, thrips and mite class, the effect on the insecticidal materials of any one or a few insect is remarkable.And suppress insect the pesticide resistance of unitary agent (thiacloprid or methoxyfenozide are arbitrary) is produced.
Beneficial effect of the present invention compared with prior art:
(1) compare with single dose, said composition antagonism lepidoptera pest, as diamond-back moth and thrips insect thrips etc. has obvious synergistic function, overcomes and has delayed pest resistance to insecticide, expanding prevention spectrum, and desinsection speed is fast, has obviously improved control efficiency; (2) reduce control recruitment, drug cost; (3) alternative high-toxic pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with methoxyfenozide single dose with thiacloprid, produce and use cost reduction; (6) suppress lepidoptera pest, Homoptera, thrips and mite pest the resistance of agricultural chemicals is strengthened, its successful is used higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1:
Taking thiacloprid, methoxyfenozide adopts conventional formulation method to be mixed with by different proportion the thiacloprid methoxyfenozide missible oil that main active ingredient weight percentage is 30%.Concrete ratio is in Table 1,2.
Adopt leaf dipping method to carry out indoor synergy biologicall test, selecting resistance diamond-back moth is target pest, and every processing repeats 3 times, and every concentration is processed 60, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism diamond-back moth by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 1:
The toxicity test of the composite and single dose antagonism diamond-back moth of table 1 thiacloprid and methoxyfenozide
As shown in Table 1, thiacloprid and methoxyfenozide are composite, and co-toxicity coefficient is all greater than 120, show good synergistic function.
Adopt leaf dipping method to carry out indoor synergy biologicall test, selection resistant bollworm is target pest, and every processing repeats 3 times, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism cotton bollworm by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 2:
The toxicity test of the composite and single dose antagonism cotton bollworm of table 2 thiacloprid and methoxyfenozide
As shown in Table 2, thiacloprid and methoxyfenozide are composite, and the co-toxicity coefficient of cotton bollworm is all greater than to 120, show good synergistic function.
Embodiment 2:
Take 5g thiacloprid, 50g methoxyfenozide, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, agriculture breast 600# 1g, solvent naphtha 13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, forms the thiacloprid methoxyfenozide aqueous emulsion that main active ingredient weight percentage is 55%.
Embodiment 3:
Take 2g thiacloprid, 18g methoxyfenozide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, agriculture breast 600# 1g, cyclohexanone 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and forms the thiacloprid methoxyfenozide microemulsion that main active ingredient weight percentage is 20%.
Embodiment 3 is prevented and treated to the vegetables diamond-back moth test of pesticide effectiveness, according to the consumption medication in form 3, every mu of ground medication 20g, 30g, contrast medicament is 40% methoxyfenozide EC(missible oil) 30g/ mu and 15% thiacloprid EC30g/ mu, with clear water, do blank, the result of looking into 3 days, 7 days, 14 days and 28 days after medicine, result is in Table 3:
Table 3: the composite field test results to vegetables diamond-back moth of thiacloprid methoxyfenozide
Field efficacy result shows, thiacloprid methoxyfenozide composition antagonism diamond-back moth has good control efficiency, and control efficiency is all better than the effect that single dose kind is used separately.
Embodiment 3 is prevented and treated to cotton cotton bollworm field medicine effect test, according to the consumption medication in form 4, every mu of ground medication 20g, 30g, contrast medicament is 40% methoxyfenozide EC(missible oil) 30g/ mu and 15% thiacloprid EC30g/ mu, with clear water, do blank, after medicine, look into 3 days, the result of 7 days, 14 days and 28 days, result is in Table 4:
Table 4: the composite field test results to cotton bollworm of thiacloprid methoxyfenozide
Field efficacy result shows, thiacloprid methoxyfenozide composition antagonism cotton bollworm has good control efficiency, and control efficiency is all better than the effect that single dose kind is used separately.
Embodiment 4:
Take 1g thiacloprid, 5g methoxyfenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the thiacloprid methoxyfenozide missible oil that main active ingredient weight percentage is 6%.
Embodiment 5:
Take 50g thiacloprid, 20g methoxyfenozide, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the thiacloprid methoxyfenozide missible oil that main active ingredient weight percentage is 70%.
Embodiment 6:
Take 2g thiacloprid, 40g methoxyfenozide, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the thiacloprid methoxyfenozide missible oil that main active ingredient weight percentage is 42%.
Embodiment 7:
Take 0.2g thiacloprid, 50g methoxyfenozide, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the thiacloprid methoxyfenozide missible oil that main active ingredient weight percentage is 50.2%.
Embodiment 8:
Take 5g thiacloprid, 0.5g methoxyfenozide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the thiacloprid methoxyfenozide missible oil that main active ingredient weight percentage is 5.5%.
Embodiment 9:
Take 5g thiacloprid, 30g methoxyfenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the thiacloprid methoxyfenozide missible oil that main active ingredient weight percentage is 35%.
Embodiment 10:
Take 20g thiacloprid, 5g methoxyfenozide, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the thiacloprid methoxyfenozide missible oil that main active ingredient weight percentage is 25%.
Embodiment 11:
Take 30g thiacloprid, 12g methoxyfenozide, sodium lignin sulfonate 2g, alkyl phenol (or fatty alcohol) polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, forms the thiacloprid methoxyfenozide suspending agent that main active ingredient weight percentage is 42% under the effect of sand mill.
Embodiment 12:
Take 2g thiacloprid, 5g methoxyfenozide, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 21g, forms by water dispersible granular agent method the thiacloprid methoxyfenozide water dispersible granules that main active ingredient weight percentage is 14% by above raw material.
Embodiment 13:
Take 50g thiacloprid, 3g methoxyfenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the thiacloprid methoxyfenozide missible oil that main active ingredient weight percentage is 53%.
Embodiment 14:
Take 2g thiacloprid, 18g methoxyfenozide, sodium lignin sulfonate 10g, Negel 2g, with diatomite, add to 100g, above raw material is mixed in micronizer, form the thiacloprid methoxyfenozide wetting powder that main active ingredient weight percentage is 20%.
Embodiment 15:
Take 7g thiacloprid, 70g methoxyfenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the thiacloprid methoxyfenozide missible oil that main active ingredient weight percentage is 77%.
Embodiment 16:
Take 60g thiacloprid, 5g methoxyfenozide, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 13g, forms by water dispersible granular agent method the thiacloprid methoxyfenozide water dispersible granules that main active ingredient weight percentage is 65% by above raw material.
Claims (10)
1. containing a compound pesticide compositions for thiacloprid and methoxyfenozide, it is characterized in that it is main active ingredient that this Pesticidal combination be take thiacloprid and methoxyfenozide, wherein, the weight ratio of thiacloprid and methoxyfenozide is 0.1 ~ 80:0.5 ~ 80.
2. the compound pesticide compositions containing thiacloprid and methoxyfenozide according to claim 1, is characterized in that described thiacloprid and the weight ratio of methoxyfenozide are 0.5 ~ 50:2 ~ 50.
3. the compound pesticide compositions containing thiacloprid and methoxyfenozide according to claim 2, is characterized in that described thiacloprid and the weight ratio of methoxyfenozide are 0.5 ~ 10:4 ~ 30.
4. the compound pesticide compositions containing thiacloprid and methoxyfenozide according to claim 1, is characterized in that the two weight percentage in this compound pesticide compositions of thiacloprid and methoxyfenozide is 3% ~ 80%.
5. the compound pesticide compositions containing thiacloprid and methoxyfenozide according to claim 4, is characterized in that the two weight percentage in this compound pesticide compositions of thiacloprid and methoxyfenozide is 5% ~ 55%.
6. the compound pesticide compositions containing thiacloprid and methoxyfenozide according to claim 5, is characterized in that the two weight percentage in this compound pesticide compositions of thiacloprid and methoxyfenozide is 10% ~ 40%.
7. the compound pesticide compositions containing thiacloprid and methoxyfenozide according to claim 1, is characterized in that this compound pesticide compositions take thiacloprid and methoxyfenozide and be mixed with any one formulation allowing on agricultural chemicals as main active ingredient and insecticides adjuvant, excipients.
8. the compound pesticide compositions containing thiacloprid and methoxyfenozide according to claim 7, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersible granules.
9. the compound pesticide compositions containing thiacloprid and methoxyfenozide claimed in claim 1 is prevented and treated the application on the insecticidal materials of any one or a few insect in resistance Homoptera, Lepidoptera, coleoptera, thrips and mite class in preparation.
10. this compound pesticide compositions that is applied as according to claim 9 is prevented and treated the application on the insecticidal materials of any one or a few insect in the application on the insecticidal materials of the insects such as plant hopper, aleyrodid, leafhopper, aphid, diamond-back moth, cotton bollworm, beet armyworm, thrips thrips and mite class in preparation.
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| CN201210281594.9A CN103563961B (en) | 2012-08-05 | 2012-08-05 | A kind of compound pesticide compositions containing thiacloprid and methoxyfenozide and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106689149A (en) * | 2015-07-20 | 2017-05-24 | 江苏龙灯化学有限公司 | Insecticide composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4849432A (en) * | 1986-03-07 | 1989-07-18 | Nihon Tokushu Noyaku Seizo K.K. | Heterocyclic compounds |
| CN1430470A (en) * | 2000-04-14 | 2003-07-16 | 拜尔公司 | Active substance combinations with insecticidal and acaricidal properties |
| CN101305732A (en) * | 2007-12-27 | 2008-11-19 | 天津市兴光农药厂 | Pesticide combination containing thiacloprid |
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2012
- 2012-08-05 CN CN201210281594.9A patent/CN103563961B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4849432A (en) * | 1986-03-07 | 1989-07-18 | Nihon Tokushu Noyaku Seizo K.K. | Heterocyclic compounds |
| CN1430470A (en) * | 2000-04-14 | 2003-07-16 | 拜尔公司 | Active substance combinations with insecticidal and acaricidal properties |
| CN101305732A (en) * | 2007-12-27 | 2008-11-19 | 天津市兴光农药厂 | Pesticide combination containing thiacloprid |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106689149A (en) * | 2015-07-20 | 2017-05-24 | 江苏龙灯化学有限公司 | Insecticide composition |
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| CN103563961B (en) | 2016-07-06 |
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Effective date of registration: 20180523 Address after: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Co-patentee after: Nanjing Redsun Co., Ltd. Patentee after: Nanjing Huazhou Pharmaceutical Co., Ltd. Address before: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Patentee before: Nanjing Huazhou Pharmaceutical Co., Ltd. |